The models describing the flow or the heat and mass transfer in stirred bioreactors can be easily adapted for the continuous phase from the stirred bed bioreactors. But, for the immobilized biocatalyst phase, new models have to be established. Therefore, in this paper the influences of the main factors on mixing for a bioreactor with stirred bed of S. cerevisiae immobilized cells in alginate have been analyzed.. The mixing efficiency continuously increases with rotation speed acceleration for th...
Autori: Anca-Irina Galaction, Anca-Marcela Lupasteanu, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25116

AbstractThe textile industry is a large water consumer. Stringent regulations of wastewater characteristics require the use of membrane processes for the removal of persistent organic pollutants (POPs) from textile wastewater prior to discharge or recycling of these effluents.This paper presents an overview of research related to the removal of persistent organic pollutants from textile industry by membrane processes, discussing also the correlations with actual pre-treatment and removal rates. ...
Autori: , Corina - Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25127

AbstractDuring the modern history the ability of plant roots to consolidate and strengthen the soil was exploited twice in France: once in1867 by Joseph Monier who created the reinforced concrete, and then in 1962 by Henry Vidal who created structured soils.The paper presents the some results obtained on the ecological protection of floodplain in major riverbeds. The aerodynamic modeling represents an efficient, economic and easy way to work with. The main condition of successful experiments is ...
Autori: Ana Virsta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25136

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractAluminum and ferric salts are widely used as coagulants in water and wastewater treatment. They are effective in removing a broad range of impurities from water, including colloidal particles and dissolved organic substances. As well as traditional additives, such as aluminum sulphate ("alum") and ferric chloride, other products containing prehydrolized metal ions such as polyaluminum chlorides are now commonly used. The aim of this study was to develop a model for coagulation/flocculati...
Autori: Avid Banihashemi, Manouchehr Nikazar, , Reza Maknoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25230

AbstractThe removal of formasine fines particles from water by precipitation with polyelectrolyte and surfactant complex of Polyacrylamide (industrial product Praestol 611 made by Degussa) and Sodium Lauryl Sulphate (SLS) was experimentally studied. Calcium oxide was added to initiate precipitation of the polyelectrolyte complex together with the fines particles. The experiments were carried out with complexes having the surfactants concentration higher then the critical aggregation concentratio...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25238

AbstractAdvanced closing of paper machine circuits results in the accumulation of the dissolved and colloidal substances (DCS) in the process water. At a critical concentration, the DCS are destabilizing even by small variations in paper machine parameters, producing operational and product quality problems. This article presents results of lab experiments simulating the process water recycling in short circuit of paper machine, without and with addition of fixing agents. Tests were performing w...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25261

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

AbstractConsidering that three-phase dispersions are common in chemical engineering and biotechnology, and with increasing airlift reactor applications to chemical and biotechnological processes, a experimental study was undertaken in order to investigate the liquid phase hydrodynamics and dispersion in an external-loop airlift reactor on laboratory scale. Experiments were conducted in order to find a relationship between relevant hydrodynamic and mixing parameters of a solidsuspended exter...
Autori: Florina Ungureanu, Maria Gavrilescu, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25268

AbstractDepletion of world recourses, increasing pollution, and climate change make us shift from linear economy to system economy - an economy of technologies integrated to reach a non-polluting zero emissions production system. Transition to renewable resources requires replacement the present crude oil refinery by biomass refinery. Along with conventional biomass refinery technologies bioengineering and nano-technologies become significant players of systems in the design of clusters of integ...
Autori: Arnis Kokorevics, Janis Abolins, Janis Gravitis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25304

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract The synergistic combination of polymers and inorganic compounds via sol-gel process has attracted great attention, by manipulating structure at molecular level, for developing new materials with desired properties. These new hybrid materials could have a controllable combination of the benefits of polymers (flexibility, toughness, ease of processing) and those of ceramics or glasses (hardness, durability, thermal stability). The microstructures and the properties of hybrid materials...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25446

Abstract Mesoporosity of about 7 nm in ETS-10 titanosilicate was generated by postsynthesis treatment with hydrogen peroxide under microwave irradiation, resulting in an increased external surface area of the materials (55 m2/g). The influence of titanosilicate porosity and its surface modification by phosphorus atoms (ET(P)S-10) on the retention of some nanoions (??-emitting radioactive U(VI) and Th(IV) ions) and biomolecules (the proteins cytochrome c, papain, and ??-globulin) was investiga...
Autori: Robert Gradinaru, Sorin O. Valu, Stefan Postolache, Claudiu C. Pavel, Ion Sandu, Karin Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25455

Abstract Arsenic (As)-contaminated drinking water is a major problem around the world. The removal efficiency depends strongly on the size of Fe3O4 sorbents.Fe3O4 prepared in laboratory is more efficient in the removal of As and is also more easily recovered from column of magnetic separator than the commercial materials. This would be beneficial in a water treatment system because the As-contaminated Fe3O4 could be flushed from the column permitting reuse of the separator system. The dispers...
Autori: Ionel Balcu, Adina Segneanu, Marius Mirica, Mirela Iorga, Catalin Badea, Iuliana Firuta Fitigau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25456

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract Highly dispersed nanoparticles of transition and noble metals are utilized for hydrocarbon reactions and rearrangements important to the chemical industry. The need to obtain 1 to 3 nm particles with narrow size distributions has prompted the development of alternative processing methods. Due to widespread speculation concerning the enhanced properties of nanoparticles over their bulk and atomic material equivalents, nanoparticle synthesis has become an active field of research withi...
Autori: , Irina Dumitriu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25482

Abstract Nanotechnologies may have properties of self-assembly, stability, specificity, drug encapsulation and biocompatibility as a result of their material composition. Nano-particles are being actively developed for tumour imaging in vivo, bio-molecular profiling of cancer biomarkers, and targeted drug delivery. These particles are stable, environmentally benign, and their chemical properties can be easily tailored by chemically modifying their surfaces. Conjugated with pharmacological a...
Autori: Simona-Florentina Pop, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25484

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract Tartrazine, (CI 19140) is an azo dye widely used in pharmaceuticals, cosmetics and foodstuff, as well as for coloring the textiles, hence it can be easily found in municipal wastewaters or wastewaters originating from textile, food, drugs and cosmetic industry. In this work, the capacity of a Romanian soil to retain Tartrazine from aqueous solution by sorption onto soil particles of different size has been investigated. The sorption kinetics was studied by applying five kinetic model...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25534

Abstract The paper presents the surfactant-assisted solvo-thermal route to synthesize nanoparticles of cerium oxide with different shape and morphology. The precursor was calcined at 400°C for 4 h in order to obtain CeO2 nanoparticles. The obtained samples were characterized by means of thermal analysis and FTIR spectroscopy. The UV-Vis analysis was used to study the optical properties. The morphologies and nano-structures were characterized by scanning electron microscopy (SEM) and XRD. It...
Autori: Nicolae Apostolescu, Gabriela Carja, Gabriela Apostolescu, Elena Husanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25541

Abstract University campuses can be seen as â€?small cities’ due to their high population (students, professors, employees) and corresponding high traffic flow, which may have a significant impact on both environment and people health. The objective of this work was to analyze particulate matter seasonal trends in the university area of Cosenza (University of Calabria). The relationship between sources emission, meteorological parameters and particle properties was defined. Sampling was co...
Autori: Monica Filice, Pierantonio De Luca, Giuseppe Piero Guido
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25564

Abstract In this paper, the capacity of a soil to retain the dye Erythrosine B from aqueous solution by sorption has been studied. Batch adsorption experiments were conducted to investigate the sorption of the dye from aqueous solutions onto soil with particles of different size. Different models were used to describe the kinetic data, to calculate the corresponding rate constants and to predict the theoretical capacities of soil for dye sorption. ...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25573

Abstract This article presents the use of salt water springs in the Moldavian Oriental sub-Carpathians for treating certain diseases, based on archaeological discoveries and ethnographical surveys, correlated with known facts from the literature in the field. Nevertheless, what differentiates it from other similar area in Europe is the intense, unexpected continuity of traditional, nonindustrial water supplying coming from salt springs. Among the uses of salt water and halite in the area, th...
Autori: Ion Sandu, Marius Alexianu, Roxana-Gabriela Curca, Olivier Weller, Constantin Pascu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25574

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract As a result of the global climatic changes generated by the alteration of the environment through polution, the ecosystems' natural ressources are incontrollably distributed, generating unforseeable effects at the level of the subsequent evolution of the natural balance factors. One of the greatest challenges of the science concerned with environment protection, is that of real time monitoring of the biochemical constitution. The real time monitoring of a great number of biochemical ...
Autori: Andrada Pretorian, Bojin Dionezie, Gabriel Epure, Ion Savu, Lucia Mutihac, Mihaela Muresan, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Rodica Lungu, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25583

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract Despite their success, the so-called Italian Industrial Districts (IIDs) have to face the crisis caused by the phenomenon of globalization. The paper presents the interventions carried out in two industrial districts, tannery district of Arzignano and artistic glass district of Murano, in order to help the public administrations to improve the environmental situation. Introducing strategic and social considerations in environmental initiatives and implementing ?radical? environmenta...
Autori: Flaviano D'Amico, Giulio D'Amico, Ion Tanase, Marian Mihai Buleandra, Mihaela Buleandra
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25603

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

? COMPARATIVE CONSIDERATIONS ON THE STRUCTURE OF SOME MOLYBDENUM/NIOBIUM DOUBLE PEROVSKITES OXIDES ? THE INFLUENCE OF THE STORAGE TIME ON THE STABILITY OF BUTTER ? CaCO3 CONTROLLABLE SYNTHESIS BY DOUBLE EXCHANGE METHOD USING CaCl2 RESIDUAL SOLUTIONS ? OPTIMIZATION OF COAGULATION-FLOCCULATION IN THE TREATMENT OF CANAL WATER ? ANODIC DETERMINATION OF PENTACHLOROPHENOL FROM WATER USING CARBON NANOFIBER-BASED COMPOSITE ELECTRODE ? STUDY OF PRECIPITATES GROWTH IN COAGULATION ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25663

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

The main phenomenon of coagulation is that particles aggregate to form floc. The formation of floc and cluster was simulated with computer in two-dimensional space using particle-cluster aggregation model and the properties of floc were analyzed using fractal theory. The effect of sticking probabilities on floc structure, density and porosity were analyzed. With the sticking probability increases, the simulated floc structure is gradually loose, floc density is gradually lower, the porosity is g...
Autori: Wanchun Tan, Yunbo Wang, Changbo Jiang, Shiquan Sun, Hong Chen, Xiaobao Niehttp://www.ecozone.ro/reviste.php?RID=25675

For a better evaluation of the impact of road traffic about air quality, this paper considers the development of a new evaluation index system and methods. They address the assessment of the air quality around the areas with an intense road traffic, according to Chinese standards considering sulfur dioxide index (SO2), total suspended particles index (TSP), floating dust index (PM10), nitrogen oxides index (NOX) and carbon monoxide index (CO). A systematic air quality evaluation model was establ...
Autori: Zhao-hui Liu, Zhi-bin Qinhttp://www.ecozone.ro/reviste.php?RID=25714

Abstract:Point of zero charge (PZC) is defined as the condition at which the surface charge density of a material equals to zero and, formost of the solids it is strongly pH dependent. The PZC can be controlled by tuning the solid surface properties (crystallinestructure, morphology) and by a proper environment control, thus it is important to evaluate the PZC for a certain type of material,in given working conditions, for enhancing the efficiency in the targeted application (e.g. layer by layer...
Autori: Laura Maria Bertus, Radu Adrian Carcel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25721

Abstract:In this paper the study on the possibilities of converting chopped reed stalk biomass into briquettes is described, in the conditions of harvesting water reed plant from Danube Delta region in winter time and based on briquetting technology used for wood waste from production. The water reed tested in the research has been harvested from Tulcea reed bed, one of the largest in Romania, chopped in a veneer drum chipper and compacted into the hydraulic briquette machine. The paper focuses ...
Autori: Aurel Lunguleasa, Camelia Coşereanu, Constantin - Radu Gheorghiu, Dumitru Lica, Gavril Budău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25734

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:The aim of this work is to obtain sintered porous membranes with graded structure for microfiltration by sedimentation andsintering of metallic powders. Our previous studies have demonstrated the possibility of obtaining sintered porous materials withgraded structure by sedimentation. In this paper, spherical nickel particles were used having a grain size in the 2-90 Âľm rangemeasured by the laser scattering particle size analyzer. The powders were sedimented into a sintering die in a s...
Autori: Gyorgy Thalmaier, Ioan Vida-Simiti, Nicolaie Jumate, Niculina Sechel, Valentin Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25775

Abstract:In this paper, photo-catalytic process for treatment of phenolic wastewater by TiO2 nano powder immobilized on concrete surfacein a recirculation hydraulic flow was investigated. The process affected by different operational conditions that the optimum onescould be obtained from variables interchange. Taguchi method as a proper method for design of experiments and optimizationwas used to find optimum conditions. Selected five parameters at four levels were consists of initial phenol con...
Autori: Bita Ayati, Hossein Ganjidoust, Mohammad Delnavaz, Sohrab Sanjabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25778

Abstract:This investigation focused on the adsorption of Pb (II) onto Lewatit FO 36 resin from aqueous solutions. The effects of initialmetal concentration, contact time, pH of solution were factors that affected the adsorption of Pb (II). Adsorption kinetic was betterexplained by the pseudo second order type 1 kinetic model that was confirmed by the values (R2>0.986). The Langmuir,Freundlich, Temkin and BET adsorption models were used for the equilibrium studies and Freundlich isotherm bette...
Autori: Alireza Asgari, Azra Setodeh, Mehdi Ahmadi, Mohamad Sedigh Mortazavi, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25791

Abstract:The paper refers at adsorption studies using the maghemite nanoparticles as adsorbent for removal of the hexavalent chromium from aqueous synthetic solutions. Adsorption reached at equilibrium within 10 minutes and was registered as maximum at pH 2.54. The adsorption data were analyzed and fitted by Langmuir isotherm. Investigation methods for characterization of the nanoparticles were X-ray diffraction, scanning and transmission electron microscopy. Also, in order to evaluate the hexav...
Autori: Andra Mihaela Predescu, Andrei Predescu, , Eugeniu Vasile
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25805

An iron(Fe+3) oxide/hydroxide nanoparticles-based agglomerates (AggFe) suspension adsorbent was synthesized for efficient, cost-effective phosphate removal. A strong effect of AggFe concentration and pH level of water containing phosphate on removal efficiency was shown. It was found that phosphate adsorption onto the AggFe suspension may be described by pseudo-secondorder reaction kinetics and the Langmuir isotherm model. The unique adsorption properties of synthesized AggFe adsorbent are demon...
Autori: Grigori Zelmanov, Raphael Semiat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25829

� SUSTAINABILITY IN ENVIRONMENTAL REMEDIATION � EVALUATING THE CLIMATIC CHANGES IN THE HYDROLOGICAL FLOW REGIME OF THE MOLDAVIAN AREAS � ENSURING ECONOMICAL AND FINANCIAL SUSTAINABILITY: STATE FISCAL CONTROL - A WAY TO PREVENT AND REDUCE TAX AVOIDANCE � COMBINED OXIDATION AND ULTRAFILTRATION PROCESSES FOR THE REMOVAL OF PRIORITY ORGANIC POLLUTANTS FROM WASTEWATERS � THE FREE LEVEL UNIFORM POST-DARCY FILTRATION THROUGH A SPHERE-MADE HOMOGENOUS MEDIUM � HSLA ST...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25838

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

AbstractIn this paper, we report a study on structural evolution, magnetic susceptibility and arsenic content of colloidal pyrite fromXinqiao deposits in Tongling, Anhui Province, China. The pyrite was treated under N2 atmosphere and charaterized with X-raypowder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), magnetic susceptibility analysis, and atomicfluorescence spectroscopy (AFS). We observed that heating of colloidal pyrite in N2 atomosphere did not change the crys...
Autori: Dong Chen, Ping Li, Tianhu Chen, Xiao Zhu, Yadan Shi, Yan Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25951

AbstractThe detection of environmental pollutants has challenged conventional chemical analysis for the rapid estimation of thebioavailability and toxicity of the contamination impact on human health and ecosystems. Magnetic nanoparticles (MNPs)functionalization as bioreporters can enhance the ability for biosensing in complex contaminated samples such as soils, and theimmobilization of bioreporters will promote the detection of gas and online monitoring. In this study, Acinetobacter baylyi ADP1...
Autori: Aizhong Ding, Cheng Chen, Dayi Zhang, Musen Duan, Steven F. Thornton, Wei E. Huang, Yanjun Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25952

AbstractThis paper analyses mathematical models and numerical simulation results for a notional miniature, planar, spiral transformer(MPST) fabricated in MEMS technology, for galvanic separation, proposed to equip an electric harvesting device (EHD). Twotypes of core – ferrite and (partially) magnetic nanofluid – are considered. We found that magnetization body forces occur in thesuper-paramagnetic nanofluid core and they result in complex, steady state flows consisting of fully 3D recirculation...
Autori: Alexandru Mihail Morega, Jean Bogdan Dumitru, Lucian Pîslaru-Dănescu, Mihaela Morega
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25998

• STUDIES ON HEAT RECOVERY FROM CELLULOSIC TEXTILES FINISHING WASTEWATER    • ASSESSMENT OF SYNERGIC REGULATORY ACTIONS OF SPRUCE BARK EXTRACT AND DEUTERIUM DEPLETED WATER ON MAIZE (Zea mays L.) CROPS    • LUNG CANCER RISK INDUCED BY RESIDENTIAL RADON IN CLUJ AND ALBA COUNTIES, ROMANIA    • A CLEAR SKY IRRADIATION ASSESSMENT USING THE ESRA MODEL AND SRTM DATABASE    • ENVIRONMENTAL FACTORS ASSOCIATED WITH DYSPHONIA IN PROFESSIONAL VOICE USERS    ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26014

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractIn this work, cyclic voltammetry (CV) and differential-pulsed voltammetry (DPV) were used to detect pentachlorophenol (PCP)at two types of multi-walled carbon nanotubes (CNT)-based composite electrode, i.e., TiO2-modified-CNT-Epoxy (TiO2-CNTEpoxy)and CNT-Epoxy in 0.1 M sodium sulphate solution supporting electrolyte. The electrochemical behaviour of theelectrodes was investigated in the absence and presence of UV irradiation. A single oxidation peak at a potential value of about+1 V vers...
Autori: , Ágnes Jakab, Aniela Pop, Cornelia Bandas, Florica Manea, Joop Schoonman, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26033

AbstractA comparative study regarding the shape, dimension and bactericidal activity of the undoped and Ag-doped TiO2 nanocrystalswas achieved. In this way, two hydrothermal methods, classical hydrothermal and microwave-assisted hydrothermal, was usedfor nanoparticles synthesis. The obtained materials were investigated by X-ray diffraction, DRUV-VIS spectroscopy, BET andSEM/EDX analysis. Antibacterial activity of undoped and Ag-doped TiO2 materials was tested on real water from Bega River.The be...
Autori: Carmen Lazau, Corina Misca, Corina Orha, Cornelia Bandas, Sorin Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26034

AbstractThe paper presents the application of cross-spectrum analysis (CSA) to air pollution and meteorological time series collected fromseven air quality monitoring stations located in three urban agglomerations of Romania, affected by industrial and trafficpollution: Braşov, Ploieşti and Târgovişte. Data have been collected from November 2011 till March 2012, at one hour samplingrate. The purpose of the analysis was to reveal the correlations between two series at different fre...
Autori: Ştefania Iordache, Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26057

AbstractThe global diming means a gradual reduction on the earth's surface of global direct irradiance. The global dimming blocks thesunlight that would otherwise cause evaporation, thereby interacting with the global warming. In order to determine somecharacteristics confirming the global dimming were conducted a series of measurements of temperature and luminosity in Iasi.The purpose of the study was to link the urban pollution to the decrease in the solar luminosity during the time of a month...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26065

Abstract The Black Sea is seriously affected by a large range of pollutants, despite severe laws regarding the protection of sea ecosystems. Heavy metals are among the most important xenobiotics from the environment, presenting also toxicity for humans. The studies upon heavy metals have proven that the sediments have the highest concentrations and they can release metals back to water and this fact represents a risk for the humans and aquatic ecosystem life. The use of aquatic ...
Autori: Oana Jitar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26112

Abstract In many industrial applications most of the solid particles are separated by size and for this purpose there are used the oscillating sieves. The separation process based on sieves is a complex one and it depends on several factors, such as the properties of solid particles submitted to the separation process and on the operating regimes of the separating equipment. We have studied the separation process of the behaviour of solid particles on a flat oscillating surface...
Autori: Ovidiu Bontas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26134

Abstract In order to accomplish the water quality standards required for a specific use, the continental surface water is treated through a sequence of operations and unit processes. The treatment technological flowsheets carry out, partially or totally, the removal of various pollutants, every treatment step being used for improving one or more qualitative parameter. The treatment scheme is specific to water source type and water use. One of the basic operations for water treatmen...
Autori: Oana Tirtoacă Irimia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26136

AbstractAs a new type of photoelectrocatalytic materials, the TiO2 nanotube arrays have drawn a lot of attention for efficientlyphotoelectrocatalytic organic pollutants degradation due to their highly photoelectrocatalytic properties. Yet, the performance ofphotoelectrocatalytic organics degradation using TiO2 nanotube arrays electrode is influenced by Cl-, a kind of typical reducingmaterial. This paper focuses on the effect of Cl- on the different photoelectrocatalytic performance of TiO2 nanot...
Autori: Jialing Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26177

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractGallinaceous feathers are an abundant solid waste from the poultry processing industries, which poses disposal problems. Akinetic study dealing with the adsorption process of wool reactive dye, Yellow Lanasol 4G (CI Reactive Yellow 39), ongallinaceous (Gallus gallus, Cobb 500) feathers was carried out. The main research goals of this work were to evaluate theviability of using this waste as adsorbent and to study the kinetics of the adsorption process, using a synthetic effluent. Thechar...
Autori: Sónia Adriana Figueiredo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26203

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractBased on principles of feeding solid waste into vertical boreholes in fully mechanized coal mining and backfilling technology,the literature established a trajectory model of particles in gas-solid two-phase flow for the sake of reducing the damage tostorage silo underground done by enormous impulsive force generated by falling solid waste. In addition, dynamical analysismethod in gas-solid two-phase flow field was adopted herein to study the solid particles’ force characteristics and th...
Autori: Nan Zhou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26271

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractIn this work, the effect of the addition of some nutrients on fungal growth and removal of Cr(III) were investigated. Theconsidered fungi, isolated from real tanning factory environment were Phanerochaete chrysosporium, Aspergillus niger and A.oryzae. Firstly, the optimal conditions for fungal growth were determined as a function of pH, contact time, temperature andagitation speed. Secondly, the effect of the addition of some nutrients on fungal growth was examined. Without the addition ...
Autori: Abdeltif Amrane, Mansur Zarrabi, Mohammad Noori Sepehr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26337

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractThe process of semi-volatile aerosol particle evaporation was studied with respect to both computational and experimentalapproaches. A Sinclair-La Mer type aerosol generator was used to produce monodisperse particles from four n-alkanes(tetradecane, hexadecane, octadecane, eicosane) while particle sizing and FID measurements were applied to quantify particleandvapor mass and their subsequent phase distribution. Aerosol dilution and later stationary analyses in a flow tube at two timeinte...
Autori: George C. Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26448

AbstractPathogenic bacteria are fetal to human health, requiring cost-effective and safe approaches to be removed from drinking watersource. With poly-allylamine-hydrochloride (PAAH) stabilization, magnetic nanoparticles (MNPs) were introduced in this studyto remove pathogenic bacteria by electrostatic interaction and magnet capture. High removal efficiency was achieved for fourmain pathogenic species, as Escherichia, Acinetobacter, Pseudomonas and Bacillus, and over 99.5% of the pathogens can b...
Autori: Yunfeng Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26475

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

AbstractThe conducted research has proved the dependence of gas flow rate in the separate channels of the two-level multichannel cycloneat a different inflow velocity and the number of channels. The carried out investigation demonstrates the dependence of changesin velocity in the channels under varying relations between peripheral and transitional flows. The work of a cyclone of the channelis based on centrifugal forces and an additionally occurring filtration process caused by the interaction ...
Autori: Pranas Baltrėnas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26488

AbstractIn this study, TiO2-zeolite modified carbon nanotubes-epoxy (TiO2-Z-CNT-Epoxy) and TiO2-zeolite modified carbon nanofibersepoxy(TiO2-Z-CNF-Epoxy) composite electrodes were applied for pentachlorophenol (PCP) degradation and determination inaqueous solution. The morpho-structural characterization of the composite electrodes was studied by scanning electronmicroscopy. The electrochemical behaviour of the electrodes was investigated under UV irradiation presence/absence, usingcyclic voltamm...
Autori: Ágnes Jakab
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26491

AbstractA soot transducer based on the measurement of the electrical resistance value of the soot layer deposited on a finger structure wastested at different thermophoretic potentials. The soot, similar to that issued from the Diesel engines, in terms of particle numberand size distribution, was obtained by the incomplete burning of propane and subsequent dilution. The decrease of the resistancevalue in time was directly proportional with the temperature gradient. Thus a soot transducer is aime...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26503

AbstractAs air quality becomes increasingly deteriorated in world-wide cities, air quality monitoring has extended beyond the criteriapollutants (CO, SO2, NOx, O3 and PM) in order to include several toxic air pollutants such as volatile organic compounds(VOCs). In the present study it was investigated the presence of 29 VOCs and PM including PM2.5, PM2.5-10 and PM>10 fractions,in an urban area from Romania. The total VOCs was higher in the urban area (176.72 - 192.54 μg/m3) than in the r...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26504

AbstractNano-Ag electrodeposited on carbon nanotubes-epoxy and carbon nanofibers-epoxy composites electrode materials as Ag-CNTand Ag-CNF electrodes were tested for simultaneous detection of arsenic (III) and lead (II) from aqueous solution. Theelectrochemical behaviour of As(III) and Pb(II) on both composite electrode offered useful detection information and Ag-CNFexhibited better electroanalytical performance. The detection scheme using Ag-CNF for simultaneous detection of As(III) andPb(II) wa...
Autori: Anamaria Baciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26511

AbstractTwo types of nanofiltration membranes had been used to study the influence of cross flow velocity on the membrane filtration ofdenitrification effluent (NF270 and NF90). Filtration had been conducted at constant transmembrane pressure of 5 bar andvariable cross flow velocity (0.03, 0.06, 0.15 and 0.39 ms-1). The obtained normal flux was 0.47, 0.58, 0.59 and 0.77for NF270membranes and 0.35, 0.38, 0.41 and 0.39 for NF90 membranes, the increase in cross flow velocity had enhanced fluxperfor...
Autori: Abdel Halim Fuqaha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26523

AbstractGreywater (GW) has attracted global attention as an alternative water source over the last few decades. GW treatment andreliable reuse require the overall qualitative characterization of samples from different sources. This paper represents aninvestigation of household-generated GW in the Northern Great Plain Region of Hungary. Modern and reliable analyticaltechniques and instruments (ion chromatography, microwave plasma atomic emission spectrometry, Zetasizer Nano Z analysis,etc.) were ...
Autori: Ildiko Bodnar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26528

Abstract Some of the major stressors of air quality in the urban areas are nitrogen oxides, ozone and suspended particles. The effect of air pollution on respiratory diseases can increase considerably at high levels of pollution and might trigger asthma symptoms. Longterm exposure can increase the rate of respiratory infections and symptoms at population level, but particularly in children. The goal was to analyze with statistical techniques the pollutant concentrations (NO, NO2, and SO2) re...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26605

Abstract Molinate (S-ethyl-azepane-1-carbothioate) is a thiocarbamate herbicide used in rice cultivation for the control of grass weeds. Environmental contamination with molinate is of major concern due to the adverse effects described both for humans and animals. Molinate hydrolase, a novel amidohydrolase previously characterized, is responsible for the initial breakdown of molinate, cleaving the thioester bond of molinate, releasing ethanethiol and azepane-1-carboxylate (ACA). Biotechnolo...
Autori: Ana M. Paiva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26642

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract Adsorption equilibrium and effective diffusion coefficients of water vapor, in cylindrical particles of activated alumina (A) and activated alumina impregnated with calcium chloride (MCA), are experimentally determined. The experiments were conducted at 303 K and 323 K using cylindrical particles with 2.5 mm in both length and diameter. Diffusion coefficients were determined from the kinetics of water sorption. The measurements were conducted in a constant pressure unit based on a m...
Autori: Eugenia Teodora Iacob Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26665

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

Abstract Nanoparticles are very interesting materials due to their properties which can be different than those of the bulk and they have many applications in various domains, like electronic, catalytic or biomedical. Gold is one of the most studied materials and is used in many applications that will have the human being as recipient, that’s why gold nanoparticles should be obtained as environmentally friendly as possible. In this work, particles of around 50 nm were obtained in a so ...
Autori: Razvan State
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26676

Abstract β-galactosidase from Aspergillus oryzae was strongly immobilized on magnetic particles functionalized with amino groups. By simple incubation without any activating agents, electrostatic interactions between amino groups and enzymes allowed obtaining a strong linkage. The immobilization efficiency was studied with the quantification of amino groups of the particles and of immobilized β-galactosidase. Kinetic parameters, especially the maximal velocity Vmax and the affinity...
Autori: Kalim Belhacene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26682

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract In this study we report the preparation and evaluation of the antimicrobial activity of a new hybrid material based on chitosan (CH), magnetite (Fe3O4) and phytocomponents from the Eugenia carryophyllata aqueous extract (AE). CH/Fe3O4 was prepared by chemical precipitation of Fe2+ and Fe3+ ions in aqueous solution of sodium hydroxide and CH. E. carryophyllata’s dried buds were hydrodistilled under microwave conditions. The AE was separated in three equal parts, one for the chl...
Autori: Ion Anghel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26707

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract This paper aims to analyze the characteristic of Road deposited sediment (RDS) using West Chang Tan highway, Hunan, China as a study site. RDS samples were collected at five representative highway sites and the particle size distribution was generally less than 150μm. Particles with the grain size (<150μm) had high metal concentrations among all sampling sites (unit: mg/kg): Cu 74-178, Zn 309-2737, Pb 601-1160, Cd 9.8-44.5. There is significant spatial variability between t...
Autori: Yunbo Zhai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26728

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract The aim of this paper is to assess the chemical and mineralogical composition and the leaching behavior of the electric arc furnace slags (EAFS) in order to improve their management by identifying suitable reuse options in different fields. The chemical and mineralogical composition of slag varies from one type of steel to another, from one technological stage to another and from one steel plant to another. In order to minimize the slag quantities disposed in the slag dumps one has ...
Autori: Dana-Adriana Iluţiu-Varvara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26835

Abstract A bibliometric analysis along with a brief historical and modifications overview and scientific applications was carried out to reveal the impact of Brunauer-Emmett-Teller (BET) isotherm on scientific research. The data was based on the Science Citation Index Expanded (SCI-EXPANDED) database of the Thomson Reuters Web of Science. BET isotherm received a total of 10,418 citations from its publication to 2012. Among them, 9,117 (88%) were research articles by 20,108 authors with 95% m...
Autori: Moonis Ali Khan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26839

Abstract Environmental research has been significantly enriched by genomic and proteomic methodologies. Particularly in the atmospheric pollution studies, where a variety of environmental hazards act simultaneously and frequently in close interrelationship, only such integrative methods can provide a comprehensive analysis. Nanoparticles are a heterogeneous class of particles, but their health effects have also common aspects. The scope of the article is to present the contribution of genomi...
Autori: Marina Otelea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26852

Abstract The photocatalytic degradation (PCD) of methylene blue (MB) in aqueous suspensions of nano-sized TiO2 particles containing high concentrations of NaCl, MgCl2, and CaCl2 was studied. The rates of PCD and adsorption of ions were monitored by measuring the total organic carbon (TOC) and using inductively coupled plasma-atomic emission spectrometry, respectively. The results showed that the removal rate decreased with increasing concentrations of NaCl, MgCl2, and CaCl2. The trend for th...
Autori: Yuping Jiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26910

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

Environmental persistence of endocrine disrupting estrogen chemicals (EDC) subsequent to endocrine function even at nanogram concentration in environmental matrices has garnered significant global attention due to their possible disruptive effects in an intact organism, or its progeny. An attempt was made in present study to investigate the occurrence of two estrogens viz. natural (estriol, E3) and synthetic (17α-ethynylestradiol, EE2) in the surface waster bodies of Hyderabad, India. A...
Autori: A. Kiran Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26953

This paper studies, in lab scale, the possibility of removing a rich-in-pollutant soil fraction using flotation, with the clean fraction been restored to its natural condition. The tests were carried out in a conventional flotation cell with mechanical agitation. Artificially polluted soil was used throughout this study by mixing soil with diesel fuel. The effect of the following flotation factors was studied: pulp pH, collector type and quantity, conditioning and flotation time, initial soil...
Autori: Nickolaos Georgiou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26960

The flocculation process is applied in wastewater treatment to separate the destabilized colloid particles (or the particles formed during the coagulation phase) by forming flocs. The scope of this research was to identify the predictability of the synthetic organic flocculants use for industrial wastewater treatment. The research was performed at small scale, in laboratory, but also at industrial scale, by applying the synthetic organic flocculants in a real industrial wastewater treatment p...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26975

The densities and distributions of airborne fungal spores known to cause respiratory tract disorders were monitored in three educational buildings located in different boroughs in Iaşi. Air samples from all locations were collected monthly over a period of 3 months (March-May 2011), using the Petri plate gravitational settling (passive) method. Petri plates containing nutrient media were exposed to room air for a 15-minute period, face upwards, to collect particles settling by gravity. A...
Autori: Florin Daniel Lipşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27003

Production and utilization of engineered nanoparticles (ENPs), which are smart materials with ability of sensing and destroying chemical contaminants, is growing rapidly. However, these materials seem to have some ecological and health adverse effects. Hence, the main goal of this review study is to give a brief description about the recent developments of the commercial available engineered nano particles in the environmental remediation and also to note the current state of findings about t...
Autori: Mohammadreza Kamali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27017

This paper aims to establish the capacity removal of hexavalent chromium [Cr(VI)] from wastewaters using a TiO2 – Fe3O4 based nanocomposite. Latest researches in the field point adsorption as a better option for removal of heavy metal ions from waters, this method being more efficient and cost effective, in comparison with other advanced methods like reverse osmosis, ion exchange, nanofiltration, etc. Based on this information, the goal of this work had as purpose the obtaining, charact...
Autori: Andra Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27025

Maghemite nanoparticles (γ-Fe2O3) were synthesized in order to be used as magnetic adsorbent for two heavy metals, Pb(II) and Zn(II), from aqueous solutions. γ-Fe2O3 was prepared from magnetite nanoparticles and was tested for single and binary aqueous solutions. Efficiency removal (%) for single solutions appears only after 10 minutes and was higher than 80%. In case of binary solutions, same results regarding efficiency removal were registered after 60 minutes, being almost 90% ...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27029

Membrane technology has become a fundamental unit operation in the industry and society of nowadays and fouling is, probably, the most important concern related with this technology. Fouling is a complex process that can limit the performances of facilities using membranes. Many research efforts have been done in order to reduce fouling tendency. Ceramic membranes can play a major role in fouling mitigation due to its high hydrophilic nature. This paper describes the characterization of a new...
Autori: Mihaela-Elena Dascalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27089

Researching and industrializing a new pharmaceutical form results in an impressive amount of waste due to the methods used. Despite numerous reports about the addition of pharmaceutical ingredients to the environment, the effect they have on the environment at the nanogram (ng) level remains largely unknown; thus, it has been proposed to retain toxic compounds using Dowex resins in biomucoadhesive tablets containing miconazole nitrate, an antifungal medication. This study demonstrates the re...
Autori: Magdalena Bîrsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27091

Iron humate (IH) produced as a waste by-product during the industrial manufacture of humic substances from young brown coal was tested as a new cost-effective sorbent for the removal of inorganic arsenic from waters. Its removal efficiency was compared with that of two other non-conventional sorbents – magnetite and oxihumolite (weathered brown coal). Magnetite and IH have been found to be effective in removing both forms of inorganic arsenic (arsenite and arsenate) from aqueous solutio...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27098

This study was carried out to monitor the presence of organophosphorus in drainage water (Kafr El-Sheikh (Kotshinar Drainage), Fowa (Fowa Drainge No.11), Metobess (El-Hokss Drainage), Beila (Karakat Drainage), Balteem (Hafeer Shihabeldeen Drainage), Nashart Drainage and El-Hamoul (El-Hamoul Drainage) in Kafr-El-Sheikh Governorate, Egypt. Furthermore, the efficacy of chemical (advanced oxidation processes) and bioremediation (effective microorganisms) for chlorpyrifos removing in drainage wat...
Autori: Aly Derbalah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27104

We computed the Product Environmental Footprint (PEF) to identify the environmental performance of recycled wool by means of data belonging to a real case study in Italy. First, we analyzed inventory data quality by computing the data quality rating (DQR) index, according to the criteria provided by the PEF protocol. Quality of specific and generic data (selected from the Ecoinvent database) was evaluated as excellent and good, respectively. We then quantified the impacts related to each rele...
Autori: Silvia Bamonti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27121

The aim of the present study was to prepare environmentally friendly silver-based materials using Cornus mas L. fruits extract. For this purpose, silver nanoparticles (Cornus mas-AgNPs) were green synthesized using this plant extract. The bioreduction of silver ions was analyzed by UV–VIS and ATR-FTIR spectroscopic studies. Scanning Electron Microscopy (SEM) analysis revealed the formation of spherical phyto-nanosilver particles with size ranging between 12 and 40 nm. Different amounts ...
Autori: Ioana-Raluca Suica-Bunghez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27139

The removal of quinoline from synthetic wastewater by heterogeneous photo-Fenton in a novel internal circulating fluidized-bed reactor was investigated systematically. The flow field in the reactor was simulated by FLUENT software conjoined with tracer particles experiment, and the influence of reaction parameters such as initial quinoline concentration, catalysts dosage and H2O2 dosage were evaluated. Results indicated that the designed reactor was suitable for the heterogeneous photo-Fenton...
Autori: Ran Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27142

The objective of this research was to study the degradation of chloramphenicol (CAP) in soil using activated carbon fiber supported nanoscale zerovalent iron (ACF/nZVI) coupled with microwave (MW) irradiation. Compared to ACF/MW, nZVI/MW and MW alone, the ACF/nZVI/MW system had a higher degradation efficiency. A Box-Behnken experimental design was employed to analyse relative significance of independent variables A (irradiation time), B (MW power), and C (MW absorber dosage), and combined ef...
Autori: Wengui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27154

In this study, a mathematical model was introduced to calculate the collection efficiency of dust particles in a wire-pipe single-stage electrostatic precipitator (ESP). The aerodynamic diameters of these particles are less than 10 μm (PM10). The mathematical model, using combined Deutsch-Anderson Equation, considers coupling effects among gas flow field, electric field and particle field. A simplified 2-D ESP model was established using GAMBIT and a software application (FLUENT) was used to ...
Autori: Jian-Ping Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27172

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

The effect of ceria content on the physicochemical properties and catalytic performance of nanostructured CeO2/Al2O3 for removal of toluene from waste gas stream was studied. The properties of the catalysts were addressed using XRD, FESEM, BET, TPR-H2 and FTIR techniques. XRD patterns confirmed the formation of CeO2 with average crystallite size of 7.8-8.7 nm. FESEM images confirmed the presence of fine particles between 25.2-189.1 nm. BET results showed that nanostructured CeO2/Al2O3 had high s...
Autori: Saeed Saedy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27245

Ammonium is an environmental contaminant encountered in water and soils, its admissible concentrations in soils and waters being established by legislation. Removal of ammonium ions from aqueous solutions from different matrix can be done with several sorbents, among which nano-adsorbents, such as oxidized exfoliated graphite nanoplatelets (ox-xGnP) offer practical solutions, based on their high specific surface area, associated sorption sites and efficiency of application. Several parameters su...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27273

Analyzing and reducing the possible effects of air pollution on human health became important issues for improving the quality of life in urban areas. Particulate matters (PM) are air pollutants with a potential important impact on human health of vulnerable people (e.g., children, elderly) and non-vulnerable people as well. The level of PM air pollution is mainly influenced by the PM concentration and parameters such as meteorological conditions and synergic effects of other air pollutants. The...
Autori: Mihaela Oprea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27286

Chlorophenols, commonly found in industrial effluents, are considered as priority pollutants because they may cause severe environmental impacts and human health related problems. Nanofiltration (NF) represents an important option for the removal of chlorophenols present in aqueous effluents. This study presents some results on the performance of nanofiltration for the removal of 4-chlorophenol and 2,4-dichlorophenol from synthetic wastewaters considering the selection of adequate operating and ...
Autori: Corina-Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27324

Pharmaceuticals contaminants in waters exhibit a significant threat on the human health and the ecosystem quality. This research demonstrates the utility of a silver-doped zeolite-modified carbon nanofiber-epoxy (AgZ-CNF) prepared by two-roll mill method in development of the fast methodology for the detection of fluoxetine (FXT) in the aqueous solution. The results showed the role of zeolite that improved the sensitivity and the limit of detection of FXT resulted to the possibility to propose a...
Autori: Magdalena Ardelean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27328

In the current context of industrialization, chemical and radioactive pollution is a concern for environmental protection and interference with human health. Care for environmental protection also includes vegetation that grows spontaneously in potentially contaminated places, thus avoiding illness among the population if consumed. The study area is located at 4.5km SSE from downtown Bacău City, Romania and is the result of the manufacture of H3PO4 through the wet method. In this study, t...
Autori: Mioara Săndulache Rachieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27331

Drilling waste management for oil and gas industry involves collection, transportation, processing, recycling, disposal, and monitoring of waste materials in order to reduce their effects on health and environment. In the Exploration and Production industry, environmental concerns have made effective management of drilling waste at well sites a great priority. Effective waste management is thus a key element in a successful drilling project. The industry therefore relies on effective expertise a...
Autori: M. Enamul Hossain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27375

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

The data presented in this work has been obtained from experimental research aiming towards the usage of natural resources of the National Park of Sila in Calabria, Southern Italy. Such resources are: “Laricio” pine resin, beeswax, mineral inert and charcoal to make natural glues. Furthermore, research has been done to find out if by using small quantities of carbon nanotubes, the strength of adhesion of prepared glues improves. Raw materials were characterized by physico–ch...
Autori: Pierantonio De Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27402

This paper presents the decolorization of p-Dimethylaminobenzalrhodanine using titanium dioxide nano-particles under photocatalytic process at various buffer media under air atmosphere. Several effective agents including nano-photocatalyst loading, illumination time, pH of medium and initial dye concentrations have been subjected to be estimated. Furthermore, kinetic investigations of photocatalytic process fitted the pseudo-first-order kinetic for dye decolorization at all considered buffer ...
Autori: Morteza Montazerozohori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27423

In this work, magnetic alginate was synthesized by encapsulating of Nickel Zinc Ferrite nanoparticle within Ca-alginate. The synthesized magnetic alginate was modified by ethylenediamine using microwave radiation to remove anionic dye from wastewater. The characteristics of magnetic nanoparticle, magnetic alginate and magnetic alginate amide (MAA) were studied using Fourier transform infrared (FTIR) and Scanning electron microscope (SEM). FTIR analysis confirmed the amidation of alginate. Di...
Autori: Niyaz Mohammad Mahmoodi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27424

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

A low-cost magnetic zeolitic material was synthesized from coal fly ash by means of a new, simple method involving alkaline hydrothermal zeolitization of fly ash (FA) followed by low-intensity wet magnetic separation. Scanning electron microscopy with energy-dispersive X-ray analysis was applied to characterize the composition, microstructure, and morphology of the material. The mineral and synthetic zeolite phases were identified by powder X-ray diffraction. The obtained magnetic zeolitic m...
Autori: Annie Shoumkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27486

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

An apatitic calcium phosphate gel (HaG) was elaborated and used to treat municipal wastewater in a physicochemical cycle prior to the standard biological degradation process. Preliminary laboratory batch experiments outlined the kinetics of heavy metal sorption by monitoring the concentrations found in filtered fractions as a function of treatment time. On site experiments were performed in a municipal wastewater treatment plant by derivation of real wastewater into an experimental tank. In this...
Autori: Nathalie Lyczko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27488

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Recycling of battery components for natural resources sustainability and consumer products has become an important endeavor that demands continuity through effective processes. In compliance with the need for waste management, LiMn1/3Ni1/3Co1/3O2 in the positive electrode of spent lithium-ion batteries has been recovered using specially designed device, consisting of two compartments separated with a plastic sieve of pore size 0.2mm. The upper compartment equipped with a mechanical stirrer conta...
Autori: Oluwatosin Emmanuel Bankolehttp://www.ecozone.ro/reviste.php?RID=27581

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

Thin-film transistor liquid-crystal display (TFT-LCD) waste glass can be used as a raw material for producing geopolymers, because it contains large amounts of silicon and aluminum in its amorphous structure. The setting time and compressive strength were evaluated to determine the quality of the geopolymer product with various amounts of nano-SiO2 (0%–3%) and TFT-LCD waste glass replacement (0% - 40%). The microstructures of the samples were characterized using mercury intrusion porosimet...
Autori: Kang Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27634

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

In this work, PM2.5 removal mechanism was explored to investigate PM2.5 collection efficiency under the influences of applied magnetic field and diffusion charging (the main charging mode for submicron particle). The proposed electrostatic precipitators (ESPs) mathematical model considered three-field interaction between fluid field, electromagnetic field and particle dynamic field. CFD software FLUENT was used to generate the simplified solid structure of the ESP. In numerical calculation, t...
Autori: Jian-Ping Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27667

Atmospheric concentrations of PM2.5 and PM10 were measured in Beirut, Lebanon, for a period of 12 months. The daily average concentrations of PM10 and PM2.5 were found to be 51.3 ± 33.1 and 30.3 ± 9.4 μg.m−3, respectively, with corresponding maximum values of 359.7 and 208.6 μg.m−3. The annual average concentrations of PM10 and PM2.5 exceeded the World Health Organization’s standards by 150% and 200%, respectively. The mean concentration of coarse particles ...
Autori: Wehbeh Farah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27696

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27782

Bare zero-valent iron nanoparticles (bare-ZVIN) have a great tendency to aggregate, which drops their reactivity with pollutants. To address this issue, polyvinylpyrrolidone stabilized-ZVIN (PVP-ZVIN) was synthesized and used for the removal of Cd2+ from aqueous solution in a batch system. The effects of operation conditions such as the pH of aqueous solution (2-8), reaction time (0-120), adsorbent concentration (1-6 g L-1) and the initial Cd2+ concentration (10-60 mg L-1) on the removal efficie...
Autori: Amirhosein Ramazanpour Esfahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27764

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27729

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27730

In this study, the removal of Cu(II) from real industrial wastewater, being taken from galvanotechnic industry, by means of manganese ferrite (MnFe2O4) nanoparticles (NPs) was investigated. The effects of pH, adsorbent dosage, and contact time on Cu(II) removal from wastewater were monitored using the real wastewater while the effect of initial concentration was studied on synthetic aqueous solutions. Optimal conditions were found for copper removal in this study. Cu(II) removal and adsorption c...
Autori: Naim Sezgin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27743

The research has been focused on concretes in which the continuous phase is some kind of polymeric resin and the discrete phase is some type of mineral aggregate. Such composite materials are known as Polymer concretes (PC) and boast several advantages such as lower weights, higher resistance to corrosive environments and chemical attacks, faster curing and lower permeabilities. In PC the inorganic fraction can reach up to 90% of the total and is made up of aggregates such as sand and gravel. Th...
Autori: Paolo Pozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27799

In this study, the effect of raw material formulation used in the core layer on the water resistance and mechanical properties of particleboard made from a mixture of rice husk and wood particles was investigated. For this aim, four series of particleboard core layer were produced from different proportions of rice husk/wood particles, different amounts of urea-formaldehyde (UF) adhesive, low density polyethylene (LDPE), and maleic anhydride grafted polyethylene (MAPE), respectively. The amounts...
Autori: Jin Heon Kwon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27871

Heavy metals are inorganic persistent pollutants with adverse health and environmental effects. In our study, self-synthesized iron oxide magnetic nanoparticles were encapsulated in the Phanerochaete chrysosporium (P. chrysosporium) hyphae. The prepared biosorbents possessed high efficiency for Pb(II) biosorption from single and binary metal systems. The maximum biosorption capacity was found to be 50.05 mg g–1 at pH 5.0. Environmental scanning electron microscope accompanied with energy d...
Autori: Danlian Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27864

In this study, five distinctive separation processes namely sand filtration (SF), adsorption, microfiltration (MF), ultrafiltration (UF) and nanofiltration (NF) were examined in two ways for the treatment of forging industry wastewater. At first, each process was examined separately, and then they were applied in association with each other as hybrid processes including pretreatment, main treatment, and post-treatment. The results related to non-hybrid experiments show that none of the mentioned...
Autori: Reza Aminzadeh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27847

In this paper, an improved engineering model and analysis techniques are presented of the fly ash particles coagulation with droplets in Venturi tubes of industrial scale, based on spatial variation of the collection efficiency of particles on individual droplets, accounting for spray water flow polydispersity and particle size distribution, which allows to define optimal droplets size and spray water flow rate at different modes of thermal power units operation. The model is validated with the ...
Autori: Igor Volchyn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27836

The aim of this study is to investigate a variety behaviors of two kinds of media (multiple-layer structures and multiple-layer structures combined with surface treatment, such as finer fibers) with ages using a scanning electron microscope (SEM) and to determine the effect of fabric microstructures on cake formation and pulse cleaning. The results show that fine particles are readily deposited on the surface and inside depth filter medium. The fine fibers with diameters (~0.08 microns, this val...
Autori: Yan Cuiping
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27842

The effect of synthesis conditions on sorptive properties of glycerol-derived mesoporous carbon materials were studied. Sorption properties of the synthesized carbon-based materials regarding to different adsorbate molecules, as well as water vapors, phenol and methylene blue molecules were analyzed. The sorption capacity of the synthesized mesoporous carbons depends upon synthesis conditions, namely upon pyrolyzing temperature and carbon precursor to silica weight ratio, being determined by ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27880

The synthesis of dimethylamino-propylamine pullulan, DMAPA-P, with a substitution degree of 0.4 was performed in dimethylsulfoxide using N,N’-carbonyldiimidazole as activator and dimethylaminopropylamine as amination agent. Then, two quaternary derivatives (trimethylammonium-propylamine pullulan, TMAPA-P, and benzyldimethylammonium-propylamine pullulan, BzDMAPA-P) were prepared from DMAPA-P by quaternization with methyl iodide and benzyl chloride. The behavior of new pullulan derivativ...
Autori: Anca Giorgiana Grigoras
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27902

In this study, Mg-doped ZnO nanoparticles with 2% Mg content were synthesized by sol-gel method. The structure and morphology of the nanoparticles were characterized by TEM, BET and UV-Vis absorbance techniques. From TEM image, it was found out that the nanoparticles had uniform size and uniform distribution. BET analysis revealed that in comparison with pure ZnO, Mg 2%/ZnO nanoparticles had a higher specific surface area. Based on UV-Vis absorbance analysis, Mg 2%/ZnO nanoparticles shifted t...
Autori: Nahide Zarei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27909

This paper presents the results of a case study conducted between 2.04 and 24.04.2013 in order to establish the most relevant indicators that characterize the influence of outdoor air pollution, with particulate matter having a nominal diameter less than 2.5μm (PM2.5), on the quality of indoor air from a new building. The tests consisted in simultaneous determination of the daily average PM2.5 concentrations at four indoor sites and at one outside, nearby the building. The average PM2.5 c...
Autori: Elena Bucur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27914

Electrically charged particles of air pollutants show the degree of atmospheric pollution they being consistent with some chemical indicators of air pollution. This study analyses these indicators of atmospheric pollution (EIAP) present in various zones around the cities of Iasi, Bacau and Piatra Neamt and correlate them with the incidence of some diseases amongst the population. The results show that certain values of electrical indicators of atmospheric pollution point to a higher incidence...
Autori: Liliana Sachelarie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27916

The theoretical and computational studies of dye sensitized solar cells (DSSCs) can contribute to a deeper understanding of these types of solar cells. The DSSCs are the novel design of solar cells which could be used as power producing windows or skylights. They represent a particular promising approach to a direct conversion of sunlight into electrical energy at low cost and with high efficiency. The light adsorption occurs in dye molecules adsorbed on a highly porous structure of TiO2 film...
Autori: Nnditshedzeni Eric Maluta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27932

The present study explores the potential use of plant waste i.e. spotted golden thistle (Scolymus maculatus L.) stalks, as an inexpensive sorbent for the removal of methylene blue from synthetic aqueous solutions. Firstly, the waste material was characterized using different analysis methods, then kinetics and equilibrium of dye sorption were investigated using a batch sorption technique. The influence of contact time, initial dye concentration, sorbent dose, particle size and agitation speed...
Autori: Zoubida Senouci Bereksi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27941

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27946

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27947

Analyzing and reducing the possible effects of air pollution on human health became important issues for improving the quality of life in urban areas. Particulate matters (PM) are air pollutants with a potential important impact on the health of vulnerable people (e.g., children, elderly) and non-vulnerable people as well. The level of PM air pollution is mainly influenced by the PM concentration and by parameters such as the meteorological conditions and the synergic effects of other air pol...
Autori: Adrian Florea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27951

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27968

Synthesis of silver nanoparticles (AgNPs) by plants is a simple, non-toxic and eco-friendly method. The purpose of this study was to develop a method for obtaining silver nanoparticles with biological properties. For reducing the silver ions, an extract of Tilia cordata (linden) flowers was used. Some parameters were investigated to optimize the synthesis method. Thus, the conditions of reaction were varied, such as pH, concentration of silver salt, different ratio of plant extract and silver sa...
Autori: Andreia Corciova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27977

Nanoparticles (NPs) have recently been concerned as emerging contaminants. Determination of NPs in different environmental compartments is a revealing topic for researchers studying their impacts in nature. Various methods of analysis have been reported in literature for their measurement and recovery. However, there are difficulties in their quatification in landfill leachate. Taking into account varying landfill components and their possible interactions with NPs, different types of NPs wer...
Autori: Ceyda Senem Uyguner-Demirel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27989

Due to emissions from power station using fossil fuels, the decrease of existing pollution as well as of operational costs should be taken into consideration, when resolving environmental economic dispatch problems. In this research, we will evidence that nonlinear constraints of generating units, forbidden regions, and ramp-rate of generating units will reduce operational costs and environmental pollution, to achieve environmental economic dispatch effectiveness, by employing an improved mul...
Autori: Daqing Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28045

Dust explosions are one of the main causes of mining disasters. To avoid them, it is important to understand how they are propagated. In the study reported here, computational fluid dynamics software was used to model a 3D diagonal pipe network then simulated a dust explosion at its inlet to examine its propagation characteristics. The initial conditions, boundary conditions and parameter settings were detailed description in the simulation to analyze possible propagation characteristics, assess...
Autori: Baichao Song
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28067

Over the last few years, the use of nanomaterials in the construction industry has grown prominently. Nanomaterials can considerably modify the properties of construction materials and even improve their performance. Despite their merits, considerable research has reported that nanomaterials pose a potential risk to human health. For this reason, it is important to fully comprehend the effects of nanomaterials on human health and the environment throughout all phases of their life cycle, includ...
Autori: Saeed Kamali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28091

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

The booming production and application of nanoparticles have raised great concern over its effect on environment, due to their increasing release in the environmental systems via intentional or unintentional activities, where their possible physicochemical and toxicological behavior remain unknown. The nanoparticles are released into the different environmental systems like air, soils and waters. However, their interaction with air matrices has been rarely investigated. For this reason, the chan...
Autori: Asli Baysal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28124

Photocatalytic processes are among the most efficient treatment methods of waters polluted with recalcitrant organic substances. Nanotubular TiO2 arrays with photocatalytic properties were obtained in the process of titanium anodic oxidation in the fluoridecontaining electrolyte. Under the proposed conditions of electrolysis, a coherent system of tightly adjoining nanotubes was formed with the internal diameter of 60-80 nm and walls thickness up to 60-65 nm, the tubes height being dependent on p...
Autori: Gheorghe Duca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28137

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Soluble dyes are intensively used in various industrial activities. They represent an important class of water pollutants from which they are rather difficult to remove. This paper focusses on the elimination of Congo Red (CR) ionic azo dye by adsorption on a low cost material. Cherry stones were used for activated carbon preparation by carbonization method. A temperature of 600 °C and a time of 4 h were found as adequate parameters for the physical activation and led to a final white powder...
Autori: Cristina-Gabriela Grigoraș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28153

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

Distribution of solid particles in the atmosphere around the pollution sources has an important role in decision making to oppose with air pollutants. This study reports the concentration and distribution of 11 heavy metals including Cu, Co, Ni, Cd, V, Ti, Mo, Cr, Pb, As, and Hg emitted from 6 incinerators (A to F) with various feeds and operating conditions to determine the extent of exposure for industrial and residential areas. These incinerators located at Petrochemical Special Economic Zone...
Autori: Akbar Pirbadali-Somarin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28166

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

Adsorption of diazinon from aqueous solution was studied by using cross-linked Chitosan/Carbon Nanotube (CHN-CNT) in a fixed-bed column. The cross linked CHN-CNT with 2.5% of MWCNT was prepared with a protected crosslinking method. The effects of the initial concentration of diazinon, bed-height, and flow rate on the adsorption of diazinon onto the cross linked CHN-CNT were investigated. The highest bed capacity of 29.47 mg/g was obtained at the initial concentration of 50 mg/L, flow rate of 10....
Autori: Tahere Taghizade Firozjaee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28174

This study aims to evaluate the properties of different wastes obtained from four red ceramic brick industries in the northern region of Santa Catarina, Brazil. The characterization of the clay brick waste (CBW) was performed using the XRD techniques, XRF, FTIR, DTA and SEM. Techniques to determine the pozzolanic activity, particle size, B.E.T. surface area and specific mass were used. The consumption of calcium hydroxide (CH) in the cementitious pastes with the CBWs was also measured. An app...
Autori: Adilson Schackow
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28184

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

The study is focused on creating magnetic mesoporous materials through the insertion of a nickel ferrite into the structure of kaolintype clay. Sol-gel auto-combustion method was employed to synthesize the materials, using glycine and tartaric acid as chelating/combustion agents. This is the first study on the combined effect of different fuel agents and of clay-to-ferrite molar ratio on the structural, textural, magnetic and adsorptive properties of nanocomposites. The value of the average por...
Autori: Stefana Cojocaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28210

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349