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Rezultatele pentru hyrogen peroxide

Rezultate gasite: 47

Wet hydrogen peroxide catalytic oxidation of parachlorophenol over clay based catalysts
Environmental Engineering and Management JournalVol. 6Nr. 5
This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

Environmental Engineering and Management Journal, Vol. 1 Nr. 2
Environmental Engineering and Management JournalVol. 1Nr. 2
Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Environmental Engineering and Management Journal, Vol. 4 Nr.4
Environmental Engineering and Management JournalVol. 4Nr. 4
Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

Environmental Engineering and Management Journal, Vol. 6 Nr. 5
Environmental Engineering and Management JournalVol. 6Nr. 5
Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

Environmental Engineering and Management Journal, Vol. 9 Nr. 1
Environmental Engineering and Management JournalVol. 9Nr. 1
? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Phenol degradation in water through a heterogeneous photo-fenton process
Environmental Engineering and Management JournalVol. 6Nr. 6
AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutants
Environmental Engineering and Management JournalVol. 6Nr. 6
AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

A kinetic model for the crystal violet mineralization in water by the electro- fenton process
Environmental Engineering and Management JournalVol. 7Nr. 1
AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

Enhanced decolorization of reactive blue 19 dye from synthetic textile wastewater through uv photolysis in alkaline conditions
Environmental Engineering and Management JournalVol. 7Nr. 2
AbstractLaboratory scale experiments were conducted in order to investigate the photolysis of Reactive Blue 19 (RB 19) dye using UV as the irradiation source in alkaline solution. The effects of operating parameters such as, pH, initial dye concentration, UV dosage, hydrogen peroxide and oxygen have been evaluated. The results indicate that the UV photolysis process in alkaline solution is ideal for decolorizing of RB 19 and it can be taken as a starting step to establish the economical feasibil...
Autori: Abbas Rezaee, Ebrahim Hajizadeh, Gholamreza Mosavi, Mohamadtaghi Ghaneian, Seyyed Jamalodin Hashemian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25245

Environmental Engineering and Management Journal, Vol. 9 Nr. 3
Environmental Engineering and Management JournalVol. 9Nr. 3
? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

Environmental Engineering and Management Journal, Vol. 8 Nr. 3
Environmental Engineering and Management JournalVol. 8Nr. 3
� Bioremediation of contaminated air using a bioscrubber� Quality risk evaluation of the groundwater resources on the moldavian area� Electrochemical characterization of some dental materials in accelerated environmental testing� Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farm� The environmental impact assessment caused by the dykes failure� Revaluation of beer industry byproducts – medical implications� ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

Environmental Engineering and Management Journal, Vol. 8 Nr. 6
Environmental Engineering and Management JournalVol. 8Nr. 6
� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farm
Environmental Engineering and Management JournalVol. 8Nr. 3
Abstract The paper presents the preliminary experimental results performed at laboratory scale set-up for different combined mechanochemical treatments of final effluents from a zootechnical farm from the central Moldavian region of Romania. Because of the high content of pollutants into wastewaters, the soil can be polluted and also the ground waters. To avoid this soil pollution episode, some combined mechano-chemical processes were studied and applied into a specific technological order as...
Autori: Carmen Zaharia, Mioara Surpăţeanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25434

On the influence of ETS - 10 porosity and surface properties in retention of some nanoions and nanomolecules
Environmental Engineering and Management JournalVol. 8Nr. 4
Abstract Mesoporosity of about 7 nm in ETS-10 titanosilicate was generated by postsynthesis treatment with hydrogen peroxide under microwave irradiation, resulting in an increased external surface area of the materials (55 m2/g). The influence of titanosilicate porosity and its surface modification by phosphorus atoms (ET(P)S-10) on the retention of some nanoions (??-emitting radioactive U(VI) and Th(IV) ions) and biomolecules (the proteins cytochrome c, papain, and ??-globulin) was investiga...
Autori: Robert Gradinaru, Sorin O. Valu, Stefan Postolache, Claudiu C. Pavel, Ion Sandu, Karin Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25455

Textile wastewater treatment by homogeneous oxidation with hydrogen peroxide
Environmental Engineering and Management JournalVol. 8Nr. 6
Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Integrated treatment of leachate from municipal waste solid landfill
Environmental Engineering and Management JournalVol. 9Nr. 1
Abstract The present paper proposes an integrated-treatment process of leachate from a municipal landfill, which involves two treatment steps. The first step consists in diminishing the organic content through an advanced oxidation process using ozone and hydrogen peroxide. The second step is performed in order to diminish the content of heavy metals through a sorption process on a natural low-cost biosorbent, thus the traces of organic substances remained after oxidative degradation or oxida...
Autori: Carmen Paduraru, Corneliu Pohontu, Igor Creţescu, Lavinia Tofan, Marius Sebastian Secula, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25589

Environmentally friendly techniques for chemical pulp bleaching
Environmental Engineering and Management JournalVol. 9Nr. 1
Abstract In the last decades there has been a rapid evolution of techniques for production of bleached pulp. Much of these processes have been environmentally driven. New techniques have been developed in order to replace chlorine-based reagents in producing bleached pulp. Reducing the environmental impact of pulp production can be attain by using non-pollutant bleaching reagents like oxygen and related compounds. This paper deals with present findings and general trends in environmentally-s...
Autori: Adrian Catalin Puitel, Alexandru Botar, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25592

Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays
Environmental Engineering and Management JournalVol. 9Nr. 1
Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Chemical oxidation of treated textile effluent by hydrogen peroxide and fenton process
Environmental Engineering and Management JournalVol. 9Nr. 3
Abstract In this study the possibility to apply the oxidation process for treating textile effluents, by using hydrogen peroxide and Fenton process was evaluated through determining the color and chemical oxygen demand (COD) removal. The experimental variables studied include the dosages of hydrogen peroxide and iron salts, oxidation time and pH value. The result showed that oxidation process using hydrogen peroxide alone is inefficient in COD and color removal, since only 25 % of COD removal...
Autori: Abdelnaser Omran, , Marniyanti Mamat Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25631

ENHANCEMENT OF PHENOL OXIDATION BY OZONE IN WASTEWATER. II: KINETIC MODELING
Environmental Engineering and Management JournalVol. 11Nr. 2
Four processes have been used to enhance the ozonation of phenol in water: I-pH increasing (O3-pH), II- hydrogen peroxide addition (O3- H2O2), III- UV irradiation (O3- UV), and in the presence of both H2O2 and UV; IV-(O3- UV- H2O2). In each of these processes the rate of phenol degradation has two components: direct and indirect....
Autori: Eszter Arany, Ildiko Bartalis, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25904

COMBINED CATALYTIC OXIDATION AND ADSORPTION OF PRIORITY ORGANIC POLLUTANTS FOR WASTEWATER RECYCLING
Environmental Engineering and Management JournalVol. 12Nr. 5
AbstractThe increased concentrations of priority pollutants in wastewaters have imposed the completion of conventional treatment withadvanced treatment stages (such as catalytic oxidation, membrane processes, adsorption, ion exchange, etc.) for their removal bychemical degradation and/or physical separation.In this study, 4-chlorophenol (4-CP) is proposed as model-pollutant for the priority organic pollutants present in syntheticwastewaters and several processes which can act as advanced treatme...
Autori: Carmen Teodosiu, Corina Petronela Musteret, Daniela Arsene, Daniela Cailean, George Bârjoveanu, Petru Apopei, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26022

RESPONSE SURFACE METHODOLOGY APPLIED FOR THE OPTIMIZATION OF REACTIVE BLACK 5 DISCOLORATION IN A FENTON-LIKE PROCESS
Environmental Engineering and Management JournalVol. 12Nr. 5
AbstractThere are many treatment methods used to remove color from textile wastewater, and Fenton oxidation, a well known AdvancedOxidation Process is one of the most efficient. Apart of Fe(II), other metal ions have been used as catalysts in Fenton’s Reagent,and Cu(II) proved to be a good alternative.In this study the effect of the concentration of dye, catalyst and hydrogen peroxide were studied and optimized for thediscoloration process of Reactive Black 5 using a Fenton-like process, H2O2/Cu...
Autori: Andrei-Petru Bertea, Armand-Florin Bertea, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26042

LEACHING PROPERTIES OF LEAD PASTE IN SPENT LEAD-ACID BATTERY WITH A HYDROMETALLURGICAL PROCESS AT ROOM TEMPERATURE
Environmental Engineering and Management JournalVol. 12Nr. 11
AbstractIn this study, as part of developing a green recycling process of spent lead-acid battery that can avoid both smelting and electrowinning, leaching agent citric acid and other additives (such as sodium citrate and hydrogen peroxide) in aqueous media were reacted with spent lead-acid battery paste. PbO, PbO2 and PbSO4, which are the three main components in a spent lead-acid battery paste, were leached to form lead citrate precursor which was crystallized and then separated from the solut...
Autori: Xinfeng Zhu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26215

SECONDARY MUNICIPAL EFFLUENT TREATMENT BY CATALYTIC WET HYDROGEN PEROXIDE OXIDATION
Environmental Engineering and Management JournalVol. 13Nr. 9
AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

LEACHING OF METALS FROM WASTE PRINTED CIRCUIT BOARDS (WPCBs) USING SULFURIC AND NITRIC ACIDS
Environmental Engineering and Management JournalVol. 13Nr. 10
AbstractThis study aims to understand the acid-leaching behavior of metals from 2 to 4 mm waste printed circuit boards (WPCBs)containing 22.0% ± 1.1 Cu, 6.7% ± 0.2 Ca, 0.68% ± 0.02 Sn, 0.59 ± 0.01 % Pb, 2.71% ± 0.08 Al, 0.22% ± 0.01 Fe, etc..Copper leaching was increased for sulfuric acid concentrations up to 1.2 mol/L and hydrogen peroxide concentrations of 10.0vol% for a pulp density of 100 g/L at 50°C over 4 h, whereas for the same concentrations of sulfuric acid and hydrogen peroxidecopper l...
Autori: Manoj Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26566

REMOVAL OF AROMATIC COMPOUNDS FROM WASTEWATER BY HEMOGLOBIN SOLUBLE AND IMMOBILIZED ON EUPERGIT CM
Environmental Engineering and Management JournalVol. 13Nr. 10
AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

MAGNETIC CONTAMINATION OF ENVIRONMENT – LABORATORY SIMULATION OF MIXED IRON OXIDES IMPACT ON MICROORGANISM CELLS
Environmental Engineering and Management JournalVol. 14Nr. 3
Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

ENHANCING THE FENTON PROCESS BY UV LIGHT APPLIED IN TEXTILE WASTEWATER TREATMENT
Environmental Engineering and Management JournalVol. 14Nr. 3
Abstract Nowadays, an efficient wastewater management involves the use of advanced treatment technologies able to decompose hardly biodegradable compounds with reasonable costs at the lowest possible environmental impact. In our work we used one of the most efficient advanced wastewater treatment, the Fenton reaction and its photo-assisted version. The hydrogen peroxide was the oxidizer; despite its relatively high cost, its high activity in oxidizing of a large variety of organic persistent...
Autori: Vasilica-Ancuta Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26677

DECOLORIZATION OF ORANGE II BY HETEROGENEOUS FENTON PROCESS USING GOETHITE AS CATALYST
Environmental Engineering and Management JournalVol. 14Nr. 4
Abstract The effect of goethite addition, hydrogen peroxide concentration, initial pH, hydroxyl radical scavenger and initial dye concentration on the decolorization of Orange II by Fenton-like process was investigated. The results showed that the decolorization rate increased with goethite addition and hydrogen peroxide concentration, but decreased with the increase of initial dye concentration. There existed an optimal initial pH to achieve the highest decolorization rate. The presence of ...
Autori: Hui Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26693

COMPARISON OF PARTICLE-SIZE ANALYZING LABORATORY METHODS
Environmental Engineering and Management JournalVol. 14Nr. 5
Abstract Particle size distribution is one of the most influential factors of most soil physical and even some soil chemical characteristics. As modern measurement techniques are being introduced, the need for comparing new methods with older methodologies arises because comparability means data continuity. Here, three institutes conducted a comparison of particle size measurement among the laser, areometer and pipette techniques. The purpose of the comparison was to a) discover any differen...
Autori: Csaba Centeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26733

CHANGES IN LOW MOLECULAR WEIGHT ORGANIC ACIDS AND ANTIOXIDATIVE ENZYME ACTIVITIES OF WETLAND PLANTS UNDER METAL STRESSES
Environmental Engineering and Management JournalVol. 15Nr. 7
The release of low molecular weight (LMW) organic acids under lead (Pb) and zinc (Zn) stresses in Typha latifolia (T. Latifolia) and Vetiver zizanioides (V. zizanioides) were investigated. In addition, changes in antioxidative enzymes: superoxide dismutase (SOD) and peroxidase (POD) in the leaves of T. Latifolia under Pb stress were also examined. Amongst the eight types of LMW organic acids detected in the present study, oxalic acid was found to be the most dominant during Pb and Zn treatmen...
Autori: Yu Bon Man
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27092

STUDIES ON THE USE OF CALCIUM HYPOCHLORITE IN THE TiO2 MEDIATED DEGRADATION OF PHARMACEUTICAL WASTEWATER
Environmental Engineering and Management JournalVol. 15Nr. 8
The present study investigates the effect of addition of calcium hypochlorite in the titanium dioxide (TiO2) mediated degradation of bio-recalcitrant wastewater from pharmaceutical industry. The degradation studies were carried out in photoreactor irradiated with ultraviolet (UV) light at 365 nm under slurry mode. The reduction in chemical oxygen demand (COD) was estimated as an index of degradation. The influence of process parameters viz., catalyst dose, pH, oxidant concentration and source...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27097

ELECTROCHEMICAL CATALYTIC DEGRADATION AND BIODEGRADABILITY ENHANCEMENT OF REAL TEXTILE WASTEWATER BY ANODIC AND CATHODIC REACTIONS
Environmental Engineering and Management JournalVol. 15Nr. 10
An electro-Fenton process was carried out using undivided cell containing tridimensional graphite felt cathode for treatment of real textile wastewater. The study is essentially focused on effects of pH, applied current and transition metal types (Fe2+ and Cu2+) as catalysts on the electrochemical degradation efficiency based on color and COD removal and BOD5/COD value. The results indicated that pH 3 and applied current of 150 mA are the optimum conditions for decolorization and COD removal of ...
Autori: Akbar Eslami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27167

SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF Mg-Zn FERRITES SUPPORTED ON ALUMINA
Environmental Engineering and Management JournalVol. 15Nr. 11
Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

A POSSIBLE DISTRIBUTION OF NITROGEN COMPOUNDS DURING NATURAL MINERAL WATERS DISINFECTION TREATMENT
Environmental Engineering and Management JournalVol. 16Nr. 3
This study aims to evaluate the effects of Fe2+ present in carbonated natural mineral waters on the decomposition of hydrogen peroxide (H2O2) used as sanitizing agent of the collector water tanks and the oxidation of NH4+ to NO3– and NO2– nitrogen compounds from bottled carbonated natural mineral water by the Fenton process. This evaluation suggests that the distribution of the nitrogen compounds, at certain concentrations of H2O2 is influenced by facilitated Fenton reaction in the p...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27279

REMOVAL OF DICLOFENAC FROM SECONDARY WASTEWATER EFFLUENTS BY FENTON BASED PROCESSES
Environmental Engineering and Management JournalVol. 16Nr. 4
This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

ENVIRONMENTALLY FRIENDLY ENZYME-CATALYZED POLYMERIZATION OF A NOVEL PHENOXY-KETIMINE
Environmental Engineering and Management JournalVol. 16Nr. 7
The monomer with ketimine side group, 2-(1-(benzylimino)ethyl)phenol (2-BEP), was synthesized from the condensation of 2- hydroxyacetophenone and benzyl amine. The enzymatic oxidative polymerization of 2-BEP was performed in the presence of hydrogen peroxide using horseradish peroxidase (HRP) as catalyst. The oxidation reaction was carried out in various solvents and phosphate buffers at room temperature. These studies have shown that a dark brown polymer was successfully synthesized by utilizin...
Autori: Senem Tapan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27377

DECOLORIZATION OF CHLOROLIGNIN WITH HYDROGEN PEROXIDE IN THE PRESENCE OF SILICA [BIS(DIBENZOYLMETHIDO) COPPER II] AS CATALYST
Environmental Engineering and Management JournalVol. 16Nr. 10
This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

ENZYMATIC AND CHEMICAL DELIGNIFICATION OF KRAFT WOOD PULP: OPTIMIZATION AND SEQUENTIAL STUDIES
Environmental Engineering and Management JournalVol. 16Nr. 11
The delignification of wood pulp using hydrogen peroxide and xylanase enzyme in an ultrasonicator was studied at different process conditions. The factors influencing the chemical delignification were studied simultaneously using the Box-Behnken design of experiments. The mathematical model for Kappa reduction as functions of consistency of the pulp, concentration of peroxide and the temperature of delignification was developed. The response optimization studies for minimizing the Kappa numb...
Autori: Palaniappan Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27480

REMOVAL OF DYES FROM WATER BY GALVANOCOAGULATION
Environmental Engineering and Management JournalVol. 17Nr. 1
Galvanocoagulation (GC) utilizing metallic iron chips and granular coke was studied as a potential technique for decolorization of dye-containing aqueous solutions. GC and chemical coagulation by inorganic metallic coagulants such as iron sulfates (Fe2+, Fe3+) were examined for the removal of individual dyes, used in the fur industry, from model aqueous solutions. The role of metal cations when progressively electrogenerated in situ was compared to when they are added simultaneously. The superio...
Autori: Marina R. Sizykh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27526

OPTIMIZATION OF PHENOLIC COMPOUNDS ABATEMENT IN OLIVE MILL WASTEWATER BY FENTON’S LIKE TREATMENT WITH H2O2/Cu2+ UNDER MICROWAVE USING EXPERIMENTAL DESIGN
Environmental Engineering and Management JournalVol. 17Nr. 5
This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

EFFECTS OF α-CYPERMETHRIN PESTICIDE ON DNA STABILITY AND OXIDATIVE ENZYMES IN MAIZE (Zea mays)
Environmental Engineering and Management JournalVol. 17Nr. 2
α-cypermethrin is a pyrethroid and environmental genotoxic pesticide extensively used worldwide for agricultural applications. However, like other pesticides, it affects non-target organisms as well as target organisms and causes various toxic effects. To evaluate α-cypermethrin toxicity in non-target organisms, the effect of α-cypermethrin on the activity of malondialdehyde (MDA, an indicator of lipid peroxidation) content, antioxidant enzymes (superoxide dismutase, SOD; perox...
Autori: Ozkan Aksakal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27647

OPTIMIZATION OF ADVANCED OXIDATION PROCESSES FOR THE REMOVAL OF ACETAMIPRID FROM WASTEWATER
Environmental Engineering and Management JournalVol. 18Nr. 1
Advanced oxidation process is getting tremendous importance in the treatment techniques for the removal of nonbiodegradable organics from wastewater due to its ability to completely mineralize the pollutants. It uses different methods to produce hydroxyl radicals which are responsible for oxidation of pollutants. In this work, studies on Fenton, ultraviolet radiation (UV) and UVhydrogen peroxide processes for removing acetamiprid, a neonicotinoid insecticide from aqueous solution are carried ...
Autori: Puthenkattil Abdukunji Fasnabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27895

SIMULTANEOUS REMOVAL AND/OR RECOVERY OF Cr(VI) AND Cr(III) USING A DOUBLE MFC TECHNIQUE
Environmental Engineering and Management JournalVol. 18Nr. 1
In order to reduce Cr(VI) and Cr(III) simultaneously, a double microbial fuel cell (MFC) system was employed to treat Crcontaining wastewater. Cr(VI)-MFC used Cr(VI) as a catholyte to supply the generated power to Cr(III)-MFC, while the latter MFC functioned as an external load resistor of the former one. Buffer characteristics of the catholyte greatly affected the reduction of chromium ions. At an initial pH of 2.0, Cr(VI) removal increased from 49.9% to 99.9% when KH2PO4 was added. Keeping ...
Autori: Fang Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27896

INFLUENCE OF CONTROLLED RELEASE FERTILIZERS ON Lilium regale SPECIES GROWTH AND FLOWERING
Environmental Engineering and Management JournalVol. 18Nr. 5
Our research aims to establish the influence of Osmocote®Pro fertilizer on ornamental characteristics, photosynthetic pigments content, superoxide dismutase and peroxidase activities for Lillium regale species. The tests were organized in four variants, each with three replicates, each replicate consisting of 10 bulbs. The growth of plants in the four experimental variants was achieved without fertilization in case of the control variant (M) and under fertilization conditions with Osmocot...
Autori: Maria Brînză
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28005

CATALYTIC OZONATION ON IRON-LOADED RICE HUSK ASH/PEANUT SHELL ASH FOR THE REMOVAL OF ERYTHROMYCIN IN WATER
Environmental Engineering and Management JournalVol. 19Nr. 5
This study investigates the mechanism and efficiency of catalytic ozonation process on iron-loaded rice husk ash (Fe-RHA) and Peanut shell ash (Fe-PSA) for the Erythromycin removal from aqueous solution. In the current study, the COD removal efficiency of Erythromycin was studied in simple ozonation and catalytic ozonation using Fe-RHA/O3 and Fe-PSA/O3 processes. The operational parameters such as pH effect, catalyst dose, and reuse performance of the catalyst were studied. Moreover, the hydroxy...
Autori: Shama Nazir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28208

EFFECT OF THIOSULFONATE-BIOSURFACTANT COMPOSITIONS ON PLANTS GROWN IN OIL POLLUTED SOIL
Environmental Engineering and Management JournalVol. 19Nr. 11
The work is devoted to the search and investigation of the properties of the effective environmentally friendly phytoremediation activators. An integrated approach was used to evaluate the effect of the compositions of thiosulfonates with rhamnolipid biosurfactant on remediation plants. The biochemical and biophysical analysis of the rapeseed and ryegrass plants grown in the oil polluted soil - photosynthetic pigments, indicators of oxidative reactions and electrical impedance characteristics we...
Autori: Olena Yaremkevych
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28319

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