Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (AAO) that is later dissolved. The diameter of the nanorods deposited on Cu foil is about 40-150 nanometres, which is in good agreement with the AAO membrane pore size used in the electrolysis process. The nanorods were found to be vertically aligned; their collapsing was observed with the height deposited, at high current densities. These nanostructure electrodes exhibit a high electrocatalytic activity both for oxygen reduction and carbon dioxide electroreduction to formic acid. Faradic efficiency up to 50% was obtained on (Ni-Cu)nano