Include urmatoarele articole� Degradation of alcian blue 8 gx by heterogeneous and homogeneous photocatalytic processes� Evaluating the performance of solid waste management models� Bioreactors with stirred bed of immobilized cells 1. Studies on mixing efficiency� Fugitive emissions estimation from petroleum storage tanks� New Ni(II) coordination polymers with insulating and anticorrosive properties� Determination of water quality deterioration at pilgrimage centre along river netrav...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25196

The models describing the flow or the heat and mass transfer in stirred bioreactors can be easily adapted for the continuous phase from the stirred bed bioreactors. But, for the immobilized biocatalyst phase, new models have to be established. Therefore, in this paper the influences of the main factors on mixing for a bioreactor with stirred bed of S. cerevisiae immobilized cells in alginate have been analyzed.. The mixing efficiency continuously increases with rotation speed acceleration for th...
Autori: Anca-Irina Galaction, Anca-Marcela Lupasteanu, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25116

The present paper examined the photocatalytic degradation (PCD) of gas-phase trichloroethylene (TCE) over thin-film TiO2. A large-scale treatment of TCE was carried out using scale-up continuous flow photo-reactor that nine reactors were arranged in parallel and serial. The parallel or serial arrangement is a significant factor to determine the special arrangement of whole reactor module as well as to compact the multi-modules in a continuous flow reactor. The conversion of TCE according to the ...
Autori: Gyung Soo Kim, Sang Bum Kim, Sung Chang Hong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25121

In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

This paper brings a review on the trends of arc plasma reactors, in the new millennium, as an alternative contribution to the reduction of carbon emission at global level. The development of technically and economically feasible plasma processes for the production of hydrogen is analyzed. Literature provides data on achievable intensification of the involved chemical processes comparing with those from the classic reactors. The hydrogen production is studied starting from hydrocarbons and alcoho...
Autori: Iulian Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25128

In this work, the ability of Romanian peat for sorption of Pb (II) ions from aqueous solution has been determined using the batch experimental techniques. The sorption equilibrium has been studied at different pH values. The equilibrium adsorption level was determined to be dependent of the pH of solution and initial Pb(II) concentration.The equilibrium adsorption capacity of Romanian peat sorbent for lead has been described by seven types of mathematical model isotherms, namely: Freundlich, Lan...
Autori: Brindusa Robu, Corneliu Cojocaru, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25160

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei, Gabriela Apostolescu, Ioan Rosca Studies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monit...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25175

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

Contain all the articles from this issueLignin in crop cultivations and bioremediationAlfred Abaecherli, Valentin I. PopaMaterials for intermediate-temperature solid oxide fuel cells and for proton exchange membrane fuel cellsAnnemarie Huijser, Joop SchoonmanAre interfacial biocatalysts important tools for nonpolluting technologies? 2. Immobilization of lipases and their  representative applications Brindusa Dragoi, Emil DumitriuUASB treatment of fruit canning wastewater: pilot-scale invest...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25180

Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

Include urmatoarele articole:� Removal of persistent organic pollutants from textile wastewater by membrane processes� Sustainability evaluation of an urban residential settlement� Removal of zinc (II) from aqueous solutions by romanian sphagnum peat moss� Development trends of cold plasma reactors in the global context of carbon emission reduction� Assessing the potential of wind power in Romania within Kyoto targets� Research on the impact induced in the environment by milk process...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25198

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractCadmium is listed by US-EPA as one of priority pollutant and as a known carcinogen, and therefore its removal from wastewaters of various industrial processes is a very important environmental problem. The paper analyzes the effectiveness of a Romanian sphagnum moss peat as available and cheaper sorbent in removal of Cd (II) from aqueous solutions. Batch sorption experiments were carried out in order to establish the influence of solution pH, peat dose, contact time and initial cadmium c...
Autori: Catalin Balan, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25231

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractConsidering that three-phase dispersions are common in chemical engineering and biotechnology, and with increasing airlift reactor applications to chemical and biotechnological processes, a experimental study was undertaken in order to investigate the liquid phase hydrodynamics and dispersion in an external-loop airlift reactor on laboratory scale. Experiments were conducted in order to find a relationship between relevant hydrodynamic and mixing parameters of a solidsuspended exter...
Autori: Florina Ungureanu, Maria Gavrilescu, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25268

AbstractThe study on distribution of oxygen transfer rate for a stirred bioreactor and simulated broths was carried out for four positions inside the broth and indicated the significant variation of kla on the bioreactor height. For all considered positions, kla initially increased to a maximum value with mixing intensification, decreasing then, as the result of the modification of mixing mechanism in presence of air bubbles. The increase of broth viscosity led to the significantly reducing of o...
Autori: Adina Segneanu, Anca-Irina Galaction, Dan Caşcaval, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25270

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

AbstractThe possibility of biological phosphorus removal (BPR) was studied using a lab-scale single reactor the same as SHARON process. Up to now, there has been no investigation of the feasibility of SHARON process for the purpose of phosphate removal. The optimal operation conditions were established to obtain highest removal rates. Under the experimental conditions, the phosphorus concentration dropped from an influent concentration of 1000 mg/L to levels around 0.1 mg/L or less. It was concl...
Autori: Abbas Rezaee, Hatam Godini, Masod Solimani, Nayera Nami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25293

AbstractBiosorption an alternative process is the uptake of heavy metals from aqueous solutions by biological materials. The biosorption of nickel ions from aqueous solution was investigated by Nordmann fir (Abies nordmanniana (Stev.) Spach. subsp. nordmanniana) in a batch adsorption system as a function of pH, initial metal concentration, biomass dosage, contact time. The data showed that the maximum pH for efficient sorption of Ni(II) was 6.5. At the optimal conditions, Ni(II) ion biosorption ...
Autori: Handan Ucun, Ozkan Aksakal, Yusuf Kaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25295

Include urmatoarele articole:� Removal of nickel from aqueous solution by Nordmann FIR (ABIES Nordmanniana (STEV.) SPACH SUBSP. Nordmanniana) cones� Determination of heavy metals in extracts and macerates from garden flowers� Biological phosphorus removal in a high performance single reactor � Advanced Cd2+ removal on dispersed TioO2-fly ash � Remediation techniques for contaminated soils� Separation of uranium(vi) from soils by extraction in aqueous PEG (1550) - Na2SO4 - Na2CO3 two-...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25296

AbstractThe purpose of this study was to investigate the immobilization of denitrifying bacteria on microbial cellulose (MC) for biological denitrification. A novel denitrifying bacterium, Pseudomonas stutzeri, was immobilized in microbial cellulose and introduced into an up flow packed bed reactor in order to remove nitrate from synthetic influent. The MC presented the high biomass concentration throughout the experiment, achieving 3.4 mg biomass/g support. The efficiency of the system for deni...
Autori: Abbas Rezaee, Hatam Godini, Hossein Bakhtou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25302

AbstractDark fermentation hydrogen production from a mixture of food components using two different methods of methanogenic inhibition (autoclaving and BES) and three different temperatures (37, 60, and 70 Â?C) was examined in batch assays for two different mixed anaerobic cultures - one suspended sludge (S) obtained from an anaerobic digester and one granular sludge (G) obtained from a brewery wastewater treatment plant. In general, BES-inhibition of sludge was more robust when compared against...
Autori: Angela A. Abreu, Anthony S. Danko, Francisco Pinheiro, Maria Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25308

AbstractThe sorption of Pb(II) and Hg(II) ions from aqueous solutions by moss peat (from Poiana Stampei, Romania) was studied in a batch system. The data obtained from experiments of a single-component sorption were analyzed using Langmuir and Freundlich models. The Langmuir equation describe sorption isotherm of Pb(II) and Hg(II) with high correlation coefficients, and better than Freundlich model. According to the Langmuir model, the maximum uptake capacities of moss peat for Pb(II) and Hg(II)...
Autori: Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu, Mioara Răţoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25311

- Artificial intelligence applications in the atmospheric environment: status and future trends- Kernel methods and neural networks for water resources management- Environmental decision support systems based on models and model-based reasoning- Towards an intelligent tutoring system for environmental decision makers- SBC-MEDIU: A multi-expert system for environmental diagnosis- Fast and accurate residential fire detection using wireless sensor networks- Validation of a knowledge-based risk mode...
Autori: http://www.ecozone.ro/reviste.php?RID=25377

AbstractPulsed high voltage discharge technology is a newly developed method for knock out viruses in blood with various electrohydraulic discharge reactors. The aim of this study is to investigate the effect of an electrohydraulic discharge treatment system on Hepatitis C virus (HCV) behaviour. The electrohydraulic discharge (EHD) reactor consist of high voltage point discharge electrode above blood surface and cylindrical ground copper electrode containing the blood (in the same time act as th...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25362

AbstractThe study on the distribution of oxygen transfer rate in a stirred bioreactor for Propionibacterium shermanii broths underlined the major influence of the presence and concentration of biomass on the interphasic transfer of oxygen. Owing to the bubbles surface blockage by the bacterial cells, the accumulation of biomass from 30.5 to 120.5 g/l d.w. led to the decreasing of kla for about 1.3- 2.4 times. Compared with the simulated broths without biomass having similar apparent viscosity, t...
Autori: Adina Segneanu, Anca-Irina Galaction, Dan Caşcaval
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25364

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractThe lead(II) ions sorption from aqueous solutions on three types of peat from Poiana Stampei (Romania) was studied. The peat was drawing from different deeps, such as 5-10 cm deep (peat 1), 0.5-1.0 m deep (peat 2) and from > 1.5 m deep (peat 3). The influence of several experimental parameters (initial lead concentration, contact time) was studied in batch experiments. The kinetics of sorption was followed based on the amount of lead(II) ions retained at various time intervals. The re...
Autori: Laura Bulgariu, Mioara Răţoi, Dumitru Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25389

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract The potential of using ultrasonic irradiation and microbiological treatment for the removal bis(1-chloro-2-propyl) ether from aqueous solutions has been investigated. Experiments were performed in a continuous bioreactor, 3500 mL volume, and in an ultrasonic bath respectively, using frequencies of 38+1kHz and applying a power of 30 W. Under these conditions, the sonochemical conversion of ether was found to be superior to the biological one. The ultrasound method was improved by air ...
Autori: Mihaela Iordache, Vasile Lucian Pavel, Lim Myunghee, Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25403

Abstract Development of industrial cell culture processes needs a good engineering practice and system expertise in achieving a successful integrated process using disposable components. The bioreactors for 3D tissues systems could be an advantageous alternative in terms of low contamination risk, easiness of handling and scaling-up. A careful and strategic design of these equipments provides a better process control and a safe and reproducible production of tissue construct. They can offer t...
Autori: Anca-Irina Galaction, Dan Caşcaval, Dan Zaharia, Radu Ciorap
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25404

Abstract This study examined the effect of hexane concentration in the inlet gas stream on the treatment performance of a concentric tube internal loop airlift bioreactor with a 7 L capacity, inoculated with a strain of Pseudomonas aeruginosa. The experiments were conducted employing hexane-contaminated air, in 0.62, 1.26, 2.15 and 4.5 g/m3 concentrations at 29 ¹ 1°C. The 100% hydrocarbon removal was verified when effluents containing 0.62 and 1.26 g/m3 of hexane were employed. Under contin...
Autori: Fernando Jorge Santos Oliveira, Leonardo Vazquez, Francisca Pessoa de Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25437

Abstract Electroflotocoagulation is used for the treatment of liquid wastes of various origins, containing suspended matter. The metal hydroxide formed by electrochemical metallic ions generation acts to aggregate the colloidal impurities, and the hydrogen bubbles evolved at the cathode allow flotation of foam containing the impurities. The aggregates formed (containing the impurities) and lifted above the solution can then be removed. Electroflotocoagulation (simultaneous electrocoagulation ...
Autori: Marius Constantin Mirica, Mirela Ioana Iorga, Adina Segneanu, Ionel Balcu, Doru Buzatu, Cristian Vaszilcsin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25457

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract This paper presents preliminary results of a batch-scale study assessing the contribution of the multiple phenomena involved in siloxane removal in three-phase biomatrices. Batch scale experiments were undertaken in shaken flasks containing acclimatised culture medium, solid media and siloxane vapours (octamethylcylotetrasiloxane and decamethylcyclopentasiloxane, respectively) under anaerobic gas-phase conditions. Abiotic and biotic phenomena, considered to be possible siloxane remov...
Autori: Gabriela Soreanu, Patricia Falletta, Michel Beland, Kara Edmonson, Peter Seto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25510

Abstract The individual physical, chemical, and biological interactions that determine the exposure of plants and animals to chemicals associated with soils are of great importance in the assessment of contaminants bioavailability. Understanding of bioavailability processes is at last needed to improve the scientific basis of risk assessment and is the purpose of the present research. Since bioavailability processes are embedded within existing human health and ecological risk frameworks, so...
Autori: Brindusa Mihaela Robu, Camelia Smaranda, Florentina Anca Căliman, Laura Carmen Apostol, Lucian Vasile Pavel, Maria Gavrilescu, Raluca Maria Hlihor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25516

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract Peat moss has been widely used as low-cost adsorbent to remove a variety of pollutants, including organic compounds and metal ions from aqueous effluents. Various functional groups allow such compounds to bind on active sites of peat moss. The adsorbent used in this study was Romanian peat moss sampled from Poiana Stampei (Romania). The adsorption of Co(II) ions from aqueous solutions on Romanian peat moss was studied in batch experiments, in order to establish the influence of initi...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25533

Abstract Plasma is often called the fourth state of matter. It is distinct from other lower-energy states of matter, most commonly solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. Plasma technique may use any gas or gas mixture, within equipment limitations. Each gas or mixture of gases produces distinctive plasma, making possible a very diverse range of chemical environments. Besides the recombination mechanisms developed...
Autori: Marian I. Totolin, Ghiocel E. Ioanid, Iordana Neamtu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25550

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract Withania frutescens plant from the south-western Morocco was used as an environmentally friendly material for the removal of As(V) ions from aqueous solutions. This work presents the characteristics of the adsorption and the desorption processes of As(V) using the dried W. frutescens plant as an environmentally friendly adsorbent. The mass of the adsorbent, the As(V) concentration, the contact time and the pH of the tested aqueous solutions were used as controlled variable parameters...
Autori: Mohamed Chiban, Gabriela Lehutu, Fouad Sinan, Gabriela Carja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25568

Abstract A prehydrolyzed aluminium chloride (PAC), commercial product selected from a previously studied series, and the electrochemically obtained PAC (E-PAC) were tested as coagulants, comparatively with the classical aluminium sulfate (alum). A new method for producing E-PAC has been applied. The level of turbidity, the amount of total organic carbon, the UV-254 absorbance and the residual aluminium were evaluated, for determining the efficiency of the coagulation process in all situations...
Autori: Adina Pacala, Ilie Vlaicu, Ciprian Radovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25569

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract In this paper, the capacity of a soil to retain the dye Erythrosine B from aqueous solution by sorption has been studied. Batch adsorption experiments were conducted to investigate the sorption of the dye from aqueous solutions onto soil with particles of different size. Different models were used to describe the kinetic data, to calculate the corresponding rate constants and to predict the theoretical capacities of soil for dye sorption. ...
Autori: Florentina Anca Căliman, Laura Carmen Apostol, Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25573

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract Chromium (Cr) is one of the most common metal contaminants in soil because of its use in ore refining, production of steel and alloys, metal plating, tanneries, wood preservation, and pigmentation. In soil environment, the most stable oxidation states of chromium are Cr (III) and Cr (VI). While Cr (III) is considered an essential trace element for the functioning of living organisms, Cr (VI) is toxic and carcinogenic to humans via inhalation for long exposures, since it is easily sol...
Autori: Dumitru Bulgariu, Laura Bulgariu, Maria Gavrilescu, Raluca Maria Hlihor, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25590

Abstract The use of biomaterials as biosorbents for treatment of wastewaters will provide as a potential alternate to the conventional treatment methods. The main advantages of biosorption are high selectivity , cost effectiveness and good removal performance. World wide numerous low cost bio materials have tried for biosorption of dyes. In this present investigation, the dead biomass of Penicillium sp. fungus and wood sawdust was used as biosorbents and their capacity to removed malachite gr...
Autori: Cornel Pohontu, Florin Luca, Igor Creţescu, Manea Liliana, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25593

Abstract The aim of this study was to investigate the Congo Red (CR) sorption behavior onto six soils from Ia?…?¸i area, with different characteristics. The rate of sorption of Congo red dye molecules from aqueous solution by soil was studied in batch conditions. The rate of sorption was very rapid in the first 5-10 minutes and reached a maximum in 20 minutes. Kinetic modeling analysis of the pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich equations reveals that t...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25594

Abstract Unlike the P. shermanii and S. cerevisiae cultures, the study on the distribution of oxygen transfer in stirred bioreactor for P. chrysogenum free mycelia broths indicated that this process is controlled mainly by the high apparent viscosity of broths, and less by the presence of fungus biomass. For this reason, the influence of fungus accumulation on the reduction of kla is attenuated compared with that obtained for bacterial or yeasts broths. The lower influence of fungus biomass i...
Autori: Anca-Irina Galaction, Dan Caşcaval, Marius Turnea, Stefanica Camarut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25606

Abstract The adsorption behavior of bael tree (BT) leaf powder for cadmium ions from aqueous solutions has been investigated as a function of appropriate equilibrium time, adsorbent dose, adsorbate concentrations and pH using a batch system. Studies showed that the pH of aqueous solutions affected cadmium removal as a result of the fact that removal efficiency increased with increasing solution pH. The maximum adsorption was 93.56% at solution pH equal to 6.0, contact time of 30 min and initi...
Autori: Ponnusamy Senthilkumar, Rangasamy Gayathri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25621

Abstract In this study, the effect of adding granular activated carbon (GAC) to aerobic sequencing batch reactor (SBR) on possibility to treat a wastewater containing a reactive dye (Brill Blue KN-R) was investigated. Experiments were performed in four cylindrical Plexiglas reactors for 68 days (5 days for acclimatization of sludge and 63 days for normal operation in two separate phases). Initial dye concentrations were adjusted to 20, 25, 30 and 40 mg/L in the reactors R1, R2, R3 and R4, res...
Autori: Amir Asadi Vaigan, Hossein Hashemi, Mohammad Reza Alavi Moghaddam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25624

Abstract Equilibrium and kinetics of sorption of Zn (II) ions from aqueous solutions of pH 5 on indigene (Romanian) peat moss were investigated in batch system. The experimental equilibrium sorption data at three temperatures were analysed by Freundlich, Langmuir, Tempkin and Dubinin-Radushkevich sorption isotherm models. Results indicate the following order in to fit the isotherm equations: Langmuir > Tempkin > Dubinin-Radushkevich > Freundlich. The equilibrium sorption capacity determine...
Autori: Angelica Kicsi, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25632

Abstract Two different inocula - acclimated and non-acclimated to fat- were used to evaluate the methane production of cow manure, food waste and oily waste in batch assays. The inoculum adapted to fat had a better performance in the methanisation of substrates with significant lipids content. Furthermore, it is demonstrated that an increase in the ratio inoculum/substrate can enhance the initial methane production rate of oily waste when using a non-adapted inoculum, improving also the ultim...
Autori: Lucia Neves, Maria Madalena Alves, Raquel Ferreira, Rosario Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25634

Abstract Mathematical models have become a valuable tool to study the anaerobic digestion process, to guide plant design and optimize operation strategies. Models require accurate and significant parameter values for being useful. Although the identification problem is an issue of concern, often is neglected. The described method for model calibration consists on the performance of simultaneous batch experiments (SBE), which requires simple and usually available equipment, and is based on the...
Autori: Belen Fernandez, Jordi Palatsi, Josep Illa, M. Angels Colomer, Xavier Flotats
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25636

Abstract The aim of this work was the evaluation of the denitrification potential of a consortium of activated sludge adapted to anoxic conditions. As the carbon source is the main parameter influencing the denitrification process, in the first stage three carbon sources (acetate, citrate and glucose) were assayed in batch activity tests. The highest denitrification efficiency was ttained with acetate, being nitrate and nitrite completely reduced. The adapted sludge was then used as a potent...
Autori: Joana Azeredo, Pilar Teixeira, Rosario Oliveira, Zelia Fernandes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25638

? SUSTAINABLE CONCRETE HARDENING PROCESSES IN NORMAL CLIMATIC AND THERMAL TREATMENT CONDITIONS ? THE ENVIRONMENTAL DIMENSION ? AN INTERDISCIPLINARY RESEARCH AREA ? MENU PLANNING STRATEGY BASED ON ECOLOGICAL FOOTPRINT ? EVALUATING ENVIRONMENTAL IMPACT OF NIGERIAN COMPOSTED WASTES USING LABORATORY EXTRACTION TEST ? IN SITU RADIOFREQUENCY FIELD LEVEL ASSESSMENT IN TWO URBAN AREAS IN ROMANIA: OPEN QUESTIONS TO ELECTROMAGNETIC POLLUTION ? INNOVATIVE SOLUTION FOR WARNING ON HI...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25657

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? EFFECT OF ELECTRICAL CURRENT ON H2/ H2O2 GENERATION IN NON-THERMAL PLASMA GLIDING ARC REACTORS ? ADVANCES IN THE VISUALIZATION OF THREE-DIMENSIONAL SEISMIC VOLUME DATA ? CHARACTERIZATION OF ELECTROMAGNETIC RADIATION FROM A PATIENT MONITOR ? METHODS OF ELECTROMAGNETIC INTERFERENCE REDUCTION IN ELECTROCARDIOGRAPHIC SIGNAL ACQUISITION ? SPHERICAL MODEL OF THE HUMAN HEAD EXPOSED TO ELECTROMAGNETIC FIELD ? BRAIN ELECTRICAL ACTIVITY RECORDING IN SOME ELECTROMAGNETIC ENVIRONM...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25667

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

? ADSORPTION OF DYE FROM AQUEOUS SOLUTION USING SILVER WOOD SAWDUST CARBON ? TIME SERIES ANALYSIS OF THE HEAVY METALS LOADED WASTEWATERS RESULTED FROM CHROMIUM ELECTROPLATING PROCESS ? WATER QUALITY CHARACTERIZATION OF THE PRUT RIVER ? ETHICAL AND SUSTAINABLE EDUCATION OF ENVIRONMENTAL ENGINEERS - BETWEEN REALITY AND HOPE ? INTERACTIONS AMONG CLIMATE, VEGETATION AND SOILS IN RADUCANENI ? IASI AREA ? DISTRIBUTION OF MIXING INTENSITY OF OXYGEN-VECTOR DISPERSIONS IN AERATED...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25669

Biosorption of lead (II) onto the biosorbent, represented by untreated S. cerevisiae and NaOH-treated S. cerevisiae was examined and the effects of contact time were investigated. The lead (II) biosorption was fast and equilibrium was attained within 90 mins. The maximum removal ratios of lead (II) for untreated S. cerevisiae and NaOH-treated S. cerevisiae after 3 h were 48.6% and 92.5%, respectively, with initial lead (II) concentration of 40 mg/L and optimum pH of 5.0. Data obtained from batch...
Autori: Ying Zhang, Yingjie Dai, Baiyin Liu, Fang Ma, Ru Zheng, Limin Donghttp://www.ecozone.ro/reviste.php?RID=25670

The removal efficiency of p-xylene from gas stream was experimentally investigated in a dielectric barrier discharge (DBD) reactor, which was combined with catalyst, MnO2/Al2O3 pellets, in the discharging and the afterglow area, respectively. The CO2 selectivity of the two kinds of structure was also discussed. The results showed that in both the situation, the synergetic removal efficiency of p-xylene by the DBD-catalyst hybrid system increased with increasing the discharge power and decreasing...
Autori: Hongxia Liu, Yun Liuhttp://www.ecozone.ro/reviste.php?RID=25674

It is a promising way for CO2 capture and sequestration by hydrates crystallization. In this study, the characteristics of CO2 hydrate formation are investigated in a small scale dynamic reactor under pressure conditions from 2.0-3.5 MPa and temperature varied between 0.5-4.0Â?C. The effects of supercooling degree and pressure on hydrates formation were discussed. Hydrates formation can be completely finished within 150 min and the final pressure-temperature points of system are just located on ...
Autori: Ni Liu, Xiaobo Xuan, Daoping Liu, Yingming Xiehttp://www.ecozone.ro/reviste.php?RID=25689

Considering the membrane fouling problem in submerged anaerobic membrane bioreactors, a set of submerged double-shaft rotary anaerobic membrane bioreactor (SDRAnMBR) was constructed by applying a double-shaft rotary module to submerged anaerobic bioreactor, and the theoretic analysis of the characteristics of hydraulics dynamics in SDRAnMBR has been performed. The membrane fouling performance for treatment of synthetic brewery wastewater was investigated by SDRAnMBR. The results of a theoretical...
Autori: Ling Bai, Chao Liu, Weiguang Lanhttp://www.ecozone.ro/reviste.php?RID=25694

A submerged membrane bioreactor (MBR) was employed to treat wastewater containing different content of seawater in this work. During the process, the operating conditions were as follows: COD was 800-1000 mg/L, ammonium-N was 80-100 mg/L, pH was 7.5-8.5, mixed liquor suspended solids (MLSS) was around 7000 mg/L, dissolved oxygen (DO) was 2-4 mg/L. The results showed that the ammonium-N removal was better than COD removal. Sludge settling property was good in saline wastewater treatment, and the ...
Autori: Jin Li, Deshuang Yu, Dan Wanghttp://www.ecozone.ro/reviste.php?RID=25697

The paper analyses the removal efficiency and fluorescence spectroscopic characterization of landfill leachate dissolved organic matter (DOM) fractions in the combined stripping, fenton oxidation, sequence batch reactor, and coagulation process. The high contents of DOM of landfill leachate in each process unit were fractionated into HA, FA, and HyI. The result was the combined process availability for effective removal of DOM fractions. The removal rates for DOM, HA, FA and HyI were 91.9%, 97.1...
Autori: Zhiping Liu, Jin-song Guo, Fang Fanghttp://www.ecozone.ro/reviste.php?RID=25702

Adding ferric or bio-ferric agent is method to improve membrane fouling and prolong membrane life.This paper analyses the influence of ferric content on treatment effect of printing and dyeing wastewater, through examining the change of COD and dyestuff content in supernatant with the change of ferric content in sludge and in supernatant. COD in supernatant is reduced with increase of ferric content in sludge, and the dyestuff content in supernatant is reversed, which might be due to the adsorpt...
Autori: Shifeng Ji, Chunmei Gao, Hong Yang, Ming Chu, Chunfeng Wanghttp://www.ecozone.ro/reviste.php?RID=25711

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:The increasing of energy consumption and fossil fuel emissions (especially CO2, SO2 and NOx) and the limitation of crude oilreserves, determined a growing trend toward renewable energy technologies, like solar, wind, geo-thermal energy and biomass forbiofuels.From all the renewable energies sources, biomass attracts more and more interest being a renewable resource with economicpotential, which can be found all over the world, with positive environmental properties due to neutral emissi...
Autori: Anca Sauciuc, Angela Potetz, Georg Schlaub, Gerald Weber, Hermann Hofbauer, Lucia Dumitrescu, Reinhard Rauch, Ziad Abosteif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25762

Abstract:The study involved investigating the effects of Cr(III) and the efficacy of powdered activated carbon (PAC) in reducing theinhibitory effects of Cr(III) on activated sludge under sequencing batch reactor (SBR) operation. The addition of Cr(III) into SBRsystem caused significant inhibitory effects on the activity of activated sludge as indicated by drastic drop in specific oxygenuptake rate (SOUR). The increase of Cr(III) concentration from 5 to 10 mg/L further deteriorated the treatment...
Autori: Eiichi Toorisaka, Makoto Hirata, Soon-An Ong, Tadashi Hano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25773

Abnstract:In recent years, solar receivers have been employed in several applications where high temperature fluids are involved, such aspower plants and solar thermal reactor. The possible presence of high temperature gradients could determine reduced receiverefficiency and a short life of the material. Thermal and fluid dynamic analysis of the receiver allows to highlight possible presenceof temperature gradients and to evaluate their values and the more critical zone of the material. Compress...
Autori: Alina Adriana Minea, Oronzio Manca, Salvatore Tamburrino, Sergio Nardini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25779

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Recovery of residual ammonium nitrogen (NH4+-N) from dissolved air flotation (DAF) pretreated poultry slaughterhouse wastewater was studied by means of magnesium ammonium phosphate hexahydrate (MgNH4PO4.6H2O, MAP) precipitation in a lab-scale batch study. The maximum recovery values were obtained as 80.2%, 97.1% and 53.6% with the addition of MgCl2.6H2O + KH2PO4, NaH2PO4.2H2O + MgSO4.7H2O, and MgOHCO3 + 85% H3PO4 at pH 9.5, respectively. Based on the physicochemical findings, subsequent...
Autori: Aylin Gunay, Idil Ozis, Ilter Turkdogan-Aydinol, Kaan Yetilmezsoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25797

Abstract:Coconut coir pith, an agricultural solid waste was used for the sorption of Cd (II) from aqueous solution in batch mode. Parameters like contact time, adsorbent dosage and pH effect were studied. Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data and the system followed both the isotherms. Cd (II) adsorption capacity of coir pith was found to be 18.72 mg/g. Kinetic parameters of adsorption such as the Langergren pseudo-first-order, pseudo second order r...
Autori: Nagendra Badabhagni, Puthiya Veetil Nidheesh, Rajan Gandhimathi, Srikrishnaperumal Thanga Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25800

Abstract:The effect of organic carbon loadings (OCLs) on NH4+-N and Mn2+ removal was investigated using a novel approach of biological aerated filter (BAF) for drinking water treatment system. Three different OCLs of 0.2, 0.5 and 1.0 kg COD/m3.d were loaded into BAF which was operated in batch-wise at 24 h hydraulic retention time. The experiments resulted in higher COD, NH4+-N and Mn2+ removal percentages at OCL of 1.0 kg COD/m3.d with removal of 97.1%, 97.4% and 94.7%, respectively. The +-N ef...
Autori: Hassimi Abu Hasan, Noorhisham Tan Kofli, Siti Kartom Kamarudin, Siti Rozaimah Sheikh Abdullah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25808

Abstract:The aim of the present study is the optimization of biosorption conditions using a metal tolerant actinomycete (strain 723) for the removal of lead ions from waste water in batch and dynamic flow mode. The optimum conditions for lead biosorption by the strain were determined as initial pH 3.0, biomass amount 2.0 g L-1, and initial metal concentration 400 mg L-1 in the batch condition. The maximum lead biosorption performance was obtained with a 19 mm diameter column, a 1 mL min-1 flow r...
Autori: Ayşe Betül Karaduman, Maria Julia Amoroso, Mustafa Yamaç, Sergio Antonio Cuozzo, Zerrin Pat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25811

The removal of Cr (VI) from aqueous solutions by sphagnum peat moss was investigated in batch experiments as a function of solution pH and initial Cr (VI) concentration. The highest removal percentage (R=99%) was obtained at pH = 1, in solutions of 20.8 mg Cr (VI)/L. In order to establish the mechanism of the removal process, Cr (VI) and total Cr (Cr (VI) + Cr (III)) in residual solutions was analyzed. The Cr (VI) removal by the peat moss at low pH is governed by two processes – electrostatic ...
Autori: Catalin Balan, Doina Bilba, Irina Volf, Matei Macoveanu, Petru Bulai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25849

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

This paper presents a new photo-Fenton procedure applied in oxidative degradation of organic pollutants using 4-chlorophenol (4-CP) as low biodegradable testing compound. The homogeneous photo-Fenton process was modified by using a photo-catalytic reactor equipped with a steel wire mesh which acts as source for Fe2+ catalyst generation into reaction medium and as heterogeneous catalyst, by iron oxy-hydroxyl compounds formation on the surface. The oxidation process was evaluated by measuring the ...
Autori: Adina-Elena Segneanu, Cristina Orbeci, Ion Untea, Mihaela Emanuela Craciun, Rodica Stanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25864

Chromium and cadmium are heavy metals that occur naturally in the environment and especially in soils. Their toxic effect is more pronounced at high concentrations and it depends on the oxidation states. While Cr (III) is considered an essential trace element for the metabolism of living organisms, Cr (VI) has a higher mobility and is easily soluble in soils and can be leached into surface water or groundwater, and taken up by plants. That leads to a toxic and carcinogenic effect to humans via i...
Autori: Dumitru Bulgariu, Florian Statescu, Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25866

Among the different types of waste products tested, the bark of different Pinus species have been identified as a promising class of low- cost sorbents for heavy metal binding. In this context, the potential of Romanian pine bark wastes as green and economical sorbent for cadmium (II) ions removal from aqueous solutions has been tested in batch conditions as function of initial pH, contact time, sorbent dose, metal ion concentration and temperature. The equilibrium data at three different temper...
Autori: Anca Miron, Brindusa Robu, Carmen Paduraru, Lavinia Tofan, Roxana Laura Mihailescu Amalinei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25871

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

Two experimental periods have been undertaken to investigate the biodegradability of sewage streams (mainly regarding the organic substances) produced by a gas cartridge production, filling and distribution company. A sequencing batch reactor (SBR) was used for the laboratory examinations launched with municipal sewage sludge with a concentration of approx. 3 g MLSS/L. The various conditions in the reactors followed each other cyclically (fill, anoxic, aerobic, settle, draw) three times a day. T...
Autori: Bence Fazekas, Karoly Reich, Krisztian Varga, Viktoria Pitas, Viola Somogyi, Zsuzsanna Banyai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25902

Abstract Effects of the aeration rate on nutrient removal from synthetic domestic wastewater using an intermittently aerated sequencing batch reactor (IASBR) were studied at ambient temperature. Two aeration rates, 0.8 and 1 L air/min, were studied. At the aeration-rate of 0.8 L air/min, removals of COD, NH4+-N, total nitrogen (TN) and PO43--P were 84%, 96%, 75% and 99%, respectively. At the aeration rate of 1 L air/min, removals of COD, NH4+-N, TN and PO43--P were 90%, 99%, 70% and 66%, re...
Autori: Liam G. Henry, Liwen Xiao, Xinmin Zhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25941

Abstract A one-stage aerobic moving bed biofilm reactor (MBBR) (Reactor A) and a combined reactor (Reactor B) involving an anoxicgravel-bed biofilm reactor (GBBR) and an aerobic MBBR were applied to the treatment of heavily polluted river water. Reactorperformance was investigated throughout the experiment for almost 200 days and molecular techniques including PCR-DGGE,FISH/CLSM and FISH/FCM were used to reveal the evolutions of bacteria community, abundance of nitrifying bacteria and their...
Autori: Linyun Gu, Xiangchun Quan, Yin Qian, Yuansheng Pei, Zhifeng Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25942

Abstract An activated sludge from SBBR (sequencing biofilm batch reactor) reactor filled with Fe0  as filler had been acclimated to Fe(III)rich environment aiming at secure an enrichment culture of iron-reducing bacteria. The dissimilatory Fe(III) reduction ability and its efficiency on the effect of nitrogen and phosphorous removal by dosing different Fe(III) under anaerobic condition were investigated. The mechanism was also proposed based on the results derived from the experiment a...
Autori: Jie Li, Juanjuan Feng, Siyuan Zhai, Ya’e Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25943

AbstractWastewater from butyl rubber production is causing an increasing environmental problem due to its large quantity and complexquality. In this paper, two types of wastewaters generated from rubber synthesis, i.e. alkaline wastewater (AW) and cleaning andflushing wastewater (CFW), were investigated. Coagulation and flocculation were firstly applied to remove suspended solids(SS) from the AW. By single factor experiment, the optimum operational conditions were obtained as pH 8, PAC dosage 40...
Autori: Lujun Chen, Rui Liu, Wei Li, Wei Zheng, Yan Zhang, Ying Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25950

AbstractThis paper reports the effects of COD:sulfate ratio on sulfate removal and electricity generation from oil shale retort watertreatment using microbial fuel cells (MFCs). Field-collected retort water was augmented with organics to obtain a range of initialCOD:SO42- ratios (0.5:1 to 2:1), and treated in two different MFC designs (tubular and two-chambered). The two-chamberedMFCs exhibited COD and sulfate removal 1 to 2 orders of magnitude higher than those of the tubular MFCs. The tubular ...
Autori: Ho Il Park, Lian-Shin Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25954

AbstractIn this paper integrated network of continuous reactors for the decontamination of gaseous flows in heterogeneouscatalytic gas-liquid-solid – also applicable for bioremediation systems is investigated. For this purpose, duringprocess integration we have identified strategies to develop an optimal system for a variety of well-definedrequirements and to discover ways to ensure cost efficiency to achieve the requirements of sustainable industry in theframe of knowledge-based sustainable eco...
Autori: Maria Gavrilescu, Oana Marlena Penciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25977

The first edition of the International Conference„ECOIMPULS 2012- Environmental Research andTechnology” plans to open a conference seriesdedicated exclusively environmental issues. Thescientific topics are devoted to the on-going research onenvironmental topics regarding: „Environment – apolitical, economic and social responsibility”,„Water in a changing world”, „ZERO – waste cities”and „ Energy – beyond the conventional”.This scientific event aims to bring togetherprofessionals, academics, scie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26015

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe performance of two cation exchanger resins, Amberjet UP1400 and Amberlite IR120 in the process of Cs(I) ions removalfrom aqueous solutions was examined. Batch experiments were carried out to determine the influence of several parameters(resin dosage, contact time, temperature and initial concentration of Cs(I) ions) on the removal process. The equilibrium wasreached after 60 min for Amberlite IR120 and after 120 min for Amberjet UP1400, with an overall adsorption performance of~97% f...
Autori: Adina Negrea, Cornelia Muntean, Corneliu Mircea Davidescu, , Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26032

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractA new approach to environmental protection management is the aerobic microbial digestion of food industry wastewaters byusing those waters as substrate, while the pollutants contained work also as oxygen-vectors. In biotechnology, oxygen masstransfer is a key parameter involved in the design and operation of mixing–sparging bioreactors and it can be analyzed by meansof the oxygen mass transfer coefficient (kLa). The influence of a second liquid phase with higher oxygen affinity (in this ...
Autori: Elena Folescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26097

AbstractThere are a quite large number of studies published in the last decade, dealing with the possible pass of the human society to thehydrogen-based energy. The efforts made by researchers all around the world, in order to bring technical solutions, seemremarkable, but at global level only minor progresses were made toward this major change. Furthermore, most of studiespredicted a fuel crisis, but not a possible economical crisis with significant effects on the developing renewable energytec...
Autori: Ştefan Stanciugelu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26099

Abstract Recently, a new failure probability index was introduced that characterizes the operation of highly sensitive chemical reactors (i.e. when highly exothermic / hazardous reactions are conducted). Based on this, the current paper exemplifies the application of the risk analysis methodology proposed to generate the Pareto optimal operating solutions accounting for reactor productivity maximization (product yield) and probabilistic risk minimization. The multi-objective optimi...
Autori: Anca Dan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26108

Abstract The reason for carrying out this research is related to the significant risk of heavy metals present in wastewater on the environment and human health. The removal of heavy metal ions from aqueous solutions was performed in a batch system, using peat (from Poiana Stampei, Romania) as adsorbent. The efficiency of the process was predicted with high accuracy (correlation with experimental data more than 0.99) based on a feed-forward neural network with two hidden layers. The...
Autori: Gabriel Dan Suditu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26150

Abstract The biosorption of Pb(II) and Cd(II) ions from aqueous solution on marine green algae biomass (Ulva lactuca sp.) was studied in batch systems, at initial solution pH of 5.0 and biomass dose of 8.0 g/L, considered as optimum experimental conditions. The obtained results from experiments of a single-component biosorption were analyzed using Langmuir, Freundlich and Dubinin- Radushkevich isotherm models. The Langmuir equation describe the biosorption isotherm of Pb(II) and Cd...
Autori: Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26152

AbstractIn the conventional water flooding process of Daqing Oilfield in China, the occurrence of abundant sulfate-reducing bacterialpopulations has substantially affected the industrial production. This study was conducted from the perspective of ecologicalsuppression by operating anaerobic ABR reactors and dosing ecological inhibitors in a continuous-flow experiment. The practicaloperating efficacy was investigated and associated dynamic bacterial population succession was analyzed. Results sh...
Autori: Bin-song Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26165

AbstractA wet flue gas desulfurization (WFGD) system adopting electrostatically-assited twin-fluid atomization injector was presented.Spatial distributions of the droplet sizes, velocity for different voltages were measured using limewater and SO2 removalefficiency for different voltages and Ca/S ratios were tested using limewater drops. The physical and chemical improvementmechanisms were analyzed using spray characteristics and double film theory. The analysis showed that electrostatically-ass...
Autori: Zhentao Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26175

AbstractExcess biomass produced in the degradation processes of organic pollutants is creating environmental challenges for wastewatertreatment plants. The A+OSA system, a modification of the anoxic / oxic (A/O) process via insertion of a sludge holding tankinto a sludge return line, has been demonstrated to be capable of achieving simultaneous nutrient removal and sludge reduction.Here we report the results of an investigation aimed at evaluating the impact of the sludge holding tank on the bio...
Autori: Li Jia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26207

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractIn this article, hydrodynamic parameters and overall Oxygen mass transfer coefficient of petroleum based micro-emulsions in anairlift reactor were investigated. Four different petroleum-in-water micro-emulsion systems containing kerosene, heavy naphtha,light naphtha and diesel as oil based were used with concentrations of 3% and 7 % (v/v). The experimental data were supportedby simulation results obtained from the Computational Fluid Dynamics (CFD) method. The CFD was properly able to si...
Autori: Mostafa Keshavarz Moraveji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26234

AbstractIn this work, a four factor three-level Box–Behnken factorial design based on response surface methodology (RSM) wasemployed to optimize the removal of phosphate from synthetic wastewater (mineral salts medium-MSM) by the bacterialconsortium (Bacillus sp. RS-1, Pseudomonas sp. YLW-7, Enterobacter sp. KLW-2). A mathematical model was then developedto show the effect of each medium composition and their interactions on phosphate removal. The effect of the lactoseconcentration (X1), pH (X2)...
Autori: Krishnaswamy Usharani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26235

AbstractThe aims of this study were to investigate the performance of anaerobic up-flow column reactor (AUFCR) and immobilizedactivated sludge biomass (ASB) potential for the adsorption of dye drimarene Blue-K2RL (Db-K2RL) and removal of chemicaloxygen demand (COD) from textile wastewater (TWW). AUFCR with ASB at flow rate of 50 mL h-1 and hydraulic retentiontime (HRT) of 10 h showed 95% dye adsorption at pH 4 and 87% COD reduction at pH 6 while non-activated sludge (NAS)showed only 60% of adsor...
Autori: Anwar Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26246

AbstractThe aim of this study is to evaluate the treatment performance of mono azo dye Methyl Orange (MO)-containing wastewater byrecirculated up-flow constructed wetland (UFCW) with and without supplementary aeration. The successive anaerobic andaerobic treatment of the UFCW reactors could effectively remove color, organic matters and intermediate aromatic aminessimultaneously in a single reactor. With influent 50 mg/L of MO, the removal efficiencies of COD and MO were 91 and 75 %,respectively,...
Autori: Soon-An Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26254

AbstractA bench-scale anaerobic bioreactor for the anaerobic treatment of textile wastewater using anaerobic sludge was experimented.The Top and bottom of hybrid bioreactor were functioned with UAF (Up Flow Anaerobic Filter) and UASB (Up Flow AnaerobicSludge Blanket), respectively. The effect of organic loading rate (OLR) and hydraulic retention time (HRT) on treatment oforganic matters in the textile wastewater was investigated. The maximum removal of chemical oxygen demand (COD) and colorwas 9...
Autori: Reza Katal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26255

AbstractThis study is focused on simulating and optimizing design and configuration of anaerobic baffled reactor (ABR) by means ofartificial neural network (ANN). This approach is aimed to assess an efficient ABR performance in various operational conditionstreating municipal wastewater. For this purpose, to analyze comprehensively on a base of experimental data, the system isoperated in two pilots of 48 liters net volume made of 8 compartments. In 7 months, more than 130 sets of data are obtain...
Autori: Gagik Badalians Gholikandi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26260

AbstractA novel RHA/PFA/CFA sorbent was developed by sol-gel method using three types of ashes, i.e. rice husk ash (RHA), palm oilfuel ash (PFA) and coal fly ash. From surface analysis of selected RHA/PFA/CFA sorbents, the spent sorbent had more compactstructures covered by irregular rough surface and the specific structure of raw RHA, PFA, and CFA were no longer visible. Inaddition, lower specific surface area was obtained for spent RHA/PFA/CFA sorbent. Batch studies were performed to evaluatet...
Autori: Irvan Dahlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26272

AbstractThe extent of the problem of the excessive fluoride in drinking water remains an important health issue. In the present work,strong-base anion resins were investigated to assess their sorptive removal capacity of fluoride from water. It was found that theremoval of fluoride was high at natural pH (7) and was improved for increasing contact time and adsorbent dosage. Themaximum sorption of the resin was 13.7 mg/g according to the Langmuir model, namely higher than the values reported in t...
Autori: Mohammad Taghi Samadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26273

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractHexavalent chromium can contaminate drinking water resources and should therefore be removed from industrial waste effluents. The use of ion exchange resin was examined in batch tests to remove Cr (VI) from acidic solution by Amberlite IRA 410. Equilibrium data were analyzed and modelled using Freundlich and Langmuir adsorption isotherms and the results showed that the adsorption behaviour of Cr (VI) could be accurately described by means of a Langmuir model. The monolayer adsorption cap...
Autori: Abdeltif Amrane, Aicha Bensmaili, Malika Chabani, Yasmine Ait Ouaissa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26289

AbstractAerobic granulation is a novel biotechnique for the treatment of coloured wastewater containing toxic xenobiotics in sequencingbatch reactor (SBR). The aerobic granules were investigated as a potential biomaterial for biodegradation of p-nitrophenol. Theremoval efficiency of p-nitrophenol was 93 % after 65 days of operation at 8 hr hydraulic retention time (HRT). The aerobicgranules were cultivated at a p-nitrophenol loading rate of 0.9 kg m-3 day-1, with sodium acetate as co-substrate t...
Autori: Pijush Kanti Mondal, Rais Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26302

AbstractA new cell design which makes an efficient use of the cathodically evolved H2 to improve the mixing efficiency and thefloatation ability during electrocoagulation was used to remove dyes from waste solution. In this study, the decolorization andCOD reduction of colored solutions containing reactive and basic dyes by electrocoagulation was investigated using aluminumelectrodes in a batch mode. The effect of operating parameters such as current density, initial dye concentration, NaClconce...
Autori: El Sayed Zakaria El Ashtoukhy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26303

AbstractIn the present study, batch adsorption experiments were performed for the removal of methylene blue (MB) dye from its aqueoussolution using newly prepared surface modified cashew nut shell (SMCNS) by varying the operating parameters like solution pH,adsorbent dose, initial dye concentration, contact time and temperature. The SMCNS has been prepared by treating the cashewnut shell with the sulphuric acid. Adsorption equilibrium data were analyzed by the model equations such as Langmuir,Fr...
Autori: Krishnan Gayathri Lashmi, Muthukumar Priyadharshini, Ponnusamy Senthil Kumar, Ramasundaram Vijayakumar Abhinaya, Subramanian Sivanesan, Vishwanathan Arthi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26309

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractIn this work, the effect of the addition of some nutrients on fungal growth and removal of Cr(III) were investigated. Theconsidered fungi, isolated from real tanning factory environment were Phanerochaete chrysosporium, Aspergillus niger and A.oryzae. Firstly, the optimal conditions for fungal growth were determined as a function of pH, contact time, temperature andagitation speed. Secondly, the effect of the addition of some nutrients on fungal growth was examined. Without the addition ...
Autori: Abdeltif Amrane, Mansur Zarrabi, Mohammad Noori Sepehr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26337

AbstractGuazuma ulmifolia seeds activated carbon was modified by sulphuric acid to enhance the adsorption capacity for Cu(II) ions.This modified activated carbon produced from Guazuma ulmifolia seeds (GUAC) was investigated by observing the changes inits characteristics and the Cu(II) adsorption behavior. The prepared GUAC was characterized by BET, FTIR and SEM analysis.The kinetic data were analyzed using four adsorption kinetic models: the pseudo-first and pseudo-second order equations,intrapa...
Autori: Muthukumar Priyadharshini, Palanichamy Baskaralingam, Palanichamy RajKumar, Ponnusamy Senthil Kumar, Selvaraj Dinesh Kirupha, Subramanian Sivanesan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26344

AbstractAmmonia pollution occurs frequently in urban water networks, which threatens the safety of water supply systems. Zeolite can beused for the removal of ammonium in the pretreatment of raw water for its peculiar adsorptive property to ammonium, but a largeamount of sludge from this measure could be a significant pollution source. In this work, the dewatering performance ofprecipitated sludge from the pretreatment of micro-polluted raw water was studied. Batch experiments of the simulatedco...
Autori: Bairong Zhu, Hao Chen, Huaizheng Li, Zhenliang Liao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26355

AbstractCatalytic wet oxidation (CWO) of phenol was studied in the present work. The effect of liquid hourly space velocity (LHSV),superficial gas velocity, reactor pressure, temperature and initial phenol concentration on phenols removal was investigated.Results showed that phenol conversion increased with increasing reaction temperature, reactor pressure, and superficial gasvelocity of oxygen, yet it decreased with increasing (LHSV). The results exhibited that the highest phenol conversion of(...
Autori: Farah T. Jasim, Luma S. Ahmed, Mohammad F. Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26381

AbstractThe industrial development, the demographic growth and the limitation of the natural regions have determined a continuousdegradation of the water quality due to high concentrations and complexity of pollutants from the wastewater. The centralizedand decentralized treatment systems apply treatment procedures and techniques which can be complementary in solving theenvironmental pollution problems due to wastewater. In the present paper a three-dimensional mathematical model waselaborated b...
Autori: Narcis Barsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26422

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractA lab-scale packed-bed biofilm channel reactor that operates as a plug-flow system equipped with top aeration modules wasconstructed and evaluated. To assess the reactor performance a microbial community able to degrade linuron was used. Changingthe fluid flow rates and the linuron concentrations in the inflowing medium the volumetric loading rates of linuron (BV,L) weregradually increased from 0.29 to 14.93 mg/Lh. During the operation of the reactor, an airflow rate of 0.15 ą 0.05 L/min...
Autori: Erick Marrón-Montiel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26465

AbstractThis work presents an original method and an automated installation to recover by combustion the waste gas obtained in theignition process of xylites in rotary kiln. The flue gas resulting from the combustion of waste gas, with light fuel support areused in the technological processes of obtaining activated carbon, satisfying the conditions where the oxygen content does notexceed 0.3 % vol. and the temperature is above 1200°C, conditions imposed by the Project Manager of the European pro...
Autori: Aurel Gaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26461

AbstractIn this study a new generation of plate-type laboratory air treatment biofilter is applied for the removal of gaseous contaminantsfrom air. The packing material for the biofilter consists of porous plates arranged vertically one after the other to produce acapillary humidification effect. The porous plate is made of polymer to secure the stiffness of the plate. Birch fibre granulesthermally treated in a steam explosion reactor are fixed on both sides of the polymer board. The granules ar...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26480

AbstractThe paper presents a hybrid method for the advanced removal of low biodegradable organic compounds from water, bycombining the separation selectivity of the membrane with the oxidation efficiency of the photocatalytic process. The aim of thisstudy is to evaluate the performance of the hybrid method to remove toxic compounds from wastewater. The advanced oxidationprocess, based on a photocatalytic reactor with continuous recirculation, ultraviolet (UV) radiations and a membrane, was usedf...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26490

AbstractThe Hungarian Parliament’s Decision 25/2009 (IV.2.) gave the approval to start preparatory activities for establishing newreactors on-site at Paks Nuclear Power Plant. Furthermore, Hungary ratified a treaty with the Russian Federation, signed inMoscow on January 14, 2014, for cooperation in the peaceful use of nuclear energy. Through these activities, Hungary has madeits commitment to nuclear energy clear. In this article, we attempt to prove that neither the law of the European Union, n...
Autori: László Fodor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26533

AbstractAnaerobic degradation (AD) of municipal solid waste (MSW) depends on the moisture and nutrient distribution within thebioreactor; these factors are affected by leachate recirculation. In this work, the effects of leachate recirculation of 15 to 120 byvolume percentage (%V) on AD were studied. The ojectives of this study are as follows: a) to determine which recirculation rateprovides the best conditions for accelerated anaerobic degradation (AD) and b) to determine the optimal range of r...
Autori: Maria del Consuelo Hernández-Berriel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26557

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractThe distribution of mixing time for a split-cylinder gas-lift bioreactor has been investigated for simulated broths with apparentviscosities up to 26 cP. The results indicated important variation of mixing time on the height of riser or downcomer, as well asdifferent behavior of dispersion flows in the two regions. Thus, the highest mixing efficiency for the ascending circulation hasbeen recorded for the intermediary positions, placed above the sparger. Contrary, for the downcomer, the i...
Autori: Anca-Irina Galaction
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26560

AbstractPresent study was envisaged to study chelators-metal interaction in phytoaccumulation of metals as a bioremediation technologyto decontaminate metal pollution and adsorption of metals on soil. Lactuca sativa was used as model plant for phytoaccumulationto identify uptake of Cadmium (Cd) and Lead (Pb) and their subsequent accumulation in edible tissue of plant. Cadmium andlead were two selected metals for phytoaccumulation and copper was also studied for adsorption experiment. Green house...
Autori: Audil Rashid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26568

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract The biological removal of organic matter from a cosmetic wastewater by sequencing batch reactors has been optimized by analyzing the influence of the hydraulic retention time as well as the inclusion of anoxic and/or aerobic stages in the process sequence. Hydraulic retention time of 5 d led to the highest total organic carbon and chemical oxygen demand removal regardless the sequence used. Although a completely aerobic sequence can be used for cosmetic wastewaters treatment, the al...
Autori: Montserrat Tobajas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26589

Abstract This study evaluates the potential of Crambe abyssinica press cake, a residue from crambe oil extraction and/or biodiesel production, as an adsorbent for removal of cationic dyes from wastewaters. Batch adsorption tests were performed at 30, 40 and 50oC. Adsorption kinetics and equilibrium were satisfactorily described by the pseudo second-order and Freundlich models, respectively. Adsorption was spontaneous and exothermic. Fixed bed adsorption (breakthrough curve) was satisfactoril...
Autori: Adriana S. Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26597

Abstract Due to its very low moisture content, the solid waste from the two-phase olive oil extraction process (dry olive mill residue, DOR) can be easily stored and used as a readily available basal liquid culture medium via its reconstitution with water. Five white-rot fungi (namely Phanerochaete chrysosporium NRRL 6361, Lentinus tigrinus CBS 577.79, Pleurotus pulmonarius CBS 664.97, Phlebia radiata DABAC 9 and Botryosphaeria rhodina DABAC P82), previously selected in a screening program, ...
Autori: Alessandro D’Annibale
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26598

Abstract This article covers the investigation of the catalyst waste (T.R.M 1 and T.R.M 2) produced in the reactor of oil catalytic cracking. The analysis of this waste was carried out. The properties of T.R.M 1 and T.R.M 2 were investigated and determined, the mineralogical analysis of catalyst waste was implemented, the analysis of thermal effects during the burning was performed. Catalyst waste materials investigated were used in a ceramic system (from 7  to 20  of the ove...
Autori: Olga Kizinievič
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26600

Abstract The objective of this study is to develop a mathematical model which would confidently predict the rate of substrate degradation of an oil-water emulsion in a laboratory-scale completely-mixed continuous flow reactor using the photo-Fenton treatment process. Two models are developed from first principles and the predicted substrate removal rates for both models are compared with experimental data. The principal conclusions of the study are that both models produce good correlations ...
Autori: Maha A. Tony
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26613

Abstract The present study deals with the removal of Cr (VI) from aqueous solution by polypyrrole (PPy). Response surface methodology (RSM) was applied for the design and analysis of experiments in the optimization of pH, temperature, initial concentration, contact time and adsorbent dose during the removal of the Cr (VI). The optimum adsorbent dose, temperature, initial concentration of Cr (VI), pH and contact time were found to be 0.8 g, 46.5 oC, 187.5 mg/L, 5.3 and 15.4 min respectively. ...
Autori: Ehsan Hasani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26614

Abstract Malathion is a toxic, wide-spectrum organophosphorus pesticide. The removal of this pesticide from water is one of the major environmental concerns. In this study, the biodegradation of malathion using batch activated sludge was studied. The effect of initial malathion concentration (5 to 140 mg/L) on the degradation process was investigated. The biokinetic parameters (rs max, Ks and Ki) were estimated. Identification of dominant bacterial flora was also achieved. In addition, two k...
Autori: Djaber Tazdaďt
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26625

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract 18F-FDG is a glucose analog in which the hydroxyl group on the second carbon is substituted with 18F, being used as an indicator of glucose uptake and cell viability. The aim of this work was to synthesize the 18F-FDG and to validate the methodology for the assessment of its both radiochemical and chemical purities, according to the European Pharmacopoeia. The proposed methodology encompasses three chromatographic methods: radio-HPLC, radio-TLC and HS/GC. Radiochemical impurities ...
Autori: Mirela Mihon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26640

Abstract The caraway (Carum carvi L.) samples were collected from little meadows situated in Harghita Mountain (Mădăraş Ciuc, Harghita Băi, Jigodin, Tuşnadu Nou), where a relatively small area was covered by a group of rich populations of wild cumin. The harvested plants are dried by: a) convective laboratory dryer in thick layer, b) static outdoors in sunshine, and (c) static in a warm indoor place in darkness. The hand-picked seeds were separated from debris by sie...
Autori: Csaba Dezső András
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26646

Abstract The oxygen transfer into the fermentation broths could be improved in presence of oxygen-vectors, without intensification of mixing or aeration. The experimental results for simulated, P. shermanii and S. cerevisiae broths indicated the significant increase of kLa, by adding n-dodecane, but the magnitude of this effect depends especially on the cells affinity for hydrocarbon droplets. Therefore, due to the higher affinity of yeasts cells for hydrocarbon droplets during their entire ...
Autori: Anca Irina Galaction
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26657

Abstract The development of biodiesel industry in the recent past brought into discussion the valorization of glycerol as the byproduct of this technology. Dehydration of glycerol leads to acrolein, mainly used as a raw material in the production of acrylic acid and its esters. Several research efforts dealing with the synthesis of acrolein from glycerol are reported in the literature. However, they are limited to catalyst testing on laboratory scale, no attention being paid to the process f...
Autori: Ionut Banu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26666

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract The performance of electrocoagulation (EC) process, a non-specific electrochemical technology, was investigated for the removal of carbamazepine (CBZ), an antiepileptic drug, from water. Experiments were carried out in synthetic wastewater in a batch cell. The respective influences of some key process parameters were studied, such as mixing conditions, initial pH, and current on aluminium electrodes. Experimental results showed that a CBZ removal efficiency of 62% was observed under...
Autori: Tania Yehya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26683

Abstract The adaptation of commercially available ion-selective electrodes (ISEs) for use in wastewater matrices was demonstrated using multivariate analysis and optimization with the Microsoft Excel Solver tool. The electrodes were characterized in pure analyte solutions, and their parameters were estimated using multivariate analysis and Solver optimization. The ammonium, nitrate, and nitrite ions were measured in model systems that were designed to simulate wastewater. The accuracy of the...
Autori: Natalija Koprivanac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26687

Abstract Adsorption has proved to be an excellent way to treat industrial wastewater, due to its significant advantages like easy availability, inexpensive, ease of operation and highly efficient, compared to conventional expensive adsorbents like activated charcoal, alumina etc. The present investigation focused on utilization of Mangifera indica seed shell substrate for the removal of toxic heavy metals like Fe(II) and Mn(II) from wastewater. Mangifera indica seed shell substrate as an eff...
Autori: Tikaram D. Kose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26713

Abstract Locally sourced clay from Kuala-Kangsar town in Perak state Malaysia was used in both its raw (RKKC) and modified (MKKC) form as adsorbents for the removal of methylene blue (MB) from synthetic textile wastewater in batch adsorption process. The raw clay was modified through H2SO4 acid treatment, Al(OH)3 ion exchange, calcinations and then molded into beads before freeze drying. The BET surface areas of RKKC and MKKC were 11 and 100 m2/g, respectively; their elemental analysis and ...
Autori: Manase Auta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26717

Abstract Chitosan was cross linked with gluteraldehyde and chemically modified by introducing xanthate group onto its backbone using carbon disulfide under alkaline conditions. This crosslinked xanthated chitosan flakes (XC) was used as an adsorbent for the removal of mercury ions from contaminated water streams near the coal mines. XC was found to be far more efficient than the conventionally used adsorbent activated carbon. FTIR studies indicated the interaction both amine and the xanthate...
Autori: Avinash Gupta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26725

Abstract Large quantities of snail and clam shells are left as waste material when their meat is used as food for people. It has been a big problem that how to treat these wastes and usually these are land filled as wastes. In the present paper, these shells are studied as recycling resource for phosphate removal from solutions. Laboratory-scale batch experiments were conducted to evaluate the efficiency of snail and clam shells in removing phosphate from aqueous solutions. Major factors inv...
Autori: Ji Bing Xiong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26727

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract In paper processes, the variability of effluent composition and flow is impossible to predict and generally depends on the type of production method used and the manufacturing breakdowns suffered. Wastewater treatment plant operators find it difficult to maintain the efficiency of biological treatment processes. This paper focuses on activated sludge treatment modelling of paper mill wastewater to provide operators with additional support. Based on both standard activated sludge mod...
Autori: Catherine Cadet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26732

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract Thermophilic anaerobic digestion is a suitable technology to treat agricultural waste because of its higher biogas production, hygienisation effect and solids removal efficiency. Although these benefits, poor effluent quality and instability are encountered in some cases. The anaerobic co-digestion of winery waste and waste activated sludge at 55°C, operating at 23 days HRT and with an organic loading rate of 3.2 kg COD/m3d, was characterized by accumulation of volatile fatty ac...
Autori: Cinzia Da Ros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26775

Abstract The Bio.Lea.R project aims to demonstrate the performance of a landfill for less reactive, biologically treated waste (pretreated organic wastes) compared to a conventionally managed landfill, with regard to both environmental (biogas and leachate production) and economic aspects. The objective is to control the pretreated biodegradable waste through a liquid injection in order to achieve the same biogas quantity in a shorter time than in conventional landfill. Laboratory and full ...
Autori: Alberto Godio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26784

Abstract The use of non-conventional water resources including treated municipal wastewater has been increasing in the Mediterranean regions over the last decades to cope with water shortages and uneven rainfalls due to climate change. The aim of this paper is to present the first results from two years of experimental field activities carried out in two different demo-places in Southern Italy: the municipal wastewater treatment plants of Noci and Castellana Grotte (Apulia region). In these ...
Autori: Antonio Lonigro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26787

Abstract Treatment experiments for mature landfill leachate were conducted by using combined aged refuse bioreactor (ARB) process and sulfate radical oxidation. In the ARB process, the effects of wet/dry ratios, hydraulic loading, and influent introduction time on contaminant removal were investigated. In the oxidation process, Na2S2O8 was activated by heat to generate powerful oxidants, such as sulfate radicals, to oxide residual contaminants in the effluent. The removal of chemical oxygen ...
Autori: Zhanmeng Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26818

Abstract Drying wood requires a significant amount of energy. This includes both thermal energy, necessary to heat-up wood, evaporate the water inside it and cover the insulation and vent losses, as well as electric energy consumed to force air circulation through the stacks. When wood is frozen, both energy consumptions increase; on one hand because frozen water requires a supplementary heat for transformation into liquid and then into gaseous state, and on the other hand, because of the lo...
Autori: Maria Bernadett Szmutku
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26841

Abstract This study investigated the use of tea waste to decolorize refractory dyestuff from textile wastewater. The influence of the solution pH and the contacting time were examined for various adsorbents, namely green tea-leaf powder (GTP), black tea-leaf powder (BTP), and powdered activated carbon (PAC). Results from batch experiments revealed that the reduction in true color (ADMI) increases with decreasing pH. The ADMI reduced from 1106 to 150 with 0.8 g/L of GTP at pH 2. The results a...
Autori: Chih-Huang Weng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26863

Abstract A study of a classical BLEVE fireball model associated with a toxic Puff release one was made in order to evaluate the influence of accident conjugate conditions on its consequences in two neighbouring industrial plants. The possible occurrence of the Domino effect is also exemplified for the approached chemical complex including two sensitive neighbouring chemical plants including tubular reactors for catalytic oxidation of butane to maleic anhydride and catalytic hydrogenation of ...
Autori: Hasan Hadi Salman Khwayyir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26880

Abstract Safe operation of highly thermally sensitive industrial reactors is still considered a major issue in chemical engineering practice. The problem becomes even more stringent when highly exothermic reactions are conducted under randomly fluctuating operating variables, and especially when the set-point is located in a close vicinity of the runaway boundaries for increasing the reactor productivity. This study is aiming to derive the runaway boundaries and their associated region of co...
Autori: Constantin Muscalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26884

Abstract The results of batch tests of anaerobic dechlorination on groundwater samples collected downgradient from an industrial site in Northern Italy are presented and discussed. The experiments were carried out using sucrose as electron donor at equimolar concentration and at selected excess with respect to the total reducible species. The purpose of the study was to investigate the effectiveness of sucrose to achieve a complete chlorinated solvents degradations at the specific site, and ...
Autori: Luca Di Palma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26895

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

Abstract This study investigated the feasibility of electrocoagulation (EC) process on the treatment of palm oil mill effluent (POME). The effect of several parameters namely initial pH, current density, stirring speed and operating time on removal efficiency of total suspended solids (TSS) and chemical oxygen demand (COD) were investigated. The experiments were conducted batch wise using 400 mL of the POME per batch and pair of aluminum electrodes immersed in the reactor. At optimal initial...
Autori: Firdaus Ghazali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26914

As the serious effect of climate change and global warming is recognized, nitrous oxide (N2O) emission during wastewater treatment is receiving lots of attention due to its high potential to greenhouse effect. In this study, nitrifiers were acclimated in sequencing batch reactors with influent ammonium nitrogen (NH4-N) concentrations of 60 mg/L (SBR60) and 180 mg/L (SBR180), respectively. Nitrous oxide emission during nitrification was examined in both typical cycles and batch experiments. T...
Autori: Enge Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26926

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

Moving bed biofilm reactor (MBBR) technique is a useful technology for the treatment of mature landfill leachate. The reactor start-up and acclimation processes illustrated that many factors, such as biomass, C/N ratio, and influent volumetric loading rates, could affect the ammonium-nitrogen (NH4+–N) and COD removal. The factorial experiments were carried out to determine the optimal reactor operational conditions, and the results demonstrated that when DO 2-4 mg/L, pH 7.5, and hydraul...
Autori: Wei Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26932

The pickling liquor used in the stainless steel manufacturing process is a mixture of nitric and hydrofluoric acid which generates wastewater with nitrate concentrations ranging between 500 and 6000 mgNO3--N/L. In the present study, laboratory-scale anoxic Sequencing Batch Reactors (SBRs) were used to treat high nitrate wastewaters. Two different sludge inocula were tested: one from a Municipal Solid Waste Leachate Treatment Plant (LTP), and the other from a Sewage Treatment Plant (STP). Meth...
Autori: Ana Isabel Pelaez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26933

Because of their toxic effects on the food chain and sources of water, antibiotics are potential pollutants that represent an important environmental problem. The objective of this research was to study the adsorption of penicillin G (PEN G) onto chestnut shell using a batch adsorption system. Maximum adsorption was achieved at pH 3.0. The equilibrium uptake capacity (mg/g) increased with increasing levels of initial penicillin G concentration. The uptake capacity of penicillin G onto chestnu...
Autori: Amir Sheikh Mohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26940

One way to improve the performance of non-thermal plasma (NTP) reactor for volatile organic compound decomposition is by the introduction of ferroelectric materials into the discharge zone of NTP. This paper is a review of the breakthroughs and the current status of the applications of this technology for the abatement of volatile organic compounds (VOCs). It covers the process of energy generation in NTP, VOCs decomposition processes and the effects of critical factors such as type of packed...
Autori: Abdullahi Mohammed Evuti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26948

Treatment of agrochemical industry wastewater is difficult to carry out unless integration with some advanced oxidation process (AOP) is used. The present study deals with treatment of an agrochemical industry wastewater, first using activated sludge and then with sulfuric acid treated activated carbon (SAAC) in presence of Fenton reagent. During the activated sludge treatment the food-to-microorganisms (F/M) ratio is varied from 0.1 to 0.2 mg chemical oxygen demand (COD) per mg mixed liquor ...
Autori: Makarand Vasant Karkare
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26957

The release of nitrogen compounds into the environment is a major concern worldwide. Different studies howed that recycled materials have a high removal capacity for pollutants. Bentonite and its major clay minerals, smectites clays are common bleaching agents used for oil refinery bleaching and known as bleaching earth (BE). In this study regeneration of spent bleaching earth (SBE) acquired from the vegetable oil industry was surveyed via different methods and the regenerated spent bleaching...
Autori: Mohammad Malakootian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27000

This paper presents a mathematical model developed to solve the problem of adequate blending composition for copper smelting process and it is exclusively for the purpose of the case study in "RTB BOR" (Copper Smelter in Bor). The model proposes an objective function, which maximizes the profit by calculating both the “penalties” for the hazardous concentrate elements and “benefits” for the useful ones. Apart from the basic constraints of the existing mathema...
Autori: Ivan Jovanović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27002

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

A pure strain of Pseudomonas chlororaphis DJ-4 capable of anaerobic biodegradation of o-xylene, m-xylene and p-xylene was isolated from gasoline contaminated soil. In batch cultures, growth of the strain and biodegradation of xylene isomers led to stoichiometric reduction of nitrate. P. chlororaphis DJ-4 could degrade 150 mg L-1 of m-xylene completely within 12 days and without a lag period. However, higher initial concentrations of o-xylene and p-xylene were toxic to the bacterium of P. chl...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27005

The arsenic removal from aqueous medium was investigated through adsorption by employing finely powdered bark of Pinus roxburghii Sarg. The batch mode laboratory scale experiments were conducted to investigate the removal efficiency of Pinus bark against total arsenic and the effect of pH, contact time, adsorbent dose and initial adsorbate concentration on adsorption to optimize the process. Langmuir and Freundlich isotherms were used to validate the adsorption data and respective constants w...
Autori: Syed Hasnain Shah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27013

Semi-conductor oxide enhanced photocatalysis is a sustainable technology suitable for disinfection of water contaminated with pathogens. Disinfection of Escherichia coli was investigated using an immobilized thin film tungsten trioxide (WO3) photocatalyst in a visible light-driven photoelectrocatalytic batch cell (PECB). Disinfection efficiency was monitored under dark electrocatalytic, photolytic and photoelectrocatalytic conditions and assessed using a culture-based approach. Optimal disin...
Autori: Efetobor Scott-Emuakpor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27014

The aim of this study was the diversification of fodder yeast assortments with viable economic effects while reducing the pollution to the environment by capitalisation of wastewaters with high monosaccharides content from pulp and paper industry. As inoculum, in the bioreactor, a mixture of two species of yeasts Candida utilis and Candida arboreea (1:1 ratio) was used at 38°C, pH 5.5 and an air flow of 0.02 L/h was insured. Wastewaters from technological process of pulping of softwood wi...
Autori: Andrei I. Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27028

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

This work evaluates the potential of Phyllanthus debilis for the adsorption of Zn2+ and Ni2+ ions using synthetic solutions. Adsorption experiments were performed in order to examine the effect of pH, contact time, biomass concentration and initial metal ion concentration in the removal process, in a batch mode. The results revealed that the adsorption is highly pH dependent. The adsorption of Zn2+ and Ni2+ ions were concentration dependent and increased from 2.446 to 8.688 mg/g for Zn2+ and ...
Autori: Mohammad Aslam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27084

Heavy metal pollution is a major source of aquatic contamination and has deleterious effect on the environment, therefore treatment of the polluted sites and wastewater becomes very essential. Biofilm based bioremoval of heavy metals have been a new area of research. Bacterial strains belonging to the genus Bacillus, isolated from chromium polluted soil (Palar river basin, India) have been employed as consortium for Cr(III) removal from chrome tanning effluent. The bacterial isolates were fou...
Autori: Aafreen Fathima
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27086

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

The present study investigates the effect of addition of calcium hypochlorite in the titanium dioxide (TiO2) mediated degradation of bio-recalcitrant wastewater from pharmaceutical industry. The degradation studies were carried out in photoreactor irradiated with ultraviolet (UV) light at 365 nm under slurry mode. The reduction in chemical oxygen demand (COD) was estimated as an index of degradation. The influence of process parameters viz., catalyst dose, pH, oxidant concentration and source...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27097

Biological control relying on soil microorganisms may offer feasible and sustainable perspectives in many agrosystems for management of soil pests such as root-knot nematodes (RKNs, Meloidogyne spp.). The rhizosphere environment shows a complex of soil microbial communities, including beneficial organisms such as specialized bacterial pathogens and/or of rhizosphere fungi. New advanced technologies like Next Generation Sequencing (NGS) may enlarge our knowledge about the biodiversity and rol...
Autori: Aurelio Ciancio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27109

Sequencing Batch Biofilter Granular Reactors (SBBGRs) represent an innovative technology; coupling granular and attached biomass and operating in a batch mode. These systems allow good removal rates with low sludge production and space requirement. A particular application, consisting of an aeration unit and an upflow SBBGR in series, has been tested at pilot scale. The pilot system was installed at a conventional activated sludge plant and fed with average-strength urban wastewater after pre...
Autori: Paolo Cirello
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27123

Microbial fuel cells (MFCs) are bioelectrochemical reactors that directly convert the chemical energy stored in chemical bonds of organic substrates, to electrical energy. Saccharomyces cerevisiae was implemented as biocatalyst in the anaerobic anode compartment of an MFC using glucose as carbon source and methylene blue as electron mediator. Our results showed the effect of methylene blue on the microbial metabolism and the reversibility of the redox reaction of the shuttle mediator in the p...
Autori: Ruggero Rossi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27131

In this study, the potential for biogas production from biodegradable bioplastics was evaluated. Mater-Bi® (a family of maizestarch based flexible films) and PLA (PolyLactic Acid; a rigid, polylactide-based, polymer) bioplastics were digested in laboratory batch reactors, alone or in co-digestion with pig slurry or scotta (partially deproteinized cheese whey), at 35°C or 55°C. Methane (CH4) and hydrogen (H2) production were monitored during the incubation period. Maximum CH4 (Mmax...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27134

The removal of quinoline from synthetic wastewater by heterogeneous photo-Fenton in a novel internal circulating fluidized-bed reactor was investigated systematically. The flow field in the reactor was simulated by FLUENT software conjoined with tracer particles experiment, and the influence of reaction parameters such as initial quinoline concentration, catalysts dosage and H2O2 dosage were evaluated. Results indicated that the designed reactor was suitable for the heterogeneous photo-Fenton...
Autori: Ran Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27142

A submerged membrane bioreactor (MBR) was applied to treat digested piggery wastewater (DPW). The removal of chemical oxygen demand (COD), ammonium-nitrogen (NH4-N), two kinds of heavy metals and ten kinds of antibiotics were studied. The hydraulic retention time (HRT) was gradually shortened from 12 days to 2.7 days, by which correspondingly the volumetric COD loading rate was increased from 0.4±0.1 to 2.8±0.6 kg /(m3·d) and volumetric NH4-N loading rate was increased fr...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27150

A combined system of up-flow cyclic sludge bed (UCSB) and aerobic nitrification reactor (ANR) was designed for organic matter and ammonia nitrogen (NH4-N) removals of swine wastewater. The UCSB had one acidogenic zone for hydrolytic acidification to solve the problem of poor carbon source in swine wastewater, and the other zone for denitrification. Results showed that average removals of the chemical oxygen demand (COD) and NH4-N were 92% and 95%, respectively, under the following conditions...
Autori: Jie Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27160

Two 17β-Estradiol (E2) degrading strains were isolated from the activated sludge of swine wastewater bio-treatment aerobic facility and affiliated to Bacillus subtilis based on 16S rRNA gene sequencing. The degradation rates were more than 90–95% at 37 °C in 4 days when E2 was the sole carbon source. Steady and effective nutrients and estrogen removals were achieved in three parallel sequencing batch reactors (SBRs) treating real swine wastewater for 90 days, which contributed to ...
Autori: Meixue Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27162

Dried Typha angustifolia (TA) leavesor commonly known as the common cattail were evaluated as an adsorbent for the adsorption of lead in synthetic aqueous solutions. Equilibrium studies were conducted in a batch mode and the selected sorption isotherms were then applied. Equilibrium was achieved after 8 hours. The selected sorption isotherms were the Langmuir, Freundlich, D-R and Temkin model. Data fitting was done based on linear regression analysis. The adsorption system fitted the Langmui...
Autori: Yen Ling Sharain-Liew
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27166

Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by local low-cost agricultural by-products – peanut hulls, soybean shells and grapefruit peels were compared to develop high-efficient and low-cost biosorbents for removal of lead(II) from wastewater. Batch kinetics showed adsorption equilibrium at about 90 min and the adsorption process for the three biosorbents was better represented by the pseudo-second-order model than the pseudo-first-order model. Batch equilib...
Autori: Rui Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27176

The adsorbent gels utilized in this research project were synthesized from non-commercially available chitosan, obtained by deacetylation of chitin, which was isolated from fermented shrimp waste by a major local industrial food biopolymer. Chitosan-based adsorbent gels were used for the removal of a tris-azo dye (Direct Blue 71) from aqueous solutions. Sorption experiments focused on the chemical modification of chitosan using two cross-linking agents, sodium tripolyphosphate (TPP) and glutaral...
Autori: Reyna G. Sánchez-Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27184

This study was carried out to (1) investigate the potential of in-vessel solid-state anaerobic acidogenic co-digestion of high solids containing substrates, namely organic fraction of municipal solid waste (OFMSW) and cow manure and (2) examine the feasibility of using leaching bed reactors (LBR) for hydrolysis/liquefaction and acidification of OFMSW and cow manure mixtures for maximum total volatile fatty acid (VFA) and alcohol production. Results indicated that hydrolysis efficiency of 20-25% ...
Autori: Tuba H. Erguder
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27186

In this work, the effect of cyclic anaerobic/aerobic conditions on the biodegradative capability of the mixed microbial culture for the azo dye Acid Red 18 was investigated in the sequencing batch reactors. For this purpose, five anaerobic/aerobic sequencing batch reactors were operated under the same operation conditions at different anaerobic/aerobic reaction times. The whole reaction time was 22-h with anaerobic/aerobic periods of 6/16, 10/12, 14/8, 18/4 and 22/0 (h/h) in An/ASBR1 to 5, respe...
Autori: Mohammad Hakimelahi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27191

In this study, S-TE pretreated mariculture organic waste (MOW) was used as substrate. Acid, alkaline, S-TE, sterilization and microwave pretreated waste sludge was used as inoculation respectively. The highest hydrogen yield of 22.02 ml H2/g COD (chemical oxygen demand) was obtained from MOW with sterilization pretreated inoculation at mesophilic conditions in batch reactors. The impacts of different pretreatments on the changes of soluble chemical oxygen demand (SCOD), protein, carbohydrate, pH...
Autori: Liang Guo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27193

A new simple empirical model is proposed to describe the waste sludge volumetric flow rate in the steady-state completely mixed activated sludge process. The model is derived based on the nonlinear regression analysis by using the Richardson’s extrapolation method and the Levenberg–Marquardt algorithm. The application of the model has been explored for a wide range of eleven fundamental biological design variables and tested against a total of 1500 additional computational scenarios ...
Autori: Kaan Yetilmezsoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27202

In this study, the biosorption of zinc(II) ions from the aqueous solutions by the lichen biomass of Xanthoria parietina (L.) Th. Fr. was studied as a function of contact time, initial pH of metal solution, biosorbent concentration, initial metal ion concentration and stirring speed in a batch system. The optimum pH value for maximum zinc biosorption was found to be 5.5. Concentrations intervals from 50 mg/L to 250 mg/L were tested and it was observed that the biosorption efficiency depends on th...
Autori: Zuleyha Bingul
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27213

Banana stalk (BS) waste is used to remove Pb2+ from aqueous solution. Equilibrium data were analyzed with Langmuir and Freundlich adsorption models, which fit better in the former equation. The qmax (maximum metal uptake capacity) for Pb2+ adsorption was 105.14 mg/g of BS at pH 5.0, which followed pseudo-second order kinetics model. IR spectra confirmed the participation of hydroxyl, amino, and acidic functional moieties in the removal of Pb2+. The major mechanism involved in the biosorption of ...
Autori: Kashif Iqbal Sahibzada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27214

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

The mixed microbial culture, isolated from the aerobic sludge was used to study biodegradation of 1,1-DCE as the sole carbon source in batch flasks. 1,1-DCE initial concentration in the medium was varied from 100μg/L to 1000μg/L. The maximum removal rate of 1,1-DCE was 89.2% obtained at 400μg/L 1,1-DCE concentration in the medium. The biodegradation kinetics of 1,1-DCE was found to follow three-half-order model at all initial 1,1-DCE concentrations with regression values greater than 0....
Autori: Shizong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27219

The application of advanced oxidation processes (AOPs) emerged as an interesting topic during the last decade. Many studies have been devoted to the complexity of phenomena imposed by AOPs, and a lot of effort was made to justify the application of AOPs. However, the reliability of AOPs has not been an issue of any extensive work. In this work, failure analysis and comparative reliability study were performed for the chosen AOP system, i.e. a laboratory scale photo- and sonoreactor, during the p...
Autori: Ivana Grčić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27220

This study was carried out to assess the efficiency of down-flow hanging sponge (DHS) system for decolorizing the reactive dyes wastewater. The reactor was operated at different hydraulic retention times (HRTs) of 1.7, 3.5 and 6 h., and organic loading rates (OLRs) of 3.6, 2.2 and 1.3 g COD/l.d., respectively. The results obtained indicated that increasing the HRT from 1.7 to 3.6 h., significantly increased color and CODt removal efficiencies from 81±6.7 to 91.7 ±8.7% and from 24.2...
Autori: Ahmed Tawfik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27224

This study compared performance of the O3/UV process and biotrickling filtration as standalone and combined system on elimination of toluene from a waste gas stream. The performance of the bench scale O3/UV reactor was investigated with inlet toluene concentration of 650 ppmv and reaction time of 7.5 s. The results demonstrated that the combined O3/UV process degraded 34.1% of toluene under the selected conditions. The biotrickling filter had a maximum elimination capacity of 125.6 g/m3.h, corre...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27228

In this paper photo-oxidative degradation of degradable mulching films was studied. Low-density polyethylene (LDPE) films were denominated as 3# and 4# (containing 3.43% and 0.44% degradable masterbatch, respectively), They were exposed to different irradiation condition of i: ultra violet A irradiation (UVA), ii: ultra violet A and B irradiation (UVA-B), both at 58±2°C. The physical chemical property of the plastic film is influenced by factors in many aspects, especially the composi...
Autori: Ya-xi Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27232

In this study, an upflow anaerobic sludge blanket (UASB) bioreactor at the mesophilic temperature (38ºC) was successfully used for the treatment of petroleum refinery effluents. Response surface methodology (RSM) was applied for the design and analysis of experiments to predict the behavior of the initial COD and the hydraulic retention time (HRT) in the bioreactor. A statistical analysis indicated that the models adequately represented the experimental data. At the optimal conditions, the ...
Autori: Seyed Omid Rastegar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27233

A Microwave-Ultraviolet reactor was developed and the effect of microwaves on photodegradation of various phenols was studied using the reactor. The degradation study was carried out by six methods - microwave irradiation, photodegradation with UV light, microwave and ultraviolet radiations (microwave irradiation in presence of TiO2, photodegradation with UV light in the presence of TiO2 and also simultaneous MW and UV irradiations in the presence of TiO2). The relative efficiencies of the degr...
Autori: Singaram Karthikeyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27248

Composted livestock waste (CLW) was studied as one low-cost material to remove Pb(II), Cu(II), Cd(II) and Zn(II) from simulated acid mine drainage (AMD) by batch and column experiments. The adsorption isotherm data were well fitted by the Langmuir model. The maximum monolayer adsorption capacities were 0.5485 mmol/g for Pb(II), 0.4092 mmol/g for Cu(II), 0.2246 mmol/g for Cd(II), and 0.1879 mmol/g for Zn(II) at pH 4.0. Due to the competition effect, the adsorption capacity of the single metal ion...
Autori: Mingliang Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27262

After the entry into force of Landfill Directive 1999/31/EC the member states of European Union (EU) turned towards other technologies for waste treatment and management, such as mechanical-biological treatment of waste (MBT) in order to meet the obligations related to the reduction of the amount of landfilled biodegradable waste. This paper presents an analysis of the waste management in Poland in terms of the current regulations and requirements of the EU and achievement of the mechanical - bi...
Autori: Monika Suchowska-Kisielewicz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27266

This study investigates the adsorption of several metals in aqueous solution, by hemp materials (loose fibre and felted fibre). After characterization of the fibre, an extensive study was conducted on the adsorption properties of this material. The experiments were carried out in poly-metallic aqueous solutions containing Al, Co, Cr, Cu, Ni and Zn at a concentration of 1 mg L-1 and 10 mg L-1 each. The pH effect was found to lead to an optimum between pH 4 and 4.5. The kinetics of the adsorption ...
Autori: Justine Bugnet
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27272

This research offers a novel approach for potato wastewater (PW) bioconversion to alcohol by microwaves gelatinization, liquefaction and simultaneous saccharification and fermentation (SSF). Concentrated PW from potato processing to obtain fries was treated by gelatinization, enzymatic hydrolysis through liquefaction and saccharification, and fermentation; a mini-bioreactor was used, with low oxygen, temperature, pH and mixing control. The yeast Saccharomyces cerevisiae and a commercial mix of l...
Autori: Maria Iasmina Moza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27275

The aim of this work was to study the effectiveness of photocatalysis in the removal of contaminants from secondary treated municipal wastewater, on a batch scale. The samples were collected from the outlet of the secondary clarifier in the municipal wastewater plant located at Al Khoudh, Muscat, Sultanate of Oman. The influences of TiO2 catalyst loading and solar radiation exposure time were investigated for the removal of COD and total Coliforms. 60% removal of COD was achieved with a catalyst...
Autori: Anna Jesil Cheriyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27376

Effective adsorbents were developed from sewage sludge by chemical activation with different activators (5M ZnCl2, 3M H2SO4, 3M H3PO4, 5M ZnCl2: 3M H2SO4, and 5M ZnCl2: 3M H3PO4). The developed adsorbents were used for the removal of the heavy metals Cd (II), Pb (II), Cu (II) and Mn (II) from wastewater. The effect of several parameters (pH, initial metal ion concentration, adsorbent dose, contact time and solution temperature) on the metal adsorption capacity were evaluated by batch experiments...
Autori: Mohamed Nageeb Rashed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27385

The kinetics of azo dye reduction based on combined effect of biochemical reduction by anaerobic mixed culture and chemical reduction with hydrogen sulfide was investigated. Hydrogen sulfide was produced by sulphate reducing bacteria existing in the anaerobic mixed culture. The effect of initial anaerobic biomass, initial substrate, and initial dye (Reactive Orange 107) concentrations on reduction kinetics were studied with batch assays. The municipal waste sludge was used as electron donating s...
Autori: Umay Gokce Ozkan-Yucel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27386

The anaerobic digestion (AD) of fat-containing waste is often prolonged in time and problematic. Differences in AD performances could rely in a different probability for microorganisms to access the substrate. The aim of this study was to study the AD of waste cooking oil (WCO) with a biophysical approach. Two laboratory experiments were carried out using model systems consisting of WCO + hydration medium (HM) in 100 mL, static, in-batch reactors. In the first experiment, we assumed the WCO to H...
Autori: Francesca Fiume
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27409

Lignocellulosic residues are relatively recalcitrant to bioconversion during anaerobic digestion (AD) for biogas production. Pre-treatments with cellulolytic enzymes or diluted alkali can facilitate biomass hydrolysis and enhance the process. Both pre-treatments require low energy and chemical inputs, without accumulation of inhibitor. Milled wheat straw was pre-treated with hydrolytic enzymes or with diluted NaOH before AD. The pre-treatments were performed on sterilized, stabilized with formic...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27420

The objectives of this study were to investigate the composition of activated sludge biofilms and flocs in a sequential batch reactor (SBR) and in a sequential biofilm batch reactor (SBBR), and to evaluate the role of the extracellular polymeric substances produced in the reactors in comparison with the respective treatment efficiency of domestic wastewater, containing 1 to 40 mg/L phenol. Both reactors showed variable removal efficiencies. The SBR was found to contain more protistan species ...
Autori: Chrysi A. Papadimitriou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27422

The aim of present study was the effective utilization of waste apple for high yield of ethanol using immobilized cells of Saccharomyces cerevisiae S-3S through fed-batch fermentation. Low cost biomaterial was also developed for immobilization. Immobilization was carried out on different inert supports (agar-agar, k-carrageenan, Ca-alginate, sugar cane bagasse and apple bagasse). The results revealed that immobilized cells of S. cerevisiae S-3S gave high yield of ethanol as compared to free c...
Autori: Arifa Tahir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27425

This study was conducted to evaluate the cyanide removal efficiency by coupled process of Fenton and coagulation/precipitation from aqueous solution. The study was performed at laboratory scale in a batch system. Variations of pH, Fenton and precipitation reagents (molar ratios of Fe2+/H2O2 and ferric chloride), contact time and initial concentration of cyanide were investigated, and the optimum conditions obtained from each of the Fenton and precipitation processes were followed in the coupl...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27426

In the present study, anaerobic treatment of food wastes from restaurants of a fermentation industry and methane gas production yields produced during the treatment were investigated. For this purpose, food wastes with a Total Solid Contents (TS) ratio of 5- 7-10% were digested in a 100l experimental reactor. Batch anaerobic digestion studies were conducted at mesophilic temperatures (36.5 oC) for 30 days and optimum Volatile Fatty Acids (VFA) and alkalinity values for methane gas production ...
Autori: Sevgi Fersiz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27429

The negative effects of acid mine drainage (AMD) on the natural and human environments are well understood in South Africa, yet a robust and economic AMD treatment technology has not been developed. The current study aimed at exploring the performance of synthetic zeolite F9 in AMD treatment with specific focus on iron and manganese removal. For this, batch adsorption mode was adopted for which the effects of adsorbent dosage, initial pH and temperature were investigated. As a result, it was fou...
Autori: Mike Masukume
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27454

The partial nitrification bioreactor (PNBR) was operated at a constant temperature and an influent synthetic wastewater pH of 35°C and 8.5, respectively. The effects of dissolved oxygen concentrations (DO), hydraulic retention times (HRT), and the nitrogen loading rates (NLR) on the ammonium removal efficiencies and the NO2-N/NOx-N ratio were investigated. The activity of nitrite oxidizing bacteria was stimulated at high DO concentrations. The highest NO2-N/NOx-N ratio of 0.76 was obtained a...
Autori: Sukru Aslan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27455

In the present work, the removal of anionic phosphate from aqueous solution by electrocoagulation (EC) process using aluminium electrodes was carried out. Batch studies were carried out to investigate the influence of different operating parameters (supporting electrolyte concentration, pH, spacing between electrodes, applied voltage, electrode area, and initial concentration of phosphate) on removal of phosphate from aqueous solution. The initial value of pH was varied from 3 to 8, while the co...
Autori: Sarasan Seena Mithra
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27458

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

Wastewater treatment using sequencing batch reactor (SBR) has certain advantages over conventional activated sludge system. The performance of sequencing batch reactor in treating high C/N ratio was investigated with suspended polyurethane and polystyrene attached growth biomass configuration. A sequence of 4 hr HRT, 0.3 month SRT and 1kg COD/m3 was employed to study treatment efficacy. Treatment performance was assessed by means of chemical oxygen demand (COD), total nitrogen (TN) and total pho...
Autori: Beenish Saba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27478

Three modified bentonites, hydroxy-aluminum pillared bentonite (Al(OH)-Bent), cetyl trimethylammonium bromide modified bentonite (CTAB-Bent), and both cetyl trimethylammonium bromide and hydroxy-aluminum modified bentonite (Al(OH)-CTAB-Bent) were prepared and characterized by Fourier transform infrared spectroscopy (FTIR) analysis. Batch experiments were conducted on the adsorption of phenol at different temperatures, pH and initial concentration. The results indicated that adsorption capacity o...
Autori: Xiping Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27481

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

An apatitic calcium phosphate gel (HaG) was elaborated and used to treat municipal wastewater in a physicochemical cycle prior to the standard biological degradation process. Preliminary laboratory batch experiments outlined the kinetics of heavy metal sorption by monitoring the concentrations found in filtered fractions as a function of treatment time. On site experiments were performed in a municipal wastewater treatment plant by derivation of real wastewater into an experimental tank. In this...
Autori: Nathalie Lyczko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27488

This paper highlights the utility of rice husk ash for the adsorption of Cr(VI) ions from aqueous solutions. Rice husk ash (RHA) is produced when rice husk is burnt for various purposes. Application of Treated Rice Husk Ash (TRHA) as an adsorbent for the removal of Cr(VI) from aqueous solutions has been investigated. For this purpose, RHA was thermally treated. RHA and treated RHA (TRHA) were characterized by XRD, SEM and FTIR to investigate the effect of treatment on the nature and surface char...
Autori: Varsha Srivastava
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27504

An anaerobic-aerobic (An-Ox) sequencing batch reactor (SBR) was operated for the growth of phosphate accumulating organisms (PAOs), while an anaerobic-anoxic (An-Ax) SBR was used for the growth of denitrifying PAOs (dPAOs). Both reactors exhibited successful enhanced biological phosphorous removal (EBPR) performance. The sludge P contents in the two reactors increased from approximately 2% at the beginning of the operation to 9.1% (An-Ox SBR) and 7.3% (An-Ax SBR) after 140 d. The results of the...
Autori: Hansaem Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27525

The potential of Sphagnum moss peat to adsorb oxyanions (As(III), As(V), Sb(III), Sb(V) and Se(VI)) from aqueous solution was studied in batch mode. For arsenic (both species) and selenium, the results were negative: moss peat is not able to retain these oxyanion. For antimony, the hydroxyl and carboxyl groups from the Sphagnum moss peat surface seems to be responsible for Sb uptake. Kinetic studies were conducted for both Sb(III) and Sb(V) and a fast uptake process was observed, equilibrium bei...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27565

This study dealt with investigation of arsenic removal from groundwater using electrocoagulation (EC) method in a batch mode by the Box-Behnken experimental design method. Effects of some cations like Ca, Fe, Mg, Mn and operating time on the removal were explored by an air injected EC reactor. The combined effects of these variables were analyzed by the quadratic model for predicting the highest removal efficiency of arsenic from groundwater. The arsenic removal efficiency was found to be depen...
Autori: Mehmet Kobya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27584

A factorial design analysis was performed in order to determine the significant factors influencing cadmium removal from aqueous solutions by powdered marble wastes (PMW), using a continuous stirring tank reactor (CSTR) system. Investigated factors were initial cadmium aqueous concentration (5-30 mg L-1), PMW dosage (5-15 g L-1) and flow rate (20-40 mL min-1). Results showed that the cadmium aqueous concentration and PMW dosage were the most influencing factors on metal removal from synthetic aq...
Autori: Ammar Mlayah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27590

The performance and microbial community of an anoxic-aerobic sequencing batch reactor (SBR) treating saline wastewater were investigated at different influent COD/N ratios. The average COD removal efficiencies at steady states were 87.46%, 73.75%, 64.87% and 88.34% at the COD/N ratios of 20, 10, 6 and 30, respectively. The average NH4+-N removal efficiencies were 79.74%, 74.34%, 64.55% and 89.29% at the COD/N ratios of 20, 10, 6 and 30, respectively. No obvious accumulation of NO2--N and NO3--N ...
Autori: Sen Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27592

In this research, the capability of uranium biosorption by dried biomass of the red algae was investigated in a batch system. For the screening of the most appropriate biosorbent, they were placed in 0.5 mmol/L uranium solution with different pH for 3hrs of contact times. The obtained results showed that the species of the Gracilaria corticata (J. Agardh) are having the maximum rate of the biosorption. Sorption equilibrium was reached within 3hrs of contact time (at pH 4.5), and the results of t...
Autori: Reza Dabbagh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27596

The hydrodynamic behavior of bubble column bioreactors (BCB) is strongly dependent on the bubbly flow regime. Therefore, the influence of superficial gas velocity (Ug) and Sauter mean diameter (d32) on gas hold up (εg) was evaluated for the cultivation of a petroleum-degrading consortium. Hydrodynamic parameters were determined by photographic techniques. Also, the biomass cultivation was quantified by suspended solids formation (SS). Our findings indicated that the d32 increased at high...
Autori: Olivia Tzintzun-Camacho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27597

The study of binary biosorption of Pb(II) and Cu(II) was performed by pine nuts shell. Results were compared with the single biosorption of Pb(II) and the single biosorption of the Cu(II). Experiments were performed in batch stirred and in a continuous system. The presence of lead caused a slightly decrease of the copper biosorption yield and can be related to the copper equilibrium uptake. This antagonistic action can be related to competition phenomena between metal ions in solution for active...
Autori: Gabriel Blázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27611

β-glucosidases are very important in the improvement of cellulose degradation rates by diminishing the inhibition of end products. Although, cellulase cost has reduced significantly in last decade but still the high costs of biomass saccharification is one of the main challenges for the commercialization of ethanol from LC biomass. In this work, β-glucosidase immobilization in calcium alginate was optimized using response surface methodology. 89% immobilization efficiency was achieved ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27614

Aerobic treatment processes using attached media have been studied extensively to remove organic matter from wastewater and also denitrification process. The objective of this study was to assess the ability of down flow anaerobic up flow oxic submerged bio-film reactor (DAUOSBR) to remove phosphorus, nitrogen compounds, BOD5, COD, turbidity and total suspended solids from the Farabi Hospital wastewater. The present work involved designing and building a reactor loaded with down flow anaerobic u...
Autori: Meghdad Pirsaheb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27622

The link between the concentration of biodegradable organic matter and the rate of phenol removal in anaerobic conditions was examined in this work. This study was undertaken using a laboratory scale anaerobic stabilization pond and five closed reactors at two retention times, 2 and 5 days. The initial concentration of phenol and soluble COD decreased in the anaerobic pond effluent and the reactors with increasing hydraulic retention time; 98.6 % phenol removal was observed in reactors after 50 ...
Autori: Ali Almasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27623

FLUCTUATION OF RIVER NETWORK WATER ENVIRONMENTAL CARRYING CAPACITY IN A COMPLICATED RIVER-LAKE SYSTEM    • MINERALOGY AND GEOCHEMICAL DISTRIBUTION OF HEAVY METALS FOR THE FAGUL CETĂȚII TAILINGS, ROMANIA    • ACCUMULATION AND AVAILABILITY OF TRACE ELEMENTS FROM SOIL INTO ORIENTAL TOBACCO GROWN IN MACEDONIA    • OLFACTORY EFFECT ON LANDSCAPE PREFERENCE    • EFFECT OF MOLASSES ADDITION AS BIODEGRADABLE MATERIAL ON PHENOL REMO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27628

Polycyclic aromatic hydrocarbons (PAHs) are very hazardous compounds. This investigation is the third in a series of three experiments carried out in conventional wastewater treatment plants with regard to PAHs. The first experiment regarded the analysis of PAHs in a municipal wastewater sewage system and in the wastewater treatment plant (WWTP) effluent, followed by a comparison between the observed removal efficiency and FATE model (US-EPA) predictions. The second experiment was carried out in...
Autori: Vincenzo Torretta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27629

Two sets of simulated landfill reactors, namely conventional landfill (CL) and leachate recirculated landfill (RL) were operated to investigate the effect of leachate recirculation on the fractionation of Zn in municipal solid waste (MSW) landfill leachate. Zn in landfill leachate was fractionated into three fractionations: particulate and colloidal matter >0.45 μm, non-labile complexes <0.45 μm and free cations/labile complexes <0.45 μm. The result showed that the recirculatio...
Autori: Jun Yao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27648

Inadequate sanitation and poor infrastructure for waterborne sanitation are common in many developing countries. The anaerobic/aerobic baffled reactor (AABR) is a sustainable option for water sanitation in developing countries. In the present study, a 2.50 m3 AABR reactor working with real municipal wastewater was monitored. Four sequenced chambers, the first three being anaerobic and the fourth aerobic composed the AABR reactor. AABR efficiency and performance were examined during four diff...
Autori: Gustavo Henrique Ribeiro da Silva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27656

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

The separate and simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions were examined with trace amounts of commercial titania nanoparticles (up to 50 mg/L). A direct irradiation photo-reactor, equipped with ultrasonic source was employed. The effects of four influencing parameters, catalyst dosage, pH, temperature and metal ions concentration ratio were investigated. The simultaneous operations, in the ternary Cr(VI)/Ni(II)/TiO2 system, show a synergism in reduction effici...
Autori: Javad Saien
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27662

One of the main challenges for the development of biomass algal system production is the high operational and capital costs for these technologies. A great opportunity to overcome these challenges may however exist in the integration of wastewater treatment with algal biomass production. The algae are used for treatment of industrial wastewater, for purification of effluent originating from livestock production, while the studies concerning the use of algae species for the treatment of aquacultu...
Autori: Katya Velichkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27684

Adsorption, desorption, and kinetics behavior of Gd(III) ion on chelating resin were investigated in this paper. Batch adsorption studies were carried out with different pH, contact time, and temperature. The adsorption of Gd(III) follows the Langmuir model better than the Freundlich model. The apparent activation energy Ea and adsorption rate constant are k308 4.16 kJ/mol and 6.01×10-5 s-1, respectively. Thermodynamic parameters such as ΔH, ΔS and ΔG indicated that Gd(II...
Autori: Leilei Pi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27688

Hexavalent chromium Cr(VI), a constituent of wastewater from many industries, is regulated by the Environmental Protection Agency (EPA) as one of the priority pollutants. Adsorption is an important technique that can be used for Cr(VI) removal from wastewater. The challenge in adsorption techniques is to find a cheap, widely available adsorbent that has a high adsorption capacity to Cr(VI). Dates stones (DS) and palm fiber (PF) are two agricultural wastes that are produced from palm trees. These...
Autori: Reda Abubeah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27689

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27782

This paper aims to compare the adsorption performance of activated carbon and pine bark for iron and manganese removal from contaminated groundwater. Moreover, their environmental compatibility was checked for their possible use as reactive media in a permeable reactive barrier for in situ remediation. Batch tests were carried out with different iron and manganese concentrations and different particle-size distributions, in order to evaluate the effectiveness of the activated carbon and pine bar...
Autori: Silvia Sbaffoni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27779

In the present study, Dowex HCR-S/H, cationic resin was used as a resin for the removal of cadmium from aqueous solutions. The experiments were carried out in a batch vessel. Subsequent experiments were performed as a function of initial solution pH, resin dosage, agitation time, initial Cd2+ concentration, solution temperature and agitation speed. Ion exchange rate increased with the increase in initial cadmium concentration, stirring speed and temperature. The Langmuir, Freundlich, Elovich,...
Autori: Baybars Ali Fil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27777

The adsorption rate and dynamic behavior of the system are important factors as regards the process design and operational control. The aim of this study was to find a suitable kinetic model for the hexavalent chromium removal in a batch reactor. The experimental data were analyzed using four adsorption kinetic models: the pseudo- first and second order equations, the Elovich equation, and the intraparticle diffusion equation, so as to determine the best fit equation of the Cr(VI) adsorption ont...
Autori: Ankica Radjenovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27773

Application of a biological treatment system using white rot fungi is an interesting alternative for treatment of water and wastewater contaminated with persistent organic pollutants, such as polycyclic aromatic hydrocarbons (PAHs). A packed bed bioreactor using the white rot fungi, Phanerochaete chrysosporium (P. chrysosporium) was evaluated for degradation of pyrene and phenanthrene in polluted wastewater. White rot fungi have significant potential to metabolize organic pollutants such as PAHs...
Autori: Mahsa Baniasadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27767

Bare zero-valent iron nanoparticles (bare-ZVIN) have a great tendency to aggregate, which drops their reactivity with pollutants. To address this issue, polyvinylpyrrolidone stabilized-ZVIN (PVP-ZVIN) was synthesized and used for the removal of Cd2+ from aqueous solution in a batch system. The effects of operation conditions such as the pH of aqueous solution (2-8), reaction time (0-120), adsorbent concentration (1-6 g L-1) and the initial Cd2+ concentration (10-60 mg L-1) on the removal efficie...
Autori: Amirhosein Ramazanpour Esfahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27764

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27729

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27730

Large amounts of spent coffee grounds (SCG) are currently available all over the world due to the enormous increase in coffee consumption. This increase has in turn to be related to the even greater diffusion of coffee vending machines. The aim of this study was to evaluate the biomethanation potential (BMP) of SCG alone or in co-digestion with pig slurry (PS). Pig slurry was chosen because it is frequently utilized as feedstock for biogas production from agricultural waste. The raw material was...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27794

Activated sludge (AS) is the mainly used biological process in water treatment; therefore, assessing the influence of various operating conditions on this process is relevant. This study aimed to evaluate at laboratory-scale the influence of the gas-to-liquid volume ratio (RG/L) and the stirring speed (SS) on the biodegradation of carbamazepine (CBZ) by activated sludge. For this purpose, a central composite design (CCD) was used in association with response surface methodology (RSM). Batch cult...
Autori: Samer Semrany
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27869

Ultrasounds has a wide range of active applications spreading in solid, liquid and gaseous mediums, embedded in new methods and technologies for preventing, reducing and removing of existing pollution. This paper deals with the sonochemistry reactors and their combinations with photocatalysis and electrochemistry. Various parameters such as ultrasound frequency, power, number of ultrasound sources, lab-scale or large-scale equipment used for environmental applications of sonochemical reactors h...
Autori: Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27867

In this study, application of integrated anaerobic-aerobic membrane sequencing batch reactor (MSBR) for treatment of an azo dye-containing wastewater was investigated. For this purpose, three lab-scale MSBR systems were operated at various hydraulic retention times (HRT) of 48, 24 and 16 h with constant value of solid retention time (SRT) for all reactors. The treatment performance and the decolorization kinetic of the systems as well the fouling rate of the membranes were evaluated during the e...
Autori: Maryam Hasani Zonoozi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27851

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

High sulfide inhibited the activities of sulfate-reducing bacteria (SRB) and methane-producing bacteria (MPB). In addition, a large number of domestic sewages should be treated in China. Thus, it is the first time that domestic sewage was collected to dilute high-sulfate wastewater in this study to achieve simultaneous treatment of sulfate wastewater and domestic sewage in the anaerobic baffled reactor (ABR). The results showed that there were obvious separation of sulfate reduction phase and me...
Autori: Peng Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27840

This study emphasis the hydrogen fermentation from de-oiled Jatropha waste (DJW), a secondary and promising waste from biodiesel industry via influence of various combination of heat pretreatment using sewage sludge as inoculum. Batch experiments were carried out at a DJW concentration of 50 g/L, temperature of 55oC and an initial cultivation pH of 7. The peak hydrogen production rate and hydrogen yield of 16.3 mmol H2/L-d and 1.10 mmol H2/g volatile solids (VS), respectively, were obtained ...
Autori: Gopalakrishnan Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27874

Greywater reuse is widely accepted as a suitable response to the increasing demand of fresh water in urban areas. On the other hand, strict environmental regulations have obligated the development and implementation of membrane separation technologies for production of municipal potable water, in industrial water supply and in wastewater treatment. Potential energy crisis in the future has highlighted the importance of using renewable source of energy for membrane separation processes. This r...
Autori: Mohammad Ramezanianpour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27889

The catalytic hydrogenolysis of glycerol, a by-product of the biodiesel manufacturing process was studied on copper chromite catalysts with different chemical composition. The obtaining of propylene glycol was studied under mild reaction conditions (180- 240oC temperature range, 8 hours reaction time and moderate pressures). These important parameters have significant effects on the glycerol conversion and that is way the actual study was concerned to the obtaining of a superior selectivity t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27892

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

In this work, we report a methodology to provide emission factors based on micro-reactor studies. We propose emission factors for ammonia (NH3, 158 mg/km), nitrous oxide (N2O, 322 mg/km) and molecular hydrogen (H2, 72 mg/km) for vehicles equipped with three-way catalytic converter (TWC). Our experimental conditions were similar to those prevailing on vehicles during catalyst light-off and transient urban driving cycle. NH3 and H2 emission factors reported in this work are quantitatively simil...
Autori: Gustavo Ariel Fuentes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27899

The influence of initial metal ion concentration and temperature on the adsorption of Zn(II) from aqueous solution onto amino ethyl cellulose (AEC) functionalized with Orange 16 reactive dye, was examined. Batch experiments were performed at pH of 4.0 and adsorbent dose of 8.0 g/L previously established as optimum, ranging the initial Zn(II) concentration between 22.74-181.92 mg/L and temperature between 2 and 60 C. Three isotherm models (Langmuir, Freundlich and Dubinin – Radus...
Autori: Gabriela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27904

The main aim of this paper was to obtain, on the base of sensitivity analysis, a guide for correct operation of the sewage treatment plant at Eforie Sud which uses sequential batch reactors (SBRs). For this purpose several original procedures were realized. An initial regression model was obtained using the SBR simulation with STOAT 5.0 software, confronted with the process data collected on-line. As it was expected, the range of these data was small, corresponding to the usual domain of SBR ...
Autori: Cristina Singureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27923

The application of complex ecological approaches in biological wastewater treatment, assessment of its effect on the effectiveness of the process and comparison of the obtained data to the restrictions in the environmental legislation are key elements of the study. The processes in an anaerobic sequencing batch biofilm reactor, the first module from diphase anaerobic-aerobic biotechnology for dairy wastewater treatment, are investigated. The creation of highly specialized biological system by...
Autori: Irina Schneider
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27929

The present study explores the potential use of plant waste i.e. spotted golden thistle (Scolymus maculatus L.) stalks, as an inexpensive sorbent for the removal of methylene blue from synthetic aqueous solutions. Firstly, the waste material was characterized using different analysis methods, then kinetics and equilibrium of dye sorption were investigated using a batch sorption technique. The influence of contact time, initial dye concentration, sorbent dose, particle size and agitation speed...
Autori: Zoubida Senouci Bereksi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27941

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

Chlortetracycline (CTC) and copper (Cu) are simultaneously used as feed additives to improve the growth performance and to prevent infection in pig farming. After ingestion by animals, most of these compounds are excreted and coexist in swine manure. They might have an influence on anaerobic digestion when the swine manure is used as substrate in a biogas plant. The purpose of this study was to investigate the effects of both CTC and Cu on batch swine manure anaerobic digestion in order to bette...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27983

In this study, Coal Fly Ash (CFA), a byproduct of coal combustion power plants, was used as an adsorbent to remove color from locally-obtained pulp mill effluent (PME). Batch adsorption studies were conducted to determine the adsorption parameters that would result in the maximum color removal from PME at the lowest CFA dosage and process cost. The effects of operating variables on color removal were studied by varying: 1) CFA dosage, 2) initial PME pH, and 3) contact time. The findings indic...
Autori: Christopher Willett
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27986

Dairy wastewater has been a major environmental concern because of massive effluents characterized by high pollution load. This study reports the influence of initial pH (pHi), residence time (τ) and elapsed time (t) on the %COD removal (Y1) and specific energy consumed (kWh per kg of COD removed, Y2) for real dairy industry wastewater treatment in continuous stirred tank electrochemical reactor (CSTER) using aluminum electrodes. Central composite design (CCD) was applied for designing th...
Autori: Poonam Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28011

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

Clinoptilolite (Clin), the most widely used natural zeolite in environmental applications, was used as soil additive to investigate its effectiveness in protecting and improving the quality of soils that received surface disposal of OMW, as well as in limiting nutrients leaching from the degraded soils. Clin was added in a batch experiment of 18 months, where OMW were added in evaporation ponds and on soil for a period of more than 12 years. The zeolite was added as dust (particle diameter &l...
Autori: Maria K. Doula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28018

The polyhydroxybutyrate (PHB) production by photoautotrophic cultures is a potential eco-sustainable process to produce bioplastics. The biosynthesis of PHB by cyanobacteria meets a twofold target: the use of CO2 as feedstock alternative to the fossil resource used in the conventional processes; the contribution to the reduction of the CO2 concentration in the atmosphere. This contribution reports results of a study regarding the optimal growth conditions for cyanobacteria to produce PHB unde...
Autori: Roberta Carpine
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28021

Aspergillus fumigatus has been selected to bioleach the metals ion from brown shale. Process parameters like pH (5.0, 5.5, 5.8, 6.0, and 6.5), substrate concentration (2, 4, 6, 8, and 10%), pulp density (1, 5, 10, 15, and 20%), temperature (30, 35, 40, 45, 50oC) and agitation (100, 150, 200, 250, 300 rpm) were optimized according to L25 Taguchi orthogonal experimental array design that resulted in the twenty five batch bio recovery experiments. After biorecovery experiments, optimum value of ...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28035

The aim of this paper is studying light intensity values which maximize the photosynthesis in microalgal cultures by means of models of the photochemical process and by changing cultures strategies. The photosynthetic performances of Graesiella emersonii under batch, fed-batch, semi-continuous cultivation modes and with only air sparged or CO2 added to air were quantified by means of gas exchange measure and pulse amplitude modulated fluorimetry (PAM); kinetics of the photochemical processes...
Autori: Dora Allegra Carbone
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28037

The aim of this research was to improve the removal of organic matter and nutrients from wastewater from pig farms in a combined batch reactor performed as anaerobic-aerobic sequential. For this purpose, it was suggested to include recirculation cycles of wastewater in a sequentially pulsed manner in the anaerobic treatment followed by intermittent aeration in the aerobic-anoxic treatment. This novelty implemented in both sequential reactors was studied under pilot scale conditions. The process ...
Autori: Jorge Alonso Cortes-Esquivel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28101

Aim of the study is to determine Fe, Mn and Cd adsorption in the carbonate-rich clayey soils and to assess their environmental impacts. Soil samples represented a carbonate-rich clayey soil (Isaoren), carbonate-rich soil (Maşuk) and clayey soil (Aşık) was obtained from three different villages in Sanliurfa, southeast of Turkey. Adsorption studies were carried out with batch method. The maximum Fe, Mn and Cd adsorption was found on Isaoren, Maşuk and Aşık soils with ...
Autori: Ayse Dilek Atasoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28116

The production of food wastes is a serious issue in developed and developing countries. The biogas production technology is one of the most sustainable methods for treating food wastes. Currently, there is a great need to implement suitable methods to enhance biodegradation and methane production. This study investigated the effect of manure addition and leachate lime-pretreatment on the biogas and methane production from spoilable municipal solid wastes using a hybrid anaerobic-aerobic bioreact...
Autori: Fatemeh Aliasgari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28123

The present study represents an extension of ergosterol production by Saccharomyces cerevisiae fermentation processes using oxygen-vector by establishing the influence of the analyzed main factors, such as aeration efficiency and hydrocarbon concentration. The study has been developed for batch and fed-batch fermentation systems and has been focused on the variation of ergosterol content inside the yeast cells during the fermentation cycle in correlation with hydrocarbon volumetric fraction, COV...
Autori: Corina Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28130

The mesoporous MCM-48 was synthesized at room temperature with different templates such as hexadecytrimethylammonium bromide (C16TABr), hexadecytrimethylammonium chloride (C16TACl) and dodecyltrimethlammonium chloride (C12TACl). The obtained materials were characterized by XRD, N2 adsorption/desorption, FTIR and SEM techniques, and their performance as uranium adsorbent were investigated. In this framework, the effect of contact time, pH of solution, initial uranium concentration and temperat...
Autori: Meriem Chabane Sari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28131

Photocatalytic processes are among the most efficient treatment methods of waters polluted with recalcitrant organic substances. Nanotubular TiO2 arrays with photocatalytic properties were obtained in the process of titanium anodic oxidation in the fluoridecontaining electrolyte. Under the proposed conditions of electrolysis, a coherent system of tightly adjoining nanotubes was formed with the internal diameter of 60-80 nm and walls thickness up to 60-65 nm, the tubes height being dependent on p...
Autori: Gheorghe Duca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28137

As CO2 concentration levels in the atmosphere are steadily reaching a point of no return, it is paramount that actions are taken towards mitigating emissions by improving the efficiency of existing processes. Sorption-enhanced water-gas shift (SEWGS) combines the water-gas shift reaction with in-situ adsorption of CO2 on potassium-promoted hydrotalcite (K-HTC). This enables a direct conversion of syngas into separate hot streams of H2 at feed pressure and CO2 at regeneration pressure, making th...
Autori: Vlad-Cristian Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28149

Apart of new equipment’s development such as absorption columns with higher efficiency, for chemical industry, there is a strong need for greenhouse gases reduction in order to assure the environmental protection and, consequently, many studies regarding the purification methods of exhausted gases have been performed. There are several types of reactors used for gases purification, such as: bubbling jet reactor, combined packed and spray tower absorber, cable wet scrubber and packed column...
Autori: Elisabeta Droniuc Hultuana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28160

The contamination of aquatic and terrestrial environments by pesticides is highlighted by their possible toxic properties and poor biodegradability on the environment. The development of low cost by products from agricultural sectors as a suitable solution for contaminated areas remediation is of great environmental interest. Straw wastes can be considered as a promising alternative to remove different chemical compound that are environmentally toxic. In this study, some materials derived from ...
Autori: Irina Gabriela Cara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28161

The valorization of a metallurgical waste (i.e., an iron-rich slag) as raw material for the fabrication of high hardness glass-ceramics using differential thermal analysis, X-ray diffraction, X-ray fluorescence and scanning electron microscopy was investigated. The melting of the slag was aided by the addition of waste glass cullet (WGC) and the vitrification field of this system was investigated. The non-isothermal crystallization kinetics of the parent glass with the highest slag content was s...
Autori: Erika Iveth Cedillo-GonzĂĄlez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28168

The study attempted to identify the best suited models to determine the kinetics of chlorine decay and trihalomethanes (THMs) formation in drinking water supplies. Batch experiments were conducted on synthetic water samples to simulate the characteristics of raw water collected from Maithon water treatment plant (MWTP), Dhanbad, Jharkhand, India. Influence of various parameters like total organic carbon (TOC), reaction time, pH and chlorine dose on the rate of THMs formation were analysed. The s...
Autori: Minashree Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28171

Biological ammonium removal from wastewater requires coupling of nitrification and denitrification processes in respective aerobic and anaerobic conditions. This difference in environmental requirements pose a big challenge in the design of systems intended to effect both nitrification and denitrification processes. Alcaligenes faecalis strain No. 4, however, has both heterotrophic nitrification and aerobic denitrification abilities in aerobic conditions, eliminating the need to provide anaerobi...
Autori: Hung-Soo Joo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28186

This study investigates the capability of furnace bottom ash (FBA) as a filter media for phosphorus removal from wastewater effluents. Lab-scale studies were conducted, in which a mass of FBA was brought into contact with the phosphate solution (a predominant form of phosphorus in wastewater) in batch experiments and lab-scale filter. Intraparticle Diffusion Model (IPD) was applied and revealed that the mechanism of phosphate adsorption onto FBA consist of three phases; film phase occurred in...
Autori: Ali Alzeyadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28191

The textile industry has been contributing to the generation of wastewater containing dyes during the dyeing process. In this sector, Reactive Blue BB is a dye used on a large scale. One method widely applied to dyes wastewater treatment is adsorption. This technique is inexpensive since it can apply industrial by-products as adsorbents. In this work, the adsorption of Reactive Blue BB dye by the sugarcane bagasse, a by-product from the sugar and alcohol industry, was evaluated in batch syste...
Autori: Handria Hariane Piffer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28226

In Brazil, there is a deficit of access in relation to sewage services for a large part of the population, and this fact is the one responsible for the contamination of watercourses. This is because to the lack of investment in infrastructure in the country, since sewage treatment plants require high costs and high area demand for deployment, besides the installation of the collection system, which directs the wastewater to treatment. This paper describes the behavior of wetlands as a post trea...
Autori: Rodrigo de Freitas Bueno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28241

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

The olive oil extraction industry is one of the most polluting wastewaters from the food industry, which is considered an important economic activity in the world. The environmental effects of olive wastewater are related to chemical and organic loading, which is resistant to biodegradation processes. The purpose of this study was to determine the efficiency of combined electrocoagulation, catalytic ozonation, to reduce organic load and improve the biodegradability of olive oil sewage. The pres...
Autori: Mohammad Reza Khani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28261

MABR (Membrane Aerated Biofilm Reactor) consists in an attached-growth process in which a gas permeable membrane is used as a biofilm carrier, and bubble-less oxygen transfer allows for a counter-diffusional mechanism where the electron donor (NH4+, biodegradable organics) and electron acceptor (O2) reach the biofilm from opposing sides. The paper reports results form the largest MABR installation in the world, demonstrating the beneficial impact of the technology in terms of improved process r...
Autori: Giuseppe Guglielmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28299