AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

Include urmatoarele articole� Degradation of alcian blue 8 gx by heterogeneous and homogeneous photocatalytic processes� Evaluating the performance of solid waste management models� Bioreactors with stirred bed of immobilized cells 1. Studies on mixing efficiency� Fugitive emissions estimation from petroleum storage tanks� New Ni(II) coordination polymers with insulating and anticorrosive properties� Determination of water quality deterioration at pilgrimage centre along river netrav...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25196

Contine urmatoarele articole:??Â?Â? Alternative energy sources in transition countries. The case of bioenergy in Ukraine??Â?Â? Catalytic destruction of aromatic VOCs on SCR-DeNOx commercial catalyst??Â?Â? Ecological Economics And Transport Systems??Â?Â? Bioleaching of uranyl ions from uranium ores by some algae??Â?Â? Irreversible affinity immobilization of lentil seedling??Â?Â? Evaluation of artificial neural network techniques for river flow forecasting??Â?Â? Hydrogen and sustainable energy. Re...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25194

<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

The present paper examined the photocatalytic degradation (PCD) of gas-phase trichloroethylene (TCE) over thin-film TiO2. A large-scale treatment of TCE was carried out using scale-up continuous flow photo-reactor that nine reactors were arranged in parallel and serial. The parallel or serial arrangement is a significant factor to determine the special arrangement of whole reactor module as well as to compact the multi-modules in a continuous flow reactor. The conversion of TCE according to the ...
Autori: Gyung Soo Kim, Sang Bum Kim, Sung Chang Hong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25121

This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

In recent years, the release of volatile organic compounds (VOCs) has received much attention. Catalytic oxidation of VOCs, found in small concentration in industrial gas emissions constitutes an alternative for environmental pollution reduction.In this paper, a comparative study regarding the non-catalytic and catalytic oxidative destruction of non-halogenated or halogenated C6 hydrocarbons (C6H14, C6H12, C6H6, Cl-C6H5, Br-C6H5), is presented. Catalytic oxidation was studied in the presence of ...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25162

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueDestruction of Volatile Organic Compounds by catalytic oxidationAlice Oana Rusu, Emil DumitriuRisk assessment for a shipyard from Romanian Black Sea CoastAnca Florentina Caliman, Ion Balasanian Monitoring the behavior of the restoration interventions of the Probota Monastery’s indoor frescoes under the influence of the environmental factors. II. Modifications of the physical-structural and chemical characteristicsIon Sandu, Adrian Dima, Ioan Gabriel Sand...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25173

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueBiosorption of Cu2+ ions from aqueous solution by Enteromorpha sp.Loredana Brinza, Matthew Dring, Maria Gavrilescu  Environmental impact assessment for steel processingBrindusa Robu, Carmen Zaharia, Matei MacoveanuEnhanced primary treatment of municipal wastewater by ion exchange and membrane processesDaniela Teleman, Peter A. Wilderer, Carmen Teodosiu, Thilo K?śtzle Best practices in kraft pulping - benefits and costs Dan GavrilescuAspects of waste m...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25177

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

AbstractVolatile organic compounds (VOCs) constitutes an important class of environmental pollutants, which, together with other contaminants as NOx, SOx, CO, NH3, CO2 etc. participate in degradation of atmosphere and exhibit a potential risk for human health. VOC emissions may be generated in more than 25 percentages through the use of solvents in different industrial or house holding activities. For applying a certain plan concerning the pollution reduction, any user of organic solvents contai...
Autori: Florin Bandrabur, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25218

AbstractThe perovskite structure was synthesized by sol-gel method type citrate. Three perovskite LaMnO3 samples were obtained after calcination and were characterized by XRD, XPS and TPR. The catalytic testing was carried out in SCR-HC equipment (HC=C3H6 and C3H6 respectively) in presence and also in absence of oxygen atmosphere. The results pointed out a good activity in NOx reduction but only in oxygen absence. As it was expecting, LaMnO3 perovskite has shown a good activity for hydrocarbons ...
Autori: Helmut Papp, Ion Balasanian, Liliana-Mihaela Chirilă, Wladimir Suprun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25222

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

AbstractObservations and data regarding the intense corrosion and deposit phenomena of the carbon steel tube bundle of the heat exchanger are presented. The bundle ensures the cooling of the light fraction C1 - C5 from the top of the distillation column which carries out the removal of pentane and smaller derivates into the RC equipment. Chemical and mineralogical analyses confirm the aggressive action of the fluids flowing through the exchanger. Tests have been done in order to replace the carb...
Autori: Ana-Daniela Georgescu, Lucian Georgescu, Maria Apostolescu, Nicolae Apostolescu, Ovidiu Georgescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25333

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract The photocatalytic degradation of sulfamethazine, a sulfonamide drug, has been investigated experimentally, in aqueous heterogeneous solutions containing n-type oxide semiconductors as photocatalysts, and by simulation, using neural network modeling. Through direct neural network modeling, the evolution of the photocatalytic oxidation process is evaluated as function of illumination time and type of catalyst. Inverse neural network modeling is a particular optimization that gives inf...
Autori: Ciprian George Piuleac, Ioannis Poulios, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25430

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract Highly dispersed nanoparticles of transition and noble metals are utilized for hydrocarbon reactions and rearrangements important to the chemical industry. The need to obtain 1 to 3 nm particles with narrow size distributions has prompted the development of alternative processing methods. Due to widespread speculation concerning the enhanced properties of nanoparticles over their bulk and atomic material equivalents, nanoparticle synthesis has become an active field of research withi...
Autori: , Irina Dumitriu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25482

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract The paper presents the results obtained when using thin films (doctor blade) of titanium oxide powder (Degussa P25) and fly ashactivated with NaOH, for advanced treatment of complex waters resulted in the textile industry. There are studied the heavy metal(cadmium, copper) adsorption and the dyes (methyl orange and methylene blue) photo-degradation using these novel substrates.The thin films crystallinity (XRD), morphology and roughness (AFM) were evaluated and no significant changes...
Autori: Anca Duta, Luminita Andronic, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25500

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Abstract:The textile industry uses high quantities of water which in many cases are disposed to the environment with inadequate treatment.In this work the effluents from the polyamide textile industry containing Bemacid Gelb, Bemacid Rot and Bemacid Blau weretreated by heterogeneous photodegradation. Treatment performances have been evaluated in terms of conductivity, turbidity, totaldissolved solids (TSD), chemical oxygen demand (COD), total organic carbon (TOC), biochemical oxygen demand (BOD5...
Autori: Luminita Andronic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25720

Abstract:The paper presents the influence of different WO3:TiO2 ratios on the photocatalytic and photoelectrolytic properties of the films.The investigations are focused on the morphological (Atomic Force Microscopy, Contact angle), compositional (X-raydiffraction), optoelectric (conductivity, photocurrent) and photocatalytic properties of titanium dioxide films mixed with tungstenoxide. The most important application of these layers is in wastewater purification and hydrogen production using ap...
Autori: Alexandru Enesca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25743

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:In this paper, photo-catalytic process for treatment of phenolic wastewater by TiO2 nano powder immobilized on concrete surfacein a recirculation hydraulic flow was investigated. The process affected by different operational conditions that the optimum onescould be obtained from variables interchange. Taguchi method as a proper method for design of experiments and optimizationwas used to find optimum conditions. Selected five parameters at four levels were consists of initial phenol con...
Autori: Bita Ayati, Hossein Ganjidoust, Mohammad Delnavaz, Sohrab Sanjabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25778

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

This paper presents a study on the integration of two advanced treatment processes for the removal of priority organic processes from wastewaters: catalytic oxidation (Fenton homogenous process) followed by ultrafiltration. The aim of this study was to assess the removal efficiency for 4-chlorophenol (used as model pollutant), as well as the decrease in effluent toxicity in various processes conditions. The experiments have mainly focused on studying the effect of the oxidant dose of the catalyt...
Autori: , Cezar Catrinescu, Corina Petronela Musteret, Daniela Arsene, George Barjoveanu, Petru Apopei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25834

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Four processes have been used to enhance the ozonation of phenol in water: I-pH increasing (O3-pH), II- hydrogen peroxide addition (O3- H2O2), III- UV irradiation (O3- UV), and in the presence of both H2O2 and UV; IV-(O3- UV- H2O2). In each of these processes the rate of phenol degradation has two components: direct and indirect....
Autori: Eszter Arany, Ildiko Bartalis, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25904

AbstractIn this paper integrated network of continuous reactors for the decontamination of gaseous flows in heterogeneouscatalytic gas-liquid-solid – also applicable for bioremediation systems is investigated. For this purpose, duringprocess integration we have identified strategies to develop an optimal system for a variety of well-definedrequirements and to discover ways to ensure cost efficiency to achieve the requirements of sustainable industry in theframe of knowledge-based sustainable eco...
Autori: Maria Gavrilescu, Oana Marlena Penciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25977

AbstractIn the last years many papers have reported about the occurrence of the pharmaceuticals in the surface waters and theirundesirable effects upon the aquatic life. Most of pharmaceuticals pass through the wastewater treatment plants unchangedbecause they are biorefractory compounds and as a result they enter the water bodies. Therefore, it is necessary to improve thebiodegradability of pharmaceuticals effluents (PhEs) before their discharge in the sewerage systems. The aim of this paper wa...
Autori: Carmen Lazău, Florica Manea, Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26021

AbstractThe increased concentrations of priority pollutants in wastewaters have imposed the completion of conventional treatment withadvanced treatment stages (such as catalytic oxidation, membrane processes, adsorption, ion exchange, etc.) for their removal bychemical degradation and/or physical separation.In this study, 4-chlorophenol (4-CP) is proposed as model-pollutant for the priority organic pollutants present in syntheticwastewaters and several processes which can act as advanced treatme...
Autori: Carmen Teodosiu, Corina Petronela Musteret, Daniela Arsene, Daniela Cailean, George Bârjoveanu, Petru Apopei, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26022

AbstractIn this work, cyclic voltammetry (CV) and differential-pulsed voltammetry (DPV) were used to detect pentachlorophenol (PCP)at two types of multi-walled carbon nanotubes (CNT)-based composite electrode, i.e., TiO2-modified-CNT-Epoxy (TiO2-CNTEpoxy)and CNT-Epoxy in 0.1 M sodium sulphate solution supporting electrolyte. The electrochemical behaviour of theelectrodes was investigated in the absence and presence of UV irradiation. A single oxidation peak at a potential value of about+1 V vers...
Autori: , Ágnes Jakab, Aniela Pop, Cornelia Bandas, Florica Manea, Joop Schoonman, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26033

AbstractWater quality is an inportant concern for the ecosystem state from a particular region. Since the continuous urban and economicdevelopment induces a negative impact on entire hydrological cycle, this study investigates the water quality of a Romanian lake,located in the Surduc area - Timis County. This perimeter has undergone significant economic development in the past twodecades due to increased tourism potential and the number of holiday residences.We proposed hybrid materias for the ...
Autori: Adina-Elena Segneanu, Cornelia Bandas, Florentina Cziple, Ioan Grozescu, Paula Sfîrloagă, Titus Slavici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26040

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Recently, a new failure probability index was introduced that characterizes the operation of highly sensitive chemical reactors (i.e. when highly exothermic / hazardous reactions are conducted). Based on this, the current paper exemplifies the application of the risk analysis methodology proposed to generate the Pareto optimal operating solutions accounting for reactor productivity maximization (product yield) and probabilistic risk minimization. The multi-objective optimi...
Autori: Anca Dan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26108

AbstractAs a new type of photoelectrocatalytic materials, the TiO2 nanotube arrays have drawn a lot of attention for efficientlyphotoelectrocatalytic organic pollutants degradation due to their highly photoelectrocatalytic properties. Yet, the performance ofphotoelectrocatalytic organics degradation using TiO2 nanotube arrays electrode is influenced by Cl-, a kind of typical reducingmaterial. This paper focuses on the effect of Cl- on the different photoelectrocatalytic performance of TiO2 nanot...
Autori: Jialing Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26177

AbstractThe purpose of the undertaken research work is to degrade the biopolymeric pigments present in the distillery spentwash. This isdone by direct electro-oxidation using iridium oxide coated titanium mesh as catalytic anode. The effects of current intensity,dilution, pH and time of electro-oxidation were studied. The combined effects were analyzed using Box-Behnken design foroptimization and statistical analysis. The rate constant for first order electrochemical kinetics relating the rate c...
Autori: R. Krishna Prasad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26253

AbstractThe inactivation of Escherichia coli was investigated with two types of underwater electrical discharge systems such as pulsedelectrical discharge (PED) and dielectric barrier discharge (DBD). The DBD system consisted of a quartz tube and a coaxialdischarging electrode, which was submerged in biologically contaminated water. In the underwater PED system, the electricaldischarge starting from the tip of submerged tubular discharging electrode propagated downward and the direction of worki...
Autori: Sang Don Kim
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26263

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractThe paper presents a hybrid method for the advanced removal of low biodegradable organic compounds from water, bycombining the separation selectivity of the membrane with the oxidation efficiency of the photocatalytic process. The aim of thisstudy is to evaluate the performance of the hybrid method to remove toxic compounds from wastewater. The advanced oxidationprocess, based on a photocatalytic reactor with continuous recirculation, ultraviolet (UV) radiations and a membrane, was usedf...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26490

AbstractIn this study, TiO2-zeolite modified carbon nanotubes-epoxy (TiO2-Z-CNT-Epoxy) and TiO2-zeolite modified carbon nanofibersepoxy(TiO2-Z-CNF-Epoxy) composite electrodes were applied for pentachlorophenol (PCP) degradation and determination inaqueous solution. The morpho-structural characterization of the composite electrodes was studied by scanning electronmicroscopy. The electrochemical behaviour of the electrodes was investigated under UV irradiation presence/absence, usingcyclic voltamm...
Autori: Ágnes Jakab
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26491

AbstractA soot transducer based on the measurement of the electrical resistance value of the soot layer deposited on a finger structure wastested at different thermophoretic potentials. The soot, similar to that issued from the Diesel engines, in terms of particle numberand size distribution, was obtained by the incomplete burning of propane and subsequent dilution. The decrease of the resistancevalue in time was directly proportional with the temperature gradient. Thus a soot transducer is aime...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26503

AbstractThe alkylation of light hydrocarbons leads to produce the high octane number gasoline blending components. The homogeneouscatalytic alkylation reaction is usually carried out at low temperature in the presence of H2SO4 and HF. The use of heterogeneouscatalysis for this reaction is a promising solution for the replacement of hazardous acids to environmentally friendly zeolitecatalyst. The alkylation reaction of isobutane with 1-butene was studied on selected zeolite catalysts. The objecti...
Autori: Tatjána Juzsakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26514

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

Abstract This article covers the investigation of the catalyst waste (T.R.M 1 and T.R.M 2) produced in the reactor of oil catalytic cracking. The analysis of this waste was carried out. The properties of T.R.M 1 and T.R.M 2 were investigated and determined, the mineralogical analysis of catalyst waste was implemented, the analysis of thermal effects during the burning was performed. Catalyst waste materials investigated were used in a ceramic system (from 7  to 20  of the ove...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26600

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract The class of xanthene dyes has a complex chemical structure, which showed to be toxic for mixed culture of microorganisms (i.e. anaerobic granular sludge). Because of the unwanted effects of Erythrosin B (Ery B) on environmental components and some food confirmed previously, the dye was chosen in this study to evaluate its ecotoxicity. Also, the Ery B photocatalytic degradation products were assessed in terms of their ecotoxicity. Three-days of seed germination and root growth test...
Autori: Laura Carmen Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26660

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Abstract The recycling of plastic waste is important both in the conservation of resources and the environmental protection. A plastic waste (PE/PP/PS/PVC) was pyrolyzed over a series of post-use FCC catalysts using a fluidizing reaction system similar to the FCC process operating isothermally at ambient pressure. Experiments carried out with these catalysts gave good yields of valuable hydrocarbons with differing selectivity in the final products dependent on reaction conditions. A model ba...
Autori: Ta-Tung Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26836

Abstract The paper describes a numerical analysis concerning the behaviour of Cu and Ni based catalysts having different mole ratios of Ni to Cu in the process of glycerol hydrogenolysis. The impregnation technique was used to prepare the copper and nickel based catalysts. Our study revealed that their performances are different and depends on the Ni/Cu ratio. The catalysts were tested using various reaction conditions, such as time and temperature, and their performances analysed based on t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26843

Abstract A study of a classical BLEVE fireball model associated with a toxic Puff release one was made in order to evaluate the influence of accident conjugate conditions on its consequences in two neighbouring industrial plants. The possible occurrence of the Domino effect is also exemplified for the approached chemical complex including two sensitive neighbouring chemical plants including tubular reactors for catalytic oxidation of butane to maleic anhydride and catalytic hydrogenation of ...
Autori: Hasan Hadi Salman Khwayyir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26880

Abstract Safe operation of highly thermally sensitive industrial reactors is still considered a major issue in chemical engineering practice. The problem becomes even more stringent when highly exothermic reactions are conducted under randomly fluctuating operating variables, and especially when the set-point is located in a close vicinity of the runaway boundaries for increasing the reactor productivity. This study is aiming to derive the runaway boundaries and their associated region of co...
Autori: Constantin Muscalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26884

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

The influence of key process parameters of homogenous catalytic ozonation using ferrous or manganese catalysts on the mineralization rate of salicylic acid (SA), model pharmaceutical pollutant, in water was investigated. In order to assess the combined influence and interactions of studied process parameters as well, the empirical/statistical approach applying Box- Behnken experimental design (BBD) combined with response surface methodology (RSM) was applied. Three numerical and one categori...
Autori: Kresimir Koricic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26939

Semi-conductor oxide enhanced photocatalysis is a sustainable technology suitable for disinfection of water contaminated with pathogens. Disinfection of Escherichia coli was investigated using an immobilized thin film tungsten trioxide (WO3) photocatalyst in a visible light-driven photoelectrocatalytic batch cell (PECB). Disinfection efficiency was monitored under dark electrocatalytic, photolytic and photoelectrocatalytic conditions and assessed using a culture-based approach. Optimal disin...
Autori: Efetobor Scott-Emuakpor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27014

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

The present study investigates the effect of addition of calcium hypochlorite in the titanium dioxide (TiO2) mediated degradation of bio-recalcitrant wastewater from pharmaceutical industry. The degradation studies were carried out in photoreactor irradiated with ultraviolet (UV) light at 365 nm under slurry mode. The reduction in chemical oxygen demand (COD) was estimated as an index of degradation. The influence of process parameters viz., catalyst dose, pH, oxidant concentration and source...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27097

This work focuses on treatment of lead polluted waste glass from urban collection (Pb≈5% wt) for its valorization as support in the immobilization of lipase, because soda-lime glasses are used in enzymatic catalysis. First of all, an extraction process of surface Pb was performed. The process is based on nitrilotriacetic acid (NTA) chelating agent. The operating conditions are: T=80°C, t=1h, pH 10, solid/liquid weight ratio=1/10, reagent concentration=0.1 M. Leaching tests at contr...
Autori: Luisa Barbieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27122

Ozonation of oxytetracycline in aqueous solution with an activated carbon (AC)-supported cerium oxide (CeO2/AC) catalyst was conducted. The activity and stability of CeO2/AC, and the effects of ozone dosage, catalyst dosage, reaction temperature, initial oxytetracycline concentration, and initial pH on the catalytic activity of CeO2/AC for the removal efficiency of total organic carbon (TOC) were investigated. It was found that CeO2/AC catalyst was efficient in TOC removal during ozonation of...
Autori: Zheng-Qian Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27156

An electro-Fenton process was carried out using undivided cell containing tridimensional graphite felt cathode for treatment of real textile wastewater. The study is essentially focused on effects of pH, applied current and transition metal types (Fe2+ and Cu2+) as catalysts on the electrochemical degradation efficiency based on color and COD removal and BOD5/COD value. The results indicated that pH 3 and applied current of 150 mA are the optimum conditions for decolorization and COD removal of ...
Autori: Akbar Eslami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27167

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

The application of advanced oxidation processes (AOPs) emerged as an interesting topic during the last decade. Many studies have been devoted to the complexity of phenomena imposed by AOPs, and a lot of effort was made to justify the application of AOPs. However, the reliability of AOPs has not been an issue of any extensive work. In this work, failure analysis and comparative reliability study were performed for the chosen AOP system, i.e. a laboratory scale photo- and sonoreactor, during the p...
Autori: Ivana Grčić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27220

The effect of ceria content on the physicochemical properties and catalytic performance of nanostructured CeO2/Al2O3 for removal of toluene from waste gas stream was studied. The properties of the catalysts were addressed using XRD, FESEM, BET, TPR-H2 and FTIR techniques. XRD patterns confirmed the formation of CeO2 with average crystallite size of 7.8-8.7 nm. FESEM images confirmed the presence of fine particles between 25.2-189.1 nm. BET results showed that nanostructured CeO2/Al2O3 had high s...
Autori: Saeed Saedy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27245

A Microwave-Ultraviolet reactor was developed and the effect of microwaves on photodegradation of various phenols was studied using the reactor. The degradation study was carried out by six methods - microwave irradiation, photodegradation with UV light, microwave and ultraviolet radiations (microwave irradiation in presence of TiO2, photodegradation with UV light in the presence of TiO2 and also simultaneous MW and UV irradiations in the presence of TiO2). The relative efficiencies of the degr...
Autori: Singaram Karthikeyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27248

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

The remarkable photocatalytic properties of titanium dioxide and the high adsorption capacity of the mesoporous materials were combined to obtain active photocatalysts for the decomposition of Rhodamine 6G dye. The mesoporous TiO2 was obtained by the controlled hydrolysis-condensation of titanium isopropoxide, using hexadecyl-trimethyl-ammonium bromide as template, followed by calcination to remove the organic matter. Subsequently, this sample was doped with sodium wolframate and platinum. T...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27325

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Simulation experiments were conducted to investigate the behaviour of ozonation by-products and the removal of organic matter in the treatment of the Pearl River raw water. The treatment processes include pre-ozonation, conventional treatment processes (coagulation/sedimentation and sand filtration), post-ozonation and granular activated carbon (GAC) filtration. Treatment efficiency of each unit process was evaluated by using several parameters such as permanganate index (CODMn), ultraviolet abs...
Autori: Yue Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27580

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

Water is currently becoming a strategically important material, and the importance of water and wastewater treatment technologies is therefore increasing. Wastewater from the food industry has many special features originating from its high organic matter content. Meat industry wastewater additionally has a high fat content. We investigated the effects of ultrafiltration and ozonation, individually and in combination, for the treatment of meat industrial wastewater. Ozone gas was generated from ...
Autori: Cecilia Hodúr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27631

The mineralization of azo dyes could be realized through solar photocatalytic degradation that is a green method where non-harmful end products are produced. The aim of this study was to investigate the mineralization of Orange G (OG) and New Coccine (NC) using ZnO as catalyst. The degradation of the azo dyes was conducted at different experimental conditions, and parameters such as effect of sunlight to the degradation rate, initial azo dye concentration, amounts of catalyst dosage, pH and effe...
Autori: Wan Fadhilah Khalik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27643

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

Ti/TiO2 films were prepared by DC reactive magnetron sputtering followed by annealing in air at 400 ºC for 4 h. Structural tests have been performed to characterize the films, showing that the prepared films present 70% of anatase phase. When these results are compared with those from TiO2 films grown on glass substrates with similar deposition parameters, it can be seen that Ti substrates favour the formation of rutile phase, which is not observed on the films supported on glass, indicatin...
Autori: Susana Sério
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27868

The catalytic hydrogenolysis of glycerol, a by-product of the biodiesel manufacturing process was studied on copper chromite catalysts with different chemical composition. The obtaining of propylene glycol was studied under mild reaction conditions (180- 240oC temperature range, 8 hours reaction time and moderate pressures). These important parameters have significant effects on the glycerol conversion and that is way the actual study was concerned to the obtaining of a superior selectivity t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27892

In this work, we report a methodology to provide emission factors based on micro-reactor studies. We propose emission factors for ammonia (NH3, 158 mg/km), nitrous oxide (N2O, 322 mg/km) and molecular hydrogen (H2, 72 mg/km) for vehicles equipped with three-way catalytic converter (TWC). Our experimental conditions were similar to those prevailing on vehicles during catalyst light-off and transient urban driving cycle. NH3 and H2 emission factors reported in this work are quantitatively simil...
Autori: Gustavo Ariel Fuentes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27899

In this study, Mg-doped ZnO nanoparticles with 2% Mg content were synthesized by sol-gel method. The structure and morphology of the nanoparticles were characterized by TEM, BET and UV-Vis absorbance techniques. From TEM image, it was found out that the nanoparticles had uniform size and uniform distribution. BET analysis revealed that in comparison with pure ZnO, Mg 2%/ZnO nanoparticles had a higher specific surface area. Based on UV-Vis absorbance analysis, Mg 2%/ZnO nanoparticles shifted t...
Autori: Nahide Zarei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27909

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

The main objective of the research was to study the efficiency of the glyphosate amine pesticide mineralization in wastewaters (real and model type of wastewaters respectively) using ozonation treatment as an advanced oxidation processes (AOP). The wastewater samples (model wastewater) were obtained by mixing a given volume of the stock solution prepared from glyphosate isopropyl-amine in different volumetric ratios with distillated water and with real wastewater obtained from a domestic wastewa...
Autori: József Németh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28050

Water is a vital resource for both human needs and the functioning of our ecosystem. Fresh water availability and water use have been a growing problem for centuries. This paper gives a brief overview on the current knowledge of water stress and describes possible solutions. In addition to a differentiated consideration of the various types of water stress, the special importance of water purification by membrane technology and the associated processes is discussed in detail. The economic provis...
Autori: Jan Koppe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28086

Photocatalytic processes are among the most efficient treatment methods of waters polluted with recalcitrant organic substances. Nanotubular TiO2 arrays with photocatalytic properties were obtained in the process of titanium anodic oxidation in the fluoridecontaining electrolyte. Under the proposed conditions of electrolysis, a coherent system of tightly adjoining nanotubes was formed with the internal diameter of 60-80 nm and walls thickness up to 60-65 nm, the tubes height being dependent on p...
Autori: Gheorghe Duca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28137

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

This study investigates the mechanism and efficiency of catalytic ozonation process on iron-loaded rice husk ash (Fe-RHA) and Peanut shell ash (Fe-PSA) for the Erythromycin removal from aqueous solution. In the current study, the COD removal efficiency of Erythromycin was studied in simple ozonation and catalytic ozonation using Fe-RHA/O3 and Fe-PSA/O3 processes. The operational parameters such as pH effect, catalyst dose, and reuse performance of the catalyst were studied. Moreover, the hydroxy...
Autori: Shama Nazir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28208

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

The solar energy received by the atmosphere of the Earth is universally distributed, which constitutes the atmospheric dynamics. The changes observed in the climate of the Earth are due to solar output variations. Some detailed reviews have accounted for the influence of solar activities on the climate using sunspot number derived from peak Sun hours, but has gaps in analyzing critical statistical background information, seasonal, latitudinal and solar activity year validation. A number of st...
Autori: Chukwuma Moses Anoruo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28260

The olive oil extraction industry is one of the most polluting wastewaters from the food industry, which is considered an important economic activity in the world. The environmental effects of olive wastewater are related to chemical and organic loading, which is resistant to biodegradation processes. The purpose of this study was to determine the efficiency of combined electrocoagulation, catalytic ozonation, to reduce organic load and improve the biodegradability of olive oil sewage. The pres...
Autori: Mohammad Reza Khani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28261

Biomethane is incentivized in Italy and in many other European countries as a substitute fuel for transport, in order to reduce fossil fuel and cut CO2 emissions. In Italy, Certificato di Immissione in Consumo (CIC) is actually sustaining biomethane production, charging petrochemical companies who need to cover their obligation quotes. Actually, biomethane production has to fulfil sustainability requirements in order to be entitled to get CIC. Sustainability principles are, among others, the typ...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28305

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323