Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

AbstractThe paper presents new experimental results on the photodegradation of two important phenyl urea herbicides in water: Monuron and Isoproturon. The photodegradation was performed by two Advanced Oxidation Processes (AOPs): the homogeneous photo- Fenton process (, UV-H2O2 - Fe3+) and a heterogeneous photo - Fenton reaction using an iron pillared Laponide- RD catalyst (Fe-Lap-RD). The Fe-Lap-RD catalyst was prepared from iron nitrate 0.2 M solution and a suspension of Laponite - RD clay. Th...
Autori: Elsa Lundanes, Ilie Siminiceanu, Maria-Magdalena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25234

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

AbstractThe purpose of this study was to investigate the immobilization of denitrifying bacteria on microbial cellulose (MC) for biological denitrification. A novel denitrifying bacterium, Pseudomonas stutzeri, was immobilized in microbial cellulose and introduced into an up flow packed bed reactor in order to remove nitrate from synthetic influent. The MC presented the high biomass concentration throughout the experiment, achieving 3.4 mg biomass/g support. The efficiency of the system for deni...
Autori: Abbas Rezaee, Hatam Godini, Hossein Bakhtou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25302

AbstractAt global level, the microbiological quality of water is a matter of concern, since diarrhoea represents the second cause of mortality. In addition, nitrates represent a significant problem and their high concentration - above the accepted limits - in drinking water is frequently encountered in Romania. Water samples have been analyzed in accordance with the methodology recommended by The Public Health Institute Bucharest. 78.15% of the water samples evaluated during the interval 2004-20...
Autori: Claudia Sarmasan, Lucia Daina, Sonia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25325

AbstractGroundwater is an important source of drinking water, especially for rural population. In the last years, bacteria, nitrate, organic chemicals and other pollutants existing in groundwater have increased public concern about the quality of groundwater. Groundwater provides about 22% of all freshwater withdrawals; 37% of agricultural use (mostly for irrigation); 37% of the public water supply withdrawals; 51% of all drinking water for the total population and 99% of drinking water for the ...
Autori: Ancuţa Rotaru, Paulica Raileanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25329

Abstract The analysis over the underground water monitoring system and the collected data from survey drilling show that the underground water has an unsatisfactory quality due to some physical and chemical characteristics. Along with these, factors like the surface water pollution, the hydrodynamic exchange between surface and underground waters and the reintroduction in the agricultural activities of nitrates and phosphorus based fertilizers lowers, as well, the quality that it has been tal...
Autori: Ioan Crăciun, Catrinel-Raluca Giurma-Handley, Ion Giurma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25436

Abstract The paper presents new studies about the removal efficiency of the biochemical treatment process of the Municipal Wastewater Treatment Plant from Constanta city, during 2008. Influent and effluent samples of biochemical treatment stage were collected and ammonium concentration, chemical oxygen demand (CODCr) and biochemical oxygen demand in five days (BOD5) were measured, aiming to study the evolution of the removal efficiency, during 2008. Additional analyses have been performed in ...
Autori: Elisabeta Chirilă, Camelia Draghici, Adriana Puhacel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25458

Abstract The constructed wetlands are considered as a low-cost alternative system for nitrogen removal. Shale was selected as a media in constructed wetlands, on the basis of adsorption capacity and suitability for plant growth. The specific objective of this study was to evaluate nitrogen adsorption capacity for using as a media in constructed wetlands. Shale was sieved into 5 particle sizes Shale A-E. The physical and chemical characteristics of shale showed that it is suitable to be use as...
Autori: Amara Daothaisong, Jareeya Yimrattanabovorn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25535

Abstract The aim of this study was to assess nitrate removal using impregnated activated carbon (AC) with MgCl2. After impregnating of AC using heat treatment, the MgCl2 is converted to efficient MgO. The denitrification was conducted at pH 6.2, 25?C, and initial concentrations of 20 mg/L nitrate-N. The effects of the operating parameters including AC dosage, pH, and contact time have been investigated. Experimental data show that AC modified by MgCl2 was more effective than virgin AC for nit...
Autori: Abbas Rezaee, Hatam Godini, Sahand Jorfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25618

Abstract The aim of this work was the evaluation of the denitrification potential of a consortium of activated sludge adapted to anoxic conditions. As the carbon source is the main parameter influencing the denitrification process, in the first stage three carbon sources (acetate, citrate and glucose) were assayed in batch activity tests. The highest denitrification efficiency was ttained with acetate, being nitrate and nitrite completely reduced. The adapted sludge was then used as a potent...
Autori: Joana Azeredo, Pilar Teixeira, Rosario Oliveira, Zelia Fernandes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25638

The variation of acidity and the wet deposition fluxes of rainwater in Nanning City were analyzed based on the local acid rain monitoring data provided by environmental protection authorities from 1991 to 2004. The result shows that the annual value of pH is less than 5.6 in the past 14 years and the wet deposition has been getting more and more severe in Nanning. The ratio of SO42-/NO3 - has decreased. NO3 - has played an increasingly large role in acidity, though SO4 2- remains a key player. T...
Autori: Feng-qin Zheng, Guo-liang Liao, Hai-hong Huang, Yu-chun Mo, Shen-xian Wuhttp://www.ecozone.ro/reviste.php?RID=25678

Abstract:The present paper presents an enhanced Activated Sludge Model No. 1 in which nitrification and denitrification are modelled astwo-step processes. The nitrification process is considered as a sequence of two steps carried out by two distinct genera ofbacteria, with nitrite as an intermediate product. For the denitrification process a parallel approach was used that considers nitrateand nitrite to be directly reduced to molecular nitrogen. The new model is compared to the original Activat...
Autori: George Simion Ostace, Paul Şerban Agachi, Vasile Mircea Cristea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25786

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

The availability of good quality water is an indispensable condition for preventing diseases and improving the quality of life. Water is one of the most important renewable resources, which must be prevented from deterioration in quality. Various physicochemical parameters like pH, alkalinity, total hardness, total dissolved solids, calcium, magnesium, nitrate, have a significant role in determining the potability of drinking water. In this study, samples were collected from wells situated in vi...
Autori: Maria Cioroi, Mirela Praisler
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25853

Abstract An activated sludge from SBBR (sequencing biofilm batch reactor) reactor filled with Fe0  as filler had been acclimated to Fe(III)rich environment aiming at secure an enrichment culture of iron-reducing bacteria. The dissimilatory Fe(III) reduction ability and its efficiency on the effect of nitrogen and phosphorous removal by dosing different Fe(III) under anaerobic condition were investigated. The mechanism was also proposed based on the results derived from the experiment a...
Autori: Jie Li, Juanjuan Feng, Siyuan Zhai, Ya’e Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25943

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThis paper is an analysis of a case study which entails the assessment of pollution degree with nitrate in the Prut river basin, byanalysing 23 wells. The novelty of this work is the use of modeling done by GIS techniques, namely the Digital Terrain Model(DTM) interpolation technique, to obtain further information starting from discrete information.In the present paper, we emphasized the increasing tendency of nitrates and nitrites content in the underground waters, in directcorrelation ...
Autori: Florian Statescu, Gabriela Biali, Lucian Vasile Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26073

AbstractTwo laboratory-scale constructed wetlands planted with Juncus effusus were used to investigate the effect of nitrate load on thesulfur transformation dynamics related to the removal of organic carbon and ammonium. Organic carbon was removed at aconstant high mean level of 80% (inflow of 25 mg/L total organic carbon), irrespective of the nitrate load. In contrast, sulfatereduction responded immediately to the presence or absence of nitrate in an opposing manner, indicating a high abundanc...
Autori: Shubiao Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26095

Abstract A set of 500 water samples collected from various sites of Tarnava Mare River, between Medias and Copsa Mica were analyzed, during three years (2010-2012). The physicochemical parameters like: temperature, pH, electrical conductivity (EC), total dissolved solids (TDS), salinity, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), lead (Pb2+), chloride (Cl-), sulfate (SO4 2-), ammonium (NH4 +), nitrite (NO2 -) and nitrate (NO3 -) were determined. The results were co...
Autori: Ioana Piştea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26114

AbstractKnown concentrations of naphthalene were added to soil samples to investigate the anaerobic degradation potential by theinoculated naphthalene-adapted bacteria under nitrate reducing conditions. Naphthalene could be anaerobically biodegraded tonon-detectable levels within 35 days when the initial concentrations were 5.8 mg/kg, 34.7 mg/kg, 61.4 mg/kg, 93.7 mg/kg and146.6 mg/kg in soil, respectively. The degradation rates of naphthalene increased with increasing initial concentrations. The...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26157

AbstractThe extent of the problem of the excessive fluoride in drinking water remains an important health issue. In the present work,strong-base anion resins were investigated to assess their sorptive removal capacity of fluoride from water. It was found that theremoval of fluoride was high at natural pH (7) and was improved for increasing contact time and adsorbent dosage. Themaximum sorption of the resin was 13.7 mg/g according to the Langmuir model, namely higher than the values reported in t...
Autori: Mohammad Taghi Samadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26273

AbstractThis paper presents the full-scale treatment of nylon production wastewater in a wastewater treatment plant in Henan province, Central China. In this case, a 9600 m3/d capacity wastewater treatment plant was installed to treat the wastewater generated from the production of nylon-66 salt, based on the biological anaerobic filter (BAnF) combined with an anoxic/oxic (A/O) process. The performance of the biological combined system was monitored over a 75-day period. The results revealed tha...
Autori: Chunlian Xu, Haiming Huang, Jiankun Dai, Jianrong Qi, Qianwu Song, Shaowei Wu, Wenjun Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26276

AbstractIn the present paper, support vector machines (SVMs) are used to develop a quantitative structure-activity relationships (QSAR) model for the reaction rate constants (-logkNO3) of 115 heterogeneous organic compounds, through reaction with nitrate radicals (NO3•) in the troposphere. Two quantum chemical descriptors used as the inputs for the SVM model were calculated with density functional theory (DFT), at the B3LYP level of theory with 6-31G(d) basis set. The best predictions were obtai...
Autori: Bing Yi, Jiyong Deng, Xinliang Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26284

AbstractThis study aims to investigate the environmental impacts of the municipal waste disposal facility of Pata Rat, Cluj-Napoca, Romania during dry periods of the year. The environmental impact assessment on the landfill site was carried out on the basis of the measurements of environmental quality indicators. Environmental indicators were measured in the surface water, soil and air. For the assessment of the environmental impacts generated by landfill on surface water measurements were carri...
Autori: Ákos Rédey, Anca Gurzau, Antoanela Popovici, Constantin Măruţoiu, Fazekas Bence, , Ildiko Varga, Raluca Mariana Haţegan, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26296

AbstractThe main aim of this study is to evaluate the residents public awareness from water-polluted areas in Tehran city, in terms ofwater quality (in particular nitrate pollution), and to measure their different performance and approaches to this environmentalproblem. For this purpose, district 18 (Yaft Abad, southwest of Tehran) was selected as a case study. A questionnaire wasprepared and distributed randomly among residents of the selected area in May 2011. The data were analyzed statistica...
Autori: Mohammad Mahdi Azadegan, , Reza Maknoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26314

AbstractThe survival of Formosan landlocked salmon has been threatened by the change of habitat ambience. Because of the potentialtoxicity of nitrite (NO2-) and ammonium (NH4+) to salmonid fisheries, we studied the evolution of nitrogen compounddistributions in stream water and their relationship with ambient abiotic factors. The water was sampled at five sites surroundedwith various land-use types in bi-monthly intervals for seven years. The results indicated that a high NO2- concentration occu...
Autori: Wen-Hui Kuan, Yi-Lang Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26351

AbstractIn this study, boron-doped diamond (BDD) electrode was tested in electrochemical oxidation and reduction processes using thesame vertical electrodes undivided cell in order to remove natural organic matter (NOM) and nitrogen compounds (NC) fromdrinking water. Boron-doped diamond-based electrochemical oxidation process has proven to be an efficient and versatilemethod suitable for NOM and NC in forms of nitrite and ammonium present in drinking water sources. However, the applicationof BDD...
Autori: Florica Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26492

AbstractWe reported the results of an isotopic study aimed at evaluating the medium to long-term effects of different water qualities anddeficit irrigation strategies on the ecophysiology of grapefruit in a 7-year-old plantation in SE Spain. For a better understandingof the interaction between nitrogen and salts from reclaimed water, RW, an experiment using natural abundance (δ) of 15N wasconducted. This study showed that in grapefruit crop irrigated with RW leaf δ15N value increased. ...
Autori: Cristina Romero-Trigueros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26573

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract The adaptation of commercially available ion-selective electrodes (ISEs) for use in wastewater matrices was demonstrated using multivariate analysis and optimization with the Microsoft Excel Solver tool. The electrodes were characterized in pure analyte solutions, and their parameters were estimated using multivariate analysis and Solver optimization. The ammonium, nitrate, and nitrite ions were measured in model systems that were designed to simulate wastewater. The accuracy of the...
Autori: Natalija Koprivanac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26687

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract Chitosan was cross linked with gluteraldehyde and chemically modified by introducing xanthate group onto its backbone using carbon disulfide under alkaline conditions. This crosslinked xanthated chitosan flakes (XC) was used as an adsorbent for the removal of mercury ions from contaminated water streams near the coal mines. XC was found to be far more efficient than the conventionally used adsorbent activated carbon. FTIR studies indicated the interaction both amine and the xanthate...
Autori: Avinash Gupta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26725

Abstract In Hungary, 0.5 million m3 of thermal water is exploited every day for diverse purposes. After utilization, this enormous amount of thermal water becomes sewage water with a high concentration of salts, heavy metals, ammonia, nitrate, an unfavorable ion composition and high temperature. A common treatment is to dispose of waste water into a surface recipient through uninsulated channels surrounded by arable land. By infiltration, sewage water can cause potential salinization/sodific...
Autori: Andrea Farsang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26742

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract The short-term effects of plant diversity (number of plant species and species compositions) on aboveground biomass, substrate inorganic nitrogen (N) concentrations, and substrate solution “effluent” N concentrations were studied in a subsurface verticalflow constructed wetland (CW). Results showed that (1) the number of plant species increased aboveground biomass (P< 0.05) but had no effect on the overyielding index DMax; (2) the species compositions and presence of ...
Autori: Hai Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26822

Abstract The paper presents a study on the hazards associated with solid ammonium nitrate (AN) storage and handling, in particular the hazard of explosion. Due to its flammable and explosive characteristics, AN is largely used as an explosive material in the mining industry. Some specific problems encountered in the risk estimation are related to the determination of the explosive power of the AN, which depends on several characteristics. The simulation results of AN explosion using differen...
Autori: Zoltán Török
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26891

Abstract This study presents enhanced reduction of soluble contaminants in a modified electrocoagulation process that is capable of treating a mixture of aqueous contaminants. By incorporating an iron foam cathode, the process can remove aqueous trichloroethylene (TCE) by 99.1% and nitrate ions by 98.2%, which represents 58.1 and 20 percent higher than the removal rates achieved by iron plate cathode, respectively. pH and ORP measurements indicate the development of a reducing electrolyte c...
Autori: Xuhui Mao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26915

Moving bed biofilm reactor (MBBR) technique is a useful technology for the treatment of mature landfill leachate. The reactor start-up and acclimation processes illustrated that many factors, such as biomass, C/N ratio, and influent volumetric loading rates, could affect the ammonium-nitrogen (NH4+–N) and COD removal. The factorial experiments were carried out to determine the optimal reactor operational conditions, and the results demonstrated that when DO 2-4 mg/L, pH 7.5, and hydraul...
Autori: Wei Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26932

The pickling liquor used in the stainless steel manufacturing process is a mixture of nitric and hydrofluoric acid which generates wastewater with nitrate concentrations ranging between 500 and 6000 mgNO3--N/L. In the present study, laboratory-scale anoxic Sequencing Batch Reactors (SBRs) were used to treat high nitrate wastewaters. Two different sludge inocula were tested: one from a Municipal Solid Waste Leachate Treatment Plant (LTP), and the other from a Sewage Treatment Plant (STP). Meth...
Autori: Ana Isabel Pelaez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26933

As a result of the rapid development of China’s economy, many surface and groundwater have become polluted. Assuring high quality drinking water, especially for the rural areas has recently received much attention. In this study, the drinking water quality in one centralized water supply network was evaluated by analyzing 28 pollutant indices at 35 sampling points. It was determined that the concentrations of most organoleptic and physical indices were stable in all the water samples. T...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26967

The adsorption characteristics of nitrate ions from aqueous solution using Lewatit FO 36 was investigated as a function of pH, biomass dosage and contact time. Results showed that optimum conditions were obtained at pH 8, adsorbent dosage of 160 mg/L and contact time of 60 min. At the optimized experimental parameters, the maximum nitrate adsorption capacity of Lewatit FO 36 was 200 mg/g and nitrate adsorption followed Freundlich model. Among seven kinetic models used in this study, the adso...
Autori: Mehdi Ahmadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26996

Treatment of domestic wastewater using constructed wetland system vegetated with Phragmites australis was studied at lab scale. Response surface methodology (RSM) a mathematical model was employed for analyzing the effect of independent factors (inlet flow rate, outlet flow rate, retention time) on wastewater parameters e.g. electrical conductivity, BOD5, COD, nitrates, phosphates, total solids, suspended solids, heavy metals in order to maximally treat wastewater. All independent variables w...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26999

A pure strain of Pseudomonas chlororaphis DJ-4 capable of anaerobic biodegradation of o-xylene, m-xylene and p-xylene was isolated from gasoline contaminated soil. In batch cultures, growth of the strain and biodegradation of xylene isomers led to stoichiometric reduction of nitrate. P. chlororaphis DJ-4 could degrade 150 mg L-1 of m-xylene completely within 12 days and without a lag period. However, higher initial concentrations of o-xylene and p-xylene were toxic to the bacterium of P. chl...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27005

Researching and industrializing a new pharmaceutical form results in an impressive amount of waste due to the methods used. Despite numerous reports about the addition of pharmaceutical ingredients to the environment, the effect they have on the environment at the nanogram (ng) level remains largely unknown; thus, it has been proposed to retain toxic compounds using Dowex resins in biomucoadhesive tablets containing miconazole nitrate, an antifungal medication. This study demonstrates the re...
Autori: Magdalena Bîrsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27091

Three different winter wheat production systems for three European countries (United Kingdom, France and Italy), all with different climatic conditions, soil management and input levels (e.g. tillage, fertilizers, herbicides and pesticides) were analysed from an environmental perspective. The intended applications were the analysis and comparison from a Life Cycle Assessment (LCA) perspective and the identification of the key parameters which have the greatest influence on final results. The ...
Autori: Daniele Cambria
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27102

Freshwater marshes are the single largest source of atmospheric methane (CH4). Climate change and anthropogenic nitrogen (N) deposition can alter the production and oxidation of CH4 respectively and thereby also CH4 exchange. But there was little known about how N regulate key carbon (C) processes, like CH4 production and oxidation under freshwater marshland conditions. In this study, field-fertilization and incubation experiments were conducted to investigate the effects of four N-fertilizat...
Autori: Lihua Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27107

Three pilot-scale biofilters consisting of 1 m aerobic woodchip layers and 0.5 m submerged woodchip layers were constructed to treat the separated pig manure anaerobic digestate (SAD). Reductions of 54% dry matter, 80% of chemical oxygen demand (COD), 93% of 5-day biochemical oxygen demand (BOD5), 86% of total nitrogen (TN) and 79% of total phosphorus (TP) were achieved. The study results confirm the occurrence of nitrification in the aerobic woodchip layers and denitrification in the submer...
Autori: Kathy Carney
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27161

Groundwater originating from two rural communities from Cluj and Bistrita Nasaud counties was analyzed using parallel ion chromatography, the focus being on major anions (chloride, nitrite, nitrate, phosphate and sulphate) and cations (potassium, sodium, ammonium, calcium and magnesium). These analytes were determined simultaneously using a Shimadzu two-channel instrument with non-suppressed conductivity detection, separations being carried out using an Allsep Anion 7u column and an Universal Ca...
Autori: Edward Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27211

The Storm Water Flow (SWF) and the Dry Weather Flow (DWF) canals carry composite industrial and municipal effluent (nearly 50,000 m3 d-1) from Kolkata city. Wastewater from SWF and DWF canals is used for pisciculture at the East Calcutta Wetland (ECW) for nearly a century. A wastewater fed pisciculture pond was selected to study the efficiency of the pond in treatment of wastewater. Monthly changes of hydraulic variables viz. inflow and outflow rates, depth, hydraulic loading rates, detention ti...
Autori: Abhishek Roy Goswami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27255

Water quality index is an essential tool for water quality assessment. Considering the frequent use of automated water quality monitoring systems, their importance in generating data and information for the efficient management of water treatment plants, the design of such an index would allow the detection of point-pollution episodes, which otherwise would occur undetected and would have a significant impact on the water quality and its further treatment. In this study, a versatile weighted wat...
Autori: Ioana Gabriela Dascalescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27271

This paper describes laboratory experiments conducted to investigate groundwater flow and solute transport within the capillary fringe (CF) and exchanges between the CF and the region below the water-table. An experimental bench was developed in order to simulate an unconfined aquifer, to observe the development of the CF and to study nitrates transfer from groundwater to CF, and also the fate of nitrates into the CF. The experimental bench has three compartments, the middle one being filled wi...
Autori: Mihaela Amalia Diminescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27277

Water is the source of life and a high water quality leads to a harmonious development of the surrounding environment (biotic and abiotic) and of humans. When water is loaded with various chemicals due to erosion, corrosion and human activities, the pollution phenomenon appears, causing harmfull effects over plant and animal organisms. The presence in water of substances derived from agriculture or mismanagement of manure organic obtained from various species of domestic animals affects the envi...
Autori: Alina Simionică Bădilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27285

Chemical composition variations of aerosols during summer and winter seasons have been investigated using an Aerosol Mass Spectrometer (AMS) at Magurele, a city near Bucharest, Romania. Proportions of chemical species, concentration time series, mass range distribution and aerodynamic size distribution of aerosols have been analyzed. AMS measurements proved that the organics, nitrate, sulphate and ammonium, with small amounts of chloride were the main species at ground level during the investig...
Autori: Jeni Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27479

Groundwater pollution investigation near old and closed landfill sites is increasingly attracting more attention. Nitrogen compounds, especially those leached from the landfill area, are often regarded as a main pollution source for the groundwater. This study investigated the nitrogen pollution in the groundwater near a closed old landfill area of Beijing, China. The field investigation showed that the nitrate-polluted groundwater was determined as Class VI (refers to bad quality) at the detect...
Autori: Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27585

The performance and microbial community of an anoxic-aerobic sequencing batch reactor (SBR) treating saline wastewater were investigated at different influent COD/N ratios. The average COD removal efficiencies at steady states were 87.46%, 73.75%, 64.87% and 88.34% at the COD/N ratios of 20, 10, 6 and 30, respectively. The average NH4+-N removal efficiencies were 79.74%, 74.34%, 64.55% and 89.29% at the COD/N ratios of 20, 10, 6 and 30, respectively. No obvious accumulation of NO2--N and NO3--N ...
Autori: Sen Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27592

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

An attempt has been made in the present study to investigate the wastewater characteristics from six different rural human settlements in the state of Punjab, India. The six selected rural catchments are located on a radius of about 5-50 kilometers from Phagwara town, Kapurthala district. The study area comprises the villages of the districts of Jalandhar, Kapurthala and Shaheed Bhagat Singh Nagar in Central Punjab. The wastewater samples were collected between January, 2012 and July, 2012 and a...
Autori: Puneet Pal S. Cheema
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27641

This study deals with the decolorization and detoxification of tannery wastewater by an indigenous fungal isolate, Trichoderma viride SPFT1 isolated from untreated tannery wastewater. The results showed that treatment with Trichoderma viride SPFT1 reduced chemical oxygen demand (COD) (74.20%), nitrate (60.83%) and color (45.24%) of the tannery wastewater after six days of the incubation period. The toxicity assessment of the tannery wastewater on Phaseolus mungo L. var. PU-19 showed 70% seed ...
Autori: Smiley Sharma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27658

One of the main challenges for the development of biomass algal system production is the high operational and capital costs for these technologies. A great opportunity to overcome these challenges may however exist in the integration of wastewater treatment with algal biomass production. The algae are used for treatment of industrial wastewater, for purification of effluent originating from livestock production, while the studies concerning the use of algae species for the treatment of aquacultu...
Autori: Katya Velichkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27684

The presence of nitrogen in its reduced forms serves as an indicator of natural aquatic system degradation. The excessive concentrations of nitrogen in reduced forms (NH4+, NO2-) found in the sections of the the Shireutsi (of the Prut River) and the Olaneshti (of the Nistru River) prove that these sites are areas to focus efforts on improving water quality. Laboratory simulations indicate a good environmental buffer action of natural waters to potential pollution in Sculeni and Ungheni sections ...
Autori: Petru Spataru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27698

During the years 1965-1985, a veritable industrial platform was developed in the west part of Oradea, Bihor County, Romania. It stretches on an area of 9 sq. km. and is placed in the meadow of Crisul Repede River. Throughout that period, several industrial facilities were built that lately became sources of pollution for the environment. The purpose of the present paper is to study the influence of historical stages of industrialization and restructuring of enterprises in Western Oradea, address...
Autori: Tamara Romocea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27747

The corrosion inhibition of mild steel in acidic media at 303 – 333K in 0.1 - 0.5M acids (hydrochloric acid - HCl and trioxonitrate (v) acid - HNO3) and 0.01-0.03g/L Aloe Vera extract (AVE) were investigated by standard weight loss method. The corrosion rate was calculated in the absence and presence of the inhibitors. The inhibition efficiencies of AVE in both acid media increased with increase in concentration and decreased with increase in temperature and period of immersion. Results sh...
Autori: Maureen Ndibe
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27870

We assessed the variability of the main physico-chemical parameters of drinking water: oxidability, turbidity, conductivity, water hardness, free chlorine concentration, chlorides and nitrates across the four seasons (Spring, Summer, Autumn of 2013 and Winter of 2014). We collected data from several points in the supply network of Satu Mare city, NW of Romania, where the source of drinking water is groundwater. The results revealed significant higher average values in spring for some of the ...
Autori: Thomas Dippong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27928

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Groundwater recharge is an effective method to solve the groundwater overexploitation. In this study, the method of numerical simulation is used to discuss the environmental change of groundwater in the process of multi-source recharge. The results of multiple water sources including local regenerated water source, wetland water source and South-to-North water source show that the cumulative loss of groundwater resources in Mihuaishun area in 2007 ~ 2016 reaches -1.784 × 109 m3. The inf...
Autori: Dasheng Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28024

The main objective of the research was to study the efficiency of the glyphosate amine pesticide mineralization in wastewaters (real and model type of wastewaters respectively) using ozonation treatment as an advanced oxidation processes (AOP). The wastewater samples (model wastewater) were obtained by mixing a given volume of the stock solution prepared from glyphosate isopropyl-amine in different volumetric ratios with distillated water and with real wastewater obtained from a domestic wastewa...
Autori: József Németh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28050

This paper focuses on the effect of some water quality parameters of river water which helps in the calculation of water quality index (WQI) that culminates in the development of a regression model for prediction of WQI of the river system in India. The index was calculated by arithmetic index method using twelve various experimentally estimated water quality parameters such as potential hydrogen, chlorides, dissolved oxygen saturation, nitrates, sulphates, phosphates, total dissolved solids, bi...
Autori: Divya Airattil Haridas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28065

The increase of population and the bad management of municipal solid waste (MSW) lead to a spectacular increase of the landfill leachates volume. These effluents represent a very harmful threat that can affect the environment and the ecosystems, their control and treatment became the first occupation of the authorities. In this context, this study contributes to characterize the landfill leachate composition and how its changes over different seasons. The results have shown an intermediate leac...
Autori: Soukayna Rhouat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28100

Aim of the study is to determine Fe, Mn and Cd adsorption in the carbonate-rich clayey soils and to assess their environmental impacts. Soil samples represented a carbonate-rich clayey soil (Isaoren), carbonate-rich soil (Maşuk) and clayey soil (Aşık) was obtained from three different villages in Sanliurfa, southeast of Turkey. Adsorption studies were carried out with batch method. The maximum Fe, Mn and Cd adsorption was found on Isaoren, Maşuk and Aşık soils with ...
Autori: Ayse Dilek Atasoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28116

In this study we present time-related 3D ERI models for a site that was contaminated using waste automobile engine oil. The pristine geo-electrical characteristics of the site were recorded before the contamination was carried out. The purpose of the study was to progressively monitor the geo-electrical responses of the site for possible natural bio-transformations on the waste oil. Data were acquired once every two weeks for a period of three months using eight parallel 2D resistivity profiles....
Autori: Bokani Nthaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28118

Different anthropogenic influences and irresponsible actions pollute all the components of the environment and groundwater is no exception. Nitrates, which are one of the most common groundwater contaminants, come from different sources and they are not always easily detectable. The paper presents a study of a groundwater quality at the VaraĹždin wellfield in the north part of Croatia. The nitrate concentration at this location has been above the maximum allowed concentration for several decades...
Autori: Marko Ĺ rajbek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28140

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

Current landscapes have been intensively modified by humans and forest fragmentation has created substantial increases of forest edges. So far, scale-dependence between observable ecological patterns and the underlying processes affected by forest fragmentation have been widely ignored. To overcome the widespread ambiguity in selecting relevant spatial scales for studying the ecological effects of forest fragmentation, we investigated the effect of forest prevalence and edge length on carbon st...
Autori: Emilia I. Cojoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28242