AbstractThe goal of this paper is to examine the potential for ecologically and economically sustainable kraft pulp mills. This paper reviews technical and scientific literature on a wide range of factors that will influence the overall impact of a pulp mill on its total environment. The emphasis is on efforts to achieve "closed-loop," or Totally Effluent Free (TEF) mills which eliminate all liquid effluent and minimize the quantity and environmental impact of air and land discharges. An attempt...
Autori: Adrian Puitel, Dan Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25202

In this work, the ability of Romanian peat for sorption of Pb (II) ions from aqueous solution has been determined using the batch experimental techniques. The sorption equilibrium has been studied at different pH values. The equilibrium adsorption level was determined to be dependent of the pH of solution and initial Pb(II) concentration.The equilibrium adsorption capacity of Romanian peat sorbent for lead has been described by seven types of mathematical model isotherms, namely: Freundlich, Lan...
Autori: Brindusa Robu, Corneliu Cojocaru, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25160

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

AbstractThe project’s idea is really simple: using the LabView environment, we have realized a virtual instrument able to get from the GPS the information about latitude, longitude, altitude and from a prototype data acquisition board for environmental monitoring parameters the information about air pollution factors. The perfect solution regarding the costs, the covered area and the accuracy of the measured data is the use of a glider for flight, because of its characteristics: free flights (...
Autori: , Codrin Donciu, Marius Branzila, Marius Paslaru, Romeo Cristian Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25221

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractIn India, transportation sector is growing fast and the number of vehicles on Indian roads is increasing at a rate more than 7 percent a year. During the period of 50 years from 1951 to 2001, the number of vehicles has increased from 0.3 million to 43 million i.e. an increase of almost 143 times. This has led to overcrowded roads and noise pollution. The transportation sector is one of the major contributors to noise in urban areas, accounting to as much as 55 percent of total noise on t...
Autori: Arvind Kumar Shukla, Jyoti Bhushan Srivastava, Manoranjan Parida, Sukhvir Singh Jain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25279

AbstractNatural hemp fibers have been evaluated for Zn (II) ions sorption from diluted aqueous solutions. In order to establish the optimum conditions, the effect of initial pH of solution, hemp dose, Zn (II) concentration, temperature and contact time of phases on the Zn (II) sorption by natural hemp has been studied. To model the Zn (II) sorption at three different temperatures the Langmuir and Freundlich isotherms have been used. The Langmuir maximum sorption capacities were determined as bei...
Autori: Carmen Paduraru, Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25336

- Artificial intelligence applications in the atmospheric environment: status and future trends- Kernel methods and neural networks for water resources management- Environmental decision support systems based on models and model-based reasoning- Towards an intelligent tutoring system for environmental decision makers- SBC-MEDIU: A multi-expert system for environmental diagnosis- Fast and accurate residential fire detection using wireless sensor networks- Validation of a knowledge-based risk mode...
Autori: http://www.ecozone.ro/reviste.php?RID=25377

AbstractPulsed high voltage discharge technology is a newly developed method for knock out viruses in blood with various electrohydraulic discharge reactors. The aim of this study is to investigate the effect of an electrohydraulic discharge treatment system on Hepatitis C virus (HCV) behaviour. The electrohydraulic discharge (EHD) reactor consist of high voltage point discharge electrode above blood surface and cylindrical ground copper electrode containing the blood (in the same time act as th...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25362

AbstractThe study on the distribution of oxygen transfer rate in a stirred bioreactor for Propionibacterium shermanii broths underlined the major influence of the presence and concentration of biomass on the interphasic transfer of oxygen. Owing to the bubbles surface blockage by the bacterial cells, the accumulation of biomass from 30.5 to 120.5 g/l d.w. led to the decreasing of kla for about 1.3- 2.4 times. Compared with the simulated broths without biomass having similar apparent viscosity, t...
Autori: Adina Segneanu, Anca-Irina Galaction, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25364

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract The etching of iron materials in sulphuric acid solutions allows the dissolution of the iron oxides with formation of iron sulphates. The relatively low solubility of the formed sulphates imposes their separation for avoiding the contamination of the etching bath, as well as for preventing the environmental pollution through the wastewater. Within the flow sheet of the processing of the hot or cold rolled steel, a stage of separation by crystallization of iron sulphate is foreseen. T...
Autori: Liliana Lazar, Ion Balasanian, Florin Bandrabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25415

Abstract Using slag in steel making represents a challenge for road construction industry and decreasing environment interactions also.Steel making slag wit granulations of < 10 mm, which today have not a sure solution, represents the research object. The technological research solutions have aimed reducing CaO free content in these slugs, and reducing slug fraction with granulationof ...
Autori: Florian Zaman, Mirela Gabriela Sohaciu, Ecaterina Matei, Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25439

Abstract Macro-Defect-Free (MDF) cements are polymer-cement composites characterized by high value of flexural strength. Due to their thermal and electrical insulating properties, MDF cements could replace other insulators obtained by environmental non-friendlier technologies or being themselves toxic and non-biodegradable. MDF cements obtained by the use of an ecologic polymer (poly(vinyl alcohol)) shows high mechanical resistance in the initial state but also it’s dramatic decrease after ...
Autori: , Georgeta Moise, Hulusi Ozkul, Ozgur Ekincioglu, Catalin Croitoru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25493

Abstract White mustard (Sinapis white) is an annual plant of the Cruciferae family originating from the Mediterranean region and is cultivated in Europe and Asia, mainly for its seeds, but also for animal feed or crop rotation. White mustard seed is also an important source of vegetable oil that can be used as fuel. The chemical composition of mustard seed (Sinapis alba) includes glucosinolate (sinalbozida, sinapina free), essential oils, fatty oils (glycerides of oleic acid, linoleic, linole...
Autori: Camelia Ciubota-Rosie, Rodica Diaconescu, Irina Volf, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25561

Abstract Ballast water is used to supply stability on ships that have no load. It is loaded on before departure and often carries stowaways in the form of tiny organisms. To avoid that, the ballast water can be treated on board. Treating ballast water to free it from potentially harmful invasive species is a challenging problem. Alfa Laval in cooperation with Wallenius Water has been developed one system that cleans ballast water during ballasting and de ballasting operation. The paper presen...
Autori: Liviu Constantin Stan, Nicolae Buzbuchi, Feiza Memet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25567

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

Abstract The former Arad Chemical Fertilizer Plant had an important polluting effect on environment and, although it was shut down in 1990, its environmental heritage still exists. The paper contains a short description of the former plant and its impact on the environment, mainly on the quality of water and soil and emphasizes the effects of polluting heritage that still exists. Today, one of the major problems on the platform of the former Fertilizer Plant is the existence of all concrete b...
Autori: Aurica Grec, Florin Dumescu, Ladislau Klein
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25599

Abstract Unlike the P. shermanii and S. cerevisiae cultures, the study on the distribution of oxygen transfer in stirred bioreactor for P. chrysogenum free mycelia broths indicated that this process is controlled mainly by the high apparent viscosity of broths, and less by the presence of fungus biomass. For this reason, the influence of fungus accumulation on the reduction of kla is attenuated compared with that obtained for bacterial or yeasts broths. The lower influence of fungus biomass i...
Autori: Anca-Irina Galaction, Dan Caşcaval, Marius Turnea, Stefanica Camarut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25606

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

In this study, the application of freeze-concentration method to treat low-concentration polluted water was demonstrated. The effects of stirring, the temperature in a freezing cabinet and the volume of water involved in the freeze-concentration treatment of pollutants were investigated under laboratory conditions. The removal of pollutant by freeze-concentration treatment was also attempted. Results had shown that the ratio of pollutants removed was about 83% when the experiment was carried out...
Autori: Yingjie Dai, Ying Zhang, Baiyin Liu, Masahiro Teduka, Yongbo Lin, Shunitz Tanakahttp://www.ecozone.ro/reviste.php?RID=25709

Abstract:The concept of passive and low energy houses became fashionable in the last years and the European Parliament also initiated aproposal to build only near zero energy houses from 2018. The regulations already in force aim at low energy consumption (mostlikely influenced by the wide spreading of the �Passivhaus� concept in Europe) and by 2018 harmonized regulations andstandards will require the near zero energy building. According to the concept of the Energy Performance of Building D...
Autori: András Zöld, Tünde Kalmár
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25751

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:Alkaline protease from Conidiobolus coronatus which is optimally active at pH 10 and 40°C finds application in leather and detergent industries as well as for recovery of silver from waste photographic films. The protease was immobilized in Ca-alginate, polyacrylamide gel and alkali treated waste fungal biomass (ATWFB). ATWFB was found to be most suitable among the matrices tested. Glutaraldehyde marginally increased the binding to ATWFB. Binding of protease to ATWFB seems to be through...
Autori: Ryali Seeta Laxman, Shiv Shankar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25807

This paper refers to the post-Darcy free level uniform filtration. The capillary tube fascicle model is applied to this filtration. The theoretical Ch?Šzy coefficient is computed and also experimentally verified for a homogenous and isotropic material, made of glass spheres. The typical features for the free-level post-Darcy filtration (depending on slope) are the lover, critical and higher stages flows....
Autori: Aron Gabor Molnar, Daniel Toacă, Daniel Toma, Iosif Bartha, Nicolae Marcoie, Victor Gabor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25833

� SUSTAINABILITY IN ENVIRONMENTAL REMEDIATION � EVALUATING THE CLIMATIC CHANGES IN THE HYDROLOGICAL FLOW REGIME OF THE MOLDAVIAN AREAS � ENSURING ECONOMICAL AND FINANCIAL SUSTAINABILITY: STATE FISCAL CONTROL - A WAY TO PREVENT AND REDUCE TAX AVOIDANCE � COMBINED OXIDATION AND ULTRAFILTRATION PROCESSES FOR THE REMOVAL OF PRIORITY ORGANIC POLLUTANTS FROM WASTEWATERS � THE FREE LEVEL UNIFORM POST-DARCY FILTRATION THROUGH A SPHERE-MADE HOMOGENOUS MEDIUM � HSLA ST...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25838

The removal of Cr (VI) from aqueous solutions by sphagnum peat moss was investigated in batch experiments as a function of solution pH and initial Cr (VI) concentration. The highest removal percentage (R=99%) was obtained at pH = 1, in solutions of 20.8 mg Cr (VI)/L. In order to establish the mechanism of the removal process, Cr (VI) and total Cr (Cr (VI) + Cr (III)) in residual solutions was analyzed. The Cr (VI) removal by the peat moss at low pH is governed by two processes – electrostatic ...
Autori: Catalin Balan, Doina Bilba, Irina Volf, Matei Macoveanu, Petru Bulai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25849

Chromium and cadmium are heavy metals that occur naturally in the environment and especially in soils. Their toxic effect is more pronounced at high concentrations and it depends on the oxidation states. While Cr (III) is considered an essential trace element for the metabolism of living organisms, Cr (VI) has a higher mobility and is easily soluble in soils and can be leached into surface water or groundwater, and taken up by plants. That leads to a toxic and carcinogenic effect to humans via i...
Autori: Dumitru Bulgariu, Florian Statescu, Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25866

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractIn this paper we analyzed some characteristics of vacuum sewer systems from technical, economical, environmental and socialperspectives. The vacuum sewer systems transport wastewater with lower pressure (p<pat), and are compared to conventionalsewer systems with free level (p = bed) - gravity and under pressure systems (p>pat) - gravity or pumping systems. Vacuumsewer systems are recommended for rural communities and residential neighbourhoods surrounding urban areas, developed ons...
Autori: Corina Panfil, Ion Mirel, Izabella Szigyarto, Monica Isacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26035

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractIn road traffic noise issues, experimental measurements are a relevant element in order to understand the problem and to adjustmodels. Sometimes, when measurements are not possible or in the designing phase, prediction models are used to perform anestimation of the equivalent level produced by a road infrastructure. Usually models parameters are obtained by a statistical datafit and thus they are related to the area where measurements have been performed. These models are suitable for st...
Autori: Gerardo Iannone
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26087

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract The paper deals with reinforced soil structures used in critical infrastructures for ecological landfills. During the last 17 years in Romania 28 such landfills were completed. Romania is however a country where strong earthquakes often occur. About 60% of its territory feels the seismic actions which combine with the existing ones. During earthquakes in the massive structures of landfills, huge inertial forces are developing. Due to uncontrolled movements and deformations...
Autori: Cristina Feodorov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26118

Abstract In a world of uncertainty, the only constant is change and rapid change produces a multitude of diverse facts. Risk is an integral part of life. While no country in the world is entirely safe, the lack of capacity to limit the impact of hazards remains a major burden for all countries and while the world has witnessed an exponential increase in human and material losses due to natural disasters, there is a need to reverse trends in vulnerability to earthquakes. Available d...
Autori: Gheorghe Mărmureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26140

AbstractStudying the relationship between urban typical landscape functional types and vegetation communities will conduct toinformation on management measures, people’s activities etc. Moreover, this could attain an important role for the research ofother ecological phenomena where human activities are involved. According to the data collected from the said plots, the impactof typical landscape functional types of urban core areas on the plant species was analysed. The results show that indigen...
Autori: Yantun Song
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26169

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractCd (II) removal efficiency of free and immobilized fungal consortia of 48-h-old Mucor sp. HI33 + 72-h-old Gliocladium virideAI003 + 72-h-old Aspergillus niger AH09 from aqueous solutions were tested under different aeration systems. Cd (II) removalby free cells under air bubble system aeration was higher (99.91%) than under shaker system aeration. Cd (II) removal byimmobilized fungal consortia was higher (83.18 %) under shaker system aeration and lower in air bubble system aerationrespec...
Autori: Arifa Tahir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26232

AbstractIndigenous isolated bacterium Aeromonas sp. was immobilized in calcium alginate and the related immobilization parameterslike bead diameter, inoculum size and the initial phenol concentration required for biodegradation were determined. Thebiodegradation activity was most efficient with 4 mm calcium alginate beads. The optimal immobilized biomass required wasabout 28 109 cells/mL. Compared with free-cell suspensions, the alginate matrix used for immobilization of cells provided betterenv...
Autori: Abdelkader Namane
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26249

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractIn the present paper, support vector machines (SVMs) are used to develop a quantitative structure-activity relationships (QSAR) model for the reaction rate constants (-logkNO3) of 115 heterogeneous organic compounds, through reaction with nitrate radicals (NO3•) in the troposphere. Two quantum chemical descriptors used as the inputs for the SVM model were calculated with density functional theory (DFT), at the B3LYP level of theory with 6-31G(d) basis set. The best predictions were obtai...
Autori: Bing Yi, Jiyong Deng, Xinliang Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26284

AbstractThis research introduces a new Robust Interval Type-2 Fuzzy Set Linear Programming (R-IT2FSLP) model to manage irrigationwater resources. This method improves upon previous interval fuzzy bound models by allowing uncertainties presented asmultiple fuzzy boundaries. It creates additional degrees of freedom and enable direct modeling of uncertainties within anoptimization framework. It more explicitly reflects the system’s uncertainties under the fuzzy membership function. The more ofR-IT2...
Autori: Guohe Huang, Lei Jin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26324

AbstractNowadays, when the problem of environmental protection is quite stringent, the producers are concerned to bring on the marketproducts, which have reduced environmental impact. In their turn, the consumers have become more aware and selective inpurchasing products or services. Due to the financial crisis, consumers buy less but they are asking for quality and environmentalfriendly products. Under these circumstances the producers must find solutions in order to satisfy the consumers’ requ...
Autori: Mirela Panainte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26433

AbstractThe primary objective of this research was to develop safe, programmable and cost-effective technologies of plantlet productionfrom the seeds of undomesticated American populations of Virgina fanpetals (Sida hermphrodita RUSBY). During our seedpriming treatment experiments, approximately 40% of the Virginia fanpetals seeds that were high-quality, infection-free,normally imbibing and germinating seeds. Our spring propagation tray experiments indicated that the spring large-scale trayplant...
Autori: Erika Kurucz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26545

AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract β-galactosidase from Aspergillus oryzae was strongly immobilized on magnetic particles functionalized with amino groups. By simple incubation without any activating agents, electrostatic interactions between amino groups and enzymes allowed obtaining a strong linkage. The immobilization efficiency was studied with the quantification of amino groups of the particles and of immobilized β-galactosidase. Kinetic parameters, especially the maximal velocity Vmax and the affinity...
Autori: Kalim Belhacene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26682

Abstract The degradation and adsorption behavior of dibutyl phthalate (DBP) in methanogenic phase refuse was investigated through laboratory microcosm experiments. The results showed that the half-life of DBP in the sterilized refuse was 5.9 times higher than in unsterilized samples, but that it decreased by 35.8% when dominant bacterial strains were added. Different concentrations of DBP did not have obvious effects on its degradation. The half-lives of DBP were decreased by 53.0%, 37.2% an...
Autori: Chengran Fang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26690

Abstract The main purpose of this research was to study the biodegradation ability of atrazine by using Arthrobacter sp. as free and immobilized cells of the strain DNS10, under several important environmental factors such as temperature, pH, salinity, substrate concentration. Furthermore, this paper objective was also to assess the process considering the immobilization under extreme conditions, such as high salinity and high atrazine concentration. DNS10 was immobilized on a sodium alginat...
Autori: Zhang Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26702

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Maximum removal (94±1.2%) of 2, 4 dichlorophenol (50 mg.dm-3) was achieved on silica with agitation of 4 hours, at pH 8 and 42°C. The positive enthalpy (ΔH) and negative free energy values (ΔG315K) suggested the endothermic and a spontaneous nature of sorption. The free energy of the process at all temperature was negative and increased with the increase in temperature. The values of free energy suggested a spontaneous process where the spontaneity decreased w...
Autori: Abdul Ghaffar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26718

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract The intensive vegetable system means that more toxic organic and inorganic compounds are entering the environment. The aim of this study was to obtain the necessary answers on the content of organophosphorus pesticides (OPPs) regarding to quantify these residues on soils cultivated with vegetables in conventional, organic and conversion systems, and also determine which pesticide residues are going in edible vegetable parts. A number of 23 OPPs were analyzed from soil (50 samples) ...
Autori: Vasile Stoleru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26768

Abstract A VOC monitoring was carried out inside and outside a multi-storey car park in order to characterize the emission profile of vehicular traffic source in an indoor environment. BTEX, and in particular toluene, were the most abundant compounds in all monitored sites, with different compositions between indoor parking areas and outdoor sites. The motor vehicle exhaust and gasoline vapor emission in these enclosed parking garages were characterized by diffusion or degradation phenomena ...
Autori: Gianluigi de Gennaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26778

Abstract Treatment experiments for mature landfill leachate were conducted by using combined aged refuse bioreactor (ARB) process and sulfate radical oxidation. In the ARB process, the effects of wet/dry ratios, hydraulic loading, and influent introduction time on contaminant removal were investigated. In the oxidation process, Na2S2O8 was activated by heat to generate powerful oxidants, such as sulfate radicals, to oxide residual contaminants in the effluent. The removal of chemical oxygen ...
Autori: Zhanmeng Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26818

Abstract Solar energy is one of the most important renewable resources due to its unique set of advantages. In urban configurations, wide open spaces used for parking areas close to malls, stadiums and industrial areas become justified challenges in revaluating them by placing solar panels on their wide roofs. The paper is a first attempt that reflects the scientific interest in the particularities of wind action upon the solar panels sustained by structural framed elements and which cover ...
Autori: Elena Axinte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26849

Abstract Free cells of Rhizopus oryzae were used to study adsorption of several cations (Cu2+, Zn2+, Mn2+, Ni2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The influence of biomass dosage, pH and temperature on the removal process was investigated. The sorption efficiency increased with increasing the temperature in the range from 25 ºC to 30 ºC and pH from 5 to 8. The maximum removal percentage was achieved at a biosorbent concentration 0.25 – 0.3...
Autori: Kolishka Tsekova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26857

Abstract Popular since ancient times, the mineral waters from Carpathian Chain (Romania) have gained a well-deserved reputation due to their quality and health benefits. This study provides a description of the chemical and isotopic composition (δ2H, δ18O) of mineral waters (CO2 - rich and CO2 - free water) located in six of the most popular areas, in order to improve the overall knowledge about their genesis and recharge mechanisms. The hydro-chemical facies of groundwater vary ...
Autori: Roxana Elena Ionete
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26869

Abstract In this paper we present results from the first European (EUR) and North Atlantic (NAT) volcanic ash exercise (VOLCEX) which includes all the warning phases associated as alerting, reactive and proactive phases. Because volcanic ash represents one of the most serious natural hazards that could affect aviation safety, the measurement campaign was focused on improving the reaction of relevant authorities in case of airspace contamination with volcanic ash and, particularly, to assess ...
Autori: Livio Belegante
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26874

Abstract The aim of this research was to find the optimal method of extracting oil from jatropha seeds and to discovery a technically viable process in which high quality biodiesel can be produced. To begin with, the oil extraction yield obtained with solvent extraction was 34%, using n-hexane in 2 hours. Then, the properties and fatty acid composition of jatropha oil were investigated. We must emphasize that jatropha oil contains about 11% of free fatty acids (FFA), which is far beyond the ...
Autori: Carmen María Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26909

Treatment of agrochemical industry wastewater is difficult to carry out unless integration with some advanced oxidation process (AOP) is used. The present study deals with treatment of an agrochemical industry wastewater, first using activated sludge and then with sulfuric acid treated activated carbon (SAAC) in presence of Fenton reagent. During the activated sludge treatment the food-to-microorganisms (F/M) ratio is varied from 0.1 to 0.2 mg chemical oxygen demand (COD) per mg mixed liquor ...
Autori: Makarand Vasant Karkare
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26957

The objective of this article is to study the evolution of soil erosion produced by the Siret River during 1989 – 2008. The hydrophysical and mechanic action of the river flow manifests by freeze, thaw, erosion, transportation, and alluvial deposit processes. The researched section was delimited in a sector of Siret River bed, where the exploitation of mineral aggregates is carried out on large areas. The influences and effects of deficient exploitation of mineral aggregates have a dire...
Autori: Stelian Cartacuzencu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26977

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

Accidents in spent nuclear fuel reprocessing plants are a critical issue for the safety of people, of operators and the environment, as well as for the security of the plants. The purpose of this work is to demonstrate the possibility to use a free license code to simulate radiological diffusion after an accident in these particular plants, in order to obtain a model which allows identifying escape routes for the people potentially involved in the fallout. The authors performed a benchmark an...
Autori: Mariachiara Carestia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27015

The investigation of bottom sediments in oxbow lakes was conducted in the free-flowing, meandering section of the Łyna River in N Poland. Seven oxbow lakes, differed by a degree of hydrological connectivity with the river channel, were chosen for the present study. In samples taken from 21 sediment profiles, particle size distribution, pH, bulk density, CaCO3, organic matter, total organic carbon as well as total forms of N, P, K, Ca, Na, Mg, Mn and Fe were determined. The gradient of de...
Autori: Szymon Kobus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27052

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

In studies of biochemical methane production (BMP) researchers often collate a large number of samples at the same time for a sample archive. The samples are often frozen to avoid microbial transformation, further homogenized by grinding. We studied the influence of subfreezing/thawing and drying/milling of energy crop on BMP and anaerobic biodegradability (BD). Relative standard deviation (RSD, %) between the BMP of controls and of the subfrozen was in the range 2.1–9.0%, and of the d...
Autori: Jin Mi Triolo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27079

Waste frying oil (WFO) is a complex and heterogeneous waste collected mainly from restaurants and, to a lesser extent, from food processors and households. In the last decades, interest for this waste has deeply grown and a strong competition in grabbing this raw material has begun. About 90% of WFOs collected in Europe is recycled for biodiesel production, being the high free fatty acids (FFAs) concentration in WFOs one of the main drawback limiting the yield of the conversion process. In th...
Autori: Cinzia Pezzella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27130

In this study, the impact of silicate admixture in 2-line ferrihydrite on its sorption properties is presented. Synthetic ferrihydrites with broad Si content in the range of 0 to 1.5 Si/Fe molar ratios were prepared and characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDS). With an increase in the Si/Fe ratio, a typical XRD peak at 2.5Å broadens and shifts toward 3 Å; the position of Si-O stretchi...
Autori: Gabriela Pieczara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27140

Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by local low-cost agricultural by-products – peanut hulls, soybean shells and grapefruit peels were compared to develop high-efficient and low-cost biosorbents for removal of lead(II) from wastewater. Batch kinetics showed adsorption equilibrium at about 90 min and the adsorption process for the three biosorbents was better represented by the pseudo-second-order model than the pseudo-first-order model. Batch equilib...
Autori: Rui Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27176

The discovery of entropy in thermodynamics has set fundamental premises for the study and analysis of the relationship between the entropy law and economic processes, as one of the main objectives of such endeavours was to separate the qualitative aspects from the realm of economics. The law we have chosen to focus on in the present paper states that, in the universe or in isolated structures, entropy increases constantly and irreversibly, thus causing a continuous and unidirectional degradat...
Autori: Ionel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27179

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

This paper presents an advanced numerical algorithm for the optimization of the current density distribution in electrochemical applications. The optimization principle consists in the distortion of the electric field by an insulating shield properly positioned between the electrodes. Such a distortion influences the distribution of current density at the electrodes under consideration. The electrochemical problem is approached by a Laplace equation which is numerically solved using a mesh-free ...
Autori: Alexandru Avram
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27199

For a more efficient oxygenation of free surface stationary waters, the air bubble emitted by a fine bubble generator must describe a trajectory which should be as long as possible. This purpose can be achieved by moving the fine bubble generator through water. In the paper there are determined the equations of motions and trajectory of the air bubble in stationary (still) waters. The paper aims to establish the equation of such a trajectory and the manner in which the speed of the moving genera...
Autori: Adrian Costache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27222

The present study was aimed at examining the ability of the natural zeolitic tuff from the Zlatokop deposit in Serbia to remove Pb(II) ions from aqueous solutions under various conditions. It has been found that the adsorption proceeds via an ion-exchange reaction in which the Na+ ions from the clinoptilolite phase of the tuff are replaced to a high degree by aqueous Pb(II) ions. The removal capacity of the clinoptilolite at 298 K varies from 78 mg Pb g–1 (for C0 = 100 mg Pb dm–3) to...
Autori: Djordje Stojakovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27234

The Romanian peat was used as low-cost adsorbent to remove Cd(II) ions from aqueous solutions. The cadmium adsorption capacity of the peat was studied as a function of the solution pH (3-5.5) and temperature (293 – 333 K). Adsorption capacity was found to increase with the pH increasing and temperature decreasing and attained a maximum value of 27.9 mg/g at pH = 5±0.1 (acetate buffer) and 293 K. In addition, various thermodynamic parameters such as free energy change (ΔG0), en...
Autori: Catalin Balan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27276

The paper presents a study concerning the influence of the hydraulic and hydrological connectivity among the oxbow lakes and the restoration of riparian-zones have on aging. Interconnectivity oxbow lakes emerge after complex regulating works for the protection of the shores and bottom of the lakes. Research has analyzed the influence of the hydraulic connectivity of three lakes located in northern Poland on the structure of associated bottom invertebrates – elements that monitor the cond...
Autori: Anca Balan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27342

The paper is focused on a research project aiming to provide conditions for market competitiveness of producers and to guarantee the free movement of Romanian products on the EU. This is done by guaranteeing essential health and safety requirements applicable to work equipment in order to implement policies set out in the strategy EUROPE 2020. This strategy takes into account the priority of: favourable growth of inclusion-promoting an economy with a high rate of employment, ensuring social and ...
Autori: Anca Elena Antonov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27371

The aim of this work was to study the effectiveness of photocatalysis in the removal of contaminants from secondary treated municipal wastewater, on a batch scale. The samples were collected from the outlet of the secondary clarifier in the municipal wastewater plant located at Al Khoudh, Muscat, Sultanate of Oman. The influences of TiO2 catalyst loading and solar radiation exposure time were investigated for the removal of COD and total Coliforms. 60% removal of COD was achieved with a catalyst...
Autori: Anna Jesil Cheriyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27376

The aim of present study was the effective utilization of waste apple for high yield of ethanol using immobilized cells of Saccharomyces cerevisiae S-3S through fed-batch fermentation. Low cost biomaterial was also developed for immobilization. Immobilization was carried out on different inert supports (agar-agar, k-carrageenan, Ca-alginate, sugar cane bagasse and apple bagasse). The results revealed that immobilized cells of S. cerevisiae S-3S gave high yield of ethanol as compared to free c...
Autori: Arifa Tahir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27425

This study investigates the dynamic relationship between economic growth, energy consumption, financial development, and CO2 emissions at macro level in the case of 49 countries from Europe and Central Asia over a two-year period. The research focuses exclusively on country-level characteristics and uses a heteroscedasticity-consistent standard error estimator (HC3) to analyze the aforementioned relationship. The proposed econometric models test whether: i) the level of development of financial ...
Autori: Marilena Mironiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27494

The aim of this study was to examine the adsorption of malachite green dye from aqueous solutions on the waste foundry sand. The effects of contact time, adsorbent amount, pH and initial dye concentration were investigated. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin adsorption isotherm models. The adsorption capacity of waste foundry sand for the removal of malachite green dye was determined with the Langmuir and found to be 23.29 mg/g. The adsorption isothe...
Autori: Elif Hatice Gürkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27536

On freeways with multiple on-ramps, it is a common practice to design a ramp metering strategy so as to regulate the entering rates from ramps and minimize the disruptions on the mainline. Most of the existing studies examine the performance of ramp metering on mobility and safety, rather than their impacts on the environment. This paper focuses on the estimates of vehicle emissions along mainline freeways under various ramp metering strategies. Vehicle speed and acceleration rates were measured...
Autori: Jianbang Du
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27600

This study evaluates the behavior of freeze concentration of cheese whey (CW). Parameters studied were: Chemical Oxygen Demand (COD), Total Dissolved Solids (TDS), Suspended Solids (SS), Total Settleable Solids (TSS), pH and electrical conductivity (EC) in the concentrated cheese whey and in the ice. The final concentration of TDS reached was 25 ± 0.16 %wt for the liquid phase, which corresponds to a reduction of 83% of the initial volume. The COD in the ice fractions had lower values tha...
Autori: Freddy Belén
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27613

β-glucosidases are very important in the improvement of cellulose degradation rates by diminishing the inhibition of end products. Although, cellulase cost has reduced significantly in last decade but still the high costs of biomass saccharification is one of the main challenges for the commercialization of ethanol from LC biomass. In this work, β-glucosidase immobilization in calcium alginate was optimized using response surface methodology. 89% immobilization efficiency was achieved ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27614

The aim of this study is the treatment of Chlorothiazide in an aqueous medium by Electro-Fenton process using a Platinum anode. This pharmaceutical product is used to treat hypertension. Removal rates and mineralization efficiency have been analyzed under different operational conditions. Degradation kinetics well fitted to a pseudo–first–order reaction. Apparent rate constant of the oxidation of Chlorothiazide by electrochemically generated hydroxyl radicals was determined to be 9.4...
Autori: Saied Taieb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27616

The thermal degradation of kenaf (Hibiscus cannabinus) under the effect of several variables (particle size, Ar flow rate, sample initial mass and heating rate) was investigated. From experimental data and by application of various model-free methods (Friedman, Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa), the activation energies (EA) were calculated as a function of conversion. The results obtained allowed to conclude that kenaf follows a multi-stage degradation mechanism, with EA values rang...
Autori: Silvia Román
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27617

FLUCTUATION OF RIVER NETWORK WATER ENVIRONMENTAL CARRYING CAPACITY IN A COMPLICATED RIVER-LAKE SYSTEM    • MINERALOGY AND GEOCHEMICAL DISTRIBUTION OF HEAVY METALS FOR THE FAGUL CETĂȚII TAILINGS, ROMANIA    • ACCUMULATION AND AVAILABILITY OF TRACE ELEMENTS FROM SOIL INTO ORIENTAL TOBACCO GROWN IN MACEDONIA    • OLFACTORY EFFECT ON LANDSCAPE PREFERENCE    • EFFECT OF MOLASSES ADDITION AS BIODEGRADABLE MATERIAL ON PHENOL REMO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27628

Degradation of Clindamycin phosphate (CMP) was studied in aqueous solutions by an anodic oxidation process under galvanostatic conditions. The electrolysis cell consisted of a Ti/SnO2-Sb anode, prepared by dip-coating technique, and a 316 stainless steel cathode, both of which had a surface area of 6 cm2. The effects of critical factors, including CMP concentration, current density, initial pH, and the supporting electrolyte were evaluated. The electrochemical oxidation of CMP was controlled by ...
Autori: Mitra Gholami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27639

Two sets of simulated landfill reactors, namely conventional landfill (CL) and leachate recirculated landfill (RL) were operated to investigate the effect of leachate recirculation on the fractionation of Zn in municipal solid waste (MSW) landfill leachate. Zn in landfill leachate was fractionated into three fractionations: particulate and colloidal matter >0.45 μm, non-labile complexes <0.45 μm and free cations/labile complexes <0.45 μm. The result showed that the recirculatio...
Autori: Jun Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27648

Industrial wastewater is of particular importance. In most wastewater treatments, physicochemical parameters are used to determine the performances which are costly while protozoa can be used as less expensive biological indicators to determine the efficiency of the treatment plant. The purpose of this study was to investigate the relationship between protozoa and physic-chemical characteristics of the Abadan wastewater treatment industry. Samples were collected from wastewater stabilization po...
Autori: Abotaleb Bay
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27694

The adsorption rate and dynamic behavior of the system are important factors as regards the process design and operational control. The aim of this study was to find a suitable kinetic model for the hexavalent chromium removal in a batch reactor. The experimental data were analyzed using four adsorption kinetic models: the pseudo- first and second order equations, the Elovich equation, and the intraparticle diffusion equation, so as to determine the best fit equation of the Cr(VI) adsorption ont...
Autori: Ankica Radjenovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27773

Gaseous toluene biofiltration as affected by ryegrass (Lolium perenne L.) roots was investigated in this study. The results revealed that the populations of bacteria, actinomycetes were larger in the ryegrass rhizosphere than in the bulk soil since ryegrass provided root exudates as major nutrients available for the microorganisms. An increase in the microbial populations in a ryegrass-growing biofilter would significantly stimulate toluene biodegradation in comparison with a vegetation-free bio...
Autori: Zhongjun Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27772

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

This study was carried out to determine the feasibility of applying a freeze concentration technique to rarefy milking wastewater using either a stationary wastewater vessel (the first series of tests) or a rotary ice–making machine (the second series of tests). In this study, we investigated the impact of freezing temperature, initial milking wastewater concentration and vessel depth upon the removal rate of chemical oxygen demand (COD). Results show that when the freezing temperature ...
Autori: Yingjie Dai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27845

This study was carried out to determine the feasibility of applying a freeze-concentration technique to purify wastewater polluted with dye, such as methylene blue (MB) using a stationary wastewater vessel. In this study, we investigated the impact of freezing temperature, initial MB wastewater concentration and vessel depth upon the removal ratio of MB. Results showed that when the freezing temperature was decreased (from –5 °C to –15 °C), the freezing rate increased. The...
Autori: Yingjie Dai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27878

Advanced oxidation process is getting tremendous importance in the treatment techniques for the removal of nonbiodegradable organics from wastewater due to its ability to completely mineralize the pollutants. It uses different methods to produce hydroxyl radicals which are responsible for oxidation of pollutants. In this work, studies on Fenton, ultraviolet radiation (UV) and UVhydrogen peroxide processes for removing acetamiprid, a neonicotinoid insecticide from aqueous solution are carried ...
Autori: Puthenkattil Abdukunji Fasnabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27895

We assessed the variability of the main physico-chemical parameters of drinking water: oxidability, turbidity, conductivity, water hardness, free chlorine concentration, chlorides and nitrates across the four seasons (Spring, Summer, Autumn of 2013 and Winter of 2014). We collected data from several points in the supply network of Satu Mare city, NW of Romania, where the source of drinking water is groundwater. The results revealed significant higher average values in spring for some of the ...
Autori: Thomas Dippong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27928

Removal of excessive ammonium nitrogen (NH+4-N) from aqueous solution has been of considerable concern for several decades. It can be removed by air stripping, a necessary prerequisite is adding enough alkali. This study presented the first attempt to investigate the potential use of ceramsite coated with magnesium hydroxide (CCMH) on the effectiveness of NH+4-N removal coupled with air stripping at ambient temperature without alkali addition. The results showed that the CCMH coupled with air...
Autori: Tianpeng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27940

Watercourses that transit rural / urban areas are susceptible to the phenomenon of aquatic pollution due to various types of polluting species. The important issues of river pollution and of polluting species dispersion, require an approach with predictive tools (models for transport of polluting species) which can evaluate the performance of depollution measures/actions to reduce pollution and to take optimal management decisions. Thus, from January 2017 to May 2017, a monitoring investigati...
Autori: Lorand Toth
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27967

The main objective of this research is to investigate the effects of lime and waste silica fume additive on a silt and its utilization on railway subgrades stabilization. For this purpose, lime and waste silica fume were added to the silty soil in different contents at the soil optimum moisture; then the California Bearing Ratio (CBR) tests were conducted on the soil samples to estimate the favorable mixture design. At the next step, a selected sample was chosen to be exposed to wetting–dr...
Autori: Reza Ziaie Moayed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27972

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Proteins from Hermetia illucens (or Black Soldier Fly, BSF) have been employed in this study as possible source for bioplastic formulation. This type of bioplastic can replace the actual materials employed in agriculture, avoiding the critical issues concerning the soil pollution due to conventional plastic end-life. Different plasticizing agents (glycerol and polyethylene glycol) have been tested and the ability to generate a homogenous film, through wet casting, has been evaluated. Characteriz...
Autori: Silvia Barbi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28074

Photocatalytic processes are among the most efficient treatment methods of waters polluted with recalcitrant organic substances. Nanotubular TiO2 arrays with photocatalytic properties were obtained in the process of titanium anodic oxidation in the fluoridecontaining electrolyte. Under the proposed conditions of electrolysis, a coherent system of tightly adjoining nanotubes was formed with the internal diameter of 60-80 nm and walls thickness up to 60-65 nm, the tubes height being dependent on p...
Autori: Gheorghe Duca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28137

As CO2 concentration levels in the atmosphere are steadily reaching a point of no return, it is paramount that actions are taken towards mitigating emissions by improving the efficiency of existing processes. Sorption-enhanced water-gas shift (SEWGS) combines the water-gas shift reaction with in-situ adsorption of CO2 on potassium-promoted hydrotalcite (K-HTC). This enables a direct conversion of syngas into separate hot streams of H2 at feed pressure and CO2 at regeneration pressure, making th...
Autori: Vlad-Cristian Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28149

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

Advanced oxidation processes (AOPs) are used with high efficiency in wastewater treatment due to the formation of hydroxyl radicals with high oxidation capacity. However, there exists many different variables which affect the efficiency of theses processes as it affects the amount of hydroxyl radicals formed; such as reaction time, pH, temperature, reactant concentrations and catalyst amount. In this study, the removal of 2-chlorophenol (2-CP) and 2,4-dichlorophenol (2,4-DCP), which are highly t...
Autori: Aysun Altikat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28251

The quality of drinking water can be kept under control through the protection of raw water sources and the permanent monitoring and control of the processes of treatment and distribution of drinking water. The dangers and risks faced by drinking water supply systems may arise from inside or outside the system. Water disinfection is the key element behind obtaining and maintaining quality. Chlorine is the most widely used disinfectant, due to its high efficiency. However, it has a major disadvan...
Autori: Alice Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28254

In this study, the change of freeze-thaw test result of unconfined compressive strength of clayey soils reinforced with pine tree sawdust and marble dust was investigated. Mixtures containing 5%, 10% and 15% marble dust and 0.5%, 1% and 1.5% pine tree sawdust were compressed by standard Proctor test with optimum moisture content. After curing the mixture samples for 1, 7 and 28 days at a working room temperature of +21°C, they were subjected to the freeze-thaw test at -21°C, +21°C fo...
Autori: Necmi Yarbasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28342

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349