AbstractMunicipal solid waste (MSW) management is an important and challenging issue for sustainable development. It is also one of themost controversial problems and a subject of an ongoing debate between different interested parties. A particularly controversial issue is MSW incineration (with or without energy recovery) which has in many countries become a socially unacceptable option for dealing with solid waste. On the other hand, the increasing amounts of waste each year demand immediate a...
Autori: Adisa Azapagic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25147

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractThis paper analyses a new technology for minimizing the use of metalworking fluids (MWF) during the machining process. Despite the fact that near dry machining (NDM) produces almost similar cutting performance to conventional flood supply machining while using much less MWF, for being fully utilized in industry is necessary to research ecological impact of these machining techniques. To take full advantage of minimal quantity lubrication (MQL) technique and expand its applicability, an u...
Autori: Domnita Florina Fratila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25382

Abstract Corrosion control, using inhibitors like, polymerisable porphyrins and multifunctional nanocomposites, is extremely useful in many environments. Phosphogypsum is a waste product resulted from the process of obtaining the phosphoric acid and it can be also used as corrosion inhibitor; in a mixture with other coating materials. Two types of modified porphyrin: Na4TFP Ac - dissolved in KOH and H2SO4 and H2TPP - dissolved in benzonitrile, were tested. The structure characterization of pho...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Amalia Macarie, Iuliana Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25477

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract Plasma is often called the fourth state of matter. It is distinct from other lower-energy states of matter, most commonly solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. Plasma technique may use any gas or gas mixture, within equipment limitations. Each gas or mixture of gases produces distinctive plasma, making possible a very diverse range of chemical environments. Besides the recombination mechanisms developed...
Autori: Marian I. Totolin, Ghiocel E. Ioanid, Iordana Neamtu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25550

Abstract This work describes the preparation of a hydroxyapatite/polyurethane composite membrane and their characteristics. The porous hydroxyapatite/polyurethane composite membranes were made via solvent casting process. The deposited hydroxyapatite layers were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The data suggest that the method utilized in this work can be applied to obtain deposition of coating of crystalline hydroxyapatite on porous polyurethane...
Autori: Gabriela Ciobanu, Dorina Ignat, Gabriela Carja, Constantin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25572

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

The variation of acidity and the wet deposition fluxes of rainwater in Nanning City were analyzed based on the local acid rain monitoring data provided by environmental protection authorities from 1991 to 2004. The result shows that the annual value of pH is less than 5.6 in the past 14 years and the wet deposition has been getting more and more severe in Nanning. The ratio of SO42-/NO3 - has decreased. NO3 - has played an increasingly large role in acidity, though SO4 2- remains a key player. T...
Autori: Feng-qin Zheng, Guo-liang Liao, Hai-hong Huang, Yu-chun Mo, Shen-xian Wuhttp://www.ecozone.ro/reviste.php?RID=25678

Abstract:Point of zero charge (PZC) is defined as the condition at which the surface charge density of a material equals to zero and, formost of the solids it is strongly pH dependent. The PZC can be controlled by tuning the solid surface properties (crystallinestructure, morphology) and by a proper environment control, thus it is important to evaluate the PZC for a certain type of material,in given working conditions, for enhancing the efficiency in the targeted application (e.g. layer by layer...
Autori: Laura Maria Bertus, Radu Adrian Carcel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25721

Abstract:The paper presents the virtual prototype of a robotic system for spray pyrolysis deposition (SPD). To design of the mechanicaldevice model of the robotic system, the MBS environment ADAMS of MSC Software was used, while the MATLAB/Simulink ofMathworks was used for the dynamic analysis of the robotic system, according to the mechatronic concept. A control loop waschosen, composed by a multi-body mechanical model, connected to the dynamic model of each motor. The main objective is toverif...
Autori: Cătălin Alexandru, Monica Enescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25744

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

AbstractThe aim of this study was to evaluate the effect of polyphenolic extract and deuterium depleted water (DDW) as bioregulators inmaize (Zea mays L.) plant cultivation. The aqueous extract obtained from spruce bark (two levels of concentration), pure DDWand DDW in combination with spruce extract were used. The test solutions were applied by spraying and the maize plant growthand alelopatic effect on the development were studied. The following specific plants parameters were monitored: growt...
Autori: Corneliu Tănase, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26012

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

Abstract Being involved in the synthesis of precursors for amphetamine and amphetamine-like drugs, pyridine (Py) may be also regarded as a by-product found when these drugs are obtained via the Leuckart method. Also, pyridine is well known as a biomarker of microorganisms, when those are subjected to pyrolysis before analysis by various instrumental techniques. Consequently, since Py is not commonly found in the air, its presence as a contaminant at trace levels in a room could ind...
Autori: George-Bogdan Ghira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26109

Abstract Volcanic hazard is ignored in natural hazard studies in Romania because no active volcano is known on its territory. However, the 2010 eruption of Eyjafjallajökull volcano in Iceland and its consequences on air traffic safety across Europe and the whole northern hemisphere dramatically demonstrated that volcanic hazard in a certain area, such as a country, is not necessarily related to the presence of active volcanoes in the same territory. Therefore, target-focused approa...
Autori: Alexandru Szakács
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26146

AbstractA wet flue gas desulfurization (WFGD) system adopting electrostatically-assited twin-fluid atomization injector was presented.Spatial distributions of the droplet sizes, velocity for different voltages were measured using limewater and SO2 removalefficiency for different voltages and Ca/S ratios were tested using limewater drops. The physical and chemical improvementmechanisms were analyzed using spray characteristics and double film theory. The analysis showed that electrostatically-ass...
Autori: Zhentao Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26175

AbstractThe aim of this study is to analyze the surface-ozone concentration mass variations in Bucharest for the 2005-2007 period. Data files from eight urban sites in Bucharest area were processed to extract the surface-ozone features. Generally, the results have shown that the highest values of surface- ozone concentrations are in the summer and in the afternoon, as in the literature. The smallest values are in December and January in all the three years. Monthly mean concentrations have shown...
Autori: Constantin Rada, Cristian Necula, Laurentiu Zagar, Raluca Barladeanu, Sabina Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26275

AbstractA deep understanding of the relationship between the solids deposition and head losses is vital to optimize the backwashing inbiological aerated filters (BAFs). In this article, the deposition solids were classified into four types: heterotrophic biomass,autotrophic biomass, inert biomass and extracellular polymeric substances (EPS). A concept model was developed to simulatethe solid deposition and the head loss development. The temporal and spatial distributions of the four types of sol...
Autori: Chengda He, Dongsu Bi, Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26347

AbstractAcid rain is a general term used to describe acid depositions, i.e. rain, fog and snow (known as wet deposition), as well as acidgases and particles (known as dry deposition). Acid rain is of particular environmental concern in Romania, as many soils havelately become acidic, causing serious damages to plants, animals and human beings. The purpose of this study is to evaluate bysimulation the impact of acid rain on a podzol sample taken from the Retezat National Park, a Romanian protecte...
Autori: Clementina Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26399

AbstractThe right individuation of the more convenient solution for final treatment and destination of sewage sludge deriving fromwastewater plants, normally after anaerobic digestion process, is a very interesting problem, in accounting of urgent needs foracceptable solutions. The produced sludge, primarily after thermal drying, can be sent to energetic valorization processes as, forexample, incineration, gasification and also pyrolysis. In this work we examined the thermal solutions (both dire...
Autori: Deborah Panepinto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26435

AbstractThe paper presents a hybrid method for the advanced removal of low biodegradable organic compounds from water, bycombining the separation selectivity of the membrane with the oxidation efficiency of the photocatalytic process. The aim of thisstudy is to evaluate the performance of the hybrid method to remove toxic compounds from wastewater. The advanced oxidationprocess, based on a photocatalytic reactor with continuous recirculation, ultraviolet (UV) radiations and a membrane, was usedf...
Autori: Cristina Orbeci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26490

AbstractThe paper concentrates on the risks of modern technologies (in wood processing and metal industry, spray-painting processes andcar washing technologies) in the industrial and office environments on human health. The problems discussed are the following:fine dust (PM2.5and PM1.0) penetrating deeply into the lungs; high concentration of carbon dioxide in the air of cities and officeareas that are situated close to the transport junctions. The health damages can be described as follows: all...
Autori: Ada Traumann
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26501

AbstractNano-Ag electrodeposited on carbon nanotubes-epoxy and carbon nanofibers-epoxy composites electrode materials as Ag-CNTand Ag-CNF electrodes were tested for simultaneous detection of arsenic (III) and lead (II) from aqueous solution. Theelectrochemical behaviour of As(III) and Pb(II) on both composite electrode offered useful detection information and Ag-CNFexhibited better electroanalytical performance. The detection scheme using Ag-CNF for simultaneous detection of As(III) andPb(II) wa...
Autori: Anamaria Baciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26511

AbstractFailures of geothermal system pipes are often caused by limescale buildup on the walls of the pipes. The primary aim of thiswork is to investigate the influence of the scale formed on the walls of the pipes on the vibration parameters and naturalfrequencies of pipelines. To this end, the different phases of deposition are artificially simulated in the model experiments. In thedifferent states, vibration tests are preformed to evaluate the status of the pipe section and the rate of deposi...
Autori: Dénes Kocsis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26541

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract The effects of nitrogen (N) and phosphorus (P) addition to peatland ecosystem on emissions of nitrous oxide (N2O) were measured using the closed chamber method during one growing season within a peatland on the Tibetan Plateau. The highest N2O fluxes occurred during late spring (May), while fluxes of N2O were lowest during early autumn (September). No significant correlations were found between N2O emissions and soil temperature. Because of the sites stable hydrological conditions n...
Autori: Yongheng Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26626

Abstract Based on the spray mixing field-effect analysis method, this paper has taken into consideration the variation in the distribution of oxygen concentration in the combustion process and has put forward the combined combustion field-effect analysis method. The method is applied to the matching study of a certain kind of diesel engine’s combustion chamber with air admission and fuel injection parameters and can also be used to complete the simulation analysis and evaluation of mix...
Autori: Xiang-Rong Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26634

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract The present research reports the synthesis of poly-N-isopropylacrylamide / mesoporous carbon composites, prepared by radical polymerization of N-isopropylacrylamide inside mesoporous carbon pores functionalized with carboxylic groups. The deposition of poly-N-isopropylacrylamide on mesoporous carbon was confirmed by FT-IR spectroscopy, TEM, N2-sorption measurements. The mesoporous carbon material was found to adsorb vitamin B2 from aqueous solution at room temperature. The obtained ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26679

Abstract Wind erosion, which strongly affects both plant and soil development in arid environments, is dependent on soil properties, wind characteristics and plant cover. In a semiarid zone in SE Spain, a new technique consisting of dusting plants with a forced wind stream reduces tillage and significantly increases productivity. By using a blower once a year, dust is raised and partly retained by plants, and eventually ends up in the understory. To assess the influence of this technique on ...
Autori: Carlos Asensio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26735

Abstract The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life (EoL) treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and at the aim of their exploitation as valuable sources of raw materials. Within this study an integrated approach for waste electrical and electronic equipment (WEEE) end of life treatment is proposed based on the integration of hydrometallur...
Autori: Claudia Brunori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26777

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract New and end of life tires have been pyrolyzed in an innovative pilot plant that processes whole tires, thus saving the energy costs of shredding while allowing energy and materials recovery. Furthermore, the presence of a hydraulic guard guarantees high process safety. Several tests at different temperatures have been performed and the collected solid, liquid and gaseous products have been quantified and characterized. The influence of the maximum process temperature on yields and c...
Autori: Loris Giorgini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26783

Abstract The amount of collected Waste Electrical and Electronic Equipment (WEEE) in Europe is growing about 7 wt.-% per year (2007- 2012). It contains a number of economically relevant base, precious and high-tech metals. However, only a limited number of these metals can be recovered by currently applied recycling processes. Especially high-tech metals like gallium, germanium and tantalum get lost during the treatment of WEEE. The pyrolysis technology allows an accumulation of these metals...
Autori: Peter Hense
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26785

Abstract The identification of the critical source of nonpoint source pollution (NPS) plays an important role in formulation of Best Management Practices (BMPs). SWAT (Soil and Water Assessment Tool) was adopted for NPS nitrogen pollution modeling for Qinhuangdao City. The model was calibrated and validated by Sequential Uncertainty Fitting Version 2 algorithm of SWATCUP (SWAT Calibration and Uncertainty Programs) software. The model was used to quantify contributions of different nitrogen ...
Autori: Jihong Qu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26810

Abstract The recycling of plastic waste is important both in the conservation of resources and the environmental protection. A plastic waste (PE/PP/PS/PVC) was pyrolyzed over a series of post-use FCC catalysts using a fluidizing reaction system similar to the FCC process operating isothermally at ambient pressure. Experiments carried out with these catalysts gave good yields of valuable hydrocarbons with differing selectivity in the final products dependent on reaction conditions. A model ba...
Autori: Ta-Tung Wei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26836

Abstract The CoCrMo alloys have been widely used in artificial knee or hip joints. It is well known that these materials have a good corrosion resistance and acceptable biocompatibility properties. Zirconia as a ceramic biomaterial facilitates the osteoconductivity and tissue osteogenetic capacity in new bone formation around implant. Linear polarization and electrochemical impedance spectroscopy (EIS) were employed to characterize the electrochemical behavior of plasma sprayed yttrium oxid...
Autori: Manuela Romaş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26896

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

To explore the main sources and pathways of heavy metals entering fruits and the corresponding countermeasures, a field survey was conducted in Pujiang County, Zhejiang Province, China. The results showed that heavy metals in fruits came mainly from the use of foliar fertilizers, ripening agents, fungicides, pesticides, and other sprayed materials during the flowering and ripening stages. Therefore, a government program should be established to improve monitoring of agricultural products ente...
Autori: Bin Fang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26955

Zirconia (ZrO2) as a ceramic biomaterial facilitates the osteoconductivity in new bone formation around implant. Surface characterization before and after electrochemical testing was performed used scanning electron microscopy (SEM). The electrochemical properties of the yttrium oxide stabilized zirconium oxide (YSZ) coated and uncoated MgCa sample with the open circuit potential at different immersion time in Ringer’s solution were studied by electrochemical impedance spectroscopy (EI...
Autori: Bogdan Istrate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27021

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

Experimental research focus on the emission characteristics of a diesel engine employed a new combustion system-double swirl combustion system (DSCS) is carried out. The influence of spray angle on diesel emission characteristics with DSCS is analyzed by experimental and numerical method. Main emissions such as particulate matters (PM) and nitrogen oxidants (NOx) are measured in diesel engine with DSCS and the original engine. Also, fuel consumption, combustion pressure, heat release rate are...
Autori: Liwang Su
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27087

Membrane technology has become a fundamental unit operation in the industry and society of nowadays and fouling is, probably, the most important concern related with this technology. Fouling is a complex process that can limit the performances of facilities using membranes. Many research efforts have been done in order to reduce fouling tendency. Ceramic membranes can play a major role in fouling mitigation due to its high hydrophilic nature. This paper describes the characterization of a new...
Autori: Mihaela-Elena Dascalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27089

The main aim of this study is determination of sedimentology and sedimentary environment of Meighan Playa in the Markazi province in Iran. The purpose was to obtain information of sedimentary data and 94 samples of the sediments were collected from a wide range of Meighan playa in order to evaluate the conditions of deposition of the sediments in Meighan playa. With the goal of conducting a detailed and comprehensive study of the sediments in the playa, an attempt was made to collect samples ...
Autori: Mostafa Yousefi Rad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27103

Freshwater marshes are the single largest source of atmospheric methane (CH4). Climate change and anthropogenic nitrogen (N) deposition can alter the production and oxidation of CH4 respectively and thereby also CH4 exchange. But there was little known about how N regulate key carbon (C) processes, like CH4 production and oxidation under freshwater marshland conditions. In this study, field-fertilization and incubation experiments were conducted to investigate the effects of four N-fertilizat...
Autori: Lihua Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27107

The aim of this study is to investigate an innovative way to utilize the char obtained from tyres pyrolysis, in order to realize lightweight materials for building. Pyrolysis residue, mixed with three types of waste glass, has been used as raw material to obtain lightweight materials, exploiting its capability to behave as foaming agent. The results demonstrate that the pyrolysis char is a good foaming agent for the mixtures 50/50 with glassy sand and packaging glass waste, thermal treated at...
Autori: Fernanda Andreola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27119

In this paper low power microwave radiation impact on Zea mays root meristeme tissues was investigated. Seeds with uniform genophond were exposed for 3 hours at 10 W incident power level in controlled condition to continuous wave at three different frequencies (0.6 GHz, 1 GHz and 2.5 GHz) and let to germinate after electromagnetic exposure. Dosimetric assessment made experimentally and computationally allowed the proper energetic characterization of the interaction between vegetal tissue and rad...
Autori: Mihaela Răcuciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27196

Carbonaceous materials were obtained from waste tyres and their potential application as hydrogen sulphide adsorbents was investigated. The adsorbents were obtained by pyrolysis of waste tyres and physical (CO2) or chemical (KOH) activation at 550 and 800ºC. The effect of modification conditions on the performance of waste tyres based materials as adsorbents of H2S at room temperature in dry and wet conditions was investigated. Sorption capacity of such adsorbents was found to strongly depe...
Autori: Magdalena Hofman-Bieniek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27263

This study presents the results obtained in tailoring thin films of alumina, deposited onto aluminium substrates by spray pyrolysis, at 250°C, using AlCl3 solutions (0.15M) in a water:ethanol (1:1) solvent mixture. As morphology controlling agents, acetylacetone and maleic acid based copolymers are added in the precursors’ solutions. The precursors’ systems are analyzed by FTIR spectroscopy and the surface morphology of alumina thin films is investigated by atomic force microscop...
Autori: Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27291

Effective adsorbents were developed from sewage sludge by chemical activation with different activators (5M ZnCl2, 3M H2SO4, 3M H3PO4, 5M ZnCl2: 3M H2SO4, and 5M ZnCl2: 3M H3PO4). The developed adsorbents were used for the removal of the heavy metals Cd (II), Pb (II), Cu (II) and Mn (II) from wastewater. The effect of several parameters (pH, initial metal ion concentration, adsorbent dose, contact time and solution temperature) on the metal adsorption capacity were evaluated by batch experiments...
Autori: Mohamed Nageeb Rashed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27385

Soil erosion by water, sediment transport, sediment deposition and their impact on watershed area are complex processes. Therefore, the state of theoretical knowledge and mathematical modeling of them are still in an incipient phase. Most of the existing mathematical models are based on relations obtained either experimentally or in laboratory conditions, either in situ or physical models; because of existence of multitude factors involved in these processes and influence each other. These m...
Autori: Erika Beilicci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27449

Absorption of gases into liquids, with chemical reaction, is an important unit operation useful in many fields, especially synthesis of new products and waste gas treatment. Gas treatment means the separation of pollutants: acid gases, organic sulphur compounds, and other contaminants which may be found in gaseous streams. The absorption into liquid is a process almost exclusively used for removal of contaminants. The removal refers to retention of the majority of acid gases present in high conc...
Autori: Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27555

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

Social upgradation results more postconsumer glass and plastic waste and continuously demands newer techniques for their management. This research proposes a new waste-to-waste management strategy by using waste glass for polyolefin degradation. For this purpose, waste glass is activated by mechanochemical treatment and resultant material is used for the thermal pyrolysis of polyolefin. Certain improvement in the product quality is achieved by selectivity towards more alkane fraction. ...
Autori: Pooja Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27586

In this study, Ag/TiO2–P25 nanoparticles prepared via photodeposition method and its textural properties were characterized using X–ray diffraction (XRD), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS), and N2 physisorption techniques. The cements modified with TiO2–P25 and Ag/TiO2–P25 nanoparticles were immobilized on tile plates, and their photocatalytic activity was evaluated versus the removal of Erioglaucine as the model o...
Autori: Mohammad A. Behnajady
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27589

The thermal degradation of kenaf (Hibiscus cannabinus) under the effect of several variables (particle size, Ar flow rate, sample initial mass and heating rate) was investigated. From experimental data and by application of various model-free methods (Friedman, Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa), the activation energies (EA) were calculated as a function of conversion. The results obtained allowed to conclude that kenaf follows a multi-stage degradation mechanism, with EA values rang...
Autori: Silvia Román
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27617

In this paper the results of the aerosol flux measurements in near water boundary layer are presented. Measurements were conducted using two micrometeorological methods in the southern Baltic Sea region. The preliminary results of comparisons of two methods are discussed. The eddy covariance (EC) method is shown as a method for the calibration of the gradient method (GM). The reason for proceeding with such calibration is to show that the GM, which is an indirect measuring method, is comparable ...
Autori: Piotr Markuszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27630

This paper aims to pioneer the research into the dry nitrogen deposition in reservoirs serving as drinking water sources. For this purpose, several field experiments were performed to investigate the dry deposition in Xiaotaipingyang, Danjiangkou Reservoir (Henan) from September 2015 to August 2017. Sample concentrations were measured for NH4+-N, NO3--N and total dry deposition (TDN). Then, dry deposition flux of NH4+-N, NO3--N and TDN were estimated based on the measured concentrations and samp...
Autori: Luo Ling
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27749

According to recent estimations, the total yearly amount of end-of-life tyres (ELTs) arising in Europe exceeds 3 million tons; more than 95% are managed through mechanical and thermal treatments because ELTs represent a useful resource both of materials and energy. For this purpose, the goal of the present work is the assessment of the environmental impacts of a novel pyrolysis process and the comparison with alternative ELTs valorisation or disposal scenarios. Life Cycle Analysis (LCA) methodol...
Autori: Esmeralda Neri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27798

Ti/TiO2 films were prepared by DC reactive magnetron sputtering followed by annealing in air at 400 ºC for 4 h. Structural tests have been performed to characterize the films, showing that the prepared films present 70% of anatase phase. When these results are compared with those from TiO2 films grown on glass substrates with similar deposition parameters, it can be seen that Ti substrates favour the formation of rutile phase, which is not observed on the films supported on glass, indicatin...
Autori: Susana Sério
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27868

In this paper, an improved engineering model and analysis techniques are presented of the fly ash particles coagulation with droplets in Venturi tubes of industrial scale, based on spatial variation of the collection efficiency of particles on individual droplets, accounting for spray water flow polydispersity and particle size distribution, which allows to define optimal droplets size and spray water flow rate at different modes of thermal power units operation. The model is validated with the ...
Autori: Igor Volchyn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27836

The effect of synthesis conditions on sorptive properties of glycerol-derived mesoporous carbon materials were studied. Sorption properties of the synthesized carbon-based materials regarding to different adsorbate molecules, as well as water vapors, phenol and methylene blue molecules were analyzed. The sorption capacity of the synthesized mesoporous carbons depends upon synthesis conditions, namely upon pyrolyzing temperature and carbon precursor to silica weight ratio, being determined by ...
Autori: Maria Ignat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27880

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

The normal operation of spray humidification air cooler hinges on the good contact between droplets and air in the humidification chamber. The spiral pressure nozzle was chosen for the experiment on inlet air spray cooling. During the experiment, the spray cooling performance and atomization features were examined, and the cooling effects of different nozzle layouts were compared.Through the analysis of heat and mass transfer, the critical pressure of the spiral pressure nozzle was determined, a...
Autori: Xiaoqing Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28110

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Apart of new equipment’s development such as absorption columns with higher efficiency, for chemical industry, there is a strong need for greenhouse gases reduction in order to assure the environmental protection and, consequently, many studies regarding the purification methods of exhausted gases have been performed. There are several types of reactors used for gases purification, such as: bubbling jet reactor, combined packed and spray tower absorber, cable wet scrubber and packed column...
Autori: Elisabeta Droniuc Hultuana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28160

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162

Printed circuit boards are the most important component of any electrical and electronic device. The average metal content in waste printed circuit boards is ~30-35% whereas the rest of the material is a non-metal fraction (NMF). Metals in the waste printed circuit boards are recycled for their value whereas the NMF is mostly sent to landfills or incinerators for disposal. The circuit board laminates contain flame retardant chemicals that pose potential hazards to the environment and to public h...
Autori: Amit Dhir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28216

Car fluff is an important problem for the industrial compartment, especially for Italy, considering the huge amount of waste produced by the automotive sector, approx. 180.000 ton/year. Although car fluff (CER 191004) is suitable for CSS-Combustible production, with destination to cement factories, a very low amount of it reaches this destination. An alternative way to transform this problem into an opportunity consists into the transformation of bioliquid after its thermochemical transformati...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28289

Road dust from atmospheric deposition is considered as one of the significant environmental pollutants for containing toxic heavy metals. In this connection, to explore the present scenario of urban contamination and potential health risk of heavy metals present in road dust; this study was carried out in Tangail Municipality Area of Bangladesh. Road dust samples were collected seasonally from five different sampling sites encompassing different traffic homogeneity. Collected samples were proces...
Autori: Mir Talas Mahammad Diganta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28334