An aliphatic-amine-bearing chromatographic support, based on commercial silica, was prepared and tested as potential matrix for affinity immobilization of a copper/topaquinone-containing amine oxidase from lentil seedlings. The support proved to be noticeably effective in immobilizing the enzyme with concomitant purification and activity retention. The immobilization yields and some properties of this preparation were also determined and compared with those of the soluble enzyme. High activity r...
Autori: Barbara Noli, Enrico Sanjust, Francesca Sollai, Giovanni Floris
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25108

AbstractThe textile industry is a large water consumer. Stringent regulations of wastewater characteristics require the use of membrane processes for the removal of persistent organic pollutants (POPs) from textile wastewater prior to discharge or recycling of these effluents.This paper presents an overview of research related to the removal of persistent organic pollutants from textile industry by membrane processes, discussing also the correlations with actual pre-treatment and removal rates. ...
Autori: , Corina - Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25127

Contain all the articles from this issueICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Treatment Technologies for Gaseous Fluxes"Surface chemistry studies on molybdena–alumina catalystTatiana Yuzhakova, ?kos R?Šdey, Endre Domokos, J??zsef Kov??cs, Monica Caldararu, Cristian Hornoiu, Mariana Carata, G.Postole, Cornel Munteanu, Larisa Strukova, Jozse FazakasHebicidal behaviour of a new N,N'- biquaternary salt of 4,4'- bipyridineServilia Oancea, Marinela Irimia, Gabriela Carja, Anton Airinei, Nicu...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25189

? Kinetics considerations concerning the oxidative degradation by photo-fenton process of some antibiotics ? Catalytic wet hydrogen peroxide oxidation of 4-chlorophenol over iron-exchanged clays ? Researches on the negative effects assessment (slugging, clogging, ash deposits) developed at the biomass-coal co-firing ? Contribution to the study of the environmental heritage of a former chemical plant ? Impact of chemicals on derivatives with important therapeutic activity in C...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25376

Iinclude urmatoarele articole:â€? Phenol degradation in water through a heterogeneous photo-fenton processâ€? Study concerning the influence of oxidizing agents on heterogeneous photocatalytic degradation of persistent organic pollutantsâ€? Nonmarket valuation of acequias: Stakeholder analysisâ€? Metals concentration in soils adjacent to waste depositsâ€? Polyelectrolyte - surfactant complexesâ€? Modelling of sorption equilibrium of Cr(vi) on isomorphic substituted Mg/Zn-Al - type hydrotalcitesâ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25206

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractThe disinfection of water containing microorganisms by exposure to pulsed-discharge plasma using a low-temperature gas-liquid hybrid discharge (HD) reactor was studied.The HD reactor consists of a plexiglas cylinder containing the liquid of high voltage electrode above liquid' s surface and grounded electrode submerged in the liquid. The HD could produce both arc discharges in gas and liquid phases. The high-energy plasma arc produces a pressure shock wave, which kills the targeted micro...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25242

AbstractThe synthesis of some grafted polysiloxane and azo-polysiloxanes with potential applications as rheology modifiers or surfactants for waterborne paints is reported. Nowadays it became very important to design environmentally friendly systems exhibiting the best end-uses properties. Due to their complex architecture and their sensitivity to UV radiation the studied polymeric systems exhibit very interesting rheological properties. All the polymers containing the azobenzenic groups in the ...
Autori: Constanta Ibanescu, Ioana Moleavin, Iulian Nor, Nicolae Hurduc, Viorel Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25252

AbstractThe aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between othercomponents, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers - blue hyacinthand chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrantspringtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered ...
Autori: , Simona Dobrinas, Viorica Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25294

AbstractWood-based epoxy resin was synthesized from resorcinol-liquefied wood. First, wood components were depolymerized and liquefied by reaction with resorcinol. The resorcinol-liquefied wood with plenty of hydroxyl groups could be considered as a precursor for synthesizing wood-based epoxy resin. Namely, the phenolic-OH groups of the liquefied wood reacted with epichlorohydrine under alkali condition. By the glycidyl etherification, epoxy functionality was introduced to the liquefied wood. Th...
Autori: Akira Fujita, Hajime Kishi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25310

AbstractMilk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarke...
Autori: Alina Soceanu, Gabriela Stanciu, , Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25320

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

AbstractThe adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated. The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed at 30, 40 and 50 ?C. Thermodynamic potentials ?H, ?S, and ?G and isosteric heats of adsorption were calculated from experiment performed at different temperatures (30-50?C...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25393

Abstract The paper presents a risk analysis and assessment of the defence linear systems failure (dykes) in case of accidental flood. Also, breach scenarios and hydrographs computation for the corresponding accidental high waters are provided. The impact assessment is highlighted through a global matrix model for costs quantification. It is also presented the flooding computation model for different versions of the linear defence systems and in a correspondent way the Inundation Accidental D...
Autori: Codruta Badaluta-Minda, Gheorghe Creţu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25433

Abstract The waste recycling done in order to obtain composite products with performant properties and also, with long life cycle is the main purpose for the sustainable development. The present paper describes the way in which, different kind of solid wastes are immobilised in an organic resin as a binder matrix. Composites with different proportion of waste as, rubber/plastic, glass and silica sand have been obtained. The physical-mechanical properties and chemical stability of such organic...
Autori: Ioan Ropota, Emilia Zamfirache, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25450

Abstract In the new millennium to sustain a healthy life in harmony with nature, it will be extremely important to develop various materials and processes that minimize any harmful influence on the environment. The feasibility of sludge recycling in the brick manufacture was evaluated through laboratory testing. Several ceramic masses with clay, sand and various proportion of sludge have been synthesized and than characterized by their physical-mechanical properties. Sludge fineness also has ...
Autori: Ana - Maria Szoke, Marcela Muntean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25454

Abstract The paper presents a comparative approach concerning the properties of TiO2 thin layers obtained via spray pyrolysis deposition (SPD) using hydrophilic and hydrophobic polymers as additives. The influences of composition (X-ray diffraction), morphology (Atomic Force Mycroscopy, Contact angle) and optoelectric (electrical conductivity, absorption, band gap and photocurrent) properties on the photocatalytic activity of the layers were studied. ...
Autori: Alexandru Enesca, Luminita Andronic, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25479

Abstract Molecular imprinting is a versatile and ecological method for obtaining polymeric materials with a lot of applications in the field of pharmacy, medicine and biosensor assays. In this work, a new method of alternative molecular imprinting to design imprinted poly (vinyl alcohol) films has been proposed. Glycyrrhizinic acid has been used as template molecule. To demonstrate the obtaining of the molecular imprinted poly (vinyl alcohol) and its selectivity, studies of glycyrrhizinic and...
Autori: , Catalin Croitoru, Georgeta Moise
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25495

Abstract The purpose of this work is to investigate the secondary Al slag (SAS) relating to its technical and environmental properties and, as consequence, to its compatibility with Portland cement matrix. This study may be a contribution to establish of SAS potential valorization as secondary raw material (SRM) in low strength cement matrix composites, as construction products. DRX mineralogical analyses revealed that SAS includes transition alumina compounds, especial boehmite. The hydrati...
Autori: Maria Gheorghe, Nastasia Panait, Romanita Teodorescu, Maria Roman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25498

Abstract Preliminary investigation of contaminated soil in the surrounding area of a petroleum tank has been carried out based on fluorescence techniques: excitation emission matrix (EEM) and synchronous fluorescence scan (SFS). A fluorescence fingerprints library containing several EEM and SFS maps for various dilutions of Romanian crude oil in methanol, was used to confirm the identity of the soil contaminant. A calibration curve was created to estimate the contamination level of soil sampl...
Autori: Dan Savastru, Elfrida M. Carstea, Gabriela Pavelescu, Luminita Cristescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25505

Abstract The work studies the orientations regarding the recycling of the products from the industry of auto-vehicles parts and components, orientations that can provide solutions which permit to the enterprises producing auto components the efficient management of the related products and services during the whole life cycle of the products, from the conception phase to that of recycling. The new way of approaching the development of metallic auto products promoted in Romania will contribut...
Autori: Petrica Corabieru, Stefan Velicu, Dumitru Zait, Anisoara Corabieru, Dan Dragos Vasilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25524

Abstract Sorption is one of the several methods that have been successfully utilized for dyes removal. A large number of materials have been used as suitable sorbents for decolourization of industrial effluents: activated carbon (the most common but expensive adsorbent), polymeric resins, various low-cost adsorbents (agricultural and industrial by-products, peat, chitin, silica, bentonite, other clays, fly ash). Our paper is a review about our researches regarding different types of industri...
Autori: Daniela Suteu, Carmen Zaharia, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25532

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract In this work, the behavior of n-hexane vapors in the adsorption-desorption cycles of non-functionalized polymeric adsorbents (MN 202 and MN 250) and granular activated carbon (AC 20) was studied. The adsorption experiments were performed in a fixed bed column, under dynamic conditions, at 30?C and atmospheric pressure. The inlet concentration of n-hexane in the air streams was 0.115 mg/cm3 (32500 ppm) and the space velocity was 2.75 s-1. Also, desorption experiments were performed in...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25584

Abstract Mathematical modeling of the ultrafiltration (UF) process is motivated by the complexity of retention phenomena that occur during the UF in conjunction with the complexity of wastewater matrices submitted to ultrafiltration, as well as by the need to predict the process behavior in extreme conditions, such as high pollution loads for UF-membrane cleaning cycles optimization or for automated control of the process. Thus, series of laboratory-scale ultrafiltration experiments were perf...
Autori: , George Barjoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25630

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

A submerged membrane bioreactor (MBR) was employed to treat wastewater containing different content of seawater in this work. During the process, the operating conditions were as follows: COD was 800-1000 mg/L, ammonium-N was 80-100 mg/L, pH was 7.5-8.5, mixed liquor suspended solids (MLSS) was around 7000 mg/L, dissolved oxygen (DO) was 2-4 mg/L. The results showed that the ammonium-N removal was better than COD removal. Sludge settling property was good in saline wastewater treatment, and the ...
Autori: Jin Li, Deshuang Yu, Dan Wanghttp://www.ecozone.ro/reviste.php?RID=25697

Abstract:In this paper, the influence of two types of imidazolium-based ionic liquids (ILs) on the properties of sycamore maple (Acer pseudoplatanus) veneers, at 25 0C, 60 0C and 80 0C has been studied by using contact angle measurements and Fourier transform infrared spectroscopy analysis. The measurements showed that wood wettabillity is increased by IL treatment. It has been determined that the ILs decrease the crystallinity and improve the flexibility of the cellulose matrix. Also, it has be...
Autori: Attila Porzsolt, Catalin Croitoru, Christian Friedrich, Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25737

Abstract:This technical paper presents some aspects concerning the static finite element analysis of a wind turbine blade. For themanufacturing of the blades for a 10 kW wind turbine elaborated at the Technical University of Moldova composite materialsmade up of polyester matrix reinforced with fiber glass are being used. In order to determine the mechanical properties of theproposed composite materials 10 different samples of laminated composite plates were numerically simulated in ANSYS 11....
Autori: Marin Guţu, Viorel Bostan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25747

Abstract:Hybrid nanocomposites may synergistically combine and enhance the properties of inorganic nanoparticles and organicmolecules.The objective of this paper is to examine particular nanocomposites films based on binary copolymers and inorganic TiO2nanoparticles from the structure and properties point of view. These nanoparticles were dispersed in maleic anhydride-styrene(MAS) copolymer by using elaidic acid, trans isomer of the oleic acid, as coupling agent in order to increase the compatib...
Autori: Alina Matei, Dana Perniu, Ileana Cernica, Irina Popescu, Lucia Dumitrescu, Vasilica Schiopu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25755

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

Abstract:The hereby article presents a part of the results of the research made by the author during his PhD degree preparation with respect to asbestos and plastics wastes recycling in the form of composite with polymeric matrix, respectively the toxicological tests performed on the new product. In this respect, three categories of tests were made based on complex and modern analysis methodologies, with high results accuracy: spectral analysis of the wear wastes, morphological analysis of the w...
Autori: Cristina Corpodean, Silvian Ionescu, Valeriu Deac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25812

Environment and sustainability are key issues for the policy maker. A policy should be first designed and realistically inserted in its proper context (regional, national, European) in order to be correctly assessed. After that, suitable models need to be chosen consistently with the policy context and with the evaluation purpose, to make easier the policy maker task. The aim of this paper is twofold. Firstly, to propose a Statistical Information System (SIS) approach in order to correctly write...
Autori: Giorgio Garau, Giovanni Mandras, Lucia Schirru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25827

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The present study describes the preparation of a filtering medium from a polymeric cellulosic support (filter paper) by functionalization with monochlorotriazinyl-β-cyclodextrin. The permanent immobilization of cyclodextrins confers the new material special properties and the potential for a better decontamination of liquid and gaseous effluents. The structure, physicomechanical and filtration properties of the filter paper, successfully functionalized with MCT-β-CD, have been emphasiz...
Autori: Ana-Maria Grigoriu, Constantin Luca, Florin Ciolacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25862

This research investigates the influence of certain vitamins (A and D2) on the possibility of hydroxyapatite formation on polymer surfaces. A coating method based on biomimetic techniques was used to form a crystalline hydroxyapatite thin layer on porous polyurethane matrix. The method is based on a wet process of hydroxyapatite formation that involves porous polyurethane film soaking in a modified synthetic Simulated Body Fluid (SBF) solution. This modified SBF solution contains vitamin A and v...
Autori: Alina Costina Luca, Constantin Luca, Gabriela Ciobanu, Simona Ilisei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25884

Quantification of the floristic matrix is important both for animal’s nutrition and for the biodiversity monitoring of plants species under the influences of substance flow. Our researches have the main aim to study the possibilities offered by Infrared Spectroscopy in rapid, unpolluted and non-destructive analysis of floristic matrix modification from perennial grassland fertilized with organic and/or mineral fertilizers. It was performed three different FTIR models: for Poaceae (R2=0.949; RM...
Autori: Iosif Gergen, Moisuc Alexandru, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25892

An alternative preparation method for PAC (pre-hydrolyzed aluminium chloride with general formula Alm(OH)nCl3n-m) by electrochemical synthesis is presented in this paper. The electrochemically obtained PAC (E-PAC), in which the most effective species of the polymeric Al component were estimated by 27Al RMN method, with properties similar to the properties of a commercially available PAC solution, was successfully generated in a electrochemical reactor. For obtaining as much as Al13 polymer by el...
Autori: Adina Pacala, Ciprian Radovan, Ilie Vlaicu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25901

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractEfficient large-scale recycling of polymeric wastes for automotives is of increased interest from ecologic and economic point ofview and represents an important goal for the car recycling industry. One alternative is to develop novel composite materials,relying on waste car parts, for indoor or outdoor large-scale applications, without using small molecular plasticizer or otheradditives but insuring a good compatibility for large percentages of thermoset plastics in the composite. Previo...
Autori: Anca Duta, Cristina Cazan, Dana Perniu, Mihaela Cosnita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25982

AbstractThe present study was focused to classify various advanced oxidation processes (AOPs) to degrade sixteen commonpharmaceuticals and personal care products (PPCPs). The classification was based on the degradation rate constant (h-1).Chemometric techniques like principal component analysis (PCA) and cluster analysis (CA) were used to classify AOPs whichcan efficiently degrade a certain class of PPCPs. The bipolt based on first two principal components (PCs) of PCA modelidentified two distin...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26085

Abstract Large amount of radioactive sources generate gamma rays of various energies and intensities. Gamma-ray spectroscopy is applied for the quantitative study of the energy spectra of gamma-ray sources. In the present paper, a statistical analysis of the energy spectra of gamma-ray spectroscopy monitored during 4 years at the “Dosimetry and Radioprotection” Laboratory from ”Vasile Alecsandri” University of Bacău is provided. Several new mathematical parameters were calcula...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26144

AbstractPresent study deals with a technology that reduces the cadmium(Cd) availability to the leafy vegetable Amaranthus caudatusfrom Cd contaminated soil (6 μg Cd g-1soil), amended with farmyard manure FYM, FYM+NPK and agricultural wastes (ricehusk; RH and saw dust; SD) at different doses (0.5 %, 2 %, 5 % and 10 %). Among all the doses 5 % was found to the best foreach amendment showing maximum reduction in phytoavailability of Cd hence better vegetable yield. At this dose the reductionin...
Autori: Anita Singh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26228

AbstractIndigenous isolated bacterium Aeromonas sp. was immobilized in calcium alginate and the related immobilization parameterslike bead diameter, inoculum size and the initial phenol concentration required for biodegradation were determined. Thebiodegradation activity was most efficient with 4 mm calcium alginate beads. The optimal immobilized biomass required wasabout 28 109 cells/mL. Compared with free-cell suspensions, the alginate matrix used for immobilization of cells provided betterenv...
Autori: Abdelkader Namane
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26249

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractThe purpose of the undertaken research work is to degrade the biopolymeric pigments present in the distillery spentwash. This isdone by direct electro-oxidation using iridium oxide coated titanium mesh as catalytic anode. The effects of current intensity,dilution, pH and time of electro-oxidation were studied. The combined effects were analyzed using Box-Behnken design foroptimization and statistical analysis. The rate constant for first order electrochemical kinetics relating the rate c...
Autori: R. Krishna Prasad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26253

AbstractThe applications of biofilm treatment technologies for domestic wastewater are being increased in many parts of the world. Theaim of the study is to assess a compacted aerobic attached growth fix-film unit (termed Bio-cache) for treatment of small volumedomestic wastewater. The system consists of the miniature plastic packing matrix, which provides a large surface area of 300m2/m3, so as to maintain the high rate growth of viable organisms responsible for organic degradation. The study o...
Autori: Alireza Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26266

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractCosmetics, toiletry and household cleaning products are often based on different types of polymeric gels with specific rheologicalbehavior. Dynamic shear oscillation measurements were used for the monitoring of in situ polymerization process, and todetermine the viscoelastic properties of the hydrogels based on polyacrylamide and acetone-formaldehyde resin. Both storagemodulus G’ and loss modulus G” were measured in real time during the gelation process carried out directly between the p...
Autori: Andrei Rosu, Camelia Mihăilescu, Constanţa Ibănescu, Gabriela Halitchi, Maria Lungu, Maricel Danu, Simona Bistriceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26326

AbstractA deep understanding of the relationship between the solids deposition and head losses is vital to optimize the backwashing inbiological aerated filters (BAFs). In this article, the deposition solids were classified into four types: heterotrophic biomass,autotrophic biomass, inert biomass and extracellular polymeric substances (EPS). A concept model was developed to simulatethe solid deposition and the head loss development. The temporal and spatial distributions of the four types of sol...
Autori: Chengda He, Dongsu Bi, Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26347

AbstractThis study was conducted to generate a hierarchical modelling based on ecological land classification in the Yukarıgokdere forestdistrict of the Mediterranean region, Turkey. Two ways indicator species analysis was applied to obtain response variables fromthe relevant vegetation matrix at each level. Response variables were modelled by using classification tree technique at eachlevel. Validation tests (i.e. multi-response permutation procedures for determination of differences of pl...
Autori: Kürşad Özkan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26352

AbstractThe paper represents the application of a multicriterial analysis for establishing the decisional priorities in the field of impactsgenerated by polluting emissions from large burning installations. The analytic hierarchy process (AHP) method was used inorder to express quantitatively how the environmental protection and sustainable development objectives are met. Based onexperimental determinations carried out on site at Mintia Power Station, Romania and the brainstorming sessions held ...
Autori: Dan Codruț Petrilean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26398

AbstractWater samples from two types of sources: partially treated sewage generated by a medium-sized city, with a high quantity oftotal coliforms and partially treated industrial wastewater, which contained mostly petroleum products from refineries, weretreated using the same concentration of TiO2 catalyst, for different exposure periods. UV-Vis and fluorescence spectroscopicevaluation of the composition changes of wastewaters under non selective oxidation conditions (achieved by photocatalysis...
Autori: Gabriela Pavelescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26474

AbstractAnaerobic degradation (AD) of municipal solid waste (MSW) depends on the moisture and nutrient distribution within thebioreactor; these factors are affected by leachate recirculation. In this work, the effects of leachate recirculation of 15 to 120 byvolume percentage (%V) on AD were studied. The ojectives of this study are as follows: a) to determine which recirculation rateprovides the best conditions for accelerated anaerobic degradation (AD) and b) to determine the optimal range of r...
Autori: Maria del Consuelo Hernández-Berriel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26557

Abstract The environmental impact assessment (EIA) is a compulsory evaluation instrument for environmental management and decision making processes and applies to different phases of activities (plans, programmes, projects and /or existing production or services), because it measures the natural and anthropogenic activities effects upon the environment. These impacts may affect the cultural richness, biodiversity, social-economic conditions and human health as well as the ecosystem equilibri...
Autori: Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26645

Abstract The main purpose of this research was to study the biodegradation ability of atrazine by using Arthrobacter sp. as free and immobilized cells of the strain DNS10, under several important environmental factors such as temperature, pH, salinity, substrate concentration. Furthermore, this paper objective was also to assess the process considering the immobilization under extreme conditions, such as high salinity and high atrazine concentration. DNS10 was immobilized on a sodium alginat...
Autori: Zhang Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26702

Abstract Impact damage is considered the primary cause of in-service delamination in composite materials and promotes significant reduction in residual strength. Non-destructive techniques (NDT) include several methods able to detect the shape and the size of the interior damages without destruction of the structure or component, which is economically advantageous. The aim of this paper is to evaluate the properties after low velocity impacts using an experimental-numerical procedure based o...
Autori: Ana Martins Amaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26726

Abstract Resilience is meant in this paper as the capability of a networked infrastructure to provide its service even if some components are failed: it depends both on net-wide measures of connectivity and the role of a single component. This paper has two objectives: first to show how a set of global measures can be obtained using techniques from network theory, in particular how the spectral analysis of the adjacency and Laplacian matrices allows us to obtain a characterization of global ...
Autori: Antonio Candelieri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26746

Abstract In order to remove various radionuclides (Tl+, Sr2+and La3+) from wastewaters we used three solid supports of (styrenedivinylbenzene) grafted with different pendant groups (1-triphenylphosphonium; 2-izo-propylphosphonate; 3- aminoethylaminomethyl). The solid supports with different pendant groups were impregnated with ionic liquid (Cyphos IL-101- trihexyltetradecylphosphonium chloride). IR-spectra, EDX-ray and SEM image were used to characterize the adsorbent obtained after the imp...
Autori: Mihaela Ciopec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26749

Abstract The aim of this paper is to determine the heat of combustion of plastic wastes resulted from municipal solid waste, automotive shredder facility waste and building and construction waste. The plastic wastes have been separated by flotation technique using as flotation media: water, ethanol, their mixtures and magnetic fluid. Resulted fractions have been analyzed aiming to determine the most effective fraction from the heat of combustion point of view. The obtained results have been ...
Autori: Liviu Costiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26750

Abstract Extensive use of plastics leads to the increase of non biodegradable wastes that have to be recycled due to both dramatically decrease of natural resources to producing them and to their increasing need as well as due to environmental issues. Most of goods made by materials based on wastes have to be commonly used by people. Antibacterial character of those is necessary to avoid epidemics. This paper deals with determination of antimicrobial character of materials based on polymeric...
Autori: Florica Silvia Cristina Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26751

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract The European Commission has introduced a whole range of policies and initiatives to promote the product eco-innovation and the environmental impacts reductions. One of the key topic for the reduction of the environmental impacts is the waste recycling and reuse (turning waste into useful resources). A teamwork of Politecnico di Milano has developed a research work, still ongoing and continuously updated, called “The usefulness of the useless. Cross-sectorial evaluation of wast...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26788

Abstract In the present study, several selected formulations based on recycled (rPP) or virgin polyolefins (vPP) and lignocelluloses were prepared and subjected to microorganism attack. Biodegradation tests were performed with microbial strains belonging to fungal genera, like Aspergillus, Penicillium and Fusarium. The initiation of biodegradation was demonstrated by Scanning Electron Microscope (SEM) micrographs showing the colonization of surface samples by microbial strains. The crystalli...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26879

Abstract In the European Union, the hazardous waste recycling has become a priority, as response at legal prohibition for landfilling of untreated WEEE. The economic and eco-efficient recycling methods acquire more and more interest from the industry. The Cathode Ray Tubes (CRT) glass derived from Waste of Electric and Electronic Equipment (WEEE) dismantle is known as hazardous waste, because of their heavy metals content, especially lead. For this type of waste, the authors have proposed in...
Autori: Antoanela Popovici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26890

Abstract Poly(vinyl chloride) (PVC) is the most widely used material for the production of medical devices such as intravenous fluid bags and tubing, enteral feeding, dialysis equipment and catheters. Despite of their numerous advantages, the plastic medical devices are non biodegradable and prone to microbial colonization causing biofilm associated infections which are difficult to treat and tend to chronicisation. A possible solution to surpass these limitations could be the fabrication of...
Autori: Petruța Stoica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26894

Abstract The possibility to use release controlled fertilizers in the agriculture of the tropical countries is more important than in the agriculture of the countries of the cold regions. In this context, the purpose of this work is the characterization of an encapsulated commercial Fertilizer of Controlled Release named FERLENT®, which was covered with a polymeric material, obtained in situ, under controlled conditions, which allowed to corroborate the fairly well adjustment of the synt...
Autori: Mayra González Hurtado
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26916

Ferric sulfate and aluminum sulfate were applied to stabilize the available arsenic in solid waste residue (SWR) from the organic arsenic industry, previously pretreated by the semi-solid Fenton process. NaOH, Ca(OH)2, and MgO were introduced to adjust the matrix pH. Toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), and sequential extraction procedure (SEP) were carried out to evaluate the effect and difference on the fixation treatments of ...
Autori: Li-Fang Hu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26956

Our study aims to analyse soil quality based on the concentrations of potentially toxic elements (PTEs) in natural or slightly modified anthropogenic soils, technosols and landfill deposits in Iasi. The pollution level analysis based on lognormal distribution plot allows the differentiation of elements coming from the parent material (Mo, Cd, Ni and As) of those with anthropogenic origin (Pb, Zn and Cu). The enrichment factor (EF) calculated based on manganese (Mn) as reference in the parent ...
Autori: Cristian Vasilica Secu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26991

Treatment of domestic wastewater using constructed wetland system vegetated with Phragmites australis was studied at lab scale. Response surface methodology (RSM) a mathematical model was employed for analyzing the effect of independent factors (inlet flow rate, outlet flow rate, retention time) on wastewater parameters e.g. electrical conductivity, BOD5, COD, nitrates, phosphates, total solids, suspended solids, heavy metals in order to maximally treat wastewater. All independent variables w...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26999

Within the framework of the Water Safety Plan (WSP), it is necessary to assess and to manage risks in the catchment area, considered the first protection barrier of water supply systems. The Cauca River is one of the major water resources of Colombia and the principal source of drinking water supply for the city of Cali (approx. 2,300,000 people). Taking into account, usually in developing countries, available information and specialized technical resources are limited, in this study were eva...
Autori: Andrea Pérez-Vidal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27010

Various azodyes containing one or more sulfonic groups were removed from aqueous solutions by biosorption on untreated wood shavings from Picea abies. The sorption kinetics was described by the pseudo-first-order (PFO), pseudo-second-order (PSO) and modified pseudo-n-order (MPnO) equations, from which the MPnO model provided the best fit to the experimental data. The surface reaction was identified as a rate-limiting step governing the dye sorption on wood shavings, but a mixed kinetics (with a ...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27207

The pharmaceutical compounds are emerging pollutants for which the international scientific community has paid special attention in recent years, because these substances can have adverse effects on living organisms in the aquatic environment. In this paper we developed a chromatographic method for the quantification of trace class of analgesic and anti-inflammatory drugs in river water. The present method is a simple and economical way to perform a preliminary screening of eight widely used pha...
Autori: Vasile Ion Iancu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27227

Ammonium is an environmental contaminant encountered in water and soils, its admissible concentrations in soils and waters being established by legislation. Removal of ammonium ions from aqueous solutions from different matrix can be done with several sorbents, among which nano-adsorbents, such as oxidized exfoliated graphite nanoplatelets (ox-xGnP) offer practical solutions, based on their high specific surface area, associated sorption sites and efficiency of application. Several parameters su...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27273

This study presents the results obtained in tailoring thin films of alumina, deposited onto aluminium substrates by spray pyrolysis, at 250°C, using AlCl3 solutions (0.15M) in a water:ethanol (1:1) solvent mixture. As morphology controlling agents, acetylacetone and maleic acid based copolymers are added in the precursors’ solutions. The precursors’ systems are analyzed by FTIR spectroscopy and the surface morphology of alumina thin films is investigated by atomic force microscop...
Autori: Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27291

The composition and the structure of the soil matrix have an important role in determining the water and the air regime into the soil. In the soil pore the area occupied by water and air, capillary and adsorption phenomena occur, together defining the suction of the matrix. The suction-humidity relationship varies from one soil to another, but also to the same soil in time. This paper sets out the results of investigations aimed at highlighting the influence of the composition and structure of...
Autori: Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27332

The Strategy of Waste Management, Horizon 2014-2020, states 8 major objectives with the role of establishing new priorities for Waste Management. Thus, one of the proposed measures for the next 5 years is encouraging the wastes exploitation for energy recovery. In this context, the main goal of our study was to evaluate the level of pollution considering 5 closed municipal waste dump sites from the North-East region of Romania over the period 2013-2015, having in mind at a first glance, the poss...
Autori: Brînduşa Mihaela Slușer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27347

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

The objectives of this study were to investigate the composition of activated sludge biofilms and flocs in a sequential batch reactor (SBR) and in a sequential biofilm batch reactor (SBBR), and to evaluate the role of the extracellular polymeric substances produced in the reactors in comparison with the respective treatment efficiency of domestic wastewater, containing 1 to 40 mg/L phenol. Both reactors showed variable removal efficiencies. The SBR was found to contain more protistan species ...
Autori: Chrysi A. Papadimitriou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27422

Municipal Solid Waste (MSW) disposal is currently one of the major environmental issues in big cities. Several tools and techniques have been developed for Environmental Impact Assessment (EIA) of MSW disposal options, including scoping, checklists, matrices, qualitative and quantitative models and decision-support systems. Rapid Impact Assessment Matrix (RIAM) is a partially new method which is particularly advantageous over others as it provides a transparent and permanent record of analysi...
Autori: Zohreh Aliakbari-Beidokhti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27465

To assess energy conservation and emission reduction effect on traffic and transportation at macro level more scientifically, the evaluation system based on the improved osculating value method for transportation is established. Information entropy weight is introduced to the traditional osculating value method and the numerical matrix normalization process in the osculating value method is simplified. The pollutant emission and the energy consumption is defined as negative index, and the capaci...
Autori: Yang Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27470

Nowadays, the polyolefins (polyethylene, polypropylene) are increasingly consumed in large amounts for many applications. This issue causes a concern regarding the environmental impact of the waste materials generated after the first use. Mechanical recycling of polyolefin wastes helps to conserve oil and gas resources and reduce the polymeric waste accumulation in environment. In this paper, the modification of some post-consumer polypropylene (rPP) properties coming from packaging processi...
Autori: Maria Râpă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27493

This study focuses on some mechanical properties resulted from the tensile testing of a set of green composites with a Dammar-based matrix and reinforcement material of silk, flax, cotton and hemp fabrics. To be precise, we have ascertained the characteristic curve, the resistance to and the elongation at fraction, as well as the modulus of elasticity for each set of samples from these composites and for a set of bioresin samples. With the help of an Electronic Scanning Microscope we captured im...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27516

This paper describes an eco-efficiency decision support model for of end-of-life solid waste recycling. A holistic approach in balancing environmental pollution concern and waste recycling is required. A system dynamic model is based on mathematical model of the supply chain, and decision-making analysis is supported with the online spreadsheets. A criterion function-based modelling is used as a core model for simulation that uses net present value-based metrics of the supply chain activities. T...
Autori: Stanislav Avsec
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27591

This paper presents the research on the temporal variability of water quality parameters for the most important river system in Romania and Europe – Danube River. The data on the river water quality had been obtained during ten years. The investigation was systematic and complex. Using the Kolmogorov-Smirnov test, and traditional statistical methods based on correlation matrix - Principal Component Analysis (PCA) and Factor Analysis (FA), and ANOVA all the samples data sets were classified...
Autori: Paula Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27601

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

The enzyme-based biosensor stability and its analytical performance depend on both the immobilization process and the matrix used for immobilization of the enzyme into a stable layer. In this paper, the development and evaluation of an optimal enzymatic layer for stable encapsulation of the acetylcholinesterase enzyme (AChE) through the sol-gel method onto mediated carbon-ink screen-printed electrodes was performed, obtaining electrochemical enzyme-based biosensors. The enzyme was immobilized on...
Autori: Melinda David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27636

The paper describes the main results from a study of cement bound mixtures for road foundations with the aggregate matrix consisting of industrial wastes, i.e. foundry sands (FS), electric arc furnace (EAF) steel slags and bottom ash from municipal solid waste incineration (MSWI), combined in five different proportions. The laboratory investigation involved a preliminary analysis of the chemical, leaching, physical and mechanical properties of the industrial wastes, followed by a mechanical char...
Autori: Marco Pasetoo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27645

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

Water sea pollution is influenced mainly by anthropogenic causes due to industrial and municipal activities which affect the quality of sea water, sediments and the whole ecosystem. In this paper, the correlation between contamination sources and the environmental quality of marine sediments was analyzed through multivariate analysis, in particular Principal Components Analysis (PCA), Cluster Analysis (CA) and Correlation Analysis. Considering the case study of Mar Piccolo in Taranto (Ionian Sea...
Autori: Claudia Labianca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27793

The research has been focused on concretes in which the continuous phase is some kind of polymeric resin and the discrete phase is some type of mineral aggregate. Such composite materials are known as Polymer concretes (PC) and boast several advantages such as lower weights, higher resistance to corrosive environments and chemical attacks, faster curing and lower permeabilities. In PC the inorganic fraction can reach up to 90% of the total and is made up of aggregates such as sand and gravel. Th...
Autori: Paolo Pozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27799

In this paper, we determined some mechanical properties of a new category of green composites, based on tensile tests. More precisely, we selected a set of samples from a new bio-resin based on Dammar and two sets of samples from green-composites with matrix by bio-resin and reinforced with almost compact layers of Typha latifolia or Schoenoplectus lacustris. For these built materials, we obtained the characteristic curve, tensile strength, percentage elongation after fracture and elasticity mod...
Autori: Ion Ciucă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27980

Nanoparticles (NPs) have recently been concerned as emerging contaminants. Determination of NPs in different environmental compartments is a revealing topic for researchers studying their impacts in nature. Various methods of analysis have been reported in literature for their measurement and recovery. However, there are difficulties in their quatification in landfill leachate. Taking into account varying landfill components and their possible interactions with NPs, different types of NPs wer...
Autori: Ceyda Senem Uyguner-Demirel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27989

The paper reports on the preparation of polysiloxane hydrophobized viscose-maghemite/goethite magnetic composite with properties appropriate for uses in oil spill sorption from polluted aqueous media. A multi-step procedure was employed to obtain the polymeric composite. The structures of the prepared samples and precursors were analyzed by Fourier transform infrared spectroscopy (FTIR), whereas their morphology was investigated by means of scanning electron microscopy (SEM). The hydrophobic...
Autori: Răzvan Rotaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28008

Environmental impact assessment (EIA) for waste disposal options to examine their impacts is of great importance. Rapid impact assessment matrix (RIAM) was used in this research to evaluate impacts of the four different MSW disposal scenarios in Abyaneh village which is one of the oldest villages in Iran, attracting numerous domestic and international tourists year-round. These scenarios, respectively, were open dumping (S1), sanitary landfilling (S2), composting, followed by sanitary landfil...
Autori: Ali Daryabeigi Zand
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28057

The combustion behavior of several polymers was studied with a cone calorimeter, while the samples were based on a recycled acrylonitrile-butadiene styrene (ABS) and as additives were considered: organic montmorillonite (OMT) and a mixture of two fire retardants (FR). The samples structure and thermal properties are characterized by means of Scanning electron microscopy (SEM), X-ray Powder Diffraction(XRD) and Energy-dispersive X-ray spectroscopy (EDX) and cone calorimeter. The main objective o...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28098

China’s tremendous economic developments are achieved at the expense of environmental deterioration. In recent years, PM2.5 pollution has become increasingly serious in China, attracting widespread attention from the citizens and the government. This study aims to investigate the temporal–spatial characteristics of PM2.5 in China in 1998–2012, fully considering the potential influencing factors of PM2.5. The satellite remote sensing data compensate for the deficiency of surface...
Autori: Wenyang Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28115

Wine aroma plays an essential role and can be considered one of the most important attributes of the overall wine quality. Generally, aroma is a remarkable complex chemical matrix comprising compounds from various chemical classes (alcohols, esters, acids, aldehydes, lactones, phenols, terpenes, ketones, norisoprenoids, etc.). Although some studies tackle wine aroma in general, the chemical changes attributed to wine aroma during the ageing process are still poorly understood. In this study, th...
Autori: Georgiana-Diana Dumitriu Gabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28151

The goal of this paper is to contribute to environmental improvement. This goal has been achieved by the development of an algorithm that allows the optimization of fuel consumption and transport of combustion products. The paper considers the outlier – robust recursive algorithm. This algorithm is used for identification of multivariable ARMAX (Autoregressive Moving Average with Exogenous Variables) models. In this paper, we introduce pseudo-Huber loss function which is a continuous nonli...
Autori: Vojislav Filipovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28167

The study attempted to identify the best suited models to determine the kinetics of chlorine decay and trihalomethanes (THMs) formation in drinking water supplies. Batch experiments were conducted on synthetic water samples to simulate the characteristics of raw water collected from Maithon water treatment plant (MWTP), Dhanbad, Jharkhand, India. Influence of various parameters like total organic carbon (TOC), reaction time, pH and chlorine dose on the rate of THMs formation were analysed. The s...
Autori: Minashree Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28171

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

The treatment of acidic wastewater of copper sulfide produces a huge amount of sediment, which can be processed into the planting matrix for ecological restoration of mines. This paper attempts to screen out the plants suitable for the acidic wastewater sediment, laying the basis for ecological restoration of mines. Therefore, 14 plant species were selected for preliminary tests on survival rate and growth tests in sediment pond. The survival rates and growth conditions of each plant species in...
Autori: Jinchun Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28268