AbstractThis paper reviews some practical aspects of the application of algal biomass for the biosorption of heavy metals from wastewater. The ability of different algal species to remove metals varies with algal group and morphology, with the speciation of specific metals and their competition with others in wastewater, and with environmental or process factors. The scattered literature on the uptake of heavy metals by both living and dead algal biomass - both macroalgae and immobilized microal...
Autori: Loredana Branza, Maria Gavrilescu, Matthew J. Dring
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25133

Include urmatoarele articole:� Removal of persistent organic pollutants from textile wastewater by membrane processes� Sustainability evaluation of an urban residential settlement� Removal of zinc (II) from aqueous solutions by romanian sphagnum peat moss� Development trends of cold plasma reactors in the global context of carbon emission reduction� Assessing the potential of wind power in Romania within Kyoto targets� Research on the impact induced in the environment by milk process...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25198

AbstractBiosorption an alternative process is the uptake of heavy metals from aqueous solutions by biological materials. The biosorption of nickel ions from aqueous solution was investigated by Nordmann fir (Abies nordmanniana (Stev.) Spach. subsp. nordmanniana) in a batch adsorption system as a function of pH, initial metal concentration, biomass dosage, contact time. The data showed that the maximum pH for efficient sorption of Ni(II) was 6.5. At the optimal conditions, Ni(II) ion biosorption ...
Autori: Handan Ucun, Ozkan Aksakal, Yusuf Kaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25295

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract The present paper proposes an integrated-treatment process of leachate from a municipal landfill, which involves two treatment steps. The first step consists in diminishing the organic content through an advanced oxidation process using ozone and hydrogen peroxide. The second step is performed in order to diminish the content of heavy metals through a sorption process on a natural low-cost biosorbent, thus the traces of organic substances remained after oxidative degradation or oxida...
Autori: Carmen Paduraru, Corneliu Pohontu, Igor Creţescu, Lavinia Tofan, Marius Sebastian Secula, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25589

Abstract The use of biomaterials as biosorbents for treatment of wastewaters will provide as a potential alternate to the conventional treatment methods. The main advantages of biosorption are high selectivity , cost effectiveness and good removal performance. World wide numerous low cost bio materials have tried for biosorption of dyes. In this present investigation, the dead biomass of Penicillium sp. fungus and wood sawdust was used as biosorbents and their capacity to removed malachite gr...
Autori: Cornel Pohontu, Florin Luca, Igor Creţescu, Manea Liliana, Mariana Diaconu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25593

Abstract The structural modification of external surface of NaY was investigated in order to enhance efficient biosorption systems consisting of a bacterial biofilm, Arthrobacter viscosus, supported on that zeolite, for removing hexavalent chromium from aqueous solutions. The supported bacterial biofilm reduces Cr(VI) to Cr(III) and this cation is then retained in the zeolite by ion exchange. NaY zeolite was modified by alkali-treatments using NaOH 2.0 M, with two different contact periods of...
Autori: Bruna Silva, Cristina Quintelas, Hugo Figueiredo, Isabel C. Neves, Manuel F.R. Pereira, Teresa Tavares
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25637

Biosorption of lead (II) onto the biosorbent, represented by untreated S. cerevisiae and NaOH-treated S. cerevisiae was examined and the effects of contact time were investigated. The lead (II) biosorption was fast and equilibrium was attained within 90 mins. The maximum removal ratios of lead (II) for untreated S. cerevisiae and NaOH-treated S. cerevisiae after 3 h were 48.6% and 92.5%, respectively, with initial lead (II) concentration of 40 mg/L and optimum pH of 5.0. Data obtained from batch...
Autori: Ying Zhang, Yingjie Dai, Baiyin Liu, Fang Ma, Ru Zheng, Limin Donghttp://www.ecozone.ro/reviste.php?RID=25670

Abstract:The aim of the present study is the optimization of biosorption conditions using a metal tolerant actinomycete (strain 723) for the removal of lead ions from waste water in batch and dynamic flow mode. The optimum conditions for lead biosorption by the strain were determined as initial pH 3.0, biomass amount 2.0 g L-1, and initial metal concentration 400 mg L-1 in the batch condition. The maximum lead biosorption performance was obtained with a 19 mm diameter column, a 1 mL min-1 flow r...
Autori: Ayşe Betül Karaduman, Maria Julia Amoroso, Mustafa Yamaç, Sergio Antonio Cuozzo, Zerrin Pat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25811

AbstractZinc is an important metal for humans and the environment. Its intensive application in industry has led to water and soilcontamination. A lot of microorganisms both unicellular and multicellular can be applied for removal of metals from theenvironment. The process of zinc adsorption by cyanobacteria Spirulina platensis biomass was investigated. The concentrationsof 0.34 mM and 3.4 mM of ZnSO4ˇ7H2O were used. The process of biosorption of zinc was studied during 1-hour experiment.To dete...
Autori: Gheorghe Duca, Inga Zinicovscaia, Liliana Cepoi, Marina V. Frontasyeva, Sergey S. Pavlov, Svetlana F. Gundorina, Tatiana Chiriac, Valeriu Rudic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26041

AbstractThe biosorption characteristics of Cd(II) ions using the NaCl-treated Ceratophyllum demersum were studied. The effect ofaltering the conditions, such as solution pH, the biosorbent dosage and contact time for the biosorption of Cd(II), and thebiosorption/desorption studies, were investigated. Langmuir, Freundlich, Dubinin-Radushkevich and Redlich–Peterson modelswere applied to describe the biosorption isotherms. Langmuir model fitted the equilibrium data better than the other isotherms(R...
Autori: Ali Akbar Babaei, Mehdi Ahmadi, Nadali Alavi, Nemat Jaafarzadeh, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26331

AbstractIn the present work, the kinetics of amaranth dye biosorption onto the roots, stems, leaves and the whole plant of water hyacinth(Eichhornia crassipes) were studied for differential evaluation of the plant’s biosorptive potential to remove the toxic dye fromaqueous solutions. E. crassipes´ leaves showed the highest level of amaranth dye biosorption (43.1 mg/g), followed by the entireplant (31.18 mg/g), the roots (28.51 mg/g), and finally by the stems (23.97 mg/g). The same differential t...
Autori: Imelda Guerrero-Coronilla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26463

Abstract In the present work, the removal of cadmium ions from aqueous solution using an agricultural waste as biosorbent, namely trunk palm fibers was investigated. The adsorption equilibrium and kinetics for this system were studied. Four adsorption models were applied to understand the nature of the adsorption process. Freundlich adsorption isotherm was found to best fit the experimental data. The maximum adsorption capacity was found to be 23.8 mg/g. The adsorption process was found to b...
Autori: Hosam Altaher
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26699

Abstract The removal efficiency of algal biomass Chlamydomonas reinhardtii for Pb and Cu metal ions was evaluated in single and binary metal systems. Biosorption experiments were performed in solutions containing 0.2 g L-1 of algal biomass at 30oC and pH 6. Initial metal ion concentrations ranged from 10-7 M to 10-6 M. Thermal analysis of the biosorbent indicated that algal cells are composed of groups containing C, H, N, and S. The presence of ionisable functional groups responsible for bio...
Autori: Roula Flouty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26709

Abstract Adsorption has proved to be an excellent way to treat industrial wastewater, due to its significant advantages like easy availability, inexpensive, ease of operation and highly efficient, compared to conventional expensive adsorbents like activated charcoal, alumina etc. The present investigation focused on utilization of Mangifera indica seed shell substrate for the removal of toxic heavy metals like Fe(II) and Mn(II) from wastewater. Mangifera indica seed shell substrate as an eff...
Autori: Tikaram D. Kose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26713

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract Free cells of Rhizopus oryzae were used to study adsorption of several cations (Cu2+, Zn2+, Mn2+, Ni2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The influence of biomass dosage, pH and temperature on the removal process was investigated. The sorption efficiency increased with increasing the temperature in the range from 25 ºC to 30 ºC and pH from 5 to 8. The maximum removal percentage was achieved at a biosorbent concentration 0.25 – 0.3...
Autori: Kolishka Tsekova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26857

Abstract This study concentrates on the reactive biosorption of dyes such as Reactive Red 3:1 (RR3:1), Reactive Orange 13 (RO13), Reactive Blue 13 (RB13), Reactive Blue 72 (RB72). The modified fungal biosorbent, Paecilomyces sp., had a higher dye biosorption yield in our study. 100% of biosorption yield observed on RR3:1 and RB13 and 94.09% of color removal of RO13 with the chemically modified biosorbent were great. Also, such modified biosorbent exhibited remarkable performance in simulate...
Autori: Ahmet Çabuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26860

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

This study highlights the potential use of yellow Zea mays seed chaff (YZMSC) biomass as a biosorbent for the removal of Cr3+, Cd2+ and Pb2+ ions from aqueous solutions. Fourier transformed Infrared analysis of the biomass suggests that YZMSC biomass is basically composed of cellulose and methyl cellulose. The biosorption capacities, qmax, of YZMSC biomass for Cr3+, Cd2+ and Pb2+ are 14.68, 121.95 and 384.62 mg/g respectively. Biosorption equilibrium was achieved at 20, 30 and 60 min for Cr3+...
Autori: Jonathan Oyebamiji Babalola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27083

Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by local low-cost agricultural by-products – peanut hulls, soybean shells and grapefruit peels were compared to develop high-efficient and low-cost biosorbents for removal of lead(II) from wastewater. Batch kinetics showed adsorption equilibrium at about 90 min and the adsorption process for the three biosorbents was better represented by the pseudo-second-order model than the pseudo-first-order model. Batch equilib...
Autori: Rui Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27176

The adsorbent gels utilized in this research project were synthesized from non-commercially available chitosan, obtained by deacetylation of chitin, which was isolated from fermented shrimp waste by a major local industrial food biopolymer. Chitosan-based adsorbent gels were used for the removal of a tris-azo dye (Direct Blue 71) from aqueous solutions. Sorption experiments focused on the chemical modification of chitosan using two cross-linking agents, sodium tripolyphosphate (TPP) and glutaral...
Autori: Reyna G. Sánchez-Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27184

In this study, the biosorption of zinc(II) ions from the aqueous solutions by the lichen biomass of Xanthoria parietina (L.) Th. Fr. was studied as a function of contact time, initial pH of metal solution, biosorbent concentration, initial metal ion concentration and stirring speed in a batch system. The optimum pH value for maximum zinc biosorption was found to be 5.5. Concentrations intervals from 50 mg/L to 250 mg/L were tested and it was observed that the biosorption efficiency depends on th...
Autori: Zuleyha Bingul
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27213

Banana stalk (BS) waste is used to remove Pb2+ from aqueous solution. Equilibrium data were analyzed with Langmuir and Freundlich adsorption models, which fit better in the former equation. The qmax (maximum metal uptake capacity) for Pb2+ adsorption was 105.14 mg/g of BS at pH 5.0, which followed pseudo-second order kinetics model. IR spectra confirmed the participation of hydroxyl, amino, and acidic functional moieties in the removal of Pb2+. The major mechanism involved in the biosorption of ...
Autori: Kashif Iqbal Sahibzada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27214

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

In this research, the capability of uranium biosorption by dried biomass of the red algae was investigated in a batch system. For the screening of the most appropriate biosorbent, they were placed in 0.5 mmol/L uranium solution with different pH for 3hrs of contact times. The obtained results showed that the species of the Gracilaria corticata (J. Agardh) are having the maximum rate of the biosorption. Sorption equilibrium was reached within 3hrs of contact time (at pH 4.5), and the results of t...
Autori: Reza Dabbagh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27596

This paper aims to compare the adsorption performance of activated carbon and pine bark for iron and manganese removal from contaminated groundwater. Moreover, their environmental compatibility was checked for their possible use as reactive media in a permeable reactive barrier for in situ remediation. Batch tests were carried out with different iron and manganese concentrations and different particle-size distributions, in order to evaluate the effectiveness of the activated carbon and pine bar...
Autori: Silvia Sbaffoni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27779

Debris from deciduous trees in the form of park green waste was investigated as a potential biosorbent for the removal of chlorinated solvents from water. The sorption properties of beech leaves and cupules, oak leaves and acorns, birch leaves and lime leaves (all tree species common for a moderate climate) in a non-modified form were investigated with regard to the removal of perchloroethylene, 1,1,2-trichloroethane and 1,1,1,2-tetrachlorothane. The preliminary results showed that these biosorb...
Autori: Marek Tobiszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27760

Heavy metals are inorganic persistent pollutants with adverse health and environmental effects. In our study, self-synthesized iron oxide magnetic nanoparticles were encapsulated in the Phanerochaete chrysosporium (P. chrysosporium) hyphae. The prepared biosorbents possessed high efficiency for Pb(II) biosorption from single and binary metal systems. The maximum biosorption capacity was found to be 50.05 mg g–1 at pH 5.0. Environmental scanning electron microscope accompanied with energy d...
Autori: Danlian Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27864

The macrophyte Pistia stratiote was used as biosorbent for the removal of Black Krom KJR (BK-KJR) dye in synthetic aqueous solution. Initially, some tests were performed to verify the best operational conditions such as pH, biosorbent particle size, sorption temperature and stirring speed, which were later used in the kinetic and equilibrium tests. All tests were performed in duplicate. The highest removal rates of the pollutant were achieved at the process conditions of initial pH 2, granulo...
Autori: Aparecido Nivaldo Módenes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27843

The performance, in terms of sorption properties, of the two natural sorbents were compared with the commercial synthetic sorbent Fibroil. The experiments were conducted using two continuous setups of filtration under dynamic conditions. Experimental results revealed that the removal of chemical oxygen demand (COD) was 89%, 87% and 37% for Fibroil, Schoenoplectus lacustris and Acorus calamus respectively in a down-flow filtration, while with the up-flow filtration the removal efficacy of COD wa...
Autori: Zineb Chaouki
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28141