AbstractNatural hemp fibers have been evaluated for Zn (II) ions sorption from diluted aqueous solutions. In order to establish the optimum conditions, the effect of initial pH of solution, hemp dose, Zn (II) concentration, temperature and contact time of phases on the Zn (II) sorption by natural hemp has been studied. To model the Zn (II) sorption at three different temperatures the Langmuir and Freundlich isotherms have been used. The Langmuir maximum sorption capacities were determined as bei...
Autori: Carmen Paduraru, Lavinia Tofan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25336

Abstract This paper aims to analyze theoretically events in the economy - ecology - environment (natural resources) mega - system. This analysis includes methodologies making use of the first and second thermodynamic principles (for approaching the waste role in technological processes contour toward environment and the entropy variation importance in the main environmental segments), the application of systems theory and theories relating to emergy. The obtained results allow us to propose, ba...
Autori: Avram Nicolae, Cristian Predescu, Maria Nicolae, Mirela Gabriela Sohaciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25428

For a better evaluation of the impact of road traffic about air quality, this paper considers the development of a new evaluation index system and methods. They address the assessment of the air quality around the areas with an intense road traffic, according to Chinese standards considering sulfur dioxide index (SO2), total suspended particles index (TSP), floating dust index (PM10), nitrogen oxides index (NOX) and carbon monoxide index (CO). A systematic air quality evaluation model was establ...
Autori: Zhao-hui Liu, Zhi-bin Qinhttp://www.ecozone.ro/reviste.php?RID=25714

AbstractThis paper focused on estimating climate change impact on the future water availability in the Yellow River Basin,China. However, climate change and its impact on water availability are subject to large uncertainties. In order todeal with uncertainties, scenarios were used to explore possible future states of climate variables under uncertainty,and probabilities were attached to represent uncertainty explicitly according to the Principle of Maximum Entropy.Probabilistic scenarios of futu...
Autori: Congli Dong, Gerrit Schoups, Nick van de Giesen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25957

AbstractThe performance of four low cost Iraqi clays, bentonite (BT), kaolinite (KT), attapalgite (AT) and flint (FT) to remove lead ionsfrom aqueous solutions by adsorption was investigated. Batch experiments were carried out at pre determined equilibration time,adsorbent dosage, solution pH, particle sizes, ionic strength, initial lead ions concentration and temperature. Adsorption of Pb2+ions was strongly affected by pH and best adsorption is achieved at pH 4.5. The systems were investigated ...
Autori: Najwa I. Abdulla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26086

AbstractAdsorption of a cationic dye, methylene blue, from aqueous solutions by using sawdust (without any modification) by batchadsorbers was investigated. The surface characterization of the saw dust was carried out by Fourier transform infrared (FTIR) andscanning electron microscopy (SEM) and pHzpc of the surface was also determined. Effects of different parameters such ascontact time and initial concentration, temperature and pH on the process of removal were studied. The process of removal ...
Autori: Sushmita Banerjee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26216

AbstractIn this work, fruit shell of Cocos nucifera (FSCN) treated with H3PO4 has been tested as a low cost adsorbent for the removal of methylene blue (MB) from aqueous solution in batch and column process. The adsorption of MB onto FSCN was affected by the initial solution pH, dye concentration, temperature, column internal diameter and adsorbent dose. The adsorption equilibrium data was fitted well to the Langmuir model and the maximum adsorption capacity was found to be 20.74 mg/g at 40şC. K...
Autori: Pijush Kanti Mondal, Rais Ahmad, Rajeev Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26274

AbstractTo assess the shares of each indicator of environmental and economic benefits in iron and steel enterprises, the entropy weightfuzzy comprehensive evaluation model is built in this paper based on the consideration of entropy theory and fuzzy mathematicaltheory. The weights of each indicator are determined by entropy optimal theory, and the correlative indicators are processed byfuzzy synthesis evaluation, so as to provide some references for environmental and economic benefits evaluation...
Autori: Bin Wang, Hua Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26375

AbstractThe researches were initiated in the context emphasized by the competition having the idea of profit at its base, and sustainabledevelopment, which imposes limitations through different regulations and standards which would involve supplementary costs.The research highlights the main trends in plastic product design in conditions of sustainable development of society. Plasticshave an important role in the configuration of the new products just in the phase of conception. Having in mind t...
Autori: Petrica Corabieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26472

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract The purpose of this study was to investigate the influence of hydroxypropyl-β-cyclodextrin on diosmin, substance from the flavones category with important pharmacological properties. We carried out solubility studies, calculating the solubility constant of the complex formed between diosmin and hydroxypropyl-cyclodextrin at various temperatures (20, 25 and 37 0C) and in the presence of increasing cyclodextrin concentrations. AL type curves were obtained which suggest the format...
Autori: Constantin Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26643

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract Low-carbon logistics is an important part of the fight against global climate change. It is particularly important that rapidly expanding cities establish scientific and comprehensive evaluation indexes for low-carbon logistics in order to accurately and quickly determine their logistics development situation. This paper develops an evaluation index system, especially including low carbon technological progress, and applies the entropy weight method to calculate the weights of indic...
Autori: Yanchun Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26804

The coastal zone accommodates some of the most diverse ecosystems in the world and offers a wide range of ecosystem goods and services; therefore it has become a focal point of human development. Over the last five decades, starting from 1960s, Kuwait has seen a tremendous alteration in the natural coastal morphological landscape (CML) due to the tremendous increase on coastal population that existed 50 years ago to the present manmade environment today. Most of the population is located in ...
Autori: Saji Baby
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26947

In this study the immobilized waste black tea (Camellia synensis) was used as biosorbent for the removal and recovery of Al(III) and Cr(VI) ions from the synthetic aqueous solutions. Batch experiments were conducted to optimize the various biosorption parameters that affect the biosorption capacity of immobilized waste black tea. Maximum biosorption capacity was found with a biosorbent dose of 0.1g/100 mL for both metal ions. Optimum biosorption capacity for both Al(III) and Cr(VI) ions was o...
Autori: Haq Nawaz Bhatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27004

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

This study highlights the potential use of yellow Zea mays seed chaff (YZMSC) biomass as a biosorbent for the removal of Cr3+, Cd2+ and Pb2+ ions from aqueous solutions. Fourier transformed Infrared analysis of the biomass suggests that YZMSC biomass is basically composed of cellulose and methyl cellulose. The biosorption capacities, qmax, of YZMSC biomass for Cr3+, Cd2+ and Pb2+ are 14.68, 121.95 and 384.62 mg/g respectively. Biosorption equilibrium was achieved at 20, 30 and 60 min for Cr3+...
Autori: Jonathan Oyebamiji Babalola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27083

In this paper we applied multi-criteria methods of decision in order to establish the best encapsulation material to be used in producing photovoltaic modules. The encapsulation materials play an important role in establishing the PV module performance, especially if referring to their ability to increase their life time. For our study, we have considered the most widely used encapsulation materials available on the market, such as Ethylene-Vinyl Acetate (EVA), Polyvinyl Butyral (PVB), Thermo...
Autori: Gabriela Demian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27169

Equilibrium and kinetics of biosorption of lead(II) from aqueous solutions by local low-cost agricultural by-products – peanut hulls, soybean shells and grapefruit peels were compared to develop high-efficient and low-cost biosorbents for removal of lead(II) from wastewater. Batch kinetics showed adsorption equilibrium at about 90 min and the adsorption process for the three biosorbents was better represented by the pseudo-second-order model than the pseudo-first-order model. Batch equilib...
Autori: Rui Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27176

The discovery of entropy in thermodynamics has set fundamental premises for the study and analysis of the relationship between the entropy law and economic processes, as one of the main objectives of such endeavours was to separate the qualitative aspects from the realm of economics. The law we have chosen to focus on in the present paper states that, in the universe or in isolated structures, entropy increases constantly and irreversibly, thus causing a continuous and unidirectional degradat...
Autori: Ionel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27179

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

The Romanian peat was used as low-cost adsorbent to remove Cd(II) ions from aqueous solutions. The cadmium adsorption capacity of the peat was studied as a function of the solution pH (3-5.5) and temperature (293 – 333 K). Adsorption capacity was found to increase with the pH increasing and temperature decreasing and attained a maximum value of 27.9 mg/g at pH = 5±0.1 (acetate buffer) and 293 K. In addition, various thermodynamic parameters such as free energy change (ΔG0), en...
Autori: Catalin Balan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27276

A light-driven dissipative engine, which must necessarily operates at a nonzero rate and far from equilibrium to be capable of providing power and work, is investigated in this paper. On the basis of the assumptions that the heat exchange between the working fluid and the environment obeys the linear phenomenological heat transfer law [ q  (T 1) ], the piston trajectories minimizing the entropy generation are determined. Furthermore, numerical examples are provided for...
Autori: Lingen Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27432

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

To assess energy conservation and emission reduction effect on traffic and transportation at macro level more scientifically, the evaluation system based on the improved osculating value method for transportation is established. Information entropy weight is introduced to the traditional osculating value method and the numerical matrix normalization process in the osculating value method is simplified. The pollutant emission and the energy consumption is defined as negative index, and the capaci...
Autori: Yang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27470

The aim of this study was to examine the adsorption of malachite green dye from aqueous solutions on the waste foundry sand. The effects of contact time, adsorbent amount, pH and initial dye concentration were investigated. The equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin adsorption isotherm models. The adsorption capacity of waste foundry sand for the removal of malachite green dye was determined with the Langmuir and found to be 23.29 mg/g. The adsorption isothe...
Autori: Elif Hatice Gürkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27536

Over the last few decades intensive human activities and climate changing have stressed ecological systems impeding sustainable development of the social economy in many regions in China. The importance of ecological security has gained greater prominence. Sustaining or restoring natural functions of water ecosystems is also crucial for human welfare. To assess water related ecological security (WES), this paper constructed a framework based on the Pressure-State-Response (PSR) model with indica...
Autori: Xiuping Hao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27615

The adsorption rate and dynamic behavior of the system are important factors as regards the process design and operational control. The aim of this study was to find a suitable kinetic model for the hexavalent chromium removal in a batch reactor. The experimental data were analyzed using four adsorption kinetic models: the pseudo- first and second order equations, the Elovich equation, and the intraparticle diffusion equation, so as to determine the best fit equation of the Cr(VI) adsorption ont...
Autori: Ankica Radjenovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27773

The Eco-Indicator 99 (EI99) method and the ReCiPe method are used to determine the fundamental uncertainties in the life cycle impact assessment (LCIA) model through the configurations of the following six methodological options: egalitarian/egalitarian (e/e), egalitarian/average (e/a), hierarchist/hierarchist (h/h), hierarchist/average (h/a), individualist/individualist (i/i), and individualist/average (i/a). In this study, the aforementioned options were presented as (i) a set of methodologica...
Autori: Oleg Verbitsky
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27839

In the present work, acid treated natural oil palm trunk powder (OPTP) has been utilized as novel adsorbents for the removal of methyl orange (MO) from aqueous solution. The batch method was employed to study the adsorption behavior of MO which was subsequently determined by UV/Visible spectrophotometer. The adsorption characteristics and operational parameters were determined by monitoring different parameters such as pH, contact time, dye concentration and temperature. The acid treated OPTP an...
Autori: Akil Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27975

The paper is focused on the integrated modelling of environmental quality. It shows how we can use multi-criteria decision analysis to study some aspects about the environmental quality status in a region and its evolution during a certain period of time. The global analysis is created by taking into account the concurrent contributions of different factors such as air quality, drinking-water quality and noise pollution, on the quality of the environment people live in. We propose an indicator,...
Autori: Luminita Grecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28246

The present study describes the facile synthesis of silver nanoparticles (AgNPs) by green method using aqueous extract of Gazania rigens. The size, morphological, compositional and optical properties of silver nanoparticles were examined through X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), Scanning Electron Microscope (SEM), and UV-Vis spectroscopy respectively. Ultraviolet-Visible spectra showed the absorbance band between 425–460 nm which indicated the synthesis o...
Autori: Tayyaba Shahzadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28349