â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractThe purpose of this study is to analyze the recycling potential of printing papers, which are obtained by two different filler loading processes: conventional loading by direct addition of calcium carbonate to cellulose fiber suspension and in-situ loading by precipitating calcium carbonate within cell wall and lumen of pulp fibres. In order to evidence the influences of the both filler content and loading method, a reference sample for recycling was obtained without filler, but using th...
Autori: Maria Ciobanu, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25386

Abstract It's well known the degradation of many Romanian (including Dobrogea) soils, both in hill and in plain environments, due to the increasing anthropic pressure on natural resources. Soil erosion and organic matter loss are recognized as the main processes responsible of such degradation and of the rising risk of desertification, to which land use changes and politics for agriculture not suitable for land specificities often contribute. The knowledge of land use impact on soil quality i...
Autori: Marioara Nicolaescu, Naliana Lupascu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25453

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

AbstractBisphenol-A (BPA; 2,2-bis(4-hydroxyphenyl)propane) is a monomer used primarily in the production of polycarbonate andepoxy resins that has been reported to have estrogenic activity. The biodegradability of BPA has been previously investigated inseveral studies designed to simulate surface waters and biological wastewater treatment systems. However, there is littleinformation available about the phytoremediation of groundwater contaminated with BPA. Halophytic species are of specialintere...
Autori: Margarita A. Petoussi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26493

AbstractAnalysis and monitoring of arsenic is still a challenging analytical task. Due to its complex behaviour (different forms of arsenicthat can be present depending on pH and oxidation states of arsenic) as well as demanding analytical procedures and instrumentaltools for control of arsenic concentration in drinking water which is set to 10 μg L–1, there are still some open questions andissues when arsenic is the scientific topic. In this paper the idea was to use a multivariate statist...
Autori: Vladana N. Rajakovic-Ognjanovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26506

Abstract In the present paper we studied the competitive transport of p-nitrophenol (pNP) and 2,4-dinitrophenol (2,4-dNP) from aqueous media using the technique of liquid membranes. This technique is very efficient, economic and selective when compared to other removal techniques of phenolic derivatives. The paper presents the influence of the sodium carbonate concentration from the stripping phase, the influence of the concentration ratio [2,4-dNP]/[pNP] upon the selectivity of the transpor...
Autori: Ioana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26681

Abstract The effect of goethite addition, hydrogen peroxide concentration, initial pH, hydroxyl radical scavenger and initial dye concentration on the decolorization of Orange II by Fenton-like process was investigated. The results showed that the decolorization rate increased with goethite addition and hydrogen peroxide concentration, but decreased with the increase of initial dye concentration. There existed an optimal initial pH to achieve the highest decolorization rate. The presence of ...
Autori: Hui Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26693

Abstract Based on the study on the reformation of Dawsonite-bearing sandstones with CO2 fluids at different temperature (100oC 200oC and 300oC) and different CO2/H2O/sandstone systems, it is suggested that as the temperature increases, the corrosion intensity of dawsonite-bearing sandstones is gradually increased, but the stability of the sandstone is reduced. The SEM study shows that there are radiated aggregate sediments of boehmite in all samples. At 200oC, with the dissolving of dawsonit...
Autori: Xi-Yu Qu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26814

Abstract Popular since ancient times, the mineral waters from Carpathian Chain (Romania) have gained a well-deserved reputation due to their quality and health benefits. This study provides a description of the chemical and isotopic composition (δ2H, δ18O) of mineral waters (CO2 - rich and CO2 - free water) located in six of the most popular areas, in order to improve the overall knowledge about their genesis and recharge mechanisms. The hydro-chemical facies of groundwater vary ...
Autori: Roxana Elena Ionete
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26869

Drainage water and tailings impoundments water geochemistry (pH, EC, alkalinity, trace element concentrations, major ions) were studied at the Anjir Tangeh coal washing plant. The drainage water with neutral to alkaline pH values, high SO42- concentration and low metal content represented typical neutral alkaline mine drainage (NAMD). According to the Stiff and Piper diagrams, the majority of water samples classified into Ca-Mg-HCO3- type except drainage and processing water which were placed...
Autori: Majid Shahhosseini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26997

As part of the 2012 Land Use/Land Cover Area Frame Survey (LUCAS), topsoil samples were collected in Bulgaria and Romania using the same methodology as for other EU Member States in an equivalent survey carried out in 2009. In total, 664 Bulgarian and 1384 Romanian samples were collected which enabled a comparative assessment of topsoil properties under different land covers within, and between, these countries, as well as in a broader European context. The samples were analysed for basic soil p...
Autori: Gergely Tóth
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27205

This study investigates the adsorption of several metals in aqueous solution, by hemp materials (loose fibre and felted fibre). After characterization of the fibre, an extensive study was conducted on the adsorption properties of this material. The experiments were carried out in poly-metallic aqueous solutions containing Al, Co, Cr, Cu, Ni and Zn at a concentration of 1 mg L-1 and 10 mg L-1 each. The pH effect was found to lead to an optimum between pH 4 and 4.5. The kinetics of the adsorption ...
Autori: Justine Bugnet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27272

This study aims to evaluate the effects of Fe2+ present in carbonated natural mineral waters on the decomposition of hydrogen peroxide (H2O2) used as sanitizing agent of the collector water tanks and the oxidation of NH4+ to NO3– and NO2– nitrogen compounds from bottled carbonated natural mineral water by the Fenton process. This evaluation suggests that the distribution of the nitrogen compounds, at certain concentrations of H2O2 is influenced by facilitated Fenton reaction in the p...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27279

Deforestation is a vital problem at global level, being one of the main causes of climate change. Volume of wood used in construction, furniture and pulp and paper industries increases year by year. Stopping the decrease of forests surface is of imperative importance from the point of view of sustainability. Pulp and paper industry faces with severe lack of pulpwood and for this reason other raw materials are taken into consideration. Chemical pulp can be partially replaced with recovered paper ...
Autori: Adrian Cătălin Puiţel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27348

Chemical precipitation is an effective and relatively low cost method for removal of heavy metals. The removal of lead ions from wastewater by a precipitation process was investigated using sodium sulfide and sodium carbonate. Precipitation experiments were performed using storage battery wastewater with lead concentration of 8.8 mg/L and synthetic wastewater with different lead concentration ranging from 5 to 600 mg/L. A series of experiments (each concentration) were carried out under differen...
Autori: Mehraban Sadeghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27388

Organoarsenic compounds are used extensively as swine feed-additives to promote animal growth and control diseases, e.g. roxarsone (4-hydroxy-3-nitrobenzenearsonic acid) and arsanilic acid (4-aminophenylarsonic acid) are usually overused in swine industry in China. As a cost-effective technology for animal manure treatment and reuse, composting is widely used for swine manure treatment. Therefore, the purpose of this study was to investigate changes of arsenic species and fractions during a full...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27683

Sulfide bearing mine tailings generated through mining and processing of mineral ores is one of the serious problems around the world due to their potential environmental hazards. Current study focuses on vertical distribution and potential mobility of metals in New and Old tailings of a Lead and Zinc mining area of India. Mine tailing profiles sampled from New (0-500mm) and Old tailing (0-400mm) dams were chemically (pH, EC, Carbonate content, Cd, Pb, Zn and Mn levels) and mineralogically (usin...
Autori: Malik Anju
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27690

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

Yizhang, located in south of Hunan province of China is rich in geothermal resources. This paper aimed to study the concentrations of cations, e.g., K+, Ca2+, Na+, Mg2+ and conducted the analysis of the environmental isotope characteristics of δD, δ18O and 13C. Further there are explained the rules of the generation and evolution of geothermal groundwater in Yizhang. The temperature of geothermal groundwater in Yizhang was between 34.2 and 45.4 °C, with a neutral pH and a high...
Autori: Junjie Ba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27944

Chlortetracycline (CTC) and copper (Cu) are simultaneously used as feed additives to improve the growth performance and to prevent infection in pig farming. After ingestion by animals, most of these compounds are excreted and coexist in swine manure. They might have an influence on anaerobic digestion when the swine manure is used as substrate in a biogas plant. The purpose of this study was to investigate the effects of both CTC and Cu on batch swine manure anaerobic digestion in order to bette...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27983

In this study, the effectiveness of integrating ultrasound with mangosteen fruit peel activated carbon (MFPAC) for the removal of reactive black 5 (RB5) dye was investigated. MFPAC prepared by the potassium carbonate activation method was characterized using BET, SEM and FTIR. The effects of ultrasound power, contact time, pH and adsorbent quantity on the removal of RB5 were examined. Obtained results indicate that the MFPAC has a higher removal efficiency with ultrasound integration and can re...
Autori: Randeep Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28093

Aim of the study is to determine Fe, Mn and Cd adsorption in the carbonate-rich clayey soils and to assess their environmental impacts. Soil samples represented a carbonate-rich clayey soil (Isaoren), carbonate-rich soil (Maşuk) and clayey soil (Aşık) was obtained from three different villages in Sanliurfa, southeast of Turkey. Adsorption studies were carried out with batch method. The maximum Fe, Mn and Cd adsorption was found on Isaoren, Maşuk and Aşık soils with ...
Autori: Ayse Dilek Atasoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28116

The valorization of a metallurgical waste (i.e., an iron-rich slag) as raw material for the fabrication of high hardness glass-ceramics using differential thermal analysis, X-ray diffraction, X-ray fluorescence and scanning electron microscopy was investigated. The melting of the slag was aided by the addition of waste glass cullet (WGC) and the vitrification field of this system was investigated. The non-isothermal crystallization kinetics of the parent glass with the highest slag content was s...
Autori: Erika Iveth Cedillo-GonzĂĄlez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28168

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231