AbstractThe mechanisms in the shaping of organic food in Denmark since the 1970'ies are analysed as a contribution to the discussion of strategies for a more sustainable production and consumption of food. The background is the major  achievements in Denmark within organic food since the 1970'ies, but also the recent years' reduction in the land converted to organic farming. The analyses are based on experiences from projects, analyses and literature and draw on innovation theory and theory...
Autori: Michael Sogaard Jorgensen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25153

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Contain all the articles from this issueEnvironmental analysis by capillary electrophoresis. Atmospheric samplesCamelia Draghici, Gheorghe Coman, Mihaela Sica,Dana Perniu, Mihaela Badea   The ecological farms - A solution for sustainable agriculture. II. Position and perspectives of the ecofarms in the frame of the productive agricultural system Stela Axinte, Alina Stanciu, Lorica Axinte  The extraction and clean up of organochlorine pesticides and PCB's from water using solid phase ex...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25170

Contain all the articles from this issueDestruction of Volatile Organic Compounds by catalytic oxidationAlice Oana Rusu, Emil DumitriuRisk assessment for a shipyard from Romanian Black Sea CoastAnca Florentina Caliman, Ion Balasanian Monitoring the behavior of the restoration interventions of the Probota Monastery’s indoor frescoes under the influence of the environmental factors. II. Modifications of the physical-structural and chemical characteristicsIon Sandu, Adrian Dima, Ioan Gabriel Sand...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25173

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

Contain all the articles from this issueICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Treatment Technologies for Gaseous Fluxes"Surface chemistry studies on molybdena–alumina catalystTatiana Yuzhakova, ?kos R?Šdey, Endre Domokos, J??zsef Kov??cs, Monica Caldararu, Cristian Hornoiu, Mariana Carata, G.Postole, Cornel Munteanu, Larisa Strukova, Jozse FazakasHebicidal behaviour of a new N,N'- biquaternary salt of 4,4'- bipyridineServilia Oancea, Marinela Irimia, Gabriela Carja, Anton Airinei, Nicu...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25189

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

AbstractThe paper presents original results concerning concentrations of eight heavy metals in soils adjacent to two improperly built municipal waste deposits located in Eforie Sud and Techirghiol, Constanta County, Romania. Measurements have been done on surface and depth soils, during April-October 2006. The applied analytical technique for metal determination was flame atomic absorption spectrometry (FAAS). The mean measured values ranged as follows (in mg/kg dry weight): Cd: 0.09 - 0.15; Co:...
Autori: , Elisabeta Chirilă, Narcisa Elena Ilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25213

AbstractThe extraction of some pollutants from different matrices, the treatment of hazardous and infectious wastes, the destruction of refractory compounds and the prevention of noxious emissions are the main environmental applications of microwave-assisted chemistry. The advantages and disadvantages of this technique are also considered....
Autori: Carmen Zaharia, Georgiana G. Surpăţeanu, Mioara Surpăţeanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25217

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractSome industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the s...
Autori: Alina Soceanu, , Simona Dobrinas, Vasile Magearu, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25227

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractPolycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector ...
Autori: Alina Soceanu, , Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25237

AbstractBased on the simulation equations, which were developed earlier (Rao, 1999 and Rao et al., 2007) relating the oxygen transfer coefficient k (= KLa20 (?ľ/g2)1/3) with theoretical power per unit volume of water X (= N3D2/g4/3?ľ1/3) and k with actual powerconsumed by the surface aerators per unit volume PV (= P/(V??(g?ľ)1/3), methodology has been demonstrated to the save the energy consumption, defined by ?? (=PV /k), where KLa20 is the overall oxygen transfer coefficient at 20oC, ?ľ is kin...
Autori: Achanta Ramakrishna Rao, Bimlesh Kumar, Neelam Verma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25243

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractThe comparative study on reactive extraction of p-hydroxybenzoic acid with Amberlite LA-2 and D2EHPA in two solvents with different polarity (n-heptane and dichloromethane) indicated that the extractant type and solvent polarity control the extraction mechanism. Thus, the reactive extraction with Amberlite LA-2 occurs by means of the interfacial formation of an aminic adduct with three extractant molecules in low-polar solvent, or of an salt with one extractant molecule in higher polar s...
Autori: Anca-Irina Galaction, Dan Caşcaval, Maria Cămăruţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25250

AbstractThe synthesis of some grafted polysiloxane and azo-polysiloxanes with potential applications as rheology modifiers or surfactants for waterborne paints is reported. Nowadays it became very important to design environmentally friendly systems exhibiting the best end-uses properties. Due to their complex architecture and their sensitivity to UV radiation the studied polymeric systems exhibit very interesting rheological properties. All the polymers containing the azobenzenic groups in the ...
Autori: Constanta Ibanescu, Ioana Moleavin, Iulian Nor, Nicolae Hurduc, Viorel Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25252

AbstractIn this study, we follow the chrome distribution and his association forms with mineral and organic components, from 14 soilsamples from industrial zone of IaÂ?i city.The total chrome concentration in studied soil samples varied between 11.73-129.35 μg/g, being lower than the normal values only for four samples. The Cr(VI) weight of total chrome content varied between 3.78-14.52 %. For none of studied soil samples the chrome content is not over to value of alert concentration. The q...
Autori: Constantin Rusu, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25260

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractConsidering the importance of transfer phenomena in chemical engineering and environmental protection, in particular heat transfer modelling, numerical methods are applied to investigate the transient heat transfer inside an elliptic cylinder. The temperature of the surrounding medium was considered constant and equal to the temperature on the surface of the cylinder. The heat balance equation was solved numerically in elliptic coordinate system. The computations were focused on the infl...
Autori: Gheorghe Juncu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25269

AbstractThe investigation focused on the impact on the environment caused by a dairy farm which supplies SC CAMYLACT LTD Panaciwith raw materials, a milk processing unit whose impact on the environment was analyzed. The material balance for the activityon the farm was resized and, thanks to this, the synthetic indicators of the impact on the environment, such as the specificinfluents of materials and specific effluents could be calculated....
Autori: Constantin Hutupas, Mihai Nicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25276

AbstractThe evaluation of the occupational risk represents an operation whose purpose is to assess the risk for accidents and occupational diseases which can occur during the development of some hazards produced by human activities inside the working system, with the view to giving a qualitative and a quantitative size of this element.In the study, mathematical patterns are developed to be used for laying foundations of modern methods for the analysis and assessment of occupational risks. The sc...
Autori: Angelica Nicoleta Draghici, Constantin Baciu, Gabriel Dragoş Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25280

AbstractThe paper approaches studies of projections of future climate change that use a hierarchy of coupled ocean/atmosphere/seaice/ land-surface models to provide indicators of global response as well as possible regional patterns of climate change. It is evidenced that, after the global warming, a new phenomenon that occurs in the terrestrial atmosphere has drawn the attention of the scientific community. It is called global dimming - the decrease of the solar beams capacity (infrared, visibl...
Autori: Catrinel-Raluca Giurma-Handley, Constantin-Marin Antohi, Ioan Crăciun, Ion Giurma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25285

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractSoil pollution causes significant damage to the environment and human health as a result of their mobilities and solubilities.Significant progress has been made in regulating soil pollution, with a parallel development of methodologies for soil assessmentand remediation. The selection of the most appropriate soil and sediment remediation method depend on site characteristics, concentration, type of pollutants to be removed, and the end use of the contaminated medium. The approach include...
Autori: Attar Singh Sheoran, Poonia Poonam, Vimla Sheoran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25291

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractThe occupational safety is that state of the working system where there is no possibility that occupational accidentsand diseases should occur. Considering the specific features of the component elements there are no such full safe working systems for men because there is always a hazard of occupational accidents and diseases.Generally speaking, all the component parts of the system, together with the relations built among them have beenconceived, designed and produced so that there is n...
Autori: Constantin Baciu, Gabriel Dragoş Vasilescu, Valeriu Plesea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25322

AbstractThe work presents the negative environmental impact produced by an extraction of crude oil activity. To highlight and quantify the negative effects on the environment produced from such activity, the experimental part has been focused on evidence of samples of soil, water from groundwater aquifers and surface, and the air emissions. The values of quality indicators are presented in graphs and tables, highlighting an activity with all major impact on the environment....
Autori: Aurica Grec, Corneliu Maior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25326

AbstractNatural hemp fibers have been evaluated for Zn (II) ions sorption from diluted aqueous solutions. In order to establish the optimum conditions, the effect of initial pH of solution, hemp dose, Zn (II) concentration, temperature and contact time of phases on the Zn (II) sorption by natural hemp has been studied. To model the Zn (II) sorption at three different temperatures the Langmuir and Freundlich isotherms have been used. The Langmuir maximum sorption capacities were determined as bei...
Autori: Carmen Paduraru, Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25336

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

AbstractPaint sludge of automotive industry contains heavy metals and other toxic substances. Due to this matter, it has a high pollution potential. Incorrect disposal of paint sludge led to kinds of environmental pollution. Recycling and reusing of wastes can be one of the best solutions for decreasing of pollutant entrance to environment. The purpose of this study was to present a new method of extracting the main components of paint sludge, for determining concentration of elements in paint s...
Autori: Azadeh Akhavan Bloorchian, Seyed Mostafa Khezri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25346

AbstractAn efficient design and development of the occupational health and safety managing system in a working system involves a suitable tailoring of occupational health and safety state in relation to the risk level associated to the conditions for the occurrence of general and specific hazards all through its length of operation.This paper presents a methodological approach for the analysis and for a likelihood estimate of industrial risks identified inside complex structures of the working s...
Autori: Constantin Baciu, Gabriel Dragoş Vasilescu, Tiberiu Attila Csaszar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25347

AbstractA present challenge for research is to determine how to use the combination of oil, gas and coal most efficiently with the minimum environmental damage. In this paper the authors have compared technologies to produce the electricity using natural gas and coal. The objective of this paper consists in evaluation of the life cycle assessment of the natural gas and coal in order to compare their greenhouse gases (GHG) emissions. In this way, three systems with and without CCS were examined: ...
Autori: Adrian-Alexandru Badea, Cristian Dincă, Gheorghe Lăzăroiu, Tiberiu Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25355

AbstractPolycyclic aromatic hydrocarbons (PAHs) are included in the European Community (EC) and in the Environmental Protection Agency (EPA) priority pollutant list due to their mutagenic and carcinogenic properties. PAHs emissions from automobile traffic and industry activities were shown to influence the PAHs levels and profiles in vegetables grown nearby. The levels of 15 PAHs were determinate in samples of pepper (Capsicum Annuum) and tomato (SolanumLlycopersicum) in different stages of plan...
Autori: Alina Soceanu, Dan Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25360

AbstractTitanium alloys show attractive properties for biomedical applications where the most important factors are biocompatibility, corrosion resistance, low modulus of elasticity, very good strength-to-weight ratio, reasonable formability and osseointegration. The aim of present study was to evaluate the electrochemical behaviour of Ti6Al7Nb alloy in Ringer’s solution of different pH. This evaluation was carried out through the analysis of the potentiodynamic polarization curves, and electr...
Autori: Daniel Mareci, Julia Claudia Mirza Rosca, Marina Garcia Falcon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25363

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

AbstractThe lead(II) ions sorption from aqueous solutions on three types of peat from Poiana Stampei (Romania) was studied. The peat was drawing from different deeps, such as 5-10 cm deep (peat 1), 0.5-1.0 m deep (peat 2) and from > 1.5 m deep (peat 3). The influence of several experimental parameters (initial lead concentration, contact time) was studied in batch experiments. The kinetics of sorption was followed based on the amount of lead(II) ions retained at various time intervals. The re...
Autori: Laura Bulgariu, Mioara Răţoi, Dumitru Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25389

AbstractThe study presents the processing possibilities for marc resulted as still residue from the distillation of fermented fruits in view to obtain a compacted solid fuel. Initial marc composition (carbon, hydrogen, nitrogen, sulphur and oxygen contents) determined by elemental analysis is evidenced, as well as technical characterisation (ash and moisture contents) and ash's qualitative composition, chemical characterisation of the liquid phase (pH, total phosphorus, acidity and conductivity)...
Autori: Daniela Simina Stefan, Anca-Ileana Penu, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25391

AbstractEquilibrium data of water vapor adsorption from wet air on several materials were experimentally determined at temperature values of 313 and 333 K and air relative humidity values ranged between 30 and 90 %. Experimental data were correlated with Langmuir and Freundlich models. The obtained results emphasize the significant difference between the water retained on the adsorbent materials impregnated with various salt solutions, and on classic adsorbents....
Autori: Ioan Mămăligă, Constantin Baciu, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25394

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract Analytical equations for the variation of soil moisture content and for the local storage coefficient for a layered soil with a relatively shallow water table were developed in this study, based on a linear distribution law of the moisture retention on soil's profile, and the van Genuchten-Mualem parametrical model for the moisture-suction curve. By considering this mathematical model, an original computer code was written in MATLAB to determine and then to graphically represent the...
Autori: Dan Prepelita, Stefan Popescu, Esmeralda Chiorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25429

Abstract Spent hydroprocessing catalysts from petroleum refining industries have been classified as hazardous wastes due to their content in heavy metal and persistent organic pollutants (POPs). The aim of our paper determine the polycyclic aromatic hydrocarbons (PAHs) residues contents in spent catalysts samples from four different units of the Romanian refinery Rompetrol Rafinare,Constanta: Hydrogen (H), Gas Desulfurization Sulfur Recovery (GDSR), Hydrofining Turbojet Kerosene (HTK) and Pet...
Autori: Camelia Draghici, , , Gabriela Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25449

Abstract Electroflotocoagulation is used for the treatment of liquid wastes of various origins, containing suspended matter. The metal hydroxide formed by electrochemical metallic ions generation acts to aggregate the colloidal impurities, and the hydrogen bubbles evolved at the cathode allow flotation of foam containing the impurities. The aggregates formed (containing the impurities) and lifted above the solution can then be removed. Electroflotocoagulation (simultaneous electrocoagulation ...
Autori: Marius Constantin Mirica, Mirela Ioana Iorga, Adina Segneanu, Ionel Balcu, Doru Buzatu, Cristian Vaszilcsin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25457

Abstract The paper presents new studies about the removal efficiency of the biochemical treatment process of the Municipal Wastewater Treatment Plant from Constanta city, during 2008. Influent and effluent samples of biochemical treatment stage were collected and ammonium concentration, chemical oxygen demand (CODCr) and biochemical oxygen demand in five days (BOD5) were measured, aiming to study the evolution of the removal efficiency, during 2008. Additional analyses have been performed in ...
Autori: Elisabeta Chirilă, Camelia Draghici, Adriana Puhacel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25458

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract Knowledge of the binding mechanisms of heavy metals to cement minerals is essential for the prediction of the long-term leachability of cement-based solidified waste containing heavy metals. In this paper, the sorption of chromate ions onto calciumsilicate- hydrate (C-S-H) in equilibrated aqueous suspensions was investigated as a function of liquid-to-solid ratio. The hypothesis of super-equivalent adsorption was assumed to be involved in chromate ions immobilization. This hypothesis...
Autori: Constantin Bobirica, Ionel Constantinescu, Liliana Bobirica,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25478

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract In order to reduce the cement content used in concrete production utilization of waste materials for substitution of a part of cement can be considered. In this study, two pozzolanic-waste materials, silica fume and fly ash, are used as a part of cement up to 12% and 40%, respectively in concrete and compressive strength as well as permeability properties were determined. The test results were evaluated by using the response surface method. By keeping the cement content in concrete c...
Autori: Dogan U. Anil, Ozkul M. Hulusi, Ekincioglu Ozgur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25490

Abstract It is known that carbonhydrates are precursors of all bioactive substances we tried in thes paper work to do some investigation on these substances in the environmental area of Iasi. To observe the influence of some chemical mutagens substances on carbohydrates biosynthesis we conducted investigations on plant material (leaves) taken from the Calendula officinalis L species. We used this assay to examine the effects of the herbicide 2,4- dichlorophenoxyacetic acid (2,4-D), etidium br...
Autori: Constantin Leonte, Roxana Vatavu, Teodor Robu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25502

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract This paperwork tried to simulate the combustion inside the naval engines using the newest computer methods and technologies with the result of a diverse and rich palette of solutions, extremely useful for the study and prediction of complex phenomena of the fuel combustion. The paperwork is contributing to the theoretical systematization of the area of interest bringing into attention a thoroughly inventory of the thermodynamic description of the phenomena which take place in the co...
Autori: Nicolae Buzbuchi, Liviu Constantin Stan, Daniela-Elena Mitu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25514

Abstract The idea of sustainable farming relies on raising its yield along with a safe and constant gain with minimum environmental impact and by ensuring the population’s food security. Sustainable agriculture is a large concept that encompasses the complexity of this production system, the biological stability of farming plants and varieties, the conservation and protection of natural resources, but also the implementing and generalization of high-output modern technologies. Sustainable a...
Autori: Brindusa Robu, Carmen Cătălina Ioan, Edinel Robu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25520

Abstract The use of appropriate leaching tests and leaching models can help to predict the hazardous components release from cementbased solidified waste during either utilization or disposal. Numerous parameters influence the leaching rates such as grain size/specimen size,ccc liquid-to-solid ratio, pH value of the leachate, leaching time etc. This study evaluates the effect of initial liquid-to-solid ratio of cement paste on the release of copper from cement-based solidified waste. Dynamic ...
Autori: Constantin Bobirica, Liliana Bobirica, , Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25527

Abstract The paper makes qualitative and quantitative analyses of heavy metal contamination of surface waters in Iasi City. The examination of data acquisited from the specific sections of the rivers Bahlui (upstream section, Iasi water treatment plant, Holboca section, downstream section, Iasi water treatment station), Nicolina (quarterly data from the established monitoring system) was performed, based on data provided by the Environmental Protection Agency of Iasi District and Prut Water D...
Autori: Corneliu Horaicu, Florea Cornel Gabrian, Irina Grozavu, Catalin Constantin Calu, Monica Horaicu, Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25546

Abstract The study contains a theoretical and methodological examination of the relationship between the environmental and economic efficiency of firms. It reframes the crucial question, not whether, but when environmental efficiency improvements are profitable for firms? The paper develops the novel concept of eco - profit and try to identifies three gaps in the previous knowledge: (1) the relationship may not be constant across environmental efficiency levels, which means that it needs to b...
Autori: Luminita Horhota
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25557

Abstract White mustard (Sinapis white) is an annual plant of the Cruciferae family originating from the Mediterranean region and is cultivated in Europe and Asia, mainly for its seeds, but also for animal feed or crop rotation. White mustard seed is also an important source of vegetable oil that can be used as fuel. The chemical composition of mustard seed (Sinapis alba) includes glucosinolate (sinalbozida, sinapina free), essential oils, fatty oils (glycerides of oleic acid, linoleic, linole...
Autori: Camelia Ciubota-Rosie, Rodica Diaconescu, Irina Volf, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25561

Abstract The efficient understanding and application of mathematical models in the study of environmental phenomena keep up with the latest results in the mathematical domain which could provide solutions for controlling, analyzing, predicting and study of risk phenomena. This paper presents a browsing through some mathematical categories of interpreting statistical data, examples and their analysis in connection with the degree of polluting the water down the Danube River with the help of qu...
Autori: Valerian Antohe, Constantin Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25562

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract Ballast water is used to supply stability on ships that have no load. It is loaded on before departure and often carries stowaways in the form of tiny organisms. To avoid that, the ballast water can be treated on board. Treating ballast water to free it from potentially harmful invasive species is a challenging problem. Alfa Laval in cooperation with Wallenius Water has been developed one system that cleans ballast water during ballasting and de ballasting operation. The paper presen...
Autori: Liviu Constantin Stan, Nicolae Buzbuchi, Feiza Memet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25567

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract This work describes the preparation of a hydroxyapatite/polyurethane composite membrane and their characteristics. The porous hydroxyapatite/polyurethane composite membranes were made via solvent casting process. The deposited hydroxyapatite layers were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The data suggest that the method utilized in this work can be applied to obtain deposition of coating of crystalline hydroxyapatite on porous polyurethane...
Autori: Gabriela Ciobanu, Dorina Ignat, Gabriela Carja, Constantin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25572

Abstract In this paper, the capacity of a soil to retain the dye Erythrosine B from aqueous solution by sorption has been studied. Batch adsorption experiments were conducted to investigate the sorption of the dye from aqueous solutions onto soil with particles of different size. Different models were used to describe the kinetic data, to calculate the corresponding rate constants and to predict the theoretical capacities of soil for dye sorption. ...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25573

Abstract This article presents the use of salt water springs in the Moldavian Oriental sub-Carpathians for treating certain diseases, based on archaeological discoveries and ethnographical surveys, correlated with known facts from the literature in the field. Nevertheless, what differentiates it from other similar area in Europe is the intense, unexpected continuity of traditional, nonindustrial water supplying coming from salt springs. Among the uses of salt water and halite in the area, th...
Autori: Ion Sandu, Marius Alexianu, Roxana-Gabriela Curca, Olivier Weller, Constantin Pascu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25574

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The aim of this study is the evaluation of photo-Fenton as a suitable advanced oxidation process to degrade ampicillin and streptomycin antibiotics. The degradation was studied by monitoring the organic substrate concentration changes in aqueous solution as a function of reaction time using COD analysis. The oxidation process follows two successive stages. In the first stage (I) the oxidation of the antibiotics takes place with high reaction rate, leading to intermediate oxidation pr...
Autori: Cristina Orbeci, Daniela Simina Stefan, Ion Untea, Madelene Dancila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25602

Abstract Characterization of soil permeability is of great importance for several geotechnical analyses. In common practice, because of the difficulty in sampling of granular material, constant head permeability tests are usually employed on specimens having similar relative densities to those in the field. An alternative approach to permeability tests for granular soils is the prediction of permeability levels by means of empirical equations depending on several particle size distribution an...
Autori: Alper Sezer, Burak A. Goktepe, Selim Altun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25609

Abstract The Air Quality Management problem calls for detailed, case-specific knowledge and requires, due to legal mandates, the development of operational, environmental parameter related, incident forecasting. Both targets can be met by applying Artificial Intelligence (AI) methods, and by employing relevant computational algorithms that are capable of producing reliable results. The current paper provides with an overview of the problem domain, identifies goals and proposes methods that ma...
Autori: Kostas D. Karatzas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25616

Abstract In this study, the effect of adding granular activated carbon (GAC) to aerobic sequencing batch reactor (SBR) on possibility to treat a wastewater containing a reactive dye (Brill Blue KN-R) was investigated. Experiments were performed in four cylindrical Plexiglas reactors for 68 days (5 days for acclimatization of sludge and 63 days for normal operation in two separate phases). Initial dye concentrations were adjusted to 20, 25, 30 and 40 mg/L in the reactors R1, R2, R3 and R4, res...
Autori: Amir Asadi Vaigan, Hossein Hashemi, Mohammad Reza Alavi Moghaddam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25624

Abstract Finding solutions to the waste problems generated by human activity represents a high concern of authorities and environment specialists for many years. Furthermore, energy conservation and reduction of the dependency from fossil fuels represents a top priority of governmental organizations at world level. The developments in alcohol industry have resulted in the increase of wastewaters which are highly polluted with organic substances, causing environmental pollution hazards. A wide...
Autori: Carmen Mateescu, Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25626

Abstract The olive mill wastewater (OMW) is a stable emulsion composed by water, olive pulp and residual oil. An approach for using this waste as a renewable resource is of greater interest. Several authors have been studding physicochemical treatment methods. However, the biological treatments allow not only the treatment, but also the effluent valorization, by producing several valuable products. This effluent is also a source of natural antioxidants and its extraction is economically attra...
Autori: Carina Pereira, Cristiana Goncalves, Isabel Belo, Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25635

? SUSTAINABLE CONCRETE HARDENING PROCESSES IN NORMAL CLIMATIC AND THERMAL TREATMENT CONDITIONS ? THE ENVIRONMENTAL DIMENSION ? AN INTERDISCIPLINARY RESEARCH AREA ? MENU PLANNING STRATEGY BASED ON ECOLOGICAL FOOTPRINT ? EVALUATING ENVIRONMENTAL IMPACT OF NIGERIAN COMPOSTED WASTES USING LABORATORY EXTRACTION TEST ? IN SITU RADIOFREQUENCY FIELD LEVEL ASSESSMENT IN TWO URBAN AREAS IN ROMANIA: OPEN QUESTIONS TO ELECTROMAGNETIC POLLUTION ? INNOVATIVE SOLUTION FOR WARNING ON HI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25657

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

Abstract:In this paper the study on the possibilities of converting chopped reed stalk biomass into briquettes is described, in the conditions of harvesting water reed plant from Danube Delta region in winter time and based on briquetting technology used for wood waste from production. The water reed tested in the research has been harvested from Tulcea reed bed, one of the largest in Romania, chopped in a veneer drum chipper and compacted into the hydraulic briquette machine. The paper focuses ...
Autori: Aurel Lunguleasa, Camelia Coşereanu, Constantin - Radu Gheorghiu, Dumitru Lica, Gavril Budău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25734

Abstract:A comparative analysis is drawn on the energetic responses numerically simulated for Brasov, Romania location, delivered bytwo mono-axial pseudo-equatorial STCs (solar thermal collectors): a flat plate STC and a STC with heat pipes; the two systemsare destined for future implementation on Transilvania University Campus. Accordingly, two tracking programs are consideredfor the diurnal motion: a) of 1h constant duration steps, for school courses interval (September-June) and b) 1-step pro...
Autori: Maria M. Vatasescu, Veronica E. Dombi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25740

Abstract:The national legal framework harmonization, including in areas concerning environmental protection, with the Europeanstandards in the field, is a goal of paramount importance with regard to Romania's accession to the EU structures. From thisperspective, all the organizations, agencies and individuals operating in this field must be acquainted with the European Union'sprograms of environmental action.In this context, the paper aims to provide an overview of the relevant trends and develo...
Autori: Constanţa Enea, Constantin Enea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25742

Abstract:Ash is a waste that can be an efficient substrate in wastewater treatment for the immobilization of heavy metals and for dyesremoval. For an up-scalable wastewater treatment process, efficient substrates, with relatively constant behavior are needed andmodifying the adsorbent surface can be a feasible solution. Fly ash, resulted from coal burning, and wood ash are mixtures mainlycontaining metal oxides and carbon in various proportion, depending on the initial raw material.The paper pre...
Autori: Maria Visa, Mihaela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25771

Abstract:The oxidation of low grade complex concentrates (Cu, Pb and Zn) in aqueous media (weak alkaline) oxidized nonferrous metalsconcentrates is carried out at high pressure. Leaching is the subsequent processing step in metal extraction. The paper studies theinfluence of some parameters (temperature, time, L:S ratio, excess) on the leaching efficiency of nonferrous metals from oxidizedconcentrate. The optimum parameters determined are: S/L ratio of 10/1, 25% reactive excess, leaching tempera...
Autori: Cornelia Lupu, Dragoş Taloi, Liliana Gherghe, Luminita Mara, Teodor Velea, Vasile Predica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25774

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:The paper describes some studies on the influence of water flow rates through water-supply networks on drinking water quality. Water residence time in pipelines for more than seven days in buried pipes and two days in above-ground pipes promotes the development of biochemical systems when the flow rates are low and very low having detrimental consequences on drinking water quality. These shortcomings are due to the residual chlorine decrease below the allowed technical limits (0.5 m/s) ...
Autori: Adrian Carabeţ, Alina Gîrbaciu, Constantin Florescu, Cristian Stăniloiu, Ion Mirel, Irina Olaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25799

Abstract:Coconut coir pith, an agricultural solid waste was used for the sorption of Cd (II) from aqueous solution in batch mode. Parameters like contact time, adsorbent dosage and pH effect were studied. Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data and the system followed both the isotherms. Cd (II) adsorption capacity of coir pith was found to be 18.72 mg/g. Kinetic parameters of adsorption such as the Langergren pseudo-first-order, pseudo second order r...
Autori: Nagendra Badabhagni, Puthiya Veetil Nidheesh, Rajan Gandhimathi, Srikrishnaperumal Thanga Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25800

Soil hydraulic characteristics are variable, being influenced by climate changes. Research conducted until now in this area has been based on field soil sampling; their laboratory analysis using experimental techniques; and the use of models and programs for data processing and interpretation. The present research is based on the idea of incorporating smart sensors on site, each one having its own network address, accessible for any location. They can be programmed to send an alarm signal when t...
Autori: Constantin Victor Stătescu, Dorin Cotiusca Zauca, Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25831

Human nature constantly tends to place personal interest first, to the detriment of general interest. In this respect, tax and duty payers have always attempted to evade payments on their tax liabilities, resorting to various tactics, as they view such compulsory payments as detrimental to their wealth and income. On the other hand, the state seeks to maximise its receipts from taxes, duties, excises etc. In Romania, after 1990, an entire range of anti-tax reactions occurred in the sphere of pub...
Autori: Carmen Sandu, , Marius Vorniceanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25835

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

Polycyclic aromatic hydrocarbons (PAHs) are by-products of petrol transformation; a report prepared by ICON, London, United Kingdom in 2001, showed that the principal sources of polycyclic aromatic hydrocarbons in wastewater are domestic usage, storm runoff and commercial effluent. This work presents the results on 14 commonly occurring and/or highly carcinogenic PAH compounds listed as priority pollutants by the United States Environmental Protection Agency and the European Union. Wastewater sa...
Autori: Dumitru Ristoiu, Edward Muntean, Livia Alhafez, Nicoleta Muntean, Radu Mihaiescu, Tania Mihaiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25847

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

The most important argument of this experiment was to demonstrate an increased content of active principles under the influence of some substances (considered in the literature as mutagene), when used in low concentration, do not affect the environment. The purpose of this study was the selection of some treatment variants, which, during the experimentations show the same biosynthetic potential, stabilized or increased. The substances used in the experiment were ethidium bromide at the concentra...
Autori: Constantin Leonte, Marius Zaharia, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25867

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Among the different types of waste products tested, the bark of different Pinus species have been identified as a promising class of low- cost sorbents for heavy metal binding. In this context, the potential of Romanian pine bark wastes as green and economical sorbent for cadmium (II) ions removal from aqueous solutions has been tested in batch conditions as function of initial pH, contact time, sorbent dose, metal ion concentration and temperature. The equilibrium data at three different temper...
Autori: Anca Miron, Brindusa Robu, Carmen Paduraru, Lavinia Tofan, Roxana Laura Mihailescu Amalinei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25871

Measurements of radium concentrations in water are important from the health protection point of view, so simple and reliable analytical methods must be available. In this paper we have determined the radium activity concentration in 24 spring waters which are used as potable water reservoirs. For this purpose we used radon emanation technique and also alpha spectrometry method. This work gives details of sample processing, Lucas cell and the methodology used in the emanation method. In the meas...
Autori: Alida Timar Gabor, Constantin Cosma, Oana Alexandra Rusu, Robert Csaba Begy, Simina Dreve
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25878

This research investigates the influence of certain vitamins (A and D2) on the possibility of hydroxyapatite formation on polymer surfaces. A coating method based on biomimetic techniques was used to form a crystalline hydroxyapatite thin layer on porous polyurethane matrix. The method is based on a wet process of hydroxyapatite formation that involves porous polyurethane film soaking in a modified synthetic Simulated Body Fluid (SBF) solution. This modified SBF solution contains vitamin A and v...
Autori: Alina Costina Luca, Constantin Luca, Gabriela Ciobanu, Simona Ilisei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25884

The herbicide use can be seen as an auxiliary path for new farming methods, providing more advantageous farming and land use capabilities and increasing crop yields. Some of them are quickly degraded but others persist in the environmental compartments being toxic for human health and the environment.The aim of this study was to evaluate the impact of some triazine herbicides from agricultural sources on quality of well and surface water, in two regions of Romania with different agricultural act...
Autori: Andreea Dragus, Mihail Simion Beldean-Galea, Radu Mihaiescu, Tania Mihaiescu, Dumitru Ristoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25889

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

Four processes have been used to enhance the ozonation of phenol in water: I-pH increasing (O3-pH), II- hydrogen peroxide addition (O3- H2O2), III- UV irradiation (O3- UV), and in the presence of both H2O2 and UV; IV-(O3- UV- H2O2). In each of these processes the rate of phenol degradation has two components: direct and indirect....
Autori: Eszter Arany, Ildiko Bartalis, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25904

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractEnforcement is a crucial final step in any policy process, including environmental policies. Ideally policy formulation issubsequently implemented and enforced. Enforcement is needed to make sure that the envisioned effects are realized in the end.The questions we put forward in this paper are what the meaning of enforcement is; how enforcement can be put on the politicaland administrative agenda; what difficulties are to be countered when strengthening enforcement at the local level. We...
Autori: , Theo de Bruijn, Vera Vikolainen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25980

AbstractA case-control study was conducted in two Romanian counties (Alba and Cluj) in order to investigate lung cancer risk due toresidential radon exposure. Two hundred and forty-one subjects were included, of which 104 cases and 137 controls. Residentialradon concentrations were monitored using CR-39 track detectors, exposed over a period of at least 6 months. The odds ratioswere estimated by using multivariable logistic regression adjusted for age, sex, smoking status, education and family h...
Autori: Alexandra Cucoş Dinu, Constantin Cosma, Dan Rădulescu, Doina Todea, Dorin Iancu, Ionel Papuc, Loredana Roşca, Mircea Rişteiu, Tiberius Dicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26011

AbstractWaste management includes all activities of collection, transport, treatment, recovery and disposal of waste, includingsupervising of such operations. The framework law that regulates waste management activities in Romania is Law no. 27/2007,approving Government Emergency Ordinance no. 61/2006, amending and supplementing Government Emergency Ordinance no.78/2000 on waste regime. This legislation sets the responsibilities for waste management from generation to disposal, thepriorities in ...
Autori: Constantin Mircea Orlescu, Ioana Alina Costescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26020

AbstractLake Taihu is a shallow, wind-driven lake where eutrophication is always a serious problem. The study presented hereininvestigates the effect of wind on the eutophication of the lake, by using a two-dimensional (2D) hydrodynamic model coupledwith a 2D water quality model. The 2D water quality model looks in particular at the water quality situation of Lake Taihu in theyear 2008 and predicts future changes in the algae bloom situation. The Delft3D modelling tool was used to build thehydro...
Autori: Arthur Mynett, Chao Yue, Ioana Popescu, Leo Postma, Quan Pan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26037

AbstractThe paper intends to contribute to the stages of bioremediation technologies elaboration, by means of experiments and efficiencydemonstrations of adequate biological depollution and ecological reconstruction methods. During the 2009-2011 period, heavymetals and metalloids, etc phytoextraction tests were performed with Lolium perenne L, from tailing samples collected fromwaste heaps and tailings dams of the mining exploitations (Rodna, Bistriţa–Năsăud, Fundu-Moldovei, Sucea...
Autori: Alexandru Crihan, Alin Bolonyi, Bianca Malschi Florian, Cecilia Roman, Dana Malschi, Dorian Brăhaiţa, George Ghira, , Marin Şenilă, Mirela Miclean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26044

AbstractDefinitive transition to GNSS technology of achieving geodetic networks for cadastre implementation in cities and municipalities,enforce establishing a unique way of linking between current measurements and existing geodetic data, with a sufficient accuracyproper to urban cadastre standards. In this paper the parameters calculation is presented, for coordinates transformation of thespatial geodetic network points in local datum, starting from different determination methods of network po...
Autori: Constantin Chirilă, Raluca Maria Mihalache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26051

AbstractActing on the recommendations of the Commissioner for Education, Culture, Multilingualism and Youth - Androulla Vassiliou,EU politicians agreed, at the European Council in Brussels - 2010, that education and training are vital for development and thesuccess of society and the current knowledge-based economy. Educational partnerships among all stakeholders engaged ineducation are increasingly important, while teachers and all the professionals involved in training young people must suppor...
Autori: Carmen Olguţa Brezuleanu, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26052

AbstractA simplified numerical model of the water distribution network of a medium sized town (with 30,000 inhabitants), of elongatedshape, was implemented in EPANET. The decay of chlorine residual concentration in the above mentioned network was studied,using the extended time analysis capabilities of EPANET, for a 3 days period. The water supply system, composed of one tank, 86pipes and 52 nodes is driven by gravity. The chlorine is injected at the tank with a constant concentration amount. Th...
Autori: Andrei-Mugur Georgescu, Sanda-Carmen Georgescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26054

AbstractThe paper presents the application of cross-spectrum analysis (CSA) to air pollution and meteorological time series collected fromseven air quality monitoring stations located in three urban agglomerations of Romania, affected by industrial and trafficpollution: Braşov, Ploieşti and Târgovişte. Data have been collected from November 2011 till March 2012, at one hour samplingrate. The purpose of the analysis was to reveal the correlations between two series at different fre...
Autori: Ştefania Iordache, Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26057

AbstractIncreasing the labor force employment and participation rates is sustained by capitalization of human opportunities existent inrural areas. This entails a flexible and inclusive labour market and a decreasing rate of exclusion for some rural groups.This paper highlights the need of facilitating the access to the labour market by achievement of professional skills needed in nonagriculturalsectors from rural areas for the vulnerable groups as well as the entrepreneurial groups. The analysi...
Autori: Carmen Olguta Brezuleanu, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26059

AbstractThe role of human resources in agricultural exploitations proved to be an essential matter due to the decisive influence on theagricultural crop efficiency and production results. There exist particularities regarding the calculation of the human resourcesnecessary in vegetal crop production, animal husbandry and other activities connected with agriculture. From an economicalfinancialpoint of view, the analysis of human resources efficiency is based on two indicators, as follows: labour ...
Autori: Carmen Olguta Brezuleanu, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26068

AbstractThe removal of residual oil from palm oil mill effluent (POME) using boiler fly ash was studied in this paper, with focus on theadsorption isotherms and kinetic studies by measuring the residual oil concentration using UV-spectrophotometer. The percentresidual oil adsorbed decreased from 80% to 5% as contact time was increased from 10 mins to 120 mins but increased from2.74% to 72.98% as initial concentration of residual oil increased from 0.04812 mg/L to 0.2406 mg/L. Pseudo-second order...
Autori: Jude C. Igwe, Stella N. Anioke, Uche Arukwe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26078

AbstractThe present study was focused to classify various advanced oxidation processes (AOPs) to degrade sixteen commonpharmaceuticals and personal care products (PPCPs). The classification was based on the degradation rate constant (h-1).Chemometric techniques like principal component analysis (PCA) and cluster analysis (CA) were used to classify AOPs whichcan efficiently degrade a certain class of PPCPs. The bipolt based on first two principal components (PCs) of PCA modelidentified two distin...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26085

AbstractTwo laboratory-scale constructed wetlands planted with Juncus effusus were used to investigate the effect of nitrate load on thesulfur transformation dynamics related to the removal of organic carbon and ammonium. Organic carbon was removed at aconstant high mean level of 80% (inflow of 25 mg/L total organic carbon), irrespective of the nitrate load. In contrast, sulfatereduction responded immediately to the presence or absence of nitrate in an opposing manner, indicating a high abundanc...
Autori: Shubiao Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26095

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

The ELSEDIMA International Conference on “Environmental Legislation, Safety Engineering and Disaster Management” held its 9th edition in 2012. This edition was organized by the “Babeş-Bolyai” University of Cluj-Napoca - Faculty of Environmental Science and Engineering, together with the Ministry of Administration and Interior - General Inspectorate for Emergency Situations, the Disaster Preparedness and Prevention Initiative for South – Eastern Europe and S.C. I...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26102

Abstract The cultivation of Miscanthus sinensis x giganteus on a polluted soil near Copsa Mica – Romania has started in 2008. Since then every March and August the roots and stems have been analyzed, showing a very low amount of heavy metals in the aerial parts in February, when the harvesting takes place. The combustion properties of the material are similar to those of lignite, but without sulphur and with low ash amount. Because cultivation of edible plants poses the risk of hea...
Autori: Constantin Horia Barbu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26106

Abstract This study focuses on the local scale behavior of SO2 emissions resulting from lignite-combustion thermal power plants. The investigations aimed at monitoring the SO2 emissions and imissions over a two week period in September 2010. One of the largest power plants from Eastern Europe was chosen for monitoring using different optoelectronic techniques. Rovinari power plant (44o54’45”N – 23o09’44”E) is one of the largest electricity suppliers of Romania, having 4 groups of 3...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26113

Abstract Waste recycling represents a very significant issue for the protection of our environment. Large waste quantities (slag and ashes) are products of the coal extraction industry and its subsequent combustion in thermal power stations. The possibilities of obtaining crystallized glasses in the CaO-Al2O3-Fe2O3-SiO2 system by introducing in the raw materials mixture ashes from Mintia Deva thermal power station have been studied. The physical and chemical characterization of the...
Autori: Firuţa Goga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26121

Abstract Being constantly surrounded by sound, in most cases we operate ignoring this “environmental noise”, but when the noise intensity increases, it becomes a pollutant, adversely affecting the level of professional performance, leading to fatigue, causing nervousness or decreasing the quantitative and/or qualitative level of performance. The main objective of this paper is to evaluate the noise problem in the Strand district of Sibiu and to highlight the negative effects affect...
Autori: Valentin Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26131

Abstract In a world of uncertainty, the only constant is change and rapid change produces a multitude of diverse facts. Risk is an integral part of life. While no country in the world is entirely safe, the lack of capacity to limit the impact of hazards remains a major burden for all countries and while the world has witnessed an exponential increase in human and material losses due to natural disasters, there is a need to reverse trends in vulnerability to earthquakes. Available d...
Autori: Gheorghe Mărmureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26140

Abstract Avocado post-harvest losses and cultivar-oriented trade are relevant issues in Cameroon that affect producers and retailers incomes. Identifying specific chemical characteristics of avocado oils would give an added value to underutilized species. Five avocado varieties, Booth 7, Booth 8, Collinson, Hickson and Lula, were subjected to aqueous extraction and the Attenuated Total Reflectance-Fourier Transformed Infrared spectrometry coupled with chemometrics (ATR-FTIR) profil...
Autori: Brice Ulrich Saha Foudjo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26143

AbstractBehaviors of adsorption of di-n-butyl phthalate (DBP) on humic acid and the effects of temperature on these processes are studied by solid phase extraction-HPLC method. The results show that the adsorption amounts of DBP increase with increasingequilibrium-concentrations of DBP. Such results could be well described by Langmuir equation. The maximum adsorptionamount (Qmax) and adsorption constant (k) at 35oC were both lower than those at 25oC. Thus, high temperature is unfavorable to the ...
Autori: Zhi-dang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26162

AbstractThe Iraqi Marshlands, the largest wetland in the Middle East and one of the most outstanding in the world have been lost mainlyas result of drainage and damming. This study analyzed the dynamics of land use/cover change in Iraqi Marshlands Region from1973 to 2011. In this process, we established the land use/cover classification system and remote sensing interpretationcharacteristics. A laminar extraction technique was used in the identification of typical attributes of land use/cover ty...
Autori: Hongxia Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26168

AbstractThe solidified waste drilling mud has been landfilled into slurry ponds with impermeable layer at oil & gas field since 1990s. Thisarticle aims to elucidate the heavy metal contaminations from landfill ponds at semiarid region. The heavy metal concentration inthe waste and its potential mobility based on its binding forms was studied. Furthermore, the blocking effect of impermeable layer was used to elaborate the environmental effects of heavy metals. From the analysis, Cr was found ...
Autori: Yun Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26171

AbstractGlobal energy demand is following a strong upward trend. As highlighted by the latest analyses the overall black coal resourcesare able to satisfy human needs for more than 200 years including the particular case of intensive exploitation. According to theInternational Energy Agency (IEA) renewable energy and natural gas resources have encouraging perspectives for furtherexpansion. Even so coal will continue to cover almost a quarter of primary energy resources needs. The EU is currently...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26199

AbstractLow water quality due to high levels of ammonia, chemical oxygen demand (COD), abnormal pH, and undesirable water color isprevalent in many prawn ponds in Malaysia. A composite medium used in the treatment of prawn pond effluent was examinedfor the reduction of undesirable parameters. The composite medium is a mixture of limestone, activated carbon, zeolite, and ricehusk. Experiments were conducted under three different conditions, i.e., sole aeration, adsorption, and adsorption with pre...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26219

AbstractFluoride content in some available teas, dry leaves and tea infusions were determined, in order to check the influence of brewingtime on fluoride content in tea and to compare the percent extraction of fluoride releasing during tea infusion time. A fluoride ionselective electrode was used to determinate the fluoride content in tea samples (Hypericum perforatum, Tilia cordata andCamellia sinensis). Total fluoride contents of tea leaves were determined to be 91.1 - 162 mg/kg d.w., and 0.09...
Autori: Semaghiul Birghila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26242

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractThe purpose of the undertaken research work is to degrade the biopolymeric pigments present in the distillery spentwash. This isdone by direct electro-oxidation using iridium oxide coated titanium mesh as catalytic anode. The effects of current intensity,dilution, pH and time of electro-oxidation were studied. The combined effects were analyzed using Box-Behnken design foroptimization and statistical analysis. The rate constant for first order electrochemical kinetics relating the rate c...
Autori: R. Krishna Prasad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26253

AbstractThe aim of this study is to analyze the surface-ozone concentration mass variations in Bucharest for the 2005-2007 period. Data files from eight urban sites in Bucharest area were processed to extract the surface-ozone features. Generally, the results have shown that the highest values of surface- ozone concentrations are in the summer and in the afternoon, as in the literature. The smallest values are in December and January in all the three years. Monthly mean concentrations have shown...
Autori: Constantin Rada, Cristian Necula, Laurentiu Zagar, Raluca Barladeanu, Sabina Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26275

AbstractIn the present paper, support vector machines (SVMs) are used to develop a quantitative structure-activity relationships (QSAR) model for the reaction rate constants (-logkNO3) of 115 heterogeneous organic compounds, through reaction with nitrate radicals (NO3•) in the troposphere. Two quantum chemical descriptors used as the inputs for the SVM model were calculated with density functional theory (DFT), at the B3LYP level of theory with 6-31G(d) basis set. The best predictions were obtai...
Autori: Bing Yi, Jiyong Deng, Xinliang Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26284

AbstractThis study aims to investigate the environmental impacts of the municipal waste disposal facility of Pata Rat, Cluj-Napoca, Romania during dry periods of the year. The environmental impact assessment on the landfill site was carried out on the basis of the measurements of environmental quality indicators. Environmental indicators were measured in the surface water, soil and air. For the assessment of the environmental impacts generated by landfill on surface water measurements were carri...
Autori: Ákos Rédey, Anca Gurzau, Antoanela Popovici, Constantin Măruţoiu, Fazekas Bence, , Ildiko Varga, Raluca Mariana Haţegan, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26296

AbstractThe road infrastructure has a major environmental impact by covering important land surfaces and consuming enormous amounts of raw materials for construction and maintenance. The impact of transport pavements needs to be considered from the design stage and to be examined during the whole life cycle of the infrastructure: raw materials extraction and initial transformation, manufacturing, placement on site, exploitation, maintenance, and demolition. This paper evaluates the impact of asp...
Autori: Isabela Maria Simion, Laura Dumitrescu, Maria Gavrilescu, , Radu Andrei, Sebastian George Maxineasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26297

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractThe distribution and fractionation of nine heavy metals (Cr, Co, Ni, Cu, Cd, Zn, V, Pb and As) in the sediments of Lake Chaohu,a shallow eutrophic lake, were investigated using the BCR sequential extraction procedure. The level of pollution attributed tothese nine heavy metals was evaluated employing the potential ecological risk index (RI) and geoaccumulation index (Igeo). Metalconcentrations in sediments ranged from 65.00~104.00 for Cr, 14.50~21.70 for Co, 28.50~50.90 for Ni, 25.40~51....
Autori: Beidou Xi, Fengyu Zan, Guangchao Zhao, Jing Su, Kevin M. Yeager, Shouliang Huo, Xiujuan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26321

AbstractThe importance of energy sustainability has been constantly growing in scientific, political and economic circles. The reason forthis lies in numerous energy and environmental issues that the entire world is facing on an everyday basis. There are severaltheories about the basic elements of energy sustainability. Nevertheless, the dominant current in scientific circles sees energysustainability as a concept relying on two basic elements: energy efficiency and renewable energy sources. Thi...
Autori: Aleksandar M. Vuckovic, Dejan C. Petrovic, Marko M. Mihic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26349

AbstractA pilot scale Upflow Anaerobic Filter (UAF) treating tannery wastewaters was operated for 160 days. The UAF was fed with lowCOD/SO42- ratio (SO42- = 1810 mg L-1, CODtotal = 2530 mg L-1) for the investigation of sulphate and COD removal as a functionof substrates limitation and ammonia and sulphide inhibition. Sulphate-reducing bacteria (SRB) out-competed methanogenicbacteria due to the low influent COD/SO42- ratio, the high concentration of sulphide and the presence of inhibiting compoun...
Autori: Alberto Mannucci, Claudio Lubello, Giulio Munz, Gualtiero Mori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26353

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractAs environmental problems are of concern in modern times, decision makers, dealing with resource allocation, should considerenvironmental aspects. This paper examines a resource allocation problem confronted by a central decision making unit. Thecentral unit is assumed to be interested in maximizing the total amount of desirable outputs. The optimal scale of production isobtained by allocating available resources to decision making units (DMUs) efficiently under the current production po...
Autori: Gongbing Bi, Tao Zhu, Yan Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26377

AbstractDuring the last decades, the biodiversity conservation became a constant concern for the specialists in environmental resourcemanagement by increasing the awareness of the complexity, fragility and inestimable value of our planet. Nowadays, this issueshould be an ethical duty for all the 7.2 billion inhabitants of the planet. The biodiversity conservation should be approached as amultidisciplinary research field, developed in response to the actual world crisis. In this multidisciplinary...
Autori: Csaba Lorinţ
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26400

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

AbstractThe supply of building materials in the city of Kinshasa is one of the major challenges for sustainable development andespecially at this time when the authorities are committed to rebuild the country and to rehabilitate the basic infrastructure,mobilization and knowledge of these materials appears to be of paramount importance. In this context, the Kinshasa morphologywill change day by day because of the operations of construction materials extraction, to meet the needs of the populatio...
Autori: Holenu Holy Mangenda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26428

AbstractThe changes in fresh water quality are reflected, over time, in the structure of the biocenosis by adjusting the composition, theabundance and the spatial distribution of species, in an attempt to maintain a constant equilibrium. It is difficult to identify thisequilibrium just by analysing the physicochemical measurements because they represent water quality conditions of the moment,while the analysis based on biological indicators which are reflecting the composition of macrozoobenthos...
Autori: Roxana Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26431

AbstractAmong foods that possess potent medicinal properties, Cucurbitaceae seeds stand as a promising source, since they are assumedto have a protective effect against oxidative stress. In order to analyze the antioxidant compounds of the seeds of Citrulluslanatus, Lagenaria siceraria, Telfaria occidentalis, Cucurbita maxima, Cucumis sativus, Cucumeropsis mannii, and Cucurbitamoschata, the dried seeds were extracted in MeOH-H2O (50 %; v/v) mixture at constant mixing rate. Qualitative phytochemi...
Autori: Aristide Guillaume Silapeux Kamda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26440

AbstractThe process of semi-volatile aerosol particle evaporation was studied with respect to both computational and experimentalapproaches. A Sinclair-La Mer type aerosol generator was used to produce monodisperse particles from four n-alkanes(tetradecane, hexadecane, octadecane, eicosane) while particle sizing and FID measurements were applied to quantify particleandvapor mass and their subsequent phase distribution. Aerosol dilution and later stationary analyses in a flow tube at two timeinte...
Autori: George C. Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26448

AbstractIn this study, the reduction of phenolic compounds and other organic pollutants from greenish black (GB) and dark brown (DB)olive mill wastewater (OMW) was investigated. Ultrasonic irradiation in combination with aerobic biodegradation was adoptedas the treatment technique. Operational parameters such as the duration of ultrasonic irradiation, ultrasonic power intensity andultrasonic frequency were tested to determine their effects on phenol, BOD, and COD degradations. It was found that ...
Autori: Zakaria Al-Qodah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26484

AbstractVegetables are an important part of a healthy diet because of their nutritional value. Contamination in vegetable may provehazardous for population. Polycyclic aromatic hydrocarbons (PAHs) are compounds widespread in the environment, many ofthem showing carcinogenic effects. These compounds can reach the food chain by different ways and, therefore, the analysis ofPAHs in food is a matter of concern.The present work provides data regarding levels of PAHs: acenaphthene (Ace), acenaphthylen...
Autori: Alina Soceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26510

AbstractThe mining waste facilities in the Baia Mare region, Romania, resulted from the extraction of poly-metallic ores (including Au,Ag). Metal sulphide minerals from the mining waste facilities have a potential to produce acid rock drainage (ARD) and togenerate risk for the environment, including for the water resources. Some of the mining waste deposits from the region arelocated near the town of Baia Mare, close to the residential areas, the agricultural lands and the surface water. The sho...
Autori: Oana-Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26512

AbstractTwo types of nanofiltration membranes had been used to study the influence of cross flow velocity on the membrane filtration ofdenitrification effluent (NF270 and NF90). Filtration had been conducted at constant transmembrane pressure of 5 bar andvariable cross flow velocity (0.03, 0.06, 0.15 and 0.39 ms-1). The obtained normal flux was 0.47, 0.58, 0.59 and 0.77for NF270membranes and 0.35, 0.38, 0.41 and 0.39 for NF90 membranes, the increase in cross flow velocity had enhanced fluxperfor...
Autori: Abdel Halim Fuqaha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26523

AbstractIn European countries with temperate climates, heating represents approximately 70% of the total energy consumption of aresidential building. Different Directives of the European Parliament and Council prescribe the enhancement of energy efficiencyand the reduction of energy demand of buildings. Consequently, the control of delivered heat is indispensable. The properoperation of the control system is possible only for balanced central heating systems. In the case of central heating syste...
Autori: Sándor Hámori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26537

AbstractThe problem of noise levels in the home is of increasing interest for reasons of health and psychological well-being, amongothers. This study analyses in detail the meta-data compiled in the Spanish Census of Population and Housing, which provideddata on a large number of environmental variables, including noise pollution in the home. A geostatistical study is conductedfrom the data provided by the latter survey, in which spatial autocorrelation is measured by analytical techniques by us...
Autori: María-Dolores Huete-Morales
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26575

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract This study evaluates the potential of Crambe abyssinica press cake, a residue from crambe oil extraction and/or biodiesel production, as an adsorbent for removal of cationic dyes from wastewaters. Batch adsorption tests were performed at 30, 40 and 50oC. Adsorption kinetics and equilibrium were satisfactorily described by the pseudo second-order and Freundlich models, respectively. Adsorption was spontaneous and exothermic. Fixed bed adsorption (breakthrough curve) was satisfactoril...
Autori: Adriana S. Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26597

Abstract Due to its very low moisture content, the solid waste from the two-phase olive oil extraction process (dry olive mill residue, DOR) can be easily stored and used as a readily available basal liquid culture medium via its reconstitution with water. Five white-rot fungi (namely Phanerochaete chrysosporium NRRL 6361, Lentinus tigrinus CBS 577.79, Pleurotus pulmonarius CBS 664.97, Phlebia radiata DABAC 9 and Botryosphaeria rhodina DABAC P82), previously selected in a screening program, ...
Autori: Alessandro D’Annibale
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26598

Abstract The feasibility of catholyte-conditioning to enhance the electrokinetic (EK) remediation of cobalt and lead polluted soil has been investigated in this study. Electrokinetic experiments were conducted using an EK cell 10 cm in width, 10 cm in height, and 50 cm in length. Plate type electrode of graphite was used as electrode material. Two experiments were conducted under constant voltage condition (2 V/cm). The pH values of the soil significantly affect the removal of Co and Pb ions...
Autori: Mahdi Bahemmat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26623

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract The environmental impact assessment (EIA) is a compulsory evaluation instrument for environmental management and decision making processes and applies to different phases of activities (plans, programmes, projects and /or existing production or services), because it measures the natural and anthropogenic activities effects upon the environment. These impacts may affect the cultural richness, biodiversity, social-economic conditions and human health as well as the ecosystem equilibri...
Autori: Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26645

Abstract The caraway (Carum carvi L.) samples were collected from little meadows situated in Harghita Mountain (Mădăraş Ciuc, Harghita Băi, Jigodin, Tuşnadu Nou), where a relatively small area was covered by a group of rich populations of wild cumin. The harvested plants are dried by: a) convective laboratory dryer in thick layer, b) static outdoors in sunshine, and (c) static in a warm indoor place in darkness. The hand-picked seeds were separated from debris by sie...
Autori: Csaba Dezső András
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26646

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract Adsorption equilibrium and effective diffusion coefficients of water vapor, in cylindrical particles of activated alumina (A) and activated alumina impregnated with calcium chloride (MCA), are experimentally determined. The experiments were conducted at 303 K and 323 K using cylindrical particles with 2.5 mm in both length and diameter. Diffusion coefficients were determined from the kinetics of water sorption. The measurements were conducted in a constant pressure unit based on a m...
Autori: Eugenia Teodora Iacob Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26665

Abstract The transformation of lentic ecosystems in other types of ecosystems (plain, forest) is a part of normal process of ecological succession that occurs slowly, at geological scale. The filling of cuvette with eroded material transported by precipitations, air masses or detritus produced in situ, start from the moment when the body of water lakes is formed and has different rates depending on many factors: geographical location, geological substrate type, types of existing uses in the ...
Autori: Ofelia Axinte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26672

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Supercritical fluid and ultrasound assisted extractions were applied as a first step in a complex processing of spruce bark in order to recover polyphenols compounds. The aim of the study was to compare the efficiency of these "green" processes with a conventional extraction technique (ethanolic extraction). Supercritical fluid extraction was carried out in two steps: (i) static extraction for 15 min at 1000 psi with pure CO2 and (ii) dynamic extraction for 45 min at 35, 4...
Autori: Adina Iulia Talmaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26680

Abstract In the process of chitin extraction, shrimp shell powder was treated by Lactobacillus plantarum culture. The efficiency of microbial demineralization (DM) under aerobic and anaerobic conditions was investigated. The shrimp shell powder was incubated at 30 °C for 6 days with L. plantarum. In order to prepare microbial culture, inoculums size was 5% for culture inoculation. Date syrup with total reduce sugar concentration of 30 g.L-1 was used. The value of pH in anaerobic conditio...
Autori: Marjan Khorrami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26692

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Total anthocyanins were extracted from six sweet cherry cultivars grown in Sakarya, Turkey. In vitro inhibition effects of the extracted total anthocyanins on purified carbonic anhydrase I and II were investigated using CO2 as a substrate. All the extracted total anthocyanins inhibited the activity of the human carbonic anhydrase (hCA) I and II enzymes. Among all the cultivars, ‘Karakiraz’ was found to be the most active on both hCA I (IC50 = 30.59 μg/mL) and hCA II a...
Autori: Taki Demir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26715

Abstract The objective of this study was to identify differences between three of the most conventional UV-based advanced oxidation processes, namely photolysis, UV/TiO2, and UV/ZnO for the decolorization and mineralization of reactive red 198 (RR198) model dye in saline media. The study investigated influences of solution pH levels, salt concentration, reaction time and dye concentration on the degradation of RR198. The most effective dye removal and mineralization was observed at pH levels...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26724

Abstract Chitosan was cross linked with gluteraldehyde and chemically modified by introducing xanthate group onto its backbone using carbon disulfide under alkaline conditions. This crosslinked xanthated chitosan flakes (XC) was used as an adsorbent for the removal of mercury ions from contaminated water streams near the coal mines. XC was found to be far more efficient than the conventionally used adsorbent activated carbon. FTIR studies indicated the interaction both amine and the xanthate...
Autori: Avinash Gupta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26725

Abstract Response surface methodology and central composite experimental design were used to model and optimize the operational parameters of the excess sludge protein extraction yield by ultrasonic wave-assisted extraction. The three variables involved in this research were the ultrasonic extraction time, pH, and temperature. In the range studied, statistical analysis of the results showed that selected variables had a significant effect on protein extraction yield. The optimized extraction...
Autori: Yulin Xiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26736

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract An experimental study of mixing in autoclave vessel equipped with an anchor impeller was performed on the sludge proceeding from the treatment of mixed municipal and industrial wastewater. This unit operation is part of a process for the recovery of sludge. The mathematical modelling of the mixing was done having in view the scaling-up of this process. The mathematical model allows the calculation of the mixing power N as a function of the impeller diameter d, the vessel diameter D,...
Autori: Ancaelena Eliza Sterpu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26744

Abstract The aim of this paper is to determine the heat of combustion of plastic wastes resulted from municipal solid waste, automotive shredder facility waste and building and construction waste. The plastic wastes have been separated by flotation technique using as flotation media: water, ethanol, their mixtures and magnetic fluid. Resulted fractions have been analyzed aiming to determine the most effective fraction from the heat of combustion point of view. The obtained results have been ...
Autori: Liviu Costiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26750

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract In this paper, the structure and working principles of a microbial fuel cell (MFC) are analysed, and a mathematical simulation model of MFCs is established based on the electrochemical equation, kinetic equation and material balance equation of a MFC. A simulation analysis and discussions are conducted in a MATLAB environment to investigate the effect of acetate concentration, influent flow and external resistance on the performance of a MFC system. The simulation model is demonstra...
Autori: Aimin An
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26803

Abstract Vacuum-tube thermal collectors are used to collect heat radiated by the sun. This heat is then used to drive the forced evaporation of concentrated seawater (saltwater) released by reverse osmosis and the extraction of NaCl. This paper reports heat consumption during evaporation. About 78.90% of seawater has to be evaporated in advance through insolation to initiate forced evaporation. This step is conducted to precipitate the NaCl because only CaSO4·2H2O are initially precip...
Autori: Huaigang Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26813

Abstract Urban Tree Canopy (UTC) is an important asset in the urban ecological system by reducing the heat, runoff and improving air quality. Estimating the available urban tree canopy is important for decision makers for better understanding of urban ecosystems and helps to improve environmental quality and human health in urban areas and plan conservation activities. This paper reports on an object-oriented tree extraction method developed by using spectral and textural information of High...
Autori: Muneeswaran Mariappan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26858

Abstract This study concentrates on the reactive biosorption of dyes such as Reactive Red 3:1 (RR3:1), Reactive Orange 13 (RO13), Reactive Blue 13 (RB13), Reactive Blue 72 (RB72). The modified fungal biosorbent, Paecilomyces sp., had a higher dye biosorption yield in our study. 100% of biosorption yield observed on RR3:1 and RB13 and 94.09% of color removal of RO13 with the chemically modified biosorbent were great. Also, such modified biosorbent exhibited remarkable performance in simulate...
Autori: Ahmet Çabuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26860

Abstract Municipal (urban) wastewater treatment creates environmental problems, especially in urban areas where urban waste water and industrial waste water have a common treatment system. The present paper aims at describing a method which facilitates the mixing of resulting sludge with metallurgical coke in the process of iron agglomeration due to the heat input brought about by the combustibles in their composition. This method may be applied to reduce the huge quantities of sewage sludge...
Autori: Catalina Iticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26870

Abstract The adsorption of phosphorus (P) on sediment plays a significant role in phosphorus transport in aquatic systems. This research examined the effect of the main components of sediments (including iron (Fe), manganese (Mn) oxides and organic matter (OM)) on P adsorption and to evaluate their relative contribution with different sediment particle sizes. The sediments were separated into four particle-size fractions: 0-30 μm, 30-62 μm, 62-90 μm, and 90-125 μm, and then selec...
Autori: Yang Xiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26873

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract This paper presents the results of electrocardiography (ECG) signal acquisition, the heart rate variability (HRV) extraction method and the statistical processing of the extracted features on human exposed below the maximum level of exposure of the electromagnetic field. The ECG recordings were acquired in common situation of electromagnetic fields exposure occurring in hospitals: the power line supply (50 Hz), the fluorescent lights tubs (5 KHz - 150 KHz) and the electrosurgical un...
Autori: Narcis Iulian Adochiei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26904

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Abstract The present study was designed to determine the sound effects of ultrasonic treatment and the biologically mediated extraction of uranium from low grade black shale. Low grade uranium was subjected to fungal treatments assisted by sonication by conventional methods. In situ fungal leaching of black shale with different fungal strains in the presence of molasses as growth substrate resulted in highest leaching yield of uranium by Phoma tropica (57.73%) compared to Penicillium chrysog...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26919

Photodegradation caused by sun irradiation may be of major significance in the natural elimination process of pharmaceuticals and personal care products (PPCPs). The fate of metronidazole (MET) in surface water under solar irradiation was investigated. Several parameters affecting the photochemical degradation rate of MET were investigated, including the initial pharmaceutical concentration, continuous input and the presence of other pharmaceuticals like tinidazole (TNZ) with similar structur...
Autori: Bo Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26928

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

One way to improve the performance of non-thermal plasma (NTP) reactor for volatile organic compound decomposition is by the introduction of ferroelectric materials into the discharge zone of NTP. This paper is a review of the breakthroughs and the current status of the applications of this technology for the abatement of volatile organic compounds (VOCs). It covers the process of energy generation in NTP, VOCs decomposition processes and the effects of critical factors such as type of packed...
Autori: Abdullahi Mohammed Evuti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26948

Ferric sulfate and aluminum sulfate were applied to stabilize the available arsenic in solid waste residue (SWR) from the organic arsenic industry, previously pretreated by the semi-solid Fenton process. NaOH, Ca(OH)2, and MgO were introduced to adjust the matrix pH. Toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), and sequential extraction procedure (SEP) were carried out to evaluate the effect and difference on the fixation treatments of ...
Autori: Li-Fang Hu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26956

The influence of the Black Sea on the continental climate is generally limited, comparatively with other maritime basins. Nevertheless, the influence is important for local scale environment, with several applications in the economy, i.e. building industry, agriculture, forestry. The extension of the Black Sea influence inside the Dobroudja Plateau has been tackled constantly by the Romanian climatologists, the main methodological problem being the low number of meteorological stations in Do...
Autori: Sorin Constantin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26963

Ranunculus rionii and Ceratophyllum demersum develop aquatic dense stands, which lately started to represent a major ecological concern for all the ponds and/or lakes in Romania. The potential relationships between the phytochemical compounds detected in these plant extracts (acids, phenols, heterocycles, alcohols, hydrocarbures) and the allelopathic properties against Gram positive and Gram negative bacterial strains and microalgal cultures were investigated and discussed in the current stud...
Autori: Mariana Lupoae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26971

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

The arsenic removal from aqueous medium was investigated through adsorption by employing finely powdered bark of Pinus roxburghii Sarg. The batch mode laboratory scale experiments were conducted to investigate the removal efficiency of Pinus bark against total arsenic and the effect of pH, contact time, adsorbent dose and initial adsorbate concentration on adsorption to optimize the process. Langmuir and Freundlich isotherms were used to validate the adsorption data and respective constants w...
Autori: Syed Hasnain Shah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27013

The aim of this study was to determine the impact of mercury pollution on soil, surface water, and sediment ecosystems in the area of old mercury mines. The study was performed in the touristic area of Sântimbru Băi and Sâncrăieni villages from the Harghita County, Romania. More than twenty years ago, a mine for the extraction of mercury operated in Sântimbru Băi. The area was decontaminated, but no monitoring studies have been made for over 15 years. During t...
Autori: Luisa Roxana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27038

Renewable resources, biopolymers and bio-based materials are keywords of the sustainable development and environmental sustainability concepts. Biopolymers, the green alternatives to fossil fuel based polymers, have already found different feasible applications, from consumer goods to regenerative medicine. Keratin is the biopolymer contained in the skin derivatives and appendages and is one of the the proteins with the most sophisticated architecture nature could produce. It is found in huge...
Autori: Hossein Rajabinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27043

We examined the effluent from a municipal (Nyíregyháza, Hungary) wastewater treatment plant (WWTP) on hydrophysicochemical properties and on diversity, community structure, and stability of fish assemblages at the recipient low flow channel system during a two-year period. The WWTP outflow increased significantly the nutrient concentrations (e.g. NO2 and NO3 concentrations increased to 4x and 8x respectively), and the regime (with the permanent ~0.23m3/s load) at the recipient c...
Autori: Péter Takács
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27082

Three different winter wheat production systems for three European countries (United Kingdom, France and Italy), all with different climatic conditions, soil management and input levels (e.g. tillage, fertilizers, herbicides and pesticides) were analysed from an environmental perspective. The intended applications were the analysis and comparison from a Life Cycle Assessment (LCA) perspective and the identification of the key parameters which have the greatest influence on final results. The ...
Autori: Daniele Cambria
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27102

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

This work focuses on treatment of lead polluted waste glass from urban collection (Pb≈5% wt) for its valorization as support in the immobilization of lipase, because soda-lime glasses are used in enzymatic catalysis. First of all, an extraction process of surface Pb was performed. The process is based on nitrilotriacetic acid (NTA) chelating agent. The operating conditions are: T=80°C, t=1h, pH 10, solid/liquid weight ratio=1/10, reagent concentration=0.1 M. Leaching tests at contr...
Autori: Luisa Barbieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27122

Rapeseed meal (RM) is an abundant and cheap by-product of oil extraction process. RM is a rich source of nitrogen, carbon, and minerals. Thanks to these features, RM has a striking potential for eco-friendly production of high value products in biotechnological processes. In this study, the possibility of using a low-cost medium based on the water soluble fraction of RM for laccase production by the fungus Pleurotus ostreatus has been evaluated and compared with the use of synthetic complex ...
Autori: Lucia Guarino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27129

The production process of wine and distilled generates several by-products (20-30% of total production). Currently, most of the solid by-products (pomace, stalks, lees and seeds) obtained as downstream of the vinery industry, are conferred to the distillery or, less frequently, used in agriculture and for energy production. As a consequence, much of the antioxidant compounds contained in the grape is unused in the products of processing and is lost. These substances (among which the most impo...
Autori: Paola Zitella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27135

The discovery of entropy in thermodynamics has set fundamental premises for the study and analysis of the relationship between the entropy law and economic processes, as one of the main objectives of such endeavours was to separate the qualitative aspects from the realm of economics. The law we have chosen to focus on in the present paper states that, in the universe or in isolated structures, entropy increases constantly and irreversibly, thus causing a continuous and unidirectional degradat...
Autori: Ionel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27179

In this work, the effect of cyclic anaerobic/aerobic conditions on the biodegradative capability of the mixed microbial culture for the azo dye Acid Red 18 was investigated in the sequencing batch reactors. For this purpose, five anaerobic/aerobic sequencing batch reactors were operated under the same operation conditions at different anaerobic/aerobic reaction times. The whole reaction time was 22-h with anaerobic/aerobic periods of 6/16, 10/12, 14/8, 18/4 and 22/0 (h/h) in An/ASBR1 to 5, respe...
Autori: Mohammad Hakimelahi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27191

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

In this study, an upflow anaerobic sludge blanket (UASB) bioreactor at the mesophilic temperature (38ºC) was successfully used for the treatment of petroleum refinery effluents. Response surface methodology (RSM) was applied for the design and analysis of experiments to predict the behavior of the initial COD and the hydraulic retention time (HRT) in the bioreactor. A statistical analysis indicated that the models adequately represented the experimental data. At the optimal conditions, the ...
Autori: Seyed Omid Rastegar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27233

Rotifers are known as cosmopolitan organisms, found in high density in most waters, often representing the dominant group in terms of species diversity and abundance in the zooplankton community. Since the functionality of an ecosystem is closely related to the diversity of communities, analysis of rotifers assemblage may be a useful tool in understanding the mechanisms of the spatial and temporal changes on this level. Data were collected from 2008 until 2010, in distinct areas of Danube, Sf...
Autori: Larisa Florescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27247

A Microwave-Ultraviolet reactor was developed and the effect of microwaves on photodegradation of various phenols was studied using the reactor. The degradation study was carried out by six methods - microwave irradiation, photodegradation with UV light, microwave and ultraviolet radiations (microwave irradiation in presence of TiO2, photodegradation with UV light in the presence of TiO2 and also simultaneous MW and UV irradiations in the presence of TiO2). The relative efficiencies of the degr...
Autori: Singaram Karthikeyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27248

Different bioleaching processes were applied to mining wastes deposited in the highly polluted post-industrial region - Lower Silesia in Poland. The chemical characterization of the wastes before and after bioleaching processes was performed. The characterisation was based on the distribution of selected elements (Fe, Mn, As, Co, Cr, Cu and Ni) between operationally-defined phases. The phases were defined using a six-step extraction procedure optimised according to the properties of the studie...
Autori: Joanna Pałdyna
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27259

Environmental issues have received ascending attention in recent years due to the increase of their negative effects. Greenhouse gas emission levels have experienced an exponential increase in the last decades mainly on account of the development of the building sector. Life cycle assessment (LCA) of buildings is a proper tool to analyse the full environmental impact during their designed lifespan. Inventory databases have a shortage of local parameters in some countries and need to be developed...
Autori: Iosif Boros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27289

The paper is focused on the sustainability of packages manufactured from corrugated board. The arguments proving that corrugated board is an eco-friendly material intended for goods packaging are discussed considering carbon footprint, water footprint, Life Cycle data released as a result of comprehensive analyses elaborated by specialized bodies and scientists. A “cradle-to-cradle” approach is promoted since corrugated board is fully recyclable, it is reusable and easy disposable. M...
Autori: Teofil Câmpean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27290

In this paper carbon footprint is estimated for wastewater treatment plant Constanta South, Romania, by using a combined model from the available protocols for carbon footprint calculation. Off-site and on-site emissions were taken into account. The carbon footprint calculations were based on the operational data regarding power consumptions, sludge, chemicals and biogas production. A prediction for carbon footprint is done for upgrading wastewater treatment plant. For the current plant technolo...
Autori: Lăcrămioara Diana Robescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27299

Construction industry uses a huge quantity of traditional and modern building materials which generally are produced to satisfy different demands, such as: resistant and safety requirements, friendly with the environment, architectural aspects etc. Researches must solve any requirements related to materials properties and offer a large diversity from which the proper solution must be considered. For improving the mechanical properties of polymer concrete, the use of fibers of different types is ...
Autori: Vasilică Ciocan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27306

This paper presents the research performed in view of emphasizing the effects of mineral aggregates extraction on the geomorphological and hydraulic features of Moldova body of water. The effect on the geomorphological features was assessed by overlapping the cross profiles (22 profiles) and long profiles (2 profiles) from the entire area studied. These profiles were obtained by topographical measurements on the starting date (July 2013) and on the research end date, respectively (March 2015). T...
Autori: Paula Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27335

Although the main reason for the extraction of methane from coal beds continues to address ensuring the safety of workers, an important driver is the need to reduce emissions of greenhouse gases. In order to identify potential technical problems specific for available technologies implementation, we performed a comparative critical analysis, based on which the technically feasible systems resulted, their further selection being based on detailed analysis in financial and investment terms. The re...
Autori: Lucian-Ionel Cioca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27350

Discomfort caused by noise is ever-present, having numerous physiological, psychological and social implications. One of the most important discomfort factors for personnel working in the processes of surface coal extraction is represented by noise. This paper examines how noise generated by the process of lignite extraction influences the working capacity of employees. The covering effect of voice or different sound and verbal signals, during work, leads to tiring efforts of attention, thus de...
Autori: Sorin Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27366

In the process of underground coal mining a complex network of vertical, horizontal and inclined mine workings with the purpose of extraction, transportation and evacuation to the surface are utilized. The mining workings are also being utilized for ventilation network system, which is also used for ensuring the oxygen supply necessary for workers, as well for diluting explosive gases and/or toxic substances and, ultimately, for exhausting the heat resulted from underground workings. For air flo...
Autori: Marius Simion Morar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27372

Drilling waste management for oil and gas industry involves collection, transportation, processing, recycling, disposal, and monitoring of waste materials in order to reduce their effects on health and environment. In the Exploration and Production industry, environmental concerns have made effective management of drilling waste at well sites a great priority. Effective waste management is thus a key element in a successful drilling project. The industry therefore relies on effective expertise a...
Autori: M. Enamul Hossain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27375

The utilization of agro-industrial waste as a potential substrate for producing enzymes may serve a dual purpose of reducing the environmental pollution along with producing a high value commercial product. Twelve different agro-industrial wastes were evaluated for extracellular BGL (β-glucosidase) production by a mutant of Bacillus subtilis on solid state fermentations (SSF). The Citrus sinensis bagasse was found to be the most suitable substrate with highest BGL titer (35 U/gds). Optimum ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27378

This work presents an experimental analysis of the influence of a monocrystalline photovoltaic (PV) panels’ temperature on its main operating parameters. Victron Energy, SPM 30-12 PV panel is tested, using a double climatic chamber. The PV panel is placed as a barrier between the two rooms of the climatic chamber. The study is focused on the establishing the effect of raising temperature of PV panel over electrical parameters: voltage, current and power produced and also over the effici...
Autori: Sebastian Valeriu Hudisteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27397

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

The partial nitrification bioreactor (PNBR) was operated at a constant temperature and an influent synthetic wastewater pH of 35°C and 8.5, respectively. The effects of dissolved oxygen concentrations (DO), hydraulic retention times (HRT), and the nitrogen loading rates (NLR) on the ammonium removal efficiencies and the NO2-N/NOx-N ratio were investigated. The activity of nitrite oxidizing bacteria was stimulated at high DO concentrations. The highest NO2-N/NOx-N ratio of 0.76 was obtained a...
Autori: Sukru Aslan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27455

Timber harvesting and log extraction with conventional ground-based skidding systems in steep, mountainous terrain often results in severe damage to residual stands and forest sites. In this study, the impact of rubber-tired skidders on standing trees along sides of the trails was investigated 5 to 20 years post-harvest in terms of frequency and development of decay at the points of wounding. The study was located in the Hyrcanian mountainous forests of Iran. All standing beech trees (healthy or...
Autori: Davoud Kartoolinejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27457

In recent years, increasing temperatures and extreme weather conditions have had a significant impact on quality of life, especially in terms of the environment. Governments have made environmental preservation a priority and have received public support in turn. We formulate models to investigate a company’s optimal production quantities over two periods, including green technology efforts, to examine the impact of a carbon trading policy. We build separate inter-temporal production mode...
Autori: Changsong Ma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27469

An evolutionary game of environmental regulation among local governments in China was established in this paper, and we analyzed the dynamic evolution rules of the environmental regulation strategy among local governments as well as the impact of environmental regulation on regional ecological efficiency in China by using the spatial panel simultaneous equations based on the panel data of various regions in China from 2007 to 2014. The research results show that the local government will adjust ...
Autori: Li Xing
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27471

This paper reports the possibility of using zinc ash as a secondary source for zinc oxide, which can be further used as white pigment. For the extraction of zinc from zinc ash, sulphuric acid was used. The impact of different parameters (ash fraction, contact time, sulphuric acid concentration and liquid:solid (L:S) ratio) upon the extraction degree of metallic ions from zinc ash was studied. The optimum conditions for the metallic ions extraction are: 20 % H2SO4, 30 minutes contact time, 1:1 L:...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27475

The paper presents results obtained by analysis of some soil and wastes samples in order to establish the heavy metal (HM) content from these samples. The analyzed wastes were sewage sludge from municipal waste treatment and hydrotechnical basin sludge. These types of wastes were mixed with soil from Oltenia Sub-Carpathian area, obtaining the substrates useful for different types of plants. It was studied the migration potential of the metals from substrate to apple trees, the results being comp...
Autori: Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27476

Mobilization of micro- and macronutrients and their uptake by Zea mays L. and Triticum aestivum L. in response to EDTA additions to risk metal contaminated agricultural soil was monitored over a three year period on the field scale. EDTA addition effectively increased the mobility of total water-soluble micronutrients (Cu, Fe, Mn) and macronutrients (Ca, Mg, P) in soil extracts. Mobilization was highest in the first year and decreased strongly over time. Elements with a high affinity for EDTA (C...
Autori: Reinhard Rauch
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27477

Lijiang River is the link of Guilin landscape and the golden waterway of Guilin tourism. With the development of social economy, the pollution problem of Lijiang River in recent decades has become more and more serious, which has aroused widespread concern and attention. However, the study on the reduction of river pollution load is seldom found reported until now. In this paper, the pollutant load of Lijiang River is estimated by equal standard pollution load method and the water pollution mode...
Autori: Ronghui Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27490

The present study aims to compare the efficiency of a single extraction and a 3-stage cross-current extraction of PAHs from both lowly contaminated (LC) and highly contaminated (HC) sands using palm kernel and soybean oils (PKO, SO). It is observed that 3-stage cross-current extractions increase the total efficiencies compared to single extractions by 18.7–22.7% and 27.2–30.6% for LC and HC sands, respectively. Maximum efficiencies of 94.3% and 98.4% are obtained for phenanthrene (PH...
Autori: Ee Von Lau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27530

A series of column experiments were conducted to study volatile contaminant (benzene) removal and process principles using soil vapor extraction (SVE) under different thermal conditions. Compared with the normal SVE method, two thermal methodssteam injection and electrical resistance heating effectively increased the benzene vapor diffusion and removal rates. The removal efficiency of benzene with the electrical resistance heating method was 96.5%, which was significantly higher than that with t...
Autori: Peng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27534

The aim of this study was to examine the adsorption of malachite green dye from aqueous solutions on the waste foundry sand. The effects of contact time, adsorbent amount, pH and initial dye concentration were investigated. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin adsorption isotherm models. The adsorption capacity of waste foundry sand for the removal of malachite green dye was determined with the Langmuir and found to be 23.29 mg/g. The adsorption isothe...
Autori: Elif Hatice Gürkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27536

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

There is an increasing interest in the food industry and in protective health care for the expansion of natural antioxidants from plant materials. The solid wastes generated by the winemaking industry represent about 30% of the material used and it consists mainly of grape pomace (containing seeds, pulp, stem and skin). It is well known that high quantities of valuable compounds like dietary fibre, oils from the seeds, anthocyanins and phenolic compounds still remain within the grape marc. The p...
Autori: Valeriu V. Cotea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27553

The solid-liquid extraction process and some of its influencing factors such as solid-liquid ratio, temperature and salt initial amount have been investigated. Also, mathematical modeling for mass transfer coefficients calculation was applied. An inert porous solid material (coal), impregnated with 10% and 20% mass NaCl or 15% and 30% mass CaCl2, was used. The leaching was conducted in a fixed bed column, in laminar flow. The CaCl2 impregnated samples were investigated in a column with a height...
Autori: Marcel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27557

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Dielectric measurements were carried out on a series of bent-core liquid crystals based on resorcinol and 2, 7-dihydroxinaphtalene cores and presenting B mesophase in between 30-160°C. The dielectric constants in the liquid crystalline phase were measured as a function of frequency and temperature. The dielectric relaxation of bent-core compounds has been analyzed by dielectric constants/frequency curves. The variation of the dielectric strength with temperature has been determined as well. ...
Autori: Irina Carlescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27568

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

The influence of the active compound of Moringa oleifera Lam (MO) seeds was evaluated by different methods for the preparation of the natural coagulant in the treatment of surface water. Nine methods were analyzed, comprising samples of seed powder with different granulometry, aqueous and saline solutions, evaluated before and after oil extraction from MO seeds. Tests of coagulation/flocculation and sedimentation were accomplished using simple Jar Test. Natural coagulant dose of 50 mg.L-1 identi...
Autori: Karina Cardoso Valverde
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27588

In this research, the capability of uranium biosorption by dried biomass of the red algae was investigated in a batch system. For the screening of the most appropriate biosorbent, they were placed in 0.5 mmol/L uranium solution with different pH for 3hrs of contact times. The obtained results showed that the species of the Gracilaria corticata (J. Agardh) are having the maximum rate of the biosorption. Sorption equilibrium was reached within 3hrs of contact time (at pH 4.5), and the results of t...
Autori: Reza Dabbagh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27596

β-glucosidases are very important in the improvement of cellulose degradation rates by diminishing the inhibition of end products. Although, cellulase cost has reduced significantly in last decade but still the high costs of biomass saccharification is one of the main challenges for the commercialization of ethanol from LC biomass. In this work, β-glucosidase immobilization in calcium alginate was optimized using response surface methodology. 89% immobilization efficiency was achieved ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27614

The aim of this study is the treatment of Chlorothiazide in an aqueous medium by Electro-Fenton process using a Platinum anode. This pharmaceutical product is used to treat hypertension. Removal rates and mineralization efficiency have been analyzed under different operational conditions. Degradation kinetics well fitted to a pseudo–first–order reaction. Apparent rate constant of the oxidation of Chlorothiazide by electrochemically generated hydroxyl radicals was determined to be 9.4...
Autori: Saied Taieb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27616

Water is currently becoming a strategically important material, and the importance of water and wastewater treatment technologies is therefore increasing. Wastewater from the food industry has many special features originating from its high organic matter content. Meat industry wastewater additionally has a high fat content. We investigated the effects of ultrafiltration and ozonation, individually and in combination, for the treatment of meat industrial wastewater. Ozone gas was generated from ...
Autori: Cecilia Hodúr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27631

Pyrometallurgical recycling of lead from spent batteries entails secondary waste fractions generated in the blast furnace as iron stone and lead slags. For further purification of both fractions, hydrometallurgic processing is proposed. This paper focuses on purification of iron stone, in view of recovering metals (mainly lead) and of producing decontaminated iron stone fit for further recycling. The results demonstrate that iron stone is mainly composed of iron and lead; copper, zinc and antimo...
Autori: Bart Van der Bruggen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27642

Adsorption, desorption, and kinetics behavior of Gd(III) ion on chelating resin were investigated in this paper. Batch adsorption studies were carried out with different pH, contact time, and temperature. The adsorption of Gd(III) follows the Langmuir model better than the Freundlich model. The apparent activation energy Ea and adsorption rate constant are k308 4.16 kJ/mol and 6.01×10-5 s-1, respectively. Thermodynamic parameters such as ΔH, ΔS and ΔG indicated that Gd(II...
Autori: Leilei Pi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27688

Sulfide bearing mine tailings generated through mining and processing of mineral ores is one of the serious problems around the world due to their potential environmental hazards. Current study focuses on vertical distribution and potential mobility of metals in New and Old tailings of a Lead and Zinc mining area of India. Mine tailing profiles sampled from New (0-500mm) and Old tailing (0-400mm) dams were chemically (pH, EC, Carbonate content, Cd, Pb, Zn and Mn levels) and mineralogically (usin...
Autori: Malik Anju
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27690

The reuse of sewage sludge will be increasing in the future, with expansion of sewerage works and advanced sewage treatments. During anaerobic digestion of sewage sludge from wastewater treatment plants the humification of organic matter will have an important effect on the physico-chemical forms of heavy metals. The aim of our paper was to investigate mobility of zinc from dried anaerobic sludge (DANS) from municipal wastewater treatment plant (WWTP) via single step (simultaneous) extraction pr...
Autori: Vladimír Frišták
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27695

With the aim of contribute to a bioremediation technology drafting, this paper presents a preliminary research on bioremediation of wastewaters polluted with heavy metals and other toxic contaminants. Bioremediation tests were performed with aquatic species Lemna minor, Vallisneria spiralis, Eichhornia crassipes, Hydrilla verticillata, Pistia stratiotes, Cladophora glomerata, on samples of contaminated waters resulting from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu Co...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27702

Huge amount of red mud has been disposed for the past several decades and it is still generating all over the world. Red mud is a waste of the bauxite processing industry obtained during the alkaline extraction of alumina from bauxite ore. The red mud is a potential raw material containing several valuable components including iron, titanium and rare earth metals. The aim of the research was to develop an appropriate acid digestion technique for the red mud in order to determine the amount of...
Autori: Tatjána Juzsakova1
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27780

The adsorption rate and dynamic behavior of the system are important factors as regards the process design and operational control. The aim of this study was to find a suitable kinetic model for the hexavalent chromium removal in a batch reactor. The experimental data were analyzed using four adsorption kinetic models: the pseudo- first and second order equations, the Elovich equation, and the intraparticle diffusion equation, so as to determine the best fit equation of the Cr(VI) adsorption ont...
Autori: Ankica Radjenovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27773

Geocomposite materials consisting of lightly cemented mixtures of expanded polystyrene beads (EPS) and backfill soils are commonly used as fillers and for the construction of light weight embankments. The constant normal stress (CNS) and constant volume (CV) direct shear parameters as well as the relationship between gradation properties of four residual granular backfill soils and direct shear parameters of lightly cemented mixture of EPS and backfill soils was evaluated. The maximum density an...
Autori: Felix Okonta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27771

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

Capillary gas chromatography coupled with mass spectrometry technique was used for the assessment of low concentration of dinitrophenol pesticide, Dinocap in different spiked samples. For this purpose it has been spiked with Dinocap (15- 200 μg/mL) five environmental matrices (a soil sample and two each samples of wine and grapes). The Dinocap degradation grade in these samples was also monitored. The extraction was performed in dichloromethane. The assessment of the Dinocap in the samples we...
Autori: Nicoleta Grigoriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27746

Debris from deciduous trees in the form of park green waste was investigated as a potential biosorbent for the removal of chlorinated solvents from water. The sorption properties of beech leaves and cupules, oak leaves and acorns, birch leaves and lime leaves (all tree species common for a moderate climate) in a non-modified form were investigated with regard to the removal of perchloroethylene, 1,1,2-trichloroethane and 1,1,1,2-tetrachlorothane. The preliminary results showed that these biosorb...
Autori: Marek Tobiszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27760

Indoor environment significantly affects occupants’ health and productivity. However, in smart buildings and cities, it can be improved thanks to the implementation of innovative ICT systems and services. Thermal comfort is one of the most complex aspects to be considered to enhance occupants’ well-being, because of the relevant role played by subjective parameters (physiological, psychological and cultural) in its evaluation. This challenge can be tackled by integrating wearable dev...
Autori: Andrea Calvaresi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27783

This study aims to monitor Volatile Organic Compounds (VOCs) and odour annoyance perceived by the exposed population living nearby a petroleum plant through an integrated high temporal resolution methodological approach. The area under investigation is considered one of the most critical industrial areas of the South of Italy (Basilicata) because of presence of the largest Italian petroleum plant, called the "Center Olio Val d'Agri" (COVA). In fact, VOCs and odours emitted from ext...
Autori: Alessia Di Gilio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27791

The construction sector has evolved a lot over the last few years promoting the design and manufacturing of innovative and environmentally sustainable materials and products. In accordance with European and national guidelines, with a growing awareness of environmental issues several experiences are showing the interest of companies to qualify their products as green and environmentally sustainable. In the European context many directives have been introduced which, among their themes, speak of ...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27806

In this study, application of integrated anaerobic-aerobic membrane sequencing batch reactor (MSBR) for treatment of an azo dye-containing wastewater was investigated. For this purpose, three lab-scale MSBR systems were operated at various hydraulic retention times (HRT) of 48, 24 and 16 h with constant value of solid retention time (SRT) for all reactors. The treatment performance and the decolorization kinetic of the systems as well the fouling rate of the membranes were evaluated during the e...
Autori: Maryam Hasani Zonoozi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27851

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

The macrophyte Pistia stratiote was used as biosorbent for the removal of Black Krom KJR (BK-KJR) dye in synthetic aqueous solution. Initially, some tests were performed to verify the best operational conditions such as pH, biosorbent particle size, sorption temperature and stirring speed, which were later used in the kinetic and equilibrium tests. All tests were performed in duplicate. The highest removal rates of the pollutant were achieved at the process conditions of initial pH 2, granulo...
Autori: Aparecido Nivaldo Módenes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27843

The Danube River forms one of the largest and most complex deltas at the Black Sea, being a Biosphere Reserve, UNESCO World Heritage and Ramsar site. This study assesses the spatial variability of arsenic contamination of the water in the Danube Delta. Water samples were collected during all seasons in 2013 from the south-east of the Danube Delta and analyzed through HG-AAS method for arsenic. Data were handled using two different approaches. First, a complex hydrological model was compiled, ...
Autori: Gabriel Gati
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27884

Sand contamination is an important factor when assessing the health hazard potential of public beaches. The goals of this study are to assess the performance of four sand washing procedures on the removal of surface adsorbed chemical species, and to identify which chemical components are best suited for monitoring the health quality of beach sand. Four washing treatments were investigated: contact, stirring, sonication, and boiling. Sand samples were collected from three Portuguese beaches an...
Autori: Mário Dias Almeida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27890

The applicability of an electrocoagulation process with the biological treatment for the color removal of C.I. Basic Red 46 (BR46) dye was studied. It was shown that decolorization efficiency increased by increasing current density (j), pH, temperature (T) and agitation speed (ω) and decreased with the initial dye concentration [BR46]0. The optimal conditions in presence of a grid electrode (waste) used as cathode were found to be j=9 mA cm-², pH 8, T=35°C, [BR46]0=30 mg L-1 an...
Autori: Katia Madi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27927

Removal of excessive ammonium nitrogen (NH+4-N) from aqueous solution has been of considerable concern for several decades. It can be removed by air stripping, a necessary prerequisite is adding enough alkali. This study presented the first attempt to investigate the potential use of ceramsite coated with magnesium hydroxide (CCMH) on the effectiveness of NH+4-N removal coupled with air stripping at ambient temperature without alkali addition. The results showed that the CCMH coupled with air...
Autori: Tianpeng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27940

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

This study evaluates the environmental impacts of four types of frozen food packages throughout their lifecycle and suggests strategies for reducing their related environmental impacts. The four most widely used frozen food packaging materials were chosen for this study: (1) pouches composed of low-density polyethylene (LDPE) film; (2) pouches composed of polyethylene terephthalate (PET) and LDPE film laminate; (3) cardboard boxes coated with LDPE; and (4) multipackage composed of cardboard boxe...
Autori: Daina Kliaugaite
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27979

In this paper, several image analysis techniques have been applied aiming to obtain useful information regarding the processing of municipal solid waste polymers. An automated color extraction method has been applied in order to quantize the color distribution in the polymer wastes aiming their resource and time-efficient separation according to their color. Also, by processing different density fractions from the polymer waste the color of the final material has been predicted, as well as th...
Autori: Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27994

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

This paper analyzes the fundamental principles of the substitution of strip coal pillars with coal refuse through the combination of theoretical analysis, physical simulation and numerical calculation with engineering practice. We propose to lay out roadways through strip coal pillars in a reasonable manner so as to produce a “coal-rock bearing mass” consisting of stowboards (i.e., roadways backfilled with coal refuse) and coal pillars that substitute the original strip coal pilla...
Autori: Qiang-ling Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28014

There is a great need for an efficient geographic information system (GIS) implementation in interdisciplinary domains for providing useful information for scientific and managerial processes of further improving land-use planning and decision making in horticulture. The main goal of this study was the creation of a digital map and GIS application for the Fruit Research Station in Cluj-Napoca, North-Western Romania. The benefit of this implementation is a fully integrated land information sys...
Autori: Paul Sestraş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28015

Clinoptilolite (Clin), the most widely used natural zeolite in environmental applications, was used as soil additive to investigate its effectiveness in protecting and improving the quality of soils that received surface disposal of OMW, as well as in limiting nutrients leaching from the degraded soils. Clin was added in a batch experiment of 18 months, where OMW were added in evaporation ponds and on soil for a period of more than 12 years. The zeolite was added as dust (particle diameter &l...
Autori: Maria K. Doula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28018

The coal gas is a potential risk for the safety production in coalmines. The practical experiences in coalmine show that the gas may suffer massive desorption and migration after coal seam mining and deformation of overlying strata. Therefore, gas extraction in mines focuses on mining ground pressure relief gas extraction. In this paper, the study is carried out on gas permeability and migration pathway based on movements of overlying strata over the working face and the spatial location of t...
Autori: Jianwei Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28019

Trace elements (TEs) in contaminated soils are considered as primary jeopardy issues in developing countries which can cause major concerns for this industry and also menace the surrounding ecosystems, human health and wildlife, so urgent reclamation methods are required. The present research aims to evaluate potential phytoremediation capability of selected plant species Tamarix Spp., Haloxylon Spp. and Malcolmia Africana to grow in TE contaminated soils. Muteh Gold mine, a widespread mountaino...
Autori: Ali Daryabeigi Zand
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28056

Extracts of Bifurcaria bifurcata seaweed were obtained by diverse conditions. Different extraction techniques, such as hydrothermal and ultrasounds, and three different solvents (water, ethanol and water/ethanol (50:50)) depending on technique were used. Moreover, supercritical CO2 (SC-CO2) with 10% of ethanol as co-solvent using different extraction times (30, 45 and 60 min) was also used as extraction technique. Extraction yield, phenolic content and antioxidant activity were measured for e...
Autori: Rubén Agregán
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28039

In this work we aimed to examine the influence of the main abiotic factors (temperature, rainfall, relative humidity, atmospheric pressure) on the synthesis of active compounds (phenolics, flavonoids), with antioxidant and therapeutic effect of two herbs - Capsella bursa-pastoris (shepherd's purse) and Marrubium vulgare (horehound) collected from two different areas of Romania: Dobrogea (Constanta) and Muntenia (Bucharest). The studies have shown that biogenesis and accumulation of second...
Autori: Elena Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28041

Proteins from Hermetia illucens (or Black Soldier Fly, BSF) have been employed in this study as possible source for bioplastic formulation. This type of bioplastic can replace the actual materials employed in agriculture, avoiding the critical issues concerning the soil pollution due to conventional plastic end-life. Different plasticizing agents (glycerol and polyethylene glycol) have been tested and the ability to generate a homogenous film, through wet casting, has been evaluated. Characteriz...
Autori: Silvia Barbi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28074

The activities connected with the construction sector are responsible for several environmental impacts, both in the construction sector, and in the many manufacturing sectors involved in the supply chain of materials and products (mining sector, manufacturing sector, waste treatment etc.). The building products have a marked cross-sectorial connotation, according to the ANCE 2016 report, 31 economic sectors out of 36 are suppliers in the construction sector. One of the possibilities to reduce t...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28090

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

Aim of the study is to determine Fe, Mn and Cd adsorption in the carbonate-rich clayey soils and to assess their environmental impacts. Soil samples represented a carbonate-rich clayey soil (Isaoren), carbonate-rich soil (Maşuk) and clayey soil (Aşık) was obtained from three different villages in Sanliurfa, southeast of Turkey. Adsorption studies were carried out with batch method. The maximum Fe, Mn and Cd adsorption was found on Isaoren, Maşuk and Aşık soils with ...
Autori: Ayse Dilek Atasoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28116

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

This work seeks to develop a suitable heavy metals precipitation modeling approach that could give reasonable results in mainstream use with industrial wastewater treatment. This paper is devoted to the thermodynamic analysis of the degree of precipitation of slightly soluble hydroxides and salts in industrial wastewaters in order to optimize the technological schemes of extraction and reuse of heavy metals from industrial waste. Based on the notion of the solubility product, the equations desc...
Autori: Igor Povar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28156

The recovery of nutrients from sewage sludge ash, especial phosphorus, is one of the most important alternative in sewage sludge management. Phosphorus is an essential element for all living organisms and very important for agriculture and industry, as well as. Because the phosphorus is a non-regenerative resource, its recovery plays an important role for society. Phosphorus capitalization as struvite (NH4MgPO4.6H2O) from sewage sludge has attracted considerable attention due to its potential to...
Autori: Bogdan Adrian Militaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28158

The study attempted to identify the best suited models to determine the kinetics of chlorine decay and trihalomethanes (THMs) formation in drinking water supplies. Batch experiments were conducted on synthetic water samples to simulate the characteristics of raw water collected from Maithon water treatment plant (MWTP), Dhanbad, Jharkhand, India. Influence of various parameters like total organic carbon (TOC), reaction time, pH and chlorine dose on the rate of THMs formation were analysed. The s...
Autori: Minashree Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28171

Environmental quality is directly influenced by the level of pollution generated by economic, industrial or anthropogenic activities and directly affect the citizens’ life quality and wellbeing, and ensuring a good status of environment it is a stringent topic that must become the major interest for the local public authorities. The main goal of this study is to evaluate the environmental quality in Iasi city, how the overall quality is influenced by the level of pollution and what are the...
Autori: Silviu Petru Grecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28180

Silk sericin is a water-soluble macromolecular protein obtained from the raw cocoons of silkworm, Bombyx mori. It comprises of about 25% of the total cocoon shell weight and is categorized as a waste by-product in textile and silk industries after the extraction of silk fibers. This study emphasizes on the extraction of sericin from B. mori by a conventional salt alkaline method and characterized their physico-chemical properties, thermal stability, anti-bacterial and anti-oxidant activities. T...
Autori: Inderchand Manjubala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28213

Current landscapes have been intensively modified by humans and forest fragmentation has created substantial increases of forest edges. So far, scale-dependence between observable ecological patterns and the underlying processes affected by forest fragmentation have been widely ignored. To overcome the widespread ambiguity in selecting relevant spatial scales for studying the ecological effects of forest fragmentation, we investigated the effect of forest prevalence and edge length on carbon st...
Autori: Emilia I. Cojoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28242

The olive oil extraction industry is one of the most polluting wastewaters from the food industry, which is considered an important economic activity in the world. The environmental effects of olive wastewater are related to chemical and organic loading, which is resistant to biodegradation processes. The purpose of this study was to determine the efficiency of combined electrocoagulation, catalytic ozonation, to reduce organic load and improve the biodegradability of olive oil sewage. The pres...
Autori: Mohammad Reza Khani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28261

Water supply represents a constant worldwide challenge for people and authorities. This issue is significantly severe in semiarid regions such as Gaza Strip, where groundwater constitutes the only fresh water source. Furthermore, Gaza Strip area suffers from water scarcity due to the decrease in water recharge and a constantly groundwater over-pumping, along with seawater intrusion, which cause serious problems in fresh water supply. Treated wastewater reuse represents a sustainable approach to...
Autori: Alessandra Bonoli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28288

This paper aims to investigate the root characteristics of three woody species (Pinus brutia, Quercus coccifera and Spartium junceum) planted on steep soil-denuded slopes, surfaced after ring-road excavation. The planted slopes were almost vertical, south faced and adding no soil. Fifteen plants per species were manually extracted for root system analysis and testing. The findings showed that the survivorship was different among the investigated species with S. junceum plants to survive better. ...
Autori: Petros Ganatsas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28329

The simple way to deal with obnoxious hexavalent chromium is to reduce it to its trivalent form, which is comparatively less toxic. In this article, Cr(VI) was reduced to Cr(III) using hydrazine. The effect of various process parameters such as molar ratios of Cr(VI) to N2H4, the temperature of the reaction, and the environmental chemistry of solution on the reduction kinetics have been evaluated. Experiments demonstrate an order of three for the reaction. The reaction was first order with resp...
Autori: Bharti Verma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28348