Include urmatoarele articole� Degradation of alcian blue 8 gx by heterogeneous and homogeneous photocatalytic processes� Evaluating the performance of solid waste management models� Bioreactors with stirred bed of immobilized cells 1. Studies on mixing efficiency� Fugitive emissions estimation from petroleum storage tanks� New Ni(II) coordination polymers with insulating and anticorrosive properties� Determination of water quality deterioration at pilgrimage centre along river netrav...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25196

AbstractIt was investigated the bioleaching of uranyl ions from uranium ores, in aquatic medium with algae: Scenedesmus quadricauda and Nostoc linkia under different experimental conditions. The oxidation of U(IV) to U(VI) species, like uranyl ions was done by means of the atomic oxygen generated through photosynthesis by the aquatic medium from solution above of uranium ores.After almost 10 days of direct contact with the given microorganisms, it was observed a bioleaching degree between 10% an...
Autori: Alexandru Cecal, Rodica Calmoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25107

AbstractThe objective of the paper is to present sustainability indicators for municipal solid waste management (MSWM). Sustainability implies environmental, economic and social acceptance. The complexity of the system-in-focus requires the employment of a systems (or cybernetic) approach: Acceptance implies clear objectives, from a specific point of view (here, the viewpoint of the municipal administration is taken), over a time horizon covering at least two generations, a life-cycle considerat...
Autori: Demetrios Panagiotakopoulos, Konstantinia Tsilemou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25112

<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

The present paper examined the photocatalytic degradation (PCD) of gas-phase trichloroethylene (TCE) over thin-film TiO2. A large-scale treatment of TCE was carried out using scale-up continuous flow photo-reactor that nine reactors were arranged in parallel and serial. The parallel or serial arrangement is a significant factor to determine the special arrangement of whole reactor module as well as to compact the multi-modules in a continuous flow reactor. The conversion of TCE according to the ...
Autori: Gyung Soo Kim, Sang Bum Kim, Sung Chang Hong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25121

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Plants as biomarkers, biosensors and biomonitorsModelling of wastewater treatment of a pulp and paper mill for monitoringCatalysts for heterogeneous photocatalysts. Part I. Possibilities to improve photoefficiency through catalysts modificationThe global assessment method of the water qualityAspects regarding the wood certification in RomaniaDecolorizing of pulping effluents by ammonium lignosulphonate oxidationPowder coatings-based organic filmsOn environmental effects of the pulp and paper mil...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25172

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei, Gabriela Apostolescu, Ioan Rosca Studies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monit...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25175

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

Contain all the articles from this issueLignin in crop cultivations and bioremediationAlfred Abaecherli, Valentin I. PopaMaterials for intermediate-temperature solid oxide fuel cells and for proton exchange membrane fuel cellsAnnemarie Huijser, Joop SchoonmanAre interfacial biocatalysts important tools for nonpolluting technologies? 2. Immobilization of lipases and their  representative applications Brindusa Dragoi, Emil DumitriuUASB treatment of fruit canning wastewater: pilot-scale invest...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25180

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� "Waste not, want not" a study of household attitude toward recycling of solid wastes� A kinetic model for the crystal violet mineralization in water by the electro- fenton process� Development of a coagulation/flocculation predictive model for turbidity removal from tehran water treatment plants� Removal of cadmium (II) from aqueous solutions by sphagnum moss peat: Equilibrium study� Environmental sustainability based on fuzzy models� Impact of dust emi...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25207

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

AbstractThe paper presents new experimental results on the photodegradation of two important phenyl urea herbicides in water: Monuron and Isoproturon. The photodegradation was performed by two Advanced Oxidation Processes (AOPs): the homogeneous photo- Fenton process (, UV-H2O2 - Fe3+) and a heterogeneous photo - Fenton reaction using an iron pillared Laponide- RD catalyst (Fe-Lap-RD). The Fe-Lap-RD catalyst was prepared from iron nitrate 0.2 M solution and a suspension of Laponite - RD clay. Th...
Autori: Elsa Lundanes, Ilie Siminiceanu, Maria-Magdalena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25234

AbstractPolycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector ...
Autori: Alina Soceanu, , Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25237

AbstractLaboratory scale experiments were conducted in order to investigate the photolysis of Reactive Blue 19 (RB 19) dye using UV as the irradiation source in alkaline solution. The effects of operating parameters such as, pH, initial dye concentration, UV dosage, hydrogen peroxide and oxygen have been evaluated. The results indicate that the UV photolysis process in alkaline solution is ideal for decolorizing of RB 19 and it can be taken as a starting step to establish the economical feasibil...
Autori: Abbas Rezaee, Ebrahim Hajizadeh, Gholamreza Mosavi, Mohamadtaghi Ghaneian, Seyyed Jamalodin Hashemian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25245

AbstractThe synthesis of some grafted polysiloxane and azo-polysiloxanes with potential applications as rheology modifiers or surfactants for waterborne paints is reported. Nowadays it became very important to design environmentally friendly systems exhibiting the best end-uses properties. Due to their complex architecture and their sensitivity to UV radiation the studied polymeric systems exhibit very interesting rheological properties. All the polymers containing the azobenzenic groups in the ...
Autori: Constanta Ibanescu, Ioana Moleavin, Iulian Nor, Nicolae Hurduc, Viorel Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25252

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractThe paper proposes a suitable solution for a one step treatment process of the wastewaters resulted from the textile industry, using a mixture of anatase and modified fly ash. The dyes photo-degradation on TiO2 anatase is well known. The use of fly ash in advanced wastewater treatment, for heavy metal adsorption, represents an environmental friendly process, efficient if the fly ash surface charge is controlled by solubilisation/reprecipitation. The first step in implementing the single ...
Autori: Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25292

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract Pollution with toxic metals is a serious concern, because once these elements enter in the soil they can be present for a long time, with the potential contamination of drinking water sources. Certain metals in soil may be taken up by plants which are subsequently harvest for human consumption. Our objective was to study the presence of heavy metals in soils, groundwater sources, some medicinal plants from areas of the water sources and in its watery extracts. All of the samples, af...
Autori: Diana Diaconu, Victor Nastase, Mara Mihaela Nanau, Ovidiu Nechifor, Elena Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25411

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract Textile industry is one of the most pollutant and water consuming industries. Large quantities of water are required in materials preparation and dyeing, so consumption and waste generation have become serious concerns for textile manufacturers and finishers. Textile effluents are characterized by high values of quality indicators such as BOD and COD, suspended solids and heavy metals. A serious environmental problem and also an aesthetic problem is the color of the effluent. Reactiv...
Autori: Daniela Cailean, George Barjoveanu, Corina - Petronela Musteret, Liliana Rozemarie Manea, Nicolae Sulitanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25420

Abstract The photocatalytic degradation of sulfamethazine, a sulfonamide drug, has been investigated experimentally, in aqueous heterogeneous solutions containing n-type oxide semiconductors as photocatalysts, and by simulation, using neural network modeling. Through direct neural network modeling, the evolution of the photocatalytic oxidation process is evaluated as function of illumination time and type of catalyst. Inverse neural network modeling is a particular optimization that gives inf...
Autori: Ciprian George Piuleac, Ioannis Poulios, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25430

Abstract In designing an efficient photovoltaic system, the meteorological data of the system location must be considered. Field data registered over years prove the importance of the implementation site characteristics in the design and optimal exploitation of a PV system, because wetting and atmospheric gaseous and particulate pollution can strongly distort the incident solar radiation. Thus, in addition to the efficiency of the solar module, the tracking efficiency, the clouds crossing fac...
Autori: Dorin Valentin Diaconescu, , Ioana Sinziana Hermenean, Maria Monica Vatasescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25464

Abstract Increasing the solar energy conversion into electrical or thermal energy represents an European and national priority, because it offers clean alternatives to the use of fossil fuels, in no pollutant systems, based on photovoltaic modules and solar collectors. The global solar radiation is the most important factor affecting the amount of energy produced by a PV module. In direct connection with the change in the solar energy conversion, the TR - Loss Coefficient (Tr??bungsfaktor) is...
Autori: , Dorin Valentin Diaconescu, Maria Valentina Dinicu (Popa), Bogdan Gabriel Burduhos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25465

Abstract This paper presents an experimentally study of the anionic iodide separation from a mixture with immobilized liquid membrane. The experiments were carried out in a double jet installation. In order to intensify the transfer of iodide ions from the source phase to the receiving phase, the both phases are dispersed as droplets in the membrane and the hydrodynamic parameters of the dispersed phases are measured with the photographic method. The photos of the droplets were taken with a C...
Autori: Mihaela Emanuela Craciun, Mihaela Mihai, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25476

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract Nanotechnologies may have properties of self-assembly, stability, specificity, drug encapsulation and biocompatibility as a result of their material composition. Nano-particles are being actively developed for tumour imaging in vivo, bio-molecular profiling of cancer biomarkers, and targeted drug delivery. These particles are stable, environmentally benign, and their chemical properties can be easily tailored by chemically modifying their surfaces. Conjugated with pharmacological a...
Autori: Simona-Florentina Pop, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25484

Abstract The paper presents the results obtained when using thin films (doctor blade) of titanium oxide powder (Degussa P25) and fly ashactivated with NaOH, for advanced treatment of complex waters resulted in the textile industry. There are studied the heavy metal(cadmium, copper) adsorption and the dyes (methyl orange and methylene blue) photo-degradation using these novel substrates.The thin films crystallinity (XRD), morphology and roughness (AFM) were evaluated and no significant changes...
Autori: Anca Duta, Luminita Andronic, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25500

Abstract The recent results of technical development of low cost GPS systems, geographic information systems, equipment and sensors which are needed to identify the state of the crops and soils have shown a growing awareness in agriculture and related sciences. The actual demand for modern crop management is dominated by the economic pressure and by the social request to increase the transparency of environmental impact of agricultural land. Currently, worldwide there are the public policy a...
Autori: Vergil Marian Muraru, Cornelia Muraru-Ionel, Ion Pirna, Ion Tenu, Petru Cardei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25504

Abstract In the textile finishing and dyeing industries, the total volume of water consumed is around 150 millions tons/year, and thus very large quantities of water are processed and produced as wastewater by textile plants. Quality indicators of textile wastewaters, like BOD and COD, have values which, in some cases, exceed 5 times the maximum concentration value (allowed by the national quality standards). One of the greatest concerns in wastewater treatment of a textile effluent is the co...
Autori: Daniela Cailean, , Florin Brinza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25538

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract In this work the method for the treatment of industrial waste waters effluents containing hexavalent chromium in three companies during process of treating metal surface with chromic acid is described. Industrial water polluted with hexavalent chromium is collected in separate sewage system. Polluted water is collected in precipitation tanks which are directly connected with neutralization reservoirs. The treatment process includes pre-neutralization by lime-milk, sedimentation, floc...
Autori: Igor Creţescu, Mirjana Cvijovic, Predrag Djurdjevic, Slavica Cvetkovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25596

Abstract The aim of this study is the evaluation of photo-Fenton as a suitable advanced oxidation process to degrade ampicillin and streptomycin antibiotics. The degradation was studied by monitoring the organic substrate concentration changes in aqueous solution as a function of reaction time using COD analysis. The oxidation process follows two successive stages. In the first stage (I) the oxidation of the antibiotics takes place with high reaction rate, leading to intermediate oxidation pr...
Autori: Cristina Orbeci, Daniela Simina Stefan, Ion Untea, Madelene Dancila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25602

? RESEARCH ON NaCl SALINE AEROSOLS I. NATURAL AND ARTIFICIAL SOURCES AND THEIR IMPLICATIONS ? DECISION SUPPORT MODELS FOR SOLID WASTE MANAGEMENT ? AN OVERVIEW ? POLICY AND STRATEGY FOR IMPROVING SUSTAINABLE SOCIAL DEVELOPMENT PROGRAMMES ? APPLICATION OF SHALLOW POND SYSTEM USING WATER HYACINTH FOR DOMESTIC WASTEWATER TREATMENT IN THE PRESENCE OF HIGH TOTAL DISSOLVED SOLIDS (TDS) AND HEAVY METAL SALTS ? TRENDS OF THE COMMUNITARIAN COHESION POLICIES AND ADVERTISING FOR EC...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25658

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

The beneficial effect of urban plants in improving air quality is often mentioned in literature but is seldom quantified and valuated. Quantification and valuation of the benefits provided by urban plants allow direct comparison between plant species and help make more informed urban planning decisions. Based on fieldwork study and data processing, carbon dioxide (CO2) sequestration, oxygen (O2) generation, transpiration cooling, sulfur dioxide (SO2) removal and dust interception are quantified ...
Autori: Qijiao Xie, Zhixiang Zhou, Fang Chenhttp://www.ecozone.ro/reviste.php?RID=25710

Abstract:In spite of the large use of batteries throughout the years, both in photovoltaic systems and in other uses, there are still nocomprehensive analyses in ageing studies and, when they exist, statistics turn out to be limited. In this sense, this macro-grid is aunique experience, since the experiment is already composed of 1600 identical stand-alone photovoltaic systems and almost 10years of data taking on 10 minute interval for the main magnitudes.In this paper, it is proposed a method f...
Autori: Angeles López Agüera, Daniel Rey Rey, Iago Rodriguez Cabo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25718

Abstract:The textile industry uses high quantities of water which in many cases are disposed to the environment with inadequate treatment.In this work the effluents from the polyamide textile industry containing Bemacid Gelb, Bemacid Rot and Bemacid Blau weretreated by heterogeneous photodegradation. Treatment performances have been evaluated in terms of conductivity, turbidity, totaldissolved solids (TSD), chemical oxygen demand (COD), total organic carbon (TOC), biochemical oxygen demand (BOD5...
Autori: Luminita Andronic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25720

Abstract:Point of zero charge (PZC) is defined as the condition at which the surface charge density of a material equals to zero and, formost of the solids it is strongly pH dependent. The PZC can be controlled by tuning the solid surface properties (crystallinestructure, morphology) and by a proper environment control, thus it is important to evaluate the PZC for a certain type of material,in given working conditions, for enhancing the efficiency in the targeted application (e.g. layer by layer...
Autori: Laura Maria Bertus, Radu Adrian Carcel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25721

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

Abstract:The demand for new and high performance products in the automotive industry is increasing exponentially and this trend imposesinnovative concepts for cars. The future solutions for the automotive industry may find their answer in the fabricationtechnologies and also in alternative propulsion and energy production.The car design field cannot ignore the global economic crisis, imposing new approaches in terms of materials and cost effectivetechnologies and by the means of environmental pr...
Autori: Mihai Comşiţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25733

Abstract:The article presents a method of monitoring the solar radiation components taking into consideration the isotropic model. Thewireless solar radiation monitoring system developed is innovative and original in comparison with the systems already availableon the market. The use of the wireless device, of the rechargeable batteries, of the sensors used for measuring the solar radiationcomponents and the temperature make this system an autonomous and a portable one. An experimental prototype...
Autori: Cornel Samoila, Daniel T. Cotfas, Doru Ursutiu, Paul Borza, Petru A. Cotfas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25735

Abstract:In order to capture as much solar energy as possible, the photovoltaic converter has to follow the sun movement during a day; thiscan be achieved by a tracking system. Most tracking systems have complex and costly structures that can provide wide anglevariations. This paper presents a geared linkage that is build up by a planetary system of gears fitted on a linkage, and thus helpsin reaching wide angles. Starting from a patented linkage, which reaches ≈200° angular strokes, by a...
Autori: Dorin Diaconescu, Ioana Hermenean, Nora Creanga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25736

Abstract:The paper presents the influence of different WO3:TiO2 ratios on the photocatalytic and photoelectrolytic properties of the films.The investigations are focused on the morphological (Atomic Force Microscopy, Contact angle), compositional (X-raydiffraction), optoelectric (conductivity, photocurrent) and photocatalytic properties of titanium dioxide films mixed with tungstenoxide. The most important application of these layers is in wastewater purification and hydrogen production using ap...
Autori: Alexandru Enesca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25743

Abstract:The paper aims to present the new pattern of modular agriculture, as evolution of agri-food production in the coming decades aswell as to highlight the direct relation between this pattern and the massive energy support it requires.The paper basically deals with reactions to climate change, reductions of carbon emission, in addition to high quality and safetyrequirements for food production. The author envisages the PAC measures called for in order to ensure a sustainable developmentof ...
Autori: Romulus Gruia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25746

Abstract:For the optimal working of the concentrating photovoltaic systems (CPV), these are usually tracked, and the accuracy required infollowing the sun path is much higher than in non-concentrating system. The paper focuses on the synthesis of the optimal steptracking program of an azimuth tracking system, used for accurate tracking of a CPV system. The paper presents the synthesismodelling algorithm and the numerical simulations for a CPV system, orientated with an azimuth tracking system, i...
Autori: Ioana Sinziana Hermenean, Ion Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25748

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

Abstract:Energy mix used in "Solar House" is currently composed of about 50% renewable energy sources (geothermal energy) and 50%conventional sources of energy (mainly electricity from national grid and less than 10% natural gas). The geothermal energy isextracted by the mean of a ground coupled heat pump which assures the heating load of the "Solar House" and the preparation ofdomestic hot water. The peak load in heating period is covered by a natural gas boiler and the electricity to drive the...
Autori: Bogdan Burduhos, Ion Vişa, Macedon Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25756

Abstract:It is of major importance that the mechanical structures and components of a photovoltaic (PV) system to have the same durabilityas the PV modules. The embodiment design process of the mechanical structure becomes significant as the results provide anoverall view of the PV system durability. The performance of the mechanical system must be attained based on functional andoperational requirements of the PV system. Therefore, the modelling and theoretical analysis of the mechanical behavi...
Autori: Bianca Butuc, Gheorghe Moldovean, Radu Velicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25757

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:The paper presents a method to improve the efficiency of a photovoltaic (PV) string by employing a mono-axis trackingmechanism. The tracking system was optimized so that it has minimum energy consumption during tracking. The PV stringsimultaneously changes the daily position using a linear actuator which transmits the motion to all modules by a rack-pinion gearmechanism. The system is designed in virtual prototyping concept with the following software solutions: for the solid modeling -...
Autori: Cătălin Alexandru, Nicoleta-Irina Tatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25766

Abstract:The present study proposes a comparative analysis on the clean electric energy response given by two types of PV (photovoltaic)tracking systems implemented on the same location: the azimuth and the pseudo-equatorial. The analysis is done based on analgorithm applied on the two-axes and one-axis systems. The tracking is done according to various laws, obtained by combiningdaily, seasonal and annual tracking programs. The algorithm and the comparative analysis are exemplified, by numerica...
Autori: Dorin Diaconescu, Maria Monica Vatasescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25770

Abstract:This study aimed to assess the coagulation performance using simple aluminum sulfate (Alum) and pre-hydrolyzed polyaluminumchloride (PACl) coagulation agents by conventional global parameters, i.e., turbidity and organic matter expressed by totalorganic carbon (TOC) and chemical oxygen demand (COD), and non-conventional spectrophotometric parameters.Non-conventional spectrophotometric parameters, expressed as absorbance recorded at different wavelengths, i.e., A254, A280,A365, allowed d...
Autori: Florica Manea, Georgeta Burtică, Ilie Pisoi, Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25777

Abstract:In this paper, photo-catalytic process for treatment of phenolic wastewater by TiO2 nano powder immobilized on concrete surfacein a recirculation hydraulic flow was investigated. The process affected by different operational conditions that the optimum onescould be obtained from variables interchange. Taguchi method as a proper method for design of experiments and optimizationwas used to find optimum conditions. Selected five parameters at four levels were consists of initial phenol con...
Autori: Bita Ayati, Hossein Ganjidoust, Mohammad Delnavaz, Sohrab Sanjabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25778

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:Alkaline protease from Conidiobolus coronatus which is optimally active at pH 10 and 40°C finds application in leather and detergent industries as well as for recovery of silver from waste photographic films. The protease was immobilized in Ca-alginate, polyacrylamide gel and alkali treated waste fungal biomass (ATWFB). ATWFB was found to be most suitable among the matrices tested. Glutaraldehyde marginally increased the binding to ATWFB. Binding of protease to ATWFB seems to be through...
Autori: Ryali Seeta Laxman, Shiv Shankar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25807

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

AbstractThis paper describes an integrated system of wireless temporary pacemakers for remote monitoring of patients suffering fromcardiac arrhythmias, especially atrial fibrillation. The system is built around a low power cardiac pacemaker with wireless datatransmission capability, used for patient monitoring into a limited area. The proposed system is designed to be used in emergencysituations, in healthcare institutes, helping to keep the patient’s heartbeat stable. Each wireless pacemaker at...
Autori: Cristian Rotariu, Hariton Costin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26004

AbstractA case-control study was conducted in two Romanian counties (Alba and Cluj) in order to investigate lung cancer risk due toresidential radon exposure. Two hundred and forty-one subjects were included, of which 104 cases and 137 controls. Residentialradon concentrations were monitored using CR-39 track detectors, exposed over a period of at least 6 months. The odds ratioswere estimated by using multivariable logistic regression adjusted for age, sex, smoking status, education and family h...
Autori: Alexandra Cucoş Dinu, Constantin Cosma, Dan Rădulescu, Doina Todea, Dorin Iancu, Ionel Papuc, Loredana Roşca, Mircea Rişteiu, Tiberius Dicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26011

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

• STUDIES ON HEAT RECOVERY FROM CELLULOSIC TEXTILES FINISHING WASTEWATER    • ASSESSMENT OF SYNERGIC REGULATORY ACTIONS OF SPRUCE BARK EXTRACT AND DEUTERIUM DEPLETED WATER ON MAIZE (Zea mays L.) CROPS    • LUNG CANCER RISK INDUCED BY RESIDENTIAL RADON IN CLUJ AND ALBA COUNTIES, ROMANIA    • A CLEAR SKY IRRADIATION ASSESSMENT USING THE ESRA MODEL AND SRTM DATABASE    • ENVIRONMENTAL FACTORS ASSOCIATED WITH DYSPHONIA IN PROFESSIONAL VOICE USERS    ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26014

AbstractIn the last years many papers have reported about the occurrence of the pharmaceuticals in the surface waters and theirundesirable effects upon the aquatic life. Most of pharmaceuticals pass through the wastewater treatment plants unchangedbecause they are biorefractory compounds and as a result they enter the water bodies. Therefore, it is necessary to improve thebiodegradability of pharmaceuticals effluents (PhEs) before their discharge in the sewerage systems. The aim of this paper wa...
Autori: Carmen Lazău, Florica Manea, Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26021

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractIn this work, cyclic voltammetry (CV) and differential-pulsed voltammetry (DPV) were used to detect pentachlorophenol (PCP)at two types of multi-walled carbon nanotubes (CNT)-based composite electrode, i.e., TiO2-modified-CNT-Epoxy (TiO2-CNTEpoxy)and CNT-Epoxy in 0.1 M sodium sulphate solution supporting electrolyte. The electrochemical behaviour of theelectrodes was investigated in the absence and presence of UV irradiation. A single oxidation peak at a potential value of about+1 V vers...
Autori: , Ágnes Jakab, Aniela Pop, Cornelia Bandas, Florica Manea, Joop Schoonman, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26033

AbstractWater quality is an inportant concern for the ecosystem state from a particular region. Since the continuous urban and economicdevelopment induces a negative impact on entire hydrological cycle, this study investigates the water quality of a Romanian lake,located in the Surduc area - Timis County. This perimeter has undergone significant economic development in the past twodecades due to increased tourism potential and the number of holiday residences.We proposed hybrid materias for the ...
Autori: Adina-Elena Segneanu, Cornelia Bandas, Florentina Cziple, Ioan Grozescu, Paula Sfîrloagă, Titus Slavici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26040

In 2012, the Faculty of Hydrotechnics,Geodesy and Environmental Engineering of The"Gheorghe Asachi" Technical University of Iasi,Romania celebrated 50 years of education in the fieldof hydraulic engineering at the Polytechnic Instituteof Iasi.In 1948, in the same time with the EducationReform in Romania, in Galati, the Faculty ofHidrology was founded. At the same time, studentswho were attending the Rural EngineeringSpecialization in Bucharest were also transferred tothe new established Faculty....
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26048

AbstractThe geodetic, photogrammetric and topographic works necessary for the introduction of cadastre were performed in the city ofIasi in a series of various coordinate systems depending of the cartographic projections used in different periods of time. In a firstphase (1951-1973) the creation and the organization of topographical plans relied on the coordinate system of the LocalStereographic Projection - Iasi with the central point at Golia and the Gauss - Krüger Conformal Transverse Cylindr...
Autori: Adrian Popia, Ersilia Oniga, Valeriu Moca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26060

AbstractIn recent years non-metric digital cameras have known a great development, being used in wide applications, such as: real timemonitoring and preservation of cultural heritage, the shoreline dynamics study, the wave movement for costal protection, soilerosion, etc. Clasic photogrammetry with the use of metric cameras are still of great use in areas such as architecture andenvironmental imaging. An old problem occurs when we want to extract metric information from our environment using clo...
Autori: Ersilia Oniga, Maximilian Diac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26061

AbstractThe removal of residual oil from palm oil mill effluent (POME) using boiler fly ash was studied in this paper, with focus on theadsorption isotherms and kinetic studies by measuring the residual oil concentration using UV-spectrophotometer. The percentresidual oil adsorbed decreased from 80% to 5% as contact time was increased from 10 mins to 120 mins but increased from2.74% to 72.98% as initial concentration of residual oil increased from 0.04812 mg/L to 0.2406 mg/L. Pseudo-second order...
Autori: Jude C. Igwe, Stella N. Anioke, Uche Arukwe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26078

AbstractCombined electrocoagulation (EC) and homogeneous phase TiO2 photo-assisted system were applied to methyl orange (MO)wastewater treatment. Optimum including current density, initial concentration of MO, TiO2 concentration, pH, solutionconductivity and electrode distance were investigated. 98% decolorization (initial concentration = 500 mg/L) was achieved in 30min with a current density of 125 A/m2, electrode distance of 2.5 cm, electrolyte KCl concentration of 0.5 g/L, initial pH of 6.86,...
Autori: Yi Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26090

Abstract This paper presents some optical and microphysical properties of aerosols measured over the Cluj-Napoca city, at the Faculty of Environmental Science and Engineering, Babeş-Bolyai University. This site is part of the Romanian Atmospheric 3D Research Observatory (RADO) and the Aerosol Robotic Network (NASA-AERONET) and is equipped with the only sun and sky tracking radiometer (Cimel CE 318A sun-photometer) in Transylvania. By analyzing Direct Sun measurements like Aero...
Autori: Nicolae Ajtai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26105

Abstract Being involved in the synthesis of precursors for amphetamine and amphetamine-like drugs, pyridine (Py) may be also regarded as a by-product found when these drugs are obtained via the Leuckart method. Also, pyridine is well known as a biomarker of microorganisms, when those are subjected to pyrolysis before analysis by various instrumental techniques. Consequently, since Py is not commonly found in the air, its presence as a contaminant at trace levels in a room could ind...
Autori: George-Bogdan Ghira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26109

Abstract This research has been performed during summer time at Iasi Atmosphere Optics, Spectroscopy and Lasers Laboratory site (LOA-SL), aerosol monitoring station (47.19N, 27.55E). In order to properly identify and characterize the aerosol types, Aerosol Robotic Network (AERONET) data and sun-photometer measurements were analysed using parameters such as: optical thickness, spectral dependence of Ĺngström exponent (α), spectral dependence of Single Scattering Albedo and the ...
Autori: Florin Unga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26116

Abstract Our researches have focused primarily on variations of different biophysical and biochemical effects on vegetal and animal material at macro, micro, and ultra-micro scale resulted from changes in environmental condition. Growth and spectral parameters of rapeseed seedlings from seeds exposed to UVA-VIS radiation with a high pressure lamp which emits incoherent continuously radiation for different time periods were examined 14 days after germination. These studied parameter...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26138

AbstractAs a new type of photoelectrocatalytic materials, the TiO2 nanotube arrays have drawn a lot of attention for efficientlyphotoelectrocatalytic organic pollutants degradation due to their highly photoelectrocatalytic properties. Yet, the performance ofphotoelectrocatalytic organics degradation using TiO2 nanotube arrays electrode is influenced by Cl-, a kind of typical reducingmaterial. This paper focuses on the effect of Cl- on the different photoelectrocatalytic performance of TiO2 nanot...
Autori: Jialing Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26177

AbstractSupply of heat energy is of the high importance in the northern countries of the Europe. EU energy policy and high prices of theheat energy resources takes a challenge to find any alternative resources for generation of heat energy. Therefore in this paper the integration of renewable energy source - solar energy into the existent heat energy supply system is analyzed as the alternative or additional source of heat energy. The case study of the Girionys boiler-house (at Kaunas district, ...
Autori: Jolanta Dvarionienė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26201

AbstractPresent study deals with a technology that reduces the cadmium(Cd) availability to the leafy vegetable Amaranthus caudatusfrom Cd contaminated soil (6 μg Cd g-1soil), amended with farmyard manure FYM, FYM+NPK and agricultural wastes (ricehusk; RH and saw dust; SD) at different doses (0.5 %, 2 %, 5 % and 10 %). Among all the doses 5 % was found to the best foreach amendment showing maximum reduction in phytoavailability of Cd hence better vegetable yield. At this dose the reductionin...
Autori: Anita Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26228

AbstractIn this study, changes induced in milk processed at ultra high temperature (UHT) were investigated following exposure to UVand white-light, by employing fluorescence spectroscopy. Two important indicators, namely Riboflavin (Rb) and vitamin A,were monitored to evaluate the light-induced damage in milk. It was noticed that the photo-degradation of Rb is due to thephotochemical decomposition and photosensitization. Moreover, it was found that the wavelength of the exposure light has agreat...
Autori: Maria Iliut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26241

AbstractThe aim of this study is to analyze the surface-ozone concentration mass variations in Bucharest for the 2005-2007 period. Data files from eight urban sites in Bucharest area were processed to extract the surface-ozone features. Generally, the results have shown that the highest values of surface- ozone concentrations are in the summer and in the afternoon, as in the literature. The smallest values are in December and January in all the three years. Monthly mean concentrations have shown...
Autori: Constantin Rada, Cristian Necula, Laurentiu Zagar, Raluca Barladeanu, Sabina Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26275

AbstractThis investigation compared the performance of Fenton and photo-Fenton oxidation processes in the treatment of sulfidic spentcaustic wastewater. Response surface methodology, particularly central composite design was used to investigate the effect ofFe/H2O2 and H2O2/COD in assessing treatment process efficiency. Empirical models were developed to describe the relationshipbetween the factors and responses. The models were validated through analysis of variance and were further used in pro...
Autori: Azmi Aris, Mohd Ariffin Abu Hassan, Sharifah Hanis Yasmin Sayid Abdullah, Siti Fadilah Md Noor, Zainura Zainon Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26307

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractDue to its toxicity, persistence in the environment and specific properties, 1,2-dichlorobenzene (DCB) has been listed as apriority pollutant by the European Agency. In this study, the oxidation with ozone alone as well as in combination withultraviolet irradiation was applied for the degradation of DCB. This article presents the abatements obtained, after the varioustreatments proposed, in the levels of chemical pollution as monitored by chromatographic techniques (GC/ECD, GC/MS andHPLC...
Autori: Bertrand Sancey, Corina Bradu, Grégorio Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26328

AbstractFeed-In-Tariff (FIT) mechanism is an important measure for government to incentive photovoltaic (PV) industry development. Inorder to secure the appropriate implementation of the Feed-In-Tariff (FIT) mechanism, this paper explores in the first place anoptimal bidding contract price by establishing a bidding model between government and photovoltaic power generationcompanies. On this basis, the paper adopts the Net Present Value (NPV) method and studies the impacts of the fluctuations ofd...
Autori: Hong Li, Juanrui Lou, Tingting Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26378

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractThe purpose of this article is to elaborate a mathematical model for the prediction of average monthly environmental/outsidetemperature (T) levels in the region of Ruse, Bulgaria. Based on the method of harmonic analysis, amplitudes and phases of themain harmonic oscillations were defined. The results show the dominance of the first three harmonics for the period of theresearch. Visualization of experimental and theoretical values of the model shows a high degree of consistency between t...
Autori: Stoyan Yanev
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26446

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractThe paper presents a hybrid method for the advanced removal of low biodegradable organic compounds from water, bycombining the separation selectivity of the membrane with the oxidation efficiency of the photocatalytic process. The aim of thisstudy is to evaluate the performance of the hybrid method to remove toxic compounds from wastewater. The advanced oxidationprocess, based on a photocatalytic reactor with continuous recirculation, ultraviolet (UV) radiations and a membrane, was usedf...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26490

AbstractIn this study, TiO2-zeolite modified carbon nanotubes-epoxy (TiO2-Z-CNT-Epoxy) and TiO2-zeolite modified carbon nanofibersepoxy(TiO2-Z-CNF-Epoxy) composite electrodes were applied for pentachlorophenol (PCP) degradation and determination inaqueous solution. The morpho-structural characterization of the composite electrodes was studied by scanning electronmicroscopy. The electrochemical behaviour of the electrodes was investigated under UV irradiation presence/absence, usingcyclic voltamm...
Autori: Ágnes Jakab
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26491

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractAtomic absorption spectrophotometry (AAS) technique was applied in order to identify the occurrence of certain heavy metals insamples of pork products, such as bacon, ham, sausage and salami, taken from four commercial centers in Romania. Lead levelsin samples varied from 0.58 to 0.96 mg/kg, Cadmium values from 0.11 to 0.21 mg/ kg, Copper from 0.73 to 1.32 mg/kg, whileZinc levels were detected between 32.19 and 42.12 mg/kg. Lead, Copper and Zinc found in samples were lower than themaximu...
Autori: Gabriel Vasile Hoha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26522

AbstractA zero-energy research program was recently established. Under this research program, we collaborated with anotherdepartment. The goal of the collaboration was to develop a gravitational, zero-energy ventilation system sufficiently efficient touse in a passive house or in a zero-energy building. We developed a method to measure all of the necessary variables andparameters required to calculate the effectiveness of the theoretical description of the approach....
Autori: Attila Vitéz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26552

AbstractThe aim of the present work is to study the performance of a constructed wetland for domestic wastewater depuration alsoworking as a microbial fuel cell (MFC) under two different subsurface flow modes in the upper cathodic compartment (horizontalflow, HF, or vertical flow, VF), and to compare the efficiency under both situations. A pilot-scale subsurface constructed wetlandtreating domestic wastewater was used, and the installation also included the electrodes and devices needed to work ...
Autori: José Villaseńor Camacho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26574

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract Heavy metals, such as Cr (chromium), have received attention during recent years due to their disposal in soil and water. Brave peanut (Pterogyne nitens Tul.), a tropical tree, was cultivated in 500 mol L-1 Cr+6 to observe how this species responds to this stress, with a view to its possible application in the restoration of degraded areas. In the present study, we report the use of a new method, photoacoustic spectroscopy, to evaluate the emission of CO2 and ethylene and th...
Autori: Luisa Brito Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26602

Abstract The objective of this study is to develop a mathematical model which would confidently predict the rate of substrate degradation of an oil-water emulsion in a laboratory-scale completely-mixed continuous flow reactor using the photo-Fenton treatment process. Two models are developed from first principles and the predicted substrate removal rates for both models are compared with experimental data. The principal conclusions of the study are that both models produce good correlations ...
Autori: Maha A. Tony
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26613

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract Hydrogel membranes obtained by neat polyvinyl alcohol (PVA) or PVA with various bio insertions like: Scleroglucan (Scl), Zein (Zein) or Cellulose (Cel), were subjected to diffusion and sorption/desorption experiments using different type of dyes such as: Crystal Violet (CV), Methylene Blue (MB), Congo Red (CR). If the sorption, desorption or diffusion of a dye in/from/through a hydrogel is usually monitored by the dye solution analysis, in this case the transport phenomena are follo...
Autori: Adina Papancea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26649

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract The class of xanthene dyes has a complex chemical structure, which showed to be toxic for mixed culture of microorganisms (i.e. anaerobic granular sludge). Because of the unwanted effects of Erythrosin B (Ery B) on environmental components and some food confirmed previously, the dye was chosen in this study to evaluate its ecotoxicity. Also, the Ery B photocatalytic degradation products were assessed in terms of their ecotoxicity. Three-days of seed germination and root growth test...
Autori: Laura Carmen Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26660

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Nowadays, an efficient wastewater management involves the use of advanced treatment technologies able to decompose hardly biodegradable compounds with reasonable costs at the lowest possible environmental impact. In our work we used one of the most efficient advanced wastewater treatment, the Fenton reaction and its photo-assisted version. The hydrogen peroxide was the oxidizer; despite its relatively high cost, its high activity in oxidizing of a large variety of organic persistent...
Autori: Vasilica-Ancuta Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26677

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract This paper presents a medical diagnosis method, based on the interaction of the infrared laser beam and the human body, in a hospital environment, for inflammatory diseases, avoiding infected wastes. The main advantage of the laser bio-photometry is a rapid localization of the inflammation source, deep under the skin up to 5 cm, in emergency cases, when there is not enough time for classical medical procedures. Other advantages consist in the pollution absence for environment and pa...
Autori: Ala Bondarciuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26696

Abstract Individual exposure to particulate matter (PM) fractions is mainly determined by indoor source characteristics and personal activity patterns. This paper discusses experimental results obtained through the analysis of individual exposure of women to PM10 and PM2.5. To this purpose, 15 volunteers of different ages and lifestyles living/working in Ceccano (Italy) were selected and their exposures to PM10 and PM2.5 were measured through a handheld photometer. They also filled out a tim...
Autori: Giorgio Buonanno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26703

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract The objective of this study was to identify differences between three of the most conventional UV-based advanced oxidation processes, namely photolysis, UV/TiO2, and UV/ZnO for the decolorization and mineralization of reactive red 198 (RR198) model dye in saline media. The study investigated influences of solution pH levels, salt concentration, reaction time and dye concentration on the degradation of RR198. The most effective dye removal and mineralization was observed at pH levels...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26724

`Abstract End of life tires require sound accounting of environmental performances to design sustainable procedures for material recovery. Their use in rubber modified asphalt provides could lead to the improvement of technical and environmental performances of asphalt roads, but the effectiveness of simplified procedures is to be proved. During LIFE+ project ROADTIRE, a rubber modified asphalt road prototype, with the upper surface layer containing 10% crumb rubber in the bituminous binder,...
Autori: Irene Bartolozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26741

Abstract Extensive use of plastics leads to the increase of non biodegradable wastes that have to be recycled due to both dramatically decrease of natural resources to producing them and to their increasing need as well as due to environmental issues. Most of goods made by materials based on wastes have to be commonly used by people. Antibacterial character of those is necessary to avoid epidemics. This paper deals with determination of antimicrobial character of materials based on polymeric...
Autori: Florica Silvia Cristina Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26751

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Abstract Deformation, damage and permanent loss of heritage assets due to various physical and environmental factors has always been a major problem. As the availability of funds for conservation and restoration is limited, the digital documentation of heritage objects and monitoring of environment-induced deformations are increasingly important for cultural heritage preservation. Our study elucidates developments in the digital image capturing and processing for recording architectural heri...
Autori: Jūratė Sužiedelytė-Visockienė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26759

Abstract The aim of this study is to assess indoor air quality in an educational institute located in a suburban area of the Po plain (Italy). Samplings are carried out in preschool and elementary school classrooms, and also in the garden of the institute, to have information on outdoor levels. The monitoring is performed to determine the most important indoor pollutants (i.e. volatile organic compounds (VOCs), carbonyls and NO2), by using diffusive passive samplers. Sampling in the classroo...
Autori: Ivano Vassura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26797

Abstract Superintensive growth of fish in a controlled environment involves taking a series of measures to ensure the oxygen necessary to provide optimal living conditions for stocks. Considering the fact that oxygen has a relatively low solubility in water, the photosynthesis in basins does not occur and the rate of incoming water may be low, it is imperative to supplement the water with oxygen. The paper presents theoretical researches on mathematical modelling and numerical simulation of ...
Autori: Vasilica Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26871

Abstract Solar photovoltaic (PV) system performance parametrically depends on climatic, operating and design parameters, and in view of thermodynamics it can be evaluated in terms of energy and exergy efficiencies. In this paper, thermodynamics efficiencies of two different solar PV modules technology i.e. wafer based crystalline silicon and thin-film are evaluated. As a subject, polycrystalline silicon (ASE-100) and amorphous silicon (DS-40), as components of 10 kWp grid-connected PV array ...
Autori: Dani Rusirawan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26899

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Abstract This paper is an environmental approach of land cover in rural areas, based on a case study of Eastern Romania: Studineţ catchment (9669 hectares). The information necessary to shape the profile of the research area is obtained through diachronic and comparative analysis of different land cover categories. For this purpose, three distinct aspects were analyzed: weight and fragmentation of arable land; evolution and current weight of forests; expansion of xerotermophilous shrubs...
Autori: Iulian Cătălin Stângă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26924

Photodegradation caused by sun irradiation may be of major significance in the natural elimination process of pharmaceuticals and personal care products (PPCPs). The fate of metronidazole (MET) in surface water under solar irradiation was investigated. Several parameters affecting the photochemical degradation rate of MET were investigated, including the initial pharmaceutical concentration, continuous input and the presence of other pharmaceuticals like tinidazole (TNZ) with similar structur...
Autori: Bo Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26928

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

This study investigates the effects of earthworms and a variety of substrates on photosynthetic characteristics and rate of uptake of nitrogen (N) and phosphorus (P) by Iris pseudacorus L. (Iridaceae) in a constructed wetland system under greenhouse conditions. The study seeks to identify those factors that maximize the efficient removal of N and P. Four substrates were tested: pure sand, sand and soil, sand and organic matter, and a mixture of sand, soil and organic matter. The photosyntheti...
Autori: Defu Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26936

Air pollution has a significant impact on human health and natural ecosystems. The principal gaseous pollutants compounds result from different types of combustion processes. In this category there are included carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), dust and hydrocarbons. Nitrogen oxides are a group of highly reactive gases, which contain nitrogen and oxygen in varying amounts. Most of the nitrogen oxides are colorless and odorless gas. This paper highlights the c...
Autori: Doina Capşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26988

The renewable sources of energy represent a viable alternative for satisfying the energetic needs of humanity in case the fossil fuels reserves are exhausted, which is estimated to occur in maximum 25 years if the current rate of exploitation is maintained. Nowadays, there are several concerns about the valorization of the energetic potential of these resources (wind, water flows, solar, geothermal energy etc.), but also a series of extremely beneficial practical uses (i.e. wind parks, photov...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26989

Semi-conductor oxide enhanced photocatalysis is a sustainable technology suitable for disinfection of water contaminated with pathogens. Disinfection of Escherichia coli was investigated using an immobilized thin film tungsten trioxide (WO3) photocatalyst in a visible light-driven photoelectrocatalytic batch cell (PECB). Disinfection efficiency was monitored under dark electrocatalytic, photolytic and photoelectrocatalytic conditions and assessed using a culture-based approach. Optimal disin...
Autori: Efetobor Scott-Emuakpor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27014

This paper presents the results of measurements related to the activity concentrations of 226Ra, 232Th and 40K in autoclaved aerated concrete (AAC) used as building materials for various constructions in Romania. Radiation index (I) and the hazard index (HI) were estimated to assess the risk arising from the usage of AAC materials. Our study considered various AAC samples produced by different companies, in 2015. The activity concentrations of 226Ra, 232Th and 40K were measured using by a gam...
Autori: Dorina Nicolina Isopescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27018

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

In this paper, the steps used in the process of building 3D model creation, using images acquired with the UMK 10/1318 metric terrestrial photogrammetric camera and digital images acquired with the Canon EOS Rebel XSi/450D digital non-metric camera, are presented in detail. For the calibration process of both cameras, the Heikkila and Silven algorithm and a 3D calibration object were used. In order to save time, both on the field and back to the office, instead of taking and processing UMK im...
Autori: Ersilia Oniga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27056

A test for quantifying the contribution of colour and scale to the visual impact of buildings in the rural setting was developed and validated by means of a public opinion survey. The method was based on some psychological aspects of visual perception and on a simple image treatment performed by a well known and easily available computer program. Results were provided as numerical values, enabling the quantification of the impact for the two individual elements studied and for their potential in...
Autori: María Jesús Montero-Parejo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27080

The present study investigates the effect of addition of calcium hypochlorite in the titanium dioxide (TiO2) mediated degradation of bio-recalcitrant wastewater from pharmaceutical industry. The degradation studies were carried out in photoreactor irradiated with ultraviolet (UV) light at 365 nm under slurry mode. The reduction in chemical oxygen demand (COD) was estimated as an index of degradation. The influence of process parameters viz., catalyst dose, pH, oxidant concentration and source...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27097

This study was carried out to monitor the presence of organophosphorus in drainage water (Kafr El-Sheikh (Kotshinar Drainage), Fowa (Fowa Drainge No.11), Metobess (El-Hokss Drainage), Beila (Karakat Drainage), Balteem (Hafeer Shihabeldeen Drainage), Nashart Drainage and El-Hamoul (El-Hamoul Drainage) in Kafr-El-Sheikh Governorate, Egypt. Furthermore, the efficacy of chemical (advanced oxidation processes) and bioremediation (effective microorganisms) for chlorpyrifos removing in drainage wat...
Autori: Aly Derbalah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27104

In order to improve the soil fertility, several eco-friendly alternatives to traditional cultivation practices have been proposed. The use of biofertilizers, such as rhizobacteria with different plant growth promoting properties is an environmentally-friendly option to achieve sustainability in agriculture. In this context, two bacterial strains (Bacillus pumilus R3 and Pseudomonas lini R7) isolated from the rhizosphere of runner bean plants were assessed for their plant growth promoting abil...
Autori: Gabriela Mihalache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27108

The removal of quinoline from synthetic wastewater by heterogeneous photo-Fenton in a novel internal circulating fluidized-bed reactor was investigated systematically. The flow field in the reactor was simulated by FLUENT software conjoined with tracer particles experiment, and the influence of reaction parameters such as initial quinoline concentration, catalysts dosage and H2O2 dosage were evaluated. Results indicated that the designed reactor was suitable for the heterogeneous photo-Fenton...
Autori: Ran Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27142

In this paper we applied multi-criteria methods of decision in order to establish the best encapsulation material to be used in producing photovoltaic modules. The encapsulation materials play an important role in establishing the PV module performance, especially if referring to their ability to increase their life time. For our study, we have considered the most widely used encapsulation materials available on the market, such as Ethylene-Vinyl Acetate (EVA), Polyvinyl Butyral (PVB), Thermo...
Autori: Gabriela Demian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27169

In this paper, we propose to present real solutions for close self-monitoring of older adults, given the permanent assistance and rapid intervention needed in emergency medical situations. The recent medical devices integrate existing or in development technologies that are easy to use, affordable, accessible and sustainable solutions that address a range of needs because the ultimate goal is the ensuring of a “living actively and independently at home” environment for older adults. ...
Autori: Iuliana Chiuchisan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27200

The application of advanced oxidation processes (AOPs) emerged as an interesting topic during the last decade. Many studies have been devoted to the complexity of phenomena imposed by AOPs, and a lot of effort was made to justify the application of AOPs. However, the reliability of AOPs has not been an issue of any extensive work. In this work, failure analysis and comparative reliability study were performed for the chosen AOP system, i.e. a laboratory scale photo- and sonoreactor, during the p...
Autori: Ivana Grčić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27220

Life Cycle Assessment (LCA) is a methodology that can be used to evaluate the environmental performance of municipal solid waste management systems (MSWMS). Despite of Waste Directive provisions, this methodology is insufficiently applied as a decision-support method able to identify the best option for the waste management in Romania. In this paper we applied LCA methodology to study of the municipal waste management system of Cluj County, supported by GaBi software. The aim of this study is to...
Autori: Gabriela-Emilia Popiţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27225

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

In this paper photo-oxidative degradation of degradable mulching films was studied. Low-density polyethylene (LDPE) films were denominated as 3# and 4# (containing 3.43% and 0.44% degradable masterbatch, respectively), They were exposed to different irradiation condition of i: ultra violet A irradiation (UVA), ii: ultra violet A and B irradiation (UVA-B), both at 58±2°C. The physical chemical property of the plastic film is influenced by factors in many aspects, especially the composi...
Autori: Ya-xi Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27232

A Microwave-Ultraviolet reactor was developed and the effect of microwaves on photodegradation of various phenols was studied using the reactor. The degradation study was carried out by six methods - microwave irradiation, photodegradation with UV light, microwave and ultraviolet radiations (microwave irradiation in presence of TiO2, photodegradation with UV light in the presence of TiO2 and also simultaneous MW and UV irradiations in the presence of TiO2). The relative efficiencies of the degr...
Autori: Singaram Karthikeyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27248

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

The remarkable photocatalytic properties of titanium dioxide and the high adsorption capacity of the mesoporous materials were combined to obtain active photocatalysts for the decomposition of Rhodamine 6G dye. The mesoporous TiO2 was obtained by the controlled hydrolysis-condensation of titanium isopropoxide, using hexadecyl-trimethyl-ammonium bromide as template, followed by calcination to remove the organic matter. Subsequently, this sample was doped with sodium wolframate and platinum. T...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27325

The objective of this study was to develop a naturally dyeing process of 70% wool /30% Angora mohair blended yarns by using bio-mordants as an environmentally friendly alternative for the conventional metallic salts. Bio-mordanting operation was achieved by using of condensed tannin extract from quebracho bark trees. Conventional mordanting has been performed using the conventional mordants like copper sulphate and tin chloride. Another specific objective of this study was to investigate the pos...
Autori: Ioana Stanculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27337

The aim of this work was to study the effectiveness of photocatalysis in the removal of contaminants from secondary treated municipal wastewater, on a batch scale. The samples were collected from the outlet of the secondary clarifier in the municipal wastewater plant located at Al Khoudh, Muscat, Sultanate of Oman. The influences of TiO2 catalyst loading and solar radiation exposure time were investigated for the removal of COD and total Coliforms. 60% removal of COD was achieved with a catalyst...
Autori: Anna Jesil Cheriyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27376

This work presents an experimental analysis of the influence of a monocrystalline photovoltaic (PV) panels’ temperature on its main operating parameters. Victron Energy, SPM 30-12 PV panel is tested, using a double climatic chamber. The PV panel is placed as a barrier between the two rooms of the climatic chamber. The study is focused on the establishing the effect of raising temperature of PV panel over electrical parameters: voltage, current and power produced and also over the effici...
Autori: Sebastian Valeriu Hudisteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27397

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

This paper describes shortly some outcomes of a project aiming to apply a scientific research directly to industry, passing through a system that wants to promote an economic "Pact" in relation to the new construction and renovation projects of energy, according to its fundamental guidelines of the moment: renewable energy and energy efficiency. The key point is to produce energy from recycled materials that become functional to dwellings (from the garden shed to furnishings, etc.),...
Autori: Marco Santarelli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27421

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

Decolorization of C.I. Acid Orange 7 (AO7) via TiO2-assisted photocatalysis under UV illumination in the presence of H2O2 has been investigated. The effect of pH on decolorization efficiency of AO7 was investigated in TiO2/UV/H2O2 process. The performance of TiO2/UV/H2O2 system was also evaluated by using synthetic dye-bath effluent of AO7. Solar driven TiO2 photocatalysis was found significantly efficient for the decolorization and degradation of AO7. The rates of decolorization and degrada...
Autori: Ozlem Esen Kartal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27433

Galvanocoagulation (GC) utilizing metallic iron chips and granular coke was studied as a potential technique for decolorization of dye-containing aqueous solutions. GC and chemical coagulation by inorganic metallic coagulants such as iron sulfates (Fe2+, Fe3+) were examined for the removal of individual dyes, used in the fur industry, from model aqueous solutions. The role of metal cations when progressively electrogenerated in situ was compared to when they are added simultaneously. The superio...
Autori: Marina R. Sizykh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27526

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

The hydrodynamic behavior of bubble column bioreactors (BCB) is strongly dependent on the bubbly flow regime. Therefore, the influence of superficial gas velocity (Ug) and Sauter mean diameter (d32) on gas hold up (εg) was evaluated for the cultivation of a petroleum-degrading consortium. Hydrodynamic parameters were determined by photographic techniques. Also, the biomass cultivation was quantified by suspended solids formation (SS). Our findings indicated that the d32 increased at high...
Autori: Olivia Tzintzun-Camacho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27597

Landscape preference is a result of multi-sensory input. However, the effect of interactions between multi-sensors on it is rarely involved in previous works, especially in olfactory effect on landscape preference. This research project selected three odors (flower of Osmanthus fragrans (FO), flower of Lilium longiflorum (FL), and sediment on riverbed (SR)) and ten photographs to explore the effect of odor-photograph combinations on landscape preference. The evaluation by undergraduate students ...
Autori: Jingwei Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27624

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

The mineralization of azo dyes could be realized through solar photocatalytic degradation that is a green method where non-harmful end products are produced. The aim of this study was to investigate the mineralization of Orange G (OG) and New Coccine (NC) using ZnO as catalyst. The degradation of the azo dyes was conducted at different experimental conditions, and parameters such as effect of sunlight to the degradation rate, initial azo dye concentration, amounts of catalyst dosage, pH and effe...
Autori: Wan Fadhilah Khalik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27643

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

The aim of this study is the treatment of liquid effluents from a petroleum industry (NAFTAL /Algeria) by an electrochemical treatment process (electrocoagulation). The electrocoagulation has proved to be useful for the treatment of wastewater, but in order to enhance its ecological characteristic we found it would be essential to carry out our experiments with ecological energy derived from a photovoltaic solar module, which would contribute to sustainability objectives. The electrocoagulation ...
Autori: Kahina Ighilahriz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27679

Many ecotourism destinations unfortunately tend to become unsustainable and even self-destructive due to inappropriate environmental assessments. On the other hand, because of the increasing people’s willingness to tourism and relaxation, it is necessary to select and introduce new regions for tourism. To do this, the application of relevant criteria can be a profitable method. The purpose of this study is to identify nature-based tourism activities and also site selection for them in Sisa...
Autori: Sedigheh Babazadeh Khameneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27755

This study aims to monitor Volatile Organic Compounds (VOCs) and odour annoyance perceived by the exposed population living nearby a petroleum plant through an integrated high temporal resolution methodological approach. The area under investigation is considered one of the most critical industrial areas of the South of Italy (Basilicata) because of presence of the largest Italian petroleum plant, called the "Center Olio Val d'Agri" (COVA). In fact, VOCs and odours emitted from ext...
Autori: Alessia Di Gilio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27791

Ultrasounds has a wide range of active applications spreading in solid, liquid and gaseous mediums, embedded in new methods and technologies for preventing, reducing and removing of existing pollution. This paper deals with the sonochemistry reactors and their combinations with photocatalysis and electrochemistry. Various parameters such as ultrasound frequency, power, number of ultrasound sources, lab-scale or large-scale equipment used for environmental applications of sonochemical reactors h...
Autori: Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27867

The main topic of this study is the photo-optical and electrochemical behavior of a series of fluorinated copolyimides containing both oxadiazole and perylene moieties in the main chain. The polymers prove a strong photo-optical stability on a large temperature domain and display different types of photoluminescent behavior in solution and in solid state, with emission maxima in the bluish and green–yellow domains. Cyclic voltammetry investigations suggest that the polymers can be easil...
Autori: Radu-Dan Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27883

A wide range and globally active agro-industries such as olive oil processing, winery, tannery, textile and food production discharge a large volume of wastewater containing tannins. Tannins are complex structured chemicals which cause high organic content, requiring high dissolved oxygen in wastewater treatment plants or producing oxygen depletion in the aquatic environment. Tannins are known to be hardly degraded in biological treatment. There has been evidence that the presence of natural ...
Autori: Giusy Lofrano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27885

The utilization of inorganic carbon by the red macroalgae, Gracilaria edulis (G. edulis) was investigated in this study. G. edulis were grown in brackish water aerated with varying concentration of carbon dioxide - 350 ppm (actual atmospheric carbon dioxide, CO2), 700 ppm and 1400 ppm CO2 gas. Higher growth rate was observed in culture medium aerated with 1400 ppm CO2 and the lowest growth rate was observed at actual atmospheric carbon concentration. Besides that, significant pH drift was obs...
Autori: Lavania-Baloo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27900

Sustainable development is a key issue for the modern world economy. A solution for reducing the impact of carbon dioxide emissions on climate change and for compensating depletion of conventional energy resources relies on green economy and renewable energy. Polytechnic University Timisoara has a pioneering role in research and applications of solar energy to industrial and residential systems in Romania. The "Renewable Energies - Solar Energy" master program has been introduced fo...
Autori: Ioan Luminosu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27901

In this study, Mg-doped ZnO nanoparticles with 2% Mg content were synthesized by sol-gel method. The structure and morphology of the nanoparticles were characterized by TEM, BET and UV-Vis absorbance techniques. From TEM image, it was found out that the nanoparticles had uniform size and uniform distribution. BET analysis revealed that in comparison with pure ZnO, Mg 2%/ZnO nanoparticles had a higher specific surface area. Based on UV-Vis absorbance analysis, Mg 2%/ZnO nanoparticles shifted t...
Autori: Nahide Zarei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27909

Electrically charged particles of air pollutants show the degree of atmospheric pollution they being consistent with some chemical indicators of air pollution. This study analyses these indicators of atmospheric pollution (EIAP) present in various zones around the cities of Iasi, Bacau and Piatra Neamt and correlate them with the incidence of some diseases amongst the population. The results show that certain values of electrical indicators of atmospheric pollution point to a higher incidence...
Autori: Liliana Sachelarie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27916

Intervention and rescue activities require knowledge of the real situation in the affected area as accurately as possible. Therefore, the physical exploration of this area is at the same time necessary and risky. The use of drones from a safe distance can protect the intervention team from exposure to unknown hazards. Endowment of the drone with a suite of sensors such as high resolution cameras, thermal imaging, infrared, and gas detection equipment permits vital data to be transmitted to t...
Autori: Alin Irimia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27955

A series of water quality and ecological problems are caused by algal blooms, and natural allelochemicals are considered as the source of algaecides due to their friendly advantages to environment. It has been reported that abundance of secondary metabolites are found in grape plants, and the extracts from the plant exhibit antioxidant, antibacterial and antifungal capacities. In order to reveal the anti-algal activity of grape pruning wastes and promote their usage, we analyzed the composition ...
Autori: Zhaojiang Zuo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27971

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

Our research aims to establish the influence of Osmocote®Pro fertilizer on ornamental characteristics, photosynthetic pigments content, superoxide dismutase and peroxidase activities for Lillium regale species. The tests were organized in four variants, each with three replicates, each replicate consisting of 10 bulbs. The growth of plants in the four experimental variants was achieved without fertilization in case of the control variant (M) and under fertilization conditions with Osmocot...
Autori: Maria Brînză
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28005

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Aspergillus fumigatus has been selected to bioleach the metals ion from brown shale. Process parameters like pH (5.0, 5.5, 5.8, 6.0, and 6.5), substrate concentration (2, 4, 6, 8, and 10%), pulp density (1, 5, 10, 15, and 20%), temperature (30, 35, 40, 45, 50oC) and agitation (100, 150, 200, 250, 300 rpm) were optimized according to L25 Taguchi orthogonal experimental array design that resulted in the twenty five batch bio recovery experiments. After biorecovery experiments, optimum value of ...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28035

The aim of this paper is studying light intensity values which maximize the photosynthesis in microalgal cultures by means of models of the photochemical process and by changing cultures strategies. The photosynthetic performances of Graesiella emersonii under batch, fed-batch, semi-continuous cultivation modes and with only air sparged or CO2 added to air were quantified by means of gas exchange measure and pulse amplitude modulated fluorimetry (PAM); kinetics of the photochemical processes...
Autori: Dora Allegra Carbone
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28037

Substantial quantities of toner cartridges are produced and used in photocopiers and printers every year. Spent toner cartridges are classified as hazardous waste because they contain toner powder with specific chemical composition, making a recovery of waste toner cartridges a very important issue from the aspect of waste management and environmental protection. Spent toner cartridges are mechanically processed to exploit valuable materials such as metals, plastics and magnets and to separate t...
Autori: Ivana Melnjak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28053

Leather processing is one of the highly polluting industries, due to generation of significant quantities of tanned and untanned wastes. Untanned wastes are less contaminated with chemicals and a better source of high value products such as collagen rather than tanned or finished leather wastes. In the present study, collagen dissolution substances (CDS) were prepared from bovine limed split wastes as value added products, by treating leather wastes with sodium hydroxide and fermented dairy b...
Autori: Gökhan Zengin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28095

This manuscript presents the bicriteria optimization of a polygeneration system to be installed in a tertiary sector building, considering economic and environmental objective functions. Electricity, hot water, steam, and cooling demands were considered. The bicriteria problem considered the annual costs and the annual carbon footprint. Updated environmental information was obtained through the application of the Life Cycle Assessment methodology and implemented within a Mixed Integer Linear Pr...
Autori: Bruno Campos Teixeira de Carvalho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28103

Photocatalytic processes are among the most efficient treatment methods of waters polluted with recalcitrant organic substances. Nanotubular TiO2 arrays with photocatalytic properties were obtained in the process of titanium anodic oxidation in the fluoridecontaining electrolyte. Under the proposed conditions of electrolysis, a coherent system of tightly adjoining nanotubes was formed with the internal diameter of 60-80 nm and walls thickness up to 60-65 nm, the tubes height being dependent on p...
Autori: Gheorghe Duca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28137

...
Autori: Florin Andrei Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28143

Salinity of irrigation water is one of the main environmental constraints limiting the geographical distribution of several species. In order to understand and to cope with critical environmental constraint, a pot experiment was undertaken to investigate the potential effect of irrigation with various natural saline waters gathered from arid and semiarid regions; on rooting of stem cuttings, growth and on the physiological responses of Mascarene grass (Zoysia tenuifolia Willd.). The obtained res...
Autori: Sihem Soufi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28169

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Nutrients have been considered the main factor affecting microorganisms responsible for methane gas production during anaerobic digestion processes. In this study, the nutritional composition of some fruit wastes; mango (M), watermelon (W), pawpaw (P), their effects on methane gas production, and resulting energy values were assessed. Substrate samples for anaerobic digestion where prepared into various slurry treatments; M, W, P, WM, PW, MP, MWP and CONTROL. Proximate compositions of the subst...
Autori: Ogemdi Chinwendu Anika
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28233

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

Growth of city population and migration of communities lead to higher accumulation of heavy metals in coastal areas of the Caspian Sea suburbs. In the present study there are represented geographical and ecological locations and environmental monitoring results of the Caspian Sea offshore and coastal area near Akshukyr (Aktau suburbs). The shallow offshore near Aktau city and adjacent areas were monitored in cooperation with the Institute of Ocean Sciences. Sea water analysis carried out specia...
Autori: Nurgul Janaliyeva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28263

The work is devoted to the search and investigation of the properties of the effective environmentally friendly phytoremediation activators. An integrated approach was used to evaluate the effect of the compositions of thiosulfonates with rhamnolipid biosurfactant on remediation plants. The biochemical and biophysical analysis of the rapeseed and ryegrass plants grown in the oil polluted soil - photosynthetic pigments, indicators of oxidative reactions and electrical impedance characteristics we...
Autori: Olena Yaremkevych
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28319

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

This research applied passive air pollution samplers to monitor the concentration of the pollutants nitrogen dioxide (NO2) and ozone (O3) in order to investigate the relationships between pollutant concentrations and meteorological variables. The study was carried out in three strategic sites in the municipality of Erechim, Brazil, which provide intense traffic of small and large vehicles. The pollutant analyses were performed using the method of UV/VIS spectrophotometry. NO2 concentrations vari...
Autori: Eduardo Pavan Korf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28326

Road dust from atmospheric deposition is considered as one of the significant environmental pollutants for containing toxic heavy metals. In this connection, to explore the present scenario of urban contamination and potential health risk of heavy metals present in road dust; this study was carried out in Tangail Municipality Area of Bangladesh. Road dust samples were collected seasonally from five different sampling sites encompassing different traffic homogeneity. Collected samples were proces...
Autori: Mir Talas Mahammad Diganta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28334

Water treatment has been extensively studied; however, only a few studies have considered it in isolated sites that do not have electric supply, which is a major inconvenience for inhabitants of rural areas. In this paper, the aim was to develop and implement a photovoltaic generator (PVG) that powers a pumping system, and water treatment with ozone. First, the PVG panel’s orientation was optimized using response surface modelling to identify the optimum operating orientation angles. Then,...
Autori: Mohammed Nadjib Brahami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28341