<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

Liquid petroleum fuel products such as High Speed Diesel (HSD), Superior Kerosene Oil (SKO), Motor Sprit (MS) are stored in floating roof tanks under atmospheric conditions. The Storage tanks are provided with fittings like rimseals, gauge float wells,sample ports, deck drains and access hatches and becomes the sources of hydrocarbon vapour emissions released to the atmosphere. The net throughput and the annual turnovers of the fuel products and annual average meteorological conditions were cons...
Autori: Bandari Chakradhar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25117

During 2005 and 2006, in the Infectious Diseases Hospital in IaÂ?i, there were admitted 26 patients suffering by Leptospirosis. The clinical investigations followed the tests of inflammation, the renal and hepatic proofs, the cefalo-rahidian liquid’s aspect, the ELISA Leptospirosis serum tests etc. The Leptospirosis etiology shown that on 50% of the patients, the affection was owed to L.ichterohemoragiae. The average cost of the treatment for a patient was evaluated as around 1000 Euro. The pa...
Autori: Carmen Dorobăţ, Doina Carmen Manciuc, Mihai Nicu, Mihnea Hurmuzache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25120

AbstractThe goal of this paper is to examine the potential for ecologically and economically sustainable kraft pulp mills. This paper reviews technical and scientific literature on a wide range of factors that will influence the overall impact of a pulp mill on its total environment. The emphasis is on efforts to achieve "closed-loop," or Totally Effluent Free (TEF) mills which eliminate all liquid effluent and minimize the quantity and environmental impact of air and land discharges. An attempt...
Autori: Adrian Puitel, Dan Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25202

AbstractThe paper describes the synthesis and characterization of layered double hydroxides (LDH) intercalated with 4,6-dinitro-o-cresol(DNOC) and 2,6-dichlorobenzonitrile (2,6DBN) by anionic exchange method. The incorporation of the organic pesticides in the structure of layered double hydroxides can offer premises to increase the pesticide active life by reducing its volatilization, controlling the release of the pesticide from the layered structure and decreasing the pesticide adsorption in s...
Autori: Gabriela Lisa, Marcel Ionel Popa, Mihaela Frunza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25144

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Contain all the articles from this issue:ICEEM/01 -- Environmental Management Section Corporate environmental competence: A concept for characterising and assessing the environmental practice in companies and product chainsMichael S?¸gaard J?¸rgensen, Marianne Forman Life cycle assessment of some alternatives for the supply of thermal energy in the municipality of Iasi (Romania).Nicolae Peiu Management options for the industrial and municipal wastes in the city of Iasi Carmen Teod...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25169

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractAn assessment of acide drainage forming potential for a mining waste material resulted in a former mine of nonferrous and precious metals ore has been made. The waste material has the following contents: 2,20?ˇ2,28% sulphide sulphur, 2,53?ˇ2,58% Fe, 0,07% Cu, 0,05% Zn, 0,36?ˇ0,40% Pb, 0,008?ˇ0,013% Ca and 3,85?ˇ7,97% sulphate. Bacterial leaching tests in percolating columns during 380 days have been made. The leaching liquor has been recirculated at a liquid:solid ratio of 1L:1kg. After ...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25239

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractAdvanced closing of paper machine circuits results in the accumulation of the dissolved and colloidal substances (DCS) in the process water. At a critical concentration, the DCS are destabilizing even by small variations in paper machine parameters, producing operational and product quality problems. This article presents results of lab experiments simulating the process water recycling in short circuit of paper machine, without and with addition of fixing agents. Tests were performing w...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25261

AbstractThe effective mass transfer area of a Mellapak 750 Y structured packing was measured in a bench-scale plant with a column having an internal diameter of 100mm, and a packing height of 518 mm, using a broad range of gas and liquid flow rates. The absorption of carbon dioxide into natrium hydroxide aqueous solutions of 0.5 and 1.0 mol/L has been employed as test reaction. The validity of data obtained was tested by checking the two conditions of fast pseudo first order irreversible reactio...
Autori: Anton Friedl, Ilie Siminiceanu, Michael Harasek, Mihaela Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25264

AbstractConsidering that three-phase dispersions are common in chemical engineering and biotechnology, and with increasing airlift reactor applications to chemical and biotechnological processes, a experimental study was undertaken in order to investigate the liquid phase hydrodynamics and dispersion in an external-loop airlift reactor on laboratory scale. Experiments were conducted in order to find a relationship between relevant hydrodynamic and mixing parameters of a solidsuspended exter...
Autori: Florina Ungureanu, Maria Gavrilescu, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25268

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractGroundwater is an important source of drinking water, especially for rural population. In the last years, bacteria, nitrate, organic chemicals and other pollutants existing in groundwater have increased public concern about the quality of groundwater. Groundwater provides about 22% of all freshwater withdrawals; 37% of agricultural use (mostly for irrigation); 37% of the public water supply withdrawals; 51% of all drinking water for the total population and 99% of drinking water for the ...
Autori: Ancuţa Rotaru, Paulica Raileanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25329

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

AbstractPulsed high voltage discharge technology is a newly developed method for knock out viruses in blood with various electrohydraulic discharge reactors. The aim of this study is to investigate the effect of an electrohydraulic discharge treatment system on Hepatitis C virus (HCV) behaviour. The electrohydraulic discharge (EHD) reactor consist of high voltage point discharge electrode above blood surface and cylindrical ground copper electrode containing the blood (in the same time act as th...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25362

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

AbstractThe study presents the processing possibilities for marc resulted as still residue from the distillation of fermented fruits in view to obtain a compacted solid fuel. Initial marc composition (carbon, hydrogen, nitrogen, sulphur and oxygen contents) determined by elemental analysis is evidenced, as well as technical characterisation (ash and moisture contents) and ash's qualitative composition, chemical characterisation of the liquid phase (pH, total phosphorus, acidity and conductivity)...
Autori: Daniela Simina Stefan, Anca-Ileana Penu, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25391

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract The potential of using ultrasonic irradiation and microbiological treatment for the removal bis(1-chloro-2-propyl) ether from aqueous solutions has been investigated. Experiments were performed in a continuous bioreactor, 3500 mL volume, and in an ultrasonic bath respectively, using frequencies of 38+1kHz and applying a power of 30 W. Under these conditions, the sonochemical conversion of ether was found to be superior to the biological one. The ultrasound method was improved by air ...
Autori: Mihaela Iordache, Vasile Lucian Pavel, Lim Myunghee, Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25403

Abstract Pollution with toxic metals is a serious concern, because once these elements enter in the soil they can be present for a long time, with the potential contamination of drinking water sources. Certain metals in soil may be taken up by plants which are subsequently harvest for human consumption. Our objective was to study the presence of heavy metals in soils, groundwater sources, some medicinal plants from areas of the water sources and in its watery extracts. All of the samples, af...
Autori: Diana Diaconu, Victor Nastase, Mara Mihaela Nanau, Ovidiu Nechifor, Elena Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25411

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract The paper presents the capacity of biodegradation of selected microorganism, cultivated on liquid culture media to which diesel was added in different amounts, to determine petroleum products and process efficiency. The optimum necessary conditions for development of microbial strains (pH, temperature, the quantities petroleum product / inoculum) have been established with the help of an experimental optimization program, SIMPLEX....
Autori: Dana-Camelia Cocut, Cornel Cojocaru, Mariana Diaconu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25414

Abstract Using slag in steel making represents a challenge for road construction industry and decreasing environment interactions also.Steel making slag wit granulations of < 10 mm, which today have not a sure solution, represents the research object. The technological research solutions have aimed reducing CaO free content in these slugs, and reducing slug fraction with granulationof ...
Autori: Florian Zaman, Mirela Gabriela Sohaciu, Ecaterina Matei, Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25439

Abstract Spent hydroprocessing catalysts from petroleum refining industries have been classified as hazardous wastes due to their content in heavy metal and persistent organic pollutants (POPs). The aim of our paper determine the polycyclic aromatic hydrocarbons (PAHs) residues contents in spent catalysts samples from four different units of the Romanian refinery Rompetrol Rafinare,Constanta: Hydrogen (H), Gas Desulfurization Sulfur Recovery (GDSR), Hydrofining Turbojet Kerosene (HTK) and Pet...
Autori: Camelia Draghici, , , Gabriela Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25449

Abstract Electroflotocoagulation is used for the treatment of liquid wastes of various origins, containing suspended matter. The metal hydroxide formed by electrochemical metallic ions generation acts to aggregate the colloidal impurities, and the hydrogen bubbles evolved at the cathode allow flotation of foam containing the impurities. The aggregates formed (containing the impurities) and lifted above the solution can then be removed. Electroflotocoagulation (simultaneous electrocoagulation ...
Autori: Marius Constantin Mirica, Mirela Ioana Iorga, Adina Segneanu, Ionel Balcu, Doru Buzatu, Cristian Vaszilcsin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25457

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract This paper presents an experimentally study of the anionic iodide separation from a mixture with immobilized liquid membrane. The experiments were carried out in a double jet installation. In order to intensify the transfer of iodide ions from the source phase to the receiving phase, the both phases are dispersed as droplets in the membrane and the hydrodynamic parameters of the dispersed phases are measured with the photographic method. The photos of the droplets were taken with a C...
Autori: Mihaela Emanuela Craciun, Mihaela Mihai, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25476

Abstract Knowledge of the binding mechanisms of heavy metals to cement minerals is essential for the prediction of the long-term leachability of cement-based solidified waste containing heavy metals. In this paper, the sorption of chromate ions onto calciumsilicate- hydrate (C-S-H) in equilibrated aqueous suspensions was investigated as a function of liquid-to-solid ratio. The hypothesis of super-equivalent adsorption was assumed to be involved in chromate ions immobilization. This hypothesis...
Autori: Constantin Bobirica, Ionel Constantinescu, Liliana Bobirica,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25478

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract Biofuels represent a possibility for renewable resources conversion, storage and distribution. Today, diesel oil is commercialized only blended with biodiesel, and according to the 30/2003 Directive of the EU, 5.75% of the total fuels used in the transportation sector must be represented by biofuels by the end of 2010. Biodiesel can be produced from vegetable oils, animal fats and used oils. Viscosity is one of the most important characteristics of liquid fuels. The viscosity of liqu...
Autori: Irina Nita, Dan Mandalopol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25499

Abstract The paper presents the experimental results, obtained using a pilot installation and hot-water boilers for reducing the pollutants emissions in combustion of heavy liquid fuels by using of additives for catalyzing of burning processes. The experiments were made using additives based on iron and cerium carboxylates. Experimental results, which are presented both in variant of heavy liquid fuels burning with additives and without additives, highlight the reducing of pollutants emissio...
Autori: Aurel Gaba, Stefania Iordache, Mircea Vladescu, Dan Ungureanu, Petrica Vizureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25509

Abstract Waste management hierarchy has as priorities waste recycling and energy recovery. Unfortunately, Romania is in the situation so as the waste landfilling is still considered as a suitable solution for waste management. European Union imposed a number of regulations and programs in the field of waste treatment and management that Romania must comply. The paper describes some aspects regarding characterization of the leachate originating from the Tomesti landfill (situated in Iasi County...
Autori: Ana-Maria Schiopu, Brindusa Mihaela Robu, Ion Apostol, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25523

Abstract The use of appropriate leaching tests and leaching models can help to predict the hazardous components release from cementbased solidified waste during either utilization or disposal. Numerous parameters influence the leaching rates such as grain size/specimen size,ccc liquid-to-solid ratio, pH value of the leachate, leaching time etc. This study evaluates the effect of initial liquid-to-solid ratio of cement paste on the release of copper from cement-based solidified waste. Dynamic ...
Autori: Constantin Bobirica, Liliana Bobirica, , Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25527

Abstract Geopolymerization is a continuous developing field of research for utilizing solid waste and by-products. It provides a solution to many problems where hazardous residue has to be treated and stored under critical environmental conditions. Consumption of fly ash in the manufacture of geopolymer is an important strategy in making materials more environmentally friendly. Fly ash has been chosen as a base material in order to utilize this industrial waste. Previous researches have show...
Autori: Maria Harja, Marinela Bărbuţă, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25542

Abstract Plasma is often called the fourth state of matter. It is distinct from other lower-energy states of matter, most commonly solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. Plasma technique may use any gas or gas mixture, within equipment limitations. Each gas or mixture of gases produces distinctive plasma, making possible a very diverse range of chemical environments. Besides the recombination mechanisms developed...
Autori: Marian I. Totolin, Ghiocel E. Ioanid, Iordana Neamtu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25550

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

? POLLUTION PREVENTION, A KEY TO ECONOMIC AND ENVIRONMENTAL SUSTAINABILITY ? A COMPARISON BETWEEN DIFFERENT SCENARIOS OF ROMANIAN MUNICIPAL SOLID WASTE TREATMENT BEFORE LANDFILLING ? A STUDY ON ENERGY CONSUMPTION IN ROMANIA ? ENVIRONMENTAL INFLUENCES ON STRESSED METALLIC SURFACES ? ASPECTS OF HYDRODYNAMICS AND MASS TRANSFER IN DIFFUSED AERATION SYSTEMS ? THE STATUS OF SOME SELECTED HEAVY METALS IN ROADSIDE SOILS OF BURSA PROVINCE, TURKEY ? PREPARATION AND CHARACTERI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25656

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

Abstract:In this paper, the influence of two types of imidazolium-based ionic liquids (ILs) on the properties of sycamore maple (Acer pseudoplatanus) veneers, at 25 0C, 60 0C and 80 0C has been studied by using contact angle measurements and Fourier transform infrared spectroscopy analysis. The measurements showed that wood wettabillity is increased by IL treatment. It has been determined that the ILs decrease the crystallinity and improve the flexibility of the cellulose matrix. Also, it has be...
Autori: Attila Porzsolt, Catalin Croitoru, Christian Friedrich, Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25737

Abstract:The paper presents the results obtained when using one ketonic Mannich base BM (1-(2’-hydroxyphenyl)-3-(1-piperidinylamino)propan-1-one hydrochloride) as corrosion inhibitor in saline environment, for different types of carbon steels,with various alloying elements. The Mannich base was synthesized and used in corrosion experiments, in concentrations varyingfrom 0….1300 ppm. The corrosion experiments were performed by potentiodynamic polarization studies, with 50 mVs-1 scanrate. The ...
Autori: Andreea Milea, Cristina Bogatu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25754

Abstract:The increasing of energy consumption and fossil fuel emissions (especially CO2, SO2 and NOx) and the limitation of crude oilreserves, determined a growing trend toward renewable energy technologies, like solar, wind, geo-thermal energy and biomass forbiofuels.From all the renewable energies sources, biomass attracts more and more interest being a renewable resource with economicpotential, which can be found all over the world, with positive environmental properties due to neutral emissi...
Autori: Anca Sauciuc, Angela Potetz, Georg Schlaub, Gerald Weber, Hermann Hofbauer, Lucia Dumitrescu, Reinhard Rauch, Ziad Abosteif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25762

Abstract:In this paper, the mathematical model is improved by considering the density variations of the liquid from the pollution source vs.pollutant’s concentration of this liquid and by including the sorption-desorption term (SDT), which takes into account thisphysical process, played by a first-order decay model defined by two coefficients and an exponent. In order to practically use thisimproved mathematical model, the authors inferred the calculating relationships from automatic processin...
Autori: Daniel Bucur, Esmeralda Chiorescu, Gheorghe Ţigaret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25783

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

The reactive extractions of propionic acid with TOA dissolved in three solvents with different dielectric constants (dichloromethane, butyl acetate, n-heptane) without and with 1-octanol as phase modifier have been comparatively analyzed. The results indicated that the mechanism of the interfacial reaction between acid and extractant is controlled by the organic phase polarity. In absence of 1-octanol, the structures of the extracted complexes are RCOOH.Q2 for dichloromethane and butyl acetate, ...
Autori: Alexandra Cârlescu, Anca-Irina Galaction, Dan Caşcaval, Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25938

Polycyclic aromatic hydrocarbons (PAHs) are by-products of petrol transformation; a report prepared by ICON, London, United Kingdom in 2001, showed that the principal sources of polycyclic aromatic hydrocarbons in wastewater are domestic usage, storm runoff and commercial effluent. This work presents the results on 14 commonly occurring and/or highly carcinogenic PAH compounds listed as priority pollutants by the United States Environmental Protection Agency and the European Union. Wastewater sa...
Autori: Dumitru Ristoiu, Edward Muntean, Livia Alhafez, Nicoleta Muntean, Radu Mihaiescu, Tania Mihaiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25847

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

The paper aims to present the environmental impact of pulp and paper manufacturing and the most important production and control practices to minimizing this impact. The environmental consequences of manufacturing pulp and paper from pulping and bleaching processes are discussed in qualitative and quantitative terms. In these processes, sulfur compounds and nitrogen oxides are emitted to the air, and chlorinated and organic compounds and nutrients are discharged to the wastewaters. Large quantit...
Autori: Adrian Catalin Puitel, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25857

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

Herbicides industry is a large consumer of water, as well as a major wastewater generator, its effluents contain priority organic pollutants in very high concentrations which have severe effects on human health and on the environment due to their toxicity and bio-recalcitrant nature, persistence in the environment and bioaccumulation. A vast number of herbicides and other priority organic pollutants have been found in wastewater effluents, surface water, and drinking water around the world. The ...
Autori: Bianca Weinberg,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25874

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

AbstractIn this paper integrated network of continuous reactors for the decontamination of gaseous flows in heterogeneouscatalytic gas-liquid-solid – also applicable for bioremediation systems is investigated. For this purpose, duringprocess integration we have identified strategies to develop an optimal system for a variety of well-definedrequirements and to discover ways to ensure cost efficiency to achieve the requirements of sustainable industry in theframe of knowledge-based sustainable eco...
Autori: Maria Gavrilescu, Oana Marlena Penciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25977

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractIn spite of the fact that concern on water quality protection raised in the last decades heavy metals pollution still represents agreat threat for both human health and environment quality. Ion exchange proved to be an effective technique for industrialwastewaters treatment, as long as it ensures an effective recovery of valuable compounds. The main purpose of this work is toassess the performances of a commercial ion resin sort (a strong basic anionic resin – VIONIT AT 21), to remove ch...
Autori: Alexandra Raluca Miron, Cristina Costache, Cristina Modrogan, Dumitru Giani Apostol, Oanamari Daniela Butucea, Redha Kouachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26025

AbstractBasic principles for assessing phytotoxicity are the same whether the test compound is a heavy metal, herbicide, fungicide,insecticide or other toxic compounds. The difference lies not in the method of evaluation, but in the experimental program andworking methodology.In this paper the phytotoxic effects of heavy metals, Cr (VI) and Cd (II) on plants germination and growth were studied. Stocksolutions of the two heavy metals were prepared at a concentration of 1000 mg/L, in distilled wat...
Autori: Dana Luminiţa Sobariu, , Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26062

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractThe ozone oxidation and disinfection stages constitute important technological phases in the modern systems of water treatment,both as unitary stages as integrated ones into systems that use advanced oxidation processes (AOP). More than half of thewater/ozone contact systems used nowadays in the water treatment plants are based on systems of contact in the bubble column.This work here aims at experimentally analysing, in terms of scale, a water-ozone contact system in the bubble column a...
Autori: Sorin Claudiu Ulinici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26088

AbstractA new approach to environmental protection management is the aerobic microbial digestion of food industry wastewaters byusing those waters as substrate, while the pollutants contained work also as oxygen-vectors. In biotechnology, oxygen masstransfer is a key parameter involved in the design and operation of mixing–sparging bioreactors and it can be analyzed by meansof the oxygen mass transfer coefficient (kLa). The influence of a second liquid phase with higher oxygen affinity (in this ...
Autori: Elena Folescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26097

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract This study describes a reversed-phase high-performance liquid chromatography (RP-HPLC) method for the analysis of several carbonyl compounds in air samples. The air samples were collected using a passive sampling method and cartridges based on florisil impregnated with 2,4-dinitrophenylhydrazine (2,4-DNPH). After derivatization the carbonyl compounds were analyzed by liquid chromatography technique coupled with UV detection. The developed RP-HPLC method was used to analyze...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26104

Abstract Recently, a new failure probability index was introduced that characterizes the operation of highly sensitive chemical reactors (i.e. when highly exothermic / hazardous reactions are conducted). Based on this, the current paper exemplifies the application of the risk analysis methodology proposed to generate the Pareto optimal operating solutions accounting for reactor productivity maximization (product yield) and probabilistic risk minimization. The multi-objective optimi...
Autori: Anca Dan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26108

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

Abstract After any treatment process of wastewater results residual sludge that is characterized depending on the type of the wastewater or by the sludge treatment type. The sludge treatment process can be divided in three important stages: the preliminary stage (with the sludge thickening), the stabilization stage, and the dewatering stage. The paper shows the results of the research for the identification of the most efficient organic cationic flocculants, which might be used wit...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26149

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractIn this article, hydrodynamic parameters and overall Oxygen mass transfer coefficient of petroleum based micro-emulsions in anairlift reactor were investigated. Four different petroleum-in-water micro-emulsion systems containing kerosene, heavy naphtha,light naphtha and diesel as oil based were used with concentrations of 3% and 7 % (v/v). The experimental data were supportedby simulation results obtained from the Computational Fluid Dynamics (CFD) method. The CFD was properly able to si...
Autori: Mostafa Keshavarz Moraveji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26234

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractThis paper proposes a tridimensional mathematical model for water migration time in a soil sample, as a prerequisite for thestudy of migration of various liquid pollutants in soil. The variables taken into consideration were measurement position, soiltype, porosity and the height of soil column. The mathematical models were elaborated and tested based on experimental data,assisted by TableCurve 3D software for generating linear and non-linear equations. The proposed mathematical models o...
Autori: Alexandra-Dana Chiţimuş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26425

AbstractThe sludge treatment processes represent a priority when we refer to the municipal wastewater treatment, but can implicate verycomplex studies and applications if we consider the industrial wastewater recovery and treatment processes. Even if the industrialsludges are seen as wastes, they can represent an important resource if are properly managed in the storage, treatment andrecovery processes. This paper aims to identify some methods to optimize the coagulation and flocculation process...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26444

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractThis work presents an original method and an automated installation to recover by combustion the waste gas obtained in theignition process of xylites in rotary kiln. The flue gas resulting from the combustion of waste gas, with light fuel support areused in the technological processes of obtaining activated carbon, satisfying the conditions where the oxygen content does notexceed 0.3 % vol. and the temperature is above 1200°C, conditions imposed by the Project Manager of the European pro...
Autori: Aurel Gaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26461

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

AbstractBiodegradation is a “green”, powerful and cost-effective way to remediate polluted environment. Still traditional biodegradationtechnologies of hazardous hydrophobic pollutants are generally limited by low bioavailability of such contaminants. That is whythere is a need to develop innovative approaches to enhance the efficiency of biodegradation. The aim of the present work was todevelop the basis of an innovative eco-friendly wastewater treatment technology for remediation of effluents ...
Autori: Tatiana Pantsyrnaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26487

AbstractThe purpose of the present study is the comparative investigation of the calcium cations removal from aqueous solutions usingtwo strong acid cationic resins recommended during the last years for water softening. The performances of the two resins wereevaluated by the means of the cationic exchange capacity and the retention degree of the calcium cations. The evaluation of thetwo resins behaviour in the ion exchange process was performed by the means of the FTIR spectra recorded on the re...
Autori: Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26489

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract This study evaluates the potential of Crambe abyssinica press cake, a residue from crambe oil extraction and/or biodiesel production, as an adsorbent for removal of cationic dyes from wastewaters. Batch adsorption tests were performed at 30, 40 and 50oC. Adsorption kinetics and equilibrium were satisfactorily described by the pseudo second-order and Freundlich models, respectively. Adsorption was spontaneous and exothermic. Fixed bed adsorption (breakthrough curve) was satisfactoril...
Autori: Adriana S. Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26597

Abstract Due to its very low moisture content, the solid waste from the two-phase olive oil extraction process (dry olive mill residue, DOR) can be easily stored and used as a readily available basal liquid culture medium via its reconstitution with water. Five white-rot fungi (namely Phanerochaete chrysosporium NRRL 6361, Lentinus tigrinus CBS 577.79, Pleurotus pulmonarius CBS 664.97, Phlebia radiata DABAC 9 and Botryosphaeria rhodina DABAC P82), previously selected in a screening program, ...
Autori: Alessandro D’Annibale
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26598

Abstract This study is focused on the dissolution kinetics of zinc oxide in ammonium acetate solutions to recover the zinc from alkaline and zinc-carbon spent battery powders. This study represents a first step for further studies in which actual waste powder is to be used. Therefore, the experiments were performed by using pure zinc oxide powder to evaluate the dissolution behavior of zinc. The effects of ammonium acetate concentration, reaction temperature, stirring speed and solid to liqu...
Autori: Nizamettin Demirkıran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26618

Abstract A model of an irreversible combined thermionic-thermoelectric generator with internal and external irreversibilities is established in this paper. The performances of the combined generator, in which the heat transfers obey radiative heat transfer law, are analyzed and optimized by using the combination of finite time thermodynamics and non-equilibrium thermodynamics. The general expressions for power output and efficiency versus drop voltage are derived. The influence of finite rat...
Autori: Zemin Ding
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26624

Abstract This paper aims to develop the theoretical framework and the applicative implementation of a new analysis method, which has the purpose of determining and classifying mineral waters in Romania and Europe, with the use of mathematical modelling and fuzzy logic. Firstly, the article underlines the properties of mineral waters in terms of curative effects, particularly the role of Ca2+ and Mg2+ upon the human metabolism. The values of these two chemical elements will constitute an inde...
Autori: Alina Stefanache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26635

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract Established applications of emulsion liquid membranes (ELM) refer to refining in hydrocarbons and hydrometallurgical processing, rehabilitation of poisoned patients. In this work we investigated the separation of aromatic compounds of biological interest, more often encountered as intermediates in dyes and drugs industry: aniline, nitrobenzene, ortho and para-toluidine, using emulsion liquid membranes. The experimental results showed that in the case of basic substances separation t...
Autori: Alexandra Raluca Miron
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26650

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

Abstract Biochar derived from agricultural biomass waste is increasingly recognized as multifunctional material for various applications according its characteristics. It is therefore essential to investigate biochar properties before large-scale application. In this study, rice straw-derived biochars produced at different temperature (550, 650, 750 oC). The resulting biochars were subjected to liquidphase oxidation by different agents including KOH, HNO3, H2SO4, H2O2 and KMnO4 to obtain bio...
Autori: Sobhy M. Yakout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26661

Abstract This study focused on the use of jet aeration to treat printing and dyeing wastewater. The related environmental factors influencing the dynamical efficiency of a jet aerator were investigated. Results showed that an ideal linear relation existed between dynamical efficiency and working pressure (R2 > 0.98), with dynamical efficiency decreasing gradually as the working pressure increased. When the gas–liquid ratio was approximately 0.6:1 to 1.4:1, more bubbles were formed b...
Autori: Chunsheng Le
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26664

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract Supercritical fluid and ultrasound assisted extractions were applied as a first step in a complex processing of spruce bark in order to recover polyphenols compounds. The aim of the study was to compare the efficiency of these "green" processes with a conventional extraction technique (ethanolic extraction). Supercritical fluid extraction was carried out in two steps: (i) static extraction for 15 min at 1000 psi with pure CO2 and (ii) dynamic extraction for 45 min at 35, 4...
Autori: Adina Iulia Talmaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26680

Abstract In the present paper we studied the competitive transport of p-nitrophenol (pNP) and 2,4-dinitrophenol (2,4-dNP) from aqueous media using the technique of liquid membranes. This technique is very efficient, economic and selective when compared to other removal techniques of phenolic derivatives. The paper presents the influence of the sodium carbonate concentration from the stripping phase, the influence of the concentration ratio [2,4-dNP]/[pNP] upon the selectivity of the transpor...
Autori: Ioana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26681

Abstract This research evaluated two electrokinetic remediation systems (EKR) for separating phenanthrene from bentonite and its electrochemical destruction by using a Boron Doped Diamond (BDD) electrode. The effect of the electrochemical potential for the oxidation of phenanthrene in liquid phase with Ti/BDD was analyzed by Normal Pulse Voltammetry and Hydroxyl Radical (●OH) analysis using the Spin Trapping Technique. The results showed that 70% of phenanthrene was removed from benton...
Autori: Alejandro Medel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26710

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life (EoL) treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and at the aim of their exploitation as valuable sources of raw materials. Within this study an integrated approach for waste electrical and electronic equipment (WEEE) end of life treatment is proposed based on the integration of hydrometallur...
Autori: Claudia Brunori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26777

Abstract New and end of life tires have been pyrolyzed in an innovative pilot plant that processes whole tires, thus saving the energy costs of shredding while allowing energy and materials recovery. Furthermore, the presence of a hydraulic guard guarantees high process safety. Several tests at different temperatures have been performed and the collected solid, liquid and gaseous products have been quantified and characterized. The influence of the maximum process temperature on yields and c...
Autori: Loris Giorgini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26783

Abstract The Bio.Lea.R project aims to demonstrate the performance of a landfill for less reactive, biologically treated waste (pretreated organic wastes) compared to a conventionally managed landfill, with regard to both environmental (biogas and leachate production) and economic aspects. The objective is to control the pretreated biodegradable waste through a liquid injection in order to achieve the same biogas quantity in a shorter time than in conventional landfill. Laboratory and full ...
Autori: Alberto Godio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26784

Abstract The amount of collected Waste Electrical and Electronic Equipment (WEEE) in Europe is growing about 7 wt.-% per year (2007- 2012). It contains a number of economically relevant base, precious and high-tech metals. However, only a limited number of these metals can be recovered by currently applied recycling processes. Especially high-tech metals like gallium, germanium and tantalum get lost during the treatment of WEEE. The pyrolysis technology allows an accumulation of these metals...
Autori: Peter Hense
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26785

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract Drying wood requires a significant amount of energy. This includes both thermal energy, necessary to heat-up wood, evaporate the water inside it and cover the insulation and vent losses, as well as electric energy consumed to force air circulation through the stacks. When wood is frozen, both energy consumptions increase; on one hand because frozen water requires a supplementary heat for transformation into liquid and then into gaseous state, and on the other hand, because of the lo...
Autori: Maria Bernadett Szmutku
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26841

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

In this work biodegradation of basic fuchsin and methyl red by the blue green algae Hydrocoleum oligotrichum and Oscillatoria limnetica was investigated. The degradation of basic fuschin after 7 days by H. oligotrichum and O. limnetica was 92.44% and 90.23%, respectively. On the other hand, the degradation of methyl red by H. oligotrichum and O. limnetica after 7 days was 53.23% and 50.18%, respectively. The degradation of these dyes by algae seems to be related to the molecular structures of...
Autori: Ghada W. Abou-El-Souod
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26949

Researching and industrializing a new pharmaceutical form results in an impressive amount of waste due to the methods used. Despite numerous reports about the addition of pharmaceutical ingredients to the environment, the effect they have on the environment at the nanogram (ng) level remains largely unknown; thus, it has been proposed to retain toxic compounds using Dowex resins in biomucoadhesive tablets containing miconazole nitrate, an antifungal medication. This study demonstrates the re...
Autori: Magdalena Bîrsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27091

This work focuses on treatment of lead polluted waste glass from urban collection (Pb≈5% wt) for its valorization as support in the immobilization of lipase, because soda-lime glasses are used in enzymatic catalysis. First of all, an extraction process of surface Pb was performed. The process is based on nitrilotriacetic acid (NTA) chelating agent. The operating conditions are: T=80°C, t=1h, pH 10, solid/liquid weight ratio=1/10, reagent concentration=0.1 M. Leaching tests at contr...
Autori: Luisa Barbieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27122

This work was aimed to test the suitability of an epoxidized cardanol derived plasticizer for the production of soft PVC characterized by low environmental and toxicological impact soft PVC. Nowadays, the use of natural derived plasticizer in soft PVC industry is emerging as valid alternative towards conventional phthalate plasticizers, in order to reduce the environmental and toxicological impact of soft PVC. In facts, cardanol is a natural and renewable resource, characterized by a wide wor...
Autori: Antonio Greco
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27128

A new material containing 2-(2′ thiazolylazo) p-cresol (TAC) grafted poly acrylamide (PAA) was prepared and its adsorption ability was studied for the removal of inorganic mercury from aqueous media. Adsorption of Mercury (II) ions from aqueous solution was investigated in detail as a function of mercury concentration, pH, ionic strength, and temperature. The adsorption data were analyzed by using the Langmuir, Freundlich and Dubinin-Radushkevich (DR) models. The adsorption of Mercury (...
Autori: Selçuk Şimşek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27170

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

The capability of ornamental rocks solid waste (ORSW) as a low-cost sorbent was investigated in order to remove As(V) and Mn(II) from aqueous solution. Physical-chemical characterization analyses of the raw material presented albite and quartz as the main minerals. The solid waste presents low surface area (209.70 m2/g). The Langmuir, Freundlich, Sips (Langmuir-Freundlich), Redlich-Petersen and Tóth models were used to analyze sorption phenomena. The maximum sorption capability from the e...
Autori: Fernando Jorge Santos Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27246

Acetone-Butanol-Ethanol (ABE) industrial production by fermentation is strongly affected by the low concentration of solvent (<25 g/L) that affects the cost of the recovery process. To decrease the overall cost of the butanol production, alternative routes for the recovery have proposed in literature. This paper presents a techno-economic analysis of an innovative butanol recovery process from ABE fermentation broth based on gas stripping technique. The comparison with a recovery process bas...
Autori: Lucia Salemme
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27346

Areas within which could arise explosive atmospheres having high concentrations, therefore requiring special precautions so as to guard the health and safety of concerned employees, are considered to be dangerous. If the electrical equipment used in these hazardous locations is not properly selected and installed for operating in explosive atmospheres, they are likely to generate an ignition and to result in explosion type events with significant environmental and material damages and, moreover...
Autori: Vlad Mihai Păsculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27360

This study presents mercury (Hg) assessment in water from tailing dumps collected form NW Romania by using commercial Diffusive Gradients in Thin-films (DGT) devices and Thermal Desorption - Atomic Absorption Spectrometry method (TD-AAS) technique. Additional aim of this study is to present Hg method validation and measurement uncertainty estimation for selected samples. An atomic absorption spectrometer based on thermal desorption for mercury vapor generation and DGT devices specific for Hg (c...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27383

End-of-life liquid crystal displays (LCD) represent a potential source of secondary raw materials for their relevant content of valuable materials, like plastics and metals. Furthermore, the combination of traditional and innovative recycling processes allows the recovery of indium, defined as critical raw material by European Commission. In this context, we have evaluated the environmental impacts of different management scenarios: incineration, the current recycling strategies and more inno...
Autori: Alessia Amato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27401

In this work, magnetic alginate was synthesized by encapsulating of Nickel Zinc Ferrite nanoparticle within Ca-alginate. The synthesized magnetic alginate was modified by ethylenediamine using microwave radiation to remove anionic dye from wastewater. The characteristics of magnetic nanoparticle, magnetic alginate and magnetic alginate amide (MAA) were studied using Fourier transform infrared (FTIR) and Scanning electron microscope (SEM). FTIR analysis confirmed the amidation of alginate. Di...
Autori: Niyaz Mohammad Mahmoodi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27424

Three different synthetic textile dyeing wastewaters were treated by a chemical coagulation/flocculation process, using ferric sulphate as coagulant. Polyacrylamide (Magnafloc 155) and polyamine (Superfloc C-573) based flocculants were applied. The influence of pH (between 3.5 and 10.4) and Fe3+ concentration (from 15 to 4000 mg/L) in both color and dissolved organic carbon (DOC) removal of polyester, cotton and acrylic dyeing wastewaters was assessed in the coagulation stage. As far as floc...
Autori: Carmen S.D. Rodrigues
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27427

Considering that glass containers are generally highly transparent they are good candidates for spectroscopic measurements and application of a transmittance for glass separation. The selection of glass container samples directly from municipal waste disposal bins, characterized by different colors, thicknesses, and shapes was done. Transmittance spectra of clear, green, amber and black clean glass containers were recorded, along with spectra of the usual bottled liquids. Positions of the absorp...
Autori: Dragana D. Strbac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27452

In the present work, the removal of anionic phosphate from aqueous solution by electrocoagulation (EC) process using aluminium electrodes was carried out. Batch studies were carried out to investigate the influence of different operating parameters (supporting electrolyte concentration, pH, spacing between electrodes, applied voltage, electrode area, and initial concentration of phosphate) on removal of phosphate from aqueous solution. The initial value of pH was varied from 3 to 8, while the co...
Autori: Sarasan Seena Mithra
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27458

This paper reports the possibility of using zinc ash as a secondary source for zinc oxide, which can be further used as white pigment. For the extraction of zinc from zinc ash, sulphuric acid was used. The impact of different parameters (ash fraction, contact time, sulphuric acid concentration and liquid:solid (L:S) ratio) upon the extraction degree of metallic ions from zinc ash was studied. The optimum conditions for the metallic ions extraction are: 20 % H2SO4, 30 minutes contact time, 1:1 L:...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27475

An apatitic calcium phosphate gel (HaG) was elaborated and used to treat municipal wastewater in a physicochemical cycle prior to the standard biological degradation process. Preliminary laboratory batch experiments outlined the kinetics of heavy metal sorption by monitoring the concentrations found in filtered fractions as a function of treatment time. On site experiments were performed in a municipal wastewater treatment plant by derivation of real wastewater into an experimental tank. In this...
Autori: Nathalie Lyczko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27488

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

A project called ’Cleaner Production’ is conducted in the organization of the Cleaner Production Centre of Serbia at the Faculty of Technology and Metallurgy, University of Belgrade and the United Nations Industrial Development Organization (UNIDO). The goal of the project is to perceive critical places in a company and define measures which would achieve significant financial savings and, at the same time, protect and improve the condition of the environment with minimal investment...
Autori: Snezana Urosevic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27541

Among the organic pollutants, the chlorinated phenols represent an important class of compounds having a stable world market of ca. 100 kt per year. Due to their aryl structure and presence of the chlorine atom, chlorinated phenols are exceptionally recalcitrant toward chemical reactions aimed at their reduction. Adsorption from liquid phase has received special interest due to its flexibility and simplicity in operation. Especially adsorption using activated carbon (AC) has been recognized by t...
Autori: Marius Sebastian Secula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27552

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

The solid-liquid extraction process and some of its influencing factors such as solid-liquid ratio, temperature and salt initial amount have been investigated. Also, mathematical modeling for mass transfer coefficients calculation was applied. An inert porous solid material (coal), impregnated with 10% and 20% mass NaCl or 15% and 30% mass CaCl2, was used. The leaching was conducted in a fixed bed column, in laminar flow. The CaCl2 impregnated samples were investigated in a column with a height...
Autori: Marcel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27557

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Dielectric measurements were carried out on a series of bent-core liquid crystals based on resorcinol and 2, 7-dihydroxinaphtalene cores and presenting B mesophase in between 30-160°C. The dielectric constants in the liquid crystalline phase were measured as a function of frequency and temperature. The dielectric relaxation of bent-core compounds has been analyzed by dielectric constants/frequency curves. The variation of the dielectric strength with temperature has been determined as well. ...
Autori: Irina Carlescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27568

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

The performance and microbial community of an anoxic-aerobic sequencing batch reactor (SBR) treating saline wastewater were investigated at different influent COD/N ratios. The average COD removal efficiencies at steady states were 87.46%, 73.75%, 64.87% and 88.34% at the COD/N ratios of 20, 10, 6 and 30, respectively. The average NH4+-N removal efficiencies were 79.74%, 74.34%, 64.55% and 89.29% at the COD/N ratios of 20, 10, 6 and 30, respectively. No obvious accumulation of NO2--N and NO3--N ...
Autori: Sen Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27592

Phenolic compounds are known as recalcitrant pollutants in many industrial wastewaters, e.g. olive mill wastewater. An efficient treatment is therefore needed before the discharge of phenol-containing wastewaters into the environment. The possibility of removing some natural occurring phenolics, namely tyrosol, p-coumaric acid and vanillic acid, by micellar-enhanced ultrafiltration (MEUF) using a cationic surfactant, cetylpyridinium chloride (CPC), and polyethersulfone membranes of 20 and 50 kDa...
Autori: Abdelilah El-Abbassi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27607

This study evaluates the behavior of freeze concentration of cheese whey (CW). Parameters studied were: Chemical Oxygen Demand (COD), Total Dissolved Solids (TDS), Suspended Solids (SS), Total Settleable Solids (TSS), pH and electrical conductivity (EC) in the concentrated cheese whey and in the ice. The final concentration of TDS reached was 25 ± 0.16 %wt for the liquid phase, which corresponds to a reduction of 83% of the initial volume. The COD in the ice fractions had lower values tha...
Autori: Freddy Belén
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27613

FLUCTUATION OF RIVER NETWORK WATER ENVIRONMENTAL CARRYING CAPACITY IN A COMPLICATED RIVER-LAKE SYSTEM    • MINERALOGY AND GEOCHEMICAL DISTRIBUTION OF HEAVY METALS FOR THE FAGUL CETĂȚII TAILINGS, ROMANIA    • ACCUMULATION AND AVAILABILITY OF TRACE ELEMENTS FROM SOIL INTO ORIENTAL TOBACCO GROWN IN MACEDONIA    • OLFACTORY EFFECT ON LANDSCAPE PREFERENCE    • EFFECT OF MOLASSES ADDITION AS BIODEGRADABLE MATERIAL ON PHENOL REMO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27628

Thin-film transistor liquid-crystal display (TFT-LCD) waste glass can be used as a raw material for producing geopolymers, because it contains large amounts of silicon and aluminum in its amorphous structure. The setting time and compressive strength were evaluated to determine the quality of the geopolymer product with various amounts of nano-SiO2 (0%–3%) and TFT-LCD waste glass replacement (0% - 40%). The microstructures of the samples were characterized using mercury intrusion porosimet...
Autori: Kang Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27634

In this study, a soil washing process in the presence of a nonionic surfactant solution of Tween 80 or Triton X-100 was investigated. Sandy soil was contaminated in the laboratory with naphthalene (10 mg/kg and 5000 mg/kg) and anthracene (25 mg/kg and 200 mg/kg), then washed with surfactant solution. A preliminary water washing step showed the performance of water in the removal of the two polycyclic aromatic hydrocarbons (PAH), especially naphthalene. The effect of Tween 80 and Triton X-100 was...
Autori: Razika Khalladi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27637

The mineralization of azo dyes could be realized through solar photocatalytic degradation that is a green method where non-harmful end products are produced. The aim of this study was to investigate the mineralization of Orange G (OG) and New Coccine (NC) using ZnO as catalyst. The degradation of the azo dyes was conducted at different experimental conditions, and parameters such as effect of sunlight to the degradation rate, initial azo dye concentration, amounts of catalyst dosage, pH and effe...
Autori: Wan Fadhilah Khalik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27643

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

Porous membranes as gas-liquid contactors are widely used in carbon dioxide (CO2) absorption systems. It provides larger mass transfer area and excellent operational flexibility. Membrane contactors have been considered as alternative to conventional approaches in removing CO2. In spite of its advantages over conventional technologies, membrane wetting is a major problem which reduces performance of CO2 absorption. This paper explains the concept of membrane wetting phenomenon and its influen...
Autori: Abdul Latif Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27676

This paper presents an assessment of the toxic compounds released from metalworking fluids (MWFs) used in aluminum solid waste processing and from aluminum slag landfills, and their impact on environmental quality and human health. The mean concentrations of dust, oil mist, aldehydes, volatile organic compounds (VOCs) released from metalworking fluids were determined in machine shops. The exposure in machine shops was quantitatively dominated by VOCs, whose concentrations varied in the range...
Autori: http://www.ecozone.ro/reviste.php?RID=27677

The aim of this study is the treatment of liquid effluents from a petroleum industry (NAFTAL /Algeria) by an electrochemical treatment process (electrocoagulation). The electrocoagulation has proved to be useful for the treatment of wastewater, but in order to enhance its ecological characteristic we found it would be essential to carry out our experiments with ecological energy derived from a photovoltaic solar module, which would contribute to sustainability objectives. The electrocoagulation ...
Autori: Kahina Ighilahriz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27679

In the present study, Dowex HCR-S/H, cationic resin was used as a resin for the removal of cadmium from aqueous solutions. The experiments were carried out in a batch vessel. Subsequent experiments were performed as a function of initial solution pH, resin dosage, agitation time, initial Cd2+ concentration, solution temperature and agitation speed. Ion exchange rate increased with the increase in initial cadmium concentration, stirring speed and temperature. The Langmuir, Freundlich, Elovich,...
Autori: Baybars Ali Fil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27777

Activated sludge (AS) is the mainly used biological process in water treatment; therefore, assessing the influence of various operating conditions on this process is relevant. This study aimed to evaluate at laboratory-scale the influence of the gas-to-liquid volume ratio (RG/L) and the stirring speed (SS) on the biodegradation of carbamazepine (CBZ) by activated sludge. For this purpose, a central composite design (CCD) was used in association with response surface methodology (RSM). Batch cult...
Autori: Samer Semrany
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27869

Ultrasounds has a wide range of active applications spreading in solid, liquid and gaseous mediums, embedded in new methods and technologies for preventing, reducing and removing of existing pollution. This paper deals with the sonochemistry reactors and their combinations with photocatalysis and electrochemistry. Various parameters such as ultrasound frequency, power, number of ultrasound sources, lab-scale or large-scale equipment used for environmental applications of sonochemical reactors h...
Autori: Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27867

The analysis by numerical simulations can be applied to building materials subjected to different climatic conditions to envisage the influence of environmental factors in terms of drying time, water absorption and thermal performance of materials. Currently there is a wide variety of new building materials used for insulation, waterproofing and rehabilitation, each contributing in a specific way to constructions improvement during their service life. In time, every building is subjected to degr...
Autori: Alexandra Alisa Găină
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27863

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

The study developed a quantitative evaluation model of environmental performance, using a hybrid multi-criteria decision making (MCDM) approach by key environmental indicators based on the ISO14031 environmental performance evaluation (EPE) dimensions. The causal relationships and influence intensity among the EPE dimensions were explored to construct the network evaluation structure. Three well-known thin film transistor-liquid crystal display (TFT-LCD) panel manufacturers in Taiwan were us...
Autori: Hung-Yi Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27930

Fire and explosion prevention requires the knowledge of the explosive or flammability parameters of combustible gases and vapours that can be found in industrial and civil environments, as well as the influence of certain substances in the process on these parameters. In some cases, pyrophoric sulphides can be formed and it is supposed that they may influence the known flammability parameters of the substances used in various industrial processes. In order to track the influence of iron sulp...
Autori: Maria Prodan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27963

The paper presents a methodology for determining the conditions in which the liquid phase occurs in the transported natural gas. This methodology allows fast and accurate determination of the phase in which water can be found in natural gas transmission pipelines and also the possibility to highlight the points in the transmission system in which water is in liquid state. A complex function which can describe the phase behavior of water from natural gas has been defined by processing the phase e...
Autori: Sorin Neacşu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27970

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

The paper reports on the preparation of polysiloxane hydrophobized viscose-maghemite/goethite magnetic composite with properties appropriate for uses in oil spill sorption from polluted aqueous media. A multi-step procedure was employed to obtain the polymeric composite. The structures of the prepared samples and precursors were analyzed by Fourier transform infrared spectroscopy (FTIR), whereas their morphology was investigated by means of scanning electron microscopy (SEM). The hydrophobic...
Autori: Răzvan Rotaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28008

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

The purpose of this paper was to sum up the most appropriate pretreatment methods for destabilizing the oil waste emulsions coming from metal surface processing operations. A three steps oil waste management pretreatment methodology was proposed considering the application of the waste hierarchy and end-of waste criteria in the spirit of circular economic concept. Our main objective was to valorize the high energy content of oil waste flows using low cost pretreatment methods. The obtained phase...
Autori: Lidia Kim
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28122

To produce drinking water, the water treatment plants generate huge quantities of sludge, this sludge is a waste and they are evacuated to the dump. The valuation of these sludge will be benific This study focuses on the development of composite alginates beads and sludge activated chemically by sulphuric acid and thermally for the removal of dyes from aqueous solutions. Two dyes were studied; a basic cationic dye (methylene blue) and an acidic anionic dye (Congo red) to compare the adsorption m...
Autori: Hasna Elmontassir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28125

There are considerable environmental and health and safety concerns regarding liquid crystal display (LCD) waste glass because of the waste electrical and electronic equipment (e-waste) that is deposited in landfills. In current study, the effect of variation in LCD waste glass on the deconvoluted fractions of silicon centers of metakaolin geopolymers has been comprehensively investigated to discover the underlying mechanisms governing the performance. Solid/liquid ratio affects the kinetics of ...
Autori: Kang-Wei Lo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28146

Soluble dyes are intensively used in various industrial activities. They represent an important class of water pollutants from which they are rather difficult to remove. This paper focusses on the elimination of Congo Red (CR) ionic azo dye by adsorption on a low cost material. Cherry stones were used for activated carbon preparation by carbonization method. A temperature of 600 °C and a time of 4 h were found as adequate parameters for the physical activation and led to a final white powder...
Autori: Cristina-Gabriela Grigoraș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28153

The Cellets product represents a cellulose material, which combines different properties such as the perfect sphericity, fine particle size distribution, low friability and solubility, and inertness. The experiments were carried out with Cellets 200 granulated celluloses used as a filling material for a laboratory glass column, using diluted dye solution (9-10 mg of dye /L of solution) at adequate initial pH (4.7). The effect of flow rate was investigated, and the modeling of experimental data f...
Autori: Iulia Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28155

Apart of new equipment’s development such as absorption columns with higher efficiency, for chemical industry, there is a strong need for greenhouse gases reduction in order to assure the environmental protection and, consequently, many studies regarding the purification methods of exhausted gases have been performed. There are several types of reactors used for gases purification, such as: bubbling jet reactor, combined packed and spray tower absorber, cable wet scrubber and packed column...
Autori: Elisabeta Droniuc Hultuana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28160

The contamination of aquatic and terrestrial environments by pesticides is highlighted by their possible toxic properties and poor biodegradability on the environment. The development of low cost by products from agricultural sectors as a suitable solution for contaminated areas remediation is of great environmental interest. Straw wastes can be considered as a promising alternative to remove different chemical compound that are environmentally toxic. In this study, some materials derived from ...
Autori: Irina Gabriela Cara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28161

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162

Growth rate and biomass yield in the case of Arthrospira platensis depend on nutrient availability, temperature and light, which can determine changes in the metabolism and therefore in the biomass composition. The aim of this study is to evaluate the behavior of A. platensis during the growing time in several liquid culture media and their influence on the yield of biomass production. The following culture media have been investigated in this sense: ARS, Zarrouk (Z), modified Zarrouk (MZ), eco...
Autori: Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28163

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

Printed circuit boards are the most important component of any electrical and electronic device. The average metal content in waste printed circuit boards is ~30-35% whereas the rest of the material is a non-metal fraction (NMF). Metals in the waste printed circuit boards are recycled for their value whereas the NMF is mostly sent to landfills or incinerators for disposal. The circuit board laminates contain flame retardant chemicals that pose potential hazards to the environment and to public h...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28216

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Impregnation of aluminium ion onto silica gel (SG) surface (Al/SG) is to increase the adsorption capacity of an anionic dye such as Indigo carmine (IC). The impregnation was carried out using wetness impregnation. The change of the functional group was evaluated by FTIR, crystallinity was determined using XRD, surface morphology were studied by SEM-EDX, while surface area and pore size using N2 gas adsorption-desorption analyzer. Meanwhile, the best of IC adsorption condition onto SG and Al/SG ...
Autori: Yudi Aris Sulistiyo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28253

Car fluff is an important problem for the industrial compartment, especially for Italy, considering the huge amount of waste produced by the automotive sector, approx. 180.000 ton/year. Although car fluff (CER 191004) is suitable for CSS-Combustible production, with destination to cement factories, a very low amount of it reaches this destination. An alternative way to transform this problem into an opportunity consists into the transformation of bioliquid after its thermochemical transformati...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28289

Groundwater at an abandoned industrial area near Bergamo, Italy, was historically contaminated by tetrachloroethylene (PCE) (>100 μg/L) and, to a lesser extent, by trichlorethylene (TCE), dichloropropane (DP) and 1,1,2,2-tetrachloroethane (R-130). A liquid reagent (EHC® Liquid) was selected for remediation of groundwater at the site. The reagent is provided in two parts: EHC® Liquid Mix (a soluble organo-iron salt), and ELS® Microemulsion (a lecithin-based carbon substrate), a...
Autori: Alberto Leombruni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28300

The steady increase in separate waste collection has highlighted the urgent need to adequately deal not only with urban waste (differentiated and undifferentiated) but also with special waste produced by separate waste collection and recycling processes. Source collected municipal solid waste produces different waste streams. One of this is the organic fraction of municipal solid waste (OFMSW). This fraction is central for circular economy, since it can be further transformed in order to recove...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28302