AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

The use of gasoline oxygenated with MTBE (methyl tert-butyl ether) reduced significantly air pollution (16 - 23% lower emissions of CO and 18% lower emissions of unburned hydrocarbons) but increased water pollution. There is no European or national regulations for MTBE in drinking water except for Denmark, which has set a limit value of 30 Âľg/ L for MTBE. USEPA proposed a maximum concentration of 20- 40 Âľg/L. This paper is a review with 70 references on the MTBE production, use, properties and...
Autori: Camelia Beţianu, Florina Ungureanu, Loredana Branza, Lucian Vasile Pavel, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25122

In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

AbstractLead is unique among the toxic air contaminants that the World Health Organization (WHO) has identified it in several ways. Lead concentration is increasing rapidly in the environment due to increased use in anthropic activity. Lead is released into the atmosphere from metallurgy and siderurgy industry, during coal burning, oil or wastes, from power plants which use solid fuel, from traffic and the building sites. Regardless the exposure mode, the presence of lead in urban air, even in r...
Autori: Alina Murariu, Aurelia Meghea, Aurelian Stanescu, Ioana Lacatusu, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25205

In this work, the ability of Romanian peat for sorption of Pb (II) ions from aqueous solution has been determined using the batch experimental techniques. The sorption equilibrium has been studied at different pH values. The equilibrium adsorption level was determined to be dependent of the pH of solution and initial Pb(II) concentration.The equilibrium adsorption capacity of Romanian peat sorbent for lead has been described by seven types of mathematical model isotherms, namely: Freundlich, Lan...
Autori: Brindusa Robu, Corneliu Cojocaru, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25160

In recent years, the release of volatile organic compounds (VOCs) has received much attention. Catalytic oxidation of VOCs, found in small concentration in industrial gas emissions constitutes an alternative for environmental pollution reduction.In this paper, a comparative study regarding the non-catalytic and catalytic oxidative destruction of non-halogenated or halogenated C6 hydrocarbons (C6H14, C6H12, C6H6, Cl-C6H5, Br-C6H5), is presented. Catalytic oxidation was studied in the presence of ...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25162

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueBiosorption of Cu2+ ions from aqueous solution by Enteromorpha sp.Loredana Brinza, Matthew Dring, Maria Gavrilescu  Environmental impact assessment for steel processingBrindusa Robu, Carmen Zaharia, Matei MacoveanuEnhanced primary treatment of municipal wastewater by ion exchange and membrane processesDaniela Teleman, Peter A. Wilderer, Carmen Teodosiu, Thilo K?śtzle Best practices in kraft pulping - benefits and costs Dan GavrilescuAspects of waste m...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25177

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

AbstractHeavy metals can be transported by rivers which flow through areas with industrial pollution, both as metal in solution and metal adsorbed to suspended solids. They can settle in lakes and accumulate in the sediment, exhibiting significant effects on wildlife and humans if they enter into the food chain.In this work, heavy metals transport and sedimentation is simulated based on an analytical model proposed in literature, considering the material balance and complementary equations, unde...
Autori: Camelia Beţianu, Florina Ungureanu, Loredana Branza, Lucian Vasile Pavel, Maria Gavrilescu, Simona Pintilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25197

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractThe paper presents original results concerning concentrations of eight heavy metals in soils adjacent to two improperly built municipal waste deposits located in Eforie Sud and Techirghiol, Constanta County, Romania. Measurements have been done on surface and depth soils, during April-October 2006. The applied analytical technique for metal determination was flame atomic absorption spectrometry (FAAS). The mean measured values ranged as follows (in mg/kg dry weight): Cd: 0.09 - 0.15; Co:...
Autori: , Elisabeta Chirilă, Narcisa Elena Ilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25213

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractThis paper dealt with Cr(VI) sorption on isomorphic substituted Mg/Zn-Al - type hydrotalcites under proper working conditions. The prepared samples were named Mg3Al, Mg2ZnAl, Mg1.5Zn1.5Al, MgZn2Al and Zn3Al. The experimental data concerning sorption isotherms were modelled in accordance with four equilibrium equations: Langmuir (L), Freundlich (F), Langmuir-Freundlich (L-F) and Redlich-Peterson (R-P) by using two ways: (i) estimation of qmax, K and n; and (ii) estimation of K and n, for ...
Autori: Aurel Iovi, Eveline Popovici, Laura Cocheci, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25215

AbstractVolatile organic compounds (VOCs) constitutes an important class of environmental pollutants, which, together with other contaminants as NOx, SOx, CO, NH3, CO2 etc. participate in degradation of atmosphere and exhibit a potential risk for human health. VOC emissions may be generated in more than 25 percentages through the use of solvents in different industrial or house holding activities. For applying a certain plan concerning the pollution reduction, any user of organic solvents contai...
Autori: Florin Bandrabur, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25218

AbstractThe present paper suggests making an intelligent video system of command over crossroads with traffic lights, its main goal being diminishing road congestion, a better traffic speed of vehicles, diminishing the environment pollution and improvement of negative effects that vehicle concentration has over the physical and psychological state of the population....
Autori: Codrin Donciu, Marinel Temneanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25224

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractSome industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the s...
Autori: Alina Soceanu, , Simona Dobrinas, Vasile Magearu, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25227

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractCadmium is listed by US-EPA as one of priority pollutant and as a known carcinogen, and therefore its removal from wastewaters of various industrial processes is a very important environmental problem. The paper analyzes the effectiveness of a Romanian sphagnum moss peat as available and cheaper sorbent in removal of Cd (II) from aqueous solutions. Batch sorption experiments were carried out in order to establish the influence of solution pH, peat dose, contact time and initial cadmium c...
Autori: Catalin Balan, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25231

AbstractThe paper presents new experimental results on the photodegradation of two important phenyl urea herbicides in water: Monuron and Isoproturon. The photodegradation was performed by two Advanced Oxidation Processes (AOPs): the homogeneous photo- Fenton process (, UV-H2O2 - Fe3+) and a heterogeneous photo - Fenton reaction using an iron pillared Laponide- RD catalyst (Fe-Lap-RD). The Fe-Lap-RD catalyst was prepared from iron nitrate 0.2 M solution and a suspension of Laponite - RD clay. Th...
Autori: Elsa Lundanes, Ilie Siminiceanu, Maria-Magdalena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25234

AbstractThe removal of formasine fines particles from water by precipitation with polyelectrolyte and surfactant complex of Polyacrylamide (industrial product Praestol 611 made by Degussa) and Sodium Lauryl Sulphate (SLS) was experimentally studied. Calcium oxide was added to initiate precipitation of the polyelectrolyte complex together with the fines particles. The experiments were carried out with complexes having the surfactants concentration higher then the critical aggregation concentratio...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25238

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractDespite its well known toxic effects, lead continues to be a part of modern life. Lead concentrations in the environment have increased steadily throughout history, with a huge increase when lead became a common additive to paint and gasoline. Although the use of lead in gasoline and most paint has been banned in many countries, there are still many ways for lead to be released on the environment. The effects of lead on human health have been the subject of significant international exam...
Autori: Alina Murariu, Aurelia Meghea, Ioana Lacatusu, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25244

AbstractLaboratory scale experiments were conducted in order to investigate the photolysis of Reactive Blue 19 (RB 19) dye using UV as the irradiation source in alkaline solution. The effects of operating parameters such as, pH, initial dye concentration, UV dosage, hydrogen peroxide and oxygen have been evaluated. The results indicate that the UV photolysis process in alkaline solution is ideal for decolorizing of RB 19 and it can be taken as a starting step to establish the economical feasibil...
Autori: Abbas Rezaee, Ebrahim Hajizadeh, Gholamreza Mosavi, Mohamadtaghi Ghaneian, Seyyed Jamalodin Hashemian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25245

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractThis paper deals with a statistical treatment applied to the determination of U(VI)/U(IV) ratio in some uranium ores, depending on the pH and humidity samples taken out directly from a uranium mine. The concentrations of different uranium species were determined spectrofotometrically. Some statistical parameters were calculated for a subsequent statistical interpretation of the experimental data....
Autori: Alexandru Cecal, Gabriel Barbir, Marian E. Răileanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25255

AbstractIn this study, we follow the chrome distribution and his association forms with mineral and organic components, from 14 soilsamples from industrial zone of IaÂ?i city.The total chrome concentration in studied soil samples varied between 11.73-129.35 μg/g, being lower than the normal values only for four samples. The Cr(VI) weight of total chrome content varied between 3.78-14.52 %. For none of studied soil samples the chrome content is not over to value of alert concentration. The q...
Autori: Constantin Rusu, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25260

AbstractAdvanced closing of paper machine circuits results in the accumulation of the dissolved and colloidal substances (DCS) in the process water. At a critical concentration, the DCS are destabilizing even by small variations in paper machine parameters, producing operational and product quality problems. This article presents results of lab experiments simulating the process water recycling in short circuit of paper machine, without and with addition of fixing agents. Tests were performing w...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25261

AbstractThe purpose of this paper was to quantify the environmental impact and risk applying a new integrated method designed as a soft SAB. The evaluation of impact and risk induced in environment was performed for surface  waters (Bahlui River, IaÂ?i), considering the presence of some minerals and heavy metals in surface water in high concentrations. The new method for integrated environmental impact and risk assessment that considers the pollutants concentration levels in surface water w...
Autori: Brindusa Robu, Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25262

AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

AbstractTheoretical and experimental studies of gas drying processes by adsorption in fixed bed of grains are presented in this paper. Based on an extensive literature study, some of the most representative mathematical models describing gas adsorption in fixed bed and consequently gas drying processes by adsorption in fixed bed are also presented. Using a mathematical model from those mentioned describing adsorption under isotherm regime, the temperature and gas flow velocity effects over the d...
Autori: Marius Sebastian Secula, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25272

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractSoil pollution causes significant damage to the environment and human health as a result of their mobilities and solubilities.Significant progress has been made in regulating soil pollution, with a parallel development of methodologies for soil assessmentand remediation. The selection of the most appropriate soil and sediment remediation method depend on site characteristics, concentration, type of pollutants to be removed, and the end use of the contaminated medium. The approach include...
Autori: Attar Singh Sheoran, Poonia Poonam, Vimla Sheoran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25291

AbstractThe possibility of biological phosphorus removal (BPR) was studied using a lab-scale single reactor the same as SHARON process. Up to now, there has been no investigation of the feasibility of SHARON process for the purpose of phosphate removal. The optimal operation conditions were established to obtain highest removal rates. Under the experimental conditions, the phosphorus concentration dropped from an influent concentration of 1000 mg/L to levels around 0.1 mg/L or less. It was concl...
Autori: Abbas Rezaee, Hatam Godini, Masod Solimani, Nayera Nami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25293

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractBiosorption an alternative process is the uptake of heavy metals from aqueous solutions by biological materials. The biosorption of nickel ions from aqueous solution was investigated by Nordmann fir (Abies nordmanniana (Stev.) Spach. subsp. nordmanniana) in a batch adsorption system as a function of pH, initial metal concentration, biomass dosage, contact time. The data showed that the maximum pH for efficient sorption of Ni(II) was 6.5. At the optimal conditions, Ni(II) ion biosorption ...
Autori: Handan Ucun, Ozkan Aksakal, Yusuf Kaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25295

AbstractThis paper presents the connection between the heavy metals concentration in soil and their bioaccumulation in lettuce. Lettuce is a very good bioaccumulator of heavy metals and nutrients. In general, plants manifest a certain reaction to increasing the toxic metal concentrations in soil which they are cultivated on. The differences depend on plants sensitivity, and time exposure intensity (concentration of heavy metals, cultivation length, etc.), presence or absence of nutrients and oth...
Autori: Ana-Irina Smical, Elena Pop, Jozsef Juhasz, Vasile Hotea, Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25299

AbstractThe purpose of this study was to investigate the immobilization of denitrifying bacteria on microbial cellulose (MC) for biological denitrification. A novel denitrifying bacterium, Pseudomonas stutzeri, was immobilized in microbial cellulose and introduced into an up flow packed bed reactor in order to remove nitrate from synthetic influent. The MC presented the high biomass concentration throughout the experiment, achieving 3.4 mg biomass/g support. The efficiency of the system for deni...
Autori: Abbas Rezaee, Hatam Godini, Hossein Bakhtou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25302

AbstractA greenhouse experiment was conducted to determine the phytotoxic effect of heavy metals such as Cd, Cu, Ni, Pb and Zn on the growth of Sunflower (Helianthus annuus): on the seed germination, root/shoot growth and uptake of metals in soil-vermicompost media. The selected metals were dosed at various concentrations ranging from 0, 5, 10, 20, 40 and 50 ppm separately in soil - vermicompost media (3:1) in pot experiment. The seed germination, root and shoot growth were found significantly a...
Autori: Chhotu D. Jadia, Madhusudan H. Fulekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25306

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

AbstractThe aim of this paper was to accurately analyze the sources of water pollution and loading concentrations in textile finishing mills. A process data collection was performed and integrated with a characterization of the process effluents in terms of treatability and reusability. In order to evaluate properly the wastewater loading, an analysis course was set. The samples have been gathered for two months; instantaneous samples (PI) were drawn from the wastewater, as well as from the pain...
Autori: Irina-Isabella Savin, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25314

AbstractThe question of whether environmental assessment has achieved its goal of helping to reach better decisions has continually engaged the attention of academics, policy makers and environmental impact assessment practitioners. Answering this question requires several different groups working together and/or in sequence, and examining the effectiveness of environmental impact and risk assessment. EIA has tended to focus on the identification of impacts associated with planned activities or ...
Autori: Brindusa Robu, Elena Doinita Carlig, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25321

AbstractAt global level, the microbiological quality of water is a matter of concern, since diarrhoea represents the second cause of mortality. In addition, nitrates represent a significant problem and their high concentration - above the accepted limits - in drinking water is frequently encountered in Romania. Water samples have been analyzed in accordance with the methodology recommended by The Public Health Institute Bucharest. 78.15% of the water samples evaluated during the interval 2004-20...
Autori: Claudia Sarmasan, Lucia Daina, Sonia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25325

AbstractDrinking water treatment plays an important role in maintaining public health. Chlorine is the most often disinfectant used for microbiological protection of water. Required residual chlorine concentration must be in treated water when it leaves treatment plant, to comply with the regulations. The chlorine residual must be 0.5 mg/L at the entrance into the distribution system and 0.25 mg/l at consumers, according to the law. Any less and there is no guarantee that the water has adequate ...
Autori: Dan Robescu, Diana Robescu, Nicolae Jivan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25328

AbstractThe removal of Acid Red 398 (AR398) dye from dye-containing solution using coagulation/flocculation process with polyaluminum chloride (PAC) and Alum was investigated. The effect of different parameters involving pH, dosage of coagulant, initial dye concentration, and bentonite as a natural coagulant aid was examined. According to the obtained results, the optimum pH, at which the maximum removal occurred, was about 4 and 5 for PAC and Alum, respectively. However, PAC performed efficient...
Autori: Maryam Hasani Zonoozi, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25335

AbstractNatural hemp fibers have been evaluated for Zn (II) ions sorption from diluted aqueous solutions. In order to establish the optimum conditions, the effect of initial pH of solution, hemp dose, Zn (II) concentration, temperature and contact time of phases on the Zn (II) sorption by natural hemp has been studied. To model the Zn (II) sorption at three different temperatures the Langmuir and Freundlich isotherms have been used. The Langmuir maximum sorption capacities were determined as bei...
Autori: Carmen Paduraru, Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25336

A study was conducted to investigate the organic compounds residues in different types of coffee from market inThe detection limits ranged from 0.02 ng/kg to 0.04 ng/kg and quantification limits were 0.2 ng/kg. Calibration and recovery studies gave satisfactory results. Concentrations of OCPs in coffee samples varied from 0.001 mg/Kg to 0.007 mg/Kg. The methods provide a rapid and accurate determination of these organic compounds in coffee samples....
Autori: Gabriela Stanciu, Mariana Popescu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25338

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

Abstract        The sorption of metal ions from aqueous solution plays an important role in water pollution control and in recent years there has been considerable interest in the use of low-cost adsorbents. Many researchers have tried to exploit naturally occurring materials as low-cost adsorbents, for removing of heavy metals. In this article the removal performance of various low-cost adsorbents derived from agricultural waste or natural material is evaluate...
Autori: Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25379

AbstractPaint sludge of automotive industry contains heavy metals and other toxic substances. Due to this matter, it has a high pollution potential. Incorrect disposal of paint sludge led to kinds of environmental pollution. Recycling and reusing of wastes can be one of the best solutions for decreasing of pollutant entrance to environment. The purpose of this study was to present a new method of extracting the main components of paint sludge, for determining concentration of elements in paint s...
Autori: Azadeh Akhavan Bloorchian, Seyed Mostafa Khezri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25346

AbstractUrban air pollution is responsible for the highest burden of environmentally related diseases in Europe. Air pollutants with strongly indicated respiratory health effects are particulate matter, nitrogen oxides and sulfur dioxide. The retrospective ecological survey has taken into account the urban air pollution with sulfur dioxide (SO2), nitrogen dioxide (NO2), ammonia (NH3) and particulate matter (PM10). The analyzed data show that after applying the European regulations regarding the ...
Autori: Catalin Adrian Petrisor, Dorin Petrişor, Lucreţiu Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25348

AbstractA study was fulfilled concerning the source and the distribution of PAHs in the effluent proceeding from an oil refinery. The monitoring of the PAHs concentration in the refinery’s effluent also was performed during a year long. The practical goal of the work was to observe the complying with the limits imposed by the current legislation and to identify the potential risks of exceeding these limits in the future. For this study, gas chromatographic and HPLC methods were used. The metho...
Autori: Anca Iuliana Birladeanu, Claudia Irina Koncsag, Mariana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25357

AbstractPolycyclic aromatic hydrocarbons (PAHs) are included in the European Community (EC) and in the Environmental Protection Agency (EPA) priority pollutant list due to their mutagenic and carcinogenic properties. PAHs emissions from automobile traffic and industry activities were shown to influence the PAHs levels and profiles in vegetables grown nearby. The levels of 15 PAHs were determinate in samples of pepper (Capsicum Annuum) and tomato (SolanumLlycopersicum) in different stages of plan...
Autori: Alina Soceanu, Dan Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25360

AbstractThe study on the distribution of oxygen transfer rate in a stirred bioreactor for Propionibacterium shermanii broths underlined the major influence of the presence and concentration of biomass on the interphasic transfer of oxygen. Owing to the bubbles surface blockage by the bacterial cells, the accumulation of biomass from 30.5 to 120.5 g/l d.w. led to the decreasing of kla for about 1.3- 2.4 times. Compared with the simulated broths without biomass having similar apparent viscosity, t...
Autori: Adina Segneanu, Anca-Irina Galaction, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25364

AbstractThe main goal of this study is to determine the trend in exhaust concentrations during the last 12 years. Accordingly, a nondisperse infrared gas analyzer was used to measure the concentrations of carbon monoxide (CO) and hydrocarbons (HC) emitted from vehicle exhaust. A total of 449 vehicles distributed across model years ranging between 1968 and 2005 were tested under idling conditions. The results indicated that there is a strong relationship between the age of the vehicle and the con...
Autori: Kamel Al Zboon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25365

AbstractThis paper analyses a new technology for minimizing the use of metalworking fluids (MWF) during the machining process. Despite the fact that near dry machining (NDM) produces almost similar cutting performance to conventional flood supply machining while using much less MWF, for being fully utilized in industry is necessary to research ecological impact of these machining techniques. To take full advantage of minimal quantity lubrication (MQL) technique and expand its applicability, an u...
Autori: Domnita Florina Fratila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25382

AbstractThe lead(II) ions sorption from aqueous solutions on three types of peat from Poiana Stampei (Romania) was studied. The peat was drawing from different deeps, such as 5-10 cm deep (peat 1), 0.5-1.0 m deep (peat 2) and from > 1.5 m deep (peat 3). The influence of several experimental parameters (initial lead concentration, contact time) was studied in batch experiments. The kinetics of sorption was followed based on the amount of lead(II) ions retained at various time intervals. The re...
Autori: Laura Bulgariu, Mioara Răţoi, Dumitru Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25389

AbstractUltrafiltration (UF) represents an important option for the advanced wastewater treatment as it offers good performances from both technical and economical points of view, for the removal of suspended solids, colloids and some of the organic compounds present in different effluents. The occurrence of priority organic pollutants in wastewaters streams and the environment has raised intensive scientific debates about their effects and the possible abatement technologies. As part of a broad...
Autori: George Barjoveanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25390

AbstractThe adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated. The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed at 30, 40 and 50 ?C. Thermodynamic potentials ?H, ?S, and ?G and isosteric heats of adsorption were calculated from experiment performed at different temperatures (30-50?C...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25393

Abstract The efficiency of Cd (II) removal from aqueous solutions was investigated using Sphagnum moss peat as sorbent. A 23 orthogonal central composite design was successfully employed for experimental design and analysis of results. The combined effect of the initial solution pH, peat dosage and initial Cd (II) concentration was studied and optimized using Response Surface Methodology (RSM). The optimum values of these variables were found to be pH = 4.72, 14.7 g peat /L and 13.64 mg Cd /L, ...
Autori: Catalin Balan, Corneliu Cojocaru, Petru Bulai, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25399

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract Fine particulate matter and ground-level ozone are now generally recognized as the most significant in terms of health impacts. This study shows that concentrations of particulate matter up to 10 microns in diameter (PM10) in Suceava city exceeded EU limits set to protect human health during 2004-2007. In order to design effective PM10 air quality management programmes, it is essential to identify the sources affecting PM10 background levels. For this, PM10 data series were analyzed ...
Autori: Lacramioara Gina Ursul, , Doina Carmen Manciuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25409

Abstract A set of experimental data resulted from environmental monitoring and its informational content has to be revealed and checked for its statistical character. As a result in this paper the aim was to verify if the environmental monitoring data obtained for a specific air pollutant monitored during three years presents statistical properties. Based on the results obtained by applying statistical requirements such as fixed location, fixed variation, randomness and fixed distribution, a ...
Autori: Irina Meghea, Mihaela Mihai, Ioana Lacatusu, Tiberiu Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25410

Abstract Pollution with toxic metals is a serious concern, because once these elements enter in the soil they can be present for a long time, with the potential contamination of drinking water sources. Certain metals in soil may be taken up by plants which are subsequently harvest for human consumption. Our objective was to study the presence of heavy metals in soils, groundwater sources, some medicinal plants from areas of the water sources and in its watery extracts. All of the samples, af...
Autori: Diana Diaconu, Victor Nastase, Mara Mihaela Nanau, Ovidiu Nechifor, Elena Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25411

Abstract Phytoremediation is an eco-friendly, cost effective, in situ treatment technology. In the present research study, phytoremediation technology has been employed for remediation of radionuclides namely 137Cs and 90Sr by using living green plant Catharanthus roseus. C. roseus plants were exposed to different activity levels of 137Cs and 90Sr in aquatic condition to assess the efficiency of plants for remediation of radionuclides. C. roseus plants have been found to remediate 70%, 52% an...
Autori: Singh Anamika, Susan Eapen, Madhusudan H. Fulekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25417

Abstract Textile industry is one of the most pollutant and water consuming industries. Large quantities of water are required in materials preparation and dyeing, so consumption and waste generation have become serious concerns for textile manufacturers and finishers. Textile effluents are characterized by high values of quality indicators such as BOD and COD, suspended solids and heavy metals. A serious environmental problem and also an aesthetic problem is the color of the effluent. Reactiv...
Autori: Daniela Cailean, George Barjoveanu, Corina - Petronela Musteret, Liliana Rozemarie Manea, Nicolae Sulitanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25420

Abstract This study examined the effect of hexane concentration in the inlet gas stream on the treatment performance of a concentric tube internal loop airlift bioreactor with a 7 L capacity, inoculated with a strain of Pseudomonas aeruginosa. The experiments were conducted employing hexane-contaminated air, in 0.62, 1.26, 2.15 and 4.5 g/m3 concentrations at 29 ¹ 1°C. The 100% hydrocarbon removal was verified when effluents containing 0.62 and 1.26 g/m3 of hexane were employed. Under contin...
Autori: Fernando Jorge Santos Oliveira, Leonardo Vazquez, Francisca Pessoa de Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25437

Abstract The Romanian standard for the analytical method for phenols measurements in aquatic media was subject of internal validation procedure, adapted to the specific concentration domain of the laboratory. Method performance criteria were investigated on standard samples measurements: selectivity, linearity domain, precision, accuracy, limit of detection, limit of quantification androbustness. The validated method was further used on real samples of domestic and industrial wastewaters from...
Autori: Carmen Dima, Cristina Jelescu, Camelia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25448

Abstract Spent hydroprocessing catalysts from petroleum refining industries have been classified as hazardous wastes due to their content in heavy metal and persistent organic pollutants (POPs). The aim of our paper determine the polycyclic aromatic hydrocarbons (PAHs) residues contents in spent catalysts samples from four different units of the Romanian refinery Rompetrol Rafinare,Constanta: Hydrogen (H), Gas Desulfurization Sulfur Recovery (GDSR), Hydrofining Turbojet Kerosene (HTK) and Pet...
Autori: Camelia Draghici, , , Gabriela Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25449

Abstract The methods generally used for developing these studies are the assessment and investigation. Assessment – all methods used for measuring, reckoning, modeling, forecasting or estimating the presence of a pollutant in the environment. Investigation - the process of identifying the presence of pollutants in the environment, the spatial dispersion of these pollutants, the level of their concentration, as well as the analysis of the environment’s structure. The steps that were follow...
Autori: , Gheorghe - Viorel Cosara, Calin Baciu, Ileana - Codruta Stezar, Augusta - Diana Crisan, Camelia Costan, Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25451

Abstract The paper presents new studies about the removal efficiency of the biochemical treatment process of the Municipal Wastewater Treatment Plant from Constanta city, during 2008. Influent and effluent samples of biochemical treatment stage were collected and ammonium concentration, chemical oxygen demand (CODCr) and biochemical oxygen demand in five days (BOD5) were measured, aiming to study the evolution of the removal efficiency, during 2008. Additional analyses have been performed in ...
Autori: Elisabeta Chirilă, Camelia Draghici, Adriana Puhacel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25458

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract Two types of zeolite-modified electrodes, e.g., Ag-doped zeolite-expanded graphite-epoxy (AgZEG) and Cu-doped zeoliteexpanded graphite-epoxy (CuZEG) composite electrodes were tested for the application of the electrochemical determination of 4-aminophenol (4-AP). The electrochemical techniques used for the electrochemical determination of 4-AP were cyclic voltammetry (CV) and chronoamperometry (CA). Some aspects related to the mechanistic behaviour are discussed. The electrochemical ...
Autori: Cornelia Ratiu, Carmen Lazau, Corina Orha, Ioan Grozescu, Aniela Pop, Daniela Sonea, Florica Manea, Georgeta Burtica, Joop Schoonman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25468

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract The purpose of this work is to investigate the secondary Al slag (SAS) relating to its technical and environmental properties and, as consequence, to its compatibility with Portland cement matrix. This study may be a contribution to establish of SAS potential valorization as secondary raw material (SRM) in low strength cement matrix composites, as construction products. DRX mineralogical analyses revealed that SAS includes transition alumina compounds, especial boehmite. The hydrati...
Autori: Maria Gheorghe, Nastasia Panait, Romanita Teodorescu, Maria Roman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25498

Abstract It is known that carbonhydrates are precursors of all bioactive substances we tried in thes paper work to do some investigation on these substances in the environmental area of Iasi. To observe the influence of some chemical mutagens substances on carbohydrates biosynthesis we conducted investigations on plant material (leaves) taken from the Calendula officinalis L species. We used this assay to examine the effects of the herbicide 2,4- dichlorophenoxyacetic acid (2,4-D), etidium br...
Autori: Constantin Leonte, Roxana Vatavu, Teodor Robu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25502

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract Preliminary investigation of contaminated soil in the surrounding area of a petroleum tank has been carried out based on fluorescence techniques: excitation emission matrix (EEM) and synchronous fluorescence scan (SFS). A fluorescence fingerprints library containing several EEM and SFS maps for various dilutions of Romanian crude oil in methanol, was used to confirm the identity of the soil contaminant. A calibration curve was created to estimate the contamination level of soil sampl...
Autori: Dan Savastru, Elfrida M. Carstea, Gabriela Pavelescu, Luminita Cristescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25505

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract The individual physical, chemical, and biological interactions that determine the exposure of plants and animals to chemicals associated with soils are of great importance in the assessment of contaminants bioavailability. Understanding of bioavailability processes is at last needed to improve the scientific basis of risk assessment and is the purpose of the present research. Since bioavailability processes are embedded within existing human health and ecological risk frameworks, so...
Autori: Brindusa Mihaela Robu, Camelia Smaranda, Florentina Anca Căliman, Laura Carmen Apostol, Lucian Vasile Pavel, Maria Gavrilescu, Raluca Maria Hlihor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25516

Abstract Waste management hierarchy has as priorities waste recycling and energy recovery. Unfortunately, Romania is in the situation so as the waste landfilling is still considered as a suitable solution for waste management. European Union imposed a number of regulations and programs in the field of waste treatment and management that Romania must comply. The paper describes some aspects regarding characterization of the leachate originating from the Tomesti landfill (situated in Iasi County...
Autori: Ana-Maria Schiopu, Brindusa Mihaela Robu, Ion Apostol, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25523

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract Peat moss has been widely used as low-cost adsorbent to remove a variety of pollutants, including organic compounds and metal ions from aqueous effluents. Various functional groups allow such compounds to bind on active sites of peat moss. The adsorbent used in this study was Romanian peat moss sampled from Poiana Stampei (Romania). The adsorption of Co(II) ions from aqueous solutions on Romanian peat moss was studied in batch experiments, in order to establish the influence of initi...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25533

Abstract In the textile finishing and dyeing industries, the total volume of water consumed is around 150 millions tons/year, and thus very large quantities of water are processed and produced as wastewater by textile plants. Quality indicators of textile wastewaters, like BOD and COD, have values which, in some cases, exceed 5 times the maximum concentration value (allowed by the national quality standards). One of the greatest concerns in wastewater treatment of a textile effluent is the co...
Autori: Daniela Cailean, , Florin Brinza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25538

Abstract This paper is the investigation concerning the removal, from surface water, of humic acids and of some cations (Cu2+, Al3+) on activated carbons AG-3, BAU, CASO-16 from individual solutions as well as from their mixtures both in static and dynamic conditions. The conclusions of the paper are that, when humic acids are adsorbed from micellar solutions, semiassociates are formed on the surface of activated carbon BAU (in its porous structure), while humic acids adsorption on activated ...
Autori: Tudor Lupascu, Mihail Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25539

Abstract The paper presents the surfactant-assisted solvo-thermal route to synthesize nanoparticles of cerium oxide with different shape and morphology. The precursor was calcined at 400°C for 4 h in order to obtain CeO2 nanoparticles. The obtained samples were characterized by means of thermal analysis and FTIR spectroscopy. The UV-Vis analysis was used to study the optical properties. The morphologies and nano-structures were characterized by scanning electron microscopy (SEM) and XRD. It...
Autori: Nicolae Apostolescu, Gabriela Carja, Gabriela Apostolescu, Elena Husanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25541

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract Withania frutescens plant from the south-western Morocco was used as an environmentally friendly material for the removal of As(V) ions from aqueous solutions. This work presents the characteristics of the adsorption and the desorption processes of As(V) using the dried W. frutescens plant as an environmentally friendly adsorbent. The mass of the adsorbent, the As(V) concentration, the contact time and the pH of the tested aqueous solutions were used as controlled variable parameters...
Autori: Mohamed Chiban, Gabriela Lehutu, Fouad Sinan, Gabriela Carja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25568

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract In this work, the behavior of n-hexane vapors in the adsorption-desorption cycles of non-functionalized polymeric adsorbents (MN 202 and MN 250) and granular activated carbon (AC 20) was studied. The adsorption experiments were performed in a fixed bed column, under dynamic conditions, at 30?C and atmospheric pressure. The inlet concentration of n-hexane in the air streams was 0.115 mg/cm3 (32500 ppm) and the space velocity was 2.75 s-1. Also, desorption experiments were performed in...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25584

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract The use of biomaterials as biosorbents for treatment of wastewaters will provide as a potential alternate to the conventional treatment methods. The main advantages of biosorption are high selectivity , cost effectiveness and good removal performance. World wide numerous low cost bio materials have tried for biosorption of dyes. In this present investigation, the dead biomass of Penicillium sp. fungus and wood sawdust was used as biosorbents and their capacity to removed malachite gr...
Autori: Cornel Pohontu, Florin Luca, Igor Creţescu, Manea Liliana, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25593

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The aim of this study is the evaluation of photo-Fenton as a suitable advanced oxidation process to degrade ampicillin and streptomycin antibiotics. The degradation was studied by monitoring the organic substrate concentration changes in aqueous solution as a function of reaction time using COD analysis. The oxidation process follows two successive stages. In the first stage (I) the oxidation of the antibiotics takes place with high reaction rate, leading to intermediate oxidation pr...
Autori: Cristina Orbeci, Daniela Simina Stefan, Ion Untea, Madelene Dancila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25602

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

Abstract The aim of this study was to assess nitrate removal using impregnated activated carbon (AC) with MgCl2. After impregnating of AC using heat treatment, the MgCl2 is converted to efficient MgO. The denitrification was conducted at pH 6.2, 25?C, and initial concentrations of 20 mg/L nitrate-N. The effects of the operating parameters including AC dosage, pH, and contact time have been investigated. Experimental data show that AC modified by MgCl2 was more effective than virgin AC for nit...
Autori: Abbas Rezaee, Hatam Godini, Sahand Jorfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25618

Abstract The adsorption behavior of bael tree (BT) leaf powder for cadmium ions from aqueous solutions has been investigated as a function of appropriate equilibrium time, adsorbent dose, adsorbate concentrations and pH using a batch system. Studies showed that the pH of aqueous solutions affected cadmium removal as a result of the fact that removal efficiency increased with increasing solution pH. The maximum adsorption was 93.56% at solution pH equal to 6.0, contact time of 30 min and initi...
Autori: Ponnusamy Senthilkumar, Rangasamy Gayathri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25621

Abstract In this study, the effect of adding granular activated carbon (GAC) to aerobic sequencing batch reactor (SBR) on possibility to treat a wastewater containing a reactive dye (Brill Blue KN-R) was investigated. Experiments were performed in four cylindrical Plexiglas reactors for 68 days (5 days for acclimatization of sludge and 63 days for normal operation in two separate phases). Initial dye concentrations were adjusted to 20, 25, 30 and 40 mg/L in the reactors R1, R2, R3 and R4, res...
Autori: Amir Asadi Vaigan, Hossein Hashemi, Mohammad Reza Alavi Moghaddam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25624

Abstract The Jajrood River watershed is one of the main drinking water resources of Tehran, the capital city of Iran. In addition it provides many recreational usages. However, a variety of microbial pollutions is commonly perceived in the Jajrood River, among them a high concentration of coliform group bacteria that has caused strong concerns. In this article, different aspects of microbial pollution as well as the main microbial pollution sources in the region are discussed. Coliform group ...
Autori: Mahdi Jamshidi, Mahdi Maghrebi, Masoud Tajrishy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25627

Abstract As a result of the chemical-analytical studies of the marine environment of the water area of some Black Sea ports it was found that the water content of standardized components - toxins do not exceed their maximum allowable concentration, and the corresponding sediment significantly contaminated with cadmium, lead, phenols, petroleum products....
Autori: Anatoliy Andrianov, Eugeniy Malinovsky, Inna Bezlutskaya, Inna Chebotarskaya, Oleg Nedostoup, Tatyana Kovalchuk, Valeriy Antonovich
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25628

Abstract In this study the possibility to apply the oxidation process for treating textile effluents, by using hydrogen peroxide and Fenton process was evaluated through determining the color and chemical oxygen demand (COD) removal. The experimental variables studied include the dosages of hydrogen peroxide and iron salts, oxidation time and pH value. The result showed that oxidation process using hydrogen peroxide alone is inefficient in COD and color removal, since only 25 % of COD removal...
Autori: Abdelnaser Omran, , Marniyanti Mamat Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25631

Abstract Textile dyeing process is an important source of contamination responsable for the continous pollution of the environment. Control of water pollution has importance for both organisms, which live in water and those who benefit from water. Many dyes reaching the water source are difficult to decompose and cause many problems due to their carcinogenicity. Consequently, it is important to remove these pollutants from wastewater before their final disposal. This paper reports the resuls ...
Autori: Alina Dughila, Alina Stefanache, Cornel Pohontu, Igor Creţescu, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25633

Abstract The olive mill wastewater (OMW) is a stable emulsion composed by water, olive pulp and residual oil. An approach for using this waste as a renewable resource is of greater interest. Several authors have been studding physicochemical treatment methods. However, the biological treatments allow not only the treatment, but also the effluent valorization, by producing several valuable products. This effluent is also a source of natural antioxidants and its extraction is economically attra...
Autori: Carina Pereira, Cristiana Goncalves, Isabel Belo, Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25635

Abstract The structural modification of external surface of NaY was investigated in order to enhance efficient biosorption systems consisting of a bacterial biofilm, Arthrobacter viscosus, supported on that zeolite, for removing hexavalent chromium from aqueous solutions. The supported bacterial biofilm reduces Cr(VI) to Cr(III) and this cation is then retained in the zeolite by ion exchange. NaY zeolite was modified by alkali-treatments using NaOH 2.0 M, with two different contact periods of...
Autori: Bruna Silva, Cristina Quintelas, Hugo Figueiredo, Isabel C. Neves, Manuel F.R. Pereira, Teresa Tavares
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25637

Abstract The aim of this work was the evaluation of the denitrification potential of a consortium of activated sludge adapted to anoxic conditions. As the carbon source is the main parameter influencing the denitrification process, in the first stage three carbon sources (acetate, citrate and glucose) were assayed in batch activity tests. The highest denitrification efficiency was ttained with acetate, being nitrate and nitrite completely reduced. The adapted sludge was then used as a potent...
Autori: Joana Azeredo, Pilar Teixeira, Rosario Oliveira, Zelia Fernandes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25638

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Biosorption of lead (II) onto the biosorbent, represented by untreated S. cerevisiae and NaOH-treated S. cerevisiae was examined and the effects of contact time were investigated. The lead (II) biosorption was fast and equilibrium was attained within 90 mins. The maximum removal ratios of lead (II) for untreated S. cerevisiae and NaOH-treated S. cerevisiae after 3 h were 48.6% and 92.5%, respectively, with initial lead (II) concentration of 40 mg/L and optimum pH of 5.0. Data obtained from batch...
Autori: Ying Zhang, Yingjie Dai, Baiyin Liu, Fang Ma, Ru Zheng, Limin Donghttp://www.ecozone.ro/reviste.php?RID=25670

Temperature distribution in the vacuum directional solidification system influenced seriously on the impurities concentration andmicrostructure in Polycrystalline Silicon. In this study, a numerical model for the transient global heat transfer for directionsolidification process has been developed by the finite element method (FEM). A two-dimension numerical simulation fortemperature distribution of directional solidification process was carried out using software Multi-physics Comsol 3.5a. Ther...
Autori: Guoqiang Lv, Wenhui Ma, Hua Wang, Xiangyang Mei, Kuixian Weihttp://www.ecozone.ro/reviste.php?RID=25671

The combustion process plays the important role to improve performance and emission of diesel engine. To improve the rate of combustion process, the fuel-air mixing process should be accelerated. In this paper, based on the Double Swirl combustion chamber, from the macroscopic characteristics and simulation analysis, the effect of the incylinder forced swirls on performance and emission of diesel engine was studied. The results indicated that due to the incylinder forced swirls, the distribution...
Autori: Chang-Yuan Wang, Fu-Shui Liu, Xiang-Rong Lihttp://www.ecozone.ro/reviste.php?RID=25673

The removal efficiency of p-xylene from gas stream was experimentally investigated in a dielectric barrier discharge (DBD) reactor, which was combined with catalyst, MnO2/Al2O3 pellets, in the discharging and the afterglow area, respectively. The CO2 selectivity of the two kinds of structure was also discussed. The results showed that in both the situation, the synergetic removal efficiency of p-xylene by the DBD-catalyst hybrid system increased with increasing the discharge power and decreasing...
Autori: Hongxia Liu, Yun Liuhttp://www.ecozone.ro/reviste.php?RID=25674

Rhizobag incubation experiments were conducted to study microbial biomass carbon (MBC), microbial biomass nitrogen (MBN), soil respiration and enzyme activity (urease and phosphatase) in the rhizosphere soil of three different wetland plants and its influence on the removal of total organic carbon (TOC) and total nitrogen (TN). MBC, MBN, soil respiration and enzyme activity were higher in the rhizosphere than in the non-rhizosphere soil of the wetland plants. Microbial activity in the rhizospher...
Autori: Defu Xu, Hua Fang, Xianghua Xu, Xiaoli Zhao, Yingxue Lihttp://www.ecozone.ro/reviste.php?RID=25679

PM10-2.5 and PM2.5 samples were collected from December 2007 to January 2008 at six sampling sites in Urumqi Xinjiang, China. The concentrations of seven kinds of water-soluble ions––SO4 2-, NO3-, Cl-, NH4 +, K+, Na+, and Ca2+––were analyzed using ion chromatography. The concentrations of heavy metal elements, Cr, Co, Cd, Pb, and Hg were measured using inductively coupled plasma mass spectrometry (ICP-MS). The results indicated that, in PM2.5 and PM10-2.5, the average mass concentration ...
Autori: Talip Dilnur, Tursun Yalkunjan, Manabu Igawa, Yimit Abulizihttp://www.ecozone.ro/reviste.php?RID=25683

Treatment of mustard wastewater with high salinity and organic concentration by electrochemical degradation was studied. The influence of the critical parameters of electro-oxidation such as pH, current density, salt concentration and energy consumption on the removal efficiency of COD and NH3-N was studied using porous carbon electrode. It was found that the COD and NH3-N removal efficiency could be enhanced by increasing pH, current density and salt concentration. The current density of 0.032A...
Autori: Hainan Ai, Qiang He, Hongxiang Chai, Xuebin Hu, Tengrui Longhttp://www.ecozone.ro/reviste.php?RID=25685

Acidithiobacillus ferrooxidans plays an important role in the pyrite oxidation process and has been widely studied in order to determine the kinetics of the reactions, but the details of the oxidation processes on the surface of pyrite keeps poorly known. In this study, the bio-oxidation process of pyrite by Acidithiobacillus ferrooxidans was studied by comparing with abiotic oxidation by Fe3+. The attachment of Acidithiobacillus ferrooxidans on pyrite surface was found by using Scanning Electro...
Autori: Lei Jiang, Huiqun Yang, Yuruo Tao, Jinyan Yanghttp://www.ecozone.ro/reviste.php?RID=25686

Our investigation in 2007 revealed that the concentration of microcystin (MC-LR) in Miyun reservoir was 0.224 μg L-1, below the safety limit of surface drinking water in China (1.0 μg L-1). The phytoplankton community in Miyun reservoir was composed of 8 divisions and 84 species (including genera and varieties). The density of phytoplangkton was 393.71?—104 cells L-1 including 24.6% of Chlorophyta, 32.5% of Cyanophyta and 15.3% of Bacillariophyta. The toxin-producing cyanobacteria incl...
Autori: Huimin Li, Guisen Du, Yumei Wu, Dianwei Wu, Jingshi Wanghttp://www.ecozone.ro/reviste.php?RID=25691

Considering the membrane fouling problem in submerged anaerobic membrane bioreactors, a set of submerged double-shaft rotary anaerobic membrane bioreactor (SDRAnMBR) was constructed by applying a double-shaft rotary module to submerged anaerobic bioreactor, and the theoretic analysis of the characteristics of hydraulics dynamics in SDRAnMBR has been performed. The membrane fouling performance for treatment of synthetic brewery wastewater was investigated by SDRAnMBR. The results of a theoretical...
Autori: Ling Bai, Chao Liu, Weiguang Lanhttp://www.ecozone.ro/reviste.php?RID=25694

Ecological adaptation of heavy metal polluted environments is significantly enhanced through plants inoculated with plant growth-promoting bacteria (PGPB), and the cost of phytostabilization in metal tailings can be reduced. On the basis of the systematic investigation of manganese tolerant plants which grew on Xiangtan manganese tailings, rhizosphere soils of th Chenopodium album Linn. were collected. One yellow manganese-resistant strain named XZL01 was isolated from the rhizosphere of fresh p...
Autori: Shengguo Xue, Yameng Ma, Xiaohua Zhou, Xiyan Zhou, Fenghao Liuhttp://www.ecozone.ro/reviste.php?RID=25696

The solubility and sorption behavior of naphthalene in the presence of dissolved organic acid was studied. The presence of dissolved organic acids at lower concentrations had only a little effect on naphthalene sorption. However, when the concentration exceeds a certain concentration, a significant inhibition was observed. Moreover, the inhibition enhanced with the increasing concentrations of dissolved organic acids. The change trend on solubility is similar to the sorption of naphthalene, that...
Autori: Jin hua Li, Bao xue Zhou, Qing Zheng, Wei min Caihttp://www.ecozone.ro/reviste.php?RID=25698

This study investigated the effectiveness of using anaerobic effluent as a nutrient supplement for cultivation of green algae Chlorella sp. Different concentration of 0%, 15%, 30%, 45%, 60%, 75%, 90% and 100% which were raw (group �r�) as well as autoclaved (group �a�) were applied to the anaerobic effluent and algae growth. They were compared in terms of growth rate and final algae biomass production. In the initial cultivation days, slower growth rates with an increased anaerobic efflu...
Autori: Yubi Chen, Renjie Dong, Gaojun Peng, Zhu Yi, Shuhao Huo, Yupeng Liu, Changle Panghttp://www.ecozone.ro/reviste.php?RID=25701

In this study, the application of freeze-concentration method to treat low-concentration polluted water was demonstrated. The effects of stirring, the temperature in a freezing cabinet and the volume of water involved in the freeze-concentration treatment of pollutants were investigated under laboratory conditions. The removal of pollutant by freeze-concentration treatment was also attempted. Results had shown that the ratio of pollutants removed was about 83% when the experiment was carried out...
Autori: Yingjie Dai, Ying Zhang, Baiyin Liu, Masahiro Teduka, Yongbo Lin, Shunitz Tanakahttp://www.ecozone.ro/reviste.php?RID=25709

This paper presents a study of the numerical simulation applied for unsymmetrical dimethylhrazine (UDMH) gas dispersion. This study considers an assumed UDMH store conditions and provides important data regarding the relation between the concentration distribution of UDMH and dispersion distance from the source based on the computation fluid dynamic (CFD) software FLUENT. The simulation results show that the ventilation vent and distance of dispersion play an important role in the concentration ...
Autori: Zhiyong Huang, Guofeng Jin, Xuanjun Wanghttp://www.ecozone.ro/reviste.php?RID=25712

Chemical composition data of coalbed produced water can provide information to determine the water sources, understand the evolution, select appropriate treatment processes and increase the utilization efficiency of water resources. Based on methods of hydrogeology, water chemistry and environmental chemistry, the characters of coalbed produced water in the Powder River Basin in the USA and Qinshui Basin in China have been analyzed. Conclusions have been drawn as follows: (1) The coalbed produce...
Autori: Guang Xu, Li Tong, Mei Yang, Yi-wen Juhttp://www.ecozone.ro/reviste.php?RID=25715

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

Abstract:Methyl orange and methylen blue are two dyes resulted from the textile industry. They are not raising just esthetical problems, butthey are toxic and hence harmful to aquatic animals. The aim of this study is to test the capacity of three types of sawdust (oak,willow and white poplar) and mixed substrates, sawdust: fly ash (FA), to remove the methyl orange (MO) and methylen blue(MB) from wastewater. The influence of contact time, solution pH and initial concentration of dyes on the blea...
Autori: Anca Duta, Dora Lucaci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25752

Abstract:The paper presents the results obtained when using one ketonic Mannich base BM (1-(2’-hydroxyphenyl)-3-(1-piperidinylamino)propan-1-one hydrochloride) as corrosion inhibitor in saline environment, for different types of carbon steels,with various alloying elements. The Mannich base was synthesized and used in corrosion experiments, in concentrations varyingfrom 0….1300 ppm. The corrosion experiments were performed by potentiodynamic polarization studies, with 50 mVs-1 scanrate. The ...
Autori: Andreea Milea, Cristina Bogatu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25754

Abstract:The study involved investigating the effects of Cr(III) and the efficacy of powdered activated carbon (PAC) in reducing theinhibitory effects of Cr(III) on activated sludge under sequencing batch reactor (SBR) operation. The addition of Cr(III) into SBRsystem caused significant inhibitory effects on the activity of activated sludge as indicated by drastic drop in specific oxygenuptake rate (SOUR). The increase of Cr(III) concentration from 5 to 10 mg/L further deteriorated the treatment...
Autori: Eiichi Toorisaka, Makoto Hirata, Soon-An Ong, Tadashi Hano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25773

Abstract:The study was conducted to evaluate the concentration variation of heavy metals in milk collected from two different groups ofsources: milk collecting centers and dairy farms. Also, their incidence in milk products, as pasteurized milk, butter milk, yogurt,cream, cheese, hard cheese was determined in the NE Romania (Moldavia).The analytical results revealed that the milk samples from the collecting centers had higher levels than the samples from the dairyfarms of Pb (2.90 to 3.45 vs. 1....
Autori: Andrei - Cristian Grădinaru, Gheorghe Solcan, Ovidiu Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25776

Abstract:In this paper, photo-catalytic process for treatment of phenolic wastewater by TiO2 nano powder immobilized on concrete surfacein a recirculation hydraulic flow was investigated. The process affected by different operational conditions that the optimum onescould be obtained from variables interchange. Taguchi method as a proper method for design of experiments and optimizationwas used to find optimum conditions. Selected five parameters at four levels were consists of initial phenol con...
Autori: Bita Ayati, Hossein Ganjidoust, Mohammad Delnavaz, Sohrab Sanjabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25778

Abstract:In this paper, the mathematical model is improved by considering the density variations of the liquid from the pollution source vs.pollutant’s concentration of this liquid and by including the sorption-desorption term (SDT), which takes into account thisphysical process, played by a first-order decay model defined by two coefficients and an exponent. In order to practically use thisimproved mathematical model, the authors inferred the calculating relationships from automatic processin...
Autori: Daniel Bucur, Esmeralda Chiorescu, Gheorghe Ţigaret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25783

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:Experimental research evaluated the possibilities of air treatment efficiency of a cylindrically shaped bio-charge, namely straw, toremove volatile organic compounds from the air. As determined during experiments, the air treatment efficiency of the straw biochargefor acetone removal reached 97.3%, while for butanol removal the efficiency was 86.0%. It has been determined that, withvolatile organic compound concentrations increasing biological air treatment efficiency is decreasing as h...
Autori: Alvydas Zagorskis, Petras Vaitiekunas, Pranas Baltrenas, Raimondas Leopoldas Idzelis,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25790

Abstract:This investigation focused on the adsorption of Pb (II) onto Lewatit FO 36 resin from aqueous solutions. The effects of initialmetal concentration, contact time, pH of solution were factors that affected the adsorption of Pb (II). Adsorption kinetic was betterexplained by the pseudo second order type 1 kinetic model that was confirmed by the values (R2>0.986). The Langmuir,Freundlich, Temkin and BET adsorption models were used for the equilibrium studies and Freundlich isotherm bette...
Autori: Alireza Asgari, Azra Setodeh, Mehdi Ahmadi, Mohamad Sedigh Mortazavi, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25791

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract: In this study, decolorization and degradation of aqueous nickel phthalocyanine reactive dye solutions was comparatively studied by electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton processes. In the electrocoagulation process with aluminum electrodes the colored aqueous solutions containing 100 mg/L nickel phthalocyanine and 6 g/L NaCl were treated at initial pH 7.5 and applied current densities of 5, 10 and 20 mA/cm2, where fast and 100% decolori...
Autori: Achilleas Christoforidis, Dimitrios Marmanis, Evgenia Valsamidou, Konstantinos Dermentzis, Konstantinos Ouzounis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25804

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

Abstract:The effect of organic carbon loadings (OCLs) on NH4+-N and Mn2+ removal was investigated using a novel approach of biological aerated filter (BAF) for drinking water treatment system. Three different OCLs of 0.2, 0.5 and 1.0 kg COD/m3.d were loaded into BAF which was operated in batch-wise at 24 h hydraulic retention time. The experiments resulted in higher COD, NH4+-N and Mn2+ removal percentages at OCL of 1.0 kg COD/m3.d with removal of 97.1%, 97.4% and 94.7%, respectively. The +-N ef...
Autori: Hassimi Abu Hasan, Noorhisham Tan Kofli, Siti Kartom Kamarudin, Siti Rozaimah Sheikh Abdullah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25808

Abstract:The aim of the present study is the optimization of biosorption conditions using a metal tolerant actinomycete (strain 723) for the removal of lead ions from waste water in batch and dynamic flow mode. The optimum conditions for lead biosorption by the strain were determined as initial pH 3.0, biomass amount 2.0 g L-1, and initial metal concentration 400 mg L-1 in the batch condition. The maximum lead biosorption performance was obtained with a 19 mm diameter column, a 1 mL min-1 flow r...
Autori: Ayşe Betül Karaduman, Maria Julia Amoroso, Mustafa Yamaç, Sergio Antonio Cuozzo, Zerrin Pat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25811

An iron(Fe+3) oxide/hydroxide nanoparticles-based agglomerates (AggFe) suspension adsorbent was synthesized for efficient, cost-effective phosphate removal. A strong effect of AggFe concentration and pH level of water containing phosphate on removal efficiency was shown. It was found that phosphate adsorption onto the AggFe suspension may be described by pseudo-secondorder reaction kinetics and the Langmuir isotherm model. The unique adsorption properties of synthesized AggFe adsorbent are demon...
Autori: Grigori Zelmanov, Raphael Semiat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25829

The aim of this work is the study of activated sludge floc samples stained with different dyes and imaged by Confocal Laser Scanning Microscopy (CLSM). Activated sludge flocs were stained for lipids, sugars and esterase enzyme producing bacteria. Images were acquired for different samples to analyze the structural characteristics of the bioaggregates. The analysis of the CLSM images allowed for the localization and estimation of the quantity of different build-up materials. The 3-D reconstructio...
Autori: Bela Abraham, Botond Raduly, Dan Niculae Robescu, Szabolcs Lanyi, Szabolcs Szilveszter, Szilard Bucs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25937

Polycyclic aromatic hydrocarbons (PAHs) are by-products of petrol transformation; a report prepared by ICON, London, United Kingdom in 2001, showed that the principal sources of polycyclic aromatic hydrocarbons in wastewater are domestic usage, storm runoff and commercial effluent. This work presents the results on 14 commonly occurring and/or highly carcinogenic PAH compounds listed as priority pollutants by the United States Environmental Protection Agency and the European Union. Wastewater sa...
Autori: Dumitru Ristoiu, Edward Muntean, Livia Alhafez, Nicoleta Muntean, Radu Mihaiescu, Tania Mihaiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25847

This paper presents a mathematical model for the prediction of pollutant transport in rivers. The model has been developed and calibrated using the Matlab software and relying on field data from Romanian Someş River (collected in case of accidental cyanide release). Field data has been used to estimate model parameters (e.g. dispersion coefficient, velocity) as variable in time and space in order account for river features non-uniformity in time and also in space. These initial parameter va...
Autori: Elisabeta-Cristina Ani, Vasile Mircea Cristea, Paul Serban Agachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25848

The removal of Cr (VI) from aqueous solutions by sphagnum peat moss was investigated in batch experiments as a function of solution pH and initial Cr (VI) concentration. The highest removal percentage (R=99%) was obtained at pH = 1, in solutions of 20.8 mg Cr (VI)/L. In order to establish the mechanism of the removal process, Cr (VI) and total Cr (Cr (VI) + Cr (III)) in residual solutions was analyzed. The Cr (VI) removal by the peat moss at low pH is governed by two processes – electrostatic ...
Autori: Catalin Balan, Doina Bilba, Irina Volf, Matei Macoveanu, Petru Bulai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25849

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

The availability of good quality water is an indispensable condition for preventing diseases and improving the quality of life. Water is one of the most important renewable resources, which must be prevented from deterioration in quality. Various physicochemical parameters like pH, alkalinity, total hardness, total dissolved solids, calcium, magnesium, nitrate, have a significant role in determining the potability of drinking water. In this study, samples were collected from wells situated in vi...
Autori: Maria Cioroi, Mirela Praisler
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25853

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

Pollutants transfer via the food chain was investigated in a wetland ecosystem from the Lower Prut Floodplain Natural Park in Romania. Trace elements (Cd, Cu, Pb and Zn) were determined by Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) from samples belonging to primary producers and primary and secondary consumers, and also from water and sediments samples. Non-essential trace elements as Cd and Pb exhibited low concentrations in molluscs and fish, but zinc had shown conc...
Autori: Alin Tudorache, Gabriel Chisamera, Gabriel Lucian Radu, Iulia Gabriela David, Laurentiu Rozylowicz, Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25855

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

Marine species (n=36) available in a supermarket of Cluj-Napoca city, Romania were collected and analyzed for the levels of heavy metals (Cr, Cu, Zn, Cd, Pb, Hg) and As, polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and analogous, hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB). The collection included samples from twelve fish groups (sardine, tuna, herring, pangasius, marbled rockcod, hake, shrimp, pink shrimp, lo...
Autori: Adriana Gog, Claudiu Tanaselia, Ioan Ştefan Groza, Marin Senila, Mirela Miclean, Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25863

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

Chromium and cadmium are heavy metals that occur naturally in the environment and especially in soils. Their toxic effect is more pronounced at high concentrations and it depends on the oxidation states. While Cr (III) is considered an essential trace element for the metabolism of living organisms, Cr (VI) has a higher mobility and is easily soluble in soils and can be leached into surface water or groundwater, and taken up by plants. That leads to a toxic and carcinogenic effect to humans via i...
Autori: Dumitru Bulgariu, Florian Statescu, Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25866

The most important argument of this experiment was to demonstrate an increased content of active principles under the influence of some substances (considered in the literature as mutagene), when used in low concentration, do not affect the environment. The purpose of this study was the selection of some treatment variants, which, during the experimentations show the same biosynthetic potential, stabilized or increased. The substances used in the experiment were ethidium bromide at the concentra...
Autori: Constantin Leonte, Marius Zaharia, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25867

In this study, we have tested the possibility of utilization of three types of natural low-cost sorbents: (Sphagnum moss peat, natural moss peat and alkaline treated moss peat) for the active biomonitoring of air quality from Căliman National Park area (Dorna Basin), during of two months (September – October 2010). The concentrations of some heavy metals (Pb, Cd, Cu, Mn and Fe) in the sorbent samples were used as an indicator of the level of air pollution in the studied region. After expo...
Autori: Iulian-Ovidiu Sandu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25868

Among the different types of waste products tested, the bark of different Pinus species have been identified as a promising class of low- cost sorbents for heavy metal binding. In this context, the potential of Romanian pine bark wastes as green and economical sorbent for cadmium (II) ions removal from aqueous solutions has been tested in batch conditions as function of initial pH, contact time, sorbent dose, metal ion concentration and temperature. The equilibrium data at three different temper...
Autori: Anca Miron, Brindusa Robu, Carmen Paduraru, Lavinia Tofan, Roxana Laura Mihailescu Amalinei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25871

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

The indoor climate of educational institutions (kindergartens, secondary schools and universities) in Estonia is investigated. The main hazards for students’ health are: the high concentration (over 800 ppm) of carbon dioxide in the classrooms that refers to the inappropriate ventilation; the non-ergonomic computer workplaces where the direction of the natural light (without blinds for the windows) is causing glare on the monitors; the low humidity of the air in winter; the low air temperature...
Autori: Ada Traumann, Piia Tint, Viiu Tuulik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25873

Herbicides industry is a large consumer of water, as well as a major wastewater generator, its effluents contain priority organic pollutants in very high concentrations which have severe effects on human health and on the environment due to their toxicity and bio-recalcitrant nature, persistence in the environment and bioaccumulation. A vast number of herbicides and other priority organic pollutants have been found in wastewater effluents, surface water, and drinking water around the world. The ...
Autori: Bianca Weinberg,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25874

Measurements of radium concentrations in water are important from the health protection point of view, so simple and reliable analytical methods must be available. In this paper we have determined the radium activity concentration in 24 spring waters which are used as potable water reservoirs. For this purpose we used radon emanation technique and also alpha spectrometry method. This work gives details of sample processing, Lucas cell and the methodology used in the emanation method. In the meas...
Autori: Alida Timar Gabor, Constantin Cosma, Oana Alexandra Rusu, Robert Csaba Begy, Simina Dreve
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25878

In this paper, Cadmium and Zinc removal from soil by phytoremediation was investigated. The experiments were carried out with two types of plants, Brassica napus and Triticales sp. Response surface modeling and optimization of Cd and Zn removal rate was performed for each type of plant under controlled conditions, i.e. as a function of Cd concentration, Zn concentration and pH. Although the maximum heavy metal uptake (i.e. 2.4 % Cd removal rate and 1.80 % Zn removal rate, respectively) was obtai...
Autori: Corneliu Pohontu, Gabriela Soreanu, Igor Creţescu, Matei Macoveanu, Paula Caraiman Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25881

The herbicide use can be seen as an auxiliary path for new farming methods, providing more advantageous farming and land use capabilities and increasing crop yields. Some of them are quickly degraded but others persist in the environmental compartments being toxic for human health and the environment.The aim of this study was to evaluate the impact of some triazine herbicides from agricultural sources on quality of well and surface water, in two regions of Romania with different agricultural act...
Autori: Andreea Dragus, Mihail Simion Beldean-Galea, Radu Mihaiescu, Tania Mihaiescu, Dumitru Ristoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25889

Global existence of a large percentage of lakes with eutrophication problems (54% in Romania) demands a predictive tool for the quality of these ecosystems. In this context, this paper proposes an eutrophication model that describes the thermal and biochemical behaviour of an eutrophic reservoir. This model was used to study an artificial lake (Goleşti reservoir) located in Romania. The conceptual model concerns a lake, which is considered as a closed aquatic system, and analyze a simply fo...
Autori: Gabriela Elena Dumitran, Iulia Rodica Damian, Liana Ioana Vuta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25890

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

Two experimental periods have been undertaken to investigate the biodegradability of sewage streams (mainly regarding the organic substances) produced by a gas cartridge production, filling and distribution company. A sequencing batch reactor (SBR) was used for the laboratory examinations launched with municipal sewage sludge with a concentration of approx. 3 g MLSS/L. The various conditions in the reactors followed each other cyclically (fill, anoxic, aerobic, settle, draw) three times a day. T...
Autori: Bence Fazekas, Karoly Reich, Krisztian Varga, Viktoria Pitas, Viola Somogyi, Zsuzsanna Banyai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25902

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

Abstract Effects of the aeration rate on nutrient removal from synthetic domestic wastewater using an intermittently aerated sequencing batch reactor (IASBR) were studied at ambient temperature. Two aeration rates, 0.8 and 1 L air/min, were studied. At the aeration-rate of 0.8 L air/min, removals of COD, NH4+-N, total nitrogen (TN) and PO43--P were 84%, 96%, 75% and 99%, respectively. At the aeration rate of 1 L air/min, removals of COD, NH4+-N, TN and PO43--P were 90%, 99%, 70% and 66%, re...
Autori: Liam G. Henry, Liwen Xiao, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25941

AbstractThis paper reports the effects of COD:sulfate ratio on sulfate removal and electricity generation from oil shale retort watertreatment using microbial fuel cells (MFCs). Field-collected retort water was augmented with organics to obtain a range of initialCOD:SO42- ratios (0.5:1 to 2:1), and treated in two different MFC designs (tubular and two-chambered). The two-chamberedMFCs exhibited COD and sulfate removal 1 to 2 orders of magnitude higher than those of the tubular MFCs. The tubular ...
Autori: Ho Il Park, Lian-Shin Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25954

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

AbstractGroundwater hydrochemical evolution has influences on the rational use and conservation of water resources. This paper whichtakes MapGIS as the platform is aimed at demonstrating the evolution of shallow groundwater hydrochemistry in Guanzhongbasin (China) by adopting mathematical statistics, ratios of ion pair equivalents, geochemical simulation. The direction ofevolution is dependent on the geological, geomorphological, and hydrogeological conditions of the study area. The spatialdistr...
Autori: Hua Tian, Lei Duan, Wenke Wang, Xiaoting Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25956

Geochemical cycling of reduced inorganic sulfur in sediments may affect water quality. This study investigated the reducedinorganic sulfur distribution and environmental behaviour in superficial sediments in different watersheds and coastal zones inBohai Bay, China. Acid volatile sulfur (AVS), chromium (II)-reducible sulfur (CRS) and elemental sulfur (ES) distributed insurface sediment were quantified. Total organic carbon and total nitrogen were presented in higher concentrations in the fluvial...
Autori: Robert Mortimer, Simon Bottrell, Wenjing Shi, Yanqing Sheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25959

AbstractBy investigating the basic physicochemical characteristics, nutrients (nitrogen, phosphorus and potassium) and heavy metalconcentrations of the excess sludges from four wastewater treatment plant (WWTP) in Xi’an city, the feasibility of applyingsewage sludge to landscaping in Xi'an was studied. The results showed that the basic physicochemical properties of sewagesludge satisfy the requirement of most plants growth. The sewage sludges are rich of organisms, nitrogen and phosphorus, butre...
Autori: Bohan Yin, Qin Zheng, Rixia Zhang, Sheping Wang, Xinan Liu, Zhengliang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25964

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

AbstractWastewater streams and particularly industrial effluents tend to increase in volumes and to get more complex in terms ofpollution. Nevertheless, nowadays the focus is directed towards recycling or reuse of treated wastewater so as to close the wateruse loop. Advanced wastewater treatment allows these possible applications by achieving good quality effluent to suit the newpurposes, but the implementation of this treatment stage is a difficult task. This study gives an example on how to ap...
Autori: , Daniela Cailean, Florina Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25971

AbstractThis study presents the development and use of a hydraulic-coupled water quality model for the simulation of BiochemicalOxygen Demand (BOD) concentrations in the Bahlui River, a small river located in northeastern Romania. This river experiencesthe typical pollution problems for many Romanian water bodies: heavy pollution from both diffuse and point sources, lowconnectivity to wastewater systems in rural areas and moderate removal of pollutants in municipal wastewater treatment plants.Th...
Autori: , Claudia Cojocariu, Denie C.M. Augustijn, George Bârjoveanu, Ioan Crăciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25985

AbstractA case-control study was conducted in two Romanian counties (Alba and Cluj) in order to investigate lung cancer risk due toresidential radon exposure. Two hundred and forty-one subjects were included, of which 104 cases and 137 controls. Residentialradon concentrations were monitored using CR-39 track detectors, exposed over a period of at least 6 months. The odds ratioswere estimated by using multivariable logistic regression adjusted for age, sex, smoking status, education and family h...
Autori: Alexandra Cucoş Dinu, Constantin Cosma, Dan Rădulescu, Doina Todea, Dorin Iancu, Ionel Papuc, Loredana Roşca, Mircea Rişteiu, Tiberius Dicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26011

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractThe increased concentrations of priority pollutants in wastewaters have imposed the completion of conventional treatment withadvanced treatment stages (such as catalytic oxidation, membrane processes, adsorption, ion exchange, etc.) for their removal bychemical degradation and/or physical separation.In this study, 4-chlorophenol (4-CP) is proposed as model-pollutant for the priority organic pollutants present in syntheticwastewaters and several processes which can act as advanced treatme...
Autori: Carmen Teodosiu, Corina Petronela Musteret, Daniela Arsene, Daniela Cailean, George Bârjoveanu, Petru Apopei, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26022

AbstractIn spite of the fact that concern on water quality protection raised in the last decades heavy metals pollution still represents agreat threat for both human health and environment quality. Ion exchange proved to be an effective technique for industrialwastewaters treatment, as long as it ensures an effective recovery of valuable compounds. The main purpose of this work is toassess the performances of a commercial ion resin sort (a strong basic anionic resin – VIONIT AT 21), to remove ch...
Autori: Alexandra Raluca Miron, Cristina Costache, Cristina Modrogan, Dumitru Giani Apostol, Oanamari Daniela Butucea, Redha Kouachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26025

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe hydrodynamics of two equipments from a surface water treatment pilot plant has been investigated through residence timedistribution (RTD) experiments using brine solution as tracer. Computational Fluid Dynamics (CFD) procedure, which isincreasingly utilized to study a wide variety of complex environmental fluid mechanics processes, was used to predict the flowpatterns and other properties of flowing fluids (e.g. velocity, concentration of species etc.). In this work, ANSYS Fluent 14....
Autori: Adina Pacala, Alain Liné, Alexandru-Dan Filep, Cosmina-Mariana Militaru, Teodor Todinca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26030

AbstractThe performance of two cation exchanger resins, Amberjet UP1400 and Amberlite IR120 in the process of Cs(I) ions removalfrom aqueous solutions was examined. Batch experiments were carried out to determine the influence of several parameters(resin dosage, contact time, temperature and initial concentration of Cs(I) ions) on the removal process. The equilibrium wasreached after 60 min for Amberlite IR120 and after 120 min for Amberjet UP1400, with an overall adsorption performance of~97% f...
Autori: Adina Negrea, Cornelia Muntean, Corneliu Mircea Davidescu, , Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26032

AbstractIn this work, cyclic voltammetry (CV) and differential-pulsed voltammetry (DPV) were used to detect pentachlorophenol (PCP)at two types of multi-walled carbon nanotubes (CNT)-based composite electrode, i.e., TiO2-modified-CNT-Epoxy (TiO2-CNTEpoxy)and CNT-Epoxy in 0.1 M sodium sulphate solution supporting electrolyte. The electrochemical behaviour of theelectrodes was investigated in the absence and presence of UV irradiation. A single oxidation peak at a potential value of about+1 V vers...
Autori: , Ágnes Jakab, Aniela Pop, Cornelia Bandas, Florica Manea, Joop Schoonman, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26033

AbstractLake Taihu is a shallow, wind-driven lake where eutrophication is always a serious problem. The study presented hereininvestigates the effect of wind on the eutophication of the lake, by using a two-dimensional (2D) hydrodynamic model coupledwith a 2D water quality model. The 2D water quality model looks in particular at the water quality situation of Lake Taihu in theyear 2008 and predicts future changes in the algae bloom situation. The Delft3D modelling tool was used to build thehydro...
Autori: Arthur Mynett, Chao Yue, Ioana Popescu, Leo Postma, Quan Pan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26037

AbstractZinc is an important metal for humans and the environment. Its intensive application in industry has led to water and soilcontamination. A lot of microorganisms both unicellular and multicellular can be applied for removal of metals from theenvironment. The process of zinc adsorption by cyanobacteria Spirulina platensis biomass was investigated. The concentrationsof 0.34 mM and 3.4 mM of ZnSO4ˇ7H2O were used. The process of biosorption of zinc was studied during 1-hour experiment.To dete...
Autori: Gheorghe Duca, Inga Zinicovscaia, Liliana Cepoi, Marina V. Frontasyeva, Sergey S. Pavlov, Svetlana F. Gundorina, Tatiana Chiriac, Valeriu Rudic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26041

AbstractThere are many treatment methods used to remove color from textile wastewater, and Fenton oxidation, a well known AdvancedOxidation Process is one of the most efficient. Apart of Fe(II), other metal ions have been used as catalysts in Fenton’s Reagent,and Cu(II) proved to be a good alternative.In this study the effect of the concentration of dye, catalyst and hydrogen peroxide were studied and optimized for thediscoloration process of Reactive Black 5 using a Fenton-like process, H2O2/Cu...
Autori: Andrei-Petru Bertea, Armand-Florin Bertea, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26042

AbstractA simplified numerical model of the water distribution network of a medium sized town (with 30,000 inhabitants), of elongatedshape, was implemented in EPANET. The decay of chlorine residual concentration in the above mentioned network was studied,using the extended time analysis capabilities of EPANET, for a 3 days period. The water supply system, composed of one tank, 86pipes and 52 nodes is driven by gravity. The chlorine is injected at the tank with a constant concentration amount. Th...
Autori: Andrei-Mugur Georgescu, Sanda-Carmen Georgescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26054

AbstractBasic principles for assessing phytotoxicity are the same whether the test compound is a heavy metal, herbicide, fungicide,insecticide or other toxic compounds. The difference lies not in the method of evaluation, but in the experimental program andworking methodology.In this paper the phytotoxic effects of heavy metals, Cr (VI) and Cd (II) on plants germination and growth were studied. Stocksolutions of the two heavy metals were prepared at a concentration of 1000 mg/L, in distilled wat...
Autori: Dana Luminiţa Sobariu, , Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26062

AbstractThe stability of soil aggregates is an indicator of soil structure. Soil acidity affects soil structure stability. Soil acidity has twocomponents: active acidity and exchangeable acidity. In natural conditions, each soil type has a certain level of acidity, which isgiven by its composition, natural vegetation, the chemical composition of precipitations and other factors that cause changes overtime in soil pH. Acidic soils are characterized by physical, chemical and biological properties ...
Autori: Dorin Cotiusca Zauca, , Lucian Vasile Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26064

AbstractThis paper is an analysis of a case study which entails the assessment of pollution degree with nitrate in the Prut river basin, byanalysing 23 wells. The novelty of this work is the use of modeling done by GIS techniques, namely the Digital Terrain Model(DTM) interpolation technique, to obtain further information starting from discrete information.In the present paper, we emphasized the increasing tendency of nitrates and nitrites content in the underground waters, in directcorrelation ...
Autori: Florian Statescu, Gabriela Biali, Lucian Vasile Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26073

AbstractThe scope of the present paper is water management dimensioning closed to the copper mining area in the Medet region(Bulgaria). The mining works left an open pit and several waste rock dumps within the catchment area of Medetska River. Atpresent although the flooding of open pit is going on, it will be finished approximately in 2018. Water treatment is necessary dueto the high concentrations of pollutants (sulphate and copper) in the waters influenced by mining. The objective of the stud...
Autori: Gabriela Biali, Petra Schneider, Ralf Löser
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26077

AbstractThe removal of residual oil from palm oil mill effluent (POME) using boiler fly ash was studied in this paper, with focus on theadsorption isotherms and kinetic studies by measuring the residual oil concentration using UV-spectrophotometer. The percentresidual oil adsorbed decreased from 80% to 5% as contact time was increased from 10 mins to 120 mins but increased from2.74% to 72.98% as initial concentration of residual oil increased from 0.04812 mg/L to 0.2406 mg/L. Pseudo-second order...
Autori: Jude C. Igwe, Stella N. Anioke, Uche Arukwe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26078

AbstractExperiments were designed to optimize the Cr(VI) adsorption on Salvinia cucullata. The significance of different adsorptionparameters along with their combined effect on the adsorption process has been established. A regression equation wasformulated by representing percentage of Cr(VI) adsorption as a function of different independent variables such as contact time,pH, adsorbate concentration and adsorbent dose. The insignificant terms were assessed through student ‘t’ test and are remo...
Autori: Saroj Sundar Baral
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26084

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractThe ozone oxidation and disinfection stages constitute important technological phases in the modern systems of water treatment,both as unitary stages as integrated ones into systems that use advanced oxidation processes (AOP). More than half of thewater/ozone contact systems used nowadays in the water treatment plants are based on systems of contact in the bubble column.This work here aims at experimentally analysing, in terms of scale, a water-ozone contact system in the bubble column a...
Autori: Sorin Claudiu Ulinici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26088

AbstractA study on the electrochemical decolourisation, aromatic ring degradation and mineralization of Reactive Red 147 (RR) syntheticsolutions using boron-doped diamond (BDD) electrodes is presented. Electrolyses were carried out under galvanostaticconditions in 0.1 M Na2SO4 supporting electrolyte using undivided electrolytic cell. Prior to electrolysis application, theelectrochemical behaviour of BDD electrode was characterized in the presence of RR dye by cyclic voltammetry in order toestabl...
Autori: Sorina Moţoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26089

AbstractCombined electrocoagulation (EC) and homogeneous phase TiO2 photo-assisted system were applied to methyl orange (MO)wastewater treatment. Optimum including current density, initial concentration of MO, TiO2 concentration, pH, solutionconductivity and electrode distance were investigated. 98% decolorization (initial concentration = 500 mg/L) was achieved in 30min with a current density of 125 A/m2, electrode distance of 2.5 cm, electrolyte KCl concentration of 0.5 g/L, initial pH of 6.86,...
Autori: Yi Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26090

AbstractEast Calcutta Wetland ecosystem is a Ramsar Site in India covering almost 51 km2 and is one of the largest of its type. Thiswetland receives a massive load of almost untreated industrial and domestic effluents every day, throughout the year, that hasbeen effectively utilized in pisciculture for having a better yield (2.85 metric tons of fish per 0.01 km2 of water body per annum).The present investigation was carried out to study the toxicity of the untreated effluents discharged from tan...
Autori: Utpal Singha Roy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26094

Abstract This paper presents some optical and microphysical properties of aerosols measured over the Cluj-Napoca city, at the Faculty of Environmental Science and Engineering, Babeş-Bolyai University. This site is part of the Romanian Atmospheric 3D Research Observatory (RADO) and the Aerosol Robotic Network (NASA-AERONET) and is equipped with the only sun and sky tracking radiometer (Cimel CE 318A sun-photometer) in Transylvania. By analyzing Direct Sun measurements like Aero...
Autori: Nicolae Ajtai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26105

Abstract Being involved in the synthesis of precursors for amphetamine and amphetamine-like drugs, pyridine (Py) may be also regarded as a by-product found when these drugs are obtained via the Leuckart method. Also, pyridine is well known as a biomarker of microorganisms, when those are subjected to pyrolysis before analysis by various instrumental techniques. Consequently, since Py is not commonly found in the air, its presence as a contaminant at trace levels in a room could ind...
Autori: George-Bogdan Ghira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26109

Abstract Known as the most important byproducts of water disinfection with chlorigen chemicals, trihalomethanes (THMs) are incriminated in causing severe effects upon human health. The exposure pathways that can lead to potentially significant uptake of THMs include for adults ingestion of tap water and inhalation of THMs in vapor phase resulting from bathing, showering and washing. The purpose of this paper is the exposure assessment to THMs through ingestion, inhalation and derma...
Autori: Anca Elena Gurzău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26110

Abstract The Black Sea is seriously affected by a large range of pollutants, despite severe laws regarding the protection of sea ecosystems. Heavy metals are among the most important xenobiotics from the environment, presenting also toxicity for humans. The studies upon heavy metals have proven that the sediments have the highest concentrations and they can release metals back to water and this fact represents a risk for the humans and aquatic ecosystem life. The use of aquatic ...
Autori: Oana Jitar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26112

Abstract This study focuses on the local scale behavior of SO2 emissions resulting from lignite-combustion thermal power plants. The investigations aimed at monitoring the SO2 emissions and imissions over a two week period in September 2010. One of the largest power plants from Eastern Europe was chosen for monitoring using different optoelectronic techniques. Rovinari power plant (44o54’45”N – 23o09’44”E) is one of the largest electricity suppliers of Romania, having 4 groups of 3...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26113

Abstract A set of 500 water samples collected from various sites of Tarnava Mare River, between Medias and Copsa Mica were analyzed, during three years (2010-2012). The physicochemical parameters like: temperature, pH, electrical conductivity (EC), total dissolved solids (TDS), salinity, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), lead (Pb2+), chloride (Cl-), sulfate (SO4 2-), ammonium (NH4 +), nitrite (NO2 -) and nitrate (NO3 -) were determined. The results were co...
Autori: Ioana Piştea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26114

Abstract Heavy metals are common contaminants of freshwaters and they can produce toxic effects on aquatic fauna and flora. The ions of heavy metals existing in freshwaters are well known as toxicants for the aquatic organisms. Duckweed is an aquatic plant of small size that floats on fresh water surface of lakes and marshes. The small plants are highly exposed to aquatic pollutants and as a result they are very sensitive to the toxic effects. As consequence the duckweed plants are...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26122

Abstract The main purpose of this paper is to identify, highlight and analyze the recycling possibilities for the activated glass derived from the treatment of the cathode ray tubes (CRT) waste equipment and to demonstrate the recycling viability, economical and environment protection efficiency. A total of 95 pieces of waste electronic equipments (TVs and PC monitors) were processed and a number of five TVs and five PC monitors from the ‘95s were analyzed. Significant quantitie...
Autori: Antoanela Popovici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26124

Abstract The aim of this paper is to analyze how local and atmospheric conditions influence pollutants’ distribution. Two different sites in Romania were chosen for measurement campaigns: Surlari (44° 34', 26° 19') located into a forest and near a lake, and a suburban area, Magurele (44° 21', 26° 2'), where the anthropogenic activities dominate. The same equipments for measurements of surface ozone, CO, NO2, NO and PM10 were used at the two sites. The measurements were performed in...
Autori: Sabina Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26126

Abstract This paper presents a research method for the exploratory analysis of non-compliant municipal waste landfills by determining the gas composition of emissions. The proposed method has the following stages: establishing municipal landfill surface contour by topographic measurements; setting measuring points on the deposit surface; setting the number of points needed and their spatial coordinate; field location of points for making exploratory measurements; making and recordi...
Autori: Michaela Bianca Vac Soporan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26127

Abstract This paper presents a proposal for measurements and interpretation of gaseous emissions from the municipal landfills, especially for non-compliant sites. Based on the measurements made on the Pata Rat landfill, Cluj-Napoca, a methodology for interpreting the results is presented, in order to assess current energy potential of the deposit. Measurements are the main basis for determining the energy potential of the deposit. By applying the methodology for determining the ene...
Autori: Michaela Bianca Vac Soporan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26128

Abstract In order to accomplish the water quality standards required for a specific use, the continental surface water is treated through a sequence of operations and unit processes. The treatment technological flowsheets carry out, partially or totally, the removal of various pollutants, every treatment step being used for improving one or more qualitative parameter. The treatment scheme is specific to water source type and water use. One of the basic operations for water treatmen...
Autori: Oana Tirtoacă Irimia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26136

Abstract Using sludge with dangerous substances content as an agricultural fertilizer can provide risks for humans and all environmental components. An important risk factor that had to be taken into account is the combination of sludge used as a fertilizer and agriculture activities that has its own consequences. In this paper, a risk evaluation for sludge disposal was elaborated. The most important risk factors in the studied case, wastewater sludge used as an agricultural fer...
Autori: Elena Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26141

Abstract Pesticides can be considered useful to eliminate pests, but can also induce negative effects to the processes of germination, growth and development of plants or disrupt some physiological and metabolic processes. By studying the effect of pesticides on treated seeds germination, and determination of growth indices, it was possible to evaluate the positive or negative influence or toxicity of the chemical compounds. The aim of this research is to highlight the effects of d...
Autori: Daniela Nicuţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26142

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

Abstract The reason for carrying out this research is related to the significant risk of heavy metals present in wastewater on the environment and human health. The removal of heavy metal ions from aqueous solutions was performed in a batch system, using peat (from Poiana Stampei, Romania) as adsorbent. The efficiency of the process was predicted with high accuracy (correlation with experimental data more than 0.99) based on a feed-forward neural network with two hidden layers. The...
Autori: Gabriel Dan Suditu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26150

AbstractTo understand the typical organic pollutant contamination status of the main source water in Yellow River basin, samples werecollected from fifty source water points (including reservoir and river) in Yellow River basin. The samples were analyzed for therepresentative organic pollutants, including benzene homologous, chlorobenzene compounds, organophosphorous pesticides, and nitrobenzene compounds, total of 17 compounds. It was observed that all concentrations of the 17 compounds in the ...
Autori: Jijun Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26155

AbstractKnown concentrations of naphthalene were added to soil samples to investigate the anaerobic degradation potential by theinoculated naphthalene-adapted bacteria under nitrate reducing conditions. Naphthalene could be anaerobically biodegraded tonon-detectable levels within 35 days when the initial concentrations were 5.8 mg/kg, 34.7 mg/kg, 61.4 mg/kg, 93.7 mg/kg and146.6 mg/kg in soil, respectively. The degradation rates of naphthalene increased with increasing initial concentrations. The...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26157

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractIn the conventional water flooding process of Daqing Oilfield in China, the occurrence of abundant sulfate-reducing bacterialpopulations has substantially affected the industrial production. This study was conducted from the perspective of ecologicalsuppression by operating anaerobic ABR reactors and dosing ecological inhibitors in a continuous-flow experiment. The practicaloperating efficacy was investigated and associated dynamic bacterial population succession was analyzed. Results sh...
Autori: Bin-song Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26165

AbstractThe solidified waste drilling mud has been landfilled into slurry ponds with impermeable layer at oil & gas field since 1990s. Thisarticle aims to elucidate the heavy metal contaminations from landfill ponds at semiarid region. The heavy metal concentration inthe waste and its potential mobility based on its binding forms was studied. Furthermore, the blocking effect of impermeable layer was used to elaborate the environmental effects of heavy metals. From the analysis, Cr was found ...
Autori: Yun Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26171

AbstractMethane production and concentration from six cells were investigated in two landfills in China. Long-term monitoring tests wereconducted to evaluate the methane recovery efficiency of active wells. Results showed that the recovery efficiency of a wellsdistribution simulation method was 75.6% to 83.5%, which was much higher than 50.1% to 53.6% when considering the EPAmethod in the EST (Ecological Sludge Evapotranspiration Technology) cover structure. The recovery efficiency of methane in...
Autori: Qiang Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26174

AbstractA wet flue gas desulfurization (WFGD) system adopting electrostatically-assited twin-fluid atomization injector was presented.Spatial distributions of the droplet sizes, velocity for different voltages were measured using limewater and SO2 removalefficiency for different voltages and Ca/S ratios were tested using limewater drops. The physical and chemical improvementmechanisms were analyzed using spray characteristics and double film theory. The analysis showed that electrostatically-ass...
Autori: Zhentao Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26175

AbstractAs a new type of photoelectrocatalytic materials, the TiO2 nanotube arrays have drawn a lot of attention for efficientlyphotoelectrocatalytic organic pollutants degradation due to their highly photoelectrocatalytic properties. Yet, the performance ofphotoelectrocatalytic organics degradation using TiO2 nanotube arrays electrode is influenced by Cl-, a kind of typical reducingmaterial. This paper focuses on the effect of Cl- on the different photoelectrocatalytic performance of TiO2 nanot...
Autori: Jialing Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26177

AbstractSurface soil samples and vegetable samples from the Pearl River Delta, South China were collected and analyzed for 16 USEPApriority polycyclic aromatic hydrocarbons (PAHs). The total concentrations of 16 PAHs in soils ranged from 22.1 to 1256.9 ng/g.Naphthalene, phenanthrene, fluoranthene and benzo(b)fluoranthene were consistently the most prevalent individual PAHs. Theconcentrations of 16 PAHs in vegetables varied from 31.2 to 726.8ng/g. Naphthalene and phenanthrene were the predominant...
Autori: Song Yantun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26180

AbstractGallinaceous feathers are an abundant solid waste from the poultry processing industries, which poses disposal problems. Akinetic study dealing with the adsorption process of wool reactive dye, Yellow Lanasol 4G (CI Reactive Yellow 39), ongallinaceous (Gallus gallus, Cobb 500) feathers was carried out. The main research goals of this work were to evaluate theviability of using this waste as adsorbent and to study the kinetics of the adsorption process, using a synthetic effluent. Thechar...
Autori: Sónia Adriana Figueiredo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26203

AbstractThe dominant litter samples Pinus sylvestris L. needle litter and Acer platanoides L. leaf litter were collected in the coniferousmixed forest located at 54ş43‘ N 25ş19‘ E (Vilnius, Lithuania) in April 2010. Different heating temperatures (150, 250, 350, 450and 550şC) and 2 hour heating duration were used to produce ashes. The selected heating temperatures affected mass loss, colour, pH, electrical conductivity (EC), C/N ratio, nutrient concentrations of the ash. The darkness of Munsell ...
Autori: Jolita Dūdaitė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26208

AbstractPotential of unmodified Wheat Straw as an adsorbent for the removal of lead and copper was studied. Effect of pH, adsorbentdose, contact time and initial metal concentration on the removal of the metal ions were also investigated. Maximum removal oflead was found to be 43.55% by wheat straw under optimum conditions (pH=5, adsorbent dose=16g/L, contact time= 240minutes, metal concentration=100 mg/L). Unmodified Wheat straw removed 0.381 mg/g of lead. While 56.36% copper removalwas achieve...
Autori: Mehwish Anis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26209

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractDespite the Moderate Resolution Imaging Spectrometer (MODIS/Aqua) presently collects data on operational basis, evaluationof its biogeochemical products from standard bio-optical algorithms is scare especially in Arctic waters. The present study isaimed to evaluate several MODIS/Aqua bio-optical algorithms and MODIS/Aqua remote sensing reflectance (Rrs) products inKongsfjorden waters on the western side of Svalbard, Arctic. Data sets consisting of in-situ measurements of radiometric quan...
Autori: Palanisamy Shanmugam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26220

AbstractIn an urban environment, visibility strongly reflects human safety and welfare. Generally, visibility is dependent on particlescattering and absorption. The former is influenced by light wavelength, atmospheric gaseous species and particle characteristics,especially number and size distribution. Therefore, it is necessary to establish the relationship between visibility and particlecharacteristics. Furthermore, it is important to understand the formation mechanism of secondary aerosols. ...
Autori: Chih-Ming Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26221

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractIn 1979, the Gheshlagh river continuum was affected by the construction of Gheshlagh dam. More than three decades afterpresence and operation of this dam, there is a necessity to evaluate water quality in Gheshlagh reservoir. Therefore, water quality data was determined monthly from October 2008 to September 2009, to evaluate the impact of Gheshlagh dam presence and operation on the reservoir’s water quality. Eight parameters were analyzed (dissolved oxygen, biological oxygen demand,chem...
Autori: Fariba Rezaei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26225

AbstractKohonen Self-organizing map (KSOM) modeling have been applied increasingly for analysis, estimation and prediction ofseveral water quality processes, which are embedded with high complexity, dynamism and non-linearity. KSOM or unsupervisedneural networks were applied to microbial data (Escherichia coli, faecal streptococci, and total coliforms) from the effluent of atwo year data set (2008-2010) on two permeable (pervious) pavement systems used to treat storm water runoff contaminated wi...
Autori: Kiran Tota-Maharaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26226

AbstractPresent study deals with a technology that reduces the cadmium(Cd) availability to the leafy vegetable Amaranthus caudatusfrom Cd contaminated soil (6 μg Cd g-1soil), amended with farmyard manure FYM, FYM+NPK and agricultural wastes (ricehusk; RH and saw dust; SD) at different doses (0.5 %, 2 %, 5 % and 10 %). Among all the doses 5 % was found to the best foreach amendment showing maximum reduction in phytoavailability of Cd hence better vegetable yield. At this dose the reductionin...
Autori: Anita Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26228

AbstractIn this article, hydrodynamic parameters and overall Oxygen mass transfer coefficient of petroleum based micro-emulsions in anairlift reactor were investigated. Four different petroleum-in-water micro-emulsion systems containing kerosene, heavy naphtha,light naphtha and diesel as oil based were used with concentrations of 3% and 7 % (v/v). The experimental data were supportedby simulation results obtained from the Computational Fluid Dynamics (CFD) method. The CFD was properly able to si...
Autori: Mostafa Keshavarz Moraveji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26234

AbstractIn this work, a four factor three-level Box–Behnken factorial design based on response surface methodology (RSM) wasemployed to optimize the removal of phosphate from synthetic wastewater (mineral salts medium-MSM) by the bacterialconsortium (Bacillus sp. RS-1, Pseudomonas sp. YLW-7, Enterobacter sp. KLW-2). A mathematical model was then developedto show the effect of each medium composition and their interactions on phosphate removal. The effect of the lactoseconcentration (X1), pH (X2)...
Autori: Krishnaswamy Usharani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26235

AbstractNutrient runoff is an environmental concern. There is a need for a robust method of predicting nutrient concentrations in runofffrom feedlots to facilitate management practices. To investigate the feasibility of using multiple linear regression (MLR) andartificial neural network (ANN) in predicting nutrients in runoff, simple water quality paramters (e.g., pH and EC) of runoff froma feedlot in North Dakota, USA, were used to train an ANN. Both models accurately predicted potassium concen...
Autori: Bilal Cemek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26236

AbstractIn this research, response surface methodology (RSM) was applied to model the effect of main operational variables includinginitial pH, initial phosphate concentration, current density and reaction time on phosphate removal by electrocoagulation. It wasfound that the decrease of initial pH and initial phosphate concentration, and the increase of current density and reaction time are beneficial for improving phosphate removal efficiency. According to the ANOVA (analysis of variance) resul...
Autori: Mohsen Behbahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26237

AbstractWater system integration can minimize both fresh water consumption and wastewater discharge from the paper mills. In thepresent study, Pinch Technology was used to analyze and optimize the water network of an integrated paper mill. A system wasdeveloped and a limiting constraint (COD concentration) was identified based on investigations for water quality, and thenminimum fresh water and wastewater targets were determined without considering water losses. The analysis was extended byestim...
Autori: Sudheer Kumar Shukla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26240

AbstractThe aims of this study were to investigate the performance of anaerobic up-flow column reactor (AUFCR) and immobilizedactivated sludge biomass (ASB) potential for the adsorption of dye drimarene Blue-K2RL (Db-K2RL) and removal of chemicaloxygen demand (COD) from textile wastewater (TWW). AUFCR with ASB at flow rate of 50 mL h-1 and hydraulic retentiontime (HRT) of 10 h showed 95% dye adsorption at pH 4 and 87% COD reduction at pH 6 while non-activated sludge (NAS)showed only 60% of adsor...
Autori: Anwar Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26246

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractIndigenous isolated bacterium Aeromonas sp. was immobilized in calcium alginate and the related immobilization parameterslike bead diameter, inoculum size and the initial phenol concentration required for biodegradation were determined. Thebiodegradation activity was most efficient with 4 mm calcium alginate beads. The optimal immobilized biomass required wasabout 28 109 cells/mL. Compared with free-cell suspensions, the alginate matrix used for immobilization of cells provided betterenv...
Autori: Abdelkader Namane
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26249

AbstractThe present study is aimed at a long-term treatment performance of a constructed wetland with horizontal subsurface flow atJimlíkov, Czech Republic. The system was put in operation in 1993 and the treatment performance is evaluated for the period1998-2009 due to non-existence of results from the beginning of operation. The parameters of concern were BOD5 (biochemicaloxygen demand), COD (chemical oxygen demand), TSS (total suspended solids), NH4-N (ammonia-N) and TP (totalphosphorus). A t...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26258

AbstractThe aim of this study is to elaborate a survey on the efficiency of three anti-aging cosmetic formulations by applying FourierTransform Infrared Spectroscopy (FTIR) with Attenuated Total Reflection (ATR) in order to characterize and identify thespecific recognition markers of the active ingredients. FTIR (ATR) spectrometry in specific regions was applied also to theingredients used in these products, depending on their role in the specific cream. Comparing the different composition of th...
Autori: Anca Maria Juncan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26261

AbstractZarshuran As-Au deposit is the major ore deposit in northwest of Iran. Having been exposed to weathering, the accumulatedmining waste is consumed to deteriorate regional soil and water quality. Accordingly, 11 composite surface soil samples werecollected to evaluate the metallic pollution. Mean concentration of elements As, Sb, Hg and Zn were measured to be 234.9, 19.6,24.2 and 476.7 ppm, respectively. In comparison with mean earth crust and local guidelines for agricultural soil, the sa...
Autori: Abdolreza Karbassi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26262

AbstractThe applications of biofilm treatment technologies for domestic wastewater are being increased in many parts of the world. Theaim of the study is to assess a compacted aerobic attached growth fix-film unit (termed Bio-cache) for treatment of small volumedomestic wastewater. The system consists of the miniature plastic packing matrix, which provides a large surface area of 300m2/m3, so as to maintain the high rate growth of viable organisms responsible for organic degradation. The study o...
Autori: Alireza Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26266

AbstractThe Lake Bafa is an alluvial bar lake located in the Aegean Region in the Big Meander river basin in Aydın and Muğlaprovinces. However, the lake is currently threatened by severe pollution, being under the risk of serious degradation because of(i) uncontrolled urbanization; (ii) point and non-point source pollution; (iii) algae bloom; (iv) sediment transportation andpollution via influent creeks to the lake; and (v) severe degradation of the natural wetlands within its drainage...
Autori: Ebru Yilmaz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26267

AbstractA novel RHA/PFA/CFA sorbent was developed by sol-gel method using three types of ashes, i.e. rice husk ash (RHA), palm oilfuel ash (PFA) and coal fly ash. From surface analysis of selected RHA/PFA/CFA sorbents, the spent sorbent had more compactstructures covered by irregular rough surface and the specific structure of raw RHA, PFA, and CFA were no longer visible. Inaddition, lower specific surface area was obtained for spent RHA/PFA/CFA sorbent. Batch studies were performed to evaluatet...
Autori: Irvan Dahlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26272

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractThe aim of this study is to analyze the surface-ozone concentration mass variations in Bucharest for the 2005-2007 period. Data files from eight urban sites in Bucharest area were processed to extract the surface-ozone features. Generally, the results have shown that the highest values of surface- ozone concentrations are in the summer and in the afternoon, as in the literature. The smallest values are in December and January in all the three years. Monthly mean concentrations have shown...
Autori: Constantin Rada, Cristian Necula, Laurentiu Zagar, Raluca Barladeanu, Sabina Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26275

AbstractThe aim of the present study was to investigate the mechanism of Cr(VI) bioaccumulation by livingand active Phanerochaete chrysosporium. Fungal growth was inhibited beyond 10 mg L-1 Cr(VI) concentration thereby reducing the chromium bioaccumulation capacity. The optimum pH was found to be 6 for the growth and bioaccumulation of Cr(VI) by P. chrysosporium. Bioaccumulation efficiency decreased from 81.47% to 23.82% when Cr(VI) concentration was increased from 10 to 40 mg L-1. A Fourier tra...
Autori: Kaustubha Mohanty, Somasundaram Murugavelh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26280

AbstractThe objectives of this study were to investigate of cadmium and chromium adsorption from aqueous solutions by using orange (Citrus sinensis var Tampson) and sour orange (Citrus aurantium) mesocarp. The chemometric approach was applied for the optimization of removal percent of Cd2+ and Cr6+. To optimize Cd2+ and Cr6+ removal percent, the effect of four experimental parameters on removal percent was investigated by means of multivariate analysis. The considered factors were Cd2+ and Cr6+ ...
Autori: Maryam Bagheri Ardebilian, Mohammad Ali Zazouli, Pouneh Ebrahimi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26287

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractA new cell design which makes an efficient use of the cathodically evolved H2 to improve the mixing efficiency and thefloatation ability during electrocoagulation was used to remove dyes from waste solution. In this study, the decolorization andCOD reduction of colored solutions containing reactive and basic dyes by electrocoagulation was investigated using aluminumelectrodes in a batch mode. The effect of operating parameters such as current density, initial dye concentration, NaClconce...
Autori: El Sayed Zakaria El Ashtoukhy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26303

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractThe paper compares the electrocoagulation performance during the removal of Acid Brown 14, Acid Yellow 17, Acid Blue 113and Acid Black 172 dyes from aqueous solutions. For this purpose, pH changes and effectiveness of main parameters includinginitial dye concentrations and current densities for the selected dyes were examined. In addition, effluent turbidity, energyconsumption and amounts of released aluminum were also investigated. The present work shows that Acid Yellow 17 removaleffic...
Autori: Mahsa Taheri, , Mokhtar Arami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26310

AbstractThe monitored natural attenuation (MNA) of groundwater contamination is in many cases considered to be a cost-effective andappropriate strategy to manage the remediation of contaminated aquifers. A prerequisite for the public acceptance of such NAremediationapproaches is that the efficiency of the presumed NA-processes should be proven. This proof must be based on anextensive hydrogeological and in-situ characterization of the ongoing aquifer processes. Additional investigations of aquif...
Autori: Achim Möller, Anja Berning, Anne Berghoff, Bernd Mahro, Christoph Wortmann
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26312

AbstractSeed priming has been reported to be a simple technique for enhancing seedling establishment in environment and cropproduction under stressed condition. In this study, we investigated osmo and hydropriming effect in two salt stressed chickpeacultivars. This research monitors the changes in growth factors, proline content, lipid peroxidation and H2O2 scavenging enzymesactivities in osmo (mannitol 4%) and hydro (water) primed plantlets of two salt stressed chickpea cultivars (Arman and Biv...
Autori: Akbar Mostajeran, Fatemeh Khodabakhsh, Rayhaneh Amooaghaie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26315

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractThe distribution and fractionation of nine heavy metals (Cr, Co, Ni, Cu, Cd, Zn, V, Pb and As) in the sediments of Lake Chaohu,a shallow eutrophic lake, were investigated using the BCR sequential extraction procedure. The level of pollution attributed tothese nine heavy metals was evaluated employing the potential ecological risk index (RI) and geoaccumulation index (Igeo). Metalconcentrations in sediments ranged from 65.00~104.00 for Cr, 14.50~21.70 for Co, 28.50~50.90 for Ni, 25.40~51....
Autori: Beidou Xi, Fengyu Zan, Guangchao Zhao, Jing Su, Kevin M. Yeager, Shouliang Huo, Xiujuan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26321

AbstractThe aim of this paper was to study the performance of a single-stage rotating biological contactor with supplemental aeration interms of removal efficiency of organic and nitrogen content. Research was based on fifteen samples collected during the fouryear period. The wastewater was low strength with maximal measured concentration of 362 mg COD/l, 100 mg NH4/l, and 324mg TSS/L. The maximal measured removal efficiency of COD (chemical oxygen demand) and TSS (total suspend solids) were71% ...
Autori: Dragan Cvetkovic, Dusan Gordic, Milorad Bojić, Srdjan Stosic, Vanja Susterstic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26322

AbstractDue to its toxicity, persistence in the environment and specific properties, 1,2-dichlorobenzene (DCB) has been listed as apriority pollutant by the European Agency. In this study, the oxidation with ozone alone as well as in combination withultraviolet irradiation was applied for the degradation of DCB. This article presents the abatements obtained, after the varioustreatments proposed, in the levels of chemical pollution as monitored by chromatographic techniques (GC/ECD, GC/MS andHPLC...
Autori: Bertrand Sancey, Corina Bradu, Grégorio Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26328

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractAlgal blooms in reservoirs used for both fish and drinking water production are a major water quality problem. The authorsassessed data gathered from both published literature and from their own field enclosure experiments to analyze the relationshipsof phytoplankton chlorophyll α concentrations with biomass and algal cell count. Experimental data were collected from indoorlocations, field enclosures, and natural water bodies. Under laboratory conditions, where the types of algae an...
Autori: Chang-juan Zang, Chao Lin, Feng Gao, Hong-chuan Pan, Miklas Scholz, Min Wu, Sheng-lan Du, Sui-liang Huang, Yong Guo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26335

AbstractIn this work, the effect of the addition of some nutrients on fungal growth and removal of Cr(III) were investigated. Theconsidered fungi, isolated from real tanning factory environment were Phanerochaete chrysosporium, Aspergillus niger and A.oryzae. Firstly, the optimal conditions for fungal growth were determined as a function of pH, contact time, temperature andagitation speed. Secondly, the effect of the addition of some nutrients on fungal growth was examined. Without the addition ...
Autori: Abdeltif Amrane, Mansur Zarrabi, Mohammad Noori Sepehr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26337

AbstractMetal concentrations in plants, soil and sediment were evaluated in the vicinity of a former iron/nickel enriching factory atPogradec, near Ohrid Lake in Albania. Metal levels were significantly higher in soil samples than in the corresponding plants.Iron concentrations in both soil and plants were much higher than the nickel ones. Lower plants (lichens, mosses and fungi) had ahigher uptake and accumulation of nickel, followed by water plants and non-cultivated (wild) plants. Iron levels...
Autori: Dimitrios Bellos, Dimitrios Veros, John M. Halley, Lazaros Symeonidis, Sonila Llupo, Thomas Sawidis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26340

AbstractThe removal of phosphorus by strongly basic anion exchanger was investigated. Removal efficiency increased with contact time,resin mass and initial solute concentration, while temperature showed a reverse effect. Equilibrium data were best fitted ontoLangmuir isotherm model (R2>0.99). Maximum sorption capacity of the resin was 66.22 mg/g, namely significantly higher thevalues reported in the literature. The Freundlich parameter (n = 4.3) and the Langmuir separation factor (RL = 0.067-...
Autori: Abdeltif Amrane, Hamid Reza Ghaffari, Mansur Zarrabi, Mohammad Mahdi Soori, Mohammad Noori Sepehr, Saied Borji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26343

AbstractThe discharge of industrial effluents is a growing concern for companies, policy makers and the sanitary water system due to thepossible damage to environment. In Spain, wastewater discharge made into the sewer network is regulated locally by the SanitaryTax (ST). Consequently, for the latter, regulation and cost differences exist. In this paper, the role of Spanish STs to promoteenvironmental protection through the treatment of industrial wastewater (IWW) is analyzed. The study is focus...
Autori: Irene Carra, Isabel María Román Sánchez, José Antonio Sánchez Pérez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26350

AbstractThe survival of Formosan landlocked salmon has been threatened by the change of habitat ambience. Because of the potentialtoxicity of nitrite (NO2-) and ammonium (NH4+) to salmonid fisheries, we studied the evolution of nitrogen compounddistributions in stream water and their relationship with ambient abiotic factors. The water was sampled at five sites surroundedwith various land-use types in bi-monthly intervals for seven years. The results indicated that a high NO2- concentration occu...
Autori: Wen-Hui Kuan, Yi-Lang Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26351

AbstractA pilot scale Upflow Anaerobic Filter (UAF) treating tannery wastewaters was operated for 160 days. The UAF was fed with lowCOD/SO42- ratio (SO42- = 1810 mg L-1, CODtotal = 2530 mg L-1) for the investigation of sulphate and COD removal as a functionof substrates limitation and ammonia and sulphide inhibition. Sulphate-reducing bacteria (SRB) out-competed methanogenicbacteria due to the low influent COD/SO42- ratio, the high concentration of sulphide and the presence of inhibiting compoun...
Autori: Alberto Mannucci, Claudio Lubello, Giulio Munz, Gualtiero Mori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26353

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractThe importance of air pollution for health results from the major role the air plays in preserving life. The air pollution is one ofthe most serious problems of the current society, both temporally and spatially. The air pollution of the environment is stronglyinfluenced by meteorological factors because of a complex combination of emission processes, transport, chemicaltransformations and the removal of pollutants through wet and dry processes. This study established a database on ozone...
Autori: Gilda Rusu-Zagar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26391

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractEmployers notified about working places under special conditions are required to develop Preventive and Protective RevisedPlan, in order to ensure the improvement of workers safety and health protection, including specific measures and actions, so thatthose working places comply with the norms and operate under normal conditions by the late 31 December 2013.This paper considers some outcomes of the Nucleu Program PN 07450226 funded by Romanian National Authority for Research(ANCS) and de...
Autori: Marius Kovacs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26404

AbstractThe objective of this work was to analyse safety and health at work regarding the exposure of workers to styrene, and to establishthe basis for an exposure control system over the entire Republic of Slovenia. The main goals were to determine the number ofexposed workers, the levels of exposure at workplaces, and the effects to workers health. The measurements of the airbornestyrene concentrations and the biological monitoring of the exposed workers were performed. One thousand four hundr...
Autori: Lidija Korat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26415

AbstractThe industrial development, the demographic growth and the limitation of the natural regions have determined a continuousdegradation of the water quality due to high concentrations and complexity of pollutants from the wastewater. The centralizedand decentralized treatment systems apply treatment procedures and techniques which can be complementary in solving theenvironmental pollution problems due to wastewater. In the present paper a three-dimensional mathematical model waselaborated b...
Autori: Narcis Barsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26422

AbstractAir quality in urban areas mostly depends on the type and size of industrial activities, traffic intensity, municipal and industrialwaste management. In addition to these factors, air quality in urban areas also depends on the size and quality of green areas,population density, geographic and climatic conditions. This paper reveals the correlations between air quality aspects in BacauCity, Romania (related to 2011) and the most representative climatic factors that influence the pollutant...
Autori: Doina Capsa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26424

AbstractThe main objective of the current research is to determine the content of heavy metals from the Bistrita river banks, respectivelyupstream of Bacau city, Romania, in Bogdan Voda area, and downstream of Bacau city. Because of their bio-accumulationtendency heavy metals can generate a negative impact on soil, as well as on certain physiological and biochemical indicators ofplants and animals metabolism. The selection of sampling points (upstream and downstream of Bacau city) took intoconsi...
Autori: Cristian Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26436

AbstractThe aim of our investigations was to assess the potential ecotoxicological effects induced by complex chemical mixtures ofanaerobically digested sewage sludge. The sensitivity of monocotyledonae cereal (Triticum aestivum L.) test plant to varioussanitization treatments of anaerobic stabilized sewage sludge was evaluated. Several biometrical and biochemical responseindicators were selected as endpoint in this ecotoxicological tests. Thus, the ecotoxicity of sewage sludge was evaluated thr...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26437

AbstractAmong foods that possess potent medicinal properties, Cucurbitaceae seeds stand as a promising source, since they are assumedto have a protective effect against oxidative stress. In order to analyze the antioxidant compounds of the seeds of Citrulluslanatus, Lagenaria siceraria, Telfaria occidentalis, Cucurbita maxima, Cucumis sativus, Cucumeropsis mannii, and Cucurbitamoschata, the dried seeds were extracted in MeOH-H2O (50 %; v/v) mixture at constant mixing rate. Qualitative phytochemi...
Autori: Aristide Guillaume Silapeux Kamda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26440

AbstractEvaluation of radon concentration is a very difficult task and a very important issue, in relation to the protection of human health.This is especially the case when there is an increase in concentration of radon on a deterministic basis, as is the case of nearbyphosphogypsum residues or geological characteristics. Radon gaseous that can be found in the environment occurs mainly fromnatural radioactive decay chains. The gamma ray spectroscopy is a powerful tool in order to monitor the en...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26441

AbstractThe sludge treatment processes represent a priority when we refer to the municipal wastewater treatment, but can implicate verycomplex studies and applications if we consider the industrial wastewater recovery and treatment processes. Even if the industrialsludges are seen as wastes, they can represent an important resource if are properly managed in the storage, treatment andrecovery processes. This paper aims to identify some methods to optimize the coagulation and flocculation process...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26444

AbstractIn order to diminish the climat changes due to greenhouse gases, the capture from the source, transport and storage of carbondioxide is one of the environmental priorities of the EU until 2050. Transportation of this gas through pipelines (one of thesolutions with most advantages in transport) can be done at ambient temperature only at high pressures, so the carbon dioxide toremain in the supercritical state. In case of underground pipelines, there is a risk of cracking at the wall of th...
Autori: Valentin Zichil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26447

AbstractThe process of semi-volatile aerosol particle evaporation was studied with respect to both computational and experimentalapproaches. A Sinclair-La Mer type aerosol generator was used to produce monodisperse particles from four n-alkanes(tetradecane, hexadecane, octadecane, eicosane) while particle sizing and FID measurements were applied to quantify particleandvapor mass and their subsequent phase distribution. Aerosol dilution and later stationary analyses in a flow tube at two timeinte...
Autori: George C. Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26448

AbstractThe washing method for uranium contaminated soils using three different reagents was investigated. Experimental data havebeen obtained for four types of soils, which have been characterized in terms of particle size distribution, as well as structure andchemical composition. Thus, the decontamination degree for each type of soil and reagent respectively has been measured.Subsequently, the decontamination process has been simulated using an artificial neural network. Based on this neural ...
Autori: Alexandru Woinaroschy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26451

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractA lab-scale packed-bed biofilm channel reactor that operates as a plug-flow system equipped with top aeration modules wasconstructed and evaluated. To assess the reactor performance a microbial community able to degrade linuron was used. Changingthe fluid flow rates and the linuron concentrations in the inflowing medium the volumetric loading rates of linuron (BV,L) weregradually increased from 0.29 to 14.93 mg/Lh. During the operation of the reactor, an airflow rate of 0.15 ą 0.05 L/min...
Autori: Erick Marrón-Montiel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26465

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractThe present study was undertaken to experimentally evaluate the heavy metal (HM) removal capacity of a municipal wastewatertreatment plant (WWTP) as a kind of mass balance. The aim of the work was to find a water or sludge stream in the WWTP thatcould be treated separately for heavy metal removal to maximize the same efficiency of the whole treatment technology.Although literature says that the HM content of sewage accumulates in the sewage sludge, the experimental results showed nocompl...
Autori: Gábor Gulyás
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26477

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

AbstractThe present work is dealing with the identification of the mercury sources and the quantification of the mercury level in air andurban dust in the industrial area of Iasi municipality. A correlation between some meteorological indicators, atmospheric mercurycontent and the urban dust from the investigated area was pointed out, based on the real time measurements as well as spatialdistribution of other heavy metals in urban dust.The measurements of mercury level in air were carried out at...
Autori: Oana Maria Tucaliuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26479

AbstractThe conducted research has proved the dependence of gas flow rate in the separate channels of the two-level multichannel cycloneat a different inflow velocity and the number of channels. The carried out investigation demonstrates the dependence of changesin velocity in the channels under varying relations between peripheral and transitional flows. The work of a cyclone of the channelis based on centrifugal forces and an additionally occurring filtration process caused by the interaction ...
Autori: Pranas Baltrėnas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26488

AbstractThe study site is located on South of Bacau City, Romania, on two water courses: the Siret River – the branch flowing throughthe old riverbed downstream Galbeni Reservoir, and one of its tributaries - an infiltration channel, both of them being used by thelocals for fishing and irrigation, and the common meadow for grazing. The study covers the right side of the Siret River, betweenthe interception point up to Galbeni Reservoir dam and the equivalent length of the infiltration channel. T...
Autori: Maria Ema Faciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26494

AbstractAir flow measurements as well as concentration measurements within a naturally ventilated dairy barn (NVD) were carried outduring one summer season of 2012. Air flow measurements were performed using ultrasonic anemometers (UA), either as shortduration (20 min duration) measurements with a higher spatial distribution (using up to 9 UAs at the same time) or as long period(roughly 2 weeks) measurements with a lower spatial resolution (3 to 5 UAs). Measurements were conducted at two heights...
Autori: Merike Fiedler
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26496

AbstractConcentrations of seven heavy metals (Cd, Cr, Cu, Fe, Ni, Pb and Zn) in the discharged effluents of four wastewater treatmentplants located on the Romanian Black Seacoast, evaluated as average values for four seasons, during 2010-2011 are presented.Total and dissolved metals occurrence was investigated from seasonal samples, to assess the bioavailability of the heavy metalsin the discharged effluents. The analytical measurements were performed by flame atomic absorption spectrometry (FAA...
Autori: Elisabeta Chirilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26498

AbstractA pot experiment was conducted to evaluate the growth and metal accumulation in water spinach (Ipomoea aquatica) establishedon a 30-year old active firing range soil amended with chicken manure (CM) and coconut tree sawdust (CTS) at application ratesof 0%, 1% and 3% (w/w). Both amendments increased biomass yield and reduced plant metal uptake. The bioconcentrationfactor (BCF) and transportation factor (TF) values of the metals were in the order of Zn > Cu > Pb. The ammonium acetate...
Autori: Azlan Kamari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26499

AbstractThe paper concentrates on the risks of modern technologies (in wood processing and metal industry, spray-painting processes andcar washing technologies) in the industrial and office environments on human health. The problems discussed are the following:fine dust (PM2.5and PM1.0) penetrating deeply into the lungs; high concentration of carbon dioxide in the air of cities and officeareas that are situated close to the transport junctions. The health damages can be described as follows: all...
Autori: Ada Traumann
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26501

AbstractAnalysis and monitoring of arsenic is still a challenging analytical task. Due to its complex behaviour (different forms of arsenicthat can be present depending on pH and oxidation states of arsenic) as well as demanding analytical procedures and instrumentaltools for control of arsenic concentration in drinking water which is set to 10 μg L–1, there are still some open questions andissues when arsenic is the scientific topic. In this paper the idea was to use a multivariate statist...
Autori: Vladana N. Rajakovic-Ognjanovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26506

AbstractThe objective of this study is air pollutants discharging on active centers, depending on its relative electric permittivity, effectivein thermal, chemical and mechanical hydrogen relaxation enabling the fastest velocity of pollutant heat transport. The diagnosticsof relative electric permittivity is carried out on the basis of the daily pollutants mass concentration monitoring results, in sixthday period in the various seasons and locations in Romania and Serbia. The monitoring results ...
Autori: Milan Pavlović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26507

AbstractVegetables are an important part of a healthy diet because of their nutritional value. Contamination in vegetable may provehazardous for population. Polycyclic aromatic hydrocarbons (PAHs) are compounds widespread in the environment, many ofthem showing carcinogenic effects. These compounds can reach the food chain by different ways and, therefore, the analysis ofPAHs in food is a matter of concern.The present work provides data regarding levels of PAHs: acenaphthene (Ace), acenaphthylen...
Autori: Alina Soceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26510

AbstractThe mining waste facilities in the Baia Mare region, Romania, resulted from the extraction of poly-metallic ores (including Au,Ag). Metal sulphide minerals from the mining waste facilities have a potential to produce acid rock drainage (ARD) and togenerate risk for the environment, including for the water resources. Some of the mining waste deposits from the region arelocated near the town of Baia Mare, close to the residential areas, the agricultural lands and the surface water. The sho...
Autori: Oana-Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26512

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractAccurate quantification of gaseous emissions from livestock buildings to the atmosphere requires accurate determination of theventilation rate and the representative gas concentration in the exhaust air. But there is a lack in the investigation of reasons anduncertainties for selecting sampling points and locations in naturally ventilated dairy (NVD) buildings. The objective of thisstudy was to investigate uncertainties in calculating AER based on carbon dioxide (CO2) balance method. The...
Autori: Chayan K. Saha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26515

AbstractMost studies exploring the contribution of the mycorrhizal symbiosis to plant metal tolerance focus on plant-metal uptake anddisregard metal effects on the symbiotic fungi. We examined the tolerance of the model arbuscular mycorrhizal fungusRhizophagus irregularisto Al and Pb in vitro cultures with transformed carrot (Daucus carota L.) roots that exclude theinterference of other microbiota. We studied the development of roots and external mycelium of R. irregularis in monoxenic andaxenic...
Autori: Mayra E. Gavito
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26516

AbstractPetroleum tanker trucks are integral vehicles for delivering fuel and other petrochemical products from place to place and must becleaned regularly. Pressure washing with hot or cold water serving to remove oil and filth from the tanker truck container,produces oily waste water with an oil concentration of about 300-500 mg L-1 which, according to environmental standards andregulations worldwide, must be disposed of and treated properly. In the present paper an integrated electrochemical ...
Autori: Konstantinos Dermentzis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26520

AbstractTwo types of nanofiltration membranes had been used to study the influence of cross flow velocity on the membrane filtration ofdenitrification effluent (NF270 and NF90). Filtration had been conducted at constant transmembrane pressure of 5 bar andvariable cross flow velocity (0.03, 0.06, 0.15 and 0.39 ms-1). The obtained normal flux was 0.47, 0.58, 0.59 and 0.77for NF270membranes and 0.35, 0.38, 0.41 and 0.39 for NF90 membranes, the increase in cross flow velocity had enhanced fluxperfor...
Autori: Abdel Halim Fuqaha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26523

AbstractGreywater (GW) has attracted global attention as an alternative water source over the last few decades. GW treatment andreliable reuse require the overall qualitative characterization of samples from different sources. This paper represents aninvestigation of household-generated GW in the Northern Great Plain Region of Hungary. Modern and reliable analyticaltechniques and instruments (ion chromatography, microwave plasma atomic emission spectrometry, Zetasizer Nano Z analysis,etc.) were ...
Autori: Ildiko Bodnar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26528

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractThis study aims to understand the acid-leaching behavior of metals from 2 to 4 mm waste printed circuit boards (WPCBs)containing 22.0% ą 1.1 Cu, 6.7% ą 0.2 Ca, 0.68% ą 0.02 Sn, 0.59 ą 0.01 % Pb, 2.71% ą 0.08 Al, 0.22% ą 0.01 Fe, etc..Copper leaching was increased for sulfuric acid concentrations up to 1.2 mol/L and hydrogen peroxide concentrations of 10.0vol% for a pulp density of 100 g/L at 50°C over 4 h, whereas for the same concentrations of sulfuric acid and hydrogen peroxidecopper l...
Autori: Manoj Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26566

AbstractPresent study was envisaged to study chelators-metal interaction in phytoaccumulation of metals as a bioremediation technologyto decontaminate metal pollution and adsorption of metals on soil. Lactuca sativa was used as model plant for phytoaccumulationto identify uptake of Cadmium (Cd) and Lead (Pb) and their subsequent accumulation in edible tissue of plant. Cadmium andlead were two selected metals for phytoaccumulation and copper was also studied for adsorption experiment. Green house...
Autori: Audil Rashid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26568

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

Abstract The effects of cadmium (Cd), Zinc (Zn), and Cd–Zn on growth and their accumulation in the Matthiola flavida shoots were investigated. A factorial experiment with two factors (Cd and Zn) concerning four concentrations of Cd (0, 5, 10 and 20 mg L-1) and four Zn concentrations (0, 10, 20 and 40 mg L-1) were carried out. The shoot and root biomass of M. flavida growing in Cd- Zn medium decreased significantly (p<0.01) compared to the control. Growing in the presence of 20 mg L-...
Autori: Naser Jamali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26587

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract The assessment of heavy metals pollution using Xanthoria parietina (L.) Th. Fr. as an indicator species was performed for forests from Bucharest metropolitan area. This study aims to provide original data concerning environmental quality in relation to the intensity of car traffic. Metal concentrations in Xanthoria parietina measured in sites adjacent to roads were compared with those measured at a distance from traffic. The results show significant correlations between the Cd and C...
Autori: Ioana Vicol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26593

Abstract The present study was conducted to determine the heavy metals (Fe, Mn, Zn, Cu, Pb, and Cd) and essential oils content in the berries of Juniperus phoenicea L. grown in two different geographic origins; Dana conservation and Al-Hisha forest in Jordan. Atomic absorption and Hydrodistillation methods were used to determine heavy metals concentrations and oil contents in plant samples of J. phoenicea L., respectively. Results showed that, the oil yielded from J. phoenicea L. berries in ...
Autori: Mohammad Sanad Abu-darwish
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26595

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract Heavy metals, such as Cr (chromium), have received attention during recent years due to their disposal in soil and water. Brave peanut (Pterogyne nitens Tul.), a tropical tree, was cultivated in 500 mol L-1 Cr+6 to observe how this species responds to this stress, with a view to its possible application in the restoration of degraded areas. In the present study, we report the use of a new method, photoacoustic spectroscopy, to evaluate the emission of CO2 and ethylene and th...
Autori: Luisa Brito Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26602

Abstract Some of the major stressors of air quality in the urban areas are nitrogen oxides, ozone and suspended particles. The effect of air pollution on respiratory diseases can increase considerably at high levels of pollution and might trigger asthma symptoms. Longterm exposure can increase the rate of respiratory infections and symptoms at population level, but particularly in children. The goal was to analyze with statistical techniques the pollutant concentrations (NO, NO2, and SO2) re...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26605

Abstract Xi’an-Baoji Highway is one of the oldest and most important highways in northwest China. In this study, the concentrations (0-20 cm) of Pb, Zn, Cu and Cr at 5-1000 m distances in the roadside soils along Xi’an-Baoji Highway were experimentally determined to analyze their spatial distribution and evaluate their contamination levels. The spatial distribution (mg·kg-1) of Pb, Zn, Cu and Cr at 5-1000 m distances from the both roadsides (North/South) is, respectively, ...
Autori: Shuanxi Fan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26610

Abstract The present study deals with the removal of Cr (VI) from aqueous solution by polypyrrole (PPy). Response surface methodology (RSM) was applied for the design and analysis of experiments in the optimization of pH, temperature, initial concentration, contact time and adsorbent dose during the removal of the Cr (VI). The optimum adsorbent dose, temperature, initial concentration of Cr (VI), pH and contact time were found to be 0.8 g, 46.5 oC, 187.5 mg/L, 5.3 and 15.4 min respectively. ...
Autori: Ehsan Hasani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26614

Abstract This article presents the results of investigations addressing the accumulation of heavy metals in different layers of the Lake Talkša, Lithuania. For the sampling from the ice of intact structure of the sediment the turf borer was used. Concentrations of these heavy metals in sapropel layers were determined in the extracts of sapropel. After the preparation of samples, the concentration of Pb, Ni, Cr, Zn and Cu were measured in the laboratory by means of atomic absorption sp...
Autori: Justyna Kozlovska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26615

Abstract Samples were collected for six months (nine storm events) to observe the contaminant loads from three highway segments at Rawalpindi, Pakistan. The contaminants analyzed include total suspended solids (TSS), total dissolved solids (TDS), total nitrogen (TN), chemical oxygen demand (COD), total organic carbon (TOC), total phosphorous (TP), sulphate (SO4), chloride (Cl-), iron (Fe), copper (Cu), zinc (Zn), lead (Pb), and chromium (Cr). Mass vs. volume [M (V)] curves were drawn to inve...
Autori: Hamid Iqbal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26617

Abstract This study is focused on the dissolution kinetics of zinc oxide in ammonium acetate solutions to recover the zinc from alkaline and zinc-carbon spent battery powders. This study represents a first step for further studies in which actual waste powder is to be used. Therefore, the experiments were performed by using pure zinc oxide powder to evaluate the dissolution behavior of zinc. The effects of ammonium acetate concentration, reaction temperature, stirring speed and solid to liqu...
Autori: Nizamettin Demirkıran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26618

Abstract Malathion is a toxic, wide-spectrum organophosphorus pesticide. The removal of this pesticide from water is one of the major environmental concerns. In this study, the biodegradation of malathion using batch activated sludge was studied. The effect of initial malathion concentration (5 to 140 mg/L) on the degradation process was investigated. The biokinetic parameters (rs max, Ks and Ki) were estimated. Identification of dominant bacterial flora was also achieved. In addition, two k...
Autori: Djaber Tazdaďt
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26625

In the Huai River Basin, pollutant masses are frequently concentrated into dams and sluices, which are subsequently discharged anddestroying the downstream ecology and environment. This phenomenon has been termed the specified paroxysmal water pollution incident (SPWPI), which has attracted worldwide attention as a large-scale water pollution problem. Studies of the formation mechanism of SPWPIs have become an urgent topic for fundamental research in water pollution prevention and control. I...
Autori: Şukru Dursun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26628

Abstract The degradation of polycyclic aromatic hydrocarbons (PAHs) including fluorene, phenanthrene, anthracene, fluoranthene and pyrene were investigated under thermophilic and mesophilic anaerobic-methanogenic conditions. By using central composite design, the impact of PAH concentration and soil to inocula ratio were systematically studied for their influence on PAH removal and biogas production. During the first 30 days, PAH concentration decreased in all samples indicating that the ino...
Autori: Tahseen Sayara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26629

Abstract Based on the spray mixing field-effect analysis method, this paper has taken into consideration the variation in the distribution of oxygen concentration in the combustion process and has put forward the combined combustion field-effect analysis method. The method is applied to the matching study of a certain kind of diesel engine’s combustion chamber with air admission and fuel injection parameters and can also be used to complete the simulation analysis and evaluation of mix...
Autori: Xiang-Rong Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26634

Abstract This paper aims to develop the theoretical framework and the applicative implementation of a new analysis method, which has the purpose of determining and classifying mineral waters in Romania and Europe, with the use of mathematical modelling and fuzzy logic. Firstly, the article underlines the properties of mineral waters in terms of curative effects, particularly the role of Ca2+ and Mg2+ upon the human metabolism. The values of these two chemical elements will constitute an inde...
Autori: Alina Stefanache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26635

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract 18F-FDG is a glucose analog in which the hydroxyl group on the second carbon is substituted with 18F, being used as an indicator of glucose uptake and cell viability. The aim of this work was to synthesize the 18F-FDG and to validate the methodology for the assessment of its both radiochemical and chemical purities, according to the European Pharmacopoeia. The proposed methodology encompasses three chromatographic methods: radio-HPLC, radio-TLC and HS/GC. Radiochemical impurities ...
Autori: Mirela Mihon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26640

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract The environmental impact assessment (EIA) is a compulsory evaluation instrument for environmental management and decision making processes and applies to different phases of activities (plans, programmes, projects and /or existing production or services), because it measures the natural and anthropogenic activities effects upon the environment. These impacts may affect the cultural richness, biodiversity, social-economic conditions and human health as well as the ecosystem equilibri...
Autori: Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26645

Abstract Anaerobic digestion was analyzed as the biological process that converts the organic matter present in various types of wastes, activated sludge from the wastewater treatment facilities respectively, into biogas. Latest advancements in the mathematical modeling, simulation and control practices have helped in gaining a better insight of the process. In this paper, an energy efficiency and techno-economical investigation of anaerobic digestion technology for the CHP cogeneration unit...
Autori: Alexandrina Zuza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26648

Abstract Hydrogel membranes obtained by neat polyvinyl alcohol (PVA) or PVA with various bio insertions like: Scleroglucan (Scl), Zein (Zein) or Cellulose (Cel), were subjected to diffusion and sorption/desorption experiments using different type of dyes such as: Crystal Violet (CV), Methylene Blue (MB), Congo Red (CR). If the sorption, desorption or diffusion of a dye in/from/through a hydrogel is usually monitored by the dye solution analysis, in this case the transport phenomena are follo...
Autori: Adina Papancea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26649

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract The class of xanthene dyes has a complex chemical structure, which showed to be toxic for mixed culture of microorganisms (i.e. anaerobic granular sludge). Because of the unwanted effects of Erythrosin B (Ery B) on environmental components and some food confirmed previously, the dye was chosen in this study to evaluate its ecotoxicity. Also, the Ery B photocatalytic degradation products were assessed in terms of their ecotoxicity. Three-days of seed germination and root growth test...
Autori: Laura Carmen Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26660

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract The experiments on the olive oil mill wastewater treatment for removing the lipids by anaerobic and aerobic biodegradation with mixed Bacillus spp. culture indicated that the rate of the aerobic process is up to two times higher than that of the anaerobic one. In this context, it was found that the influence of the dissolved oxygen concentration on the lipids biodegradation process is significant, but the kinetic model given in literature does not consider this parameter. Therefore,...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26674

Abstract Nowadays, an efficient wastewater management involves the use of advanced treatment technologies able to decompose hardly biodegradable compounds with reasonable costs at the lowest possible environmental impact. In our work we used one of the most efficient advanced wastewater treatment, the Fenton reaction and its photo-assisted version. The hydrogen peroxide was the oxidizer; despite its relatively high cost, its high activity in oxidizing of a large variety of organic persistent...
Autori: Vasilica-Ancuta Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26677

Abstract In the present paper we studied the competitive transport of p-nitrophenol (pNP) and 2,4-dinitrophenol (2,4-dNP) from aqueous media using the technique of liquid membranes. This technique is very efficient, economic and selective when compared to other removal techniques of phenolic derivatives. The paper presents the influence of the sodium carbonate concentration from the stripping phase, the influence of the concentration ratio [2,4-dNP]/[pNP] upon the selectivity of the transpor...
Autori: Ioana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26681

Abstract The adaptation of commercially available ion-selective electrodes (ISEs) for use in wastewater matrices was demonstrated using multivariate analysis and optimization with the Microsoft Excel Solver tool. The electrodes were characterized in pure analyte solutions, and their parameters were estimated using multivariate analysis and Solver optimization. The ammonium, nitrate, and nitrite ions were measured in model systems that were designed to simulate wastewater. The accuracy of the...
Autori: Natalija Koprivanac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26687

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract The degradation and adsorption behavior of dibutyl phthalate (DBP) in methanogenic phase refuse was investigated through laboratory microcosm experiments. The results showed that the half-life of DBP in the sterilized refuse was 5.9 times higher than in unsterilized samples, but that it decreased by 35.8% when dominant bacterial strains were added. Different concentrations of DBP did not have obvious effects on its degradation. The half-lives of DBP were decreased by 53.0%, 37.2% an...
Autori: Chengran Fang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26690

Abstract In the process of chitin extraction, shrimp shell powder was treated by Lactobacillus plantarum culture. The efficiency of microbial demineralization (DM) under aerobic and anaerobic conditions was investigated. The shrimp shell powder was incubated at 30 °C for 6 days with L. plantarum. In order to prepare microbial culture, inoculums size was 5% for culture inoculation. Date syrup with total reduce sugar concentration of 30 g.L-1 was used. The value of pH in anaerobic conditio...
Autori: Marjan Khorrami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26692

Abstract The effect of goethite addition, hydrogen peroxide concentration, initial pH, hydroxyl radical scavenger and initial dye concentration on the decolorization of Orange II by Fenton-like process was investigated. The results showed that the decolorization rate increased with goethite addition and hydrogen peroxide concentration, but decreased with the increase of initial dye concentration. There existed an optimal initial pH to achieve the highest decolorization rate. The presence of ...
Autori: Hui Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26693

Abstract Anaerobic processes have been successfully applied in the treatment of municipal and industrial wastewaters. Judicious use of nutrients in anaerobic treatment has not been systematically investigated. The optimal nutrient dosage for anaerobic wastewater treatment systems is largely unknown. In this paper, COD:N:P ratio used by various researchers in anaerobic wastewater treatment systems for treating different types of wastewaters are compiled and critically analyzed. In order to ha...
Autori: Athar Hussain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26697

Abstract The main purpose of this paper is to assess the concentration levels of pollutants at six urban sites in Bucharest, Romania in order to draw conclusions on their temporal variability in different sources and under different meteorological conditions. The analysis of measured pollutant concentrations (NOx, NO2, CO, PM10) runs over three years: 2005, 2006 and 2007, and uses data from the network of monitoring stations of Environmental Protection Agency of Bucharest, which was establis...
Autori: Sabina Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26701

Abstract The main purpose of this research was to study the biodegradation ability of atrazine by using Arthrobacter sp. as free and immobilized cells of the strain DNS10, under several important environmental factors such as temperature, pH, salinity, substrate concentration. Furthermore, this paper objective was also to assess the process considering the immobilization under extreme conditions, such as high salinity and high atrazine concentration. DNS10 was immobilized on a sodium alginat...
Autori: Zhang Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26702

Abstract Individual exposure to particulate matter (PM) fractions is mainly determined by indoor source characteristics and personal activity patterns. This paper discusses experimental results obtained through the analysis of individual exposure of women to PM10 and PM2.5. To this purpose, 15 volunteers of different ages and lifestyles living/working in Ceccano (Italy) were selected and their exposures to PM10 and PM2.5 were measured through a handheld photometer. They also filled out a tim...
Autori: Giorgio Buonanno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26703

Abstract In this study, the efficiency of Fenton’s process to remove nickel (II) from industrial plating effluent was investigated. The effect of pH, contact time, concentrations of Fe2+ and H2O2 were surveyed. Kinetic experiments were performed in order to predict the nickel (II) removal rate from wastewater. At pH 1 to 4, nickel (II) removal efficiency increased and declined at pH > 4. The maximum nickel (II) removal efficiency was 98% at 60 min contact time, pH: 4, and Fe2+ and H...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26704

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract The removal efficiency of algal biomass Chlamydomonas reinhardtii for Pb and Cu metal ions was evaluated in single and binary metal systems. Biosorption experiments were performed in solutions containing 0.2 g L-1 of algal biomass at 30oC and pH 6. Initial metal ion concentrations ranged from 10-7 M to 10-6 M. Thermal analysis of the biosorbent indicated that algal cells are composed of groups containing C, H, N, and S. The presence of ionisable functional groups responsible for bio...
Autori: Roula Flouty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26709

Abstract Adsorption has proved to be an excellent way to treat industrial wastewater, due to its significant advantages like easy availability, inexpensive, ease of operation and highly efficient, compared to conventional expensive adsorbents like activated charcoal, alumina etc. The present investigation focused on utilization of Mangifera indica seed shell substrate for the removal of toxic heavy metals like Fe(II) and Mn(II) from wastewater. Mangifera indica seed shell substrate as an eff...
Autori: Tikaram D. Kose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26713

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract The objective of this study was to identify differences between three of the most conventional UV-based advanced oxidation processes, namely photolysis, UV/TiO2, and UV/ZnO for the decolorization and mineralization of reactive red 198 (RR198) model dye in saline media. The study investigated influences of solution pH levels, salt concentration, reaction time and dye concentration on the degradation of RR198. The most effective dye removal and mineralization was observed at pH levels...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26724

Abstract Large quantities of snail and clam shells are left as waste material when their meat is used as food for people. It has been a big problem that how to treat these wastes and usually these are land filled as wastes. In the present paper, these shells are studied as recycling resource for phosphate removal from solutions. Laboratory-scale batch experiments were conducted to evaluate the efficiency of snail and clam shells in removing phosphate from aqueous solutions. Major factors inv...
Autori: Ji Bing Xiong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26727

Abstract This paper aims to analyze the characteristic of Road deposited sediment (RDS) using West Chang Tan highway, Hunan, China as a study site. RDS samples were collected at five representative highway sites and the particle size distribution was generally less than 150μm. Particles with the grain size (<150μm) had high metal concentrations among all sampling sites (unit: mg/kg): Cu 74-178, Zn 309-2737, Pb 601-1160, Cd 9.8-44.5. There is significant spatial variability between t...
Autori: Yunbo Zhai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26728

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract The juglone (5-hydroxy-1,4-naphthalenedione) can be found in the leaves and fruits of the black walnut (Juglans nigra L.). This substance has an inhibitory effect on the growth of the vegetal species, phenomenon which is named allelopathy. The inhibitory effect of the 50-100% concentration of this water extract, prepared from the black walnut fruits, on the seeds germination, plantlets growth and peroxidasic activity – registered in the seedlings roots – was poor, compar...
Autori: Dorina Cachiţă-Cosma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26730

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract In paper processes, the variability of effluent composition and flow is impossible to predict and generally depends on the type of production method used and the manufacturing breakdowns suffered. Wastewater treatment plant operators find it difficult to maintain the efficiency of biological treatment processes. This paper focuses on activated sludge treatment modelling of paper mill wastewater to provide operators with additional support. Based on both standard activated sludge mod...
Autori: Catherine Cadet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26732

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract In Hungary, 0.5 million m3 of thermal water is exploited every day for diverse purposes. After utilization, this enormous amount of thermal water becomes sewage water with a high concentration of salts, heavy metals, ammonia, nitrate, an unfavorable ion composition and high temperature. A common treatment is to dispose of waste water into a surface recipient through uninsulated channels surrounded by arable land. By infiltration, sewage water can cause potential salinization/sodific...
Autori: Andrea Farsang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26742

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract Diclofenac (DCF), which belongs to nonsteroidal anti-inflammatory drugs (NSAIDs), is a biorefractory micropollutant and its removal from wastewaters has become strongly necessary. This paper dealt with the DCF removal from aqueous solutions by electrooxidation at boron-doped diamond (BDD) electrode. In addition, the dual character of BDD electrode in electrochemical degradation processes and their control was investigated. The electrooxidation process was assessed based on ultraviol...
Autori: Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26755

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract A VOC monitoring was carried out inside and outside a multi-storey car park in order to characterize the emission profile of vehicular traffic source in an indoor environment. BTEX, and in particular toluene, were the most abundant compounds in all monitored sites, with different compositions between indoor parking areas and outdoor sites. The motor vehicle exhaust and gasoline vapor emission in these enclosed parking garages were characterized by diffusion or degradation phenomena ...
Autori: Gianluigi de Gennaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26778

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract Hydrolysates of Arundo donax, a crop offering high productivity in contaminated or salinized soils with no inputs of irrigation and agrochemicals, were used in a discontinuous fermenter to grow the oleaginous yeast Lipomyces starkey, to obtain microbial oils potentially useful for the production of 2nd-generation biodiesel. A mixture of fermentable sugars was obtained by steam-explosion and subsequent enzymatic hydrolysis of the lignocellulosic materials. The concentration of Ni2+ ...
Autori: Domenico Pirozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26789

Abstract This study was aimed to stimulate laccase production by Trametes pubescens MUT 2400 by using a tomato-based medium. Two sequential 2x2 factorial designs were used to determine the effect of carbon (C) and nitrogen (N) source concentration on laccase activity and biomass concentration; copper was used as the sole inducer (0.75 mM). Analysis of the first factorial design showed that N had a strong positive effect on the maximum laccase activity, which occurred at day 12 of cultivation...
Autori: Federica Spina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26795

Abstract The aim of this study is to assess indoor air quality in an educational institute located in a suburban area of the Po plain (Italy). Samplings are carried out in preschool and elementary school classrooms, and also in the garden of the institute, to have information on outdoor levels. The monitoring is performed to determine the most important indoor pollutants (i.e. volatile organic compounds (VOCs), carbonyls and NO2), by using diffusive passive samplers. Sampling in the classroo...
Autori: Ivano Vassura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26797

Abstract In this paper, the structure and working principles of a microbial fuel cell (MFC) are analysed, and a mathematical simulation model of MFCs is established based on the electrochemical equation, kinetic equation and material balance equation of a MFC. A simulation analysis and discussions are conducted in a MATLAB environment to investigate the effect of acetate concentration, influent flow and external resistance on the performance of a MFC system. The simulation model is demonstra...
Autori: Aimin An
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26803

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract The short-term effects of plant diversity (number of plant species and species compositions) on aboveground biomass, substrate inorganic nitrogen (N) concentrations, and substrate solution “effluent” N concentrations were studied in a subsurface verticalflow constructed wetland (CW). Results showed that (1) the number of plant species increased aboveground biomass (P< 0.05) but had no effect on the overyielding index DMax; (2) the species compositions and presence of ...
Autori: Hai Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26822

Abstract Following the implementation rules of EU INSPIRE Directive, we designed, developed and tested a system for pollution detection, alert and pollution propagation simulation on the Cyberwater platform. We address the challenge of providing public information about water quality parameters measured by Wireless Sensor Networks placed on the river shore. The system provides pollution alerts based on the analysis made on the monitored water parameters. Furthermore, it is able to estimate t...
Autori: Lucia Vacariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26828

Abstract This article presents the result of investigation on the spatial and temporal changes in water quality of Uluabat Lake. It examines the relationship between water and sediment quality parameters, and assesses the factors affecting eutrophication. Water and sediment quality are examined at 8 stations in the lake between May 2008, and May 2009. Water and sediment quality parameters measured are T, pH, EC, SD, NH4-N, NO3-N, TN, PO4-P, TP. Also DO, alkalinity, hardness, SS, BOD, COD, Ch...
Autori: Feza Karaer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26850

Abstract The amount of bottom ash produced in Italy from municipal solid waste incinerators is estimated at over a million tons per year. Up to now, it has almost all been disposed of in landfills. Therefore, large profit margins, from both the economic and environmental standpoint, can be expected from the recovery of this material, or at least from a fraction of it. In this study, a rapid procedure for the recovery of different bottom ash fractions based on mechanical sorting and aging was...
Autori: Ivano Vassura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26853

Abstract This work presents the optimization of process variables to maximize the percent of Fe (II) removal, R (%), by chelating resin Purolite S930 from 34% CaCl2 solutions. To study the combined effect of the initial solution pH, initial Fe (II) concentration and resin dosage was used a 23 orthogonal central composite design and Response Surface Methodology (RSM) for analysis of experimental data. To optimize the regression equation was used The Gradient method. The study discovered that ...
Autori: Camelia Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26856

Abstract Free cells of Rhizopus oryzae were used to study adsorption of several cations (Cu2+, Zn2+, Mn2+, Ni2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The influence of biomass dosage, pH and temperature on the removal process was investigated. The sorption efficiency increased with increasing the temperature in the range from 25 ºC to 30 ºC and pH from 5 to 8. The maximum removal percentage was achieved at a biosorbent concentration 0.25 – 0.3...
Autori: Kolishka Tsekova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26857

Abstract The atmospheric air is considered a large and renewable source of fresh water. The present work investigates the application of solar energy to heat wick clothes impregnated with calcium chloride to extract water from atmospheric air. A wick desiccant solar collector is erected at Tanta – Egypt for this purpose. The desiccant concentration at the beginning of regeneration is determined according to the climatic conditions. The saturated wick desiccant is exposed to an ambient ...
Autori: Abd elnaby Kabeel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26861

Abstract In this study, Moringa oleifera seed extract was applied as coagulant under different pH values (2.5 - 9.5), coagulant dosages (200-600 mg/L), initial dye concentrations (50-300 mg/L) and different settling times (0- 60 minutes) for R. Blue 19 and R. Red 120 dyes removal. Results revealed that with increase in pH (from 2.5 to 9.5), removal efficiency decreased from 95% to 87.3% for R. Blue 19 and from 97.2% to 62% for R. Red 120. By increasing coagulant dosage to 400 mg/L, removal e...
Autori: Ali Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26864

Abstract In this paper we present results from the first European (EUR) and North Atlantic (NAT) volcanic ash exercise (VOLCEX) which includes all the warning phases associated as alerting, reactive and proactive phases. Because volcanic ash represents one of the most serious natural hazards that could affect aviation safety, the measurement campaign was focused on improving the reaction of relevant authorities in case of airspace contamination with volcanic ash and, particularly, to assess ...
Autori: Livio Belegante
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26874

Abstract Flame atomic absorption spectrometry (FAAS) and X-ray fluorescence spectrometry (XRF) were used as investigation techniques in the assessment of soils contaminated with metals such as Pb, Cu and Zn. The investigation focused on the comparability of the concentrations determined by the two methods, in order to identify the most suitable approach for Pb, Cu and Zn quantification, with respect to metal monitoring in brownfields. Generally, the concentrations obtained through FAAS were...
Autori: Maria Lucia Bizo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26875

Abstract The aim of this study was to determine the content of the main essential trace (Co, Cr, Cu, Mn, Se and Zn) and toxic (As, Cd, Hg and Pb) elements in milk by inductively coupled plasma-mass spectrometry (ICP-MS) and cold vapor atomic fluorescence spectrometer (CV-AFS) following priory microwave-assisted digestion with HNO3-H2O2. The milk samples were collected from local small-scale producers of different parts of Rodnei Mountains, Eastern Carpathians, Romania. Mean concentrations in...
Autori: Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26876

Abstract The aim of the present study was to determine the most feasible experimental conditions for the dissolution of base metals (Cu, Ni, Zn, Pb, etc.) from waste printed circuit boards (WPCBs) obtained from WMP. The leaching of WPCB samples was performed with FeCl3 in HCl solution which allowed the separation of a precious metal rich solid residue and a high base metal concentration solution adequate for base metal recovery. The most favorable conditions for the leaching process were ide...
Autori: Szabolcs Fogarasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26877

Abstract Ash resulting from wood combustion constitutes a waste disposal problem to facility owners. The use of ash fertilizer or soil amendment could provide nutrients for agriculture if its nutrient content is adequate and it does not contain harmful amounts of heavy metals. The recycling of nutrients bound in ash would provide an inexpensive solution to waste problem. In our study, we aimed to characterize ash and clinker resulted from incineration of oak waste resulted from wood industry...
Autori: Ioan Oroian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26885

Abstract Urban areas represent the main zones of anthropogenic emissions and, at the same time, includes the largest number of population exposed to air pollution. Data related to traffic hot spots locations in Sibiu urban areas are presented and discussed in this paper. It is important to assess the impact of changing climate conditions and concentration of pollutants, these aspects are of special interest because of high and increasing population of urban regions exposed to consequences of...
Autori: Valentin Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26887

Abstract Air pollution is an increasing critical issue and the focus of innumerable studies and monitoring activities. In addition to automatic monitoring systems typically used to measure fine dust, ozone, nitrogen oxide and sulfur oxide, the use of bioaccumulation monitors can also be exploited, especially when monitoring large areas. The advantage of biomarkers is the very low costs involved compared to traditional monitoring systems. Bio-indicator techniques do not measure directly air q...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26892

Abstract Romania has recorded a dramatic number of road traffic accidents in the last five years. The latest European documents and statistics indicate that the country has the highest number of traffic fatalities across the Member States of the European Union. The aim of the paper is twofold. First, the authors aim to analyze the spatial characteristics of traffic accidents for the period 2010-2014: spatial distribution of accidents at county level, number of vehicles involved, socio-spatia...
Autori: Silviu Marian Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26893

Abstract The results of batch tests of anaerobic dechlorination on groundwater samples collected downgradient from an industrial site in Northern Italy are presented and discussed. The experiments were carried out using sucrose as electron donor at equimolar concentration and at selected excess with respect to the total reducible species. The purpose of the study was to investigate the effectiveness of sucrose to achieve a complete chlorinated solvents degradations at the specific site, and ...
Autori: Luca Di Palma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26895

Abstract The present study analyzes the background pollution in Romania using official data reported for recorded air pollutants from the automated regional stations located at three mountain sites. A series of key figures regarding the trend of background pollution at Romanian mountain sites was extracted based on annual average concentrations recorded between 2010 and 2013 i.e. 8.8 ± 5.2 μg NO2/m3, 5.3 ± 1.6 μg SO2/m3, 0.075 ± 0.035 μg CO/m3, 3.2 ± 0.9 ...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26897

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

Abstract The objective of this study is to manufacture a geopolymer by replacing part of the metakaolinite by calcined oil-contaminated clay (OCC) and investigate its properties. The effects of the calcination temperature, the mix design of the alkali activator, and the degree of calcined OCC replacement on the properties of the geopolymer were studied. Evaluation of pozzolanic activity and compressive strength as well as micro structure observation by SEM and XRD were performed in this stud...
Autori: Huan-Lin Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26905

Abstract Much attention is paid to removing formaldehyde from indoor air to decrease the health risk for urban inhabitants since formaldehyde is a main indoor pollutant causing various symptoms. In this study, formaldehyde removal by the shoots of potted Chlorphytum comosum (spider plant), Epipremnum aureum (golden pothos) and Aloe vera (aloe) was investigated with a dynamic chamber technique. The results indicated that the order of formaldehyde removal capacities for the plant shoots was C....
Autori: Haiping Hou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26908