AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

The use of gasoline oxygenated with MTBE (methyl tert-butyl ether) reduced significantly air pollution (16 - 23% lower emissions of CO and 18% lower emissions of unburned hydrocarbons) but increased water pollution. There is no European or national regulations for MTBE in drinking water except for Denmark, which has set a limit value of 30 Âľg/ L for MTBE. USEPA proposed a maximum concentration of 20- 40 Âľg/L. This paper is a review with 70 references on the MTBE production, use, properties and...
Autori: Camelia Beţianu, Florina Ungureanu, Loredana Branza, Lucian Vasile Pavel, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25122

Actual trends in papermaking concern on the use of recycled fibers and minimizing effluent volume by closing water circuit. Beside environmental and economic advantages, both trends can lead to serious problems in papermaking processes due to contaminants introduced with recycled fibers and their accumulation in closed water system. A key factor to avoid disturbances in the papermaking is to prevent the accumulation of detrimental compounds. In this respect, first it is necessary to find out met...
Autori: Dan Belosinschi, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25134

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

In recent years, the release of volatile organic compounds (VOCs) has received much attention. Catalytic oxidation of VOCs, found in small concentration in industrial gas emissions constitutes an alternative for environmental pollution reduction.In this paper, a comparative study regarding the non-catalytic and catalytic oxidative destruction of non-halogenated or halogenated C6 hydrocarbons (C6H14, C6H12, C6H6, Cl-C6H5, Br-C6H5), is presented. Catalytic oxidation was studied in the presence of ...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25162

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Contain all the articles from this issueEditorialEstablishing effluent discharge limits - have we got it right?Yusuf Chisti Full papersSurvey on the treatment of gaseous streams containing volatile organic compoundsOana Penciu, Maria GavrilescuEU environmental policy for industrial pollution control. IPPC DirectiveElena Bobu Environmental monitoring Antonius A.F. KettrupProcess The sonochemical degradationof cyanide ions using atmospheric oxygen as oxidizing agentIoan Iordache, Mircea Teodor Nec...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25171

Plants as biomarkers, biosensors and biomonitorsModelling of wastewater treatment of a pulp and paper mill for monitoringCatalysts for heterogeneous photocatalysts. Part I. Possibilities to improve photoefficiency through catalysts modificationThe global assessment method of the water qualityAspects regarding the wood certification in RomaniaDecolorizing of pulping effluents by ammonium lignosulphonate oxidationPowder coatings-based organic filmsOn environmental effects of the pulp and paper mil...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25172

Contain all the articles from this issueDestruction of Volatile Organic Compounds by catalytic oxidationAlice Oana Rusu, Emil DumitriuRisk assessment for a shipyard from Romanian Black Sea CoastAnca Florentina Caliman, Ion Balasanian Monitoring the behavior of the restoration interventions of the Probota Monastery’s indoor frescoes under the influence of the environmental factors. II. Modifications of the physical-structural and chemical characteristicsIon Sandu, Adrian Dima, Ioan Gabriel Sand...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25173

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei, Gabriela Apostolescu, Ioan Rosca Studies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monit...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25175

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractThe extraction of some pollutants from different matrices, the treatment of hazardous and infectious wastes, the destruction of refractory compounds and the prevention of noxious emissions are the main environmental applications of microwave-assisted chemistry. The advantages and disadvantages of this technique are also considered....
Autori: Carmen Zaharia, Georgiana G. Surpăţeanu, Mioara Surpăţeanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25217

AbstractVolatile organic compounds (VOCs) constitutes an important class of environmental pollutants, which, together with other contaminants as NOx, SOx, CO, NH3, CO2 etc. participate in degradation of atmosphere and exhibit a potential risk for human health. VOC emissions may be generated in more than 25 percentages through the use of solvents in different industrial or house holding activities. For applying a certain plan concerning the pollution reduction, any user of organic solvents contai...
Autori: Florin Bandrabur, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25218

AbstractThe behaviour of three types of steel, with a variable carbon concentration (from 0.20 to 0.40 %) is studied in medium of ethylene glycol - 10 % methanol - 5 % succinic or adipic acid with water concentration varying between 1 % to 5 %. IR spectroscopy, Xray diffraction and chemical analysis were the methods used for corrosion compounds analysis. The weight losses were measured; also the polarization curves were plotted and the corrosion parameters were established. Based on the obtained...
Autori: Daniel Mareci, Daniel Sutiman, Ioan Iordache, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25240

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

AbstractThe present work describes an investigation of process of ion-exchange separation of tartaric acid in model systems. These investigations will be used for the separation of tartaric acid from secondary wine products. Their valorisation allows obtaining valuable compounds, as well as decreasing the huge quantities of wastes accumulated at wine making factories.As ionic exchangers, there have been used weakly basic anion exchanger Amberlite IRA-67 (tertiary functional amine groups) and str...
Autori: Aliona Mereuţa, Gheorghe Duca, Herbert G. Boechzelt, Natalia Marchitan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25286

AbstractIn this work it had been tested the recovery of some compounds like: Fe2O3, TiO2, PO4 3- ions, Al2O3 from the sludges, which result in the industrial facilities for output of pure uranium dioxide. Solubilization of the chemical compounds from the uraniumwastes was performed in strong acidic media, using adequate methods....
Autori: Alexandru Cecal, Doina Humelnicu, Romeo Iulian Olariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25288

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractThe Romanian strategy in the field of irrigations for the years of 2008-2011 consists of the modernization of the existing works covering about 3.1 mil. ha, while for the years of 2011-2025 the irrigation of additional area of 0.9 mil. ha is expected. In the climate conditions of Romania, the irrigation has a complementary character over the precipitations. Because of this reason, a correct regime of irrigations needs a very good correlation between watering and precipitations in order t...
Autori: Dorin Cotiusca Zauca,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25317

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

A study was conducted to investigate the organic compounds residues in different types of coffee from market inThe detection limits ranged from 0.02 ng/kg to 0.04 ng/kg and quantification limits were 0.2 ng/kg. Calibration and recovery studies gave satisfactory results. Concentrations of OCPs in coffee samples varied from 0.001 mg/Kg to 0.007 mg/Kg. The methods provide a rapid and accurate determination of these organic compounds in coffee samples....
Autori: Gabriela Stanciu, Mariana Popescu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25338

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractPaint sludge of automotive industry contains heavy metals and other toxic substances. Due to this matter, it has a high pollution potential. Incorrect disposal of paint sludge led to kinds of environmental pollution. Recycling and reusing of wastes can be one of the best solutions for decreasing of pollutant entrance to environment. The purpose of this study was to present a new method of extracting the main components of paint sludge, for determining concentration of elements in paint s...
Autori: Azadeh Akhavan Bloorchian, Seyed Mostafa Khezri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25346

AbstractUrban air pollution is responsible for the highest burden of environmentally related diseases in Europe. Air pollutants with strongly indicated respiratory health effects are particulate matter, nitrogen oxides and sulfur dioxide. The retrospective ecological survey has taken into account the urban air pollution with sulfur dioxide (SO2), nitrogen dioxide (NO2), ammonia (NH3) and particulate matter (PM10). The analyzed data show that after applying the European regulations regarding the ...
Autori: Catalin Adrian Petrisor, Dorin Petrişor, Lucreţiu Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25348

AbstractThe technological process of basic chemical organic compounds synthesis is included among the economic activities that can affect the environment quality. The environmental impact of chemical organic synthesis is evaluated using the alternative method of global pollution index that considers the concentric circles graphical methodology proposing a scale of the arithmetic mean values for the evaluation scores of each environmental components (e.g. water resources, gaseous emission, soil a...
Autori: Carmen Zaharia, Ilie Murăraşu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25352

AbstractHigh proton conductivity of CsHSO4 opened new opportunities for applications as electrolyte in solid acid fuel cells (SAFC). Relatively recent, it was proved that the accommodation of this solid electrolyte by silica supports improves its proton conductivity. During this work, solid acid CsHSO4 and its composites with mesoporous silica of SBA-15 and MCF-types as host materials were synthesized and studied for the first time. Studies were mainly focused on the influence of mesoporous supp...
Autori: Adrian Ungureanu, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25366

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractThe use of adhesives for floor covering have been deeply modified for longtime, by formulations of polymer-based products in aqueous dispersion as an alternative to organic solvents. These advances envisaged ways for obtaining nonpolluting products. Developing these adhesives required the parallel development of methods for monitoring and analyzing the emissions over time. This paper shows the results of some research devoted to identify the indoor presence of volatile organic compounds ...
Autori: Irina Ioniţă, Domnica Ciobanu, Monica Tulbure, Iulian Tanţoş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25388

AbstractUltrafiltration (UF) represents an important option for the advanced wastewater treatment as it offers good performances from both technical and economical points of view, for the removal of suspended solids, colloids and some of the organic compounds present in different effluents. The occurrence of priority organic pollutants in wastewaters streams and the environment has raised intensive scientific debates about their effects and the possible abatement technologies. As part of a broad...
Autori: George Barjoveanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25390

AbstractThe study presents the processing possibilities for marc resulted as still residue from the distillation of fermented fruits in view to obtain a compacted solid fuel. Initial marc composition (carbon, hydrogen, nitrogen, sulphur and oxygen contents) determined by elemental analysis is evidenced, as well as technical characterisation (ash and moisture contents) and ash's qualitative composition, chemical characterisation of the liquid phase (pH, total phosphorus, acidity and conductivity)...
Autori: Daniela Simina Stefan, Anca-Ileana Penu, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25391

AbstractPersistent organic pollutants (POPs) are toxic chemicals that adversely affect human health and the environment around. This group of priority pollutants consists of pesticides, industrial chemicals and unintentional by-products of industrial processes. Natural materials, waste from industry and agriculture and bioadsorbents can be employed as inexpensive adsorbents to remove POPs from environmental components by sorption processes. The paper presents various natural sorbents and some ou...
Autori: Laura Carmen Apostol, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25395

Abstract Protection of plants from diseases, pests and weeds plays a decisive role in agricultural development, as an essential part in planning and policy of numerous countries. Since the plant protection products are mainly chemicals and may be not only poisonous for humans and fauna, but they may also pollute water bodies, ground water and soil with hazardous pollutants, their use have to be environmentally friendly and sustainable. The paper discuss some aspects of benefits and risks con...
Autori: Manuela Olga Pogăcean, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25405

Abstract This paper presents a comparative study of natural and mechanically mixed composting processes of marc resulting as a byproduct during the production of alcohol obtained from fermented fruits. Moisture, temperature, pH values, soluble fraction, total organic carbon, Kjeldahl nitrogen and ash content were monitored for 60 days. During this period the atmospheric temperature varied from 18Â?C to 21Â?C. The composting process could be considered a combination of three stages: mesophilic...
Autori: Anca-Ileana Penu, Daniela Simina Stefan, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25407

Abstract The synergistic combination of polymers and inorganic compounds via sol-gel process has attracted great attention, by manipulating structure at molecular level, for developing new materials with desired properties. These new hybrid materials could have a controllable combination of the benefits of polymers (flexibility, toughness, ease of processing) and those of ceramics or glasses (hardness, durability, thermal stability). The microstructures and the properties of hybrid materials...
Autori: Lucia Dumitrescu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25446

Abstract The Romanian standard for the analytical method for phenols measurements in aquatic media was subject of internal validation procedure, adapted to the specific concentration domain of the laboratory. Method performance criteria were investigated on standard samples measurements: selectivity, linearity domain, precision, accuracy, limit of detection, limit of quantification androbustness. The validated method was further used on real samples of domestic and industrial wastewaters from...
Autori: Carmen Dima, Cristina Jelescu, Camelia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25448

Abstract The aim of this present paper is investigation of the reactions of preparation of unsymmetrical reactive carbonates from the corresponding symmetrical carbonates and different type of alcohols. The asymmetrical carbonates represent alternative reagents (mild, efficient) for alkoxycarbonylation of amines and amino-acids. The synthesized compounds were characterized by spectroscopic and chromatographic methods. A general method for preparation of asymmetrical carbonates was develop fro...
Autori: Adina-Elena Segneanu, Ionel Balcu, Marius Constantin Mirica, Mirela Ioana Iorga, Marius Milea, Zoltan Urmosi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25472

Abstract Herbs have been used as food and for medicinal purposes for centuries. In recent years, natural compounds such as phenolic acids, phenolic diterpenes and triterpenes, present in various plants, have been the subject of intense research due to their potential benefits for human health. It has been demonstrated that the antioxidant and radical scavenge activities are the main properties of these compounds. The main difficulties in using natural products as a source for pharmaceutical ...
Autori: Ruxanda Bodirlau, Iuliana Spiridon, Carmen Alice Teaca, Narcis Anghel, Maria Ichim, Svetlana Colceru , Alice Armatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25474

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract Application of ozone is known to yield favorable results in purification of phosphate plant water from elemental phosphorus, in treatment of water of alkali aluminate solutions of aluminum plants, in decontamination of cyanide-containing waste water of enrichment plants, and so on. It has been proved that halogen-containing compounds, most of which have mutagenic properties, and some of which are carcinogenic to humans, are formed when water is treated with chlorine. Conclusions made...
Autori: Irina Dumitriu, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25483

Abstract Nanotechnologies may have properties of self-assembly, stability, specificity, drug encapsulation and biocompatibility as a result of their material composition. Nano-particles are being actively developed for tumour imaging in vivo, bio-molecular profiling of cancer biomarkers, and targeted drug delivery. These particles are stable, environmentally benign, and their chemical properties can be easily tailored by chemically modifying their surfaces. Conjugated with pharmacological a...
Autori: Simona-Florentina Pop, ,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25484

Abstract The purpose of this work is to investigate the secondary Al slag (SAS) relating to its technical and environmental properties and, as consequence, to its compatibility with Portland cement matrix. This study may be a contribution to establish of SAS potential valorization as secondary raw material (SRM) in low strength cement matrix composites, as construction products. DRX mineralogical analyses revealed that SAS includes transition alumina compounds, especial boehmite. The hydrati...
Autori: Maria Gheorghe, Nastasia Panait, Romanita Teodorescu, Maria Roman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25498

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract Peat moss has been widely used as low-cost adsorbent to remove a variety of pollutants, including organic compounds and metal ions from aqueous effluents. Various functional groups allow such compounds to bind on active sites of peat moss. The adsorbent used in this study was Romanian peat moss sampled from Poiana Stampei (Romania). The adsorption of Co(II) ions from aqueous solutions on Romanian peat moss was studied in batch experiments, in order to establish the influence of initi...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25533

Abstract The constructed wetlands are considered as a low-cost alternative system for nitrogen removal. Shale was selected as a media in constructed wetlands, on the basis of adsorption capacity and suitability for plant growth. The specific objective of this study was to evaluate nitrogen adsorption capacity for using as a media in constructed wetlands. Shale was sieved into 5 particle sizes Shale A-E. The physical and chemical characteristics of shale showed that it is suitable to be use as...
Autori: Amara Daothaisong, Jareeya Yimrattanabovorn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25535

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract This work presentes a study of preparation and stability in aqueous medium of complexes obtained by the reaction between Fe(III) with 2-amino-6-methoxy-benzothiazol-sodium sulphonate ??†’1 naphtol-4-sodium sulphonate. In this purpose, the investigation methods applied were as follows: pH-metry, conductometry, and the UV-VIS spectrophotometry. The molar combination ratio of ligand to central metallic atom, and the stability constants for new obtained compounds were determined usin...
Autori: Doina Sibiescu, Gabriela Carja, Ioan Roşca, Laura Chirila, Mihaela Vizitiu, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25585

Abstract In the last decades there has been a rapid evolution of techniques for production of bleached pulp. Much of these processes have been environmentally driven. New techniques have been developed in order to replace chlorine-based reagents in producing bleached pulp. Reducing the environmental impact of pulp production can be attain by using non-pollutant bleaching reagents like oxygen and related compounds. This paper deals with present findings and general trends in environmentally-s...
Autori: Adrian Catalin Puitel, Alexandru Botar, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25592

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract The aim of this study is the evaluation of photo-Fenton as a suitable advanced oxidation process to degrade ampicillin and streptomycin antibiotics. The degradation was studied by monitoring the organic substrate concentration changes in aqueous solution as a function of reaction time using COD analysis. The oxidation process follows two successive stages. In the first stage (I) the oxidation of the antibiotics takes place with high reaction rate, leading to intermediate oxidation pr...
Autori: Cristina Orbeci, Daniela Simina Stefan, Ion Untea, Madelene Dancila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25602

Abstract A method based on measuring substrate depletion rate was developed to evaluate the denitrifying activity of activated sludge in suspension and in biofilm form in anoxic serum flasks. The adapted activated sludge inoculum was grown as biofilm in an anoxic rotating biological contactor (RBC). Acetate was used as external carbon source to obtain a carbon to nitrogen ratio (C/N) of 2. The results showed that the specific activity of cells in biofilm form was higher than in planktonic for...
Autori: Elba Vivanco, Juan Carlos Ruiz, Paola Poirrier, Rolando Chamy, Yves Lesty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25617

Abstract The aim of this study was to evaluate the capacity of certain bacterial and fungal strains - isolated from the dairy industry wastewater - to biodegrade the organic compounds such as casein, lactose and lactic acid similarly to those which determine the organic pollution. The strains able to rapidly biodegrade organic compounds were identified and screened for the inoculum preparation which is afterward tested for the aerobic biological treatment of the simulated dairy-processing was...
Autori: Gabriela Bahrim, George Ifrim, Marian Barbu, Mihaela Palela, Sergiu Caraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25625

Abstract The aim of this work was the evaluation of the denitrification potential of a consortium of activated sludge adapted to anoxic conditions. As the carbon source is the main parameter influencing the denitrification process, in the first stage three carbon sources (acetate, citrate and glucose) were assayed in batch activity tests. The highest denitrification efficiency was ttained with acetate, being nitrate and nitrite completely reduced. The adapted sludge was then used as a potent...
Autori: Joana Azeredo, Pilar Teixeira, Rosario Oliveira, Zelia Fernandes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25638

Abstract A method based on measuring substrate depletion rate was developed to evaluate the denitrifying activity of activated sludge in suspension and in biofilm form in anoxic serum flasks. The adapted activated sludge inoculum was grown as biofilm in an anoxic rotating biological contactor (RBC). Acetate was used as external carbon source to obtain a carbon to nitrogen ratio (C/N) of 2. The results showed that the specific activity of cells in biofilm form was higher than in planktonic for...
Autori: Manuel Mota, Pilar Teixeira, Rosario Oliveira, Susana Cortez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25639

? POLLUTION PREVENTION, A KEY TO ECONOMIC AND ENVIRONMENTAL SUSTAINABILITY ? A COMPARISON BETWEEN DIFFERENT SCENARIOS OF ROMANIAN MUNICIPAL SOLID WASTE TREATMENT BEFORE LANDFILLING ? A STUDY ON ENERGY CONSUMPTION IN ROMANIA ? ENVIRONMENTAL INFLUENCES ON STRESSED METALLIC SURFACES ? ASPECTS OF HYDRODYNAMICS AND MASS TRANSFER IN DIFFUSED AERATION SYSTEMS ? THE STATUS OF SOME SELECTED HEAVY METALS IN ROADSIDE SOILS OF BURSA PROVINCE, TURKEY ? PREPARATION AND CHARACTERI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25656

? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS II. EVALUATION OF BIODISEL PRODUCTION FROM SOME CULTIVARS OF RAPES ? STUDY OF BIODIESEL PRODUCTION FROM OILSEED PLANTS I. EVALUATION OF THE GENETIC SIMILARITY OF SOME Brassica Napus CULTIVARS USING RAPD MARKERS ? STRUCTURAL CHARACTERIZATION AND IN VITRO CYTOTOXIC POTENTIAL OF COAL DUST IN A ROMANIAN POWER PLANT ? MUNICIPAL SOLID WASTE MANAGEMENT IN BENGHAZI (LIBYA): CURRENT PRACTICES AND CHALLENGES ? COMPARATIVE ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25661

? COMPACT MICROPULSE BACKSCATTER LIDAR: AIRBORNE AND GROUND-BASED APPLICATIONS ? STUDIES OF THE IMPACT OF AEROSOL OPTICAL PROPERTIES ON CLIMATE CHANGE PROCESSES ? A STUDY OF THE AEROSOL OPTICAL PROPERTIES AT TWO AERONET STATIONS FROM ROMANIA ? COMPLEMENTARY ATMOSPHERIC URBAN POLLUTION STUDIES IN THE NORTH-EAST REGION OF ROMANIA, IASI COUNTY ? ?NGSTR?M TURBIDITY IN THE LOWER LAYERS OF THE TROPOSPHERE ? LIDAR MONITORING OF ANTHROPOGENIC POLLUTION AND NATURAL PHENOMENA ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25665

Rhizobag incubation experiments were conducted to study microbial biomass carbon (MBC), microbial biomass nitrogen (MBN), soil respiration and enzyme activity (urease and phosphatase) in the rhizosphere soil of three different wetland plants and its influence on the removal of total organic carbon (TOC) and total nitrogen (TN). MBC, MBN, soil respiration and enzyme activity were higher in the rhizosphere than in the non-rhizosphere soil of the wetland plants. Microbial activity in the rhizospher...
Autori: Defu Xu, Hua Fang, Xianghua Xu, Xiaoli Zhao, Yingxue Lihttp://www.ecozone.ro/reviste.php?RID=25679

A multi-stage filtration system located next to Lushan River in Gaofeng Town of Chongqing, P.R. China was built to indicate the impact of loading rate on agricultural runoff purification performance. The experimental system was proved to be effective in the removal of agricultural non-point source pollutants, and it was adapted to the changes of influent quality and quantity. The average removal rate of chemical oxygen demand (COD), ammonia (NH4 +-N), total nitrogen (TN) and total phosphorus (TP...
Autori: Lei Huang, Xu Gao, Wei-dan Xie, Jun-hong Chen, Xiao-xia Ma, Ming-guo Chen, Jin-song Guohttp://www.ecozone.ro/reviste.php?RID=25682

Our investigation in 2007 revealed that the concentration of microcystin (MC-LR) in Miyun reservoir was 0.224 μg L-1, below the safety limit of surface drinking water in China (1.0 μg L-1). The phytoplankton community in Miyun reservoir was composed of 8 divisions and 84 species (including genera and varieties). The density of phytoplangkton was 393.71?—104 cells L-1 including 24.6% of Chlorophyta, 32.5% of Cyanophyta and 15.3% of Bacillariophyta. The toxin-producing cyanobacteria incl...
Autori: Huimin Li, Guisen Du, Yumei Wu, Dianwei Wu, Jingshi Wanghttp://www.ecozone.ro/reviste.php?RID=25691

For a better evaluation of the impact of road traffic about air quality, this paper considers the development of a new evaluation index system and methods. They address the assessment of the air quality around the areas with an intense road traffic, according to Chinese standards considering sulfur dioxide index (SO2), total suspended particles index (TSP), floating dust index (PM10), nitrogen oxides index (NOX) and carbon monoxide index (CO). A systematic air quality evaluation model was establ...
Autori: Zhao-hui Liu, Zhi-bin Qinhttp://www.ecozone.ro/reviste.php?RID=25714

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

Abstract:Incineration plants are used since the beginning of the twentieth century to transform the mixed municipal waste into thermalenergy and to convert the hazardous components of waste into harmless compounds. To minimize the environmental pollutionand maximize the energy efficiency of the produced energy, the control of the complex processes that occur into the waste toenergy conversion is of major importance. In this work, the system identification approach is used to determine the dynami...
Autori: Adrian Danila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25739

Abstract:Our research was focused on developing some new procedures to reduce the biodegradable wastes by composting. The aim of thisstudy was to obtain and asses at laboratory scale the maturity of three compost samples of different proportion of vegetable waste,beech sawdust and sewage sludge by analyzing their FT-IR spectra and C/N ratio. The composting process was monitored by testsperformed weekly on the three samples in order to investigate the physical parameters (pH and electroconductivi...
Autori: Anca Sauciuc, Claudia Zaha, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25772

Abstract:This study aimed to assess the coagulation performance using simple aluminum sulfate (Alum) and pre-hydrolyzed polyaluminumchloride (PACl) coagulation agents by conventional global parameters, i.e., turbidity and organic matter expressed by totalorganic carbon (TOC) and chemical oxygen demand (COD), and non-conventional spectrophotometric parameters.Non-conventional spectrophotometric parameters, expressed as absorbance recorded at different wavelengths, i.e., A254, A280,A365, allowed d...
Autori: Florica Manea, Georgeta Burtică, Ilie Pisoi, Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25777

Abstract:Based on the fuzzy logic principle, a modified Fuzzy Synthetic Evaluation (FSE) is proposed to assess water quality status ofWeihe River (Baoji, China). The potential application of the FSE has been tested in a case study. Twelve sampling locations ofWeihe River and its tributaries in Baoji area were selected and seven water quality parameters of BOD5, COD, fluoride, ammonia,total phosphorus (TP), total nitrogen (TN) and permanganate index, were monitored from 2008 to 2009. The findings...
Autori: Chundi Xu, Jun Zhang, Qi Zhou, Yani Geng, Yaqian Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25780

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:The present paper presents an enhanced Activated Sludge Model No. 1 in which nitrification and denitrification are modelled astwo-step processes. The nitrification process is considered as a sequence of two steps carried out by two distinct genera ofbacteria, with nitrite as an intermediate product. For the denitrification process a parallel approach was used that considers nitrateand nitrite to be directly reduced to molecular nitrogen. The new model is compared to the original Activat...
Autori: George Simion Ostace, Paul Şerban Agachi, Vasile Mircea Cristea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25786

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

Abstract:Experimental research evaluated the possibilities of air treatment efficiency of a cylindrically shaped bio-charge, namely straw, toremove volatile organic compounds from the air. As determined during experiments, the air treatment efficiency of the straw biochargefor acetone removal reached 97.3%, while for butanol removal the efficiency was 86.0%. It has been determined that, withvolatile organic compound concentrations increasing biological air treatment efficiency is decreasing as h...
Autori: Alvydas Zagorskis, Petras Vaitiekunas, Pranas Baltrenas, Raimondas Leopoldas Idzelis,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25790

Abstract:Recovery of residual ammonium nitrogen (NH4+-N) from dissolved air flotation (DAF) pretreated poultry slaughterhouse wastewater was studied by means of magnesium ammonium phosphate hexahydrate (MgNH4PO4.6H2O, MAP) precipitation in a lab-scale batch study. The maximum recovery values were obtained as 80.2%, 97.1% and 53.6% with the addition of MgCl2.6H2O + KH2PO4, NaH2PO4.2H2O + MgSO4.7H2O, and MgOHCO3 + 85% H3PO4 at pH 9.5, respectively. Based on the physicochemical findings, subsequent...
Autori: Aylin Gunay, Idil Ozis, Ilter Turkdogan-Aydinol, Kaan Yetilmezsoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25797

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

The corrosion products of high strength low-alloyed steel and of cast iron, maintained a prolonged period in natural seawater, were analyzed. A part of the corrosion products are soluble compounds of divalent and trivalent iron, the iron dissolution being accelerated when divalent ions are formed and in the case of the aerated seawater. The solid corrosion product formed during corrosion in seawater is principally oxy-hydroxide (FeOOH), but were identified small quantities of Fe2O3, Fe3O4 and so...
Autori: Daniel Mareci, Maria Lungu, Nicanor Cimpoeşu, Nicolae Aelenei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25832

This paper presents a study on the integration of two advanced treatment processes for the removal of priority organic processes from wastewaters: catalytic oxidation (Fenton homogenous process) followed by ultrafiltration. The aim of this study was to assess the removal efficiency for 4-chlorophenol (used as model pollutant), as well as the decrease in effluent toxicity in various processes conditions. The experiments have mainly focused on studying the effect of the oxidant dose of the catalyt...
Autori: , Cezar Catrinescu, Corina Petronela Musteret, Daniela Arsene, George Barjoveanu, Petru Apopei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25834

Polycyclic aromatic hydrocarbons (PAHs) are by-products of petrol transformation; a report prepared by ICON, London, United Kingdom in 2001, showed that the principal sources of polycyclic aromatic hydrocarbons in wastewater are domestic usage, storm runoff and commercial effluent. This work presents the results on 14 commonly occurring and/or highly carcinogenic PAH compounds listed as priority pollutants by the United States Environmental Protection Agency and the European Union. Wastewater sa...
Autori: Dumitru Ristoiu, Edward Muntean, Livia Alhafez, Nicoleta Muntean, Radu Mihaiescu, Tania Mihaiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25847

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The paper aims to present the environmental impact of pulp and paper manufacturing and the most important production and control practices to minimizing this impact. The environmental consequences of manufacturing pulp and paper from pulping and bleaching processes are discussed in qualitative and quantitative terms. In these processes, sulfur compounds and nitrogen oxides are emitted to the air, and chlorinated and organic compounds and nutrients are discharged to the wastewaters. Large quantit...
Autori: Adrian Catalin Puitel, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25857

This paper presents original studies about the influence of mineral and/or organic fertilization on the minerals contents (P, Na, K, Ca, Mg, Fe, Mn, Zn, Cu, Ni and Pb) in leguminous plants from permanent grassland situated in a hill area of Banat County. Determination of minerals in grassland is very important both for the nutritional or toxic effects of these elements and their compounds, in the plants, animals and environment. Phosphorous was analyzed colorimetric and all the others metals hav...
Autori: Alexandru Moisuc, Iosif Gergen, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25858

Marine species (n=36) available in a supermarket of Cluj-Napoca city, Romania were collected and analyzed for the levels of heavy metals (Cr, Cu, Zn, Cd, Pb, Hg) and As, polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and analogous, hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB). The collection included samples from twelve fish groups (sardine, tuna, herring, pangasius, marbled rockcod, hake, shrimp, pink shrimp, lo...
Autori: Adriana Gog, Claudiu Tanaselia, Ioan Ştefan Groza, Marin Senila, Mirela Miclean, Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25863

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

Herbicides industry is a large consumer of water, as well as a major wastewater generator, its effluents contain priority organic pollutants in very high concentrations which have severe effects on human health and on the environment due to their toxicity and bio-recalcitrant nature, persistence in the environment and bioaccumulation. A vast number of herbicides and other priority organic pollutants have been found in wastewater effluents, surface water, and drinking water around the world. The ...
Autori: Bianca Weinberg,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25874

Newly prepared SnO2-CeO2 catalyst samples used as depollution catalysts were characterized applying low-temperature nitrogen adsorption (BET), X-ray diffraction (XRD), thermo-gravimetry (TG-dTG) and temperature-programmed reduction (TPR) methods. Pure SnO2 has higher surface area (17 m2/g) than the pure CeO2 (8 m2/g). Addition of organic tin oxide precursor to ceria in amount of 5 wt% slightly decreases the surface area of CeO2 (SSn5-Ce= 7 m2/g). The increase of tin oxide content to 10 and 20 wt...
Autori: , Anca Vasile, , Cristian Hornoiu, Jozsef Kovacs, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25875

The herbicide use can be seen as an auxiliary path for new farming methods, providing more advantageous farming and land use capabilities and increasing crop yields. Some of them are quickly degraded but others persist in the environmental compartments being toxic for human health and the environment.The aim of this study was to evaluate the impact of some triazine herbicides from agricultural sources on quality of well and surface water, in two regions of Romania with different agricultural act...
Autori: Andreea Dragus, Mihail Simion Beldean-Galea, Radu Mihaiescu, Tania Mihaiescu, Dumitru Ristoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25889

The nitrogen and phosphorus management in agricultural systems leads to an increased input of plant nutrients and sustains the soil fertility. Microbes contribute through different mechanisms to nutrient cycles, transforming it available for plants. Isolation of 18 Azospirillum and 18 Azotobacter bacterial isolates was effectuated from the rizosphere and interior roots of the following plants: Carex fusca All., Carex rostrata Stokes., Eriogonum latifolium Sm., Carex elata All., and from Equisetu...
Autori: Csaba Dezso Andras, Eva Gyorgy, Eva Laslo, Gyongyver Mara, Rozalia Veronika Salamon, Sarolta Szentes, Szabolcs Lanyi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25894

According to the Romanian Law no. 265/2006, which adopted the Governmental Decision no. 195/2005 on environmental protection, environmental agencies are responsible for air quality monitoring in Romania. Since Romania is now an EU Member State, such a plan is a must to enhance life quality, in order to meet the objectives of the National Strategy for Sustainable Development. Having regarded to this Strategy and the Kyoto Protocol signed in 1997, this paper provides the results from a study of am...
Autori: Corina AnaMaria Ioan, Florin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25895

Five new aryloxyalkylcarboxylic acid derivatives (diazoaminoderivatives) are studied for their thermal behavior by applying a coupled TG-FTIR technique over the (30-400 oC) range in correlation with the environmental impact of gaseous species resulting by thermal degradation. These compounds are of a particular practical significance since they show a high biological potential as agrochemicals, such as pesticides (herbicides, acaricides, fungicides, growing stimulators etc.). This is why the pap...
Autori: Anca Mihaela Mocanu, Carmen Zaharia, Constantin Iordache, Constantin Luca, Lucia Odochian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25899

Abstract Effects of the aeration rate on nutrient removal from synthetic domestic wastewater using an intermittently aerated sequencing batch reactor (IASBR) were studied at ambient temperature. Two aeration rates, 0.8 and 1 L air/min, were studied. At the aeration-rate of 0.8 L air/min, removals of COD, NH4+-N, total nitrogen (TN) and PO43--P were 84%, 96%, 75% and 99%, respectively. At the aeration rate of 1 L air/min, removals of COD, NH4+-N, TN and PO43--P were 90%, 99%, 70% and 66%, re...
Autori: Liam G. Henry, Liwen Xiao, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25941

Abstract An activated sludge from SBBR (sequencing biofilm batch reactor) reactor filled with Fe0  as filler had been acclimated to Fe(III)rich environment aiming at secure an enrichment culture of iron-reducing bacteria. The dissimilatory Fe(III) reduction ability and its efficiency on the effect of nitrogen and phosphorous removal by dosing different Fe(III) under anaerobic condition were investigated. The mechanism was also proposed based on the results derived from the experiment a...
Autori: Jie Li, Juanjuan Feng, Siyuan Zhai, Ya’e Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25943

AbstractIn this study, a novel excess activated sludge (EAS) based nitrification and denitrification process was developed using EAS toprovide nitrifiers and denitrifers for nitrogen removal from the reject water of a municipal wastewater treatment plant (MWWTP).This can achieve a significant reduction in the nitrogen (N) loading in wastewater treatment plants. The results show that theammoniacal-nitrogen (NH4+-N) and total nitrogen (TN) removal efficiencies were in the range from 74.7% to 93.1%...
Autori: Wei Li, Xiaoxia Yang, Xinchao Guo, Yongzhe Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25946

AbstractPartial nitrification for the biological nitrogen removal (BNR) via nitrite has recently gained interest for treating high-strengthammonium wastewater with low organic matter content. However, stability of partial nitrification is still a challenge in activatedsludge system. In the present study, the technique of aerobic granulation was developed to produce granules for stable nitritation,treating ammonia-rich inorganic influent with 400 mg NH4+-N/L. The morphology, physical properties, ...
Autori: An-Jie Li, Xiang-Chun Quan, Xiao-Yan Li, Zhi-Feng Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25947

AbstractVegetable waste was used as the fuel of a two-chamber microbial fuel cell (MFC) for simultaneous power recovery and wastedegradation. Effects of ultrasonic pretreatment, organic loadings, anolyte pH adjustment on the MFC performance wereinvestigated. Results showed that higher power generation and organic compounds removal efficiency were achieved in theMFCs with the vegetable waste pretreated with ultrasonication at >1.0W/mL compared to the un-pretreated control. A maximumvoltage of ...
Autori: Kun Tao, Xiangchun Quan, Yanping Quan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25953

AbstractEstrogens and anti-inflammatories can pose adverse effects on human health and wildlife. This paper investigated four estrogens(estrone, E1; 17β-estradiol, E2; estriol, E3; 17α-ethynylestradiol, EE2) and three anti-inflammatories (ibuprofen, ketoprofen andnaproxen) by solid-phase extraction (SPE) and liquid chromatography tandem mass spectrometry (LC-MS/MS) in BaiyangdianLake during the dry (April) and wet seasons (September). These compounds were mostly detected at low levels ...
Autori: Jianghong Shi, Jinling Cao, Ting Bo, Xiaowei Liu, Yingxia Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25955

Geochemical cycling of reduced inorganic sulfur in sediments may affect water quality. This study investigated the reducedinorganic sulfur distribution and environmental behaviour in superficial sediments in different watersheds and coastal zones inBohai Bay, China. Acid volatile sulfur (AVS), chromium (II)-reducible sulfur (CRS) and elemental sulfur (ES) distributed insurface sediment were quantified. Total organic carbon and total nitrogen were presented in higher concentrations in the fluvial...
Autori: Robert Mortimer, Simon Bottrell, Wenjing Shi, Yanqing Sheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25959

AbstractA rapid increase of wastewater treatment plants (WWTPs) has made the disposal of excess sludge from WWTPs a seriousproblem. In order to enhance the management of sludge, both development of sludge reduction technologies and sludgeevaluation system are of great importance. Based on the survey data from 696 plants in China in 2009, an empirical model wasdeveloped to simulate the production and discharge of excess sludge, which considered influent, temperature, Chemical OxygenDemand (COD), ...
Autori: Chengwen Wang, Tao Xie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25963

AbstractBy investigating the basic physicochemical characteristics, nutrients (nitrogen, phosphorus and potassium) and heavy metalconcentrations of the excess sludges from four wastewater treatment plant (WWTP) in Xi’an city, the feasibility of applyingsewage sludge to landscaping in Xi'an was studied. The results showed that the basic physicochemical properties of sewagesludge satisfy the requirement of most plants growth. The sewage sludges are rich of organisms, nitrogen and phosphorus, butre...
Autori: Bohan Yin, Qin Zheng, Rixia Zhang, Sheping Wang, Xinan Liu, Zhengliang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25964

AbstractIn this paper we describe a wireless system, including smart sensing nodes for indoor air quality and unobtrusive cardiorespiratorymonitoring. The sensing nodes include a set of solid state gas sensors, sensors for temperature and relative humidity, amicrowave Doppler radar sensor for cardio-respiratory function, and appropriate conditioning circuits expressed by active filtersand amplifiers. The analog signals provided by the signal conditioning circuits is applied to a data acquisition...
Autori: Gabriela Postolache, Octavian Postolache, Pedro Silva Girăo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26007

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractIn the last years many papers have reported about the occurrence of the pharmaceuticals in the surface waters and theirundesirable effects upon the aquatic life. Most of pharmaceuticals pass through the wastewater treatment plants unchangedbecause they are biorefractory compounds and as a result they enter the water bodies. Therefore, it is necessary to improve thebiodegradability of pharmaceuticals effluents (PhEs) before their discharge in the sewerage systems. The aim of this paper wa...
Autori: Carmen Lazău, Florica Manea, Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26021

AbstractIn spite of the fact that concern on water quality protection raised in the last decades heavy metals pollution still represents agreat threat for both human health and environment quality. Ion exchange proved to be an effective technique for industrialwastewaters treatment, as long as it ensures an effective recovery of valuable compounds. The main purpose of this work is toassess the performances of a commercial ion resin sort (a strong basic anionic resin – VIONIT AT 21), to remove ch...
Autori: Alexandra Raluca Miron, Cristina Costache, Cristina Modrogan, Dumitru Giani Apostol, Oanamari Daniela Butucea, Redha Kouachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26025

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractLake Taihu is a shallow, wind-driven lake where eutrophication is always a serious problem. The study presented hereininvestigates the effect of wind on the eutophication of the lake, by using a two-dimensional (2D) hydrodynamic model coupledwith a 2D water quality model. The 2D water quality model looks in particular at the water quality situation of Lake Taihu in theyear 2008 and predicts future changes in the algae bloom situation. The Delft3D modelling tool was used to build thehydro...
Autori: Arthur Mynett, Chao Yue, Ioana Popescu, Leo Postma, Quan Pan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26037

AbstractWater quality is an inportant concern for the ecosystem state from a particular region. Since the continuous urban and economicdevelopment induces a negative impact on entire hydrological cycle, this study investigates the water quality of a Romanian lake,located in the Surduc area - Timis County. This perimeter has undergone significant economic development in the past twodecades due to increased tourism potential and the number of holiday residences.We proposed hybrid materias for the ...
Autori: Adina-Elena Segneanu, Cornelia Bandas, Florentina Cziple, Ioan Grozescu, Paula Sfîrloagă, Titus Slavici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26040

AbstractThe paper presents the application of cross-spectrum analysis (CSA) to air pollution and meteorological time series collected fromseven air quality monitoring stations located in three urban agglomerations of Romania, affected by industrial and trafficpollution: Braşov, Ploieşti and Târgovişte. Data have been collected from November 2011 till March 2012, at one hour samplingrate. The purpose of the analysis was to reveal the correlations between two series at different fre...
Autori: Ştefania Iordache, Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26057

AbstractBasic principles for assessing phytotoxicity are the same whether the test compound is a heavy metal, herbicide, fungicide,insecticide or other toxic compounds. The difference lies not in the method of evaluation, but in the experimental program andworking methodology.In this paper the phytotoxic effects of heavy metals, Cr (VI) and Cd (II) on plants germination and growth were studied. Stocksolutions of the two heavy metals were prepared at a concentration of 1000 mg/L, in distilled wat...
Autori: Dana Luminiţa Sobariu, , Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26062

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract This study describes a reversed-phase high-performance liquid chromatography (RP-HPLC) method for the analysis of several carbonyl compounds in air samples. The air samples were collected using a passive sampling method and cartridges based on florisil impregnated with 2,4-dinitrophenylhydrazine (2,4-DNPH). After derivatization the carbonyl compounds were analyzed by liquid chromatography technique coupled with UV detection. The developed RP-HPLC method was used to analyze...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26104

Abstract The aim of this paper is to analyze how local and atmospheric conditions influence pollutants’ distribution. Two different sites in Romania were chosen for measurement campaigns: Surlari (44° 34', 26° 19') located into a forest and near a lake, and a suburban area, Magurele (44° 21', 26° 2'), where the anthropogenic activities dominate. The same equipments for measurements of surface ozone, CO, NO2, NO and PM10 were used at the two sites. The measurements were performed in...
Autori: Sabina Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26126

Abstract Using sludge with dangerous substances content as an agricultural fertilizer can provide risks for humans and all environmental components. An important risk factor that had to be taken into account is the combination of sludge used as a fertilizer and agriculture activities that has its own consequences. In this paper, a risk evaluation for sludge disposal was elaborated. The most important risk factors in the studied case, wastewater sludge used as an agricultural fer...
Autori: Elena Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26141

Abstract Pesticides can be considered useful to eliminate pests, but can also induce negative effects to the processes of germination, growth and development of plants or disrupt some physiological and metabolic processes. By studying the effect of pesticides on treated seeds germination, and determination of growth indices, it was possible to evaluate the positive or negative influence or toxicity of the chemical compounds. The aim of this research is to highlight the effects of d...
Autori: Daniela Nicuţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26142

AbstractTo understand the typical organic pollutant contamination status of the main source water in Yellow River basin, samples werecollected from fifty source water points (including reservoir and river) in Yellow River basin. The samples were analyzed for therepresentative organic pollutants, including benzene homologous, chlorobenzene compounds, organophosphorous pesticides, and nitrobenzene compounds, total of 17 compounds. It was observed that all concentrations of the 17 compounds in the ...
Autori: Jijun Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26155

AbstractTo explore the water quality and biodiversity of surface microlayer (SML) in fresh waters, we investigated the water status ofSML and subsurface water (SSW) of three fresh waters in China during April to August of 2010, by chemical and biologicalmonitoring methods. The results showed that the indexes such as total nitrogen (TN), total phosphorus (TP), chemical oxygendemand (COD) exceeded the national III or IV level of surface water quality, and the contents of indexes of SML were muchhi...
Autori: Jiang Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26158

AbstractA novel parallel A2O-MBR system was developed in this study based on the theory of denitrification with phosphorus removal.By utilizing the denitrifying phosphorus accumulating bacteria (DPB), the carbon source in the influent could meet the needs ofboth the denitrification and dephosphorization processes. Therefore, the carbon source restriction in conventional A2O processeswas resolved. The proposed system was inoculated with the sludge collected from the secondary settling tank in a m...
Autori: Liang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26170

AbstractLow water quality due to high levels of ammonia, chemical oxygen demand (COD), abnormal pH, and undesirable water color isprevalent in many prawn ponds in Malaysia. A composite medium used in the treatment of prawn pond effluent was examinedfor the reduction of undesirable parameters. The composite medium is a mixture of limestone, activated carbon, zeolite, and ricehusk. Experiments were conducted under three different conditions, i.e., sole aeration, adsorption, and adsorption with pre...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26219

AbstractRiparian buffers play an important role in improving water quality, providing wildlife habitat, and reducing suspended sedimentsand pollutants entering the water body. The efficiency of pollutant reduction by a riparian buffer is greatly influenced by thewidth of the riparian buffer. In this study, the Soil and Water Assessment Tool (SWAT) model was applied to the YudeungStream watershed, Daejeon Stream watershed, and Gap Stream watershed to determine the most effective width of the ripa...
Autori: Jongpil Moon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26223

AbstractIn 1979, the Gheshlagh river continuum was affected by the construction of Gheshlagh dam. More than three decades afterpresence and operation of this dam, there is a necessity to evaluate water quality in Gheshlagh reservoir. Therefore, water quality data was determined monthly from October 2008 to September 2009, to evaluate the impact of Gheshlagh dam presence and operation on the reservoir’s water quality. Eight parameters were analyzed (dissolved oxygen, biological oxygen demand,chem...
Autori: Fariba Rezaei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26225

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe vortex flame concept of combustion has been well known to produce low levels of NOx. This feature qualifies it to be usedin industrial processes and in power generation to comply with the environmental regulations concerning nitrogen oxideemissions. An asymmetric vortex flame combustor has been recently proposed by the authors. The present article reports thelevels of NOx emissions of such combustor for the first time. An experimental platform designed and developed to examine theNOx...
Autori: Khalid M. Saqr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26245

AbstractConcerns for the river environment in Malaysia were highlighted. There had been occurrences of inadequate supply of water incertain cities and unexpected floods over the last few years. This paper discusses the results and efforts to clean the Gombak Riverwhich passes through several industrial areas and the City of Kuala Lumpur and the Penchala River which has an extra burden ofpassing through a highly densely populated Kuala Lumpur satellite city. Both rivers were considered polluted w...
Autori: Zubaidah Ismail
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26257

AbstractThe inactivation of Escherichia coli was investigated with two types of underwater electrical discharge systems such as pulsedelectrical discharge (PED) and dielectric barrier discharge (DBD). The DBD system consisted of a quartz tube and a coaxialdischarging electrode, which was submerged in biologically contaminated water. In the underwater PED system, the electricaldischarge starting from the tip of submerged tubular discharging electrode propagated downward and the direction of worki...
Autori: Sang Don Kim
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26263

AbstractThe applications of biofilm treatment technologies for domestic wastewater are being increased in many parts of the world. Theaim of the study is to assess a compacted aerobic attached growth fix-film unit (termed Bio-cache) for treatment of small volumedomestic wastewater. The system consists of the miniature plastic packing matrix, which provides a large surface area of 300m2/m3, so as to maintain the high rate growth of viable organisms responsible for organic degradation. The study o...
Autori: Alireza Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26266

AbstractThis paper presents the full-scale treatment of nylon production wastewater in a wastewater treatment plant in Henan province, Central China. In this case, a 9600 m3/d capacity wastewater treatment plant was installed to treat the wastewater generated from the production of nylon-66 salt, based on the biological anaerobic filter (BAnF) combined with an anoxic/oxic (A/O) process. The performance of the biological combined system was monitored over a 75-day period. The results revealed tha...
Autori: Chunlian Xu, Haiming Huang, Jiankun Dai, Jianrong Qi, Qianwu Song, Shaowei Wu, Wenjun Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26276

AbstractIn the present paper, support vector machines (SVMs) are used to develop a quantitative structure-activity relationships (QSAR) model for the reaction rate constants (-logkNO3) of 115 heterogeneous organic compounds, through reaction with nitrate radicals (NO3•) in the troposphere. Two quantum chemical descriptors used as the inputs for the SVM model were calculated with density functional theory (DFT), at the B3LYP level of theory with 6-31G(d) basis set. The best predictions were obtai...
Autori: Bing Yi, Jiyong Deng, Xinliang Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26284

AbstractSecondary aluminium production inherently generates significant amounts of slag of variate composition and including dangerous compounds. Consequently, a care treatment of the resulted slag is imperatively necessary for preventing the environment pollution and for recovering valuable materials even if present in low amounts. The aluminium recovering procedure is based on a chemical and hydrometallurgical slag treatment, leading to the technical grade aluminium sulphate (AS), possible to ...
Autori: Carmen Tociu, Cristina Maria, Elena Diacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26295

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractThe aim of this paper was to study the performance of a single-stage rotating biological contactor with supplemental aeration interms of removal efficiency of organic and nitrogen content. Research was based on fifteen samples collected during the fouryear period. The wastewater was low strength with maximal measured concentration of 362 mg COD/l, 100 mg NH4/l, and 324mg TSS/L. The maximal measured removal efficiency of COD (chemical oxygen demand) and TSS (total suspend solids) were71% ...
Autori: Dragan Cvetkovic, Dusan Gordic, Milorad Bojić, Srdjan Stosic, Vanja Susterstic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26322

AbstractA septic tank is an essential part of the decentralized wastewater management system. The aim of the experiment described inthis paper was to evaluate the impact of the method of sampling and hydraulic retention time (HRT) on the performance of acircular three chamber septic tank and to design a septic tank for a single household with four residents and wastewater flowrateof 0.6 m3/d. It was found out that the difference between suspended solids (SS) and chemical oxygen demand (COD) remo...
Autori: Ala Kirjanova, Mindaugas Rimeika, Regimantas Dauknys
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26329

AbstractIn this work, the effect of the addition of some nutrients on fungal growth and removal of Cr(III) were investigated. Theconsidered fungi, isolated from real tanning factory environment were Phanerochaete chrysosporium, Aspergillus niger and A.oryzae. Firstly, the optimal conditions for fungal growth were determined as a function of pH, contact time, temperature andagitation speed. Secondly, the effect of the addition of some nutrients on fungal growth was examined. Without the addition ...
Autori: Abdeltif Amrane, Mansur Zarrabi, Mohammad Noori Sepehr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26337

AbstractThe discharge of industrial effluents is a growing concern for companies, policy makers and the sanitary water system due to thepossible damage to environment. In Spain, wastewater discharge made into the sewer network is regulated locally by the SanitaryTax (ST). Consequently, for the latter, regulation and cost differences exist. In this paper, the role of Spanish STs to promoteenvironmental protection through the treatment of industrial wastewater (IWW) is analyzed. The study is focus...
Autori: Irene Carra, Isabel María Román Sánchez, José Antonio Sánchez Pérez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26350

AbstractThe survival of Formosan landlocked salmon has been threatened by the change of habitat ambience. Because of the potentialtoxicity of nitrite (NO2-) and ammonium (NH4+) to salmonid fisheries, we studied the evolution of nitrogen compounddistributions in stream water and their relationship with ambient abiotic factors. The water was sampled at five sites surroundedwith various land-use types in bi-monthly intervals for seven years. The results indicated that a high NO2- concentration occu...
Autori: Wen-Hui Kuan, Yi-Lang Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26351

AbstractA pilot scale Upflow Anaerobic Filter (UAF) treating tannery wastewaters was operated for 160 days. The UAF was fed with lowCOD/SO42- ratio (SO42- = 1810 mg L-1, CODtotal = 2530 mg L-1) for the investigation of sulphate and COD removal as a functionof substrates limitation and ammonia and sulphide inhibition. Sulphate-reducing bacteria (SRB) out-competed methanogenicbacteria due to the low influent COD/SO42- ratio, the high concentration of sulphide and the presence of inhibiting compoun...
Autori: Alberto Mannucci, Claudio Lubello, Giulio Munz, Gualtiero Mori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26353

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractThe effects of natural (soil properties) and technogenic factors (atmospheric pollution by harmful industrial discharges, soilcontamination) on accumulation of heavy metals in natural grasslands have been studied at monitoring plots located within theinfluence zone of Novocherkassk power station. Contamination of grass plants by Ni, Cd, Zn and Pb occurs at plots located nearthis station along the line of wind rose. They are contaminated with Pb and Cd through vehicular emission as well. ...
Autori: Galina Motuzova, Saglara Mandzhieva, Sergey Kolesnikov, Svetlana Sushkova, Tatiana Bauer, Tatiana Minkina, Victor Chapligin, Yuriy Fedorov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26384

AbstractThe study aimed the diversification of fodder yeast assortments with viable economic effects while reducing the environmentpollution by capitalization of wastewaters with high monosaccharides content from pulp and paper industry and residual wheyfrom milk industry. Using the Response Surface Methodology the fabrication recipe has been optimized according to anexperimental program based on a mathematical model with biomass, protein and residual sugar as response functions. Theculture medi...
Autori: Livia Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26429

AbstractThe aim of our investigations was to assess the potential ecotoxicological effects induced by complex chemical mixtures ofanaerobically digested sewage sludge. The sensitivity of monocotyledonae cereal (Triticum aestivum L.) test plant to varioussanitization treatments of anaerobic stabilized sewage sludge was evaluated. Several biometrical and biochemical responseindicators were selected as endpoint in this ecotoxicological tests. Thus, the ecotoxicity of sewage sludge was evaluated thr...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26437

AbstractAmong foods that possess potent medicinal properties, Cucurbitaceae seeds stand as a promising source, since they are assumedto have a protective effect against oxidative stress. In order to analyze the antioxidant compounds of the seeds of Citrulluslanatus, Lagenaria siceraria, Telfaria occidentalis, Cucurbita maxima, Cucumis sativus, Cucumeropsis mannii, and Cucurbitamoschata, the dried seeds were extracted in MeOH-H2O (50 %; v/v) mixture at constant mixing rate. Qualitative phytochemi...
Autori: Aristide Guillaume Silapeux Kamda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26440

AbstractThe sludge treatment processes represent a priority when we refer to the municipal wastewater treatment, but can implicate verycomplex studies and applications if we consider the industrial wastewater recovery and treatment processes. Even if the industrialsludges are seen as wastes, they can represent an important resource if are properly managed in the storage, treatment andrecovery processes. This paper aims to identify some methods to optimize the coagulation and flocculation process...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26444

AbstractCarbon monoxide (CO) is a gas obtained both from natural sources (bush fires, volcanic emissions and electric discharges) andby anthropogenic processes (incomplete combustion of fossil fuels). Together with particulate matter, nitrogen oxides andhydrocarbons, it is part of the air pollutants associated with the transport sector, which have a negative impact on human health,animals and vegetation. In this paper the authors propose a methodology for assessing CO emissions from road traffic...
Autori: Gabriela Mitran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26466

AbstractThe electrochemical properties of two fluorinated substrates, namely 1H-3-methyl-4-ethoxycarbonyl-5-(4-fluorobenzylidenehydrazino)-pyrazole (Ia) and 1H-3-methyl-4-ethoxycarbonyl-5-(2-fluoro-benzylidenehydrazino)-pyrazole (Ib)respectively have been investigated in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborateon a platinum electrode. The voltammetric investigation of the above compounds in the mentioned RTIL shows mainly twoirreversible anodic peaks...
Autori: Liviu-Virgil Costea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26471

AbstractIn this study, the reduction of phenolic compounds and other organic pollutants from greenish black (GB) and dark brown (DB)olive mill wastewater (OMW) was investigated. Ultrasonic irradiation in combination with aerobic biodegradation was adoptedas the treatment technique. Operational parameters such as the duration of ultrasonic irradiation, ultrasonic power intensity andultrasonic frequency were tested to determine their effects on phenol, BOD, and COD degradations. It was found that ...
Autori: Zakaria Al-Qodah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26484

AbstractThe paper presents a hybrid method for the advanced removal of low biodegradable organic compounds from water, bycombining the separation selectivity of the membrane with the oxidation efficiency of the photocatalytic process. The aim of thisstudy is to evaluate the performance of the hybrid method to remove toxic compounds from wastewater. The advanced oxidationprocess, based on a photocatalytic reactor with continuous recirculation, ultraviolet (UV) radiations and a membrane, was usedf...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26490

AbstractIn this study, boron-doped diamond (BDD) electrode was tested in electrochemical oxidation and reduction processes using thesame vertical electrodes undivided cell in order to remove natural organic matter (NOM) and nitrogen compounds (NC) fromdrinking water. Boron-doped diamond-based electrochemical oxidation process has proven to be an efficient and versatilemethod suitable for NOM and NC in forms of nitrite and ammonium present in drinking water sources. However, the applicationof BDD...
Autori: Florica Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26492

AbstractEnhanced nitrogen inputs to both terrestrial and aquatic ecosystems affects biodiversity at all its levels. Grasslands provide acomplex range of functions, due to their wide representation throughout terrestrial ecosystems. Numerous studies demonstratesoil acidification, eutrophication and species richness reduction as a result of elevated reactive nitrogen availability. The presentstudy aims to assess soil nitrogen stocks and transformations for two Romanian grasslands during November 2...
Autori: Carmen Postolache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26497

AbstractAs air quality becomes increasingly deteriorated in world-wide cities, air quality monitoring has extended beyond the criteriapollutants (CO, SO2, NOx, O3 and PM) in order to include several toxic air pollutants such as volatile organic compounds(VOCs). In the present study it was investigated the presence of 29 VOCs and PM including PM2.5, PM2.5-10 and PM>10 fractions,in an urban area from Romania. The total VOCs was higher in the urban area (176.72 - 192.54 μg/m3) than in the r...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26504

AbstractAnalysis and monitoring of arsenic is still a challenging analytical task. Due to its complex behaviour (different forms of arsenicthat can be present depending on pH and oxidation states of arsenic) as well as demanding analytical procedures and instrumentaltools for control of arsenic concentration in drinking water which is set to 10 μg L–1, there are still some open questions andissues when arsenic is the scientific topic. In this paper the idea was to use a multivariate statist...
Autori: Vladana N. Rajakovic-Ognjanovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26506

AbstractVegetables are an important part of a healthy diet because of their nutritional value. Contamination in vegetable may provehazardous for population. Polycyclic aromatic hydrocarbons (PAHs) are compounds widespread in the environment, many ofthem showing carcinogenic effects. These compounds can reach the food chain by different ways and, therefore, the analysis ofPAHs in food is a matter of concern.The present work provides data regarding levels of PAHs: acenaphthene (Ace), acenaphthylen...
Autori: Alina Soceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26510

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractAnaerobic degradation (AD) of municipal solid waste (MSW) depends on the moisture and nutrient distribution within thebioreactor; these factors are affected by leachate recirculation. In this work, the effects of leachate recirculation of 15 to 120 byvolume percentage (%V) on AD were studied. The ojectives of this study are as follows: a) to determine which recirculation rateprovides the best conditions for accelerated anaerobic degradation (AD) and b) to determine the optimal range of r...
Autori: Maria del Consuelo Hernández-Berriel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26557

AbstractWe reported the results of an isotopic study aimed at evaluating the medium to long-term effects of different water qualities anddeficit irrigation strategies on the ecophysiology of grapefruit in a 7-year-old plantation in SE Spain. For a better understandingof the interaction between nitrogen and salts from reclaimed water, RW, an experiment using natural abundance (δ) of 15N wasconducted. This study showed that in grapefruit crop irrigated with RW leaf δ15N value increased. ...
Autori: Cristina Romero-Trigueros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26573

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

Abstract Wildfire emissions are a major contributor of atmospheric gaseous and particulate pollutants for local air pollution levels. With respect to wildfires, Turkey faces one of Europe’s most severe problems during summer. In this study, a database which holds data for wildfire emissions in Turkey for the last decade (between 2000 and 2009) was established in order to create a wildfire emissions inventory. The emissions of carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), n...
Autori: Faruk Dincer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26584

Abstract The biological removal of organic matter from a cosmetic wastewater by sequencing batch reactors has been optimized by analyzing the influence of the hydraulic retention time as well as the inclusion of anoxic and/or aerobic stages in the process sequence. Hydraulic retention time of 5 d led to the highest total organic carbon and chemical oxygen demand removal regardless the sequence used. Although a completely aerobic sequence can be used for cosmetic wastewaters treatment, the al...
Autori: Montserrat Tobajas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26589

Abstract Some of the major stressors of air quality in the urban areas are nitrogen oxides, ozone and suspended particles. The effect of air pollution on respiratory diseases can increase considerably at high levels of pollution and might trigger asthma symptoms. Longterm exposure can increase the rate of respiratory infections and symptoms at population level, but particularly in children. The goal was to analyze with statistical techniques the pollutant concentrations (NO, NO2, and SO2) re...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26605

Abstract Samples were collected for six months (nine storm events) to observe the contaminant loads from three highway segments at Rawalpindi, Pakistan. The contaminants analyzed include total suspended solids (TSS), total dissolved solids (TDS), total nitrogen (TN), chemical oxygen demand (COD), total organic carbon (TOC), total phosphorous (TP), sulphate (SO4), chloride (Cl-), iron (Fe), copper (Cu), zinc (Zn), lead (Pb), and chromium (Cr). Mass vs. volume [M (V)] curves were drawn to inve...
Autori: Hamid Iqbal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26617

Abstract The effects of nitrogen (N) and phosphorus (P) addition to peatland ecosystem on emissions of nitrous oxide (N2O) were measured using the closed chamber method during one growing season within a peatland on the Tibetan Plateau. The highest N2O fluxes occurred during late spring (May), while fluxes of N2O were lowest during early autumn (September). No significant correlations were found between N2O emissions and soil temperature. Because of the sites stable hydrological conditions n...
Autori: Yongheng Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26626

Abstract The degradation of polycyclic aromatic hydrocarbons (PAHs) including fluorene, phenanthrene, anthracene, fluoranthene and pyrene were investigated under thermophilic and mesophilic anaerobic-methanogenic conditions. By using central composite design, the impact of PAH concentration and soil to inocula ratio were systematically studied for their influence on PAH removal and biogas production. During the first 30 days, PAH concentration decreased in all samples indicating that the ino...
Autori: Tahseen Sayara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26629

Abstract Dipyridine derivatives are used on large scale and pose significant environmental problems. We have synthesized dipyridine derivatives with: 5-chlorovaleric acid, α-dichlorhidrin, iodoacetamide and 11-bromoundecanoic acid. The synthesized substituted compounds were investigated by LC-MS. The adsorptive removal of dipyridine derivatives from aqueous solution has been studied using medicinal activated carbon. The adsorption rate has been investigated under the controlled process...
Autori: Ana Chira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26638

Abstract The interest in waterborne paints amelioration increased lately due to the toxicological effect of certain ingredients on human health, the restrictive environmental legislation and the depletion and escalation in price of raw materials. Research efforts in formulating waterborne paints are directed to insure low volatile organic compounds (VOCs) emission while maintaining and even improving their properties. This paper presents a waterborne paint formulation process. The required ...
Autori: Andrei Ionut Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26639

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract Established applications of emulsion liquid membranes (ELM) refer to refining in hydrocarbons and hydrometallurgical processing, rehabilitation of poisoned patients. In this work we investigated the separation of aromatic compounds of biological interest, more often encountered as intermediates in dyes and drugs industry: aniline, nitrobenzene, ortho and para-toluidine, using emulsion liquid membranes. The experimental results showed that in the case of basic substances separation t...
Autori: Alexandra Raluca Miron
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26650

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract Biochar derived from agricultural biomass waste is increasingly recognized as multifunctional material for various applications according its characteristics. It is therefore essential to investigate biochar properties before large-scale application. In this study, rice straw-derived biochars produced at different temperature (550, 650, 750 oC). The resulting biochars were subjected to liquidphase oxidation by different agents including KOH, HNO3, H2SO4, H2O2 and KMnO4 to obtain bio...
Autori: Sobhy M. Yakout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26661

Abstract The influence of exogenous form of heavy metals intake on their transformation in the soil is determined during model experiments. Distinctions in quantity of extracted mobile compounds of heavy metals in the soil depending on a form of addition various connections of Cu and Zn are established. The smallest mobility of Cu and Zn at addition of heavy metal oxides is observed. It is established that Cu accumulates mainly in the fraction connected with organic matter; Zn accumulates in...
Autori: Tatiana M. Minkina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26662

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract Drinking water treatment using activated carbon (AC) decontamination offers effective methods for removing some organic compounds, tastes and odors, but it is not so efficient for metals, nitrates, microbial contaminants and other organic and inorganic contaminants. In the last years, nanotechnologies introduced several types of nanomaterials for organic, inorganic and biological removal of contaminants in drinking water, such as: sorption, filtrations and catalytic processes. In th...
Autori: Elena Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26671

Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

Abstract Nowadays, an efficient wastewater management involves the use of advanced treatment technologies able to decompose hardly biodegradable compounds with reasonable costs at the lowest possible environmental impact. In our work we used one of the most efficient advanced wastewater treatment, the Fenton reaction and its photo-assisted version. The hydrogen peroxide was the oxidizer; despite its relatively high cost, its high activity in oxidizing of a large variety of organic persistent...
Autori: Vasilica-Ancuta Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26677

Abstract Supercritical fluid and ultrasound assisted extractions were applied as a first step in a complex processing of spruce bark in order to recover polyphenols compounds. The aim of the study was to compare the efficiency of these "green" processes with a conventional extraction technique (ethanolic extraction). Supercritical fluid extraction was carried out in two steps: (i) static extraction for 15 min at 1000 psi with pure CO2 and (ii) dynamic extraction for 45 min at 35, 4...
Autori: Adina Iulia Talmaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26680

Abstract The use of hydrogen in spark ignition engines as a supplementary fuel can enhance combustion and reduce toxic emissions. Difficulties in hydrogen storage and production limit its use in internal combustion engines. This paper investigates the performance of a spark ignition engine with the addition of a mixture of hydrogen (H2) and oxygen (O2) into the intake manifold. Hydrogen is produced by an alkaline electrolyser and consumed simultaneously to eliminate the need for a storage de...
Autori: Yasin Karagöz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26685

Abstract Anaerobic processes have been successfully applied in the treatment of municipal and industrial wastewaters. Judicious use of nutrients in anaerobic treatment has not been systematically investigated. The optimal nutrient dosage for anaerobic wastewater treatment systems is largely unknown. In this paper, COD:N:P ratio used by various researchers in anaerobic wastewater treatment systems for treating different types of wastewaters are compiled and critically analyzed. In order to ha...
Autori: Athar Hussain
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26697

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract This research evaluated two electrokinetic remediation systems (EKR) for separating phenanthrene from bentonite and its electrochemical destruction by using a Boron Doped Diamond (BDD) electrode. The effect of the electrochemical potential for the oxidation of phenanthrene in liquid phase with Ti/BDD was analyzed by Normal Pulse Voltammetry and Hydroxyl Radical (●OH) analysis using the Spin Trapping Technique. The results showed that 70% of phenanthrene was removed from benton...
Autori: Alejandro Medel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26710

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract In this study, the electrocoagulation process using aluminium anodes was tested as alternative for coagulation process for the drinking water treatment using two types of real groundwater sources, characterized by low turbidity, moderate and high organic load, and nitrite and ammonium species for one of them. The optimum operating conditions determined to be pH 6.5, current density (i) 25A/m2 at 30 min resulted in removal efficiency of over 70 % for total organic carbon (TOC) parame...
Autori: Anamaria Baciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26756

Abstract The intensive vegetable system means that more toxic organic and inorganic compounds are entering the environment. The aim of this study was to obtain the necessary answers on the content of organophosphorus pesticides (OPPs) regarding to quantify these residues on soils cultivated with vegetables in conventional, organic and conversion systems, and also determine which pesticide residues are going in edible vegetable parts. A number of 23 OPPs were analyzed from soil (50 samples) ...
Autori: Vasile Stoleru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26768

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract A VOC monitoring was carried out inside and outside a multi-storey car park in order to characterize the emission profile of vehicular traffic source in an indoor environment. BTEX, and in particular toluene, were the most abundant compounds in all monitored sites, with different compositions between indoor parking areas and outdoor sites. The motor vehicle exhaust and gasoline vapor emission in these enclosed parking garages were characterized by diffusion or degradation phenomena ...
Autori: Gianluigi de Gennaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26778

Abstract The preliminary results of aromatic hydrocarbon (AR) levels and PM2.5 physico-chemical characterization in Rome urban air throughout the 2014 are reported. A gas chromatograph was used for continuous measurements of AR concentrations with 30 minute time intervals. PM2.5 was collected by PM swam Dual Channel. Metal content was determined by ICP-MS. Single particle characterization was performed by Scanning Electron Microscopy equipped with a thin window system for X-ray microanalysis...
Autori: Carla Fanizza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26780

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract This study was aimed to stimulate laccase production by Trametes pubescens MUT 2400 by using a tomato-based medium. Two sequential 2x2 factorial designs were used to determine the effect of carbon (C) and nitrogen (N) source concentration on laccase activity and biomass concentration; copper was used as the sole inducer (0.75 mM). Analysis of the first factorial design showed that N had a strong positive effect on the maximum laccase activity, which occurred at day 12 of cultivation...
Autori: Federica Spina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26795

Abstract The aim of this study is to assess indoor air quality in an educational institute located in a suburban area of the Po plain (Italy). Samplings are carried out in preschool and elementary school classrooms, and also in the garden of the institute, to have information on outdoor levels. The monitoring is performed to determine the most important indoor pollutants (i.e. volatile organic compounds (VOCs), carbonyls and NO2), by using diffusive passive samplers. Sampling in the classroo...
Autori: Ivano Vassura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26797

Abstract The identification of the critical source of nonpoint source pollution (NPS) plays an important role in formulation of Best Management Practices (BMPs). SWAT (Soil and Water Assessment Tool) was adopted for NPS nitrogen pollution modeling for Qinhuangdao City. The model was calibrated and validated by Sequential Uncertainty Fitting Version 2 algorithm of SWATCUP (SWAT Calibration and Uncertainty Programs) software. The model was used to quantify contributions of different nitrogen ...
Autori: Jihong Qu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26810

Abstract Treatment experiments for mature landfill leachate were conducted by using combined aged refuse bioreactor (ARB) process and sulfate radical oxidation. In the ARB process, the effects of wet/dry ratios, hydraulic loading, and influent introduction time on contaminant removal were investigated. In the oxidation process, Na2S2O8 was activated by heat to generate powerful oxidants, such as sulfate radicals, to oxide residual contaminants in the effluent. The removal of chemical oxygen ...
Autori: Zhanmeng Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26818

Abstract Waste engine oil contains hydrocarbons which are potentially carcinogenic. The objective of this study was to determine if organic wastes, specifically cow dung (T1) and poultry manure (T2) can improve the microbial degradation of the hydrocarbons. A questionnaire survey to determine generation, management and disposal of waste engine oil was carried out. A Complete Randomized Design, with two treatments and three replications was used to set up plots at Makerere University Agricult...
Autori: Richard Elijah Ssonko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26820

Abstract The short-term effects of plant diversity (number of plant species and species compositions) on aboveground biomass, substrate inorganic nitrogen (N) concentrations, and substrate solution “effluent” N concentrations were studied in a subsurface verticalflow constructed wetland (CW). Results showed that (1) the number of plant species increased aboveground biomass (P< 0.05) but had no effect on the overyielding index DMax; (2) the species compositions and presence of ...
Autori: Hai Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26822

Abstract The aim of this paper is to assess the chemical and mineralogical composition and the leaching behavior of the electric arc furnace slags (EAFS) in order to improve their management by identifying suitable reuse options in different fields. The chemical and mineralogical composition of slag varies from one type of steel to another, from one technological stage to another and from one steel plant to another. In order to minimize the slag quantities disposed in the slag dumps one has ...
Autori: Dana-Adriana Iluţiu-Varvara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26835

Abstract This article presents the result of investigation on the spatial and temporal changes in water quality of Uluabat Lake. It examines the relationship between water and sediment quality parameters, and assesses the factors affecting eutrophication. Water and sediment quality are examined at 8 stations in the lake between May 2008, and May 2009. Water and sediment quality parameters measured are T, pH, EC, SD, NH4-N, NO3-N, TN, PO4-P, TP. Also DO, alkalinity, hardness, SS, BOD, COD, Ch...
Autori: Feza Karaer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26850

Abstract Air pollution is an increasing critical issue and the focus of innumerable studies and monitoring activities. In addition to automatic monitoring systems typically used to measure fine dust, ozone, nitrogen oxide and sulfur oxide, the use of bioaccumulation monitors can also be exploited, especially when monitoring large areas. The advantage of biomarkers is the very low costs involved compared to traditional monitoring systems. Bio-indicator techniques do not measure directly air q...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26892

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

This paper presents municipal solid waste (MSW) responsibility and management structure in Sinop, Turkey together with the current situation of collection, recycling, transport and disposal of MSW. In order to examine the MSW management, a longterm study was conducted between 1994 and 2010. In this study, physical composition of MSW was determined. Proximate analysis (moisture content, density and calorific value) and ultimate analysis (carbon, hydrogen, oxygen, nitrogen, sulfur and ash) of ...
Autori: Nurdan Gamze Turan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26925

As the serious effect of climate change and global warming is recognized, nitrous oxide (N2O) emission during wastewater treatment is receiving lots of attention due to its high potential to greenhouse effect. In this study, nitrifiers were acclimated in sequencing batch reactors with influent ammonium nitrogen (NH4-N) concentrations of 60 mg/L (SBR60) and 180 mg/L (SBR180), respectively. Nitrous oxide emission during nitrification was examined in both typical cycles and batch experiments. T...
Autori: Enge Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26926

In this work, coagulation features and characteristics of dissolved organic matter (DOM) in combined sewer overflow (CSO) wastewater were investigated. Ferric chloride (FeCl3) and polyaluminum chloride (PAC) were employed in the coagulation process. Results showed that both FeCl3 and PAC are effective in removing turbidity and total phosphorus (TP). Removal efficiencies were all above 90% when dosages were reasonable. Chemical oxygen demand (COD) removal efficiency was between 60% and 70%. T...
Autori: Wei-gang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26931

Moving bed biofilm reactor (MBBR) technique is a useful technology for the treatment of mature landfill leachate. The reactor start-up and acclimation processes illustrated that many factors, such as biomass, C/N ratio, and influent volumetric loading rates, could affect the ammonium-nitrogen (NH4+–N) and COD removal. The factorial experiments were carried out to determine the optimal reactor operational conditions, and the results demonstrated that when DO 2-4 mg/L, pH 7.5, and hydraul...
Autori: Wei Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26932

This study investigates the effects of earthworms and a variety of substrates on photosynthetic characteristics and rate of uptake of nitrogen (N) and phosphorus (P) by Iris pseudacorus L. (Iridaceae) in a constructed wetland system under greenhouse conditions. The study seeks to identify those factors that maximize the efficient removal of N and P. Four substrates were tested: pure sand, sand and soil, sand and organic matter, and a mixture of sand, soil and organic matter. The photosyntheti...
Autori: Defu Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26936

One way to improve the performance of non-thermal plasma (NTP) reactor for volatile organic compound decomposition is by the introduction of ferroelectric materials into the discharge zone of NTP. This paper is a review of the breakthroughs and the current status of the applications of this technology for the abatement of volatile organic compounds (VOCs). It covers the process of energy generation in NTP, VOCs decomposition processes and the effects of critical factors such as type of packed...
Autori: Abdullahi Mohammed Evuti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26948

Ranunculus rionii and Ceratophyllum demersum develop aquatic dense stands, which lately started to represent a major ecological concern for all the ponds and/or lakes in Romania. The potential relationships between the phytochemical compounds detected in these plant extracts (acids, phenols, heterocycles, alcohols, hydrocarbures) and the allelopathic properties against Gram positive and Gram negative bacterial strains and microalgal cultures were investigated and discussed in the current stud...
Autori: Mariana Lupoae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26971

The study aims to identify important challenges that the practitioners and researchers in wastewater collection systems are facing in order to reduce the emissions of hydrogen sulphide and greenhouse gas emissions. Based on literature review, it identifies the main technologies used for avoiding and removing odorous compounds from wastewater gas streams. The paper also highlights issues pertaining to the emission and biofiltration of hydrogen sulphide, methane and nitrous oxide from sewage co...
Autori: Iulia Carmen Ciobotici Terryn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26984

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

Air pollution has a significant impact on human health and natural ecosystems. The principal gaseous pollutants compounds result from different types of combustion processes. In this category there are included carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), dust and hydrocarbons. Nitrogen oxides are a group of highly reactive gases, which contain nitrogen and oxygen in varying amounts. Most of the nitrogen oxides are colorless and odorless gas. This paper highlights the c...
Autori: Doina Capşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26988

The renewable sources of energy represent a viable alternative for satisfying the energetic needs of humanity in case the fossil fuels reserves are exhausted, which is estimated to occur in maximum 25 years if the current rate of exploitation is maintained. Nowadays, there are several concerns about the valorization of the energetic potential of these resources (wind, water flows, solar, geothermal energy etc.), but also a series of extremely beneficial practical uses (i.e. wind parks, photov...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26989

Environmental threats posed in the environment by plastic production and plastic wastes continue to be a major problem today, closely connected with the increase of plastics consumption by the population. Moreover, little efforts are involved in some parts of the world associated to plastic waste collection, recycling and reuse. Considering all these prerequisites, the identification and discussion of risks generated by plastic production and waste in the environment are performed in this pap...
Autori: Elena - Diana Comăniță
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26990

Measurements were taken for Ozone (O3) and its precursors simultaneously from June to August 2008 in Beijing. We analyzed the spatial and temporal variability of O3 and its precursors and the roles of the precursors in O3 formation. The results suggest that O3 mixing ratios are higher in rural areas than in urban areas. Highest mixing ratios of VOCs were alkanes, followed by aromatics; alkenes and biogenics were present at lower mixing ratios. Because of their relatively high reactivities, ar...
Autori: Junlin An
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26994

The release of nitrogen compounds into the environment is a major concern worldwide. Different studies howed that recycled materials have a high removal capacity for pollutants. Bentonite and its major clay minerals, smectites clays are common bleaching agents used for oil refinery bleaching and known as bleaching earth (BE). In this study regeneration of spent bleaching earth (SBE) acquired from the vegetable oil industry was surveyed via different methods and the regenerated spent bleaching...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27000

Emission from the combustion processes can cause adverse effect to the environment. The formation of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), carbon dioxide (CO2) and oxides of sulphur (SOx) are hazardous and harmful to the ecosystem. Due to these pollutants and also depletion of fossil fuel, several steps should be taken in order to mitigate this problem. Biofuel is known as the potential replacement for fossil fuel. Envo Diesel is one form of biofuel that can be us...
Autori: Mohammad Nazri Mohd Ja’afar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27011

A biodegradable iron based alloy was obtained through classical melting method using a furnace with controlled atmosphere. The metallic material was obtained from high purity materials using a proper obtaining method. The material is proposed as an alternative to magnesium alloys that have a very fast degradation period for applications with longer healing periods (more than 3 and between 12 to 18 months). The material was analyzed using scanning electron microscopy (SEM) and X-ray dispersive...
Autori: Sergiu Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27023

The removal of toxic heavy metal ions such as lead and zinc from industrial and mining wastewaters has been widely studied because their existence in surface and underground water is responsible for several types of health problems caused to animals and human beings. Also, there are some organic compounds, which must be prevented from reaching in drinking water from various sources of pollution. For these reasons in this paper the experiments were conducted to study the ability of activated ...
Autori: Cristina Ileana Covaliu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27027

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

While the water quality issues in suburban watersheds have been greatly attributed to rapid urban development and stormwater runoff, pollution contribution from agricultural practices are still significant but often overlooked. The objective of this study is to assess water quality impacts of managing both agricultural and urban lands in a suburban watershed. Neshanic River watershed is a headwater watershed with mixed land uses located in Hunterdon County, New Jersey, USA. It has 40% of agr...
Autori: Zeyuan Qiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27081

Experimental research focus on the emission characteristics of a diesel engine employed a new combustion system-double swirl combustion system (DSCS) is carried out. The influence of spray angle on diesel emission characteristics with DSCS is analyzed by experimental and numerical method. Main emissions such as particulate matters (PM) and nitrogen oxidants (NOx) are measured in diesel engine with DSCS and the original engine. Also, fuel consumption, combustion pressure, heat release rate are...
Autori: Liwang Su
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27087

Researching and industrializing a new pharmaceutical form results in an impressive amount of waste due to the methods used. Despite numerous reports about the addition of pharmaceutical ingredients to the environment, the effect they have on the environment at the nanogram (ng) level remains largely unknown; thus, it has been proposed to retain toxic compounds using Dowex resins in biomucoadhesive tablets containing miconazole nitrate, an antifungal medication. This study demonstrates the re...
Autori: Magdalena Bîrsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27091

Freshwater marshes are the single largest source of atmospheric methane (CH4). Climate change and anthropogenic nitrogen (N) deposition can alter the production and oxidation of CH4 respectively and thereby also CH4 exchange. But there was little known about how N regulate key carbon (C) processes, like CH4 production and oxidation under freshwater marshland conditions. In this study, field-fertilization and incubation experiments were conducted to investigate the effects of four N-fertilizat...
Autori: Lihua Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27107

Intensive agriculture has become an indispensable practice because it has to meet the needs of increasingly large yields to feed the population of the planet. In recent years, tough challenges to increase the efficiency of bioconversion were performed, since the conventional system has negative impacts on the environment, especially on health products by low intake in nutrients. In this context, the aim of this study is to show the effects of fertilization measures, which improve the quality ...
Autori: Daniela Cristina Dimitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27110

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

Sequencing Batch Biofilter Granular Reactors (SBBGRs) represent an innovative technology; coupling granular and attached biomass and operating in a batch mode. These systems allow good removal rates with low sludge production and space requirement. A particular application, consisting of an aeration unit and an upflow SBBGR in series, has been tested at pilot scale. The pilot system was installed at a conventional activated sludge plant and fed with average-strength urban wastewater after pre...
Autori: Paolo Cirello
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27123

The selection of proper compounds to include in perfumes’ formulation is of particular interest for the perfume industry. Essential oils and perfumes are subject to quality control as well as to chemical characterization; therefore, GC/MS-O methodology can be considered a useful tool for research purposes and/or for improving industrial manufacturing processes. In this study, GC/MS-O methodology was applied to a commercial brand perfume and a natural-derived one, both characterized by ...
Autori: Antonella Amenduni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27125

In this study, the toxic effects of binary mixtures of Pharmaceutical Active Compounds (PhACs) that are observed in the effluents from a wide range sewage treatment plants and surface water bodies were investigated using the bioluminescent bacterium Aliivibrio fischeri (Microtox® test). The selected chemicals were the nonsteroidal anti-inflammatory drug (NSAID) diclofenac sodium [DCF] and the anti-epileptic carbamazepine [CBZ]. In addition, caffeine [CFF], a psychoactive stimulant of the...
Autori: Valeria Di Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27126

Rapeseed meal (RM) is an abundant and cheap by-product of oil extraction process. RM is a rich source of nitrogen, carbon, and minerals. Thanks to these features, RM has a striking potential for eco-friendly production of high value products in biotechnological processes. In this study, the possibility of using a low-cost medium based on the water soluble fraction of RM for laccase production by the fungus Pleurotus ostreatus has been evaluated and compared with the use of synthetic complex ...
Autori: Lucia Guarino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27129

The production process of wine and distilled generates several by-products (20-30% of total production). Currently, most of the solid by-products (pomace, stalks, lees and seeds) obtained as downstream of the vinery industry, are conferred to the distillery or, less frequently, used in agriculture and for energy production. As a consequence, much of the antioxidant compounds contained in the grape is unused in the products of processing and is lost. These substances (among which the most impo...
Autori: Paola Zitella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27135

An electrochemical oxidation system using Titanium-based material as anode was setup and used to remove ammonium nitrogen (NH4-N) from swine wastewater. The effects of electrode material, current density, pH, and chlorine ion concentration were evaluated by removal rate of NH4-N and energy consume. The results showed that the NH4-N removal rate reached 98.5% using Ti/Mn-Ni/SnO2-Sb-CeO2 material as anode under the conditions: detention time of 60 minutes, pH of 8-10, current density of 20 mA/...
Autori: Xuewen Yi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27146

A submerged membrane bioreactor (MBR) was applied to treat digested piggery wastewater (DPW). The removal of chemical oxygen demand (COD), ammonium-nitrogen (NH4-N), two kinds of heavy metals and ten kinds of antibiotics were studied. The hydraulic retention time (HRT) was gradually shortened from 12 days to 2.7 days, by which correspondingly the volumetric COD loading rate was increased from 0.4±0.1 to 2.8±0.6 kg /(m3·d) and volumetric NH4-N loading rate was increased fr...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27150

This study examines the impact of the chemical oxygen demand to nitrogen ratio (COD:N) on nitrous oxide (N2O) emissions during N removal via a nitrite (NO2−) pathway for synthetic livestock wastewater treatment. Based on typical cycle operations, 1.07 ± 0.07% of the incoming N load was emitted as N2O at a COD:N ratio of 3:1. This was higher than the 0.83 ± 0.08% emitted at a COD:N ratio of 6:1. The low COD:N ratio in the synthetic livestock wastewater may thus cause increa...
Autori: Qiang Kong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27157

It is of great concern to reduce greenhouse gases (GHG) and ammonia (NH3) emissions from animal manure composting in China. The purpose of this study was to investigate effects of adding red mud on emissions of GHG (methane (CH4), nitrous oxide (N2O)) and NH3 in full-scale swine manure windrow composting. Two full-scale swine manure windrow composting experiments were carried out to compare emission of GHG and NH3 with and without addition of red mud. Results showed that the addition of modified...
Autori: Chenyang Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27158

Occurrence of antibiotics and heavy metals, together with concentrations of conventional pollution indicators were assessed in digested piggery wastewater (DPW) generated in ten large-scale pig farms in Jiaxing City, China. Results showed that water quality of DPW varied in different farms as well as in different seasons. Digested piggery wastewater pollution tended to be less serious in Summer than in Spring, Autumn and Winter. Conventional pollution indicators of chemical oxygen demand (COD...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27159

A combined system of up-flow cyclic sludge bed (UCSB) and aerobic nitrification reactor (ANR) was designed for organic matter and ammonia nitrogen (NH4-N) removals of swine wastewater. The UCSB had one acidogenic zone for hydrolytic acidification to solve the problem of poor carbon source in swine wastewater, and the other zone for denitrification. Results showed that average removals of the chemical oxygen demand (COD) and NH4-N were 92% and 95%, respectively, under the following conditions...
Autori: Jie Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27160

Three pilot-scale biofilters consisting of 1 m aerobic woodchip layers and 0.5 m submerged woodchip layers were constructed to treat the separated pig manure anaerobic digestate (SAD). Reductions of 54% dry matter, 80% of chemical oxygen demand (COD), 93% of 5-day biochemical oxygen demand (BOD5), 86% of total nitrogen (TN) and 79% of total phosphorus (TP) were achieved. The study results confirm the occurrence of nitrification in the aerobic woodchip layers and denitrification in the submer...
Autori: Kathy Carney
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27161

Safe utilization of fly ash (FA) and reclamation of sodic soils are important environmental problems. In this study a field experiment was carried out with Vigna radiata L. crop using fly ash (FA) and phosphogypsum (PGY) as amendments in sodic soil during 2011 at Lucknow, Uttar Pradesh, India. V. radiata L. was sown in sodic soil amended with press mud (10 t ha-1) considered as control. Besides, 10 and 20 t ha-1 doses of FA and PGY were considered as other four treatments, respectively. The grow...
Autori: Kripal Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27180

In this work, the effect of cyclic anaerobic/aerobic conditions on the biodegradative capability of the mixed microbial culture for the azo dye Acid Red 18 was investigated in the sequencing batch reactors. For this purpose, five anaerobic/aerobic sequencing batch reactors were operated under the same operation conditions at different anaerobic/aerobic reaction times. The whole reaction time was 22-h with anaerobic/aerobic periods of 6/16, 10/12, 14/8, 18/4 and 22/0 (h/h) in An/ASBR1 to 5, respe...
Autori: Mohammad Hakimelahi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27191

As part of the 2012 Land Use/Land Cover Area Frame Survey (LUCAS), topsoil samples were collected in Bulgaria and Romania using the same methodology as for other EU Member States in an equivalent survey carried out in 2009. In total, 664 Bulgarian and 1384 Romanian samples were collected which enabled a comparative assessment of topsoil properties under different land covers within, and between, these countries, as well as in a broader European context. The samples were analysed for basic soil p...
Autori: Gergely Tóth
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27205

The important factor for health hazards in major cities in India is air pollution. Due to the sudden increase in vehicular population in the city of Chennai, South India, there is a high increase in vehicular emission caused by the vehicular effluents like Carbon monoxide, oxides of Nitrogen, oxides of Sulfur and other Particulate Matter. This study proposes an advanced state of the art technology (On Board Diagnostics) to acquire and process data from the vehicular emissions through online data...
Autori: Gunaselvi Manohar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27221

In this study, the oleaginous yeasts cultured in tomato waste hydrolysates (TWH) to produce microbial lipids that offer a suitable alternative to vegetable oils as feedstock for the biodiesel synthesis. The TWH were prepared by acid hydrolysis (2.5% H2SO4). To obtain higher growth rates, as well as higher lipid contents, Lipomyces starkeyi were cultured under original nitrogen content (TWHON), lower nitrogen content (TWHLN), attained by alkaline precipitation of TWHON followed by centrifugation ...
Autori: Abu Yousuf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27226

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

This study compared performance of the O3/UV process and biotrickling filtration as standalone and combined system on elimination of toluene from a waste gas stream. The performance of the bench scale O3/UV reactor was investigated with inlet toluene concentration of 650 ppmv and reaction time of 7.5 s. The results demonstrated that the combined O3/UV process degraded 34.1% of toluene under the selected conditions. The biotrickling filter had a maximum elimination capacity of 125.6 g/m3.h, corre...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27228

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

The effect of ceria content on the physicochemical properties and catalytic performance of nanostructured CeO2/Al2O3 for removal of toluene from waste gas stream was studied. The properties of the catalysts were addressed using XRD, FESEM, BET, TPR-H2 and FTIR techniques. XRD patterns confirmed the formation of CeO2 with average crystallite size of 7.8-8.7 nm. FESEM images confirmed the presence of fine particles between 25.2-189.1 nm. BET results showed that nanostructured CeO2/Al2O3 had high s...
Autori: Saeed Saedy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27245

The present work reports the gaseous emissions of the following industries, Interloop Textile (IP Tex), Crescent Textile (CT Tex), Kalash Textile (KH Tex), Noor Fatima Textile (NF Tex), Bashir Textile (BP Tex) and Hina Sana Texile (HS Tex), which are located in Faisalabad, Pakistan. Industries were tested for the mixture of gases containing carbon monoxide (CO), nitrogen oxides (NOx), sulphur oxides (SOx), carbon dioxide (CO2) and hydrogen (H2) emitting from these industries. The maximum amounts...
Autori: Muhammad Zubair
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27256

Non-availability of good quality water in sufficient quantities and the environmental impacts of used water discharges have led to the treatment and reuse of the aquaculture water contaminated with dissolved organics and ammonia rather than discharging it. This paper explores the effectiveness of in-situ sediment microbial fuel cell (MFC) for aquaculture water treatment along with generation of electricity. A sediment microbial fuel cell (SMFC) was designed and the efficiency of stainless steel ...
Autori: Thypparampil Karunakaran Sajana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27261

Carbonaceous materials were obtained from waste tyres and their potential application as hydrogen sulphide adsorbents was investigated. The adsorbents were obtained by pyrolysis of waste tyres and physical (CO2) or chemical (KOH) activation at 550 and 800ºC. The effect of modification conditions on the performance of waste tyres based materials as adsorbents of H2S at room temperature in dry and wet conditions was investigated. Sorption capacity of such adsorbents was found to strongly depe...
Autori: Magdalena Hofman-Bieniek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27263

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

This study aims to evaluate the effects of Fe2+ present in carbonated natural mineral waters on the decomposition of hydrogen peroxide (H2O2) used as sanitizing agent of the collector water tanks and the oxidation of NH4+ to NO3– and NO2– nitrogen compounds from bottled carbonated natural mineral water by the Fenton process. This evaluation suggests that the distribution of the nitrogen compounds, at certain concentrations of H2O2 is influenced by facilitated Fenton reaction in the p...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27279

The paper discusses the pollution status in the case of an important NE Romanian watercourse (Siret River) in Pascani town area based on the analysis of some water quality indicators (pH, temperature, dissolved oxygen, organics (COD and BOD5), conductivity, fixed residues, nitrogen-based nutrients (N-NH4+, N-NO3-, N-NO2-), phosphates, total phosphorus (P), total calcium (Ca2+), magnesium (Mg2+), iron (Fe2+, Fe3+), turbidity and suspended solids content) measured at three local strategic control ...
Autori: Carmen Zaharia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27281

The Amara Lake is located at the south-eastern part of Romania. It is a shallow lake with an average depth of 3m and average extent of 1.32 km2, having a particular importance for the area in which is situated. This importance derives from its main functions in the ecosystem, namely: source of food, shelter and breeding place for almost 54 bird, balneary tourism attraction and jobs for the residents of Amara who live in the northern part of the lake. Under these conditions, the sustainable devel...
Autori: Ofelia Axinte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27282

The remarkable photocatalytic properties of titanium dioxide and the high adsorption capacity of the mesoporous materials were combined to obtain active photocatalysts for the decomposition of Rhodamine 6G dye. The mesoporous TiO2 was obtained by the controlled hydrolysis-condensation of titanium isopropoxide, using hexadecyl-trimethyl-ammonium bromide as template, followed by calcination to remove the organic matter. Subsequently, this sample was doped with sodium wolframate and platinum. T...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27325

Conversion of natural ecological systems has been one of the greatest human impact on terrestrial ecosystems. The expansion of anthroposphere altered virtually all biogeochemical cycles of elements. Nitrogen holds a key place in sustaining life and presents unique traits such as broad chemical speciation and mobility within the environmental compartments. With historically adapted ecosystems to low bioavailable nitrogen, understanding the complexity of the nitrogen disruption is a continuous cha...
Autori: Andreea Csolti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27329

To evaluate the effects of seasonal fluctuations, soil types, land use and management inputs on the abundance and composition of soil bacteria, twenty soils types from Moldavia region located in north-eastern Romania were compared. Changes in soil microbiota are an early and sensitive indicator of soil pollution and can be used to predict long-term trends in soil quality. The use of microbial properties as indicator of soil pollution is easily measured and can also be measured accurately across ...
Autori: Eugen Ulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27333

The utilization of agro-industrial waste as a potential substrate for producing enzymes may serve a dual purpose of reducing the environmental pollution along with producing a high value commercial product. Twelve different agro-industrial wastes were evaluated for extracellular BGL (β-glucosidase) production by a mutant of Bacillus subtilis on solid state fermentations (SSF). The Citrus sinensis bagasse was found to be the most suitable substrate with highest BGL titer (35 U/gds). Optimum ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27378

This study was to optimize the fermentation process for protein enrichment of potato starch residue (PSR) by solid state fermentation with mixed strains. Three single-factor experiments were conducted to optimize the fermentation conditions, and a Plackett-Burman design followed by a central composite design of response surface methodology was investigated to optimize the medium constituents. The optimal fermentation conditions were fermentation temperature 28°C, fermentation period 72 h and...
Autori: Heng Lei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27380

Common issues of the gasification systems relate to filtering apparatus. Dry filtering processes are simple and reliable. However, the filtering material defines the maximum and minimum temperature at which the filter can operate properly. In addition, dry filtration is not effective on light tar compounds (i.e. benzene and toluene) or ammonia compounds. On the other hand, despite being very efficient, wet filters drop the gas temperature below the line of condensation of tar, ammonia and ste...
Autori: Giulio Allesina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27412

Lignocellulosic residues are relatively recalcitrant to bioconversion during anaerobic digestion (AD) for biogas production. Pre-treatments with cellulolytic enzymes or diluted alkali can facilitate biomass hydrolysis and enhance the process. Both pre-treatments require low energy and chemical inputs, without accumulation of inhibitor. Milled wheat straw was pre-treated with hydrolytic enzymes or with diluted NaOH before AD. The pre-treatments were performed on sterilized, stabilized with formic...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27420

Removal of the heavy metal ions from water disposals remains a widespread problem due to their adverse influence on public health. The most harmful materials are the products of nuclear fission called radioisotopes such as cerium ions. Cerium barely interacts with adsorbent materials, therefore the new substances capable to bind cerium are of great interest. Ca and Na alginate samples were incubated in Ce3+ solutions; adsorption capacity was measured and the results were evaluated using Langm...
Autori: Maxim Khotimchenko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27435

This study analyses the relationship between the scattering properties and the chemical compounds internal mixture of the aerosols near Bucharest, Romania. Several cases of local aerosols influenced by heating sources, like wood or fossil fuel, are characterized in order to retrieve the winter period specificity. Correlation between organic and inorganic aerosols composition from mass spectrometry measurements made with Compact Time (CT) of Flight Aerosol Mass Spectrometer (AMS) and scatteri...
Autori: Luminita Marmureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27444

Turfy soil is a special soil formed in the swamp environment with the incomplete decomposition of plant residue. On one hand, the special engineering geological properties of turfy soil such as high compressibility, high moisture content, high void ratio, will cause great difficulty with engineering construction in turfy soil area, this study will make it clear of parameters value for engineering design. Turfy soil, on the other hand, is a part of the wetland, the essence of protection of the...
Autori: Lei Nie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27445

The partial nitrification bioreactor (PNBR) was operated at a constant temperature and an influent synthetic wastewater pH of 35°C and 8.5, respectively. The effects of dissolved oxygen concentrations (DO), hydraulic retention times (HRT), and the nitrogen loading rates (NLR) on the ammonium removal efficiencies and the NO2-N/NOx-N ratio were investigated. The activity of nitrite oxidizing bacteria was stimulated at high DO concentrations. The highest NO2-N/NOx-N ratio of 0.76 was obtained a...
Autori: Sukru Aslan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27455

Wastewater treatment using sequencing batch reactor (SBR) has certain advantages over conventional activated sludge system. The performance of sequencing batch reactor in treating high C/N ratio was investigated with suspended polyurethane and polystyrene attached growth biomass configuration. A sequence of 4 hr HRT, 0.3 month SRT and 1kg COD/m3 was employed to study treatment efficacy. Treatment performance was assessed by means of chemical oxygen demand (COD), total nitrogen (TN) and total pho...
Autori: Beenish Saba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27478

The phenol degradation capacity of Serratia marcescens NSO9-1 isolated from olive mill wastewater was evaluated and optimized in this study. Plackett-Burman design coupled with Box-Behnken methodology was used to evaluate the effects of medium components and significant parameters on phenol degradation by this relevant strain. According to Plackett-Burman-based statistical screening, seven of the eleven components of the medium had a significant effect on the metabolism of phenol degradation. Th...
Autori: Nurdan Saraç
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27495

Average emission factors of air toxic compounds, emitted from motorcycles in Bangkok, Thailand were analyzed using the IVE (International Vehicle Emission) model. The model was utilized taking into account the actual fleet and characteristics of motorcycles of the study area. Four air toxic compounds (namely benzene, 1,3 butadiene, acetaldehyde and formaldehyde) and their emission rates were calculated under two main pollution abatement scenarios (the improvement of fuel quality and switching of...
Autori: Pantitcha Outapa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27513

This study undertakes to characterize through thermal analysis in dynamic conditions a wide range of building materials used for various types of insulation and presents for the first time a comparative analysis of their thermal stability. To this effect, the dynamic thermal analysis TG/DTG was applied. The results show a degradation resulting in one, two or three stages after a complex mechanism, with different mass loss, depending on the structure and atmosphere in which the thermal decomposit...
Autori: Andreea-Camelia Sprânceană
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27514

The aim of the studies was to evaluate the influence of the 30-year operation of a small retention reservoir fed with water from a forest-agricultural catchment area on the contents of selected mineral elements substances in bottom deposits. The studies were carried out in the Łoje dam reservoir (N 53o7’28’’, E 20o48’20’’), supplied by the regulated Łojówka stream. Deposit samples were collected in four transects perpendicular to the reservoir...
Autori: Ireneusz Cymes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27518

This paper introduces basic information on the biodegradation of polymers as well as the mechanisms of degradation and factors influencing this process. This paper describes prodegradant additives that induce decomposition of polymers to biodegradable compounds with regard to additives causing oxo-biodegradation. Based on the results of experiments conducted for molded pieces made of polypropylene and extrudates made of low density polyethylene with a d2w prodegradant additive, dependences betwe...
Autori: Tomasz Jachowicz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27519

This work describes the variations in nitrogen (N) and phosphorus (P) removal performances and bacterial population dynamics in response to different influent C/N and C/P ratios in a novel BNR-IC process combining biological nutrients removal (BNR) with induced crystallization (IC). A good nutrients removal performance was achieved at 7.8 of C/N ratio and 23.3 of C/P ratio, where P and TN removal efficiencies were 94.0±2.4% and 90.5±4.3%, respectively. Moreover, significant changes...
Autori: Haiming Zou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27523

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

Among the organic pollutants, the chlorinated phenols represent an important class of compounds having a stable world market of ca. 100 kt per year. Due to their aryl structure and presence of the chlorine atom, chlorinated phenols are exceptionally recalcitrant toward chemical reactions aimed at their reduction. Adsorption from liquid phase has received special interest due to its flexibility and simplicity in operation. Especially adsorption using activated carbon (AC) has been recognized by t...
Autori: Marius Sebastian Secula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27552

There is an increasing interest in the food industry and in protective health care for the expansion of natural antioxidants from plant materials. The solid wastes generated by the winemaking industry represent about 30% of the material used and it consists mainly of grape pomace (containing seeds, pulp, stem and skin). It is well known that high quantities of valuable compounds like dietary fibre, oils from the seeds, anthocyanins and phenolic compounds still remain within the grape marc. The p...
Autori: Valeriu V. Cotea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27553

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

Microalgae can be considered as significant sources of sustainable and beneficial biocompounds such as carotenoids, lipids, proteins, polysaccharides, pigments, vitamins etc., with many uses in energy production (biofuels), pharmaceutical, cosmetic and food industries. This class of microorganisms are considered as sustainable feedstock due to some major advantages related to metabolism modulation, faster growth rate compared to plants, no use of terrestrial land. This review will present the mo...
Autori: Alexandra Cristina Blaga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27558

Urban expansion, often seen as an indicator of economic growth and a possible response to housing crisis in big cities, is the main driver for carbon emissions in the metropolitan area due to higher values of household income, vehicle ownership and home size. The transport related pollution includes over 200 different compounds: besides CO2 emissions, CO, NOx, BTX and dust resulting from exhausting processes, from abrasive wear of brakes, tires and road surfaces. The expansion of the urban areas...
Autori: Lucian Roșu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27560

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

Dielectric measurements were carried out on a series of bent-core liquid crystals based on resorcinol and 2, 7-dihydroxinaphtalene cores and presenting B mesophase in between 30-160°C. The dielectric constants in the liquid crystalline phase were measured as a function of frequency and temperature. The dielectric relaxation of bent-core compounds has been analyzed by dielectric constants/frequency curves. The variation of the dielectric strength with temperature has been determined as well. ...
Autori: Irina Carlescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27568

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

Groundwater pollution investigation near old and closed landfill sites is increasingly attracting more attention. Nitrogen compounds, especially those leached from the landfill area, are often regarded as a main pollution source for the groundwater. This study investigated the nitrogen pollution in the groundwater near a closed old landfill area of Beijing, China. The field investigation showed that the nitrate-polluted groundwater was determined as Class VI (refers to bad quality) at the detect...
Autori: Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27585

This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

Phenolic compounds are known as recalcitrant pollutants in many industrial wastewaters, e.g. olive mill wastewater. An efficient treatment is therefore needed before the discharge of phenol-containing wastewaters into the environment. The possibility of removing some natural occurring phenolics, namely tyrosol, p-coumaric acid and vanillic acid, by micellar-enhanced ultrafiltration (MEUF) using a cationic surfactant, cetylpyridinium chloride (CPC), and polyethersulfone membranes of 20 and 50 kDa...
Autori: Abdelilah El-Abbassi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27607

Aerobic treatment processes using attached media have been studied extensively to remove organic matter from wastewater and also denitrification process. The objective of this study was to assess the ability of down flow anaerobic up flow oxic submerged bio-film reactor (DAUOSBR) to remove phosphorus, nitrogen compounds, BOD5, COD, turbidity and total suspended solids from the Farabi Hospital wastewater. The present work involved designing and building a reactor loaded with down flow anaerobic u...
Autori: Meghdad Pirsaheb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27622

FLUCTUATION OF RIVER NETWORK WATER ENVIRONMENTAL CARRYING CAPACITY IN A COMPLICATED RIVER-LAKE SYSTEM    • MINERALOGY AND GEOCHEMICAL DISTRIBUTION OF HEAVY METALS FOR THE FAGUL CETĂȚII TAILINGS, ROMANIA    • ACCUMULATION AND AVAILABILITY OF TRACE ELEMENTS FROM SOIL INTO ORIENTAL TOBACCO GROWN IN MACEDONIA    • OLFACTORY EFFECT ON LANDSCAPE PREFERENCE    • EFFECT OF MOLASSES ADDITION AS BIODEGRADABLE MATERIAL ON PHENOL REMO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27628

Polycyclic aromatic hydrocarbons (PAHs) are very hazardous compounds. This investigation is the third in a series of three experiments carried out in conventional wastewater treatment plants with regard to PAHs. The first experiment regarded the analysis of PAHs in a municipal wastewater sewage system and in the wastewater treatment plant (WWTP) effluent, followed by a comparison between the observed removal efficiency and FATE model (US-EPA) predictions. The second experiment was carried out in...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27629

Degradation of Clindamycin phosphate (CMP) was studied in aqueous solutions by an anodic oxidation process under galvanostatic conditions. The electrolysis cell consisted of a Ti/SnO2-Sb anode, prepared by dip-coating technique, and a 316 stainless steel cathode, both of which had a surface area of 6 cm2. The effects of critical factors, including CMP concentration, current density, initial pH, and the supporting electrolyte were evaluated. The electrochemical oxidation of CMP was controlled by ...
Autori: Mitra Gholami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27639

An attempt has been made in the present study to investigate the wastewater characteristics from six different rural human settlements in the state of Punjab, India. The six selected rural catchments are located on a radius of about 5-50 kilometers from Phagwara town, Kapurthala district. The study area comprises the villages of the districts of Jalandhar, Kapurthala and Shaheed Bhagat Singh Nagar in Central Punjab. The wastewater samples were collected between January, 2012 and July, 2012 and a...
Autori: Puneet Pal S. Cheema
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27641

Pyrometallurgical recycling of lead from spent batteries entails secondary waste fractions generated in the blast furnace as iron stone and lead slags. For further purification of both fractions, hydrometallurgic processing is proposed. This paper focuses on purification of iron stone, in view of recovering metals (mainly lead) and of producing decontaminated iron stone fit for further recycling. The results demonstrate that iron stone is mainly composed of iron and lead; copper, zinc and antimo...
Autori: Bart Van der Bruggen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27642

Pesticides are considered among the most serious environmental pollutants, frequently used in the control of agricultural and domestic pests. Biodegradation of chlorpyrifos and its 3,5,6-trichloro-2-pyridinol (TCP) derivative was studied in mineral medium and soil with fungal consortium consisting of JAS1 and JAS4 strains which were isolated from paddy field soil. The fungal consortium was spiked with 300 mg l-1 chlorpyrifos which was degraded completely within 12 h of incubation in the miner...
Autori: Jayanthi Abraham
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27655

In this study, the concentrations of 15 phenol derivatives were analyzed from the phreatic and groundwater wells surrounding a decommissioned chemical factory in a village from the western part of Romania. An UPLC-MS method was used to assess the concentrations of the chemical target compounds in the water samples. The most frequent compounds were 4-chlorophenol, 4-tertoctylphenol and 4-nonylphenol, being detected in 17 of the 19 sampling sites, while the least frequent compound was 2,4,6- t...
Autori: Elena Preda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27661

This study presents a Rough Set Analysis (RSA) application, partially based on dominance in relation to air micro-pollution management in an industrial place with a high environmental risk rate, such as the industrial area of Siracusa, located in the South of Italy. This new data analysis instrument has been applied to different decisional problems in various fields with considerable success. Therefore, it is believed that it could also be used for the environmental issue related to multi-att...
Autori: Agata Matarazzo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27663

The objective of the present study was to (i) compare different treatment options for greywater (GW) reuse, (ii) assess the potential of treated GW for reuse, and (iii) select the optimal treatment option by using Analytic Hierarchy Process (AHP). Raw GW was settled for 2 h. Five different treatment options were investigated simultaneously in parallel using the same influent (settled GW). The treatment options were (1) sand filtration, (2) sand/brick bat filtration, (3) alum coagulation/floc...
Autori: Dilip Machindra Ghaitidak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27669

This paper presents an assessment of the toxic compounds released from metalworking fluids (MWFs) used in aluminum solid waste processing and from aluminum slag landfills, and their impact on environmental quality and human health. The mean concentrations of dust, oil mist, aldehydes, volatile organic compounds (VOCs) released from metalworking fluids were determined in machine shops. The exposure in machine shops was quantitatively dominated by VOCs, whose concentrations varied in the range...
Autori: http://www.ecozone.ro/reviste.php?RID=27677

The objectives of this study were to investigate: a) whether the duration of organic farming influences the dimension, shape and geometry (fractal dimension) of soil micropores (<50μm) and b) for relationships of morphometric traits with certain chemical and biochemical soil variables (microbial biomass, N- and C-mineralization rates, NH4+, NO3-, organic C and N, extractable P, Mg+2, K+, Ca+2). We compared soil micromorphometric traits (area, perimeter, compactness, solidity, eccentricity)...
Autori: Nikolaos Monokrousos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27682

Organoarsenic compounds are used extensively as swine feed-additives to promote animal growth and control diseases, e.g. roxarsone (4-hydroxy-3-nitrobenzenearsonic acid) and arsanilic acid (4-aminophenylarsonic acid) are usually overused in swine industry in China. As a cost-effective technology for animal manure treatment and reuse, composting is widely used for swine manure treatment. Therefore, the purpose of this study was to investigate changes of arsenic species and fractions during a full...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27683

One of the main challenges for the development of biomass algal system production is the high operational and capital costs for these technologies. A great opportunity to overcome these challenges may however exist in the integration of wastewater treatment with algal biomass production. The algae are used for treatment of industrial wastewater, for purification of effluent originating from livestock production, while the studies concerning the use of algae species for the treatment of aquacultu...
Autori: Katya Velichkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27684

Industrial wastewater is of particular importance. In most wastewater treatments, physicochemical parameters are used to determine the performances which are costly while protozoa can be used as less expensive biological indicators to determine the efficiency of the treatment plant. The purpose of this study was to investigate the relationship between protozoa and physic-chemical characteristics of the Abadan wastewater treatment industry. Samples were collected from wastewater stabilization po...
Autori: Abotaleb Bay
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27694

Though Scirpus triqueter plays an important role in protecting the ecological functions of Yangtze River estuary wetland which is frequently contaminated by petroleum, knowledge is limited about the mechanisms involved. In this study, comparative analysis of soil properties, microbial community structure and soil enzymes in the rhizosphere of S. triqueter and bulk soil was conducted throughout one year to provide an insight into the phytoremediation mechanism in the field. The total petroleum hy...
Autori: Jing Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27697

The presence of nitrogen in its reduced forms serves as an indicator of natural aquatic system degradation. The excessive concentrations of nitrogen in reduced forms (NH4+, NO2-) found in the sections of the the Shireutsi (of the Prut River) and the Olaneshti (of the Nistru River) prove that these sites are areas to focus efforts on improving water quality. Laboratory simulations indicate a good environmental buffer action of natural waters to potential pollution in Sculeni and Ungheni sections ...
Autori: Petru Spataru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27698

Indoor air quality (IAQ) improvement potential of rotor turbine ventilator (RTV) was researched by setting up an RTV on the outer part of the chimney of a kitchen, located in a “windy” city, Çanakkale, Turkey. Efficiency of RTV was assessed by preliminary tests, conducted in a three-storey restaurant. After obtaining positive results in terms of airborne bacteria count (TBC) from these tests, long-term measurements were carried out in a cafeteria by air sampling before and aft...
Autori: Sibel Mentese
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27734

Evaluation of spatial/ temporal water quality data at reservoirs has shown differences after the dam construction as well as long-term changes of water chemistry. One of the most recent reservoirs created in Europe is Ilarion Reservoir in Western Macedonia – Greece (2012). In this work, the water physicochemical characteristics of this young reservoir and the spatiotemporal water quality variation of the feeding river and its main tributaries have been studied, and statistically interprete...
Autori: Elisavet Amanatidou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27737

Monitoring of air emission and pollution control cost is a key to improve air quality management of electricity generation industry. This research comprehensively evaluates abatement cost of sulfur dioxide (SO2), nitrogen oxides (NOx), emission intensity and emission inventory of sulfur dioxide (SO2), nitrogen oxides (NOx), particulate matter (PM), and carbon dioxide (CO2) emitted from Thailand’s fossil fuel power plants. The research applied bottom-up approach with continuously monitored ...
Autori: Wasin Pinprateep
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27740

Petroleum hydrocarbons not only are toxic to humans and other living organisms, but will also pollute groundwater. It is thus critical to decrease the concentration of these pollutants in soil. Phytoremediation is an effective way to remove toxic compounds from soil. The current study used sorghum (Sorghum bicolor (L.) Moench) and barley (Hordeum vulgare) to reduce petroleum hydrocarbon content of contaminated soil around Isfahan Oil Refinery (Isfahan, Iran) and assessed the concentrations of pe...
Autori: Farida Iraji Asiabadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27741

The objective of this study was to evaluate the effect of different doses of meat and bone meal (MBM) applied as organic fertilizer on the quality of groundwater in arable fields. The effect of meat and bone meal fertilizer applied at rates of 1.0, 1.5, 2.0 and 2.5 t ha-1 was compared with no fertilization, mineral fertilization, and manure fertilization (10 t ha-1). Groundwater samples for chemical analyses were collected every month during the growing season using piezometers installed in the ...
Autori: Arkadiusz Stępień
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27742

Leather manufacturing process generates significant volume of wastewater. Deliming is one of the unit processes, in which about 4.5 L of wastewater is generated per one Kg of pelt. Reuse of wastewater from the unit processes, where significant volume of wastewater is generated is much important to address pollution mineralization and water conservation. Presence of significant level of organic pollutants is the primary factor that deters reuse of waste streams. In this paper, the Electro-Oxidati...
Autori: Sundaramoorthy Sundarapandiyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27744

This paper aims to pioneer the research into the dry nitrogen deposition in reservoirs serving as drinking water sources. For this purpose, several field experiments were performed to investigate the dry deposition in Xiaotaipingyang, Danjiangkou Reservoir (Henan) from September 2015 to August 2017. Sample concentrations were measured for NH4+-N, NO3--N and total dry deposition (TDN). Then, dry deposition flux of NH4+-N, NO3--N and TDN were estimated based on the measured concentrations and samp...
Autori: Luo Ling
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27749

The City of Jacksonville, Florida USA is in the midst of an important program to reduce nutrient load from its municipal storm water system. New regulations promulgated by the US EPA and State of Florida have targeted nutrient reduction within the St. Johns River watershed which includes most of the City of Jacksonville. In order to reduce overall nutrient loads to the St. Johns River, the City of Jacksonville and its consultant team have begun a construction program to build a series of wet det...
Autori: Killian Eckert
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27750

The bioremediation represents an ongoing challenge, especially in the case of organochlorinated compounds, due to the difficulties in their degradation that causes persistence in the environment. Herein we report a study on the ability of a mixture of microorganisms (MOM) to interact with organochlorinated compounds belonging to different chemical classes, i.e. DDT, PCB, tetrachlorobenzene, and lindane. Experiments in vitro showed the disappearance, partially reversible of these compounds in mix...
Autori: Carla Boga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27784

This study aims to monitor Volatile Organic Compounds (VOCs) and odour annoyance perceived by the exposed population living nearby a petroleum plant through an integrated high temporal resolution methodological approach. The area under investigation is considered one of the most critical industrial areas of the South of Italy (Basilicata) because of presence of the largest Italian petroleum plant, called the "Center Olio Val d'Agri" (COVA). In fact, VOCs and odours emitted from ext...
Autori: Alessia Di Gilio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27791

The aim of this paper was to investigate the possibility of incorporation non-metal fraction (NMF) in concrete products as a substitute for aggregate on industrial scale, while other studies are mostly based on NMF incorporation in concrete only on laboratory scale. Mineral filler was supplemented with 5, 10, 15 and 20 wt.% NMF from waste printed circuit boards (WPCBs) and its influence on concrete quality was assessed based on compressive and tensile strength conducted on laboratory and indust...
Autori: Vitomir Premur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27857

Tunisian fish-processing industries generates large amounts of by-products. Their disposal is an increasing environmental and health problem. For an economic utilization, these by-products may be used in producing higher value-added products such as protein hydrolyzates. In this study, protein hydrolyzates with different degrees of hydrolysis (12%, 20% and 26%) were prepared from heads and viscera of Sardinella aurita using crude protease of Bacillus licheniformis NH1. The obtained hydrolyzates ...
Autori: Nabil Souissi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27852

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

A wide range and globally active agro-industries such as olive oil processing, winery, tannery, textile and food production discharge a large volume of wastewater containing tannins. Tannins are complex structured chemicals which cause high organic content, requiring high dissolved oxygen in wastewater treatment plants or producing oxygen depletion in the aquatic environment. Tannins are known to be hardly degraded in biological treatment. There has been evidence that the presence of natural ...
Autori: Giusy Lofrano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27885

Sand contamination is an important factor when assessing the health hazard potential of public beaches. The goals of this study are to assess the performance of four sand washing procedures on the removal of surface adsorbed chemical species, and to identify which chemical components are best suited for monitoring the health quality of beach sand. Four washing treatments were investigated: contact, stirring, sonication, and boiling. Sand samples were collected from three Portuguese beaches an...
Autori: Mário Dias Almeida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27890

Lake Hazar is one of the largest and deepest lakes in the Eastern Anatolia Region of Turkey. It is an outstanding natural resource and famous for its blue, clear, deep and alkaline waters. However, a drastic decrease in water quality and water clarity of the lake has occured in recent years. This decrease is mainly a result of nutrient and sediment transport to the lake. This study was conducted to assess water quality of Behrimaz Stream and amounts of freshwater, nutrients, major ions, biolo...
Autori: Memet Varol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27891

In this work, we report a methodology to provide emission factors based on micro-reactor studies. We propose emission factors for ammonia (NH3, 158 mg/km), nitrous oxide (N2O, 322 mg/km) and molecular hydrogen (H2, 72 mg/km) for vehicles equipped with three-way catalytic converter (TWC). Our experimental conditions were similar to those prevailing on vehicles during catalyst light-off and transient urban driving cycle. NH3 and H2 emission factors reported in this work are quantitatively simil...
Autori: Gustavo Ariel Fuentes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27899

Agro-industrial waste are seen as potential precursors in the development of adsorbents for the removal of phenolic compounds, which exhibit a harmful effect to human health due to their high toxicity. This work evaluated the use of coal prepared from coconut tree agro-industrial waste, for the adsorption of phenol in aqueous solutions. Three coal samples were prepared as follows: carbonized only (Cb), activated with synthetic air (Cair) and activated with CO2 (CCO2). Based on the results of ...
Autori: Marta Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27937

Removal of excessive ammonium nitrogen (NH+4-N) from aqueous solution has been of considerable concern for several decades. It can be removed by air stripping, a necessary prerequisite is adding enough alkali. This study presented the first attempt to investigate the potential use of ceramsite coated with magnesium hydroxide (CCMH) on the effectiveness of NH+4-N removal coupled with air stripping at ambient temperature without alkali addition. The results showed that the CCMH coupled with air...
Autori: Tianpeng Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27940

The related European directives in force stipulate that product testing shall be performed in conditions that reproduce as accurately as possible the real ones that may be encountered during their operation. These are products whose intended use are specified in the safety data sheet or within the instructions for use, and whose limits of the micro-climatic parameters that can be encountered (temperature, humidity, wind - for the outside ones, temperature, humidity, generation of restricted t...
Autori: Ilie Ciprian Jitea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27956

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

A series of water quality and ecological problems are caused by algal blooms, and natural allelochemicals are considered as the source of algaecides due to their friendly advantages to environment. It has been reported that abundance of secondary metabolites are found in grape plants, and the extracts from the plant exhibit antioxidant, antibacterial and antifungal capacities. In order to reveal the anti-algal activity of grape pruning wastes and promote their usage, we analyzed the composition ...
Autori: Zhaojiang Zuo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27971

Chlortetracycline (CTC) and copper (Cu) are simultaneously used as feed additives to improve the growth performance and to prevent infection in pig farming. After ingestion by animals, most of these compounds are excreted and coexist in swine manure. They might have an influence on anaerobic digestion when the swine manure is used as substrate in a biogas plant. The purpose of this study was to investigate the effects of both CTC and Cu on batch swine manure anaerobic digestion in order to bette...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27983

Little is known about the degradation kinetics of sewage sludge, sanitized with Ca(OH)2, in soil. Thus, this work aimed to monitor the degradation of limed sludge, under field conditions, when applied on soil surface or incorporated into the soil. The limed sludge was applied in dystrophic Inceptisol at a dose of 500 kg ha-1 yr-1 of total nitrogen. The mineralization process in the soil was monitored for 131 days. Samples of organic material were collected for analysis of total and easily oxi...
Autori: Isabela Diniz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27995

In this study the effectiveness of Lactuca sativa, Medicago sativa and Phragmites australis for the treatment of domestic wastewater in horizontal subsurface flow was investigated. The removal efficiency of chemical oxygen demand (COD), total nitrogen (TKN), total phosphorus (TP), and total suspended solids (TSS) was measured. The experiment was conducted in two different retention time (5 and 7 days) in three seasons (spring, summer and fall). The removal efficiency was increased as the rete...
Autori: Farham Aminsharei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28009

Clinoptilolite (Clin), the most widely used natural zeolite in environmental applications, was used as soil additive to investigate its effectiveness in protecting and improving the quality of soils that received surface disposal of OMW, as well as in limiting nutrients leaching from the degraded soils. Clin was added in a batch experiment of 18 months, where OMW were added in evaporation ponds and on soil for a period of more than 12 years. The zeolite was added as dust (particle diameter &l...
Autori: Maria K. Doula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28018

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Groundwater recharge is an effective method to solve the groundwater overexploitation. In this study, the method of numerical simulation is used to discuss the environmental change of groundwater in the process of multi-source recharge. The results of multiple water sources including local regenerated water source, wetland water source and South-to-North water source show that the cumulative loss of groundwater resources in Mihuaishun area in 2007 ~ 2016 reaches -1.784 × 109 m3. The inf...
Autori: Dasheng Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28024

This paper presents an interdisciplinary methodology for handling the exposure of workers to lead and its compounds in a systematic way by connecting different disciplines, and thus enabling the comprehensive supervision of the workplace exposure. The exposure of workers to lead and its compounds was studied in the Republic of Slovenia. The research comprised 1079 employers being exposed to the lead concentrations between 0.01 and 0.9 mg/m3, which exceeded the limit value by 9 times. Workers ...
Autori: Lidija Korat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28032

Extracts of Bifurcaria bifurcata seaweed were obtained by diverse conditions. Different extraction techniques, such as hydrothermal and ultrasounds, and three different solvents (water, ethanol and water/ethanol (50:50)) depending on technique were used. Moreover, supercritical CO2 (SC-CO2) with 10% of ethanol as co-solvent using different extraction times (30, 45 and 60 min) was also used as extraction technique. Extraction yield, phenolic content and antioxidant activity were measured for e...
Autori: Rubén Agregán
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28039

In this work we aimed to examine the influence of the main abiotic factors (temperature, rainfall, relative humidity, atmospheric pressure) on the synthesis of active compounds (phenolics, flavonoids), with antioxidant and therapeutic effect of two herbs - Capsella bursa-pastoris (shepherd's purse) and Marrubium vulgare (horehound) collected from two different areas of Romania: Dobrogea (Constanta) and Muntenia (Bucharest). The studies have shown that biogenesis and accumulation of second...
Autori: Elena Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28041

The development of green eco-friendly inhibitors for the corrosion of metallic surfaces in acid media is still considered as a major challenge and target for corrosion-mitigation engineers. We have prepared in this work 4 different extracts from the plant Ruta Chalepensis using methanol, chloroform, ethyl acetate, and aqueous ethyl acetate solvent systems. The flavonoids content, as well as the other oxygenated compounds, in the 4 extracts was carefully screened using the gas chromatographic&nda...
Autori: Meryem Amal Benghalia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28063

The article describes a pilot study on a wastewater treatment plant operating a biogas plant (2.793 MW). The authors of the experiment used organic waste material, including: chicken fat with feathers (FF), molasses (M), glycerol (GL), raw sewage sludge (SS) and digested sewage sludge as an inoculum. The parameters of raw and digested sludge were compared, e.g. changes in the concentrations of ammonium nitrogen (N-NH4+), alkalinities, chemical oxygen demand (COD) and light metal ions. Potenti...
Autori: Agnieszka A. Pilarska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28064

Common centaury, Centaurium erythraea Rafn., represent the best known and the most investigated medicinal plant species of genus Centaurium. Centaury has been used for centuries in traditional medicine. Secondary metabolites such as bitter secoiridoid glucosides (gentiopicrin, swertiamarin and sweroside), xanthones (eustomin and demethyleustomin), and phenolic acids are the main constituents responsible for the therapeutic properties of centaury. Previous investigation showed that overexpression...
Autori: Milana Trifunović-Momčilov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28068

Wastewater for irrigating tree crops may act both as water and mineral nutrients source, offering potential agronomical and environmental advantages. This work investigated the effect of an entire season supply of secondary treated wastewater (STW) on the nutritional and physiological responses of 3 year old apple trees. Trees (Gala /M9) were individually grown on 40-L pots filled with a sandy-loamy soil and drip irrigated with: 1)Tap water (TW) (without any mineral fertilizer inputs); 2) Tap wa...
Autori: Giulio Demetrio Perulli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28079

The scarcity of water resources, especially in the agricultural sector, is an increasing problem both in developing and industrialized countries. Recent studies and reports have shown the high potential of wastewater reuse mostly in South European countries. In this paper, we study the possibility to reuse wastewater from the Santerno full-scale wastewater treatment plant located in Imola (Bologna, Italy). Specific monitoring campaigns have been carried out in Basin 1 of the natural finishing tr...
Autori: Carmine Fiorentino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28085

Leather processing is one of the highly polluting industries, due to generation of significant quantities of tanned and untanned wastes. Untanned wastes are less contaminated with chemicals and a better source of high value products such as collagen rather than tanned or finished leather wastes. In the present study, collagen dissolution substances (CDS) were prepared from bovine limed split wastes as value added products, by treating leather wastes with sodium hydroxide and fermented dairy b...
Autori: Gökhan Zengin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28095

The aim of this research was to improve the removal of organic matter and nutrients from wastewater from pig farms in a combined batch reactor performed as anaerobic-aerobic sequential. For this purpose, it was suggested to include recirculation cycles of wastewater in a sequentially pulsed manner in the anaerobic treatment followed by intermittent aeration in the aerobic-anoxic treatment. This novelty implemented in both sequential reactors was studied under pilot scale conditions. The process ...
Autori: Jorge Alonso Cortes-Esquivel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28101

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

Little information is available on the combined effect of weather conditions and tillage systems on nitrogen lost from wind erosion. A field study was carried out on an Entic Haplustoll to analyze N content in the eroded material. Field measurements were made during the winter fallow (WF) and summer fallow (SF) periods in conventional (CT) and a no-till (NT) fields. Winters are more humid and less windy than summers. Results showed that there were N losses and gains by the wind with both tillage...
Autori: Sergio Alberto Abascal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28119

Soils are influenced by stand composition and hydrological regime as well as by stress abiotic factors, including forest fires. As such, this study analyzed three stands affected by fires of different severities. Soil samples were gathered during the spring of 2017 from three sample areas in Vrancea County, eastern part of Romania. For each area studied, soil profiles were studied in 3 areas affected by fires and in control areas located close to each other. The soil respiration was determined b...
Autori: Aurelia Oneț
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28120

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

This work seeks to develop a suitable heavy metals precipitation modeling approach that could give reasonable results in mainstream use with industrial wastewater treatment. This paper is devoted to the thermodynamic analysis of the degree of precipitation of slightly soluble hydroxides and salts in industrial wastewaters in order to optimize the technological schemes of extraction and reuse of heavy metals from industrial waste. Based on the notion of the solubility product, the equations desc...
Autori: Igor Povar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28156

The recovery of nutrients from sewage sludge ash, especial phosphorus, is one of the most important alternative in sewage sludge management. Phosphorus is an essential element for all living organisms and very important for agriculture and industry, as well as. Because the phosphorus is a non-regenerative resource, its recovery plays an important role for society. Phosphorus capitalization as struvite (NH4MgPO4.6H2O) from sewage sludge has attracted considerable attention due to its potential to...
Autori: Bogdan Adrian Militaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28158

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162

The paper covers the results of a study, carried out during 2005 and 2018, regarding the impact of sludge dump of a wastewater treatment plant from Iasi city, Romania, on the soil characteristics. Experimental research was conducted to highlight the evolution of the heavy metal content of both the material in the storage site and the soil in its proximity. The following heavy metal concentrations were analyzed with atomic adsorption spectrometry method: Zn, Ni, Cr, Pb, Co, Cu and Cd. Research ha...
Autori: Georgiana Cezarina Bartic Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28164

Biological ammonium removal from wastewater requires coupling of nitrification and denitrification processes in respective aerobic and anaerobic conditions. This difference in environmental requirements pose a big challenge in the design of systems intended to effect both nitrification and denitrification processes. Alcaligenes faecalis strain No. 4, however, has both heterotrophic nitrification and aerobic denitrification abilities in aerobic conditions, eliminating the need to provide anaerobi...
Autori: Hung-Soo Joo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28186

Diesel oil (DO) as a mixture of alkanes and aromatic compounds causes damage to the ecosystem in terrestrial and aquatic habitats. One of the best methods of treating contaminated areas is to use microorganisms in a bioremediation method that can degrade pollutants. The aim of this study was to isolate indigenous bacteria with high biodegradation potential of DO from oil-contaminated wastewater. Bacterial isolation was performed using a mineral medium containing contain 1% DO as the sole source ...
Autori: Sharareh Dashteepour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28224

In Brazil, there is a deficit of access in relation to sewage services for a large part of the population, and this fact is the one responsible for the contamination of watercourses. This is because to the lack of investment in infrastructure in the country, since sewage treatment plants require high costs and high area demand for deployment, besides the installation of the collection system, which directs the wastewater to treatment. This paper describes the behavior of wetlands as a post trea...
Autori: Rodrigo de Freitas Bueno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28241

Current landscapes have been intensively modified by humans and forest fragmentation has created substantial increases of forest edges. So far, scale-dependence between observable ecological patterns and the underlying processes affected by forest fragmentation have been widely ignored. To overcome the widespread ambiguity in selecting relevant spatial scales for studying the ecological effects of forest fragmentation, we investigated the effect of forest prevalence and edge length on carbon st...
Autori: Emilia I. Cojoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28242

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

Air pollutants have harmful effects on the human health and exacerbate morbidity and mortality. The aim of this study is to assess the short-and long-term effects of the suspended particulate matter with the diameter of smaller than 2.5 μm (PM2.5), nitrogen dioxide (NO2), and ozone (O3) on the mortality cases in city of Kerman in 2016 and 2017. In this study, AirQ+ software presented by European Center for Environment and Health and World Health Organization (WHO) was employed. Daily mean con...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28255

Pharmaceuticals in the environment are considered as emerging contaminants which are particularly persistent and which could represent a threat both for animals and humans following long-term exposure. Pharmaceuticals include, among others, antibiotics, anti-inflammatory drugs, steroid hormones, antidepressants, β-blockers and lipid regulators. Excretion from humans is considered the main source of release of such compounds in the environment. The excreted compounds reach wastewater treatm...
Autori: Cristiana Morosini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28257

Natural wastewater treatment systems can represent a smart solution in small communities (50-2000 Population Equivalent) as they are very low-cost technologies in terms of energy consumption and maintenance. Moreover, those systems could be implemented as clean processes for wastewater reuse in the frame of circular economy applications. In this context the present study examines the main features of Subsurface Flow System - horizontal (SFS-H) phyto-treatment process. To this aim a pilot plant w...
Autori: Carmine Fiorentino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28297

Groundwater at an abandoned industrial area near Bergamo, Italy, was historically contaminated by tetrachloroethylene (PCE) (>100 μg/L) and, to a lesser extent, by trichlorethylene (TCE), dichloropropane (DP) and 1,1,2,2-tetrachloroethane (R-130). A liquid reagent (EHC® Liquid) was selected for remediation of groundwater at the site. The reagent is provided in two parts: EHC® Liquid Mix (a soluble organo-iron salt), and ELS® Microemulsion (a lecithin-based carbon substrate), a...
Autori: Alberto Leombruni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28300

Citrus is one of the most important fruit tree crops worldwide, with respect to both total production and economic value. About 80% of the world production is destined to the fresh market, the remaining is processed to obtain various products (juices, jams, etc.). Citrus processing residues account for about 50-60% of processed fruits; their huge amounts and peculiar characteristics need a correct management that imply cost for producers and processors. If not well managed, they can represent an...
Autori: Paola Sangiorgio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28309

A significant reduction in nitrogen (N) losses from agricultural fields will make a positive impact on the environment. Managing nitrogen for the optimum application provides economic benefits as well as environmental protection. This study presents a model that was developed to determine the optimum ratio of N to yield based on N sensor indices in winter wheat. A quadratic polynomial model was used to characterize the relationship between N and yield for the optimum N rate. The N was applied t...
Autori: Uğur Yegül
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28317

This research applied passive air pollution samplers to monitor the concentration of the pollutants nitrogen dioxide (NO2) and ozone (O3) in order to investigate the relationships between pollutant concentrations and meteorological variables. The study was carried out in three strategic sites in the municipality of Erechim, Brazil, which provide intense traffic of small and large vehicles. The pollutant analyses were performed using the method of UV/VIS spectrophotometry. NO2 concentrations vari...
Autori: Eduardo Pavan Korf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28326