Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Green technology foresight of high technology: Hype of potentials - The challenges from nanotechnology, Biotechnology and ICTMichael S?¸gaard J?¸rgensenIntrinsic properties of noble metals in catalytic selective reduction of NO by propene in lean burn conditionsAnne Giroir-Fendler, Helleh Saadallah, Adela HaletaICEEM/02 - ENVIRONMENTAL ENGINEERING ...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25178

Include urmatoarele articole:� Cost sensitivity analysis by Monte Carlo simulation� Mathematical modeling of gas drying by adsorption� Methyl isobutyl ketone combustion over Pt/Al2O3 catalyst� Distribution of oxygen transfer rate in stirred bioreactors with simulated broths� Unsteady heat transfer inside an elliptic cylinder� Triphasic external-loop airlift reactors. Hydrodynamic and dispersion studies� Sustainable combined utilization of renewable forest resources and coal in Roma...
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ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25209

AbstractMesoporous Ti-SBA-15 materials have been synthesized up to a Si/Ti ratio of 20 using a two-step pH adjusting method. Low angle X-ray diffraction and diffuse reflectance UV-Vis spectroscopy revealed that the optimal pH value to synthesize highly ordered mesoporous solids having Ti atoms primarily in tetrahedral coordination environments is around 7.5. The nitrogen physisorption and TEM indicated also ordered mesostructures having relatively large surface areas and uniform mesopore size di...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Cezar Catrinescu, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25263

AbstractZeolites Cs+, Na+-chabazite with SiO2 /Al2O3 ratio of 7 were prepared from gels with molar composition (2.41-2.73)(Cs+ + Na+)2O : (0.02 TPAOH) : Al2O3 : 7.21 SiO2 : (194-204) H2O in static hydrothermal conditions at 108 – 132 0C for 8-21 days. The solids were characterized by X - ray diffraction, scanning electron microscopy, thermal analysis and nitrogen sorption measurements. The nitrogen sorption isotherms at -1960C present a hysteresis loop which is indicative for the existence of ...
Autori: Ionela Droahna, Iuliean Asaftei, Nicolae Bilba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25266

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract Mesoporosity of about 7 nm in ETS-10 titanosilicate was generated by postsynthesis treatment with hydrogen peroxide under microwave irradiation, resulting in an increased external surface area of the materials (55 m2/g). The influence of titanosilicate porosity and its surface modification by phosphorus atoms (ET(P)S-10) on the retention of some nanoions (??-emitting radioactive U(VI) and Th(IV) ions) and biomolecules (the proteins cytochrome c, papain, and ??-globulin) was investiga...
Autori: Robert Gradinaru, Sorin O. Valu, Stefan Postolache, Claudiu C. Pavel, Ion Sandu, Karin Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25455

Abstract Knowledge of the binding mechanisms of heavy metals to cement minerals is essential for the prediction of the long-term leachability of cement-based solidified waste containing heavy metals. In this paper, the sorption of chromate ions onto calciumsilicate- hydrate (C-S-H) in equilibrated aqueous suspensions was investigated as a function of liquid-to-solid ratio. The hypothesis of super-equivalent adsorption was assumed to be involved in chromate ions immobilization. This hypothesis...
Autori: Constantin Bobirica, Ionel Constantinescu, Liliana Bobirica,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25478

Abstract Chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. Surfactant-modified natural zeolites (SMZs) represent an important class of sorbents for water treatment. This work presents a comparat...
Autori: Roxana Elena Apreutesei, Cezar Catrinescu, Adrian Ungureanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25537

Abstract Geopolymerization is a continuous developing field of research for utilizing solid waste and by-products. It provides a solution to many problems where hazardous residue has to be treated and stored under critical environmental conditions. Consumption of fly ash in the manufacture of geopolymer is an important strategy in making materials more environmentally friendly. Fly ash has been chosen as a base material in order to utilize this industrial waste. Previous researches have show...
Autori: Maria Harja, Marinela Bărbuţă, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25542

Abstract In this work the experimental conditions to synthesize, by direct hydrothermal synthesis, self-bonded pellets of ETS-10 phase containing iron were studied. The following gel composition was used: xNa2O-0.6KF-1.28xHCl-yFe2O3-0.2TiO2-1.49SiO2-39.5H2O with 0.8Â???xÂ???1.4 and 0.015Â???yÂ???0.08. The products obtained were characterized through X-ray diffraction on powders (XRD), thermal analysis (TG, DSC, DTG), scanning electron microscopy (SEM) and microanalysis (EDS). The data obtai...
Autori: Pierantonio De Luca, Danilo Vuono, Monica Filice
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25544

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

Abstract Ash resulting from wood combustion constitutes a waste disposal problem to facility owners. The use of ash fertilizer or soil amendment could provide nutrients for agriculture if its nutrient content is adequate and it does not contain harmful amounts of heavy metals. The recycling of nutrients bound in ash would provide an inexpensive solution to waste problem. In our study, we aimed to characterize ash and clinker resulted from incineration of oak waste resulted from wood industry...
Autori: Ioan Oroian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26885

Abstract Synthesized silicates and their organically modified products have been least explored for their potential use in contaminated water remediation and also as slow release formulations. In this study, adsorption potential and applicability of surfactant modified clinoptilolite (SMC) and montmorillonite (SMM) nanoparticles as adsorbent and slow release formulation of 2,4- dichlorophenoxyacetic acid (2,4-D) have been investigated. The surface modification of hydrothermally synthesized s...
Autori: Deepesh Bhardwaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26913

In this study, the impact of silicate admixture in 2-line ferrihydrite on its sorption properties is presented. Synthetic ferrihydrites with broad Si content in the range of 0 to 1.5 Si/Fe molar ratios were prepared and characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDS). With an increase in the Si/Fe ratio, a typical XRD peak at 2.5Å broadens and shifts toward 3 Å; the position of Si-O stretchi...
Autori: Gabriela Pieczara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27140

Building industry is a very large domain in the global economy and it has a lot of consequences over the environment through many and different aspects. These consequences are various, from the more and more extended area of construction up to gas emissions released during materials manufacture and transportation, construction process, exploitation of buildings and, finally, their deconstruction. The concrete, the most used material in construction industry all over the world, must become green...
Autori: Catalina Mihaela Gradinaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28138

There are considerable environmental and health and safety concerns regarding liquid crystal display (LCD) waste glass because of the waste electrical and electronic equipment (e-waste) that is deposited in landfills. In current study, the effect of variation in LCD waste glass on the deconvoluted fractions of silicon centers of metakaolin geopolymers has been comprehensively investigated to discover the underlying mechanisms governing the performance. Solid/liquid ratio affects the kinetics of ...
Autori: Kang-Wei Lo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28146

The main goal of this work was to develop a cheap and easy method for the synthesis of the porous metallosilicate macrospheres. Zirconium silicate macrospheres with diameters in the range 1.5 – 1.6 mm were obtained by the spray gelling technique, using the multi templating method. Tetraethyl orthosilicate was used as silica source. The chitosan played a dual role (pore and shape generating agent), while other inexpensive and easily accessible biomaterials including yeast, sugar and gelatin...
Autori: Emil Ioan Mureșan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28148

Sodium silicate, iron sulfate, magnesium sulfate, and zinc sulfate were used as the raw materials to prepare a new inorganic polymer flocculant, polysilicate ferric magnesium zinc (PSFMZ), using direct recombination. The effects of molar ratio of zinc to silicon, ratio of iron to magnesium, reaction temperature, and reaction time on deoiling rate were explored. The optimal synthesis conditions for the flocculant for the thermal-washing treatment of oily sludge were determined. Results showed tha...
Autori: Lanlan Yu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28165

LED waste quartz sand (LEDWS), which is a prominent by product of the LED manufacturing process, may contaminate the environment because it comprises specific heavy metals (e.g., As and Cu), which are hazardous ingredients to the environment when disposed of improperly. Therefore, this study investigated the use of light-emitting diode (LED) waste quartz sand to partially replace Portland Type I cement (OPC) to evaluate the feasibility of reusing it as a pozzolanic material. The SiO2, Na2O, and ...
Autori: Kae-Long Lin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28207