This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

Abstract The Romanian standard for the analytical method for phenols measurements in aquatic media was subject of internal validation procedure, adapted to the specific concentration domain of the laboratory. Method performance criteria were investigated on standard samples measurements: selectivity, linearity domain, precision, accuracy, limit of detection, limit of quantification androbustness. The validated method was further used on real samples of domestic and industrial wastewaters from...
Autori: Carmen Dima, Cristina Jelescu, Camelia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25448

Abstract Herbs have been used as food and for medicinal purposes for centuries. In recent years, natural compounds such as phenolic acids, phenolic diterpenes and triterpenes, present in various plants, have been the subject of intense research due to their potential benefits for human health. It has been demonstrated that the antioxidant and radical scavenge activities are the main properties of these compounds. The main difficulties in using natural products as a source for pharmaceutical ...
Autori: Ruxanda Bodirlau, Iuliana Spiridon, Carmen Alice Teaca, Narcis Anghel, Maria Ichim, Svetlana Colceru , Alice Armatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25474

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract As a result of the chemical-analytical studies of the marine environment of the water area of some Black Sea ports it was found that the water content of standardized components - toxins do not exceed their maximum allowable concentration, and the corresponding sediment significantly contaminated with cadmium, lead, phenols, petroleum products....
Autori: Anatoliy Andrianov, Eugeniy Malinovsky, Inna Bezlutskaya, Inna Chebotarskaya, Oleg Nedostoup, Tatyana Kovalchuk, Valeriy Antonovich
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25628

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

? COMPARATIVE CONSIDERATIONS ON THE STRUCTURE OF SOME MOLYBDENUM/NIOBIUM DOUBLE PEROVSKITES OXIDES ? THE INFLUENCE OF THE STORAGE TIME ON THE STABILITY OF BUTTER ? CaCO3 CONTROLLABLE SYNTHESIS BY DOUBLE EXCHANGE METHOD USING CaCl2 RESIDUAL SOLUTIONS ? OPTIMIZATION OF COAGULATION-FLOCCULATION IN THE TREATMENT OF CANAL WATER ? ANODIC DETERMINATION OF PENTACHLOROPHENOL FROM WATER USING CARBON NANOFIBER-BASED COMPOSITE ELECTRODE ? STUDY OF PRECIPITATES GROWTH IN COAGULATION ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25663

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractAmong foods that possess potent medicinal properties, Cucurbitaceae seeds stand as a promising source, since they are assumedto have a protective effect against oxidative stress. In order to analyze the antioxidant compounds of the seeds of Citrulluslanatus, Lagenaria siceraria, Telfaria occidentalis, Cucurbita maxima, Cucumis sativus, Cucumeropsis mannii, and Cucurbitamoschata, the dried seeds were extracted in MeOH-H2O (50 %; v/v) mixture at constant mixing rate. Qualitative phytochemi...
Autori: Aristide Guillaume Silapeux Kamda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26440

AbstractIn this study, the reduction of phenolic compounds and other organic pollutants from greenish black (GB) and dark brown (DB)olive mill wastewater (OMW) was investigated. Ultrasonic irradiation in combination with aerobic biodegradation was adoptedas the treatment technique. Operational parameters such as the duration of ultrasonic irradiation, ultrasonic power intensity andultrasonic frequency were tested to determine their effects on phenol, BOD, and COD degradations. It was found that ...
Autori: Zakaria Al-Qodah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26484

AbstractThe potential application of methemoglobin from bovine blood to remove aromatic compounds in the presence of hydrogenperoxide has been evaluated. The organic compounds herein tested include phenols, amines or hydrocarbons, which arepollutants deriving from different industries and display high persistence and toxicity in waters. The oxidative process has beencharacterized by soluble hemoglobin and immobilized on Eupergit CM, using 4-chlorophenol as a model substrate. Theobtained ...
Autori: María Teresa Pérez-Prior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26580

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract Supercritical fluid and ultrasound assisted extractions were applied as a first step in a complex processing of spruce bark in order to recover polyphenols compounds. The aim of the study was to compare the efficiency of these "green" processes with a conventional extraction technique (ethanolic extraction). Supercritical fluid extraction was carried out in two steps: (i) static extraction for 15 min at 1000 psi with pure CO2 and (ii) dynamic extraction for 45 min at 35, 4...
Autori: Adina Iulia Talmaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26680

Ranunculus rionii and Ceratophyllum demersum develop aquatic dense stands, which lately started to represent a major ecological concern for all the ponds and/or lakes in Romania. The potential relationships between the phytochemical compounds detected in these plant extracts (acids, phenols, heterocycles, alcohols, hydrocarbures) and the allelopathic properties against Gram positive and Gram negative bacterial strains and microalgal cultures were investigated and discussed in the current stud...
Autori: Mariana Lupoae
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26971

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

The production process of wine and distilled generates several by-products (20-30% of total production). Currently, most of the solid by-products (pomace, stalks, lees and seeds) obtained as downstream of the vinery industry, are conferred to the distillery or, less frequently, used in agriculture and for energy production. As a consequence, much of the antioxidant compounds contained in the grape is unused in the products of processing and is lost. These substances (among which the most impo...
Autori: Paola Zitella
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27135

A Microwave-Ultraviolet reactor was developed and the effect of microwaves on photodegradation of various phenols was studied using the reactor. The degradation study was carried out by six methods - microwave irradiation, photodegradation with UV light, microwave and ultraviolet radiations (microwave irradiation in presence of TiO2, photodegradation with UV light in the presence of TiO2 and also simultaneous MW and UV irradiations in the presence of TiO2). The relative efficiencies of the degr...
Autori: Singaram Karthikeyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27248

Chlorophenols, commonly found in industrial effluents, are considered as priority pollutants because they may cause severe environmental impacts and human health related problems. Nanofiltration (NF) represents an important option for the removal of chlorophenols present in aqueous effluents. This study presents some results on the performance of nanofiltration for the removal of 4-chlorophenol and 2,4-dichlorophenol from synthetic wastewaters considering the selection of adequate operating and ...
Autori: Corina-Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27324

This study assesses the feasibility of using the filamentous fungus Fusarium solani for the removal of colour, chemical oxygen demand (COD) and total phenols from a pulp mill industry effluent, inoculated in a rotating biological contactor (RBC). The study was done in a RBC of total volume 7.2 L, operated with 40% of useful volume at 37(±2)°C, inflow 3.5 L d-1, hydraulic residence time (HRT) 20 h and rotation speed 2 rpm. A Haldane model was used to determine the kinetic parameters of...
Autori: Alberto Vergara-Fernández
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27456

In this study major factors affecting the phenolation process of lignosulfonate (LS) waste liquor (recovered from pulp and paper industry) were optimized in order to improve LS substitution for replacing petroleum-based phenols during phenolic resin manufacturing. Four different parameters, namely phenol/lignosulfonate ratio, time, temperature and lignosulfonate waste liquor concentration, were varied in an experimental program having as response function the reaction yield. Response Surface Met...
Autori: Andrei Ionuţ Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27551

Among the organic pollutants, the chlorinated phenols represent an important class of compounds having a stable world market of ca. 100 kt per year. Due to their aryl structure and presence of the chlorine atom, chlorinated phenols are exceptionally recalcitrant toward chemical reactions aimed at their reduction. Adsorption from liquid phase has received special interest due to its flexibility and simplicity in operation. Especially adsorption using activated carbon (AC) has been recognized by t...
Autori: Marius Sebastian Secula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27552

There is an increasing interest in the food industry and in protective health care for the expansion of natural antioxidants from plant materials. The solid wastes generated by the winemaking industry represent about 30% of the material used and it consists mainly of grape pomace (containing seeds, pulp, stem and skin). It is well known that high quantities of valuable compounds like dietary fibre, oils from the seeds, anthocyanins and phenolic compounds still remain within the grape marc. The p...
Autori: Valeriu V. Cotea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27553

The study provides information about separation and identification of natural bioactive compounds from beech (Fagus sylvatica L.) bark with potential therapeutic applications such as antibacterial activity against human pathogens. Beech is a common material used in the wood industry, but its bark is separated from the wood and is considered a by-product. In this study, natural compounds with biological activity were obtained from beech bark by hot water extraction. The high-performance liquid ch...
Autori: Corneliu Tănase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27561

This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

Clinoptilolite (Clin), the most widely used natural zeolite in environmental applications, was used as soil additive to investigate its effectiveness in protecting and improving the quality of soils that received surface disposal of OMW, as well as in limiting nutrients leaching from the degraded soils. Clin was added in a batch experiment of 18 months, where OMW were added in evaporation ponds and on soil for a period of more than 12 years. The zeolite was added as dust (particle diameter &l...
Autori: Maria K. Doula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28018

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

Advanced oxidation processes (AOPs) are used with high efficiency in wastewater treatment due to the formation of hydroxyl radicals with high oxidation capacity. However, there exists many different variables which affect the efficiency of theses processes as it affects the amount of hydroxyl radicals formed; such as reaction time, pH, temperature, reactant concentrations and catalyst amount. In this study, the removal of 2-chlorophenol (2-CP) and 2,4-dichlorophenol (2,4-DCP), which are highly t...
Autori: Aysun Altikat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28251

Citrus is one of the most important fruit tree crops worldwide, with respect to both total production and economic value. About 80% of the world production is destined to the fresh market, the remaining is processed to obtain various products (juices, jams, etc.). Citrus processing residues account for about 50-60% of processed fruits; their huge amounts and peculiar characteristics need a correct management that imply cost for producers and processors. If not well managed, they can represent an...
Autori: Paola Sangiorgio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28309