An aliphatic-amine-bearing chromatographic support, based on commercial silica, was prepared and tested as potential matrix for affinity immobilization of a copper/topaquinone-containing amine oxidase from lentil seedlings. The support proved to be noticeably effective in immobilizing the enzyme with concomitant purification and activity retention. The immobilization yields and some properties of this preparation were also determined and compared with those of the soluble enzyme. High activity r...
Autori: Barbara Noli, Enrico Sanjust, Francesca Sollai, Giovanni Floris
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25108

AbstractThe textile industry is a large water consumer. Stringent regulations of wastewater characteristics require the use of membrane processes for the removal of persistent organic pollutants (POPs) from textile wastewater prior to discharge or recycling of these effluents.This paper presents an overview of research related to the removal of persistent organic pollutants from textile industry by membrane processes, discussing also the correlations with actual pre-treatment and removal rates. ...
Autori: , Corina - Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25127

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

Contain all the articles from this issueICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Treatment Technologies for Gaseous Fluxes"Surface chemistry studies on molybdena–alumina catalystTatiana Yuzhakova, ?kos R?Šdey, Endre Domokos, J??zsef Kov??cs, Monica Caldararu, Cristian Hornoiu, Mariana Carata, G.Postole, Cornel Munteanu, Larisa Strukova, Jozse FazakasHebicidal behaviour of a new N,N'- biquaternary salt of 4,4'- bipyridineServilia Oancea, Marinela Irimia, Gabriela Carja, Anton Airinei, Nicu...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25189

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

AbstractTheoretical and experimental studies of gas drying processes by adsorption in fixed bed of grains are presented in this paper. Based on an extensive literature study, some of the most representative mathematical models describing gas adsorption in fixed bed and consequently gas drying processes by adsorption in fixed bed are also presented. Using a mathematical model from those mentioned describing adsorption under isotherm regime, the temperature and gas flow velocity effects over the d...
Autori: Marius Sebastian Secula, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25272

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractWood-based epoxy resin was synthesized from resorcinol-liquefied wood. First, wood components were depolymerized and liquefied by reaction with resorcinol. The resorcinol-liquefied wood with plenty of hydroxyl groups could be considered as a precursor for synthesizing wood-based epoxy resin. Namely, the phenolic-OH groups of the liquefied wood reacted with epichlorohydrine under alkali condition. By the glycidyl etherification, epoxy functionality was introduced to the liquefied wood. Th...
Autori: Akira Fujita, Hajime Kishi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25310

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

AbstractPolycyclic aromatic hydrocarbons (PAHs) are included in the European Community (EC) and in the Environmental Protection Agency (EPA) priority pollutant list due to their mutagenic and carcinogenic properties. PAHs emissions from automobile traffic and industry activities were shown to influence the PAHs levels and profiles in vegetables grown nearby. The levels of 15 PAHs were determinate in samples of pepper (Capsicum Annuum) and tomato (SolanumLlycopersicum) in different stages of plan...
Autori: Alina Soceanu, Dan Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25360

AbstractHigh proton conductivity of CsHSO4 opened new opportunities for applications as electrolyte in solid acid fuel cells (SAFC). Relatively recent, it was proved that the accommodation of this solid electrolyte by silica supports improves its proton conductivity. During this work, solid acid CsHSO4 and its composites with mesoporous silica of SBA-15 and MCF-types as host materials were synthesized and studied for the first time. Studies were mainly focused on the influence of mesoporous supp...
Autori: Adrian Ungureanu, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25366

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractEquilibrium data of water vapor adsorption from wet air on several materials were experimentally determined at temperature values of 313 and 333 K and air relative humidity values ranged between 30 and 90 %. Experimental data were correlated with Langmuir and Freundlich models. The obtained results emphasize the significant difference between the water retained on the adsorbent materials impregnated with various salt solutions, and on classic adsorbents....
Autori: Ioan Mămăligă, Constantin Baciu, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25394

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract The paper presents a risk analysis and assessment of the defence linear systems failure (dykes) in case of accidental flood. Also, breach scenarios and hydrographs computation for the corresponding accidental high waters are provided. The impact assessment is highlighted through a global matrix model for costs quantification. It is also presented the flooding computation model for different versions of the linear defence systems and in a correspondent way the Inundation Accidental D...
Autori: Codruta Badaluta-Minda, Gheorghe Creţu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25433

Abstract At present, dangerous industrial wastes are a main source of environmental pollution because they are stored and deposited improperly. Besides, dangerous industrial wastes could also be a source of secondary raw materials which are not well capitalized. This fact causes substantial losses of secondary raw materials and energy and it is explained by the lack of certain technologies of treatment, capitalization and final removal that are technically and economically sustainable. To ide...
Autori: Neculai Mihailescu, Vasilica Daescu, Elena Holban, Mariana Nicoleta Badea, Jenica Paceagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25447

Abstract The waste recycling done in order to obtain composite products with performant properties and also, with long life cycle is the main purpose for the sustainable development. The present paper describes the way in which, different kind of solid wastes are immobilised in an organic resin as a binder matrix. Composites with different proportion of waste as, rubber/plastic, glass and silica sand have been obtained. The physical-mechanical properties and chemical stability of such organic...
Autori: Ioan Ropota, Emilia Zamfirache, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25450

Abstract In the new millennium to sustain a healthy life in harmony with nature, it will be extremely important to develop various materials and processes that minimize any harmful influence on the environment. The feasibility of sludge recycling in the brick manufacture was evaluated through laboratory testing. Several ceramic masses with clay, sand and various proportion of sludge have been synthesized and than characterized by their physical-mechanical properties. Sludge fineness also has ...
Autori: Ana - Maria Szoke, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25454

Abstract Mesoporosity of about 7 nm in ETS-10 titanosilicate was generated by postsynthesis treatment with hydrogen peroxide under microwave irradiation, resulting in an increased external surface area of the materials (55 m2/g). The influence of titanosilicate porosity and its surface modification by phosphorus atoms (ET(P)S-10) on the retention of some nanoions (??-emitting radioactive U(VI) and Th(IV) ions) and biomolecules (the proteins cytochrome c, papain, and ??-globulin) was investiga...
Autori: Robert Gradinaru, Sorin O. Valu, Stefan Postolache, Claudiu C. Pavel, Ion Sandu, Karin Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25455

Abstract Knowledge of the binding mechanisms of heavy metals to cement minerals is essential for the prediction of the long-term leachability of cement-based solidified waste containing heavy metals. In this paper, the sorption of chromate ions onto calciumsilicate- hydrate (C-S-H) in equilibrated aqueous suspensions was investigated as a function of liquid-to-solid ratio. The hypothesis of super-equivalent adsorption was assumed to be involved in chromate ions immobilization. This hypothesis...
Autori: Constantin Bobirica, Ionel Constantinescu, Liliana Bobirica,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25478

Abstract In order to reduce the cement content used in concrete production utilization of waste materials for substitution of a part of cement can be considered. In this study, two pozzolanic-waste materials, silica fume and fly ash, are used as a part of cement up to 12% and 40%, respectively in concrete and compressive strength as well as permeability properties were determined. The test results were evaluated by using the response surface method. By keeping the cement content in concrete c...
Autori: Dogan U. Anil, Ozkul M. Hulusi, Ekincioglu Ozgur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25490

Abstract The purpose of this work is to investigate the secondary Al slag (SAS) relating to its technical and environmental properties and, as consequence, to its compatibility with Portland cement matrix. This study may be a contribution to establish of SAS potential valorization as secondary raw material (SRM) in low strength cement matrix composites, as construction products. DRX mineralogical analyses revealed that SAS includes transition alumina compounds, especial boehmite. The hydrati...
Autori: Maria Gheorghe, Nastasia Panait, Romanita Teodorescu, Maria Roman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25498

Abstract Preliminary investigation of contaminated soil in the surrounding area of a petroleum tank has been carried out based on fluorescence techniques: excitation emission matrix (EEM) and synchronous fluorescence scan (SFS). A fluorescence fingerprints library containing several EEM and SFS maps for various dilutions of Romanian crude oil in methanol, was used to confirm the identity of the soil contaminant. A calibration curve was created to estimate the contamination level of soil sampl...
Autori: Dan Savastru, Elfrida M. Carstea, Gabriela Pavelescu, Luminita Cristescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25505

Abstract The work studies the orientations regarding the recycling of the products from the industry of auto-vehicles parts and components, orientations that can provide solutions which permit to the enterprises producing auto components the efficient management of the related products and services during the whole life cycle of the products, from the conception phase to that of recycling. The new way of approaching the development of metallic auto products promoted in Romania will contribut...
Autori: Petrica Corabieru, Stefan Velicu, Dumitru Zait, Anisoara Corabieru, Dan Dragos Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25524

Abstract In the paper is analyzed the possibility of using some industrial wastes for obtaining new building materials. From the industry or from the power station a lot of by-products or wastes have resulted and their storage is a big problem for the environment. In the building material industry a part of these wastes can be used in different ways: for replacing the cement, as addition in concrete, as component of cements, in the mixture of polymer concrete, etc. In the present investigati...
Autori: Marinela Bărbuţă, Nicolae Taranu, Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25525

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract Geopolymerization is a continuous developing field of research for utilizing solid waste and by-products. It provides a solution to many problems where hazardous residue has to be treated and stored under critical environmental conditions. Consumption of fly ash in the manufacture of geopolymer is an important strategy in making materials more environmentally friendly. Fly ash has been chosen as a base material in order to utilize this industrial waste. Previous researches have show...
Autori: Maria Harja, Marinela Bărbuţă, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25542

Abstract In this work the experimental conditions to synthesize, by direct hydrothermal synthesis, self-bonded pellets of ETS-10 phase containing iron were studied. The following gel composition was used: xNa2O-0.6KF-1.28xHCl-yFe2O3-0.2TiO2-1.49SiO2-39.5H2O with 0.8Â???xÂ???1.4 and 0.015Â???yÂ???0.08. The products obtained were characterized through X-ray diffraction on powders (XRD), thermal analysis (TG, DSC, DTG), scanning electron microscopy (SEM) and microanalysis (EDS). The data obtai...
Autori: Pierantonio De Luca, Danilo Vuono, Monica Filice
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25544

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

? GREEN SYNTHESIS OF SYMMETRICAL CARBONATE FT-IR STUDY ? SINTERED BASALT AS A PROMISING SUSTAINABLE MATERIAL IN MECHANICAL ENGINEERING ? DESIGN OF BUILDINGS INCLUDING ENVIRONMENTAL IMPACT ? ANALYSIS METHODS FOR PYRAZINE-2,3-DICARBOXYLIC ACID SYNTHESIZED USING ELECTROCHEMICALLY REGENERATED KMnO4 ? RESEARCH ON NaCl SALINE AEROSOLS II. NEW ARTIFICIAL HALOCHAMBER CHARACTERISTICS ? DETERMINATION OF AEROSOLS POLLUTANTS ON MEMBRANES. 1. MEMBRANES PREPARATION AND CHARACTERIZATIO...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25660

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Abstract:In this paper, the influence of two types of imidazolium-based ionic liquids (ILs) on the properties of sycamore maple (Acer pseudoplatanus) veneers, at 25 0C, 60 0C and 80 0C has been studied by using contact angle measurements and Fourier transform infrared spectroscopy analysis. The measurements showed that wood wettabillity is increased by IL treatment. It has been determined that the ILs decrease the crystallinity and improve the flexibility of the cellulose matrix. Also, it has be...
Autori: Attila Porzsolt, Catalin Croitoru, Christian Friedrich, Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25737

Abstract:This technical paper presents some aspects concerning the static finite element analysis of a wind turbine blade. For themanufacturing of the blades for a 10 kW wind turbine elaborated at the Technical University of Moldova composite materialsmade up of polyester matrix reinforced with fiber glass are being used. In order to determine the mechanical properties of theproposed composite materials 10 different samples of laminated composite plates were numerically simulated in ANSYS 11....
Autori: Marin Guţu, Viorel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25747

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

Abstract:The hereby article presents a part of the results of the research made by the author during his PhD degree preparation with respect to asbestos and plastics wastes recycling in the form of composite with polymeric matrix, respectively the toxicological tests performed on the new product. In this respect, three categories of tests were made based on complex and modern analysis methodologies, with high results accuracy: spectral analysis of the wear wastes, morphological analysis of the w...
Autori: Cristina Corpodean, Silvian Ionescu, Valeriu Deac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25812

Environment and sustainability are key issues for the policy maker. A policy should be first designed and realistically inserted in its proper context (regional, national, European) in order to be correctly assessed. After that, suitable models need to be chosen consistently with the policy context and with the evaluation purpose, to make easier the policy maker task. The aim of this paper is twofold. Firstly, to propose a Statistical Information System (SIS) approach in order to correctly write...
Autori: Giorgio Garau, Giovanni Mandras, Lucia Schirru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25827

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

This research investigates the influence of certain vitamins (A and D2) on the possibility of hydroxyapatite formation on polymer surfaces. A coating method based on biomimetic techniques was used to form a crystalline hydroxyapatite thin layer on porous polyurethane matrix. The method is based on a wet process of hydroxyapatite formation that involves porous polyurethane film soaking in a modified synthetic Simulated Body Fluid (SBF) solution. This modified SBF solution contains vitamin A and v...
Autori: Alina Costina Luca, Constantin Luca, Gabriela Ciobanu, Simona Ilisei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25884

Quantification of the floristic matrix is important both for animal’s nutrition and for the biodiversity monitoring of plants species under the influences of substance flow. Our researches have the main aim to study the possibilities offered by Infrared Spectroscopy in rapid, unpolluted and non-destructive analysis of floristic matrix modification from perennial grassland fertilized with organic and/or mineral fertilizers. It was performed three different FTIR models: for Poaceae (R2=0.949; RM...
Autori: Iosif Gergen, Moisuc Alexandru, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25892

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

AbstractThe present study was focused to classify various advanced oxidation processes (AOPs) to degrade sixteen commonpharmaceuticals and personal care products (PPCPs). The classification was based on the degradation rate constant (h-1).Chemometric techniques like principal component analysis (PCA) and cluster analysis (CA) were used to classify AOPs whichcan efficiently degrade a certain class of PPCPs. The bipolt based on first two principal components (PCs) of PCA modelidentified two distin...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26085

Abstract Large amount of radioactive sources generate gamma rays of various energies and intensities. Gamma-ray spectroscopy is applied for the quantitative study of the energy spectra of gamma-ray sources. In the present paper, a statistical analysis of the energy spectra of gamma-ray spectroscopy monitored during 4 years at the “Dosimetry and Radioprotection” Laboratory from ”Vasile Alecsandri” University of Bacău is provided. Several new mathematical parameters were calcula...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26144

AbstractPresent study deals with a technology that reduces the cadmium(Cd) availability to the leafy vegetable Amaranthus caudatusfrom Cd contaminated soil (6 μg Cd g-1soil), amended with farmyard manure FYM, FYM+NPK and agricultural wastes (ricehusk; RH and saw dust; SD) at different doses (0.5 %, 2 %, 5 % and 10 %). Among all the doses 5 % was found to the best foreach amendment showing maximum reduction in phytoavailability of Cd hence better vegetable yield. At this dose the reductionin...
Autori: Anita Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26228

AbstractIndigenous isolated bacterium Aeromonas sp. was immobilized in calcium alginate and the related immobilization parameterslike bead diameter, inoculum size and the initial phenol concentration required for biodegradation were determined. Thebiodegradation activity was most efficient with 4 mm calcium alginate beads. The optimal immobilized biomass required wasabout 28 109 cells/mL. Compared with free-cell suspensions, the alginate matrix used for immobilization of cells provided betterenv...
Autori: Abdelkader Namane
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26249

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractThe applications of biofilm treatment technologies for domestic wastewater are being increased in many parts of the world. Theaim of the study is to assess a compacted aerobic attached growth fix-film unit (termed Bio-cache) for treatment of small volumedomestic wastewater. The system consists of the miniature plastic packing matrix, which provides a large surface area of 300m2/m3, so as to maintain the high rate growth of viable organisms responsible for organic degradation. The study o...
Autori: Alireza Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26266

AbstractThis paper offers a case study of the seismic vulnerability assessment of existing buildings in 18 villages located in the Val d’Agri area (Basilicata region, Southern Italy). A building-by-building inventory was carried out within the urban areas of the villages by trained technicians in two periods collecting typological data for a total of about 17,500 buildings. In the first period (2001-2003), a purposely drawn up inspection form (VSP-2001) based on the usability form adopted in Ita...
Autori: Angelo Masi, Carmelinda Samela, Leonardo Chiauzzi, Luigi Tosco, Marco Vona
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26299

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractThis study was conducted to generate a hierarchical modelling based on ecological land classification in the Yukarıgokdere forestdistrict of the Mediterranean region, Turkey. Two ways indicator species analysis was applied to obtain response variables fromthe relevant vegetation matrix at each level. Response variables were modelled by using classification tree technique at eachlevel. Validation tests (i.e. multi-response permutation procedures for determination of differences of pl...
Autori: Kürşad Özkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26352

AbstractThe paper represents the application of a multicriterial analysis for establishing the decisional priorities in the field of impactsgenerated by polluting emissions from large burning installations. The analytic hierarchy process (AHP) method was used inorder to express quantitatively how the environmental protection and sustainable development objectives are met. Based onexperimental determinations carried out on site at Mintia Power Station, Romania and the brainstorming sessions held ...
Autori: Dan Codruț Petrilean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26398

AbstractA series of experiments were performed to quantify the adsorption of Cesium on Silica impregnated withtrihexyl(tetradecyl)phosphonium chloride (Cyphos IL-101). Non-radioactive cesium solution was used as a surrogate of theradioactive 137Cs. The obtained impregnated Silica with the studied ionic liquid was characterized through scanning electronmicroscopy, energy dispersive X-ray analysis and Fourier transform infrared spectroscopy in order to put in evidence that theimpregnation with the...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26473

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractAnalysis and monitoring of arsenic is still a challenging analytical task. Due to its complex behaviour (different forms of arsenicthat can be present depending on pH and oxidation states of arsenic) as well as demanding analytical procedures and instrumentaltools for control of arsenic concentration in drinking water which is set to 10 μg L–1, there are still some open questions andissues when arsenic is the scientific topic. In this paper the idea was to use a multivariate statist...
Autori: Vladana N. Rajakovic-Ognjanovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26506

AbstractAnaerobic degradation (AD) of municipal solid waste (MSW) depends on the moisture and nutrient distribution within thebioreactor; these factors are affected by leachate recirculation. In this work, the effects of leachate recirculation of 15 to 120 byvolume percentage (%V) on AD were studied. The ojectives of this study are as follows: a) to determine which recirculation rateprovides the best conditions for accelerated anaerobic degradation (AD) and b) to determine the optimal range of r...
Autori: Maria del Consuelo Hernández-Berriel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26557

Abstract The environmental impact assessment (EIA) is a compulsory evaluation instrument for environmental management and decision making processes and applies to different phases of activities (plans, programmes, projects and /or existing production or services), because it measures the natural and anthropogenic activities effects upon the environment. These impacts may affect the cultural richness, biodiversity, social-economic conditions and human health as well as the ecosystem equilibri...
Autori: Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26645

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract The main purpose of this research was to study the biodegradation ability of atrazine by using Arthrobacter sp. as free and immobilized cells of the strain DNS10, under several important environmental factors such as temperature, pH, salinity, substrate concentration. Furthermore, this paper objective was also to assess the process considering the immobilization under extreme conditions, such as high salinity and high atrazine concentration. DNS10 was immobilized on a sodium alginat...
Autori: Zhang Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26702

Abstract Maximum removal (94±1.2%) of 2, 4 dichlorophenol (50 mg.dm-3) was achieved on silica with agitation of 4 hours, at pH 8 and 42°C. The positive enthalpy (ΔH) and negative free energy values (ΔG315K) suggested the endothermic and a spontaneous nature of sorption. The free energy of the process at all temperature was negative and increased with the increase in temperature. The values of free energy suggested a spontaneous process where the spontaneity decreased w...
Autori: Abdul Ghaffar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26718

Abstract Impact damage is considered the primary cause of in-service delamination in composite materials and promotes significant reduction in residual strength. Non-destructive techniques (NDT) include several methods able to detect the shape and the size of the interior damages without destruction of the structure or component, which is economically advantageous. The aim of this paper is to evaluate the properties after low velocity impacts using an experimental-numerical procedure based o...
Autori: Ana Martins Amaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26726

Abstract Resilience is meant in this paper as the capability of a networked infrastructure to provide its service even if some components are failed: it depends both on net-wide measures of connectivity and the role of a single component. This paper has two objectives: first to show how a set of global measures can be obtained using techniques from network theory, in particular how the spectral analysis of the adjacency and Laplacian matrices allows us to obtain a characterization of global ...
Autori: Antonio Candelieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26746

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract The European Commission has introduced a whole range of policies and initiatives to promote the product eco-innovation and the environmental impacts reductions. One of the key topic for the reduction of the environmental impacts is the waste recycling and reuse (turning waste into useful resources). A teamwork of Politecnico di Milano has developed a research work, still ongoing and continuously updated, called “The usefulness of the useless. Cross-sectorial evaluation of wast...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26788

Abstract In the present study, several selected formulations based on recycled (rPP) or virgin polyolefins (vPP) and lignocelluloses were prepared and subjected to microorganism attack. Biodegradation tests were performed with microbial strains belonging to fungal genera, like Aspergillus, Penicillium and Fusarium. The initiation of biodegradation was demonstrated by Scanning Electron Microscope (SEM) micrographs showing the colonization of surface samples by microbial strains. The crystalli...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26879

Abstract Ash resulting from wood combustion constitutes a waste disposal problem to facility owners. The use of ash fertilizer or soil amendment could provide nutrients for agriculture if its nutrient content is adequate and it does not contain harmful amounts of heavy metals. The recycling of nutrients bound in ash would provide an inexpensive solution to waste problem. In our study, we aimed to characterize ash and clinker resulted from incineration of oak waste resulted from wood industry...
Autori: Ioan Oroian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26885

Abstract In the European Union, the hazardous waste recycling has become a priority, as response at legal prohibition for landfilling of untreated WEEE. The economic and eco-efficient recycling methods acquire more and more interest from the industry. The Cathode Ray Tubes (CRT) glass derived from Waste of Electric and Electronic Equipment (WEEE) dismantle is known as hazardous waste, because of their heavy metals content, especially lead. For this type of waste, the authors have proposed in...
Autori: Antoanela Popovici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26890

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

Ferric sulfate and aluminum sulfate were applied to stabilize the available arsenic in solid waste residue (SWR) from the organic arsenic industry, previously pretreated by the semi-solid Fenton process. NaOH, Ca(OH)2, and MgO were introduced to adjust the matrix pH. Toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), and sequential extraction procedure (SEP) were carried out to evaluate the effect and difference on the fixation treatments of ...
Autori: Li-Fang Hu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26956

Our study aims to analyse soil quality based on the concentrations of potentially toxic elements (PTEs) in natural or slightly modified anthropogenic soils, technosols and landfill deposits in Iasi. The pollution level analysis based on lognormal distribution plot allows the differentiation of elements coming from the parent material (Mo, Cd, Ni and As) of those with anthropogenic origin (Pb, Zn and Cu). The enrichment factor (EF) calculated based on manganese (Mn) as reference in the parent ...
Autori: Cristian Vasilica Secu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26991

Treatment of domestic wastewater using constructed wetland system vegetated with Phragmites australis was studied at lab scale. Response surface methodology (RSM) a mathematical model was employed for analyzing the effect of independent factors (inlet flow rate, outlet flow rate, retention time) on wastewater parameters e.g. electrical conductivity, BOD5, COD, nitrates, phosphates, total solids, suspended solids, heavy metals in order to maximally treat wastewater. All independent variables w...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26999

Fly ash is the major residue produced during the combustion of coal. Research has been carried out to recover silica and alumina from fly ashes collected from different thermal power plants in India. Silica and alumina from the fly ash were recovered and the recovered products were subjected to X-ray diffraction, X-ray fluorescence and Inductively Coupled Plasma-Optical Emission Spectroscopy analyses to estimate the silica and alumina content. Total recovered silica content in the samples was...
Autori: Ruth Sherly Endluri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27007

Within the framework of the Water Safety Plan (WSP), it is necessary to assess and to manage risks in the catchment area, considered the first protection barrier of water supply systems. The Cauca River is one of the major water resources of Colombia and the principal source of drinking water supply for the city of Cali (approx. 2,300,000 people). Taking into account, usually in developing countries, available information and specialized technical resources are limited, in this study were eva...
Autori: Andrea Pérez-Vidal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27010

In this study, the impact of silicate admixture in 2-line ferrihydrite on its sorption properties is presented. Synthetic ferrihydrites with broad Si content in the range of 0 to 1.5 Si/Fe molar ratios were prepared and characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDS). With an increase in the Si/Fe ratio, a typical XRD peak at 2.5Å broadens and shifts toward 3 Å; the position of Si-O stretchi...
Autori: Gabriela Pieczara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27140

Various azodyes containing one or more sulfonic groups were removed from aqueous solutions by biosorption on untreated wood shavings from Picea abies. The sorption kinetics was described by the pseudo-first-order (PFO), pseudo-second-order (PSO) and modified pseudo-n-order (MPnO) equations, from which the MPnO model provided the best fit to the experimental data. The surface reaction was identified as a rate-limiting step governing the dye sorption on wood shavings, but a mixed kinetics (with a ...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27207

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

In this study, silica gel initially reacted with N-(2-aminoethyl)-3-aminopropyl-triethoxysilane and subsequently with formaldehyde resulted in a modified solid that contained amino imine groups, Sil2NCH2. The solids were characterized by CHN elemental analysis, thermogravimetric analysis (TGA/DTG), FTIR spectroscopy, 13C solid-state NMR, and nitrogen adsorption/desorption measurements. The adsorption of Cd(II), Pb(II) and Cr(VI) ions onto Sil2NCH2 in aqueous solutions were examined to study the ...
Autori: Franklin Pessoa Aguiar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27242

Ammonium is an environmental contaminant encountered in water and soils, its admissible concentrations in soils and waters being established by legislation. Removal of ammonium ions from aqueous solutions from different matrix can be done with several sorbents, among which nano-adsorbents, such as oxidized exfoliated graphite nanoplatelets (ox-xGnP) offer practical solutions, based on their high specific surface area, associated sorption sites and efficiency of application. Several parameters su...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27273

In this study was synthesized MCM-41 mesoporous silica by hydrothermal treatment and funtionalized with titanium in order to obtain mesoporous materials with high surfacea area and photocatalytic activity in photodegradation of organic compounds as antibiotics. The functionalization of the synthesized support material was achieved by impregnation from alcoholic solution. The obtained materials (MCM-41) and (Ti-MCM-41) were characterized by X-ray diffraction (XRD), scanning electron microscopy (S...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27274

This study presents the results obtained in tailoring thin films of alumina, deposited onto aluminium substrates by spray pyrolysis, at 250°C, using AlCl3 solutions (0.15M) in a water:ethanol (1:1) solvent mixture. As morphology controlling agents, acetylacetone and maleic acid based copolymers are added in the precursors’ solutions. The precursors’ systems are analyzed by FTIR spectroscopy and the surface morphology of alumina thin films is investigated by atomic force microscop...
Autori: Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27291

The composition and the structure of the soil matrix have an important role in determining the water and the air regime into the soil. In the soil pore the area occupied by water and air, capillary and adsorption phenomena occur, together defining the suction of the matrix. The suction-humidity relationship varies from one soil to another, but also to the same soil in time. This paper sets out the results of investigations aimed at highlighting the influence of the composition and structure of...
Autori: Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27332

The Strategy of Waste Management, Horizon 2014-2020, states 8 major objectives with the role of establishing new priorities for Waste Management. Thus, one of the proposed measures for the next 5 years is encouraging the wastes exploitation for energy recovery. In this context, the main goal of our study was to evaluate the level of pollution considering 5 closed municipal waste dump sites from the North-East region of Romania over the period 2013-2015, having in mind at a first glance, the poss...
Autori: Brînduşa Mihaela Slușer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27347

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

Construction industries generate a large amount of concrete wash water every day, and it causes soil, surface water and ground water pollution. Therefore, re-using concrete wash water to produce fresh concrete is one of the solutions to prevent environmental pollution and to sustain water use. In this study, we tested setting time of cement, slump, compressive and tensile strength of 24 triplicate cubic samples of concrete with and without micro silica plus additive admixture using concrete wash...
Autori: Gholamreza Asadollahfardi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27389

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

Municipal Solid Waste (MSW) disposal is currently one of the major environmental issues in big cities. Several tools and techniques have been developed for Environmental Impact Assessment (EIA) of MSW disposal options, including scoping, checklists, matrices, qualitative and quantitative models and decision-support systems. Rapid Impact Assessment Matrix (RIAM) is a partially new method which is particularly advantageous over others as it provides a transparent and permanent record of analysi...
Autori: Zohreh Aliakbari-Beidokhti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27465

To assess energy conservation and emission reduction effect on traffic and transportation at macro level more scientifically, the evaluation system based on the improved osculating value method for transportation is established. Information entropy weight is introduced to the traditional osculating value method and the numerical matrix normalization process in the osculating value method is simplified. The pollutant emission and the energy consumption is defined as negative index, and the capaci...
Autori: Yang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27470

Nowadays, the polyolefins (polyethylene, polypropylene) are increasingly consumed in large amounts for many applications. This issue causes a concern regarding the environmental impact of the waste materials generated after the first use. Mechanical recycling of polyolefin wastes helps to conserve oil and gas resources and reduce the polymeric waste accumulation in environment. In this paper, the modification of some post-consumer polypropylene (rPP) properties coming from packaging processi...
Autori: Maria Râpă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27493

This study focuses on some mechanical properties resulted from the tensile testing of a set of green composites with a Dammar-based matrix and reinforcement material of silk, flax, cotton and hemp fabrics. To be precise, we have ascertained the characteristic curve, the resistance to and the elongation at fraction, as well as the modulus of elasticity for each set of samples from these composites and for a set of bioresin samples. With the help of an Electronic Scanning Microscope we captured im...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27516

This paper describes an eco-efficiency decision support model for of end-of-life solid waste recycling. A holistic approach in balancing environmental pollution concern and waste recycling is required. A system dynamic model is based on mathematical model of the supply chain, and decision-making analysis is supported with the online spreadsheets. A criterion function-based modelling is used as a core model for simulation that uses net present value-based metrics of the supply chain activities. T...
Autori: Stanislav Avsec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27591

This paper presents the research on the temporal variability of water quality parameters for the most important river system in Romania and Europe – Danube River. The data on the river water quality had been obtained during ten years. The investigation was systematic and complex. Using the Kolmogorov-Smirnov test, and traditional statistical methods based on correlation matrix - Principal Component Analysis (PCA) and Factor Analysis (FA), and ANOVA all the samples data sets were classified...
Autori: Paula Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27601

Thin-film transistor liquid-crystal display (TFT-LCD) waste glass can be used as a raw material for producing geopolymers, because it contains large amounts of silicon and aluminum in its amorphous structure. The setting time and compressive strength were evaluated to determine the quality of the geopolymer product with various amounts of nano-SiO2 (0%–3%) and TFT-LCD waste glass replacement (0% - 40%). The microstructures of the samples were characterized using mercury intrusion porosimet...
Autori: Kang Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27634

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

The enzyme-based biosensor stability and its analytical performance depend on both the immobilization process and the matrix used for immobilization of the enzyme into a stable layer. In this paper, the development and evaluation of an optimal enzymatic layer for stable encapsulation of the acetylcholinesterase enzyme (AChE) through the sol-gel method onto mediated carbon-ink screen-printed electrodes was performed, obtaining electrochemical enzyme-based biosensors. The enzyme was immobilized on...
Autori: Melinda David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27636

The paper describes the main results from a study of cement bound mixtures for road foundations with the aggregate matrix consisting of industrial wastes, i.e. foundry sands (FS), electric arc furnace (EAF) steel slags and bottom ash from municipal solid waste incineration (MSWI), combined in five different proportions. The laboratory investigation involved a preliminary analysis of the chemical, leaching, physical and mechanical properties of the industrial wastes, followed by a mechanical char...
Autori: Marco Pasetoo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27645

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

This paper investigated the compressive strength and thermal conductivity of water and air cured Portland cement-fly ash-silica fume mortars. The results showed that density, compressive strength and thermal conductivity of blended cement mortars with fly ash were lower than Portland cement control. However, blended cement mortars that contained silica fume as replacement cement both in binary and ternary phase were higher than fly ash mixes and tends to increase with increase silica fume used a...
Autori: Chalermphan Narattha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27731

This study aims to monitor Volatile Organic Compounds (VOCs) and odour annoyance perceived by the exposed population living nearby a petroleum plant through an integrated high temporal resolution methodological approach. The area under investigation is considered one of the most critical industrial areas of the South of Italy (Basilicata) because of presence of the largest Italian petroleum plant, called the "Center Olio Val d'Agri" (COVA). In fact, VOCs and odours emitted from ext...
Autori: Alessia Di Gilio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27791

Water sea pollution is influenced mainly by anthropogenic causes due to industrial and municipal activities which affect the quality of sea water, sediments and the whole ecosystem. In this paper, the correlation between contamination sources and the environmental quality of marine sediments was analyzed through multivariate analysis, in particular Principal Components Analysis (PCA), Cluster Analysis (CA) and Correlation Analysis. Considering the case study of Mar Piccolo in Taranto (Ionian Sea...
Autori: Claudia Labianca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27793

The effect of synthesis conditions on sorptive properties of glycerol-derived mesoporous carbon materials were studied. Sorption properties of the synthesized carbon-based materials regarding to different adsorbate molecules, as well as water vapors, phenol and methylene blue molecules were analyzed. The sorption capacity of the synthesized mesoporous carbons depends upon synthesis conditions, namely upon pyrolyzing temperature and carbon precursor to silica weight ratio, being determined by ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27880

The main objective of this research is to investigate the effects of lime and waste silica fume additive on a silt and its utilization on railway subgrades stabilization. For this purpose, lime and waste silica fume were added to the silty soil in different contents at the soil optimum moisture; then the California Bearing Ratio (CBR) tests were conducted on the soil samples to estimate the favorable mixture design. At the next step, a selected sample was chosen to be exposed to wetting–dr...
Autori: Reza Ziaie Moayed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27972

In this paper, we determined some mechanical properties of a new category of green composites, based on tensile tests. More precisely, we selected a set of samples from a new bio-resin based on Dammar and two sets of samples from green-composites with matrix by bio-resin and reinforced with almost compact layers of Typha latifolia or Schoenoplectus lacustris. For these built materials, we obtained the characteristic curve, tensile strength, percentage elongation after fracture and elasticity mod...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27980

Nanoparticles (NPs) have recently been concerned as emerging contaminants. Determination of NPs in different environmental compartments is a revealing topic for researchers studying their impacts in nature. Various methods of analysis have been reported in literature for their measurement and recovery. However, there are difficulties in their quatification in landfill leachate. Taking into account varying landfill components and their possible interactions with NPs, different types of NPs wer...
Autori: Ceyda Senem Uyguner-Demirel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27989

Environmental impact assessment (EIA) for waste disposal options to examine their impacts is of great importance. Rapid impact assessment matrix (RIAM) was used in this research to evaluate impacts of the four different MSW disposal scenarios in Abyaneh village which is one of the oldest villages in Iran, attracting numerous domestic and international tourists year-round. These scenarios, respectively, were open dumping (S1), sanitary landfilling (S2), composting, followed by sanitary landfil...
Autori: Ali Daryabeigi Zand
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28057

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

China’s tremendous economic developments are achieved at the expense of environmental deterioration. In recent years, PM2.5 pollution has become increasingly serious in China, attracting widespread attention from the citizens and the government. This study aims to investigate the temporal–spatial characteristics of PM2.5 in China in 1998–2012, fully considering the potential influencing factors of PM2.5. The satellite remote sensing data compensate for the deficiency of surface...
Autori: Wenyang Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28115

Building industry is a very large domain in the global economy and it has a lot of consequences over the environment through many and different aspects. These consequences are various, from the more and more extended area of construction up to gas emissions released during materials manufacture and transportation, construction process, exploitation of buildings and, finally, their deconstruction. The concrete, the most used material in construction industry all over the world, must become green...
Autori: Catalina Mihaela Gradinaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28138

There are considerable environmental and health and safety concerns regarding liquid crystal display (LCD) waste glass because of the waste electrical and electronic equipment (e-waste) that is deposited in landfills. In current study, the effect of variation in LCD waste glass on the deconvoluted fractions of silicon centers of metakaolin geopolymers has been comprehensively investigated to discover the underlying mechanisms governing the performance. Solid/liquid ratio affects the kinetics of ...
Autori: Kang-Wei Lo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28146

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

The goal of this paper is to contribute to environmental improvement. This goal has been achieved by the development of an algorithm that allows the optimization of fuel consumption and transport of combustion products. The paper considers the outlier – robust recursive algorithm. This algorithm is used for identification of multivariable ARMAX (Autoregressive Moving Average with Exogenous Variables) models. In this paper, we introduce pseudo-Huber loss function which is a continuous nonli...
Autori: Vojislav Filipovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28167

The study attempted to identify the best suited models to determine the kinetics of chlorine decay and trihalomethanes (THMs) formation in drinking water supplies. Batch experiments were conducted on synthetic water samples to simulate the characteristics of raw water collected from Maithon water treatment plant (MWTP), Dhanbad, Jharkhand, India. Influence of various parameters like total organic carbon (TOC), reaction time, pH and chlorine dose on the rate of THMs formation were analysed. The s...
Autori: Minashree Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28171

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

LED waste quartz sand (LEDWS), which is a prominent by product of the LED manufacturing process, may contaminate the environment because it comprises specific heavy metals (e.g., As and Cu), which are hazardous ingredients to the environment when disposed of improperly. Therefore, this study investigated the use of light-emitting diode (LED) waste quartz sand to partially replace Portland Type I cement (OPC) to evaluate the feasibility of reusing it as a pozzolanic material. The SiO2, Na2O, and ...
Autori: Kae-Long Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28207

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

Impregnation of aluminium ion onto silica gel (SG) surface (Al/SG) is to increase the adsorption capacity of an anionic dye such as Indigo carmine (IC). The impregnation was carried out using wetness impregnation. The change of the functional group was evaluated by FTIR, crystallinity was determined using XRD, surface morphology were studied by SEM-EDX, while surface area and pore size using N2 gas adsorption-desorption analyzer. Meanwhile, the best of IC adsorption condition onto SG and Al/SG ...
Autori: Yudi Aris Sulistiyo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28253

The treatment of acidic wastewater of copper sulfide produces a huge amount of sediment, which can be processed into the planting matrix for ecological restoration of mines. This paper attempts to screen out the plants suitable for the acidic wastewater sediment, laying the basis for ecological restoration of mines. Therefore, 14 plant species were selected for preliminary tests on survival rate and growth tests in sediment pond. The survival rates and growth conditions of each plant species in...
Autori: Jinchun Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28268