AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

This paper presents a study on the integration of two advanced treatment processes for the removal of priority organic processes from wastewaters: catalytic oxidation (Fenton homogenous process) followed by ultrafiltration. The aim of this study was to assess the removal efficiency for 4-chlorophenol (used as model pollutant), as well as the decrease in effluent toxicity in various processes conditions. The experiments have mainly focused on studying the effect of the oxidant dose of the catalyt...
Autori: , Cezar Catrinescu, Corina Petronela Musteret, Daniela Arsene, George Barjoveanu, Petru Apopei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25834

The first part of this work presents the development and implementation in the Benchmark Simulation Model No 1 (BSM1) of a modified Activated Sludge Model No 3 (ASM3). The enhanced ASM3 presented in this study has three modifications compared to the original ASM3. The first modification is the representation of the simultaneous heterotrophic biomass growth on the primary substrate and on the internal storage products. Second, nitrification is modeled as a two-step process with nitrite as an inte...
Autori: George Simion Ostace, Paul Şerban Agachi, Vasile Mircea Cristea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25865

AbstractThe increased concentrations of priority pollutants in wastewaters have imposed the completion of conventional treatment withadvanced treatment stages (such as catalytic oxidation, membrane processes, adsorption, ion exchange, etc.) for their removal bychemical degradation and/or physical separation.In this study, 4-chlorophenol (4-CP) is proposed as model-pollutant for the priority organic pollutants present in syntheticwastewaters and several processes which can act as advanced treatme...
Autori: Carmen Teodosiu, Corina Petronela Musteret, Daniela Arsene, Daniela Cailean, George Bârjoveanu, Petru Apopei, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26022

AbstractA lab-scale packed-bed biofilm channel reactor that operates as a plug-flow system equipped with top aeration modules wasconstructed and evaluated. To assess the reactor performance a microbial community able to degrade linuron was used. Changingthe fluid flow rates and the linuron concentrations in the inflowing medium the volumetric loading rates of linuron (BV,L) weregradually increased from 0.29 to 14.93 mg/Lh. During the operation of the reactor, an airflow rate of 0.15 ą 0.05 L/min...
Autori: Erick Marrón-Montiel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26465

AbstractThe objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilicacid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to modelthe system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of appliedtreatment process was conducted on...
Autori: Sanja Papić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26569

Abstract Established applications of emulsion liquid membranes (ELM) refer to refining in hydrocarbons and hydrometallurgical processing, rehabilitation of poisoned patients. In this work we investigated the separation of aromatic compounds of biological interest, more often encountered as intermediates in dyes and drugs industry: aniline, nitrobenzene, ortho and para-toluidine, using emulsion liquid membranes. The experimental results showed that in the case of basic substances separation t...
Autori: Alexandra Raluca Miron
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26650

Abstract The adaptation of commercially available ion-selective electrodes (ISEs) for use in wastewater matrices was demonstrated using multivariate analysis and optimization with the Microsoft Excel Solver tool. The electrodes were characterized in pure analyte solutions, and their parameters were estimated using multivariate analysis and Solver optimization. The ammonium, nitrate, and nitrite ions were measured in model systems that were designed to simulate wastewater. The accuracy of the...
Autori: Natalija Koprivanac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26687

Degradation of Clindamycin phosphate (CMP) was studied in aqueous solutions by an anodic oxidation process under galvanostatic conditions. The electrolysis cell consisted of a Ti/SnO2-Sb anode, prepared by dip-coating technique, and a 316 stainless steel cathode, both of which had a surface area of 6 cm2. The effects of critical factors, including CMP concentration, current density, initial pH, and the supporting electrolyte were evaluated. The electrochemical oxidation of CMP was controlled by ...
Autori: Mitra Gholami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27639

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974