A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

AbstractThe corrosion behaviour of three commercial nickel-chromium based dental materials was investigated by electrochemical methods in a corroding mixture of sodium chloride, oxalic acid and lactic acid. In order to establish electrochemical parameters of the corrosion process, linear and cyclic polarization curves were plotted. The samples performances in the corroding system were investigated by weight loss, pH and electrical conductivity measurements. The quantitative analysis related with...
Autori: , Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25132

AbstractFlocculation performance of three chitosan samples with different viscosities (?§ = 400, 800 and 1000 mPas) and two strong synthetic polycations of integral type (PDADMAC and PCA5) on two model aqueous suspensions (kaolin and bentonite) was investigated. The flocculation results indicated that all the polycation samples were efficient in the kaolin flocculation, the turbidity being completely removed at approximately the same polycation dose; the flocculation window ranged between 2.7 an...
Autori: Ecaterina Stela Dragan, Luminita Ghimici, Marcela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25201

AbstractElectrochemical impedance spectroscopy (EIS) measurements were used to characterize the electrochemical behaviour of the some commercial dental alloys: two PdAg based alloys (Paliag, PaliagMaestro), two NiCr based alloys (Wirolloy, VeraSoft), two CoCr based alloys (Vitallium, VeraPDI) and two CuAl based alloys (Gaudent, NPG+2) in artificial saliva. Impedance spectra were represented in the form of Bode plots and it was fitted using a commercial softwere package called Electrochemistry Po...
Autori: Daniel Mareci, Gina Ungureanu, Julia Claudia Mirza Rosca, Neculai Aelenei, Romeo Chelariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25143

AbstractCatalysts having mobile electrons in bulk such as metals and semiconductors are good solid materials for red/ox type of reaction (oxidation) and can be effectively used in gas sensing devices as well. The aims of this work were: (i) to investigate the surface behavior of Pt(0.28%)/Al2O3 and SnO2(2.94%)-Pt(0.28%)/Al2O3 samples in inert atmosphere (He) and in reducing atmosphere containing helium-cyclopropane gas mixture under ambient condition (i.e., room temperature, atmospheric pressure...
Autori: , Cornel Munteanu, Jozsef Kovacs, Mariana Scurtu, Monica Caldararu, Tatiana Yuzhakova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25146

Contain all the articles from this issueEnvironmental analysis by capillary electrophoresis. Atmospheric samplesCamelia Draghici, Gheorghe Coman, Mihaela Sica,Dana Perniu, Mihaela Badea   The ecological farms - A solution for sustainable agriculture. II. Position and perspectives of the ecofarms in the frame of the productive agricultural system Stela Axinte, Alina Stanciu, Lorica Axinte  The extraction and clean up of organochlorine pesticides and PCB's from water using solid phase ex...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25170

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractThe paper presents original results concerning concentrations of eight heavy metals in soils adjacent to two improperly built municipal waste deposits located in Eforie Sud and Techirghiol, Constanta County, Romania. Measurements have been done on surface and depth soils, during April-October 2006. The applied analytical technique for metal determination was flame atomic absorption spectrometry (FAAS). The mean measured values ranged as follows (in mg/kg dry weight): Cd: 0.09 - 0.15; Co:...
Autori: , Elisabeta Chirilă, Narcisa Elena Ilie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25213

AbstractThis paper dealt with Cr(VI) sorption on isomorphic substituted Mg/Zn-Al - type hydrotalcites under proper working conditions. The prepared samples were named Mg3Al, Mg2ZnAl, Mg1.5Zn1.5Al, MgZn2Al and Zn3Al. The experimental data concerning sorption isotherms were modelled in accordance with four equilibrium equations: Langmuir (L), Freundlich (F), Langmuir-Freundlich (L-F) and Redlich-Peterson (R-P) by using two ways: (i) estimation of qmax, K and n; and (ii) estimation of K and n, for ...
Autori: Aurel Iovi, Eveline Popovici, Laura Cocheci, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25215

AbstractThe perovskite structure was synthesized by sol-gel method type citrate. Three perovskite LaMnO3 samples were obtained after calcination and were characterized by XRD, XPS and TPR. The catalytic testing was carried out in SCR-HC equipment (HC=C3H6 and C3H6 respectively) in presence and also in absence of oxygen atmosphere. The results pointed out a good activity in NOx reduction but only in oxygen absence. As it was expecting, LaMnO3 perovskite has shown a good activity for hydrocarbons ...
Autori: Helmut Papp, Ion Balasanian, Liliana-Mihaela Chirilă, Wladimir Suprun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25222

AbstractSome industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the s...
Autori: Alina Soceanu, , Simona Dobrinas, Vasile Magearu, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25227

AbstractBased on the polarization curves and electrochemical impedance spectroscopy (EIS) in the case of three commercial alloys (Wirolloy, NicromalSoft and VeraSoft) maintained in artificial saliva, it was established the type and the intensity of the corrosion process by means of the corrosion currents value. The passivation of all the samples occurred spontaneously at the open circuit potential. The corrosion currents value decrease after the alloys maintenance in the corrosive medium due the...
Autori: Daniel Mareci, Gina Ungureanu, Julia Claudia Mirza Rosca, Neculai Aelenei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25235

AbstractPolycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector ...
Autori: Alina Soceanu, , Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25237

AbstractThe removal of formasine fines particles from water by precipitation with polyelectrolyte and surfactant complex of Polyacrylamide (industrial product Praestol 611 made by Degussa) and Sodium Lauryl Sulphate (SLS) was experimentally studied. Calcium oxide was added to initiate precipitation of the polyelectrolyte complex together with the fines particles. The experiments were carried out with complexes having the surfactants concentration higher then the critical aggregation concentratio...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25238

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractThe crystallization of ferrierite/ZSM-35 zeolite at 180 Âą 50C in the presence of ethylenediamine as a structure-directing agent from reaction mixtures containing various active NaOH/SiO2 ratios has been studied. X-ray diffraction, scanning electron microscopy, TG/DTG/DSC analysis, nitrogen sorption measurements and temperature-programmed ammonia desorption were used to characterize the ferrierite/ZSM-35 solids. The XRD data reveal that the samples synthesized in optimized conditions are...
Autori: Ioana Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25251

AbstractThis paper deals with a statistical treatment applied to the determination of U(VI)/U(IV) ratio in some uranium ores, depending on the pH and humidity samples taken out directly from a uranium mine. The concentrations of different uranium species were determined spectrofotometrically. Some statistical parameters were calculated for a subsequent statistical interpretation of the experimental data....
Autori: Alexandru Cecal, Gabriel Barbir, Marian E. Răileanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25255

AbstractIn this study, we follow the chrome distribution and his association forms with mineral and organic components, from 14 soilsamples from industrial zone of IaÂ?i city.The total chrome concentration in studied soil samples varied between 11.73-129.35 μg/g, being lower than the normal values only for four samples. The Cr(VI) weight of total chrome content varied between 3.78-14.52 %. For none of studied soil samples the chrome content is not over to value of alert concentration. The q...
Autori: Constantin Rusu, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25260

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

AbstractThe aim of this paper was to accurately analyze the sources of water pollution and loading concentrations in textile finishing mills. A process data collection was performed and integrated with a characterization of the process effluents in terms of treatability and reusability. In order to evaluate properly the wastewater loading, an analysis course was set. The samples have been gathered for two months; instantaneous samples (PI) were drawn from the wastewater, as well as from the pain...
Autori: Irina-Isabella Savin, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25314

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractAt global level, the microbiological quality of water is a matter of concern, since diarrhoea represents the second cause of mortality. In addition, nitrates represent a significant problem and their high concentration - above the accepted limits - in drinking water is frequently encountered in Romania. Water samples have been analyzed in accordance with the methodology recommended by The Public Health Institute Bucharest. 78.15% of the water samples evaluated during the interval 2004-20...
Autori: Claudia Sarmasan, Lucia Daina, Sonia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25325

AbstractThe work presents the negative environmental impact produced by an extraction of crude oil activity. To highlight and quantify the negative effects on the environment produced from such activity, the experimental part has been focused on evidence of samples of soil, water from groundwater aquifers and surface, and the air emissions. The values of quality indicators are presented in graphs and tables, highlighting an activity with all major impact on the environment....
Autori: Aurica Grec, Corneliu Maior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25326

A study was conducted to investigate the organic compounds residues in different types of coffee from market inThe detection limits ranged from 0.02 ng/kg to 0.04 ng/kg and quantification limits were 0.2 ng/kg. Calibration and recovery studies gave satisfactory results. Concentrations of OCPs in coffee samples varied from 0.001 mg/Kg to 0.007 mg/Kg. The methods provide a rapid and accurate determination of these organic compounds in coffee samples....
Autori: Gabriela Stanciu, Mariana Popescu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25338

Include urmatoarele articole:� Composite membranes with cross-linked matrimid selective layer for gas separation� Determination of organic compounds from different types of coffee by Hplc and Gc-Ecd analysis� An integrated assessment of the suitability of domestic solar still as a viable safe water technology for India� Investigations on the possibility of natural hemp fibers use for Zn(II) ions removal from wastewaters� Removal of acid red 398 dye from aqueous solutions by coagulation...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25340

AbstractPolycyclic aromatic hydrocarbons (PAHs) are included in the European Community (EC) and in the Environmental Protection Agency (EPA) priority pollutant list due to their mutagenic and carcinogenic properties. PAHs emissions from automobile traffic and industry activities were shown to influence the PAHs levels and profiles in vegetables grown nearby. The levels of 15 PAHs were determinate in samples of pepper (Capsicum Annuum) and tomato (SolanumLlycopersicum) in different stages of plan...
Autori: Alina Soceanu, Dan Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Valentina Coatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25360

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract Pollution with toxic metals is a serious concern, because once these elements enter in the soil they can be present for a long time, with the potential contamination of drinking water sources. Certain metals in soil may be taken up by plants which are subsequently harvest for human consumption. Our objective was to study the presence of heavy metals in soils, groundwater sources, some medicinal plants from areas of the water sources and in its watery extracts. All of the samples, af...
Autori: Diana Diaconu, Victor Nastase, Mara Mihaela Nanau, Ovidiu Nechifor, Elena Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25411

Abstract The Romanian standard for the analytical method for phenols measurements in aquatic media was subject of internal validation procedure, adapted to the specific concentration domain of the laboratory. Method performance criteria were investigated on standard samples measurements: selectivity, linearity domain, precision, accuracy, limit of detection, limit of quantification androbustness. The validated method was further used on real samples of domestic and industrial wastewaters from...
Autori: Carmen Dima, Cristina Jelescu, Camelia Draghici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25448

Abstract Spent hydroprocessing catalysts from petroleum refining industries have been classified as hazardous wastes due to their content in heavy metal and persistent organic pollutants (POPs). The aim of our paper determine the polycyclic aromatic hydrocarbons (PAHs) residues contents in spent catalysts samples from four different units of the Romanian refinery Rompetrol Rafinare,Constanta: Hydrogen (H), Gas Desulfurization Sulfur Recovery (GDSR), Hydrofining Turbojet Kerosene (HTK) and Pet...
Autori: Camelia Draghici, , , Gabriela Stanciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25449

Abstract It's well known the degradation of many Romanian (including Dobrogea) soils, both in hill and in plain environments, due to the increasing anthropic pressure on natural resources. Soil erosion and organic matter loss are recognized as the main processes responsible of such degradation and of the rising risk of desertification, to which land use changes and politics for agriculture not suitable for land specificities often contribute. The knowledge of land use impact on soil quality i...
Autori: Marioara Nicolaescu, Naliana Lupascu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25453

Abstract The paper presents new studies about the removal efficiency of the biochemical treatment process of the Municipal Wastewater Treatment Plant from Constanta city, during 2008. Influent and effluent samples of biochemical treatment stage were collected and ammonium concentration, chemical oxygen demand (CODCr) and biochemical oxygen demand in five days (BOD5) were measured, aiming to study the evolution of the removal efficiency, during 2008. Additional analyses have been performed in ...
Autori: Elisabeta Chirilă, Camelia Draghici, Adriana Puhacel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25458

Abstract This paper presents the corrosion processes of steel samples with different composition, in aggressive corrosion solutions containing chloride ions. The inhibition capacity of two new Mannich basis: 2-aceto-4-morpholylmetyl-1-naphtol (BM1) and 1- (2'-hydroxynaphtyl)-3-(4-morpholyl)-1-propanone (BM2) was tested and compared. The corrosion tests were done in a potentiostatic installation and, based on the polarization curves, the Tafel plots were obtained. The kinetic and thermodynamic...
Autori: Ileana Manciulea, Cristina Bogatu, Eugenia Comanita, Anca Duta, Lucia Dumitrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25459

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract The paper briefly presents the principle, methodology basics and the research opportunities offered by a modified L-joint test for a complex in-field evaluation of wood behaviour in outdoor above ground exposure, corresponding to the biological use class 3. A comprehensive and detailed examination of the tested samples, looking not only to the biological degradation of wood but also to wood cracking and coating performance (cracking, flaking, exfoliation, adherence), was performed an...
Autori: Maria Cristina Timar, Emanuela Beldean, Mihaela Porojan, Lidia Gurau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25494

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract Preliminary investigation of contaminated soil in the surrounding area of a petroleum tank has been carried out based on fluorescence techniques: excitation emission matrix (EEM) and synchronous fluorescence scan (SFS). A fluorescence fingerprints library containing several EEM and SFS maps for various dilutions of Romanian crude oil in methanol, was used to confirm the identity of the soil contaminant. A calibration curve was created to estimate the contamination level of soil sampl...
Autori: Dan Savastru, Elfrida M. Carstea, Gabriela Pavelescu, Luminita Cristescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25505

Abstract Waste management hierarchy has as priorities waste recycling and energy recovery. Unfortunately, Romania is in the situation so as the waste landfilling is still considered as a suitable solution for waste management. European Union imposed a number of regulations and programs in the field of waste treatment and management that Romania must comply. The paper describes some aspects regarding characterization of the leachate originating from the Tomesti landfill (situated in Iasi County...
Autori: Ana-Maria Schiopu, Brindusa Mihaela Robu, Ion Apostol, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25523

Abstract The use of appropriate leaching tests and leaching models can help to predict the hazardous components release from cementbased solidified waste during either utilization or disposal. Numerous parameters influence the leaching rates such as grain size/specimen size,ccc liquid-to-solid ratio, pH value of the leachate, leaching time etc. This study evaluates the effect of initial liquid-to-solid ratio of cement paste on the release of copper from cement-based solidified waste. Dynamic ...
Autori: Constantin Bobirica, Liliana Bobirica, , Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25527

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract The paper presents the surfactant-assisted solvo-thermal route to synthesize nanoparticles of cerium oxide with different shape and morphology. The precursor was calcined at 400°C for 4 h in order to obtain CeO2 nanoparticles. The obtained samples were characterized by means of thermal analysis and FTIR spectroscopy. The UV-Vis analysis was used to study the optical properties. The morphologies and nano-structures were characterized by scanning electron microscopy (SEM) and XRD. It...
Autori: Nicolae Apostolescu, Gabriela Carja, Gabriela Apostolescu, Elena Husanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25541

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract Organic matter is ubiquitous in every type of aquatic system and due to the influence that it has on their ecological health, can be used as a useful water quality indicator. Fluorescence spectroscopy has been efficiently used in the past decades to determine and characterize organic matter, and its link to function and chemical water quality. In this paper, fluorescence fingerprints are presented in order to evidence the anthropogenic influence on different aquatic systems. Using f...
Autori: Elfrida M. Carstea, Luminita Ghervase, Gabriela Pavelescu, Dan Savastru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25576

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract This paper presents a portable device for rapid preparation of samples, in situ, in order to facilitate the detection and identification of toxic substances. This product is for research and provides increased sensitivity NBC detection equipment (ion mobility spectrometers, indicated tubes), and decreasing the time needed for preparation solid and liquid samples to identify toxic substances by spectrometric techniques (gas chromatography with mass spectrometry). It is used especially...
Autori: Alexandru Bobes, Aurica Dumitrescu, Doru Alexe, Gabriel Epure, Liliana Rece, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25595

Abstract In this work the method for the treatment of industrial waste waters effluents containing hexavalent chromium in three companies during process of treating metal surface with chromic acid is described. Industrial water polluted with hexavalent chromium is collected in separate sewage system. Polluted water is collected in precipitation tanks which are directly connected with neutralization reservoirs. The treatment process includes pre-neutralization by lime-milk, sedimentation, floc...
Autori: Igor Creţescu, Mirjana Cvijovic, Predrag Djurdjevic, Slavica Cvetkovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25596

Abstract In the study, the accumulation of secondary metabolites present in Calendula officinalis L. flowers with importance in therapeutics was examined, after the treatment with some substances considered being mutagens. The effect of substances appliedat different concentrations and different times of action was studied, qualitatively and quantitatively, considering various methanol extracts, obtained from the inflorescenses of Calendula officinalis L, which contained polyphenolic fraction...
Autori: Brindusa Robu, Constantin Leonte, Elvira Gile, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25598

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

Abstract Artificial neural networks (ANNs) are capable of learning the relationships between the dependent and predictor surface water quality variables and have a high ability to predict from the new data set. In this study, two different ANN methods, the feedforward network (FFN) and the cascadeforward network (CFN) were applied to predict two surface water quality variables such as chlorophyll-a (Chl-a) and fecal coliform (FC) using twelve other variables as an input to the models. Both me...
Autori: Hasan Merdun, Ozer Cinar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25623

PM10-2.5 and PM2.5 samples were collected from December 2007 to January 2008 at six sampling sites in Urumqi Xinjiang, China. The concentrations of seven kinds of water-soluble ions––SO4 2-, NO3-, Cl-, NH4 +, K+, Na+, and Ca2+––were analyzed using ion chromatography. The concentrations of heavy metal elements, Cr, Co, Cd, Pb, and Hg were measured using inductively coupled plasma mass spectrometry (ICP-MS). The results indicated that, in PM2.5 and PM10-2.5, the average mass concentration ...
Autori: Talip Dilnur, Tursun Yalkunjan, Manabu Igawa, Yimit Abulizihttp://www.ecozone.ro/reviste.php?RID=25683

An increasing recognition of tillage erosion processes has shown that soil redistribution by tillage directly contributes to soil loss in mechanically and nonmechanically agricultural areas worldwide. Soil translocation by tillage is normally measured by means of tracers, with which a volume of soil is labeled, and therefore yielding tillage erosion rates in a field. Two tracer methods for estimating tillage erosion rates were appraised to understand the adaptability to local conditions in the h...
Autori: Jianhui Zhang, Fucheng Lihttp://www.ecozone.ro/reviste.php?RID=25687

Abstract:The textile industry uses high quantities of water which in many cases are disposed to the environment with inadequate treatment.In this work the effluents from the polyamide textile industry containing Bemacid Gelb, Bemacid Rot and Bemacid Blau weretreated by heterogeneous photodegradation. Treatment performances have been evaluated in terms of conductivity, turbidity, totaldissolved solids (TSD), chemical oxygen demand (COD), total organic carbon (TOC), biochemical oxygen demand (BOD5...
Autori: Luminita Andronic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25720

Abstract:A method based on headspace and capillary gas chromatography with flame ionization detector technique was validated for thesimultaneous determination of five individual aromatic volatile pollutants: benzene, toluene, ethylbenzene, m/p-xylene and oxylene.The validation took in consideration liniarity, accuracy, precision, limit of detection, limit of quantification anduncertainty estimation criteria and concluded that the proposed method is suitable to determine the pollutants of interes...
Autori: Camelia Draghici, Elena Paunescu, Elisabeta Chirilă, Gabriela Stanciu, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25729

Abstract:This technical paper presents some aspects concerning the static finite element analysis of a wind turbine blade. For themanufacturing of the blades for a 10 kW wind turbine elaborated at the Technical University of Moldova composite materialsmade up of polyester matrix reinforced with fiber glass are being used. In order to determine the mechanical properties of theproposed composite materials 10 different samples of laminated composite plates were numerically simulated in ANSYS 11....
Autori: Marin Guţu, Viorel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25747

Abstract:Our research was focused on developing some new procedures to reduce the biodegradable wastes by composting. The aim of thisstudy was to obtain and asses at laboratory scale the maturity of three compost samples of different proportion of vegetable waste,beech sawdust and sewage sludge by analyzing their FT-IR spectra and C/N ratio. The composting process was monitored by testsperformed weekly on the three samples in order to investigate the physical parameters (pH and electroconductivi...
Autori: Anca Sauciuc, Claudia Zaha, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25772

Abstract:The aim of this work is to obtain sintered porous membranes with graded structure for microfiltration by sedimentation andsintering of metallic powders. Our previous studies have demonstrated the possibility of obtaining sintered porous materials withgraded structure by sedimentation. In this paper, spherical nickel particles were used having a grain size in the 2-90 Âľm rangemeasured by the laser scattering particle size analyzer. The powders were sedimented into a sintering die in a s...
Autori: Gyorgy Thalmaier, Ioan Vida-Simiti, Nicolaie Jumate, Niculina Sechel, Valentin Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25775

Abstract:The study was conducted to evaluate the concentration variation of heavy metals in milk collected from two different groups ofsources: milk collecting centers and dairy farms. Also, their incidence in milk products, as pasteurized milk, butter milk, yogurt,cream, cheese, hard cheese was determined in the NE Romania (Moldavia).The analytical results revealed that the milk samples from the collecting centers had higher levels than the samples from the dairyfarms of Pb (2.90 to 3.45 vs. 1....
Autori: Andrei - Cristian Grădinaru, Gheorghe Solcan, Ovidiu Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25776

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

Abstract:Titanium metal and its alloys have been widely used as implants under load-bearing conditions due to their biocompatibility, excellent corrosion resistance and lightness, but their inability to bond to living bone is a setback. The experiments outlined here investigated hydroxyapatite (HA) coating on Ti metal implants, used to enhance their bioactive properties. In this study, specimens of commercially pure titanium (c.p. Ti) and Ti-6Al-4V were etched in either H3PO4 or HCl, and subsequ...
Autori: Chao-Lun Fu, Hsueh-Chuan Hsu, Shih-Ching Wu, Shih-Kuang Hsu, Wen-Fu Ho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25795

Abstract:In this paper, the effect of the ultraviolet light on various pathogen microbial strains present in drinkable groundwater samples (wells) from Constanţa County, Romania (localities Moviliţa, Topraisar, M. Kogălniceanu) was analyzed. The investigations were conducted in an original UV-C irradiation prototype installation for water samples. The efficiency of this prototype in destroying the pathogen agents present in drinkable groundwater was established by monitoring the p...
Autori: Bogdan Negreanu-Pîrjol, Elena Gorun, Remus Zăgan, Sabina Zăgan, Ticuţa Negreanu-Pîrjol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25802

Abstract:The hereby article presents a part of the results of the research made by the author during his PhD degree preparation with respect to asbestos and plastics wastes recycling in the form of composite with polymeric matrix, respectively the toxicological tests performed on the new product. In this respect, three categories of tests were made based on complex and modern analysis methodologies, with high results accuracy: spectral analysis of the wear wastes, morphological analysis of the w...
Autori: Cristina Corpodean, Silvian Ionescu, Valeriu Deac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25812

The aim of this work is the study of activated sludge floc samples stained with different dyes and imaged by Confocal Laser Scanning Microscopy (CLSM). Activated sludge flocs were stained for lipids, sugars and esterase enzyme producing bacteria. Images were acquired for different samples to analyze the structural characteristics of the bioaggregates. The analysis of the CLSM images allowed for the localization and estimation of the quantity of different build-up materials. The 3-D reconstructio...
Autori: Bela Abraham, Botond Raduly, Dan Niculae Robescu, Szabolcs Lanyi, Szabolcs Szilveszter, Szilard Bucs
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25937

Polycyclic aromatic hydrocarbons (PAHs) are by-products of petrol transformation; a report prepared by ICON, London, United Kingdom in 2001, showed that the principal sources of polycyclic aromatic hydrocarbons in wastewater are domestic usage, storm runoff and commercial effluent. This work presents the results on 14 commonly occurring and/or highly carcinogenic PAH compounds listed as priority pollutants by the United States Environmental Protection Agency and the European Union. Wastewater sa...
Autori: Dumitru Ristoiu, Edward Muntean, Livia Alhafez, Nicoleta Muntean, Radu Mihaiescu, Tania Mihaiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25847

The availability of good quality water is an indispensable condition for preventing diseases and improving the quality of life. Water is one of the most important renewable resources, which must be prevented from deterioration in quality. Various physicochemical parameters like pH, alkalinity, total hardness, total dissolved solids, calcium, magnesium, nitrate, have a significant role in determining the potability of drinking water. In this study, samples were collected from wells situated in vi...
Autori: Maria Cioroi, Mirela Praisler
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25853

Pollutants transfer via the food chain was investigated in a wetland ecosystem from the Lower Prut Floodplain Natural Park in Romania. Trace elements (Cd, Cu, Pb and Zn) were determined by Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) from samples belonging to primary producers and primary and secondary consumers, and also from water and sediments samples. Non-essential trace elements as Cd and Pb exhibited low concentrations in molluscs and fish, but zinc had shown conc...
Autori: Alin Tudorache, Gabriel Chisamera, Gabriel Lucian Radu, Iulia Gabriela David, Laurentiu Rozylowicz, Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25855

The aquatic species are permanently subjected to various stresses through the ecosystem and the food habit. Elucidating the impact at the cellular level allows us to understand the ways in which the polluting elements and their derivatives can disrupt the metabolism of aquatic organisms triggering apoptosis in individual cells or necrosis affecting groups of neighbouring cells. The aim of this preliminary study is to highlight the influence of the environmental factors on two fish population by ...
Autori: , Camelia Ureche, Dorel Ureche, Gabriel Lazar, Ileana Denisa Nistor, Irina Loredana Ifrim, Iuliana Mihaela Lazar, Marius Stamate, Valentin Nedeff
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25861

Marine species (n=36) available in a supermarket of Cluj-Napoca city, Romania were collected and analyzed for the levels of heavy metals (Cr, Cu, Zn, Cd, Pb, Hg) and As, polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and analogous, hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB). The collection included samples from twelve fish groups (sardine, tuna, herring, pangasius, marbled rockcod, hake, shrimp, pink shrimp, lo...
Autori: Adriana Gog, Claudiu Tanaselia, Ioan Ştefan Groza, Marin Senila, Mirela Miclean, Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25863

In this study, we have tested the possibility of utilization of three types of natural low-cost sorbents: (Sphagnum moss peat, natural moss peat and alkaline treated moss peat) for the active biomonitoring of air quality from Căliman National Park area (Dorna Basin), during of two months (September – October 2010). The concentrations of some heavy metals (Pb, Cd, Cu, Mn and Fe) in the sorbent samples were used as an indicator of the level of air pollution in the studied region. After expo...
Autori: Iulian-Ovidiu Sandu, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25868

The synthesis of vanadium oxide systems (with 5 and 20 wt% V2O5 loadings) supported on commercial γ-alumina was carried out by a wet impregnation method. The samples were characterized by low-temperature nitrogen adsorption (BET), inductively coupled plasma (ICP) method and by in situ electrical conductance/capacitance measurements. The adsorption of CO was used to investigate the acidic properties of alumina support and V2O5/-Al2O3 catalysts by FTIR spectroscopy. The catalytic acti...
Autori: , Cristian Hornoiu, Mariana Scurtu, Monica Caldararu, Niculae I. Ionescu, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25869

The performances of two types of multi-walled carbon nanotubes-based composite electrodes, i.e., MWCNT-Epoxy (CNTEpoxy) and Natural Zeolite-modified- MWCNT- Epoxy (NZ-CNT-Epoxy) are described in order to use them for electroanalytical application. Both electrodes were synthesized, electrically and electrochemically characterized and tested for the detection of ascorbic acid (AA) in aqueous solutions. The electrochemical characterization using classical potassium ferricyanide method showed a high...
Autori: Adriana Remes, Anamaria Baciu, Elida Ilinoiu, Florica Manea, Joop Schoonman, Stephen J. Picken
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25877

Herbicides industry is a large consumer of water, as well as a major wastewater generator, its effluents contain priority organic pollutants in very high concentrations which have severe effects on human health and on the environment due to their toxicity and bio-recalcitrant nature, persistence in the environment and bioaccumulation. A vast number of herbicides and other priority organic pollutants have been found in wastewater effluents, surface water, and drinking water around the world. The ...
Autori: Bianca Weinberg,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25874

Newly prepared SnO2-CeO2 catalyst samples used as depollution catalysts were characterized applying low-temperature nitrogen adsorption (BET), X-ray diffraction (XRD), thermo-gravimetry (TG-dTG) and temperature-programmed reduction (TPR) methods. Pure SnO2 has higher surface area (17 m2/g) than the pure CeO2 (8 m2/g). Addition of organic tin oxide precursor to ceria in amount of 5 wt% slightly decreases the surface area of CeO2 (SSn5-Ce= 7 m2/g). The increase of tin oxide content to 10 and 20 wt...
Autori: , Anca Vasile, , Cristian Hornoiu, Jozsef Kovacs, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25875

Measurements of radium concentrations in water are important from the health protection point of view, so simple and reliable analytical methods must be available. In this paper we have determined the radium activity concentration in 24 spring waters which are used as potable water reservoirs. For this purpose we used radon emanation technique and also alpha spectrometry method. This work gives details of sample processing, Lucas cell and the methodology used in the emanation method. In the meas...
Autori: Alida Timar Gabor, Constantin Cosma, Oana Alexandra Rusu, Robert Csaba Begy, Simina Dreve
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25878

Fluorescence spectroscopy is a promising approach to the characterization of natural aquatic components and organic pollutants, due to its rapid analysis and high sensitivity. Petroleum products had been studied, using fluorescence technique, in numerous occasions, as seawater and soil contaminant or as raw sample. Nevertheless, no complex assessment has been made on fluorescence real–time spectra of freshwater diesel oil contamination. This study reports a 5–days experiment on an urban rive...
Autori: Elfrida M. Carstea, Gabriela Pavelescu, Luminita Ghervase, Marina Tautan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25882

The herbicide use can be seen as an auxiliary path for new farming methods, providing more advantageous farming and land use capabilities and increasing crop yields. Some of them are quickly degraded but others persist in the environmental compartments being toxic for human health and the environment.The aim of this study was to evaluate the impact of some triazine herbicides from agricultural sources on quality of well and surface water, in two regions of Romania with different agricultural act...
Autori: Andreea Dragus, Mihail Simion Beldean-Galea, Radu Mihaiescu, Tania Mihaiescu, Dumitru Ristoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25889

Quantification of the floristic matrix is important both for animal’s nutrition and for the biodiversity monitoring of plants species under the influences of substance flow. Our researches have the main aim to study the possibilities offered by Infrared Spectroscopy in rapid, unpolluted and non-destructive analysis of floristic matrix modification from perennial grassland fertilized with organic and/or mineral fertilizers. It was performed three different FTIR models: for Poaceae (R2=0.949; RM...
Autori: Iosif Gergen, Moisuc Alexandru, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25892

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

The presence of pollutants in food raises some serious questions concerning their potential impact on consumers health, being necessary to monitor their distribution in the environment. The present work provides data regarding levels of organochlorine pesticides (lindane, p,p’- DDT, p,p’- DDE, p,p’- DDD, HCB, aldrin, dieldrin, endrin and hepthaclor) and PAHs: acenaphthene (Ace), acenaphthylene (Acy), fluorene (F), naphthalene (Np), anthracene (An), fluoranthene (Fl), phenanthrene (Ph), ben...
Autori: Alina Soceanu, Danut Tiberius Epure, Gabriela Stanciu, Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25905

Abstract Oil contamination has been one of the most common environmental pollution due to its threat to both human health andecosystems. It is difficult for the application of conventional chemical analysis to detect oil contamination in-situ, estimatebioavailability and rapidly assess the environmental risk. In this study, two bioreporters were employed for the rapid and directdetection of oil content and genotoxicity in a cutting oil contaminated site in China. Acinetobacter baylyi ADPWH_...
Autori: Bo Jiang, Chuan Li, Dayi Zhang, Guanghe Li, Wei E. Huang, Yizhi Song
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25944

AbstractWastewater from butyl rubber production is causing an increasing environmental problem due to its large quantity and complexquality. In this paper, two types of wastewaters generated from rubber synthesis, i.e. alkaline wastewater (AW) and cleaning andflushing wastewater (CFW), were investigated. Coagulation and flocculation were firstly applied to remove suspended solids(SS) from the AW. By single factor experiment, the optimum operational conditions were obtained as pH 8, PAC dosage 40...
Autori: Lujun Chen, Rui Liu, Wei Li, Wei Zheng, Yan Zhang, Ying Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25950

AbstractThe detection of environmental pollutants has challenged conventional chemical analysis for the rapid estimation of thebioavailability and toxicity of the contamination impact on human health and ecosystems. Magnetic nanoparticles (MNPs)functionalization as bioreporters can enhance the ability for biosensing in complex contaminated samples such as soils, and theimmobilization of bioreporters will promote the detection of gas and online monitoring. In this study, Acinetobacter baylyi ADP1...
Autori: Aizhong Ding, Cheng Chen, Dayi Zhang, Musen Duan, Steven F. Thornton, Wei E. Huang, Yanjun Luo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25952

AbstractVegetable waste was used as the fuel of a two-chamber microbial fuel cell (MFC) for simultaneous power recovery and wastedegradation. Effects of ultrasonic pretreatment, organic loadings, anolyte pH adjustment on the MFC performance wereinvestigated. Results showed that higher power generation and organic compounds removal efficiency were achieved in theMFCs with the vegetable waste pretreated with ultrasonication at >1.0W/mL compared to the un-pretreated control. A maximumvoltage of ...
Autori: Kun Tao, Xiangchun Quan, Yanping Quan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25953

AbstractA case-control study was conducted in two Romanian counties (Alba and Cluj) in order to investigate lung cancer risk due toresidential radon exposure. Two hundred and forty-one subjects were included, of which 104 cases and 137 controls. Residentialradon concentrations were monitored using CR-39 track detectors, exposed over a period of at least 6 months. The odds ratioswere estimated by using multivariable logistic regression adjusted for age, sex, smoking status, education and family h...
Autori: Alexandra Cucoş Dinu, Constantin Cosma, Dan Rădulescu, Doina Todea, Dorin Iancu, Ionel Papuc, Loredana Roşca, Mircea Rişteiu, Tiberius Dicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26011

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractZinc is an important metal for humans and the environment. Its intensive application in industry has led to water and soilcontamination. A lot of microorganisms both unicellular and multicellular can be applied for removal of metals from theenvironment. The process of zinc adsorption by cyanobacteria Spirulina platensis biomass was investigated. The concentrationsof 0.34 mM and 3.4 mM of ZnSO4ˇ7H2O were used. The process of biosorption of zinc was studied during 1-hour experiment.To dete...
Autori: Gheorghe Duca, Inga Zinicovscaia, Liliana Cepoi, Marina V. Frontasyeva, Sergey S. Pavlov, Svetlana F. Gundorina, Tatiana Chiriac, Valeriu Rudic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26041

AbstractThe paper intends to contribute to the stages of bioremediation technologies elaboration, by means of experiments and efficiencydemonstrations of adequate biological depollution and ecological reconstruction methods. During the 2009-2011 period, heavymetals and metalloids, etc phytoextraction tests were performed with Lolium perenne L, from tailing samples collected fromwaste heaps and tailings dams of the mining exploitations (Rodna, Bistriţa–Năsăud, Fundu-Moldovei, Sucea...
Autori: Alexandru Crihan, Alin Bolonyi, Bianca Malschi Florian, Cecilia Roman, Dana Malschi, Dorian Brăhaiţa, George Ghira, , Marin Şenilă, Mirela Miclean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26044

Abstract This study describes a reversed-phase high-performance liquid chromatography (RP-HPLC) method for the analysis of several carbonyl compounds in air samples. The air samples were collected using a passive sampling method and cartridges based on florisil impregnated with 2,4-dinitrophenylhydrazine (2,4-DNPH). After derivatization the carbonyl compounds were analyzed by liquid chromatography technique coupled with UV detection. The developed RP-HPLC method was used to analyze...
Autori: Carmen Roba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26104

Abstract Known as the most important byproducts of water disinfection with chlorigen chemicals, trihalomethanes (THMs) are incriminated in causing severe effects upon human health. The exposure pathways that can lead to potentially significant uptake of THMs include for adults ingestion of tap water and inhalation of THMs in vapor phase resulting from bathing, showering and washing. The purpose of this paper is the exposure assessment to THMs through ingestion, inhalation and derma...
Autori: Anca Elena Gurzău
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26110

Abstract A set of 500 water samples collected from various sites of Tarnava Mare River, between Medias and Copsa Mica were analyzed, during three years (2010-2012). The physicochemical parameters like: temperature, pH, electrical conductivity (EC), total dissolved solids (TDS), salinity, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), lead (Pb2+), chloride (Cl-), sulfate (SO4 2-), ammonium (NH4 +), nitrite (NO2 -) and nitrate (NO3 -) were determined. The results were co...
Autori: Ioana Piştea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26114

Abstract Waste recycling represents a very significant issue for the protection of our environment. Large waste quantities (slag and ashes) are products of the coal extraction industry and its subsequent combustion in thermal power stations. The possibilities of obtaining crystallized glasses in the CaO-Al2O3-Fe2O3-SiO2 system by introducing in the raw materials mixture ashes from Mintia Deva thermal power station have been studied. The physical and chemical characterization of the...
Autori: Firuţa Goga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26121

Abstract The main purpose of this paper is to identify, highlight and analyze the recycling possibilities for the activated glass derived from the treatment of the cathode ray tubes (CRT) waste equipment and to demonstrate the recycling viability, economical and environment protection efficiency. A total of 95 pieces of waste electronic equipments (TVs and PC monitors) were processed and a number of five TVs and five PC monitors from the ‘95s were analyzed. Significant quantitie...
Autori: Antoanela Popovici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26124

Abstract The article presents the development of a mathematical model concerning thermal desorption in a tubular electric furnace, using the linear regression analysis principle. With a range of experimental data obtained from some laboratory tests on water evaporation plus pollutant (Hexaclorocyclohexane - HCH), evaporation resulting from the application of thermal desorption on some soil samples; a mathematical model was developed to calculate the mass of substance evaporated fro...
Autori: Calin Vasile Prodan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26125

Abstract Using sludge with dangerous substances content as an agricultural fertilizer can provide risks for humans and all environmental components. An important risk factor that had to be taken into account is the combination of sludge used as a fertilizer and agriculture activities that has its own consequences. In this paper, a risk evaluation for sludge disposal was elaborated. The most important risk factors in the studied case, wastewater sludge used as an agricultural fer...
Autori: Elena Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26141

Abstract Municipal waste landfill leachate results in different stages of waste stabilization and has a negative impact on the environment. When implementing a new policy on waste handling, monitoring landfill leachate should be carried out under conditions of a modern solid waste landfill. The paper discusses the quality of leachate observed in old and recently built landfills in Vilnius - the capital city of Lithuania. The landfills are situated at a distance of 20 kilometres fro...
Autori: Kristina Baziene
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26151

AbstractTo understand the typical organic pollutant contamination status of the main source water in Yellow River basin, samples werecollected from fifty source water points (including reservoir and river) in Yellow River basin. The samples were analyzed for therepresentative organic pollutants, including benzene homologous, chlorobenzene compounds, organophosphorous pesticides, and nitrobenzene compounds, total of 17 compounds. It was observed that all concentrations of the 17 compounds in the ...
Autori: Jijun Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26155

AbstractKnown concentrations of naphthalene were added to soil samples to investigate the anaerobic degradation potential by theinoculated naphthalene-adapted bacteria under nitrate reducing conditions. Naphthalene could be anaerobically biodegraded tonon-detectable levels within 35 days when the initial concentrations were 5.8 mg/kg, 34.7 mg/kg, 61.4 mg/kg, 93.7 mg/kg and146.6 mg/kg in soil, respectively. The degradation rates of naphthalene increased with increasing initial concentrations. The...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26157

AbstractDuring the normal operating of reservoir, the rock mass quality in hydro-fluctuation belt of reservoir bank will degrade graduallyunder the water-rock interaction because of the periodically impoundment and drainage. In this article, with the consideration ofthe change of water pressure, an experiment was performed to simulate the process of “immersion-air dry” cycles with sandstones selected from the hydro-fluctuation belt of Three Gorges reservoir area. Test results indicates that the ...
Autori: Huafeng Deng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26161

AbstractSurface soil samples and vegetable samples from the Pearl River Delta, South China were collected and analyzed for 16 USEPApriority polycyclic aromatic hydrocarbons (PAHs). The total concentrations of 16 PAHs in soils ranged from 22.1 to 1256.9 ng/g.Naphthalene, phenanthrene, fluoranthene and benzo(b)fluoranthene were consistently the most prevalent individual PAHs. Theconcentrations of 16 PAHs in vegetables varied from 31.2 to 726.8ng/g. Naphthalene and phenanthrene were the predominant...
Autori: Song Yantun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26180

AbstractExcess biomass produced in the degradation processes of organic pollutants is creating environmental challenges for wastewatertreatment plants. The A+OSA system, a modification of the anoxic / oxic (A/O) process via insertion of a sludge holding tankinto a sludge return line, has been demonstrated to be capable of achieving simultaneous nutrient removal and sludge reduction.Here we report the results of an investigation aimed at evaluating the impact of the sludge holding tank on the bio...
Autori: Li Jia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26207

AbstractThe dominant litter samples Pinus sylvestris L. needle litter and Acer platanoides L. leaf litter were collected in the coniferousmixed forest located at 54ş43‘ N 25ş19‘ E (Vilnius, Lithuania) in April 2010. Different heating temperatures (150, 250, 350, 450and 550şC) and 2 hour heating duration were used to produce ashes. The selected heating temperatures affected mass loss, colour, pH, electrical conductivity (EC), C/N ratio, nutrient concentrations of the ash. The darkness of Munsell ...
Autori: Jolita Dūdaitė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26208

AbstractLow water quality due to high levels of ammonia, chemical oxygen demand (COD), abnormal pH, and undesirable water color isprevalent in many prawn ponds in Malaysia. A composite medium used in the treatment of prawn pond effluent was examinedfor the reduction of undesirable parameters. The composite medium is a mixture of limestone, activated carbon, zeolite, and ricehusk. Experiments were conducted under three different conditions, i.e., sole aeration, adsorption, and adsorption with pre...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26219

AbstractFluoride content in some available teas, dry leaves and tea infusions were determined, in order to check the influence of brewingtime on fluoride content in tea and to compare the percent extraction of fluoride releasing during tea infusion time. A fluoride ionselective electrode was used to determinate the fluoride content in tea samples (Hypericum perforatum, Tilia cordata andCamellia sinensis). Total fluoride contents of tea leaves were determined to be 91.1 - 162 mg/kg d.w., and 0.09...
Autori: Semaghiul Birghila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26242

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractThe present study is aimed at a long-term treatment performance of a constructed wetland with horizontal subsurface flow atJimlíkov, Czech Republic. The system was put in operation in 1993 and the treatment performance is evaluated for the period1998-2009 due to non-existence of results from the beginning of operation. The parameters of concern were BOD5 (biochemicaloxygen demand), COD (chemical oxygen demand), TSS (total suspended solids), NH4-N (ammonia-N) and TP (totalphosphorus). A t...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26258

AbstractZarshuran As-Au deposit is the major ore deposit in northwest of Iran. Having been exposed to weathering, the accumulatedmining waste is consumed to deteriorate regional soil and water quality. Accordingly, 11 composite surface soil samples werecollected to evaluate the metallic pollution. Mean concentration of elements As, Sb, Hg and Zn were measured to be 234.9, 19.6,24.2 and 476.7 ppm, respectively. In comparison with mean earth crust and local guidelines for agricultural soil, the sa...
Autori: Abdolreza Karbassi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26262

AbstractThe Lake Bafa is an alluvial bar lake located in the Aegean Region in the Big Meander river basin in Aydın and Muğlaprovinces. However, the lake is currently threatened by severe pollution, being under the risk of serious degradation because of(i) uncontrolled urbanization; (ii) point and non-point source pollution; (iii) algae bloom; (iv) sediment transportation andpollution via influent creeks to the lake; and (v) severe degradation of the natural wetlands within its drainage...
Autori: Ebru Yilmaz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26267

AbstractWorldwide, waste materials are produced as a by-product of industrial manufacturing and placed in storage areas. One of the waste materials is filter cake (FC). FC is formed during the infiltration of cooling water in steel factories. The main aim of this research is determination of optimum usage of FC in the production of impermeable layer on ground by using fuzzy model approach. Because of this, in the study, FC as a waste material was hardened with cement and an impermeable layer was...
Autori: Ä°lker Bekir Topďż˝u, Murat Karacasu, Tayfun Uygunoğlu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26288

AbstractThe efficiency of solar disinfection (SODIS) was evaluated and enhanced by concentrating sunlight at low pH values in a solar collector disinfection (SOCODIS) system at different sunlight intensities and is highlighted in the author’s earlier findings. In order for further improving the rainwater disinfection, simple technique like wrapping the PET bottles with heat-resistant plastic bags (Wp) were used for enhancing the thermal/synergistic effects of solar radiations. An analysis of the...
Autori: Abdulrahman Ali Alazba, Mooyoung Han, Muhammad Nasir Amin, Muhammad Tahir Amin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26298

AbstractThe monitored natural attenuation (MNA) of groundwater contamination is in many cases considered to be a cost-effective andappropriate strategy to manage the remediation of contaminated aquifers. A prerequisite for the public acceptance of such NAremediationapproaches is that the efficiency of the presumed NA-processes should be proven. This proof must be based on anextensive hydrogeological and in-situ characterization of the ongoing aquifer processes. Additional investigations of aquif...
Autori: Achim Möller, Anja Berning, Anne Berghoff, Bernd Mahro, Christoph Wortmann
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26312

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractA number of 138 samples of citrus fruits (oranges), produced in Souss-Massa area in south of Morocco, were analysed. Amultiresidue method was assessed for the determination of several organophosphorus pesticides using gas chromatography. Theextraction of pesticides was carried out by liquid-liquid extraction and solid-phase clean-up. The pesticide were separated bycapillary column gas chromatography and detected by the Nitrogen Phosphorus Detector (NPD). The majority of pesticidesrecover...
Autori: Abdelaziz Ait Addi, El Habib Ait Addi, Fouad Achemchem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26320

AbstractThe aim of this paper was to study the performance of a single-stage rotating biological contactor with supplemental aeration interms of removal efficiency of organic and nitrogen content. Research was based on fifteen samples collected during the fouryear period. The wastewater was low strength with maximal measured concentration of 362 mg COD/l, 100 mg NH4/l, and 324mg TSS/L. The maximal measured removal efficiency of COD (chemical oxygen demand) and TSS (total suspend solids) were71% ...
Autori: Dragan Cvetkovic, Dusan Gordic, Milorad Bojić, Srdjan Stosic, Vanja Susterstic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26322

AbstractMetal concentrations in plants, soil and sediment were evaluated in the vicinity of a former iron/nickel enriching factory atPogradec, near Ohrid Lake in Albania. Metal levels were significantly higher in soil samples than in the corresponding plants.Iron concentrations in both soil and plants were much higher than the nickel ones. Lower plants (lichens, mosses and fungi) had ahigher uptake and accumulation of nickel, followed by water plants and non-cultivated (wild) plants. Iron levels...
Autori: Dimitrios Bellos, Dimitrios Veros, John M. Halley, Lazaros Symeonidis, Sonila Llupo, Thomas Sawidis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26340

AbstractA cloud point extraction (CPE) procedure for the simultaneous preconcentration of trace amounts of Cd(II), Pb(II), Cu(II), Co(II)and Ni(II) ions as a prior step to their determination by flame atomic absorption spectrometry (FAAS) has been developed. Thisdeveloped method is based on the formation of hydrophobic complexes of these metals with the chelating agent 1-(2-thiazolylazo)-2-naphthol (TAN), which then are entrapped “in situ” into micellar media of non ionic surfactantoctylphenoxyp...
Autori: Wanli Huang, Zhixia Zheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26357

AbstractThe objective of this work was to analyse safety and health at work regarding the exposure of workers to styrene, and to establishthe basis for an exposure control system over the entire Republic of Slovenia. The main goals were to determine the number ofexposed workers, the levels of exposure at workplaces, and the effects to workers health. The measurements of the airbornestyrene concentrations and the biological monitoring of the exposed workers were performed. One thousand four hundr...
Autori: Lidija Korat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26415

AbstractThis paper proposes a tridimensional mathematical model for water migration time in a soil sample, as a prerequisite for thestudy of migration of various liquid pollutants in soil. The variables taken into consideration were measurement position, soiltype, porosity and the height of soil column. The mathematical models were elaborated and tested based on experimental data,assisted by TableCurve 3D software for generating linear and non-linear equations. The proposed mathematical models o...
Autori: Alexandra-Dana Chiţimuş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26425

AbstractThe changes in fresh water quality are reflected, over time, in the structure of the biocenosis by adjusting the composition, theabundance and the spatial distribution of species, in an attempt to maintain a constant equilibrium. It is difficult to identify thisequilibrium just by analysing the physicochemical measurements because they represent water quality conditions of the moment,while the analysis based on biological indicators which are reflecting the composition of macrozoobenthos...
Autori: Roxana Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26431

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractPathogenic bacteria are fetal to human health, requiring cost-effective and safe approaches to be removed from drinking watersource. With poly-allylamine-hydrochloride (PAAH) stabilization, magnetic nanoparticles (MNPs) were introduced in this studyto remove pathogenic bacteria by electrostatic interaction and magnet capture. High removal efficiency was achieved for fourmain pathogenic species, as Escherichia, Acinetobacter, Pseudomonas and Bacillus, and over 99.5% of the pathogens can b...
Autori: Yunfeng Xu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26475

AbstractThis study aimed to assess the ability of microorganism populations and two aquatic plant species (water hyacinth - Eichhorniacrassipes Solms and water morning glory - Ipomoea aquatica) to treat domestic wastewater in Nhue Giang pond, Tay Mo village,Tu Liem District, Hanoi City in Vietnam. The results showed that microorganism populations in the pond water contained all ofgroups of microorganisms including bacteria, Actinomycetes, mold and yeast. In water inlet and outlet samples, bacter...
Autori: Nguyen Thi Loan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26476

AbstractIn this study, the reduction of phenolic compounds and other organic pollutants from greenish black (GB) and dark brown (DB)olive mill wastewater (OMW) was investigated. Ultrasonic irradiation in combination with aerobic biodegradation was adoptedas the treatment technique. Operational parameters such as the duration of ultrasonic irradiation, ultrasonic power intensity andultrasonic frequency were tested to determine their effects on phenol, BOD, and COD degradations. It was found that ...
Autori: Zakaria Al-Qodah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26484

AbstractFluorescence spectroscopy and parallel factor (PARAFAC) form a powerful tool in separating different fluorophores and maybe useful in detecting the fluorescent signature of dissolved organic matter (DOM). Despite the large number of studies onfluorescence and PARAFAC it is still uncertain if this combination is capable to separate DOM from different water types byanalyzing the presence of specific components and their spectral shape. This paper presents a preliminary study on thefluoresc...
Autori: Elfrida M. Carstea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26495

AbstractConcentrations of seven heavy metals (Cd, Cr, Cu, Fe, Ni, Pb and Zn) in the discharged effluents of four wastewater treatmentplants located on the Romanian Black Seacoast, evaluated as average values for four seasons, during 2010-2011 are presented.Total and dissolved metals occurrence was investigated from seasonal samples, to assess the bioavailability of the heavy metalsin the discharged effluents. The analytical measurements were performed by flame atomic absorption spectrometry (FAA...
Autori: Elisabeta Chirilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26498

AbstractThe phonic pollution has become a more serious problem in the recent years, especially because of traffic increase. This kind ofpollution is generated by all kinds of means of transport. One of its peculiarities is the repercussion it has on people, unlike theother types of pollution, i.e.: water pollution, air pollution, soil pollution, which can affect, to a certain extent, the entireenvironment. The phonic pollution is considered to be the most widely spread type. The numerous surveys...
Autori: Carmen Grecea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26500

AbstractThis study, analyzes the benthic macroinvertebrates community structure and composition in order to assess the ecological statusas required by the Water Framework Directive (WFD). Macroinvertebrates are the appropriate indicators to describe habitatheterogenity and the water bodies ecological status by turning the allochtone material into biomass, which is then transferred tothe upper trophic levels. Moreover, the macroinvertebrates have the capacity to integrate in their structure the e...
Autori: Catalina Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26502

AbstractAnalysis and monitoring of arsenic is still a challenging analytical task. Due to its complex behaviour (different forms of arsenicthat can be present depending on pH and oxidation states of arsenic) as well as demanding analytical procedures and instrumentaltools for control of arsenic concentration in drinking water which is set to 10 μg L–1, there are still some open questions andissues when arsenic is the scientific topic. In this paper the idea was to use a multivariate statist...
Autori: Vladana N. Rajakovic-Ognjanovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26506

AbstractVegetables are an important part of a healthy diet because of their nutritional value. Contamination in vegetable may provehazardous for population. Polycyclic aromatic hydrocarbons (PAHs) are compounds widespread in the environment, many ofthem showing carcinogenic effects. These compounds can reach the food chain by different ways and, therefore, the analysis ofPAHs in food is a matter of concern.The present work provides data regarding levels of PAHs: acenaphthene (Ace), acenaphthylen...
Autori: Alina Soceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26510

AbstractThe mining waste facilities in the Baia Mare region, Romania, resulted from the extraction of poly-metallic ores (including Au,Ag). Metal sulphide minerals from the mining waste facilities have a potential to produce acid rock drainage (ARD) and togenerate risk for the environment, including for the water resources. Some of the mining waste deposits from the region arelocated near the town of Baia Mare, close to the residential areas, the agricultural lands and the surface water. The sho...
Autori: Oana-Cristina Modoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26512

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractAtomic absorption spectrophotometry (AAS) technique was applied in order to identify the occurrence of certain heavy metals insamples of pork products, such as bacon, ham, sausage and salami, taken from four commercial centers in Romania. Lead levelsin samples varied from 0.58 to 0.96 mg/kg, Cadmium values from 0.11 to 0.21 mg/ kg, Copper from 0.73 to 1.32 mg/kg, whileZinc levels were detected between 32.19 and 42.12 mg/kg. Lead, Copper and Zinc found in samples were lower than themaximu...
Autori: Gabriel Vasile Hoha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26522

AbstractGreywater (GW) has attracted global attention as an alternative water source over the last few decades. GW treatment andreliable reuse require the overall qualitative characterization of samples from different sources. This paper represents aninvestigation of household-generated GW in the Northern Great Plain Region of Hungary. Modern and reliable analyticaltechniques and instruments (ion chromatography, microwave plasma atomic emission spectrometry, Zetasizer Nano Z analysis,etc.) were ...
Autori: Ildiko Bodnar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26528

AbstractCurrently, thermal insulation of buildings is required from both an energy savings perspective and a money savings perspective.Insulation is primarily installed on the outer surface of the buildings. Weather and other circumstances can produce humidity thatcan act on the building structure, e.g., by changing its heat capacity, the heat transfer coefficient and/or other factors. As a result,it is important to measure the sorption behaviors of the construction materials. To perform sorptio...
Autori: Ferenc Szodrai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26550

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractThe aim of this work is to study the valorisation of two regenerated low density polyethylene (LDPE) coming from dirty wastesby blending with polypropylene (PP) in presence of compatibilizer. The first step was the determination of the physico-chemicalproperties of the two regenerated samples (density, melt flow index, water absorption, melting temperature and oxidation index)and the mechanical properties (tensile and shore D hardness).The second step was the characterization of the phys...
Autori: Nabila Guerfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26565

Abstract The present study was conducted to determine the heavy metals (Fe, Mn, Zn, Cu, Pb, and Cd) and essential oils content in the berries of Juniperus phoenicea L. grown in two different geographic origins; Dana conservation and Al-Hisha forest in Jordan. Atomic absorption and Hydrodistillation methods were used to determine heavy metals concentrations and oil contents in plant samples of J. phoenicea L., respectively. Results showed that, the oil yielded from J. phoenicea L. berries in ...
Autori: Mohammad Sanad Abu-darwish
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26595

Abstract This study evaluates the potential of Crambe abyssinica press cake, a residue from crambe oil extraction and/or biodiesel production, as an adsorbent for removal of cationic dyes from wastewaters. Batch adsorption tests were performed at 30, 40 and 50oC. Adsorption kinetics and equilibrium were satisfactorily described by the pseudo second-order and Freundlich models, respectively. Adsorption was spontaneous and exothermic. Fixed bed adsorption (breakthrough curve) was satisfactoril...
Autori: Adriana S. Franca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26597

Abstract High resolution gas chromatography coupled with high resolution mass spectrometry systems are often used for the analyses of dioxins at low concentrations in environmental sample matrices such as soil, vegetation, sediment, air and food. Since the construction and operation costs of these systems are so expensive, the most of the laboratories in the developing countries haven’t the systems with high resolution mass spectrometry. Thus, cheaper systems with similar sensitivity s...
Autori: Mahmut Kemal Korucu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26601

Abstract This article presents the results of investigations addressing the accumulation of heavy metals in different layers of the Lake Talkša, Lithuania. For the sampling from the ice of intact structure of the sediment the turf borer was used. Concentrations of these heavy metals in sapropel layers were determined in the extracts of sapropel. After the preparation of samples, the concentration of Pb, Ni, Cr, Zn and Cu were measured in the laboratory by means of atomic absorption sp...
Autori: Justyna Kozlovska
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26615

Abstract Samples were collected for six months (nine storm events) to observe the contaminant loads from three highway segments at Rawalpindi, Pakistan. The contaminants analyzed include total suspended solids (TSS), total dissolved solids (TDS), total nitrogen (TN), chemical oxygen demand (COD), total organic carbon (TOC), total phosphorous (TP), sulphate (SO4), chloride (Cl-), iron (Fe), copper (Cu), zinc (Zn), lead (Pb), and chromium (Cr). Mass vs. volume [M (V)] curves were drawn to inve...
Autori: Hamid Iqbal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26617

Abstract This study examined the characteristics of geopolymer with solar panel waste glass. After 28 days of curing, the compressive strengths of the geopolymer samples containing 10 mass % and 20 mass % solar panel waste glass were 63.3± 1.8 and 49.1 ± 2.2 MPa, respectively. The geopolymer sample with 10% solar panel waste glass exhibited a stronger reaction than that with 20% solar panel waste glass, and the strength decreased as the amount of solar panel waste glass increas...
Autori: HuiCong Hao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26621

Abstract The degradation of polycyclic aromatic hydrocarbons (PAHs) including fluorene, phenanthrene, anthracene, fluoranthene and pyrene were investigated under thermophilic and mesophilic anaerobic-methanogenic conditions. By using central composite design, the impact of PAH concentration and soil to inocula ratio were systematically studied for their influence on PAH removal and biogas production. During the first 30 days, PAH concentration decreased in all samples indicating that the ino...
Autori: Tahseen Sayara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26629

Abstract This paper aims to develop the theoretical framework and the applicative implementation of a new analysis method, which has the purpose of determining and classifying mineral waters in Romania and Europe, with the use of mathematical modelling and fuzzy logic. Firstly, the article underlines the properties of mineral waters in terms of curative effects, particularly the role of Ca2+ and Mg2+ upon the human metabolism. The values of these two chemical elements will constitute an inde...
Autori: Alina Stefanache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26635

Abstract Wine analysis is a complex process, requiring multiple techniques and very in-depth multidisciplinary knowledge. Moreover, when talking about sensorial potent wines, like Muscat or Tămâioasă Românească (from aromatic Romanian grape variety), the identification and characterization of its volatile compounds is achieved through different methods, most calling for powerful solvents to separate the aroma substances. Supercritical fluid extraction is a powerfu...
Autori: Lucia Cintia Colibaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26641

Abstract The caraway (Carum carvi L.) samples were collected from little meadows situated in Harghita Mountain (Mădăraş Ciuc, Harghita Băi, Jigodin, Tuşnadu Nou), where a relatively small area was covered by a group of rich populations of wild cumin. The harvested plants are dried by: a) convective laboratory dryer in thick layer, b) static outdoors in sunshine, and (c) static in a warm indoor place in darkness. The hand-picked seeds were separated from debris by sie...
Autori: Csaba Dezső András
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26646

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract This paper presents the results obtained using the prehydrolysis treatments of rapeseed stalks depending on regime and the catalyst. The vegetal materials were subjected under different temperature conditions and then characterized for the yield reducing substances. The differences between samples have been established by using FTIR and depend on the successive hydrolytic treatments of dynamic and static regime in the presence of various catalysts. The experimental data show that th...
Autori: Corina Măluţan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26654

Abstract Temperature-dependent d.c. electric conductivity of some recently synthesized organic compounds, 4,7-phenanthroline derivatives is studied. Thin-film samples (d=0.34-0.63 m) spin-coated from dimethylformamide solutions onto glass substrates have been used. Organic films with reproducible electron transport properties can be obtained if, after deposition, they are submitted to a heat treatment within temperature range of 298523K. Examined organic compounds in thin fil...
Autori: Cristina M. Al Matarneh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26656

Abstract Sites contaminated with hazardous materials pose serious risks to human health and ecological environments. Quantitative health risk assessment is a site-specific complex procedure requiring evaluation of all possible pathways. Several studies have focused on the evaluation of heavy metals or organic pollutants; however, only few studies focused on the evaluation of diverse pollutants such as heavy metals and organics. In this study, the health risk of heavy metals and organic pollu...
Autori: Hou Wei
ISSN: 1
http://www.ecozone.ro/reviste.php?RID=26663

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract A novel sensitive and rapid analytical approach based on ultra-high performance liquid chromatography - mass spectrometry (UHPLC/MS/MS) tandem was developed for the monitoring of pentachlorophenol in water samples. Chromatographic separation was carried out on Acquity BEH C18 (100 x 2.1 mm, 1.7 μm) column under gradient mode using a mobile phase consisting of acetonitrile/ultrapure water/formic acid. Quantification of pentachlorophenol was performed on a triple-quadrupole tandem ...
Autori: Yassine Kadmi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26673

Abstract The adaptation of commercially available ion-selective electrodes (ISEs) for use in wastewater matrices was demonstrated using multivariate analysis and optimization with the Microsoft Excel Solver tool. The electrodes were characterized in pure analyte solutions, and their parameters were estimated using multivariate analysis and Solver optimization. The ammonium, nitrate, and nitrite ions were measured in model systems that were designed to simulate wastewater. The accuracy of the...
Autori: Natalija Koprivanac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26687

Abstract The bismuth oxide (Bi2O3) nanoparticles are easily synthesized from a solution of bismuth nitrate pentahydrate (Bi(NO3)3·5H2O) in ethylene glycol by a hydrolysis solvothermal route at temperatures of 120-150C. X-ray diffraction, scanning electron microscopy and UV-visible diffuse reflectance spectroscopy are used to characterize the products. The results show that the reaction temperature, the reaction duration and the initial solution concentration play important rol...
Autori: Xiaowen Luan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26689

Abstract The degradation and adsorption behavior of dibutyl phthalate (DBP) in methanogenic phase refuse was investigated through laboratory microcosm experiments. The results showed that the half-life of DBP in the sterilized refuse was 5.9 times higher than in unsterilized samples, but that it decreased by 35.8% when dominant bacterial strains were added. Different concentrations of DBP did not have obvious effects on its degradation. The half-lives of DBP were decreased by 53.0%, 37.2% an...
Autori: Chengran Fang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26690

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract Planktonic algal samples were collected from lakes with different salinity (Salt Lake Brăila, Amara Lake, Fundata Lake, Techirghiol Lake and Black Lake-Sovata), in which mud used in balneary therapy is formed. A total of 189 species were recorded: 35 Cyanobacteria, 10 Euglenophyceae, 96 Bacillariophyceae, 33 Chlorophyceae, 3 Chrysophyceae, 2 Cryptophyceae, 1 Xantophyceae and 9 Dinophyceae. The highest number of phytoplankton species was recorded in Techirghiol lake (127 species...
Autori: Liana Gheorghievici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26719

Abstract This paper aims to analyze the characteristic of Road deposited sediment (RDS) using West Chang Tan highway, Hunan, China as a study site. RDS samples were collected at five representative highway sites and the particle size distribution was generally less than 150μm. Particles with the grain size (<150μm) had high metal concentrations among all sampling sites (unit: mg/kg): Cu 74-178, Zn 309-2737, Pb 601-1160, Cd 9.8-44.5. There is significant spatial variability between t...
Autori: Yunbo Zhai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26728

Abstract Particle size distribution is one of the most influential factors of most soil physical and even some soil chemical characteristics. As modern measurement techniques are being introduced, the need for comparing new methods with older methodologies arises because comparability means data continuity. Here, three institutes conducted a comparison of particle size measurement among the laser, areometer and pipette techniques. The purpose of the comparison was to a) discover any differen...
Autori: Csaba Centeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26733

Abstract Wind erosion, which strongly affects both plant and soil development in arid environments, is dependent on soil properties, wind characteristics and plant cover. In a semiarid zone in SE Spain, a new technique consisting of dusting plants with a forced wind stream reduces tillage and significantly increases productivity. By using a blower once a year, dust is raised and partly retained by plants, and eventually ends up in the understory. To assess the influence of this technique on ...
Autori: Carlos Asensio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26735

Abstract Optimum conditions for the reusability of red mud were explored testing both dried and HCl-activated red mud as a coagulant in the treatment of dyehouse wastewater. Treated dyehouse wastewater was further reused in five dyebaths with different mixture ratios of distilled water (D) and treated wastewater (W) for dyeing fabrics at three color strengths of three reactive dyes. Sludge obtained from the optimum dosage of HCl-activated red mud was tested for its reuse potential in the pro...
Autori: Aylin Yildiz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26738

Abstract The aim of this work was to determine polycyclic aromatic hydrocarbon (PAH) levels in discharge waters from municipal and industrial treatment plants. For this purpose a simple and sensitive method for the analysis of 16 PAHs at ultra-trace levels in water has been developed and validated using liquid-liquid extraction (LLE) and gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS). The total PAH content was in the range 100-800 ng L-1 for samples from surface treatment ...
Autori: Nadia Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26740

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract Extensive use of plastics leads to the increase of non biodegradable wastes that have to be recycled due to both dramatically decrease of natural resources to producing them and to their increasing need as well as due to environmental issues. Most of goods made by materials based on wastes have to be commonly used by people. Antibacterial character of those is necessary to avoid epidemics. This paper deals with determination of antimicrobial character of materials based on polymeric...
Autori: Florica Silvia Cristina Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26751

Abstract The intensive vegetable system means that more toxic organic and inorganic compounds are entering the environment. The aim of this study was to obtain the necessary answers on the content of organophosphorus pesticides (OPPs) regarding to quantify these residues on soils cultivated with vegetables in conventional, organic and conversion systems, and also determine which pesticide residues are going in edible vegetable parts. A number of 23 OPPs were analyzed from soil (50 samples) ...
Autori: Vasile Stoleru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26768

Abstract Solid digestate (SD) represents an environmental problem due to the continuous increase of biogas production. In the present study four white-rot fungal strains were screened for their ability to grow on two different SD samples, obtained from industrial biogas plants, using wheat straw (WS) as a control medium. Results show that i) the feedstock used in the biogas plant influences the time required for the colonization of the corresponding SD and ii) different fungal strains have d...
Autori: Guglielmo Santi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26792

Abstract Based on the study on the reformation of Dawsonite-bearing sandstones with CO2 fluids at different temperature (100oC 200oC and 300oC) and different CO2/H2O/sandstone systems, it is suggested that as the temperature increases, the corrosion intensity of dawsonite-bearing sandstones is gradually increased, but the stability of the sandstone is reduced. The SEM study shows that there are radiated aggregate sediments of boehmite in all samples. At 200oC, with the dissolving of dawsonit...
Autori: Xi-Yu Qu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26814

Abstract Drinking of arsenic contaminated waters has been reported adversely affect our health even at a concentration level as low as 10 g/L, therefore the availability of a reliable and cheap, and an environmentally arsenic detection kit is really indispensable. Although simple field test kits have been developed, most of them use toxic mercuric salt as a color-generating reagent for arsenic detection. Hence this study was conducted to develop a simple, cost effective, and environm...
Autori: Keat Khim Ong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26819

Abstract Waste engine oil contains hydrocarbons which are potentially carcinogenic. The objective of this study was to determine if organic wastes, specifically cow dung (T1) and poultry manure (T2) can improve the microbial degradation of the hydrocarbons. A questionnaire survey to determine generation, management and disposal of waste engine oil was carried out. A Complete Randomized Design, with two treatments and three replications was used to set up plots at Makerere University Agricult...
Autori: Richard Elijah Ssonko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26820

Abstract The aim of this paper is to assess the chemical and mineralogical composition and the leaching behavior of the electric arc furnace slags (EAFS) in order to improve their management by identifying suitable reuse options in different fields. The chemical and mineralogical composition of slag varies from one type of steel to another, from one technological stage to another and from one steel plant to another. In order to minimize the slag quantities disposed in the slag dumps one has ...
Autori: Dana-Adriana Iluţiu-Varvara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26835

Abstract Drying wood requires a significant amount of energy. This includes both thermal energy, necessary to heat-up wood, evaporate the water inside it and cover the insulation and vent losses, as well as electric energy consumed to force air circulation through the stacks. When wood is frozen, both energy consumptions increase; on one hand because frozen water requires a supplementary heat for transformation into liquid and then into gaseous state, and on the other hand, because of the lo...
Autori: Maria Bernadett Szmutku
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26841

Abstract Landslides constitute an abrupt and short-lived geomorphic risk phenomena, which may cause significant damages to human made infrastructures or even claim human lives. The present study aims to assess landslide susceptibility, at regional scale, in the Bârlad Basin, situated in eastern Romania. The subject is approached by means of logistic regression analysis, which is one of the main methods employed for this purpose worldwide. A landslide inventory was carried out by digiti...
Autori: Cristian Valeriu Patriche
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26846

Abstract Popular since ancient times, the mineral waters from Carpathian Chain (Romania) have gained a well-deserved reputation due to their quality and health benefits. This study provides a description of the chemical and isotopic composition (δ2H, δ18O) of mineral waters (CO2 - rich and CO2 - free water) located in six of the most popular areas, in order to improve the overall knowledge about their genesis and recharge mechanisms. The hydro-chemical facies of groundwater vary ...
Autori: Roxana Elena Ionete
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26869

Abstract The aim of this study was to determine the content of the main essential trace (Co, Cr, Cu, Mn, Se and Zn) and toxic (As, Cd, Hg and Pb) elements in milk by inductively coupled plasma-mass spectrometry (ICP-MS) and cold vapor atomic fluorescence spectrometer (CV-AFS) following priory microwave-assisted digestion with HNO3-H2O2. The milk samples were collected from local small-scale producers of different parts of Rodnei Mountains, Eastern Carpathians, Romania. Mean concentrations in...
Autori: Oana Cadar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26876

Abstract The aim of the present study was to determine the most feasible experimental conditions for the dissolution of base metals (Cu, Ni, Zn, Pb, etc.) from waste printed circuit boards (WPCBs) obtained from WMP. The leaching of WPCB samples was performed with FeCl3 in HCl solution which allowed the separation of a precious metal rich solid residue and a high base metal concentration solution adequate for base metal recovery. The most favorable conditions for the leaching process were ide...
Autori: Szabolcs Fogarasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26877

Abstract In the present study, several selected formulations based on recycled (rPP) or virgin polyolefins (vPP) and lignocelluloses were prepared and subjected to microorganism attack. Biodegradation tests were performed with microbial strains belonging to fungal genera, like Aspergillus, Penicillium and Fusarium. The initiation of biodegradation was demonstrated by Scanning Electron Microscope (SEM) micrographs showing the colonization of surface samples by microbial strains. The crystalli...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26879

Abstract To assess the pollutants input of acid mine drainage (AMD) and domestic activities in Aries River, the water was monitored monthly, during one year, in 15 sampling points along the River. The dissolved metals (Ca, Mg, Na, K, Fe, Cu, Zn, Mn), anions (SO42-, NO3- and Cl-), pH and electrical conductivity were analyzed. The obtained data were assessed against the water quality standards, Principal Component Analysis (PCA) and Hierarchical Cluster Analysis. The results revealed the water...
Autori: Erika Andrea Levei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26881

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The results of batch tests of anaerobic dechlorination on groundwater samples collected downgradient from an industrial site in Northern Italy are presented and discussed. The experiments were carried out using sucrose as electron donor at equimolar concentration and at selected excess with respect to the total reducible species. The purpose of the study was to investigate the effectiveness of sucrose to achieve a complete chlorinated solvents degradations at the specific site, and ...
Autori: Luca Di Palma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26895

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

In this work, coagulation features and characteristics of dissolved organic matter (DOM) in combined sewer overflow (CSO) wastewater were investigated. Ferric chloride (FeCl3) and polyaluminum chloride (PAC) were employed in the coagulation process. Results showed that both FeCl3 and PAC are effective in removing turbidity and total phosphorus (TP). Removal efficiencies were all above 90% when dosages were reasonable. Chemical oxygen demand (COD) removal efficiency was between 60% and 70%. T...
Autori: Wei-gang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26931

A drainage channel network in Vojvodina, Serbia, made for collection and transition of (sub)surface waters from waterlogged arable land areas, is exposed to diffuse and/or point contamination sources. Over time, the channel network has accumulated sediment material containing potentially harmful organic substances such as polycyclic aromatic hydrocarbons (PAHs). In this study, the concentration of 16 environmentally relevant PAH substances from 42 sampling points in drainage channel sediments...
Autori: Radovan Savić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26950

Various plants were investigated here as bioindicators for control of the environment. Grass, moss and leaves of maple, birch and oak from different locations, i.e., mining, chemical industrial sites and open green area in a small industrial town in the southwestern Poland (Zloty Stok) were examined. Concentrations of As, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Se, Sr, Ti, V and Zn were measured by the ICP-OES and CVG-ICP-OES techniques. Infrared spectroscopy (FT-IR) was used to inves...
Autori: Lukasz Zarebski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26951

The work studies the degree of heavy metal pollution in water, sediment and soil in the industrial platform area from Ramnicu Valcea, Romania. The water and sediment samples were collected from three locations of the Olt River, in two distinct periods, February and June 2010. Concentrations of nickel, copper and cadmium were analyzed. The soil samples were collected from eight points and the same elements were analyzed, in the above mentioned interval of time. The results of water and sedime...
Autori: Mihaela Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26961

As a result of the rapid development of China’s economy, many surface and groundwater have become polluted. Assuring high quality drinking water, especially for the rural areas has recently received much attention. In this study, the drinking water quality in one centralized water supply network was evaluated by analyzing 28 pollutant indices at 35 sampling points. It was determined that the concentrations of most organoleptic and physical indices were stable in all the water samples. T...
Autori: Wendong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26967

Intensive vegetable crops are stressed by the influence of a large number of chemicals, applied to stimulate fructification, ripening, fertilization, pathogen, pest and weed control. The purpose of this study was to highlight the impact and risk on soil and vegetable plants and products during treatments application with organochlorine pesticides, on three cultivation systems: conventional, organic and in-conversion. The objective of this study was to monitor the content of organochlorine pes...
Autori: Vasile Stoleru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26976

The application of chemical fertilizers and fungicides is an important source of heavy metals into the agricultural soil. Leaching and weathering can facilitate the transport of the contaminants through soil to the groundwater. In most rural areas, groundwater is used for drinking and irrigation purposes, without any treatment, population being exposed to direct contamination. The study area in this paper, Arjaat Village from Rabat Salé Zemour Zaer Region of Morocco, matches into this ...
Autori: François Xavier Nshimiyimana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26980

In the present study, the effects of two methods for thermal sanitization of soil, by oven and by autoclave, and two non-ionizing radiation sterilization methods, UVC and microwave on pH, conductivity, dry weight, total number of germs and respiration of samples from neutral commercial soil were evaluated, using international standard methods. Also, the infrared and UV-VIS spectroscopy were applied for the determination of chemical properties and structural characterization of humic acid and ...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26985

The Lake Bacau I, located in Bacau City, Romania was built in 1966 with a double purpose: as reservoir belonging to the energy system of the Bistrita River and to provide the water needed for the industrial units located in the area. Also, for more than 40 years, the lake was used by the same plants to discharge the wastewater, more or less treated. In present, most of the industrial units are closed and the discharge of wastewater in the lake is banned, the area being used mainly for recreat...
Autori: Maria-Ema Faciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26987

Drainage water and tailings impoundments water geochemistry (pH, EC, alkalinity, trace element concentrations, major ions) were studied at the Anjir Tangeh coal washing plant. The drainage water with neutral to alkaline pH values, high SO42- concentration and low metal content represented typical neutral alkaline mine drainage (NAMD). According to the Stiff and Piper diagrams, the majority of water samples classified into Ca-Mg-HCO3- type except drainage and processing water which were placed...
Autori: Majid Shahhosseini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26997

The densities and distributions of airborne fungal spores known to cause respiratory tract disorders were monitored in three educational buildings located in different boroughs in Iaşi. Air samples from all locations were collected monthly over a period of 3 months (March-May 2011), using the Petri plate gravitational settling (passive) method. Petri plates containing nutrient media were exposed to room air for a 15-minute period, face upwards, to collect particles settling by gravity. A...
Autori: Florin Daniel Lipşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27003

Fly ash is the major residue produced during the combustion of coal. Research has been carried out to recover silica and alumina from fly ashes collected from different thermal power plants in India. Silica and alumina from the fly ash were recovered and the recovered products were subjected to X-ray diffraction, X-ray fluorescence and Inductively Coupled Plasma-Optical Emission Spectroscopy analyses to estimate the silica and alumina content. Total recovered silica content in the samples was...
Autori: Ruth Sherly Endluri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27007

This paper presents the results of measurements related to the activity concentrations of 226Ra, 232Th and 40K in autoclaved aerated concrete (AAC) used as building materials for various constructions in Romania. Radiation index (I) and the hazard index (HI) were estimated to assess the risk arising from the usage of AAC materials. Our study considered various AAC samples produced by different companies, in 2015. The activity concentrations of 226Ra, 232Th and 40K were measured using by a gam...
Autori: Dorina Nicolina Isopescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27018

The aim of this study was to determine the impact of mercury pollution on soil, surface water, and sediment ecosystems in the area of old mercury mines. The study was performed in the touristic area of Sântimbru Băi and Sâncrăieni villages from the Harghita County, Romania. More than twenty years ago, a mine for the extraction of mercury operated in Sântimbru Băi. The area was decontaminated, but no monitoring studies have been made for over 15 years. During t...
Autori: Luisa Roxana Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27038

The investigation of bottom sediments in oxbow lakes was conducted in the free-flowing, meandering section of the Łyna River in N Poland. Seven oxbow lakes, differed by a degree of hydrological connectivity with the river channel, were chosen for the present study. In samples taken from 21 sediment profiles, particle size distribution, pH, bulk density, CaCO3, organic matter, total organic carbon as well as total forms of N, P, K, Ca, Na, Mg, Mn and Fe were determined. The gradient of de...
Autori: Szymon Kobus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27052

In studies of biochemical methane production (BMP) researchers often collate a large number of samples at the same time for a sample archive. The samples are often frozen to avoid microbial transformation, further homogenized by grinding. We studied the influence of subfreezing/thawing and drying/milling of energy crop on BMP and anaerobic biodegradability (BD). Relative standard deviation (RSD, %) between the BMP of controls and of the subfrozen was in the range 2.1–9.0%, and of the d...
Autori: Jin Mi Triolo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27079

Triton X-100 (TX100) and Tween 80 (TW80) were used to study the decontamination of polycyclic aromatic hydrocarbons (PAHs) in the bulk and different size fractions of soil samples from a former coke oven plant. The effects of PAH ring number, initial concentration and soil total organic carbon (TOC)/black carbon (BC) contents on PAH removal efficiencies were analyzed. Surfactant washing for the bulk sample showed clear relation between the removal efficiency and PAH ring number. When the sur...
Autori: Helian Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27093

The main aim of this study is determination of sedimentology and sedimentary environment of Meighan Playa in the Markazi province in Iran. The purpose was to obtain information of sedimentary data and 94 samples of the sediments were collected from a wide range of Meighan playa in order to evaluate the conditions of deposition of the sediments in Meighan playa. With the goal of conducting a detailed and comprehensive study of the sediments in the playa, an attempt was made to collect samples ...
Autori: Mostafa Yousefi Rad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27103

The aim of this study is to investigate an innovative way to utilize the char obtained from tyres pyrolysis, in order to realize lightweight materials for building. Pyrolysis residue, mixed with three types of waste glass, has been used as raw material to obtain lightweight materials, exploiting its capability to behave as foaming agent. The results demonstrate that the pyrolysis char is a good foaming agent for the mixtures 50/50 with glassy sand and packaging glass waste, thermal treated at...
Autori: Fernanda Andreola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27119

This work was aimed to test the suitability of an epoxidized cardanol derived plasticizer for the production of soft PVC characterized by low environmental and toxicological impact soft PVC. Nowadays, the use of natural derived plasticizer in soft PVC industry is emerging as valid alternative towards conventional phthalate plasticizers, in order to reduce the environmental and toxicological impact of soft PVC. In facts, cardanol is a natural and renewable resource, characterized by a wide wor...
Autori: Antonio Greco
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27128

The aim of the present study was to prepare environmentally friendly silver-based materials using Cornus mas L. fruits extract. For this purpose, silver nanoparticles (Cornus mas-AgNPs) were green synthesized using this plant extract. The bioreduction of silver ions was analyzed by UV–VIS and ATR-FTIR spectroscopic studies. Scanning Electron Microscopy (SEM) analysis revealed the formation of spherical phyto-nanosilver particles with size ranging between 12 and 40 nm. Different amounts ...
Autori: Ioana-Raluca Suica-Bunghez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27139

The accumulated characteristics of typical veterinary antibiotics (tetracyclines, sulfonamides, quinolones and macrolides) and tetracycline resistance (tet) genes in the different wetland soils (Krasnozem and Chernozem), and the effects from Phragmites australis were evaluated in this study. Results indicated that the concentrations of targeted antibiotics and tet genes in soils with swine treatment would increase as time progressed. The tet genes and targeted antibiotics (except sulphonamide...
Autori: Lin Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27145

Hesperaloe funifera was studied as a new raw material for paper manufacturing and lignin recovery. An experimental design was carried out to improve the quality of the obtained pulp varying the process temperature (155, 170 and 185 ºC), time reaction (20, 40 and 60 minutes) and soda concentration (5, 10 and 15 %). All experiments were carried out with 1% anthraquinone. Lignin content, holocellulose content, α-cellulose, viscosity, Kappa number and drainability were determined in the d...
Autori: MŞ Ángeles de Andrés
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27185

As part of the 2012 Land Use/Land Cover Area Frame Survey (LUCAS), topsoil samples were collected in Bulgaria and Romania using the same methodology as for other EU Member States in an equivalent survey carried out in 2009. In total, 664 Bulgarian and 1384 Romanian samples were collected which enabled a comparative assessment of topsoil properties under different land covers within, and between, these countries, as well as in a broader European context. The samples were analysed for basic soil p...
Autori: Gergely Tóth
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27205

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

In this paper photo-oxidative degradation of degradable mulching films was studied. Low-density polyethylene (LDPE) films were denominated as 3# and 4# (containing 3.43% and 0.44% degradable masterbatch, respectively), They were exposed to different irradiation condition of i: ultra violet A irradiation (UVA), ii: ultra violet A and B irradiation (UVA-B), both at 58±2°C. The physical chemical property of the plastic film is influenced by factors in many aspects, especially the composi...
Autori: Ya-xi Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27232

In this article we present the results of the study concerning the relationship between the concentration of trace elements (lead, chromium, cadmium, cobalt, copper, zinc and nickel) in soil and in the leaves and bark of Populus nigra L. The samples were collected in the period May 2010 – October 2010 in two areas from the Romanian North Littoral of Black Sea. The concentrations of the trace elements in soil, leaves and bark were determined using Flame Atomic Absorption Spectrometry (F...
Autori: Lucica Barbeş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27239

Reuse of grey water is an attractive option when available water supplies are limited, and can reduce demand on water supplies and provide additional water resource. This comparative research was conducted to assess the suitability and effects of reusing grey water, treated and untreated, as irrigation water for vegetables, compared with tap water. Tomato (Lycopersicon esculentum) and green bean (Phaseolus vulgaris) plants were selected as examples. The collected grey water samples were treated ...
Autori: Jehad Y. Al-Zou by
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27254

Soil in industrial cities and their surrounding regions sustains high levels of contamination due to the intense industrialization and urbanization. Taiyuan, a city in northern China, and its surrounding regions are a hotspot for the development of heavy industry. To assess the environmental quality, we collected surface soil samples from Taiyuan’s urban–rural transition zone. We determined concentrations of Cr, Cu, Pb, Zn, As, Cd, and Hg. The primary inputs of Cr and As were pedogen...
Autori: Jinchang Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27260

Carbonaceous materials were obtained from waste tyres and their potential application as hydrogen sulphide adsorbents was investigated. The adsorbents were obtained by pyrolysis of waste tyres and physical (CO2) or chemical (KOH) activation at 550 and 800ºC. The effect of modification conditions on the performance of waste tyres based materials as adsorbents of H2S at room temperature in dry and wet conditions was investigated. Sorption capacity of such adsorbents was found to strongly depe...
Autori: Magdalena Hofman-Bieniek
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27263

In this work, twenty different physical and chemical methods were used to study the effect of pretreatment on Cr(VI) and Cd(II) biosorption by an aquatic plant (Ceratophyllum demersum) biomass. The H3PO4 boiled biomass had the highest biosorption capacity (45 mg/g) for Cr(VI). The NaOH boiled biomass showed a higher biosorption capacity for Cd(II) (63 mg/g). Dunnett's test was carried out to compare the biosorption capacity of raw biomass with those pretreated by H3PO4 and NaOH, and the resu...
Autori: Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27265

The aim of this study was to determine the actual impact of the uncontrolled landfill site in Roman town, Romania on the water resource quality. The surface water and groundwater samples were collected quarterly in two time periods: January 2012 - June 2013, when the landfill was operational and July 2013 - December 2014, after the landfill was closed. The parameters analyzed in this study include: pH, biological oxygen demand (BOD5), chemical oxygen demand (COD), NH4+ Cl-, NO2-, NO3-, SO42-, he...
Autori: Lacramioara Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27283

Paintings signed by Nicolae Grigorescu and Stefan Luchian, exponents of Romanian Modern Art were selected for a technical study on easel painting canvases. Both the physical integrity and the appearance of the artefacts derive mainly from the strength of the canvas and the physical and chemical characteristics of the fibres imparting their response to deterioration. In order to determine a deterioration pattern for canvases subjected to environmental stress, a simulation on flax fibres samples w...
Autori: Maria Geba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27292

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

According to literature, aggregate stability of soils is influenced by: particle size and soil texture, soil structure, content of Ca2+ and Mg2+, mineral clay type, soil content of organic matter, soil processing degree. This paper aims to investigate the influence of some physical, microbiological and chemical properties of saline soil concerning water-stable aggregate. The hydro system stability of the aggregates appears in the specialized studies as having a positive correlation with microorg...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27300

Construction industry uses a huge quantity of traditional and modern building materials which generally are produced to satisfy different demands, such as: resistant and safety requirements, friendly with the environment, architectural aspects etc. Researches must solve any requirements related to materials properties and offer a large diversity from which the proper solution must be considered. For improving the mechanical properties of polymer concrete, the use of fibers of different types is ...
Autori: Vasilică Ciocan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27306

Considering the actual environmental issues, the waste management has become a major challenge in Europe and worldwide. Recycling the waste into sustainable products can be an alternative to landfill with positive effects on the costs and environmental pollution. In this respect, in the last years numerous studies and research emphasize the utilization of different type of waste to obtain materials for building applications. The aim of this paper is to assess the effect of using sewage sludge ge...
Autori: Petronela Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27315

This paper presents some experimental results regarding mechanical behaviour at shear cutting Miscanthus x giganteus stem with an oblique blade of different edge angles. Experimental determinations were performed using samples of about 30 mm in length and a medium diameter of about 6.3 mm to 8.9 mm. The biomass was cut with three bevel cutting blades of 30 degrees, with a tool angle of 10, 30 and 50 degrees, fitted on an equipment used for mechanical experiments type Hounsfield, with a working s...
Autori: Georgiana Moiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27317

The remarkable photocatalytic properties of titanium dioxide and the high adsorption capacity of the mesoporous materials were combined to obtain active photocatalysts for the decomposition of Rhodamine 6G dye. The mesoporous TiO2 was obtained by the controlled hydrolysis-condensation of titanium isopropoxide, using hexadecyl-trimethyl-ammonium bromide as template, followed by calcination to remove the organic matter. Subsequently, this sample was doped with sodium wolframate and platinum. T...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27325

Mining activity implies a series of environmental issues that can have short or long term consequences: deterioration of natural landscape, air, water and soil pollution, negative impact on aquatic and terrestrial ecosystems and on human health. The present study was performed on a mine dump from the Giumalau Mountains, Eastern Carpathians, Romania. A number of 28 samples were collected and analysed by ICP-MS for 9 minor elements (As, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn) and also by XRD for the m...
Autori: Madalina Paiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27330

In the current context of industrialization, chemical and radioactive pollution is a concern for environmental protection and interference with human health. Care for environmental protection also includes vegetation that grows spontaneously in potentially contaminated places, thus avoiding illness among the population if consumed. The study area is located at 4.5km SSE from downtown Bacău City, Romania and is the result of the manufacture of H3PO4 through the wet method. In this study, t...
Autori: Mioara Săndulache Rachieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27331

The composition and the structure of the soil matrix have an important role in determining the water and the air regime into the soil. In the soil pore the area occupied by water and air, capillary and adsorption phenomena occur, together defining the suction of the matrix. The suction-humidity relationship varies from one soil to another, but also to the same soil in time. This paper sets out the results of investigations aimed at highlighting the influence of the composition and structure of...
Autori: Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27332

The present study shows the results of the chronic test in evaluating the response of lumbricidae under the action of different concentrations of Alleato 80WG. The earthworm samples were taken from a plot of land cultivated with maize. Survival, biomass and aluminum content bioaccumulated in earthworms have been analyzed. Five replicates were carried out for each experiment. The survival rate showed maximum values (100%) for V5 (control sample), and (200 mg kg-1) (p=1) for V4. The other three co...
Autori: Gheorghiţa Brînzea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27334

This paper presents the research results on the development and implementation of a traceable and efficient system which is characterized by a high accuracy level, transposed within a specialized IT application in order to properly implement certain sampling schemes required for assessing the conformity of civil use explosives and pyrotechnic articles, in compliance with the European Directives 93/15/EEC (new 2014/28/EU) and 2007/23/EC (new 2013/29/UE). The scientific research results emphasized...
Autori: Daniela Rus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27365

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

In this pilot study, exposure to airborne microorganisms in solid recovered fuel (SRF) plants has been measured. Different steps in SRF production processes such as separation and size reduction can cause generation of airborne microorganisms. Exposure to these biological agents can cause some health problems, so their levels should be measured to assess the potential risks. Therefore, exposure to airborne total bacteria, Gram-negative bacteria, actinomycetes and fungi were measured in the runn...
Autori: Şenol Yildiz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27373

The aim of this work was to study the effectiveness of photocatalysis in the removal of contaminants from secondary treated municipal wastewater, on a batch scale. The samples were collected from the outlet of the secondary clarifier in the municipal wastewater plant located at Al Khoudh, Muscat, Sultanate of Oman. The influences of TiO2 catalyst loading and solar radiation exposure time were investigated for the removal of COD and total Coliforms. 60% removal of COD was achieved with a catalyst...
Autori: Anna Jesil Cheriyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27376

This study presents mercury (Hg) assessment in water from tailing dumps collected form NW Romania by using commercial Diffusive Gradients in Thin-films (DGT) devices and Thermal Desorption - Atomic Absorption Spectrometry method (TD-AAS) technique. Additional aim of this study is to present Hg method validation and measurement uncertainty estimation for selected samples. An atomic absorption spectrometer based on thermal desorption for mercury vapor generation and DGT devices specific for Hg (c...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27383

Construction industries generate a large amount of concrete wash water every day, and it causes soil, surface water and ground water pollution. Therefore, re-using concrete wash water to produce fresh concrete is one of the solutions to prevent environmental pollution and to sustain water use. In this study, we tested setting time of cement, slump, compressive and tensile strength of 24 triplicate cubic samples of concrete with and without micro silica plus additive admixture using concrete wash...
Autori: Gholamreza Asadollahfardi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27389

Anthropogenic activities negatively affect the ecosystems by introducing high amounts of metals in the environment. The study assessed the contamination and ecological risk caused by As, Cd, Cr, Cu, Pb and Zn in urban soils situated near a metallurgical complex, based on geochemical load (Igeo), contamination factor (Cfi), degree of contamination (Cd), potential ecological risk factor (Eri) and potential ecological risk index (Ri). The results showed concentrations above the geochemical backg...
Autori: Maria-Alexandra Hoaghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27394

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

This research was focused on the valorization of agro industrial waste/by products available in the local industry with the kilometer zero (km 0) concept, as a replacement of virgin raw materials (clay) to elaborate lightweight aggregates (LWAS). The alternative raw materials were employed as pore forming agent, in order to reduce sintering temperature and energy consumption of the furnace. The three technical nutrients studied were provided for local food industries: sludge from wastewater trea...
Autori: Romina D. Farias
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27405

The research work aimed at analysing the drinking water quality in Vilanculos (Mozambique) and at investigating the influence of poor sanitation management on drinking water quality. The purpose was to understand the reasons of water source contamination and re-contamination in the water supply chain, in order to define strategies to control source contamination and to suggest practical ways for reducing the risk of recontamination. A first phase of microbiological drinking water quality monito...
Autori: Silvia Gibellini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27406

Removal of the heavy metal ions from water disposals remains a widespread problem due to their adverse influence on public health. The most harmful materials are the products of nuclear fission called radioisotopes such as cerium ions. Cerium barely interacts with adsorbent materials, therefore the new substances capable to bind cerium are of great interest. Ca and Na alginate samples were incubated in Ce3+ solutions; adsorption capacity was measured and the results were evaluated using Langm...
Autori: Maxim Khotimchenko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27435

Acid-base accounting was applied to evaluate the acid generating potential of waste rock dumps of different ages at a nickel mine in Zimbabwe. Metal concentrations in soils surrounding the dumps were also assessed. The net neutralising potential (NNP) of waste rock samples was derived from the maximum potential acidity (MPA) and the neutralising potential (NP). MPA and NP were determined based on total sulphur and acid consumption respectively. Waste rock dumps (WRDs) had more (p<0.05) su...
Autori: Artwell Kanda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27437

A total of 152 different actinomycetes isolates were recovered from samples that were collected from different ecosystems of Algeria. The desert soil of Bousaada gives the greatest number of actinomycetes compared to others soils. The first screening indicates that 63.15 % of the isolates were able to produce carboxymethyl cellulase enzyme. Isolates were evaluated for their cellulase activity by growing in carboxymethyl cellulose broth. B-PNG23 isolate is one of the isolates displayed a high enz...
Autori: Azzeddine Bettache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27451

Considering that glass containers are generally highly transparent they are good candidates for spectroscopic measurements and application of a transmittance for glass separation. The selection of glass container samples directly from municipal waste disposal bins, characterized by different colors, thicknesses, and shapes was done. Transmittance spectra of clear, green, amber and black clean glass containers were recorded, along with spectra of the usual bottled liquids. Positions of the absorp...
Autori: Dragana D. Strbac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27452

This work aims to study the physicochemical and biological parameters of Boukerdene Dam’s water and treated water at different steps of the treatment processes in Sidi-Amar’s Station (Tipaza, Algeria) with a particular interest to the phytoplankton. This work is also related to the demonstration of the enhanced coagulation (EC) process as an efficient method in algae and organic matter (OM) removal from surface water by its application in jar tests. The diversity of the phytoplank...
Autori: Djamel Ghernaout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27459

This paper displays the kinetics of the corrosion process for short-term immersion of seven mild steel samples of similar compositions. A comparison between the data obtained for corrosion process in three types of water: bidistilled water (BW), drinking water (DW) (tap water) and river water (RW) (from Bahlui River, Iasi, Romania) has been done. Electrochemical techniques such as the cyclic voltammetry (CV), the linear voltammetry (LV) and the rotating disk electrode technique (RDE) have been u...
Autori: Alexandra Ciomaga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27460

The purpose of this paper is to present the results regarding the obtaining of reducing sugars at the enzymatic hydrolysis of the lignocellulosic material, wheat straws. For these, the lignocellulosic material was submitted to a preliminary pretreatment for destruction of the cellulose crystalline structure and to increase the material's susceptibility to the enzymatic attack. The preliminary pretreated material with diluted acid (0.5%-4%) or with water at different temperatures (120-170&ord...
Autori: Eufrozina Albu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27463

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

In the present study the potential of a gene fusion between the arsB promoter from Synechocystis 6803 and the bacterial luxAB genes was evaluated to be used as a cyanobacterial bioreporter for monitoring the bioavailability of inorganic arsenic species. A whole-cell bioreporter strain, designated arsLux, was constructed based on this fusion. In concert with the specificity of the promoter presented earlier, luminescent signal could be detected upon exposure to arsenite, arsenate and antimonite, ...
Autori: Loredana Peca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27473

The paper presents results obtained by analysis of some soil and wastes samples in order to establish the heavy metal (HM) content from these samples. The analyzed wastes were sewage sludge from municipal waste treatment and hydrotechnical basin sludge. These types of wastes were mixed with soil from Oltenia Sub-Carpathian area, obtaining the substrates useful for different types of plants. It was studied the migration potential of the metals from substrate to apple trees, the results being comp...
Autori: Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27476

The particulate matter samples were studied in the surrounding of the different mills in Penang and Kedah State, Malaysia. Multivariate statistical techniques such as multivariate analysis of variance (MANOVA), discriminant analysis (DA) and principal components analysis (PCA) were applied in analyzing the air quality data. MANOVA showed a strong significant difference between the five palm oil mills. DA identified two functions responsible for discriminating the mills and it showed that the...
Autori: Nik Norulaini Nik Abd. Rahman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27484

This study focuses on some mechanical properties resulted from the tensile testing of a set of green composites with a Dammar-based matrix and reinforcement material of silk, flax, cotton and hemp fabrics. To be precise, we have ascertained the characteristic curve, the resistance to and the elongation at fraction, as well as the modulus of elasticity for each set of samples from these composites and for a set of bioresin samples. With the help of an Electronic Scanning Microscope we captured im...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27516

The aim of the studies was to evaluate the influence of the 30-year operation of a small retention reservoir fed with water from a forest-agricultural catchment area on the contents of selected mineral elements substances in bottom deposits. The studies were carried out in the Łoje dam reservoir (N 53o7’28’’, E 20o48’20’’), supplied by the regulated Łojówka stream. Deposit samples were collected in four transects perpendicular to the reservoir...
Autori: Ireneusz Cymes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27518

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

In this paper, a model based on Back-Propagation (BP) artificial neural network was proposed, as a tool predict the soil suitability for cultivation in Jiangxia district. The model takes the soil nutrients indicators as the input and the level of soil suitability as the output. The correlation analysis showed that the correlation coefficient between expected output and actual training result is 0.99. The simulative results indicate that the learning and generalization ability of the model perfor...
Autori: Zhuoyan Feng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27546

The solid-liquid extraction process and some of its influencing factors such as solid-liquid ratio, temperature and salt initial amount have been investigated. Also, mathematical modeling for mass transfer coefficients calculation was applied. An inert porous solid material (coal), impregnated with 10% and 20% mass NaCl or 15% and 30% mass CaCl2, was used. The leaching was conducted in a fixed bed column, in laminar flow. The CaCl2 impregnated samples were investigated in a column with a height...
Autori: Marcel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27557

Recently, the studies about vitamin B12 increased due to the high number of people who can develop vitamin B12 deficiency, namely: vegetarians, pregnant women or with vitamin B12 malabsorption. One solution to correct the low nutritional intake of vitamin B12 can be using food supplements or pharmaceuticals, based on the vitamin B12 microencapsulation. In the present research, the vitamin B12 microencapsulation and the controlled release of fresh and 4 months’ storage samples of vitamin B1...
Autori: Ioana C. Carlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27559

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

This work focuses on the analysis of material composition of mixed municipal solid waste (MSW) in the city of Košice, the second largest city in Slovakia, and in the village of Poproč, which is representative of the region. The paper describes the characteristics of the monitored localities, the methodology and the original evaluation procedure. The analysis of the mixed MSW composition in Poproč was performed in 2009-2010, and in Košice in 2011. In both cases, the analys...
Autori: Takáčová Zita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27570

Simulation experiments were conducted to investigate the behaviour of ozonation by-products and the removal of organic matter in the treatment of the Pearl River raw water. The treatment processes include pre-ozonation, conventional treatment processes (coagulation/sedimentation and sand filtration), post-ozonation and granular activated carbon (GAC) filtration. Treatment efficiency of each unit process was evaluated by using several parameters such as permanganate index (CODMn), ultraviolet abs...
Autori: Yue Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27580

The influence of the active compound of Moringa oleifera Lam (MO) seeds was evaluated by different methods for the preparation of the natural coagulant in the treatment of surface water. Nine methods were analyzed, comprising samples of seed powder with different granulometry, aqueous and saline solutions, evaluated before and after oil extraction from MO seeds. Tests of coagulation/flocculation and sedimentation were accomplished using simple Jar Test. Natural coagulant dose of 50 mg.L-1 identi...
Autori: Karina Cardoso Valverde
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27588

This paper presents the research on the temporal variability of water quality parameters for the most important river system in Romania and Europe – Danube River. The data on the river water quality had been obtained during ten years. The investigation was systematic and complex. Using the Kolmogorov-Smirnov test, and traditional statistical methods based on correlation matrix - Principal Component Analysis (PCA) and Factor Analysis (FA), and ANOVA all the samples data sets were classified...
Autori: Paula Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27601

A 120 kilometers reach of the Prut River, Romania was surveyed and the concentrations of four trace metals (copper, cadmium, lead and zinc) were determined in water and sediments. These elements are the main pollutants expected in the region, as a steel-producing factory in Romania is located in the close neighborhood of an area under protection, the Lower Prut Floodplain Natural Park. Samples were collected in 2010 and 2011 from the water-sediment interface at six locations along the lower sect...
Autori: Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27612

In order to investigate the influence of coal macerals on biomethane production, two types of coal samples were collected respectively from Malan mine in Gujiao and Shaqu mine in Liulin, Shanxi. The vitrinite, inertinite and liptinite were separated by the methods of hand picking and float-and-sink test. Meanwhile, biomethane production experiments using the raw coal samples, vitrinite-rich coal samples, inertinite-rich coal samples as substrates were carried out in the laboratory. Finally, the ...
Autori: Hongyu Guo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27620

Aerobic treatment processes using attached media have been studied extensively to remove organic matter from wastewater and also denitrification process. The objective of this study was to assess the ability of down flow anaerobic up flow oxic submerged bio-film reactor (DAUOSBR) to remove phosphorus, nitrogen compounds, BOD5, COD, turbidity and total suspended solids from the Farabi Hospital wastewater. The present work involved designing and building a reactor loaded with down flow anaerobic u...
Autori: Meghdad Pirsaheb
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27622

This study was conducted on samples taken from the “Fagul Cetății – Iazul nr. 4” tailings pond in the Eastern Carpathians, Romania and is focused on exploring the way in which heavy metals from sulphide rich material are spatially distributed in relation to the geochemical conditions. For comparison, concentrated ore samples from the same area, genetically linked to the Tulgheș lithogroup were also analysed. The mineralogical and chemical composition of the sampl...
Autori: Sorin-Ionuț Balaban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27626

Water is currently becoming a strategically important material, and the importance of water and wastewater treatment technologies is therefore increasing. Wastewater from the food industry has many special features originating from its high organic matter content. Meat industry wastewater additionally has a high fat content. We investigated the effects of ultrafiltration and ozonation, individually and in combination, for the treatment of meat industrial wastewater. Ozone gas was generated from ...
Autori: Cecilia Hodúr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27631

Thin-film transistor liquid-crystal display (TFT-LCD) waste glass can be used as a raw material for producing geopolymers, because it contains large amounts of silicon and aluminum in its amorphous structure. The setting time and compressive strength were evaluated to determine the quality of the geopolymer product with various amounts of nano-SiO2 (0%–3%) and TFT-LCD waste glass replacement (0% - 40%). The microstructures of the samples were characterized using mercury intrusion porosimet...
Autori: Kang Gao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27634

An attempt has been made in the present study to investigate the wastewater characteristics from six different rural human settlements in the state of Punjab, India. The six selected rural catchments are located on a radius of about 5-50 kilometers from Phagwara town, Kapurthala district. The study area comprises the villages of the districts of Jalandhar, Kapurthala and Shaheed Bhagat Singh Nagar in Central Punjab. The wastewater samples were collected between January, 2012 and July, 2012 and a...
Autori: Puneet Pal S. Cheema
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27641

In this study, the concentrations of 15 phenol derivatives were analyzed from the phreatic and groundwater wells surrounding a decommissioned chemical factory in a village from the western part of Romania. An UPLC-MS method was used to assess the concentrations of the chemical target compounds in the water samples. The most frequent compounds were 4-chlorophenol, 4-tertoctylphenol and 4-nonylphenol, being detected in 17 of the 19 sampling sites, while the least frequent compound was 2,4,6- t...
Autori: Elena Preda
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27661

Leakage through flaws in geofilm was examined with laboratory tests by flexible wall permeameter. Samples cracks were cut open by the sharp blade, with the results that the widths of the flaws were the same while the lengths were different. During the research, a series of laboratory permeameter tests have been performed to determine the influence of the various factors on the leakage rate of water through the flaw at the center of geofilm. The impact of various parameters examined included t...
Autori: Guangwei Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27674

One of the main challenges for the development of biomass algal system production is the high operational and capital costs for these technologies. A great opportunity to overcome these challenges may however exist in the integration of wastewater treatment with algal biomass production. The algae are used for treatment of industrial wastewater, for purification of effluent originating from livestock production, while the studies concerning the use of algae species for the treatment of aquacultu...
Autori: Katya Velichkova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27684

The changing characteristics of vegetation carbon patterns in the karst region of northwest Guangxi, China and their impact factors were analyzed on the basis of vegetation inventory data from 2005 to 2010. A radial basis function network model (RBFN) was constructed using data from 1377 samples and 13 environmental factors. The results for the 5-year study period were as follows: (1) The total carbon storage of vegetation had increased with an annual growth rate of 1.84% and the carbon density ...
Autori: Mingyang Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27692

Industrial wastewater is of particular importance. In most wastewater treatments, physicochemical parameters are used to determine the performances which are costly while protozoa can be used as less expensive biological indicators to determine the efficiency of the treatment plant. The purpose of this study was to investigate the relationship between protozoa and physic-chemical characteristics of the Abadan wastewater treatment industry. Samples were collected from wastewater stabilization po...
Autori: Abotaleb Bay
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27694

The presence of nitrogen in its reduced forms serves as an indicator of natural aquatic system degradation. The excessive concentrations of nitrogen in reduced forms (NH4+, NO2-) found in the sections of the the Shireutsi (of the Prut River) and the Olaneshti (of the Nistru River) prove that these sites are areas to focus efforts on improving water quality. Laboratory simulations indicate a good environmental buffer action of natural waters to potential pollution in Sculeni and Ungheni sections ...
Autori: Petru Spataru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27698

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

With the aim of contribute to a bioremediation technology drafting, this paper presents a preliminary research on bioremediation of wastewaters polluted with heavy metals and other toxic contaminants. Bioremediation tests were performed with aquatic species Lemna minor, Vallisneria spiralis, Eichhornia crassipes, Hydrilla verticillata, Pistia stratiotes, Cladophora glomerata, on samples of contaminated waters resulting from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu Co...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27702

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27782

The present paper focuses upon the analysis of 226Ra, 232Th and 40K radionuclides, making use of high-resolution HPGe γ-spectrometry devices. By means of this technique, the radiological risk is investigated in the case of various sand samples. The natural concentrations for 226Ra, 232Th and 40K, from sand samples, ranged from (9.3-20.0 Bqkg-1), (9.1-23.7 Bqkg-1) and (203.5-403.3 Bqkg-1), respectively. The radium equivalent activity of sands under investigation was also analyzed and ranged...
Autori: Dorin Vasile Moldovan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27775

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments wer...
Autori: Irina Catianis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27770

Influence of soil pH on the mechanical characteristics of glass reinforced plastic (GRP) pipes type was often investigated in different situations encountered in the field. GRP degradation is directly proportional to the exposure to soil with non-neutral reaction. The theoretical and experimental results lead during time to design standards, which allow the application of GRP pipes in water and soil, so as minimum interferences with the materials used in the manufacture of pipes would appear. Sa...
Autori: Ana Diana Ancas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27768

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27729

• INFLUENCING FACTORS OF THE ACCEPTABLE AMOUNT OF COMPENSATION OF FARMERS FOR CONTROLLING FERTILIZER-INDUCED WATER POLLUTION    • DETERMINATION OF THE RARE EARTH METALS IN THE RED MUD FOR POSSIBLE UTILIZATION    • Fe(II) AND Mn(II) REMOVAL FROM CONTAMINATED GROUNDWATER BY ADSORPTION: A COMPARISON OF ACTIVATED CARBON AND PINE BARK    • RESPONSE OF UPLAND COTTON GENOTYPES TO SALINITY AT EARLY GROWTH STAGES    • KINETICS AND ISOTH...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27730

This paper presents the effect of heavy metal soil pollutants (Pb, Cd, Cu, Zn) on soil mite communities in three urban parks within Bucharest, Romania: Cişmigiu, Unirea and Izvor. For each park, the investigations were based on three transects that were established in relation to the nearest source of air pollution i.e. heavy traffic from the main boulevards. The study was carried out in 2007. 405 soil samples were collected, comprising 14 species of Gamasina. The highest numerical density ...
Autori: Minodora Manu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27736

The objective of this study was to evaluate the effect of different doses of meat and bone meal (MBM) applied as organic fertilizer on the quality of groundwater in arable fields. The effect of meat and bone meal fertilizer applied at rates of 1.0, 1.5, 2.0 and 2.5 t ha-1 was compared with no fertilization, mineral fertilization, and manure fertilization (10 t ha-1). Groundwater samples for chemical analyses were collected every month during the growing season using piezometers installed in the ...
Autori: Arkadiusz Stępień
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27742

Capillary gas chromatography coupled with mass spectrometry technique was used for the assessment of low concentration of dinitrophenol pesticide, Dinocap in different spiked samples. For this purpose it has been spiked with Dinocap (15- 200 μg/mL) five environmental matrices (a soil sample and two each samples of wine and grapes). The Dinocap degradation grade in these samples was also monitored. The extraction was performed in dichloromethane. The assessment of the Dinocap in the samples we...
Autori: Nicoleta Grigoriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27746

During the years 1965-1985, a veritable industrial platform was developed in the west part of Oradea, Bihor County, Romania. It stretches on an area of 9 sq. km. and is placed in the meadow of Crisul Repede River. Throughout that period, several industrial facilities were built that lately became sources of pollution for the environment. The purpose of the present paper is to study the influence of historical stages of industrialization and restructuring of enterprises in Western Oradea, address...
Autori: Tamara Romocea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27747

This study was conducted to screen plants growing on potentially contaminated areas of landfill body and nearest surrounding to determine their potential for metal accumulation. In addition, enrichment coefficient (EC) for plant/soil system, correlation and principal component analysis were used for determining the environmental contamination from landfill in terms of heavy metal (HM) accumulation. The examined plant samples meet the stated requirements. The highest values in samples 1 - 8 reach...
Autori: Magdalena Daria Vaverková
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27752

A study was conducted to determine the composition and concentration of trace metals in suspended particulate matter (PM10) and indoor dust in two academic buildings of Universiti KebangsaanMalaysia. One building was in the final phases of renovation (UR) and the other building had just finished renovation (AR). PM10 sampling of air was performed using a low volume sampler (LVS), and samples of indoor dust were obtained using a brush and a small plastic bag. The compositions of trace metals in b...
Autori: Mohd Talib Latif
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27758

Water sea pollution is influenced mainly by anthropogenic causes due to industrial and municipal activities which affect the quality of sea water, sediments and the whole ecosystem. In this paper, the correlation between contamination sources and the environmental quality of marine sediments was analyzed through multivariate analysis, in particular Principal Components Analysis (PCA), Cluster Analysis (CA) and Correlation Analysis. Considering the case study of Mar Piccolo in Taranto (Ionian Sea...
Autori: Claudia Labianca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27793

Large amounts of spent coffee grounds (SCG) are currently available all over the world due to the enormous increase in coffee consumption. This increase has in turn to be related to the even greater diffusion of coffee vending machines. The aim of this study was to evaluate the biomethanation potential (BMP) of SCG alone or in co-digestion with pig slurry (PS). Pig slurry was chosen because it is frequently utilized as feedstock for biogas production from agricultural waste. The raw material was...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27794

This paper exposes the research activities regarding REBAF (Energetic Recover of River Biomasses) project, focused on the maintenance operations self-sustainability of the Secchia river (Italy). Poplar was found as the most abundant and representative wood plant of Secchia riverbanks, with a good behavior during gasification process: from 1 hectare of maintenance every three year, it was possible to produce 23 MWh of electrical power and 31 MWh of thermal power. The biochar obtained was characte...
Autori: Vittorio Vezzali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27804

The aim of this paper was to investigate the possibility of incorporation non-metal fraction (NMF) in concrete products as a substitute for aggregate on industrial scale, while other studies are mostly based on NMF incorporation in concrete only on laboratory scale. Mineral filler was supplemented with 5, 10, 15 and 20 wt.% NMF from waste printed circuit boards (WPCBs) and its influence on concrete quality was assessed based on compressive and tensile strength conducted on laboratory and indust...
Autori: Vitomir Premur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27857

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

Within this study a total content of 20 elements was determined in 25 soil samples taken from the vicinity of the "Buchim" mine, Republic of Macedonia, covering an area of 14.2 km2. The results have been compared to new Dutchlist and NOAA standards and it was concluded that the content of As, Cd, Cu, Pb and Zn in most of the samples is over the corresponding optimal or action values probably due to the anthropogenic activities. Thus As values ranged 13.1-225 mg kg-1 with 20 above the o...
Autori: Todor Serafimovski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27844

To investigate the sources and spatial distribution of heavy metals in soil, samples were collected at two scales from the alluvial plains of Shenyang, China. Statistical analysis at small scale showed average concentrations of Cu, Pb, Zn, Ni, Cr and As of 36.76, 33.33, 100.06, 37.98, 91.26, and 7.99 mg/kg, respectively. Corresponding large-scale concentrations were 34.11, 46.38, 82.44, 32.51, 83.77, and 24.06 mg/kg. At both scales, Ni and Cr were mainly controlled by parent materials and Pb ...
Autori: Jin Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27877

Air cooled and water cooled slag samples were obtained from a demonstration plasma gasification / vitrification unit. The leachability of the major heavy metals present (Cr, Cu, Mn, Fe, Pb and Zn) in both the air cooled and water cooled slag when in contact with acidic solutions was investigated under different temperature, stirring and contact time conditions. Water cooled slag showed better resistance to heavy metals leaching. The vitrification process immobilised Cr and Pb. The leachabilit...
Autori: Konstantinos Moustakas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27882

The Danube River forms one of the largest and most complex deltas at the Black Sea, being a Biosphere Reserve, UNESCO World Heritage and Ramsar site. This study assesses the spatial variability of arsenic contamination of the water in the Danube Delta. Water samples were collected during all seasons in 2013 from the south-east of the Danube Delta and analyzed through HG-AAS method for arsenic. Data were handled using two different approaches. First, a complex hydrological model was compiled, ...
Autori: Gabriel Gati
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27884

A study on the biodegradability of several formulations based on poly[vinyl alcohol] (PVA) and wood flour has been carried out. Basically, all formulations are based on PVA and wood flour, and the influence of starch, glycerol and/or polyvinyl chloride (PVC) incorporated in some of them was investigated. Biodegradation was performed by incubation of the composites with a selected Aspergillus niger strain able to act as an polymer biodegrading agent. The composites biodegradation was evaluated...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27886

In this study, the flocculating properties of different cactus juice preparations were assessed using synthetic and real industrial and leachate wastewaters. It was found that the crude CJ had a flocculating activity (FA) of 89 ± 2.2% which is significantly higher than that of a powdery sample derived from a 60°C oven-dried CJ sample and which was about 37.8 ± 2.5%. Interestingly, both crude and dried samples showed the ability to flocculate kaolin suspensions within a wide ...
Autori: Moncef Khadhraoui
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27887

Sand contamination is an important factor when assessing the health hazard potential of public beaches. The goals of this study are to assess the performance of four sand washing procedures on the removal of surface adsorbed chemical species, and to identify which chemical components are best suited for monitoring the health quality of beach sand. Four washing treatments were investigated: contact, stirring, sonication, and boiling. Sand samples were collected from three Portuguese beaches an...
Autori: Mário Dias Almeida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27890

In this work, the examination of separation of gypsum from wastewater generated during the machining of casts and the method of waste gypsum management have been presented. This waste gypsum is produced in Ortolab Poland facilities. Gypsum casts are cut and ground in water-cooled circular saws. Wastewater, with over-normative content of suspension, 10000 mg L-1 and sulphates, 1600 mg L-1 is produced in the process. The analysis of water and wastewater management in Ortolab Poland facilities l...
Autori: Ewa Liwarska-Bizukojc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27910

This study was planned to identify factors which affect workers health and their safe working in unregistered and partially registered small iron units preparing 90- 95 % iron furniture under sheds. Focused group discussions (FGD) were conducted among workers of iron furniture manufacturing units (IFMU) employing a cross sectional, descriptive, analytic and time limited study. Personal interviews methodology was adopted to assess workers for their exposure to occupational risks, protective eq...
Autori: Saima Aslam Bharwana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27925

The objective of this work was to evaluate the effects of six lactic acid bacterial strains originated from different natural habitats of fermented food and feedstuff on pasture grass and alfalfa laboratory scale silages. The prepared mini silos were inoculated with the following bacterial strains alone or in combination: Lactobacillus brevis LbB (2x107 cfu/mL), Enterococcus faecalis EF (3.6x108 cfu/mL), Lactobacillus plantarum subsp. plantarum LbP (2.8x108 cfu/mL), Weissella paramesenteroide...
Autori: Éva Laslo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27933

Agro-industrial waste are seen as potential precursors in the development of adsorbents for the removal of phenolic compounds, which exhibit a harmful effect to human health due to their high toxicity. This work evaluated the use of coal prepared from coconut tree agro-industrial waste, for the adsorption of phenol in aqueous solutions. Three coal samples were prepared as follows: carbonized only (Cb), activated with synthetic air (Cair) and activated with CO2 (CCO2). Based on the results of ...
Autori: Marta Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27937

In the mineral matter of coal there are microelements chemically bounded to organic matter or mineral impurities in various combinations that catalyzes the evolution / involution of a spontaneous combustion phenomenon as an accelerator in the oxidation reaction or which slows down these processes. Specialised literature analyzes the phenomenon of coal self-heating based on several theories of which we exemplify the theory of coal oxidation, the theory of pyrite and the theory of the microele...
Autori: Cristian Tomescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27966

The main objective of this research is to investigate the effects of lime and waste silica fume additive on a silt and its utilization on railway subgrades stabilization. For this purpose, lime and waste silica fume were added to the silty soil in different contents at the soil optimum moisture; then the California Bearing Ratio (CBR) tests were conducted on the soil samples to estimate the favorable mixture design. At the next step, a selected sample was chosen to be exposed to wetting–dr...
Autori: Reza Ziaie Moayed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27972

In this paper, we determined some mechanical properties of a new category of green composites, based on tensile tests. More precisely, we selected a set of samples from a new bio-resin based on Dammar and two sets of samples from green-composites with matrix by bio-resin and reinforced with almost compact layers of Typha latifolia or Schoenoplectus lacustris. For these built materials, we obtained the characteristic curve, tensile strength, percentage elongation after fracture and elasticity mod...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27980

In this study, Coal Fly Ash (CFA), a byproduct of coal combustion power plants, was used as an adsorbent to remove color from locally-obtained pulp mill effluent (PME). Batch adsorption studies were conducted to determine the adsorption parameters that would result in the maximum color removal from PME at the lowest CFA dosage and process cost. The effects of operating variables on color removal were studied by varying: 1) CFA dosage, 2) initial PME pH, and 3) contact time. The findings indic...
Autori: Christopher Willett
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27986

Little is known about the degradation kinetics of sewage sludge, sanitized with Ca(OH)2, in soil. Thus, this work aimed to monitor the degradation of limed sludge, under field conditions, when applied on soil surface or incorporated into the soil. The limed sludge was applied in dystrophic Inceptisol at a dose of 500 kg ha-1 yr-1 of total nitrogen. The mineralization process in the soil was monitored for 131 days. Samples of organic material were collected for analysis of total and easily oxi...
Autori: Isabela Diniz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27995

This paper aims to disclose the quantitative relationship between benthic diatom biomass in natural rivers and environmental factors. For this purpose, the author selected seven natural rivers in the basin of Minjiang River as the objects. First, the samples of benthic diatoms and the environmental factors were collected from 14 different sampling sites of five rivers and the diatom density and Chlorophyll a (Chl a) content were selected to characterize the diatom biomass. Then, the number of...
Autori: Baichuan Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28001

The paper reports on the preparation of polysiloxane hydrophobized viscose-maghemite/goethite magnetic composite with properties appropriate for uses in oil spill sorption from polluted aqueous media. A multi-step procedure was employed to obtain the polymeric composite. The structures of the prepared samples and precursors were analyzed by Fourier transform infrared spectroscopy (FTIR), whereas their morphology was investigated by means of scanning electron microscopy (SEM). The hydrophobic...
Autori: Răzvan Rotaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28008

This paper discussed the results of studies regarding metal ions distribution in water, sediments, aquatic plants and different tissues of fish from Snagov Lake, Romania, a natural lake situated 25-30 kilometers north from Bucharest, the capital of Romania. The concentration of several metal ions (Li, Ba, Al, Pb, As, Se) was measured in three points of the lake, namely receiving-input, middle and discharging-output ponds. The samples were collected during spring time from water, sediments, Ce...
Autori: Daniela Simina Ștefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28010

The diversity of fungi colonizing pine and spruce seedlings was analyzed in container and field (bare-root) nurseries in the Region of Warmia and Mazury, Poland. The presence of pathogenic fungi and Oomycetes belonging to the genera Botrytis, Cylindrocarpon, Fusarium, Pestalotia, Phoma, Phytophthora, Pythium and Rhizoctonia was noted in the sampled seedlings. The presence of the pathogenic species C. destructans and species belonging to the genera Fusarium and Phytophthora on the roots and s...
Autori: Adam Okorski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28036

This study is a comparative assessment of domestic water quality collected from 35 sampling points in seven typical rural communities in Abia State, Southeast Nigeria. Physicochemical parameters such as pH, conductivity, turbidity and bacteriological parameters such as plate count and total coliform were analysed in the laboratory using standard World Health Organization (WHO) methodology. Results indicate that there are significant variations (p<0.05) in the physicochemical parameters of the...
Autori: Oliver O. Odikamnoro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28054

The main objective of the research was to study the efficiency of the glyphosate amine pesticide mineralization in wastewaters (real and model type of wastewaters respectively) using ozonation treatment as an advanced oxidation processes (AOP). The wastewater samples (model wastewater) were obtained by mixing a given volume of the stock solution prepared from glyphosate isopropyl-amine in different volumetric ratios with distillated water and with real wastewater obtained from a domestic wastewa...
Autori: József Németh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28050

A simultaneous hierarchical classification of groundwater in the Banat Plain-southwestern Romania and associated characteristics such as As(III), As(V), total As, trace metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn), pH and redox potential using Fuzzy Hierarchical Cross Clustering Algorithm was carried out. In samples containing more than 10 μg/Ltotal As (13.9 – 77.3 μg/L), the As(V) species represented 57±20% and 73±18% in the others. Arsenic speciation pattern was in agr...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28059

The influence of 50 Hz sinusoidal magnetic field on physico-chemical properties of water was studied. Tanks with distilled water (120 mL) were individually exposed to action of homogenous 50 Hz magnetic fields, using a Helmholtz coils system. For magnetically exposure have been used different values of magnetic flux density (between 1 and 5 mT) and different durations of exposure (between 5 and 240 minutes). By means of this experimental study the physico-chemical properties of exposed water sam...
Autori: Mihaela Răcuciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28061

Leather processing is one of the highly polluting industries, due to generation of significant quantities of tanned and untanned wastes. Untanned wastes are less contaminated with chemicals and a better source of high value products such as collagen rather than tanned or finished leather wastes. In the present study, collagen dissolution substances (CDS) were prepared from bovine limed split wastes as value added products, by treating leather wastes with sodium hydroxide and fermented dairy b...
Autori: Gökhan Zengin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28095

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

Balkan endemic nephropathy (BEN) is a chronic kidney disease occurring predominantly in certain rural villages from Balkan Peninsula, including Romania. Peculiar environmental factors, such as drinking water, organic contaminants derived from coal, plant toxins, mycotoxins, heavy metals have been proposed to be causing the disease. Still, one of these etiological factors stands out: Aristolochia clematitis L., a plant that contains aristolochic acids (AAs) known as carcinogenic and nephrotoxic c...
Autori: Lavinia Paula Drăghia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28104

Wastewater generated from industrial activities has delivered elevated heavy metal concentrations into fresh and salted aqueous systems. Herein, the migrated trace metals were studied from their initial location through a coastal aquifer up to the seawater. The experiments were carried out at lab scale using a sandbox with glass beads and two attached chambers containing natural groundwater and seawater. The study focused on the transport behaviour of heavy metals such as copper, zinc and lead i...
Autori: Abdelkader Tawfeek Ahmed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28111

This study is an attempt to monitor the indoor microclimate and the microbiological contamination of some indoor objects inside a wooden Orthodox church. Standard microbiological techniques were used for the isolation and identification of the fungi present in the dust of the superficial surface of the paintings chosen to be investigated for biodeterioration. Samples were taken from approximately 1 cm2 of the surface of the analysed paintings (cotton canvas, wood, on primer) using the cotton swa...
Autori: Dorina Camelia Ilieș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28114

Aim of the study is to determine Fe, Mn and Cd adsorption in the carbonate-rich clayey soils and to assess their environmental impacts. Soil samples represented a carbonate-rich clayey soil (Isaoren), carbonate-rich soil (Maşuk) and clayey soil (Aşık) was obtained from three different villages in Sanliurfa, southeast of Turkey. Adsorption studies were carried out with batch method. The maximum Fe, Mn and Cd adsorption was found on Isaoren, Maşuk and Aşık soils with ...
Autori: Ayse Dilek Atasoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28116

Soils are influenced by stand composition and hydrological regime as well as by stress abiotic factors, including forest fires. As such, this study analyzed three stands affected by fires of different severities. Soil samples were gathered during the spring of 2017 from three sample areas in Vrancea County, eastern part of Romania. For each area studied, soil profiles were studied in 3 areas affected by fires and in control areas located close to each other. The soil respiration was determined b...
Autori: Aurelia Oneț
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28120

Municipal wastewater treatment is a global issue and an expensive process. Treatment of the wastewater using algal growth is a cost-effective approach, because of easy propagation of algae in wastewaters through utilization of most of the nutrients and in turn reduces the pollution load. As a preliminary research work, laboratory scale studies were done using native algal species collected from particular sources. They were grown in different pond waters to observe the biomass development in co...
Autori: Iqbal Ansari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28135

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

Molybdate anions are used in a lot of fields and represent an essential trace element for plant and animal life; however, excessive amounts can cause adverse effect on various organism and environment. Therefore, in the present paper the adsorption performance of MgnFe- layered double hydroxides in the removal process of molybdate from aqueous solutions was studied. The layered double hydroxide (LDH) was synthesized by co-precipitation at low oversaturation method. Different ratio between Mg and...
Autori: Alin Golban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28152

The contamination of aquatic and terrestrial environments by pesticides is highlighted by their possible toxic properties and poor biodegradability on the environment. The development of low cost by products from agricultural sectors as a suitable solution for contaminated areas remediation is of great environmental interest. Straw wastes can be considered as a promising alternative to remove different chemical compound that are environmentally toxic. In this study, some materials derived from ...
Autori: Irina Gabriela Cara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28161

The study attempted to identify the best suited models to determine the kinetics of chlorine decay and trihalomethanes (THMs) formation in drinking water supplies. Batch experiments were conducted on synthetic water samples to simulate the characteristics of raw water collected from Maithon water treatment plant (MWTP), Dhanbad, Jharkhand, India. Influence of various parameters like total organic carbon (TOC), reaction time, pH and chlorine dose on the rate of THMs formation were analysed. The s...
Autori: Minashree Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28171

The anthropic impact, having various forms, negatively changes the parameters of water quality and disturbs the living environment of benthic macroinvertebrates. The purpose of the present study is to present how the main sources of pollution influence the way of life of the benthic macroinvertebrates community. 20 quantitative benthic samples were collected from different benthic areas of the Bega River water during from June 2014 to February 2017. In addition to identify all the changes that o...
Autori: Adina Horablaga
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28178

This study is a physical characterization of household waste in the town of Annaba (Algeria North East). Based on an adequate sampling protocol that takes into account the constraints of Algerian cities; Annaba city was taken as a case study for the rapprochement of the situation in Algeria. A quantity of 90 to 120 kg was sorted for each type of habitat in the city during four seasons of the year 2010 to 2011 according to 11 components of household wastes. Variations in the percentages of som...
Autori: Hamza Cheniti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28197

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

LED waste quartz sand (LEDWS), which is a prominent by product of the LED manufacturing process, may contaminate the environment because it comprises specific heavy metals (e.g., As and Cu), which are hazardous ingredients to the environment when disposed of improperly. Therefore, this study investigated the use of light-emitting diode (LED) waste quartz sand to partially replace Portland Type I cement (OPC) to evaluate the feasibility of reusing it as a pozzolanic material. The SiO2, Na2O, and ...
Autori: Kae-Long Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28207

Water shortage is one of the most worrisome issues around the globe, especially with the increase in the human population. Nowadays, attention has been drawn towards the reuse of greywater because of its large volume and low contaminants. In the present research, greywater samples were collected from different sources including; households, restaurants, mosques, laundries, guest houses and sport clubs in Mansoura city, Egypt. The counts of total coliforms, Escherichia coli, Enterococcus sp., Ps...
Autori: Samir Radwanhttp://www.ecozone.ro/reviste.php?RID=28221

The negative environmental impact of the shooting ranges occurs through shot and bullets containing metals that are harmful to the environment. The objective of this study was to investigate the changes in physicochemical properties and contamination with heavy metals in soils of two Lithuanian outdoor shooting ranges. Soil samples were collected from the outdoor rifle shooting ranges which differed in shooting activity. The higher concentrations of Pb were found in the shooting range (8272 mg ...
Autori: Gintarė Sujetovienė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28227

Cultural heritage objects represent valuable testimonies of the past, which must be kept in the right condition to transmit to future generations. Together with the spectacular progress recorded by humankind regarding technology, opportunities to obtain valuable data on heritage objects so as to preserve them have started to emerge. The current researchers aimed to determine the internal composition of the colors and materials used in some paintings from a historic wooden church monument, from ...
Autori: Elena Demenchuk
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28230

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

Nutrients have been considered the main factor affecting microorganisms responsible for methane gas production during anaerobic digestion processes. In this study, the nutritional composition of some fruit wastes; mango (M), watermelon (W), pawpaw (P), their effects on methane gas production, and resulting energy values were assessed. Substrate samples for anaerobic digestion where prepared into various slurry treatments; M, W, P, WM, PW, MP, MWP and CONTROL. Proximate compositions of the subst...
Autori: Ogemdi Chinwendu Anika
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28233

The migration of methanogen in coal seams have great significance to study the improvement of coal bed gas (CBM) production by injecting microorganisms.This study aims to identify the migration characteristics of methanogens in different rank coals. Methanobacteria migration test was carried out by using coal samples of different particle sizes in the different rank coals. The results show that the maximum relative bacterial absorbance of a Qianqiu mine 18-35 mesh sample was 0.68, higher than th...
Autori: Hao Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28236

The aims of the paper were to determine the contamination of fluoride in edible plants, meat and poultry products in contaminated areas. The urine samples from 373 village health volunteers living in 21 villages in Ma Khuea Chae sub-district, Lamphun province, Thailand, were collected and the fluoride concentration was measured by Ion Selective Electrode. Their village health volunteers were selected for further surveys regarding the consumption of edible plants, meat and poultry products which...
Autori: Sanhawat Chaiwong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28247

Bad water quality has serious implications for human health, which may include gastrointestinal, liver, respiratory diseases and even cancer. In view of drinking water hardness in the study area, it was hypothesized that bad water quality has some association with the renal disorders. The possible association between nephrolithiasis, drinking water quality and diet in human subjects in district Abbottabad, Pakistan was investigated. Drinking water samples were collected from different areas (tot...
Autori: Suneela Jadoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28252

Taking the sandy aquifer intruded by seawater in the lower reaches of Dagu River as the research object, the samples of underground freshwater, seawater and aquifer media were collected, and their composition and properties were determined. The seepage device was used to simulate the displacement process of seawater and freshwater. The relationship between permeability change of aquifer and hydrologic-geochemical action was studied. The mechanism of water sensitivity was explained by a hydrologi...
Autori: Jiaguo Ren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28281

The aim of this study is to design and characterize a new controlled release fertilizers category by using valorization of residues from agri-food, industrial and post consumers activities normally allocated into landfill disposal. The underlying strategy in materials research fully agreed with the circular economy perspective and the more recent European legislation about critical raw materials recovering. This study covers the development of lightweight aggregates, based on a local red clay (k...
Autori: Silvia Barbi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28286

The concentrations of Copper (Cu), cadmium (Cd), manganese (Mn) and lead (Pb) in liver, kidneys and red meat of cattle slaughtered in selected abattoirs in Owerri metropolis, Nigeria were studied using atomic absorption spectroscopy (AAS). This was performed in relation to their concentrations in a forage grass, Panicum maximum randomly harvested from roadsides of Owerri- Onitsha and Owerri-Aba expressways. Results obtained showed that cattle meat samples contained all heavy metals studied. Thei...
Autori: Henry Uzoma Anuforo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28320

The spread of antibiotic resistant organisms and those producing extended spectrum β-lactamases (ESBL) has become a health care problem worldwide in communities and hospitals, as it leads to more complicated infections, longer duration of treatment, and increases in patient mortality. In the present study, we analyzed 226 clinical samples in order to assess the spread of ESBLproducing Enterobacteriaceae. 196 Enterobacteriaceae were identified and classified as members of the genera Pantoea...
Autori: Abdelbasset Mechai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28331

Road dust from atmospheric deposition is considered as one of the significant environmental pollutants for containing toxic heavy metals. In this connection, to explore the present scenario of urban contamination and potential health risk of heavy metals present in road dust; this study was carried out in Tangail Municipality Area of Bangladesh. Road dust samples were collected seasonally from five different sampling sites encompassing different traffic homogeneity. Collected samples were proces...
Autori: Mir Talas Mahammad Diganta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28334

In this study, the change of freeze-thaw test result of unconfined compressive strength of clayey soils reinforced with pine tree sawdust and marble dust was investigated. Mixtures containing 5%, 10% and 15% marble dust and 0.5%, 1% and 1.5% pine tree sawdust were compressed by standard Proctor test with optimum moisture content. After curing the mixture samples for 1, 7 and 28 days at a working room temperature of +21°C, they were subjected to the freeze-thaw test at -21°C, +21°C fo...
Autori: Necmi Yarbasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28342