<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

The present paper examined the photocatalytic degradation (PCD) of gas-phase trichloroethylene (TCE) over thin-film TiO2. A large-scale treatment of TCE was carried out using scale-up continuous flow photo-reactor that nine reactors were arranged in parallel and serial. The parallel or serial arrangement is a significant factor to determine the special arrangement of whole reactor module as well as to compact the multi-modules in a continuous flow reactor. The conversion of TCE according to the ...
Autori: Gyung Soo Kim, Sang Bum Kim, Sung Chang Hong
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25121

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei, Gabriela Apostolescu, Ioan Rosca Studies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monit...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25175

Contain all the articles from this issueCatalysis for heterogeneous photocatalysis. Part II. Methods for synthesisAnca Florentina Caliman, Ion BalasanianpH influence on sonochemical degradation of cyanides with H2O2 and O2Ioan Iordache, Mircea Teodor Nechita, Nicolae Aelenei,Gabriela Apostolescu, Ioan RoscaStudies of various wastewater nitrification bioreactor types based on modelling and simulationDiana Lupasteanu, Florina Ungureanu, Maria Gavrilescu Wastewater from winemaking industry: monitor...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25179

Contain all the articles from this issueLignin in crop cultivations and bioremediationAlfred Abaecherli, Valentin I. PopaMaterials for intermediate-temperature solid oxide fuel cells and for proton exchange membrane fuel cellsAnnemarie Huijser, Joop SchoonmanAre interfacial biocatalysts important tools for nonpolluting technologies? 2. Immobilization of lipases and their  representative applications Brindusa Dragoi, Emil DumitriuUASB treatment of fruit canning wastewater: pilot-scale invest...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25180

AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

Abstract The photocatalytic degradation of sulfamethazine, a sulfonamide drug, has been investigated experimentally, in aqueous heterogeneous solutions containing n-type oxide semiconductors as photocatalysts, and by simulation, using neural network modeling. Through direct neural network modeling, the evolution of the photocatalytic oxidation process is evaluated as function of illumination time and type of catalyst. Inverse neural network modeling is a particular optimization that gives inf...
Autori: Ciprian George Piuleac, Ioannis Poulios, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25430

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract:The textile industry uses high quantities of water which in many cases are disposed to the environment with inadequate treatment.In this work the effluents from the polyamide textile industry containing Bemacid Gelb, Bemacid Rot and Bemacid Blau weretreated by heterogeneous photodegradation. Treatment performances have been evaluated in terms of conductivity, turbidity, totaldissolved solids (TSD), chemical oxygen demand (COD), total organic carbon (TOC), biochemical oxygen demand (BOD5...
Autori: Luminita Andronic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25720

Abstract:Point of zero charge (PZC) is defined as the condition at which the surface charge density of a material equals to zero and, formost of the solids it is strongly pH dependent. The PZC can be controlled by tuning the solid surface properties (crystallinestructure, morphology) and by a proper environment control, thus it is important to evaluate the PZC for a certain type of material,in given working conditions, for enhancing the efficiency in the targeted application (e.g. layer by layer...
Autori: Laura Maria Bertus, Radu Adrian Carcel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25721

Abstract:Hydrothermal synthesis was used to obtain nanostructured TiO2 based nanopowders. There were prepared pure and ZrO2 dopedcompositions consisting mainly of anatase phase with crystallite size up to 20 nm. The agglomerates of the as-synthesizedmaterials had dimensions ranging from a few hundreds nanometers to 200 microns. The investigations concerning the thermalbehavior revealed the presence of an exothermal effect at around 550oC which could indicate a possible phase transformation ofana...
Autori: Adrian Mihail Motoc, Anca Duta, Oana Raita, Radu Adrian Carcel, Radu Robert Piticescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25758

Abstract:In this study, the adsorption mechanism of a reactive azo dye, Reactive Yellow 125 (RY 125), onto a nitrogen doped TiO2 modified zeolite (Z-TiO2-N) has been examined in order to identify the affinity of the material for the investigated pollutant envisaging its degradation by heterogeneous photocatalysis. Equilibrium experiments were performed and the data obtained were fitted with different isotherm equations, i.e., Langmuir, Freundlich, and Dubinin-Radushkevich (D-R). The Freundlich i...
Autori: Cornelia Ratiu, Elida Cristina Ilinoiu, Florica Manea, Laura Cocheci, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25809

The aim of this study was to investigate photocatalytic activity of a silver doped TiO2 modified zeolite (Z-TiO2-Ag) in the photocatalytic degradation of Reactive Yellow 125 (RY 125) azo dye. The operational conditions using photocatalyst dose of 1g¡L-1 at pH 6 were established as optimal conditions for photocatalysis application in RY 125 dye solution degradation. The photocatalyst exhibited a good performance for discoloration at all studied concentrations (25, 50 and 100 mgL-1). A go...
Autori: Carmen Lazau, Elida Cristina Ilinoiu, Florica Manea, Liliana Andreea Colar, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25854

AbstractCombined electrocoagulation (EC) and homogeneous phase TiO2 photo-assisted system were applied to methyl orange (MO)wastewater treatment. Optimum including current density, initial concentration of MO, TiO2 concentration, pH, solutionconductivity and electrode distance were investigated. 98% decolorization (initial concentration = 500 mg/L) was achieved in 30min with a current density of 125 A/m2, electrode distance of 2.5 cm, electrolyte KCl concentration of 0.5 g/L, initial pH of 6.86,...
Autori: Yi Zhang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26090

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

Abstract The objective of this study was to identify differences between three of the most conventional UV-based advanced oxidation processes, namely photolysis, UV/TiO2, and UV/ZnO for the decolorization and mineralization of reactive red 198 (RR198) model dye in saline media. The study investigated influences of solution pH levels, salt concentration, reaction time and dye concentration on the degradation of RR198. The most effective dye removal and mineralization was observed at pH levels...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26724

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract In this study, the comparative photocatalytic activities of undoped and N-doped TiO2 anatase nanocrystals towards the degradation of Reactive Yellow 125 (RY125) azo reactive dye in aqueous solutions under UV and VIS irradiation ranges were investigated. Both nanocrystals prepared by a fast-hydrothermal method using titanium isopropoxide as precursor were characterized morpho-structurally by X-ray diffraction, SEM/EDX analysis and BET measurements. Also, optical features of the nano...
Autori: Corina Orha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26757

Semi-conductor oxide enhanced photocatalysis is a sustainable technology suitable for disinfection of water contaminated with pathogens. Disinfection of Escherichia coli was investigated using an immobilized thin film tungsten trioxide (WO3) photocatalyst in a visible light-driven photoelectrocatalytic batch cell (PECB). Disinfection efficiency was monitored under dark electrocatalytic, photolytic and photoelectrocatalytic conditions and assessed using a culture-based approach. Optimal disin...
Autori: Efetobor Scott-Emuakpor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27014

Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laborat...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27034

The application of advanced oxidation processes (AOPs) emerged as an interesting topic during the last decade. Many studies have been devoted to the complexity of phenomena imposed by AOPs, and a lot of effort was made to justify the application of AOPs. However, the reliability of AOPs has not been an issue of any extensive work. In this work, failure analysis and comparative reliability study were performed for the chosen AOP system, i.e. a laboratory scale photo- and sonoreactor, during the p...
Autori: Ivana Grčić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27220

The aim of this work was to study the effectiveness of photocatalysis in the removal of contaminants from secondary treated municipal wastewater, on a batch scale. The samples were collected from the outlet of the secondary clarifier in the municipal wastewater plant located at Al Khoudh, Muscat, Sultanate of Oman. The influences of TiO2 catalyst loading and solar radiation exposure time were investigated for the removal of COD and total Coliforms. 60% removal of COD was achieved with a catalyst...
Autori: Anna Jesil Cheriyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27376

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

Decolorization of C.I. Acid Orange 7 (AO7) via TiO2-assisted photocatalysis under UV illumination in the presence of H2O2 has been investigated. The effect of pH on decolorization efficiency of AO7 was investigated in TiO2/UV/H2O2 process. The performance of TiO2/UV/H2O2 system was also evaluated by using synthetic dye-bath effluent of AO7. Solar driven TiO2 photocatalysis was found significantly efficient for the decolorization and degradation of AO7. The rates of decolorization and degrada...
Autori: Ozlem Esen Kartal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27433

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

The mineralization of azo dyes could be realized through solar photocatalytic degradation that is a green method where non-harmful end products are produced. The aim of this study was to investigate the mineralization of Orange G (OG) and New Coccine (NC) using ZnO as catalyst. The degradation of the azo dyes was conducted at different experimental conditions, and parameters such as effect of sunlight to the degradation rate, initial azo dye concentration, amounts of catalyst dosage, pH and effe...
Autori: Wan Fadhilah Khalik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27643

Ultrasounds has a wide range of active applications spreading in solid, liquid and gaseous mediums, embedded in new methods and technologies for preventing, reducing and removing of existing pollution. This paper deals with the sonochemistry reactors and their combinations with photocatalysis and electrochemistry. Various parameters such as ultrasound frequency, power, number of ultrasound sources, lab-scale or large-scale equipment used for environmental applications of sonochemical reactors h...
Autori: Ioan Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27867

A wide range and globally active agro-industries such as olive oil processing, winery, tannery, textile and food production discharge a large volume of wastewater containing tannins. Tannins are complex structured chemicals which cause high organic content, requiring high dissolved oxygen in wastewater treatment plants or producing oxygen depletion in the aquatic environment. Tannins are known to be hardly degraded in biological treatment. There has been evidence that the presence of natural ...
Autori: Giusy Lofrano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27885

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198