In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractThe paper presents new experimental results on the photodegradation of two important phenyl urea herbicides in water: Monuron and Isoproturon. The photodegradation was performed by two Advanced Oxidation Processes (AOPs): the homogeneous photo- Fenton process (, UV-H2O2 - Fe3+) and a heterogeneous photo - Fenton reaction using an iron pillared Laponide- RD catalyst (Fe-Lap-RD). The Fe-Lap-RD catalyst was prepared from iron nitrate 0.2 M solution and a suspension of Laponite - RD clay. Th...
Autori: Elsa Lundanes, Ilie Siminiceanu, Maria-Magdalena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25234

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractThe present article deals with the study of the quality of the soils in the Cordun area – the waste dump. This refers to the characteristics of the analyzed location site (geomorphological, geological considerations, the pedological and agrochemical characterization of the soils in the area outside the plant), but also to the establishment of the pollution rate in the location site (experimenata data, results and debates). The conclusion of the present article is that the analyzed area...
Autori: Elena Doinita Carlig, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25315

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract In the new millennium to sustain a healthy life in harmony with nature, it will be extremely important to develop various materials and processes that minimize any harmful influence on the environment. The feasibility of sludge recycling in the brick manufacture was evaluated through laboratory testing. Several ceramic masses with clay, sand and various proportion of sludge have been synthesized and than characterized by their physical-mechanical properties. Sludge fineness also has ...
Autori: Ana - Maria Szoke, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25454

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

Chromium and cadmium are heavy metals that occur naturally in the environment and especially in soils. Their toxic effect is more pronounced at high concentrations and it depends on the oxidation states. While Cr (III) is considered an essential trace element for the metabolism of living organisms, Cr (VI) has a higher mobility and is easily soluble in soils and can be leached into surface water or groundwater, and taken up by plants. That leads to a toxic and carcinogenic effect to humans via i...
Autori: Dumitru Bulgariu, Florian Statescu, Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25866

AbstractIn this study, palygorskite clay calcinated at different temperatures from 200 to 900 °C was used as adsorbent to removephosphate from aqueous solutions. The crystal structure and the surface property of the thermally modified material wasinvestigated to determinate the relationship between the adsorption capacity of the adsorbent and the changes of the crystalstructure and surface property. The results indicate that palygorskite clay calcinated at 700 °C had the highest adsorptioncapaci...
Autori: Chengsong Qing, Chengzhu Zhu, Dong Chen, Jiayuan Wang, Jingjing Xie, Tianhuhu Chen, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25949

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractThe objective of this paper is to investigate the effect of expansive soil treatment with Eco-Cement (EC) stabilizer, as beingcomposed of an alternative binder that partly substitutes the Ordinary Portland Cement (OPC). The extended use of EC in soilstabilization will carry several significant environmental benefits. Firstly the by-product resulted from the production of iron in ablast furnace will be reused, that otherwise will be stored on the ground in deposits representing an importa...
Autori: Anghel Stanciu, Irina Lungu, Mircea Aniculăesi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26069

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractThe construction industry is one of the main sectors of energy consumption and carbon emissions in China. The new-types ofbuilding materials can be produced by recycling industrial solid wastes which is an effective solution to development of greenbuilding materials and abatement of environmental emissions. In this paper, new-types of bricks made of fly ash (residuesgenerated in coal combustion) and coal gangue (a kind of solid wastes generated in coal mining and coal production) and the...
Autori: Haitao Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26265

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractThe washing method for uranium contaminated soils using three different reagents was investigated. Experimental data havebeen obtained for four types of soils, which have been characterized in terms of particle size distribution, as well as structure andchemical composition. Thus, the decontamination degree for each type of soil and reagent respectively has been measured.Subsequently, the decontamination process has been simulated using an artificial neural network. Based on this neural ...
Autori: Alexandru Woinaroschy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26451

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Particle size distribution is one of the most influential factors of most soil physical and even some soil chemical characteristics. As modern measurement techniques are being introduced, the need for comparing new methods with older methodologies arises because comparability means data continuity. Here, three institutes conducted a comparison of particle size measurement among the laser, areometer and pipette techniques. The purpose of the comparison was to a) discover any differen...
Autori: Csaba Centeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26733

Abstract The feasibility of treating tannery wastewater having high organic loads was studied using ceramic membrane based microfiltration process. The common effluent treatment plant (CETP) of a centralized leather complex was selected for the study which accommodates about 450 tanneries in the city, processing hides from raw to finished products. Effluent sample was collected from different locations of the CETP, i.e. untreated composite effluent, effluent from primary clarifier and from ...
Autori: Priyankari Bhattacharya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26837

Abstract The objective of this study is to manufacture a geopolymer by replacing part of the metakaolinite by calcined oil-contaminated clay (OCC) and investigate its properties. The effects of the calcination temperature, the mix design of the alkali activator, and the degree of calcined OCC replacement on the properties of the geopolymer were studied. Evaluation of pozzolanic activity and compressive strength as well as micro structure observation by SEM and XRD were performed in this stud...
Autori: Huan-Lin Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26905

Water scarcity, the degradation of freshwater resources, and wastewater pollution are reaching crisis levels, especially in arid regions of the world. The reuse of wastewater was investigated by using intermittent media infiltration (IMI) to evaluate fecal coliform (FC) removal efficiency. Twelve IMI columns were packed with soil and natural filtering materials (sand, zeolite, vermicompost and charcoal) at percentages of 25, 50 and 75. The municipal wastewater was treated for the FC analysis ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26935

The release of nitrogen compounds into the environment is a major concern worldwide. Different studies howed that recycled materials have a high removal capacity for pollutants. Bentonite and its major clay minerals, smectites clays are common bleaching agents used for oil refinery bleaching and known as bleaching earth (BE). In this study regeneration of spent bleaching earth (SBE) acquired from the vegetable oil industry was surveyed via different methods and the regenerated spent bleaching...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27000

The paper deals with the amounts of total and plant available forms of heavy metals (Pb, Cr and Cu) and relation between soil properties in three catenas in postglacial area of the Łyna River valley, NE Poland. The results were presented on the background of four geochemical landscapes distinguished within the study area: eluvial or trans-eluvial, eluvial accumulative, trans-superaqual and super-aqual. The average total content of heavy metals amounted to: Pb – 14.05 mg kg-1 d.m., ...
Autori: Paweł Sowiński
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27058

Heavy metal pollution is a major source of aquatic contamination and has deleterious effect on the environment, therefore treatment of the polluted sites and wastewater becomes very essential. Biofilm based bioremoval of heavy metals have been a new area of research. Bacterial strains belonging to the genus Bacillus, isolated from chromium polluted soil (Palar river basin, India) have been employed as consortium for Cr(III) removal from chrome tanning effluent. The bacterial isolates were fou...
Autori: Aafreen Fathima
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27086

A natural Cretaceous sodium (Na) bentonite from North Patagonia, Argentine, is considered a potential construction material for landfill liners. It is studied alone and in mixtures with sand. Physical and chemical properties of the Na-bentonite were determined to verify the suitability of this material for the construction of low permeability mineral liners. Hydraulic conductivity measurements were conducted on pure bentonite and on mixtures of poorly graded sand with 3, 6, 9 and 12% of Na-bento...
Autori: Telma Belén Musso
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27190

According to literature, aggregate stability of soils is influenced by: particle size and soil texture, soil structure, content of Ca2+ and Mg2+, mineral clay type, soil content of organic matter, soil processing degree. This paper aims to investigate the influence of some physical, microbiological and chemical properties of saline soil concerning water-stable aggregate. The hydro system stability of the aggregates appears in the specialized studies as having a positive correlation with microorg...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27300

Considering the actual environmental issues, the waste management has become a major challenge in Europe and worldwide. Recycling the waste into sustainable products can be an alternative to landfill with positive effects on the costs and environmental pollution. In this respect, in the last years numerous studies and research emphasize the utilization of different type of waste to obtain materials for building applications. The aim of this paper is to assess the effect of using sewage sludge ge...
Autori: Petronela Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27315

The composition and the structure of the soil matrix have an important role in determining the water and the air regime into the soil. In the soil pore the area occupied by water and air, capillary and adsorption phenomena occur, together defining the suction of the matrix. The suction-humidity relationship varies from one soil to another, but also to the same soil in time. This paper sets out the results of investigations aimed at highlighting the influence of the composition and structure of...
Autori: Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27332

This research was focused on the valorization of agro industrial waste/by products available in the local industry with the kilometer zero (km 0) concept, as a replacement of virgin raw materials (clay) to elaborate lightweight aggregates (LWAS). The alternative raw materials were employed as pore forming agent, in order to reduce sintering temperature and energy consumption of the furnace. The three technical nutrients studied were provided for local food industries: sludge from wastewater trea...
Autori: Romina D. Farias
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27405

Two montmorillonitic clays were modified with N-(methoxy-polyethylene glycol) ethylene diamine and tested as sorbents for removal of Rare Earths (REs) from aqueous solutions. Lanthanum was chosen as representing element of REs family and adsorption tests were performed with the aim of selecting a system with good uptake efficiency for the pollutant abatement in wastewaters. The effects of pH were studied and the properties of the obtained final materials were evaluated with simple model syst...
Autori: Elena Maria Iannicelli-Zubiani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27408

Tobacco is one of the most important agricultural products in the Republic of Macedonia. Elemental composition of tobacco and soil from different agricultural areas was studied for monitoring purposes. The main purpose was to determine the intensity of accumulation of various elements in tobacco plants and to determine possible relationships between certain chemical and physical properties of soils (pH, clay, cation exchange capacity - CEC, organic matters - OM and total organic carbon - TOC). T...
Autori: Biljana Jordanoska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27625

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

The paper analyses the compressive strength of problematic soils as marlstone, limestone, and brown clay in Jordan, considering the capacity to use the fly ash residue obtained from the combustion of oil shale as a cement-like material for building works contributing in minimizing the environmental impact of the expected huge output of solid waste resulting from the retort residue of the oil shale rocks. After blending soils collected from Jordan with both fly ash at different percentages (10...
Autori: Monther Abdelhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27765

In this paper, the typical measurement techniques and production procedures defined in the UNI-EN guidelines for ceramic manufacture are taken into consideration to evaluate the properties and the characteristics of the bricks produced by using a mixture containing cubilot slag. The results of the experimental tests demonstrate that these measurement techniques are not enough to define the safety of the waste bricks. Up to now, UNI-EN guidelines for ceramics do not define crystallinity measureme...
Autori: Domenico Luca Carni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27787

This paper exposes the research activities regarding REBAF (Energetic Recover of River Biomasses) project, focused on the maintenance operations self-sustainability of the Secchia river (Italy). Poplar was found as the most abundant and representative wood plant of Secchia riverbanks, with a good behavior during gasification process: from 1 hectare of maintenance every three year, it was possible to produce 23 MWh of electrical power and 31 MWh of thermal power. The biochar obtained was characte...
Autori: Vittorio Vezzali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27804

This paper presents the results of experimental researches regarding the optimization of a decontamination process through thermal desorption of soils contaminated with crude oil. The optimization was performed for the following desorption parameters: heating temperature of the soil and the treatment duration, by increasing the temperature from 300°C to 350°C and decreasing the treatment duration from 10, 15 and 20 minutes to 5, 10 and 15 minutes. The economic calculation of the decontam...
Autori: Dorina Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27846

In this study we investigated the possibilities of using recyclable fine and coarse grain waste obtained by grinding Polyethylene Terephthalate (PET) containers, as light filling materials for different applications (clay dams, highway embankments, and backfills behind retaining structures. Various geotechnical tests were performed on clayey soil and soil-PET mixtures using recycled fine and coarse granules of Polyethylene Terephthalate bottles. The results indicated that the use of the recyc...
Autori: Osman Gunaydin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27920

Slags are the main by-products from steelmaking cycle, which are currently recycled inside the steel industry as well as in other sectors with significant environmental and economic benefits. As in Italy slags application is not yet allowed in agriculture, the paper aims at evaluating the technical and economic feasibility of a slag treatment plant, to obtain a product to be sold in the fertilizer market as soil amendment. A preliminary assessment of the fate of some trace metals (Cr, V, Sb a...
Autori: Teresa Annunziata Branca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28012

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

Aim of the study is to determine Fe, Mn and Cd adsorption in the carbonate-rich clayey soils and to assess their environmental impacts. Soil samples represented a carbonate-rich clayey soil (Isaoren), carbonate-rich soil (Maşuk) and clayey soil (Aşık) was obtained from three different villages in Sanliurfa, southeast of Turkey. Adsorption studies were carried out with batch method. The maximum Fe, Mn and Cd adsorption was found on Isaoren, Maşuk and Aşık soils with ...
Autori: Ayse Dilek Atasoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28116

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

The efficiency of drainage installed in clay soils using ditch backfill of soil mixed with lime is presented in this paper. The drainage ditch backfill was mixed with lime where 0.6% of soil matter consists of active CaO. The paper proposes a methodology that determines an optimal amount of lime. The experimental site was set in Kalnujai, Raseiniai district, Lithuania. The measurement of filtration in drainage trench, the arable layer and the soil between drains was performed using a double r...
Autori: Mindaugas KlimaĹĄauskas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28177

This study aims to evaluate the properties of different wastes obtained from four red ceramic brick industries in the northern region of Santa Catarina, Brazil. The characterization of the clay brick waste (CBW) was performed using the XRD techniques, XRF, FTIR, DTA and SEM. Techniques to determine the pozzolanic activity, particle size, B.E.T. surface area and specific mass were used. The consumption of calcium hydroxide (CH) in the cementitious pastes with the CBWs was also measured. An app...
Autori: Adilson Schackow
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28184

Inorganic ceramic materials is receiving more attention in recent times due to their unique characteristics which include different pore structures, hydrophilic surfaces, high chemical, thermal and mechanical stabilities that offer avenues for application in water treatment. In the present work, cost-effective clay ceramic water filters of different designs were developed from clay (50, 60, and 70) %, sawdust (15, 20, 25, and 35) %, grog (5, 10 and 15)% ratios plus 5% bone char by volume and ...
Autori: Enyew Amare Zereffa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28196

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

The paper analyses the possibilities of recycling tannery sludge (TS) in clay brick manufacture. The physico-mechanical properties and microstructure of clay brick and cement mortars vary depending on TS content in the mix. 2.5 %–15.0  TS (by weight) was added to clay bricks fired at 1000 C temperature and maintained at maximum heat for 1 hour. The tests revealed that 2.5  TS addition had a positive effect on physical and mechanical properties of clay brick: reduce drying and mfi...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28209

The study is focused on creating magnetic mesoporous materials through the insertion of a nickel ferrite into the structure of kaolintype clay. Sol-gel auto-combustion method was employed to synthesize the materials, using glycine and tartaric acid as chelating/combustion agents. This is the first study on the combined effect of different fuel agents and of clay-to-ferrite molar ratio on the structural, textural, magnetic and adsorptive properties of nanocomposites. The value of the average por...
Autori: Stefana Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28210

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

Taking the sandy aquifer intruded by seawater in the lower reaches of Dagu River as the research object, the samples of underground freshwater, seawater and aquifer media were collected, and their composition and properties were determined. The seepage device was used to simulate the displacement process of seawater and freshwater. The relationship between permeability change of aquifer and hydrologic-geochemical action was studied. The mechanism of water sensitivity was explained by a hydrologi...
Autori: Jiaguo Ren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28281

The aim of this study is to design and characterize a new controlled release fertilizers category by using valorization of residues from agri-food, industrial and post consumers activities normally allocated into landfill disposal. The underlying strategy in materials research fully agreed with the circular economy perspective and the more recent European legislation about critical raw materials recovering. This study covers the development of lightweight aggregates, based on a local red clay (k...
Autori: Silvia Barbi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28286

In this study, the change of freeze-thaw test result of unconfined compressive strength of clayey soils reinforced with pine tree sawdust and marble dust was investigated. Mixtures containing 5%, 10% and 15% marble dust and 0.5%, 1% and 1.5% pine tree sawdust were compressed by standard Proctor test with optimum moisture content. After curing the mixture samples for 1, 7 and 28 days at a working room temperature of +21°C, they were subjected to the freeze-thaw test at -21°C, +21°C fo...
Autori: Necmi Yarbasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28342