AbstractThe paper describes the synthesis and characterization of layered double hydroxides (LDH) intercalated with 4,6-dinitro-o-cresol(DNOC) and 2,6-dichlorobenzonitrile (2,6DBN) by anionic exchange method. The incorporation of the organic pesticides in the structure of layered double hydroxides can offer premises to increase the pesticide active life by reducing its volatilization, controlling the release of the pesticide from the layered structure and decreasing the pesticide adsorption in s...
Autori: Gabriela Lisa, Marcel Ionel Popa, Mihaela Frunza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25144

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractThis paper presents an overview of research related to use of surfactant modified natural zeolites (SMZ) in water and wastewater treatment. The most common natural zeolite, widely used as starting material is clinoptilolite, but other natural zeolites have also been used (chabasite, heulandite, mordenite). In the first part, the preparation methods and the influence of process parameters on the final product properties is reviewed. The discussion is focused on the influence of surfactant...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25241

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract This paper presents an experimentally study of the anionic iodide separation from a mixture with immobilized liquid membrane. The experiments were carried out in a double jet installation. In order to intensify the transfer of iodide ions from the source phase to the receiving phase, the both phases are dispersed as droplets in the membrane and the hydrodynamic parameters of the dispersed phases are measured with the photographic method. The photos of the droplets were taken with a C...
Autori: Mihaela Emanuela Craciun, Mihaela Mihai, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25476

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractIn spite of the fact that concern on water quality protection raised in the last decades heavy metals pollution still represents agreat threat for both human health and environment quality. Ion exchange proved to be an effective technique for industrialwastewaters treatment, as long as it ensures an effective recovery of valuable compounds. The main purpose of this work is toassess the performances of a commercial ion resin sort (a strong basic anionic resin – VIONIT AT 21), to remove ch...
Autori: Alexandra Raluca Miron, Cristina Costache, Cristina Modrogan, Dumitru Giani Apostol, Oanamari Daniela Butucea, Redha Kouachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26025

Abstract After any treatment process of wastewater results residual sludge that is characterized depending on the type of the wastewater or by the sludge treatment type. The sludge treatment process can be divided in three important stages: the preliminary stage (with the sludge thickening), the stabilization stage, and the dewatering stage. The paper shows the results of the research for the identification of the most efficient organic cationic flocculants, which might be used wit...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26149

AbstractThe sludge treatment processes represent a priority when we refer to the municipal wastewater treatment, but can implicate verycomplex studies and applications if we consider the industrial wastewater recovery and treatment processes. Even if the industrialsludges are seen as wastes, they can represent an important resource if are properly managed in the storage, treatment andrecovery processes. This paper aims to identify some methods to optimize the coagulation and flocculation process...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26444

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract Co(II), Cd(II) and Rh(III) complexes with 2-(1H-1,2,4-triazol-3-yl)pyridine (Htzp) as ligand were synthesized and investigated. The neutral mononuclear complexes with a generic [M(tzp)n] structure have been prepared from Htzp and corresponding transition metals chlorides at 2:1 and 3:1, respectively molar ratios in H2O–EtOH. The resulted crystalline complexes were investigated through magnetic and molar conductivity measurements, elemental analysis, FT-IR, mass spectroscopy, t...
Autori: Petronela Horlescu
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26652

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

The flocculation process is applied in wastewater treatment to separate the destabilized colloid particles (or the particles formed during the coagulation phase) by forming flocs. The scope of this research was to identify the predictability of the synthetic organic flocculants use for industrial wastewater treatment. The research was performed at small scale, in laboratory, but also at industrial scale, by applying the synthetic organic flocculants in a real industrial wastewater treatment p...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26975

In this work, magnetic alginate was synthesized by encapsulating of Nickel Zinc Ferrite nanoparticle within Ca-alginate. The synthesized magnetic alginate was modified by ethylenediamine using microwave radiation to remove anionic dye from wastewater. The characteristics of magnetic nanoparticle, magnetic alginate and magnetic alginate amide (MAA) were studied using Fourier transform infrared (FTIR) and Scanning electron microscope (SEM). FTIR analysis confirmed the amidation of alginate. Di...
Autori: Niyaz Mohammad Mahmoodi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27424

Three different synthetic textile dyeing wastewaters were treated by a chemical coagulation/flocculation process, using ferric sulphate as coagulant. Polyacrylamide (Magnafloc 155) and polyamine (Superfloc C-573) based flocculants were applied. The influence of pH (between 3.5 and 10.4) and Fe3+ concentration (from 15 to 4000 mg/L) in both color and dissolved organic carbon (DOC) removal of polyester, cotton and acrylic dyeing wastewaters was assessed in the coagulation stage. As far as floc...
Autori: Carmen S.D. Rodrigues
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27427

In the present work, the removal of anionic phosphate from aqueous solution by electrocoagulation (EC) process using aluminium electrodes was carried out. Batch studies were carried out to investigate the influence of different operating parameters (supporting electrolyte concentration, pH, spacing between electrodes, applied voltage, electrode area, and initial concentration of phosphate) on removal of phosphate from aqueous solution. The initial value of pH was varied from 3 to 8, while the co...
Autori: Sarasan Seena Mithra
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27458

In this study, the flocculating properties of different cactus juice preparations were assessed using synthetic and real industrial and leachate wastewaters. It was found that the crude CJ had a flocculating activity (FA) of 89 ± 2.2% which is significantly higher than that of a powdery sample derived from a 60°C oven-dried CJ sample and which was about 37.8 ± 2.5%. Interestingly, both crude and dried samples showed the ability to flocculate kaolin suspensions within a wide ...
Autori: Moncef Khadhraoui
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27887

The native and surface modified adsorbents from agricultural waste, such as Psyllium stalks (PS) were investigated for their ability to remove the Coomassie Brilliant Blue (CBB) dye from aqueous media. The native and surface modified adsorbents were characterized by the Fourier Transform Infrared spectroscopy (FTIR). The results show that the Sodium Bicarbonate Treated Carbon (SBTC) has good surface properties for the removal of the CBB dye from aqueous media. The SBTC was analyzed by Scanni...
Autori: Premkumar Manickam Periyaraman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27898

In this work, the examination of separation of gypsum from wastewater generated during the machining of casts and the method of waste gypsum management have been presented. This waste gypsum is produced in Ortolab Poland facilities. Gypsum casts are cut and ground in water-cooled circular saws. Wastewater, with over-normative content of suspension, 10000 mg L-1 and sulphates, 1600 mg L-1 is produced in the process. The analysis of water and wastewater management in Ortolab Poland facilities l...
Autori: Ewa Liwarska-Bizukojc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27910

This paper deals with the degradation kinetics of an anionic surfactant (sodium dodecyl sulfate, SDS) under UV and UV-H2O2 advanced oxidation process (AOP). Experiments were performed in a batch reactor which emits monochromatic light centered at 253.7 nm. The photon flux of the UV reactor was 1.9(±0.1)×10-4 Einstein/L-min. Under direct UV, only 45% SDS degradation was observed at a fluence of 40.65 J/cm2 for initial SDS concentration of 0.35 mM. The apparent fluence-based pseudo...
Autori: Bijoli Mondal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28013

To produce drinking water, the water treatment plants generate huge quantities of sludge, this sludge is a waste and they are evacuated to the dump. The valuation of these sludge will be benific This study focuses on the development of composite alginates beads and sludge activated chemically by sulphuric acid and thermally for the removal of dyes from aqueous solutions. Two dyes were studied; a basic cationic dye (methylene blue) and an acidic anionic dye (Congo red) to compare the adsorption m...
Autori: Hasna Elmontassir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28125

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

Impregnation of aluminium ion onto silica gel (SG) surface (Al/SG) is to increase the adsorption capacity of an anionic dye such as Indigo carmine (IC). The impregnation was carried out using wetness impregnation. The change of the functional group was evaluated by FTIR, crystallinity was determined using XRD, surface morphology were studied by SEM-EDX, while surface area and pore size using N2 gas adsorption-desorption analyzer. Meanwhile, the best of IC adsorption condition onto SG and Al/SG ...
Autori: Yudi Aris Sulistiyo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28253