Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

Contain all the articles from this issue:ICEEM/01 -- Environmental Management Section Corporate environmental competence: A concept for characterising and assessing the environmental practice in companies and product chainsMichael S?¸gaard J?¸rgensen, Marianne Forman Life cycle assessment of some alternatives for the supply of thermal energy in the municipality of Iasi (Romania).Nicolae Peiu Management options for the industrial and municipal wastes in the city of Iasi Carmen Teod...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25169

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

Include urmatoarele articole:� Synthesis of Ferrierite/ZSM-35 type zeolite with ethylenediamine as template� Recovery of p-hydroxybenzoic acid from wastewaters by reactive extraction 1. Extraction mechanism and influencing factors� Relationships between metals extent and cytological characteristics at Prunus persica L. pollen� Smoke Emissions From Diesel Vehicles: A Case Study� Carbon dioxide generation - implications for romanian pulp and paper industry � Enhanced decolorization of ...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25208

AbstractThe aim of this work was to obtain Ag - doped zeolite as antibacterial material using natural and sodium form of zeolite from Mirsid Romania with the dimensions ranged between 0.8-1.2 mm. The comparative structural characterization of natural and Ag - doped zeolite were performed using Laser Induced Breakdown Spectroscopy (LIBS), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), and Infrared Spectroscopy (IR). In addition, the ion exchange total ...
Autori: Aurel Iovi, Corina Orha, Cornelia Ratiu, Florica Manea, Georgeta Burtica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25220

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

? Denitrifying activity of activated sludge in suspension and in biofilm? Denitrifying potential of an activated sludge derived consortium? Biosorption of hexavalent chromium based on modified Y zeolites obtained by alkali-treatment? Identifying anaerobic digestion models using simultaneous batch experiments? Olive mill wastewater as a renewable resource? Influence of innoculum acclimation in the biodegradation rate and estimated biodegradbility of cow manure, food waste and oil? Studies on the ...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25378

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

Abstract This paper presents the preliminary results of photocatalytic oxidation of humic acid from water using two types of catalysts, i.e., TiO2 and Ag-doped TiO2 modified zeolite (TMZ and Ag-TMZ). TMZ and Ag-TMZ, with zeolite granulation of 315-500 ?Źm was synthesized by sol-gel method, and the morphology and composition of the unmodified/modified zeolite were characterized by BET (Brunauer–Emmet–Teller) method, X-ray Diffraction (XRD), scanning electron microscopy (SEM) and energy dis...
Autori: Cornelia Ratiu, Carmen Lazau, Paula Sfirloaga, Corina Orha, Daniela Sonea, Stefan Novaconi, Florica Manea, Georgeta Burtica, Ioan Grozescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25397

Abstract Two types of zeolite-modified electrodes, e.g., Ag-doped zeolite-expanded graphite-epoxy (AgZEG) and Cu-doped zeoliteexpanded graphite-epoxy (CuZEG) composite electrodes were tested for the application of the electrochemical determination of 4-aminophenol (4-AP). The electrochemical techniques used for the electrochemical determination of 4-AP were cyclic voltammetry (CV) and chronoamperometry (CA). Some aspects related to the mechanistic behaviour are discussed. The electrochemical ...
Autori: Cornelia Ratiu, Carmen Lazau, Corina Orha, Ioan Grozescu, Aniela Pop, Daniela Sonea, Florica Manea, Georgeta Burtica, Joop Schoonman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25468

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract Chlorophenols were selected for this study because most of them are toxic and difficult to biodegrade. They represent a particular group of priority toxic pollutants listed by the US EPA in the Clean Water Act and by the European Decision 2455/2001/EC. The efficiency of advanced oxidation processes for degradation of chlorophenols has been extensively documented. The catalytic wet hydrogen peroxide oxidation process, involving oxidation with H2O2 and solid catalysts in mild reaction ...
Autori: Brindusa Dragoi, , Cezar Catrinescu, Daniela Arsene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25601

Abstract The structural modification of external surface of NaY was investigated in order to enhance efficient biosorption systems consisting of a bacterial biofilm, Arthrobacter viscosus, supported on that zeolite, for removing hexavalent chromium from aqueous solutions. The supported bacterial biofilm reduces Cr(VI) to Cr(III) and this cation is then retained in the zeolite by ion exchange. NaY zeolite was modified by alkali-treatments using NaOH 2.0 M, with two different contact periods of...
Autori: Bruna Silva, Cristina Quintelas, Hugo Figueiredo, Isabel C. Neves, Manuel F.R. Pereira, Teresa Tavares
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25637

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

The composite materials based on natural zeolite and undoped and N-doped TiO2, i.e., Z-Na-TiO2 and Z-Na-TiO2-N, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO2 and N-doped TiO2 nanocrystals were previously synthesized by sol-gel method. The X-rays diffraction results of TiO2 nanocrystals indicated that anatase TiO2 is the dominant crystalline type. The composite materials were structural and morphological characterized by X-ray di...
Autori: Cornelia Bandas (Ratiu), Carmen Lazau, Paula Sfirloaga, Florica Manea, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25911

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

Fly ash and fly ash based zeolites are inorganics used for improving soil quality. In the current paper, the hydrothermal modification of fly ash was studied. Three methods have been employed for this purpose. The first method involved the use of an autoclave, where synthesis has been performed at a temperature of 120 0C and a treatment time of 4 to 8 hours. Within the second method, the modification of the ash at a temperature of 600 0C by fusion was carried-out. In this method, a mixture of as...
Autori: Corneliu Munteanu, Daniel Bucur, Lacramioara Rusu, Maria Harja, Marinela Barbuta, Ramona Carla Ciocinta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25885

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

AbstractThe increased concentrations of priority pollutants in wastewaters have imposed the completion of conventional treatment withadvanced treatment stages (such as catalytic oxidation, membrane processes, adsorption, ion exchange, etc.) for their removal bychemical degradation and/or physical separation.In this study, 4-chlorophenol (4-CP) is proposed as model-pollutant for the priority organic pollutants present in syntheticwastewaters and several processes which can act as advanced treatme...
Autori: Carmen Teodosiu, Corina Petronela Musteret, Daniela Arsene, Daniela Cailean, George Bârjoveanu, Petru Apopei, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26022

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractThe reuse of a wastewater treatment system was investigated using intermittent media infiltration (IMI) to evaluate the fecalcoliform (FC) removal efficiency with natural zeolite containing clinoptilolite from the state of San Luis Potosí, Mexico and itszinc-modified form (Zeo-Zn). The municipal wastewater, which was from Saltillo, Coahuila, Mexico, was treated for FC analysisfor four months. The physicochemical properties of zeolite were analyzed, and their behavior as filter media for ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26212

AbstractLow water quality due to high levels of ammonia, chemical oxygen demand (COD), abnormal pH, and undesirable water color isprevalent in many prawn ponds in Malaysia. A composite medium used in the treatment of prawn pond effluent was examinedfor the reduction of undesirable parameters. The composite medium is a mixture of limestone, activated carbon, zeolite, and ricehusk. Experiments were conducted under three different conditions, i.e., sole aeration, adsorption, and adsorption with pre...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26219

AbstractThe possible recovery of three microelements contained in the sludges resulted after chemical leaching of uranyl ions fromuranium ores was investigated, using four types of zeolites as adsorbents. The variation of the retention degree in time of 3cations: Fe3+, Ti4+ and Ni2+, adsorbed on: ETS-10, ETS-4, ZSM-5 and mordenite was followed. The characteristic adsorptionparameters connected to Langmuir and Freundlich isotherms were also determined. For a given adsorbent, the rate of globalret...
Autori: Alexandru Cecal, Dumitru Gânju, Maria Ignat, Nicoleta Melniciuc-Puica, Petrisor Mugurel Samoila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26327

AbstractAmmonia pollution occurs frequently in urban water networks, which threatens the safety of water supply systems. Zeolite can beused for the removal of ammonium in the pretreatment of raw water for its peculiar adsorptive property to ammonium, but a largeamount of sludge from this measure could be a significant pollution source. In this work, the dewatering performance ofprecipitated sludge from the pretreatment of micro-polluted raw water was studied. Batch experiments of the simulatedco...
Autori: Bairong Zhu, Hao Chen, Huaizheng Li, Zhenliang Liao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26355

AbstractIn this study, TiO2-zeolite modified carbon nanotubes-epoxy (TiO2-Z-CNT-Epoxy) and TiO2-zeolite modified carbon nanofibersepoxy(TiO2-Z-CNF-Epoxy) composite electrodes were applied for pentachlorophenol (PCP) degradation and determination inaqueous solution. The morpho-structural characterization of the composite electrodes was studied by scanning electronmicroscopy. The electrochemical behaviour of the electrodes was investigated under UV irradiation presence/absence, usingcyclic voltamm...
Autori: Ágnes Jakab
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26491

AbstractThe alkylation of light hydrocarbons leads to produce the high octane number gasoline blending components. The homogeneouscatalytic alkylation reaction is usually carried out at low temperature in the presence of H2SO4 and HF. The use of heterogeneouscatalysis for this reaction is a promising solution for the replacement of hazardous acids to environmentally friendly zeolitecatalyst. The alkylation reaction of isobutane with 1-butene was studied on selected zeolite catalysts. The objecti...
Autori: Tatjána Juzsakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26514

Abstract The present work investigates the performance of Cristal-RightTM CR100 zeolite based on the equilibrium and thermodynamics water softening process. The commercial zeolite was characterized by scanning electron microscopy combined with energy dispersive X-ray spectroscopy and FT-IR spectroscopy. The equilibrium performances of zeolite were evaluated by the sorption capacity of calcium cations from calcium chloride solutions varying the calcium concentrations corresponding to moderate...
Autori: Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26670

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Water scarcity, the degradation of freshwater resources, and wastewater pollution are reaching crisis levels, especially in arid regions of the world. The reuse of wastewater was investigated by using intermittent media infiltration (IMI) to evaluate fecal coliform (FC) removal efficiency. Twelve IMI columns were packed with soil and natural filtering materials (sand, zeolite, vermicompost and charcoal) at percentages of 25, 50 and 75. The municipal wastewater was treated for the FC analysis ...
Autori: Sasirot Khamkure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26935

The present study was aimed at examining the ability of the natural zeolitic tuff from the Zlatokop deposit in Serbia to remove Pb(II) ions from aqueous solutions under various conditions. It has been found that the adsorption proceeds via an ion-exchange reaction in which the Na+ ions from the clinoptilolite phase of the tuff are replaced to a high degree by aqueous Pb(II) ions. The removal capacity of the clinoptilolite at 298 K varies from 78 mg Pb g–1 (for C0 = 100 mg Pb dm–3) to...
Autori: Djordje Stojakovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27234

Reuse of grey water is an attractive option when available water supplies are limited, and can reduce demand on water supplies and provide additional water resource. This comparative research was conducted to assess the suitability and effects of reusing grey water, treated and untreated, as irrigation water for vegetables, compared with tap water. Tomato (Lycopersicon esculentum) and green bean (Phaseolus vulgaris) plants were selected as examples. The collected grey water samples were treated ...
Autori: Jehad Y. Al-Zou by
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27254

Pharmaceuticals contaminants in waters exhibit a significant threat on the human health and the ecosystem quality. This research demonstrates the utility of a silver-doped zeolite-modified carbon nanofiber-epoxy (AgZ-CNF) prepared by two-roll mill method in development of the fast methodology for the detection of fluoxetine (FXT) in the aqueous solution. The results showed the role of zeolite that improved the sensitivity and the limit of detection of FXT resulted to the possibility to propose a...
Autori: Magdalena Ardelean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27328

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

The negative effects of acid mine drainage (AMD) on the natural and human environments are well understood in South Africa, yet a robust and economic AMD treatment technology has not been developed. The current study aimed at exploring the performance of synthetic zeolite F9 in AMD treatment with specific focus on iron and manganese removal. For this, batch adsorption mode was adopted for which the effects of adsorbent dosage, initial pH and temperature were investigated. As a result, it was fou...
Autori: Mike Masukume
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27454

A low-cost magnetic zeolitic material was synthesized from coal fly ash by means of a new, simple method involving alkaline hydrothermal zeolitization of fly ash (FA) followed by low-intensity wet magnetic separation. Scanning electron microscopy with energy-dispersive X-ray analysis was applied to characterize the composition, microstructure, and morphology of the material. The mineral and synthetic zeolite phases were identified by powder X-ray diffraction. The obtained magnetic zeolitic m...
Autori: Annie Shoumkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27486

This study evaluated the performances of adsorption and Fenton oxidation for the removal of multilan red (MLR) and multi-active blue (MActB) dyes from aqueous solution. Zeolite, the adsorbent used in the study was modified using two surfactants: hexadecyltrimethylammonium bromide (HDTMA-Br) and cetyltrimethylammonium bromide (CTAB). The modified zeolite characterized using FTIR, SEM and XRD analysis. The modification studies revealed that HDTMA-modified zeolite exhibited better performance than ...
Autori: Jacob Kitinya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27505

Chemical oxidation of pyrite and chalcopyrite by ferric sulfate (Fe2(SO4)3) solution and biogenic ferric iron obtained by mixed culture of isolated thermotolerant Acidithiobacillus sp. 13Zn and Leptospirilum ferriphilum CC immobilized on natural carriers- zeolite and shungite was studied. Oxidation rate of sulfide minerals was estimated by the decrease of Fe3+ (oxidant) and increase of Fe2+ ions in the solution. It was revealed that chemical oxidation of chalcopyrite by biogenic ferric iron occu...
Autori: Arevik Vardanyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27563

Clinoptilolite (Clin), the most widely used natural zeolite in environmental applications, was used as soil additive to investigate its effectiveness in protecting and improving the quality of soils that received surface disposal of OMW, as well as in limiting nutrients leaching from the degraded soils. Clin was added in a batch experiment of 18 months, where OMW were added in evaporation ponds and on soil for a period of more than 12 years. The zeolite was added as dust (particle diameter &l...
Autori: Maria K. Doula
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28018

NaA zeolite was successfully synthesised from fly ash through hydrothermal process. The synthesised NaA zeolite was modified with Li+, Ca2+ and Mg2+ through ion exchange at a temperature of 60 °C and contact times of 1 h and 4 h. In this study the crystallinity of the synthesised NaA as well as its modified (LiA, CaA and MgA) was evaluated towards CO2 adsorption capacity using temperature programmed desorption (TPD) process at low temperature (40-150°C) and high temperature (150-700°...
Autori: Muvumbu Jean-Luc Mukaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28175

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249