AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

Iinclude urmatoarele articole:� Process water of papermaking: model building and characterization� Landfill inventory in the Republic of Moldova: problems and solutions� Floodplain revegetation and river basin restoration� Environmental problems of copper complex in Bor area� Researches on air micro flora determination from public indoor spaces and hospital wards in an urban area� Current practice of solid waste management in Malaysia and its disposal� An assessment of potential he...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25199

In recent years the removal of toxic substances especially heavy metals from water and wastewater by using of non-conventional low-cost sorbent (industrial wastes and some natural material including microorganisms, plant-derived materials, agricultural products and by-products, mineral oxides, clays) has received much attention. In this paper efficiency of Zn (II) removal from aqueous solutions by sorption onto Romanian sphagnum peat moss was studied in batch experiments involving process parame...
Autori: Angelica Kicsi, , Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25126

AbstractThe paper describes the synthesis and characterization of layered double hydroxides (LDH) intercalated with 4,6-dinitro-o-cresol(DNOC) and 2,6-dichlorobenzonitrile (2,6DBN) by anionic exchange method. The incorporation of the organic pesticides in the structure of layered double hydroxides can offer premises to increase the pesticide active life by reducing its volatilization, controlling the release of the pesticide from the layered structure and decreasing the pesticide adsorption in s...
Autori: Gabriela Lisa, Marcel Ionel Popa, Mihaela Frunza
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25144

This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

Contain all the articles from this issueICEEM /01 PLENARY CONFERENCETen years of Environmental Engineering and Management education and research at the Technical University of IasiMatei Macoveanu, Carmen Teodosiu ICEEM/01  - Environmental Engineering SectionRemoval of nitrogen oxides from Diesel exhaust: Laboratory studies for development of an SCR-catalyst-system using solid urea as reducing agentWerner Weisweiler High temperature desulphurization of hydrogen sulphide containing ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25167

Contain all the articles from this issueICEEM/01 -- Environmental Engineering SectionThermodynamic and kinetic study of gas desulphurization by adsorption on zeolites  Ion Untea, Dan Brasoveanu, Madeleine Dancila, Szidonia Bocskor Mixed oxides derived from vanadium substituted layered double hydroxides as catalysts precursors for SO2 oxidationGabriela Carja, Ionel Popa, Gabriela Ciobanu, Nicolae Aelenei The impact of energy production on environment in RomaniaCarmen Zaharia, Mioara Sur...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25168

AbstractThis work presents the state of the art of qualitative and quantitative risk assessment methodologies in a variety of fields. Because risk exists in all ranges of human activity, both private and professional, risk assessment is an attempt to analyze precipitating causes of risk in order to more efficiently reduce its probability and effects. Numerous methodological guidelines within the field of environmental science exist to provide guidance for a risk assessment program, although the ...
Autori: , , Florentina Anca Căliman, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25226

AbstractDark fermentation hydrogen production from a mixture of food components using two different methods of methanogenic inhibition (autoclaving and BES) and three different temperatures (37, 60, and 70 Â?C) was examined in batch assays for two different mixed anaerobic cultures - one suspended sludge (S) obtained from an anaerobic digester and one granular sludge (G) obtained from a brewery wastewater treatment plant. In general, BES-inhibition of sludge was more robust when compared against...
Autori: Angela A. Abreu, Anthony S. Danko, Francisco Pinheiro, Maria Madalena Alves
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25308

AbstractUrban air pollution is responsible for the highest burden of environmentally related diseases in Europe. Air pollutants with strongly indicated respiratory health effects are particulate matter, nitrogen oxides and sulfur dioxide. The retrospective ecological survey has taken into account the urban air pollution with sulfur dioxide (SO2), nitrogen dioxide (NO2), ammonia (NH3) and particulate matter (PM10). The analyzed data show that after applying the European regulations regarding the ...
Autori: Catalin Adrian Petrisor, Dorin Petrişor, Lucreţiu Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25348

AbstractChemical sensors utilizing immobilized enzymes and proteins are important for monitoring chemical processes and biological systems. Glucose oxidase (GOx) from Aspergillum Niger is a flavoenzyme that has been used to determine glucose. Among the conventional methods of enzyme deposition the main strategy consists in its entrapment in an inert matrix adsorbed on the electrode surface. We report here the synthesis and physical – chemical characterization of a new bionanocomposites obtaine...
Autori: , Gabriela Ciobanu, Ion Balasanian, Simona Ratoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25359

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

Abstract This paper presents a comparative study of natural and mechanically mixed composting processes of marc resulting as a byproduct during the production of alcohol obtained from fermented fruits. Moisture, temperature, pH values, soluble fraction, total organic carbon, Kjeldahl nitrogen and ash content were monitored for 60 days. During this period the atmospheric temperature varied from 18Â?C to 21Â?C. The composting process could be considered a combination of three stages: mesophilic...
Autori: Anca-Ileana Penu, Daniela Simina Stefan, Mircea Stefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25407

Abstract A facile and straightforward synthesis route, based on the anionic clay structural â€?memory effect??, has been used to obtain Fe2O3 or CeO2 supported on iron substituted hydrotalcite-like clay (FeLDH). The surface properties of the metal oxide / anionic clay ensembles were studies by X-ray photoelectron spectroscopy (XPS). After calcination at 550°C the derived mixed oxides were tested as new catalysts in the process of the selective catalytic reduction (SCR) of NOx using NH3...
Autori: Gabriela Carja, Sofronia Dranca, Elena Husanu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25413

Abstract The etching of iron materials in sulphuric acid solutions allows the dissolution of the iron oxides with formation of iron sulphates. The relatively low solubility of the formed sulphates imposes their separation for avoiding the contamination of the etching bath, as well as for preventing the environmental pollution through the wastewater. Within the flow sheet of the processing of the hot or cold rolled steel, a stage of separation by crystallization of iron sulphate is foreseen. T...
Autori: Liliana Lazar, Ion Balasanian, Florin Bandrabur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25415

Abstract The mass of usage of secondary plastics are mostly determined by their quality and price. Therefore it was essentially to collect and evaluate the related aspects and expectations from the potential secondary-plastics users. To enable this in the frame of the W2Plastics EU7 project (Magnetic Sorting and Ultrasound Sensor Technologies for Production of High Purity Secondary Polyolefins from Waste) an adequate questionnaire was worked and sent out to automotive plastics end-product man...
Autori: Andrea Toldy, Brigitta Bodzay, Mircea Tierean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25443

Abstract Arsenic (As)-contaminated drinking water is a major problem around the world. The removal efficiency depends strongly on the size of Fe3O4 sorbents.Fe3O4 prepared in laboratory is more efficient in the removal of As and is also more easily recovered from column of magnetic separator than the commercial materials. This would be beneficial in a water treatment system because the As-contaminated Fe3O4 could be flushed from the column permitting reuse of the separator system. The dispers...
Autori: Ionel Balcu, Adina Segneanu, Marius Mirica, Mirela Iorga, Catalin Badea, Iuliana Firuta Fitigau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25456

Abstract This paperwork tried to simulate the combustion inside the naval engines using the newest computer methods and technologies with the result of a diverse and rich palette of solutions, extremely useful for the study and prediction of complex phenomena of the fuel combustion. The paperwork is contributing to the theoretical systematization of the area of interest bringing into attention a thoroughly inventory of the thermodynamic description of the phenomena which take place in the co...
Autori: Nicolae Buzbuchi, Liviu Constantin Stan, Daniela-Elena Mitu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25514

Abstract The paper presents the surfactant-assisted solvo-thermal route to synthesize nanoparticles of cerium oxide with different shape and morphology. The precursor was calcined at 400°C for 4 h in order to obtain CeO2 nanoparticles. The obtained samples were characterized by means of thermal analysis and FTIR spectroscopy. The UV-Vis analysis was used to study the optical properties. The morphologies and nano-structures were characterized by scanning electron microscopy (SEM) and XRD. It...
Autori: Nicolae Apostolescu, Gabriela Carja, Gabriela Apostolescu, Elena Husanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25541

Abstract The aim of this work was to obtain ceria-based catalysts with improved oxidation properties by adding tin dioxide (5, 10 and 20 wt %) and using the co-precipitation method of preparation. The samples were characterized by BET, ESEM, and DRIFT spectroscopy. The activity of SnO2-CeO2 catalytic systems in CO oxidation was studied between room temperature to 673 K. It was found that the increase of SnO2 content obviously increases the low temperature CO conversion. However, at 673 K all ...
Autori: Tatiana Yuzhakova, , Monica Caldararu, Jozsef Kovacs, Anca Vasile, Georgeta Postole, Cristian Hornoiu, Endre Domokos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25565

Abstract In order to obtain new complexes of Fe(III) with multiple uses, their characteristics, important applications and also the obtaining conditions are studied. The obtaining conditions consist in mixing solutions of the same concentrations of ligand 2 amino-6-methoxy-benzothiazole sulphonic acid??†’1-naphtol-4-sulphonic acid with FeCl3. The solutions are mixed in molar ratios of 1:1, 2:1 and 3:1 (ligand to central metallic atom). For determining the molar ratio ligand:central metall...
Autori: Daniela Zavastin, Doina Sibiescu, Igor Creţescu, Ioan Roşca, Mihaela Dana Tutulea, Mihaela Vizitiu
ISSN: 1843-3707
http://www.ecozone.ro/reviste.php?RID=25581

Abstract The slags are an important waste and by-products of metallurgical industry. The present paper summarizes results obtained from physical and chemical analyses on metallurgical slag provided from S.C. ?Mittal Steel Galati? S.A. The physical structure and gradation of granulated slag depend on the chemical composition of the slag, its temperature at the time of water quenching, and the method of production. The following mineralogical components were noticed through bypowder X-ray diffr...
Autori: Maria Cioroi, Licuta Nistor Cristea, Igor Creţescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25588

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

? COMPARATIVE CONSIDERATIONS ON THE STRUCTURE OF SOME MOLYBDENUM/NIOBIUM DOUBLE PEROVSKITES OXIDES ? THE INFLUENCE OF THE STORAGE TIME ON THE STABILITY OF BUTTER ? CaCO3 CONTROLLABLE SYNTHESIS BY DOUBLE EXCHANGE METHOD USING CaCl2 RESIDUAL SOLUTIONS ? OPTIMIZATION OF COAGULATION-FLOCCULATION IN THE TREATMENT OF CANAL WATER ? ANODIC DETERMINATION OF PENTACHLOROPHENOL FROM WATER USING CARBON NANOFIBER-BASED COMPOSITE ELECTRODE ? STUDY OF PRECIPITATES GROWTH IN COAGULATION ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25663

A submerged membrane bioreactor (MBR) was employed to treat wastewater containing different content of seawater in this work. During the process, the operating conditions were as follows: COD was 800-1000 mg/L, ammonium-N was 80-100 mg/L, pH was 7.5-8.5, mixed liquor suspended solids (MLSS) was around 7000 mg/L, dissolved oxygen (DO) was 2-4 mg/L. The results showed that the ammonium-N removal was better than COD removal. Sludge settling property was good in saline wastewater treatment, and the ...
Autori: Jin Li, Deshuang Yu, Dan Wanghttp://www.ecozone.ro/reviste.php?RID=25697

For a better evaluation of the impact of road traffic about air quality, this paper considers the development of a new evaluation index system and methods. They address the assessment of the air quality around the areas with an intense road traffic, according to Chinese standards considering sulfur dioxide index (SO2), total suspended particles index (TSP), floating dust index (PM10), nitrogen oxides index (NOX) and carbon monoxide index (CO). A systematic air quality evaluation model was establ...
Autori: Zhao-hui Liu, Zhi-bin Qinhttp://www.ecozone.ro/reviste.php?RID=25714

Abstract:Incineration plants are used since the beginning of the twentieth century to transform the mixed municipal waste into thermalenergy and to convert the hazardous components of waste into harmless compounds. To minimize the environmental pollutionand maximize the energy efficiency of the produced energy, the control of the complex processes that occur into the waste toenergy conversion is of major importance. In this work, the system identification approach is used to determine the dynami...
Autori: Adrian Danila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25739

Abstract:The paper presents the influence of different WO3:TiO2 ratios on the photocatalytic and photoelectrolytic properties of the films.The investigations are focused on the morphological (Atomic Force Microscopy, Contact angle), compositional (X-raydiffraction), optoelectric (conductivity, photocurrent) and photocatalytic properties of titanium dioxide films mixed with tungstenoxide. The most important application of these layers is in wastewater purification and hydrogen production using ap...
Autori: Alexandru Enesca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25743

Abstract:Methyl orange and methylen blue are two dyes resulted from the textile industry. They are not raising just esthetical problems, butthey are toxic and hence harmful to aquatic animals. The aim of this study is to test the capacity of three types of sawdust (oak,willow and white poplar) and mixed substrates, sawdust: fly ash (FA), to remove the methyl orange (MO) and methylen blue(MB) from wastewater. The influence of contact time, solution pH and initial concentration of dyes on the blea...
Autori: Anca Duta, Dora Lucaci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25752

Abstract:Ash is a waste that can be an efficient substrate in wastewater treatment for the immobilization of heavy metals and for dyesremoval. For an up-scalable wastewater treatment process, efficient substrates, with relatively constant behavior are needed andmodifying the adsorbent surface can be a feasible solution. Fly ash, resulted from coal burning, and wood ash are mixtures mainlycontaining metal oxides and carbon in various proportion, depending on the initial raw material.The paper pre...
Autori: Maria Visa, Mihaela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25771

Abstract:The study involved investigating the effects of Cr(III) and the efficacy of powdered activated carbon (PAC) in reducing theinhibitory effects of Cr(III) on activated sludge under sequencing batch reactor (SBR) operation. The addition of Cr(III) into SBRsystem caused significant inhibitory effects on the activity of activated sludge as indicated by drastic drop in specific oxygenuptake rate (SOUR). The increase of Cr(III) concentration from 5 to 10 mg/L further deteriorated the treatment...
Autori: Eiichi Toorisaka, Makoto Hirata, Soon-An Ong, Tadashi Hano
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25773

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The paper aims to present the environmental impact of pulp and paper manufacturing and the most important production and control practices to minimizing this impact. The environmental consequences of manufacturing pulp and paper from pulping and bleaching processes are discussed in qualitative and quantitative terms. In these processes, sulfur compounds and nitrogen oxides are emitted to the air, and chlorinated and organic compounds and nutrients are discharged to the wastewaters. Large quantit...
Autori: Adrian Catalin Puitel, Dan Gavrilescu, Gheorghe Dutuc, Grigore Craciun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25857

This paper presents original studies about the influence of mineral and/or organic fertilization on the minerals contents (P, Na, K, Ca, Mg, Fe, Mn, Zn, Cu, Ni and Pb) in leguminous plants from permanent grassland situated in a hill area of Banat County. Determination of minerals in grassland is very important both for the nutritional or toxic effects of these elements and their compounds, in the plants, animals and environment. Phosphorous was analyzed colorimetric and all the others metals hav...
Autori: Alexandru Moisuc, Iosif Gergen, Monica Harmanescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25858

Newly prepared SnO2-CeO2 catalyst samples used as depollution catalysts were characterized applying low-temperature nitrogen adsorption (BET), X-ray diffraction (XRD), thermo-gravimetry (TG-dTG) and temperature-programmed reduction (TPR) methods. Pure SnO2 has higher surface area (17 m2/g) than the pure CeO2 (8 m2/g). Addition of organic tin oxide precursor to ceria in amount of 5 wt% slightly decreases the surface area of CeO2 (SSn5-Ce= 7 m2/g). The increase of tin oxide content to 10 and 20 wt...
Autori: , Anca Vasile, , Cristian Hornoiu, Jozsef Kovacs, Tatiana Yuzhakova, Veronica Bratan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25875

According to the Romanian Law no. 265/2006, which adopted the Governmental Decision no. 195/2005 on environmental protection, environmental agencies are responsible for air quality monitoring in Romania. Since Romania is now an EU Member State, such a plan is a must to enhance life quality, in order to meet the objectives of the National Strategy for Sustainable Development. Having regarded to this Strategy and the Kyoto Protocol signed in 1997, this paper provides the results from a study of am...
Autori: Corina AnaMaria Ioan, Florin Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25895

AbstractGroundwater hydrochemical evolution has influences on the rational use and conservation of water resources. This paper whichtakes MapGIS as the platform is aimed at demonstrating the evolution of shallow groundwater hydrochemistry in Guanzhongbasin (China) by adopting mathematical statistics, ratios of ion pair equivalents, geochemical simulation. The direction ofevolution is dependent on the geological, geomorphological, and hydrogeological conditions of the study area. The spatialdistr...
Autori: Hua Tian, Lei Duan, Wenke Wang, Xiaoting Yang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25956

AbstractNumerous governments have adopted innovative policy instruments to deal with important environmental policy challenges.Various forms of negotiated instruments may offer the potential to improve on environmental performance beyond whatregulation alone can accomplish. Dutch covenants, which represent negotiated agreements with sectors of industry as targets ofbehavioral change in terms of mitigation of pollution, waste minimization and sustainable products and processes, provide auseful sa...
Autori: , Kris Lulofs, Laura Franco, Theo de Bruijn, Yanyan Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25972

AbstractIn this paper we describe a wireless system, including smart sensing nodes for indoor air quality and unobtrusive cardiorespiratorymonitoring. The sensing nodes include a set of solid state gas sensors, sensors for temperature and relative humidity, amicrowave Doppler radar sensor for cardio-respiratory function, and appropriate conditioning circuits expressed by active filtersand amplifiers. The analog signals provided by the signal conditioning circuits is applied to a data acquisition...
Autori: Gabriela Postolache, Octavian Postolache, Pedro Silva Girăo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26007

AbstractMultifunctional materials based on iron substituted anionic clays and their derived mixed oxides owning specific porousproperties and textural characteristics are synthesized, characterized and tested as photocatalysts in the process of the azo-dyesdegradation from aqueous solutions. The features of X-ray diffraction patterns point out the modification of the lattice parameterswhen Fe3+ is substituted Al3+ in the brucite like layer. N2 adsorption-desorption analysis reveals specific poro...
Autori: Carmen Gherasim, Gabriela Carjă, Magda Puşcaşu, Mihaela Bîrsanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26024

AbstractThe paper presents the research made on the FP7 project „Magnetic Sorting and Ultrasound Sensor Technologies for Productionof High Purity Secondary Polyolefins from Waste” in order to develop a magnetic fluid equipment for sorting of polypropylene(PP) and polyethylene (PE) from polymers mixed waste streams. Because both PP and PE float in water, it is difficult to separateone from the other. The paper presents the principles of inverse magnetic density separation process and the results ...
Autori: Bin Hu, Francesco Di Maio, Guillaume Houzeaux, Liana Baltes, Mircea Tierean, Peter Rem
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26028

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractIn road traffic noise issues, experimental measurements are a relevant element in order to understand the problem and to adjustmodels. Sometimes, when measurements are not possible or in the designing phase, prediction models are used to perform anestimation of the equivalent level produced by a road infrastructure. Usually models parameters are obtained by a statistical datafit and thus they are related to the area where measurements have been performed. These models are suitable for st...
Autori: Gerardo Iannone
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26087

Abstract The aim of this paper is to analyze how local and atmospheric conditions influence pollutants’ distribution. Two different sites in Romania were chosen for measurement campaigns: Surlari (44° 34', 26° 19') located into a forest and near a lake, and a suburban area, Magurele (44° 21', 26° 2'), where the anthropogenic activities dominate. The same equipments for measurements of surface ozone, CO, NO2, NO and PM10 were used at the two sites. The measurements were performed in...
Autori: Sabina Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26126

Abstract The paper presents several aspects regarding the optimization of the operation for a mixed cycle gas turbine, Titan 130S type, installed at S.C. CET S.A. Bacau, during the warm season. The optimization entails the partial loads operation and has been done using the multicriterial analysis, taking into consideration the operation restrictions required for this type of gas turbine. The criteria that regard this analysis are: thermal energy requirements, the global efficiency...
Autori: Marius-Ion Stanila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26145

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

AbstractKnown concentrations of naphthalene were added to soil samples to investigate the anaerobic degradation potential by theinoculated naphthalene-adapted bacteria under nitrate reducing conditions. Naphthalene could be anaerobically biodegraded tonon-detectable levels within 35 days when the initial concentrations were 5.8 mg/kg, 34.7 mg/kg, 61.4 mg/kg, 93.7 mg/kg and146.6 mg/kg in soil, respectively. The degradation rates of naphthalene increased with increasing initial concentrations. The...
Autori: Junfeng Dou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26157

AbstractThe dominant litter samples Pinus sylvestris L. needle litter and Acer platanoides L. leaf litter were collected in the coniferousmixed forest located at 54ş43‘ N 25ş19‘ E (Vilnius, Lithuania) in April 2010. Different heating temperatures (150, 250, 350, 450and 550şC) and 2 hour heating duration were used to produce ashes. The selected heating temperatures affected mass loss, colour, pH, electrical conductivity (EC), C/N ratio, nutrient concentrations of the ash. The darkness of Munsell ...
Autori: Jolita Dūdaitė
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26208

AbstractGlobal warming is happening due to increasing level of carbon dioxide and other greenhouse gases into the atmosphere. In orderto reduce this rising level of CO2 emitted by human activities, carbon capture and storage technologies are being developed.The present paper investigates and compares, from a techno-economical point of view, two of the most used conceptual methods(post- and pre- combustion) for CO2 capture generated from the fossil fuel power generation sector. For post-combustio...
Autori: Anamaria Padurean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26217

AbstractWashing black aluminum (Al) slag to obtain soluble salts is an important stage of the smelting slag treatment at technologicalprocess. This process is used to recover Al as a coagulant for water purification. This research aims at establishing the optimalconditions for washing (e.g. temperature (T), solid: liquid ratio (S : L), time, the recirculation waters in the system). The goal ofresearch was to determine: a) the removal with maximum efficiency of the soluble salts from black Al sla...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26243

AbstractThe intercalation of 2,6-dichlorobenzonitrile (DBN) into the NiMgAlLDH, CuMgAlLDH and MgAlLDH layered doublehydroxides was carried out using the calcination-rehydration reaction using NiMgAl, CuMgAl and MgAl oxide precursors,obtained by calcination at 550oC. X-ray diffraction (XRD), elemental analysis, infrared spectroscopy (FTIR) andthermogravimetric analysis (TG-DTG) confirmed that DBN molecules were successfully intercalated into the interlayer spaces ofLDHs. The resulting solid produ...
Autori: Mihaela Silion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26244

AbstractA bench-scale anaerobic bioreactor for the anaerobic treatment of textile wastewater using anaerobic sludge was experimented.The Top and bottom of hybrid bioreactor were functioned with UAF (Up Flow Anaerobic Filter) and UASB (Up Flow AnaerobicSludge Blanket), respectively. The effect of organic loading rate (OLR) and hydraulic retention time (HRT) on treatment oforganic matters in the textile wastewater was investigated. The maximum removal of chemical oxygen demand (COD) and colorwas 9...
Autori: Reza Katal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26255

AbstractIn industrial plants many types of combustible dusts are generated, processed, handled and stored. When ignited, they can burnrapidly and with a considerable explosion force, when mixed with air in proper proportions. This is the reason why adequateprecautions have to be adopted, to ensure all equipment is appropriately protected so that the ignition likelihood of the explosiveatmosphere is diminished.Explosion preventing and protection precautions aim to stop explosion occurrence, by el...
Autori: Adrian Jurca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26406

AbstractThe process of semi-volatile aerosol particle evaporation was studied with respect to both computational and experimentalapproaches. A Sinclair-La Mer type aerosol generator was used to produce monodisperse particles from four n-alkanes(tetradecane, hexadecane, octadecane, eicosane) while particle sizing and FID measurements were applied to quantify particleandvapor mass and their subsequent phase distribution. Aerosol dilution and later stationary analyses in a flow tube at two timeinte...
Autori: George C. Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26448

AbstractCarbon monoxide (CO) is a gas obtained both from natural sources (bush fires, volcanic emissions and electric discharges) andby anthropogenic processes (incomplete combustion of fossil fuels). Together with particulate matter, nitrogen oxides andhydrocarbons, it is part of the air pollutants associated with the transport sector, which have a negative impact on human health,animals and vegetation. In this paper the authors propose a methodology for assessing CO emissions from road traffic...
Autori: Gabriela Mitran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26466

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractThe incorporation of phosphorus (P) into sediments and the changes in its bioavailability under intermittent P input and sedimentresuspension conditions were investigated via laboratory experiments. The sediments were disturbed daily for 10 min and thenallowed to settle for 1430 min after each disturbance to simulate the intermittent sediment resuspension conditions. The removalof soluble reactive P from the overlying water under sediment resuspension was greater than that under static c...
Autori: Li Dapeng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26567

AbstractThe general aim of this paper is to demonstrate the sustainable management of a broad spectrum of wastes (livestock, industrial,agri-food, agricultural and non-recyclable fraction proceeding from waste treatment plants) in an integrated plant. Thetechnological development and practical application of the “Mixed Plant” concept is used to achieve this objective. In order tovalorize in a joint form all the above-mentioned categories of waste, two different processes have been integrated. Th...
Autori: Dolores Hidalgo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26579

Abstract Wildfire emissions are a major contributor of atmospheric gaseous and particulate pollutants for local air pollution levels. With respect to wildfires, Turkey faces one of Europe’s most severe problems during summer. In this study, a database which holds data for wildfire emissions in Turkey for the last decade (between 2000 and 2009) was established in order to create a wildfire emissions inventory. The emissions of carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), n...
Autori: Faruk Dincer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26584

Abstract Toxic chemical nature of tannery wastewater makes it difficult to be treated by routine biological treatment processes. Microbes, already present in tannery wastewater can adapt to these conditions and degrade the organics in tannery wastewater. In the present contribution, three bacterial electrogenic strains, tolerant to tannery environment, were isolated from soil contaminated with tannery waste and named as BS1, BS2, and BS3. Tannery wastewater was treated with these pure and mi...
Autori: Abhilasha Singh Mathuriya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26588

Abstract Some of the major stressors of air quality in the urban areas are nitrogen oxides, ozone and suspended particles. The effect of air pollution on respiratory diseases can increase considerably at high levels of pollution and might trigger asthma symptoms. Longterm exposure can increase the rate of respiratory infections and symptoms at population level, but particularly in children. The goal was to analyze with statistical techniques the pollutant concentrations (NO, NO2, and SO2) re...
Autori: Daniel Dunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26605

Abstract The objective of this study is to develop a mathematical model which would confidently predict the rate of substrate degradation of an oil-water emulsion in a laboratory-scale completely-mixed continuous flow reactor using the photo-Fenton treatment process. Two models are developed from first principles and the predicted substrate removal rates for both models are compared with experimental data. The principal conclusions of the study are that both models produce good correlations ...
Autori: Maha A. Tony
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26613

Abstract The feasibility of catholyte-conditioning to enhance the electrokinetic (EK) remediation of cobalt and lead polluted soil has been investigated in this study. Electrokinetic experiments were conducted using an EK cell 10 cm in width, 10 cm in height, and 50 cm in length. Plate type electrode of graphite was used as electrode material. Two experiments were conducted under constant voltage condition (2 V/cm). The pH values of the soil significantly affect the removal of Co and Pb ions...
Autori: Mahdi Bahemmat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26623

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract A new catalytic mixture of nanosized dioxide (CeO2) and zinc oxide (ZnO) powders have been synthesized by surfactant-assisted solvo-thermal route, characterized and evaluated for photocatalytic activity. The prepared catalysts were characterized by TG, XRD, SEM and EDAX methods. SEM analysis showed that the catalyst particles have spheroidal shape and their sizes range from 50 to 80 nm, organised as uniform distributed aggregates with large surface area, leading to the existence of ...
Autori: Gabriela Antoaneta Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26655

Abstract The class of xanthene dyes has a complex chemical structure, which showed to be toxic for mixed culture of microorganisms (i.e. anaerobic granular sludge). Because of the unwanted effects of Erythrosin B (Ery B) on environmental components and some food confirmed previously, the dye was chosen in this study to evaluate its ecotoxicity. Also, the Ery B photocatalytic degradation products were assessed in terms of their ecotoxicity. Three-days of seed germination and root growth test...
Autori: Laura Carmen Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26660

Abstract The influence of exogenous form of heavy metals intake on their transformation in the soil is determined during model experiments. Distinctions in quantity of extracted mobile compounds of heavy metals in the soil depending on a form of addition various connections of Cu and Zn are established. The smallest mobility of Cu and Zn at addition of heavy metal oxides is observed. It is established that Cu accumulates mainly in the fraction connected with organic matter; Zn accumulates in...
Autori: Tatiana M. Minkina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26662

Abstract This study focused on the use of jet aeration to treat printing and dyeing wastewater. The related environmental factors influencing the dynamical efficiency of a jet aerator were investigated. Results showed that an ideal linear relation existed between dynamical efficiency and working pressure (R2 > 0.98), with dynamical efficiency decreasing gradually as the working pressure increased. When the gas–liquid ratio was approximately 0.6:1 to 1.4:1, more bubbles were formed b...
Autori: Chunsheng Le
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26664

Abstract The experiments on the olive oil mill wastewater treatment for removing the lipids by anaerobic and aerobic biodegradation with mixed Bacillus spp. culture indicated that the rate of the aerobic process is up to two times higher than that of the anaerobic one. In this context, it was found that the influence of the dissolved oxygen concentration on the lipids biodegradation process is significant, but the kinetic model given in literature does not consider this parameter. Therefore,...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26674

Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

Abstract The use of hydrogen in spark ignition engines as a supplementary fuel can enhance combustion and reduce toxic emissions. Difficulties in hydrogen storage and production limit its use in internal combustion engines. This paper investigates the performance of a spark ignition engine with the addition of a mixture of hydrogen (H2) and oxygen (O2) into the intake manifold. Hydrogen is produced by an alkaline electrolyser and consumed simultaneously to eliminate the need for a storage de...
Autori: Yasin Karagöz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26685

Abstract Magnetite nano-particles (Fe3O4) were synthesized in order to be used as adsorbent for some toxic metal ions (Cr, Cd, Ni and Cu) present in aqueous solutions (industrial waste waters). The amount of toxic metals (Cr, Cd, Ni and Cu in quaternary aqueous solutions) before and after contact with the magnetite nano-particles was analyzed by flame atomic absorption spectrometry (FAAS). Different operational parameters such as metal concentration and pH of the quaternary solution, as well...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26721

Abstract The objective of this study was to identify differences between three of the most conventional UV-based advanced oxidation processes, namely photolysis, UV/TiO2, and UV/ZnO for the decolorization and mineralization of reactive red 198 (RR198) model dye in saline media. The study investigated influences of solution pH levels, salt concentration, reaction time and dye concentration on the degradation of RR198. The most effective dye removal and mineralization was observed at pH levels...
Autori: Gholamreza Moussavi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26724

Abstract An experimental study of mixing in autoclave vessel equipped with an anchor impeller was performed on the sludge proceeding from the treatment of mixed municipal and industrial wastewater. This unit operation is part of a process for the recovery of sludge. The mathematical modelling of the mixing was done having in view the scaling-up of this process. The mathematical model allows the calculation of the mixing power N as a function of the impeller diameter d, the vessel diameter D,...
Autori: Ancaelena Eliza Sterpu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26744

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract The aim of this study is to analyse Romanian situation regarding packaging waste generated and to find out how the targets imposed after integration were accomplished, based on data collected and published by Eurostat, as well by other publications. The municipal solid waste collection practice in Romania is based on mixed collection (approximately 96% of waste generated), without or with minor sorting at source. Waste recovery is applied to small percentages and only for certain ca...
Autori: Carmen Luiza Costuleanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26764

Abstract The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life (EoL) treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and at the aim of their exploitation as valuable sources of raw materials. Within this study an integrated approach for waste electrical and electronic equipment (WEEE) end of life treatment is proposed based on the integration of hydrometallur...
Autori: Claudia Brunori
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26777

Abstract The uncertain phenomenon is very complex and using only fuzzy or random variable cannot describe it appropriate. In addition, low carbon is the requirement of the supply chain. In order to overcome those two issues, this paper describes the uncertain phenomenon in supply chain design under fuzzy random environment and constraints on CO2 emission. It considers that the demand rate is a fuzzy random variety, and builds a mixed integer optimization models featuring multiple products, m...
Autori: Zhixue Liao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26808

Abstract The uncertain phenomenon is very complex and using only fuzzy or random variable cannot describe it appropriate. In addition, low carbon is the requirement of the supply chain. In order to overcome those two issues, this paper describes the uncertain phenomenon in supply chain design under fuzzy random environment and constraints on CO2 emission. It considers that the demand rate is a fuzzy random variety, and builds a mixed integer optimization models featuring multiple products, m...
Autori: Zhixue Liao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26824

Abstract The adsorption of phosphorus (P) on sediment plays a significant role in phosphorus transport in aquatic systems. This research examined the effect of the main components of sediments (including iron (Fe), manganese (Mn) oxides and organic matter (OM)) on P adsorption and to evaluate their relative contribution with different sediment particle sizes. The sediments were separated into four particle-size fractions: 0-30 μm, 30-62 μm, 62-90 μm, and 90-125 μm, and then selec...
Autori: Yang Xiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26873

Abstract Safe operation of highly thermally sensitive industrial reactors is still considered a major issue in chemical engineering practice. The problem becomes even more stringent when highly exothermic reactions are conducted under randomly fluctuating operating variables, and especially when the set-point is located in a close vicinity of the runaway boundaries for increasing the reactor productivity. This study is aiming to derive the runaway boundaries and their associated region of co...
Autori: Constantin Muscalu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26884

Aniline is a priority pollutant, which is known as a toxic organic pollutant released as effluent from several industries. Several physicochemical methods have been used for degradation of this pollutant. In this study, photocatalytic degradation of aniline from synthetic wastewater by ZnO nanoparticle was considered. The effects of different variables, such as irradiation time, the amount of photocatalyst, initial pH values and initial concentration of pollutant on the photodegradation of an...
Autori: Ahmad Jonidi Jafari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26929

A drainage channel network in Vojvodina, Serbia, made for collection and transition of (sub)surface waters from waterlogged arable land areas, is exposed to diffuse and/or point contamination sources. Over time, the channel network has accumulated sediment material containing potentially harmful organic substances such as polycyclic aromatic hydrocarbons (PAHs). In this study, the concentration of 16 environmentally relevant PAH substances from 42 sampling points in drainage channel sediments...
Autori: Radovan Savić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26950

Treatment of agrochemical industry wastewater is difficult to carry out unless integration with some advanced oxidation process (AOP) is used. The present study deals with treatment of an agrochemical industry wastewater, first using activated sludge and then with sulfuric acid treated activated carbon (SAAC) in presence of Fenton reagent. During the activated sludge treatment the food-to-microorganisms (F/M) ratio is varied from 0.1 to 0.2 mg chemical oxygen demand (COD) per mg mixed liquor ...
Autori: Makarand Vasant Karkare
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26957

Air pollution has a significant impact on human health and natural ecosystems. The principal gaseous pollutants compounds result from different types of combustion processes. In this category there are included carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), dust and hydrocarbons. Nitrogen oxides are a group of highly reactive gases, which contain nitrogen and oxygen in varying amounts. Most of the nitrogen oxides are colorless and odorless gas. This paper highlights the c...
Autori: Doina Capşa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26988

Measurements were taken for Ozone (O3) and its precursors simultaneously from June to August 2008 in Beijing. We analyzed the spatial and temporal variability of O3 and its precursors and the roles of the precursors in O3 formation. The results suggest that O3 mixing ratios are higher in rural areas than in urban areas. Highest mixing ratios of VOCs were alkanes, followed by aromatics; alkenes and biogenics were present at lower mixing ratios. Because of their relatively high reactivities, ar...
Autori: Junlin An
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26994

Drainage water and tailings impoundments water geochemistry (pH, EC, alkalinity, trace element concentrations, major ions) were studied at the Anjir Tangeh coal washing plant. The drainage water with neutral to alkaline pH values, high SO42- concentration and low metal content represented typical neutral alkaline mine drainage (NAMD). According to the Stiff and Piper diagrams, the majority of water samples classified into Ca-Mg-HCO3- type except drainage and processing water which were placed...
Autori: Majid Shahhosseini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26997

Emission from the combustion processes can cause adverse effect to the environment. The formation of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), carbon dioxide (CO2) and oxides of sulphur (SOx) are hazardous and harmful to the ecosystem. Due to these pollutants and also depletion of fossil fuel, several steps should be taken in order to mitigate this problem. Biofuel is known as the potential replacement for fossil fuel. Envo Diesel is one form of biofuel that can be us...
Autori: Mohammad Nazri Mohd Ja’afar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27011

While the water quality issues in suburban watersheds have been greatly attributed to rapid urban development and stormwater runoff, pollution contribution from agricultural practices are still significant but often overlooked. The objective of this study is to assess water quality impacts of managing both agricultural and urban lands in a suburban watershed. Neshanic River watershed is a headwater watershed with mixed land uses located in Hunterdon County, New Jersey, USA. It has 40% of agr...
Autori: Zeyuan Qiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27081

This study was carried out to monitor the presence of organophosphorus in drainage water (Kafr El-Sheikh (Kotshinar Drainage), Fowa (Fowa Drainge No.11), Metobess (El-Hokss Drainage), Beila (Karakat Drainage), Balteem (Hafeer Shihabeldeen Drainage), Nashart Drainage and El-Hamoul (El-Hamoul Drainage) in Kafr-El-Sheikh Governorate, Egypt. Furthermore, the efficacy of chemical (advanced oxidation processes) and bioremediation (effective microorganisms) for chlorpyrifos removing in drainage wat...
Autori: Aly Derbalah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27104

The aim of this study is to investigate an innovative way to utilize the char obtained from tyres pyrolysis, in order to realize lightweight materials for building. Pyrolysis residue, mixed with three types of waste glass, has been used as raw material to obtain lightweight materials, exploiting its capability to behave as foaming agent. The results demonstrate that the pyrolysis char is a good foaming agent for the mixtures 50/50 with glassy sand and packaging glass waste, thermal treated at...
Autori: Fernanda Andreola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27119

The direct measurement of the nutrients largely contributes to understand how the quality of the information, coming from the instruments, may improve the performances of the plants. The advanced knowledge acquired on the meaning of the signals gives new possibilities to control the biological processes and estimate the operational state of the plant, improving the quality of the effluent and keeping the operational costs as low as possible. Such information, furthermore, can be used to under...
Autori: Carmine Fiorentino
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27127

The aim of the present study was to prepare environmentally friendly silver-based materials using Cornus mas L. fruits extract. For this purpose, silver nanoparticles (Cornus mas-AgNPs) were green synthesized using this plant extract. The bioreduction of silver ions was analyzed by UV–VIS and ATR-FTIR spectroscopic studies. Scanning Electron Microscopy (SEM) analysis revealed the formation of spherical phyto-nanosilver particles with size ranging between 12 and 40 nm. Different amounts ...
Autori: Ioana-Raluca Suica-Bunghez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27139

In this study, the impact of silicate admixture in 2-line ferrihydrite on its sorption properties is presented. Synthetic ferrihydrites with broad Si content in the range of 0 to 1.5 Si/Fe molar ratios were prepared and characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDS). With an increase in the Si/Fe ratio, a typical XRD peak at 2.5Å broadens and shifts toward 3 Å; the position of Si-O stretchi...
Autori: Gabriela Pieczara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27140

An electrochemical oxidation system using Titanium-based material as anode was setup and used to remove ammonium nitrogen (NH4-N) from swine wastewater. The effects of electrode material, current density, pH, and chlorine ion concentration were evaluated by removal rate of NH4-N and energy consume. The results showed that the NH4-N removal rate reached 98.5% using Ti/Mn-Ni/SnO2-Sb-CeO2 material as anode under the conditions: detention time of 60 minutes, pH of 8-10, current density of 20 mA/...
Autori: Xuewen Yi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27146

Ozonation of oxytetracycline in aqueous solution with an activated carbon (AC)-supported cerium oxide (CeO2/AC) catalyst was conducted. The activity and stability of CeO2/AC, and the effects of ozone dosage, catalyst dosage, reaction temperature, initial oxytetracycline concentration, and initial pH on the catalytic activity of CeO2/AC for the removal efficiency of total organic carbon (TOC) were investigated. It was found that CeO2/AC catalyst was efficient in TOC removal during ozonation of...
Autori: Zheng-Qian Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27156

In this work, the effect of cyclic anaerobic/aerobic conditions on the biodegradative capability of the mixed microbial culture for the azo dye Acid Red 18 was investigated in the sequencing batch reactors. For this purpose, five anaerobic/aerobic sequencing batch reactors were operated under the same operation conditions at different anaerobic/aerobic reaction times. The whole reaction time was 22-h with anaerobic/aerobic periods of 6/16, 10/12, 14/8, 18/4 and 22/0 (h/h) in An/ASBR1 to 5, respe...
Autori: Mohammad Hakimelahi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27191

A new simple empirical model is proposed to describe the waste sludge volumetric flow rate in the steady-state completely mixed activated sludge process. The model is derived based on the nonlinear regression analysis by using the Richardson’s extrapolation method and the Levenberg–Marquardt algorithm. The application of the model has been explored for a wide range of eleven fundamental biological design variables and tested against a total of 1500 additional computational scenarios ...
Autori: Kaan Yetilmezsoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27202

Various azodyes containing one or more sulfonic groups were removed from aqueous solutions by biosorption on untreated wood shavings from Picea abies. The sorption kinetics was described by the pseudo-first-order (PFO), pseudo-second-order (PSO) and modified pseudo-n-order (MPnO) equations, from which the MPnO model provided the best fit to the experimental data. The surface reaction was identified as a rate-limiting step governing the dye sorption on wood shavings, but a mixed kinetics (with a ...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27207

The mixed microbial culture, isolated from the aerobic sludge was used to study biodegradation of 1,1-DCE as the sole carbon source in batch flasks. 1,1-DCE initial concentration in the medium was varied from 100μg/L to 1000μg/L. The maximum removal rate of 1,1-DCE was 89.2% obtained at 400μg/L 1,1-DCE concentration in the medium. The biodegradation kinetics of 1,1-DCE was found to follow three-half-order model at all initial 1,1-DCE concentrations with regression values greater than 0....
Autori: Shizong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27219

The important factor for health hazards in major cities in India is air pollution. Due to the sudden increase in vehicular population in the city of Chennai, South India, there is a high increase in vehicular emission caused by the vehicular effluents like Carbon monoxide, oxides of Nitrogen, oxides of Sulfur and other Particulate Matter. This study proposes an advanced state of the art technology (On Board Diagnostics) to acquire and process data from the vehicular emissions through online data...
Autori: Gunaselvi Manohar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27221

The effect of ceria content on the physicochemical properties and catalytic performance of nanostructured CeO2/Al2O3 for removal of toluene from waste gas stream was studied. The properties of the catalysts were addressed using XRD, FESEM, BET, TPR-H2 and FTIR techniques. XRD patterns confirmed the formation of CeO2 with average crystallite size of 7.8-8.7 nm. FESEM images confirmed the presence of fine particles between 25.2-189.1 nm. BET results showed that nanostructured CeO2/Al2O3 had high s...
Autori: Saeed Saedy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27245

The present work reports the gaseous emissions of the following industries, Interloop Textile (IP Tex), Crescent Textile (CT Tex), Kalash Textile (KH Tex), Noor Fatima Textile (NF Tex), Bashir Textile (BP Tex) and Hina Sana Texile (HS Tex), which are located in Faisalabad, Pakistan. Industries were tested for the mixture of gases containing carbon monoxide (CO), nitrogen oxides (NOx), sulphur oxides (SOx), carbon dioxide (CO2) and hydrogen (H2) emitting from these industries. The maximum amounts...
Autori: Muhammad Zubair
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27256

The present work illustrates the results of a long-term field experiment with sewage sludge used on agricultural land in order to assess the influence of sewage sludge on wheat crop productivity. The experimental research was conducted for three years as following: the evaluation of the agricultural use of sewage sludge in the year of application and its residual effect in grain and in soil for the next two years. The sewage sludge considered in the framework of the study was from Sfantu Gheorgh...
Autori: Diana Mariana Cocarta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27303

This study was to optimize the fermentation process for protein enrichment of potato starch residue (PSR) by solid state fermentation with mixed strains. Three single-factor experiments were conducted to optimize the fermentation conditions, and a Plackett-Burman design followed by a central composite design of response surface methodology was investigated to optimize the medium constituents. The optimal fermentation conditions were fermentation temperature 28°C, fermentation period 72 h and...
Autori: Heng Lei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27380

The kinetics of azo dye reduction based on combined effect of biochemical reduction by anaerobic mixed culture and chemical reduction with hydrogen sulfide was investigated. Hydrogen sulfide was produced by sulphate reducing bacteria existing in the anaerobic mixed culture. The effect of initial anaerobic biomass, initial substrate, and initial dye (Reactive Orange 107) concentrations on reduction kinetics were studied with batch assays. The municipal waste sludge was used as electron donating s...
Autori: Umay Gokce Ozkan-Yucel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27386

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

This research was focused on the valorization of agro industrial waste/by products available in the local industry with the kilometer zero (km 0) concept, as a replacement of virgin raw materials (clay) to elaborate lightweight aggregates (LWAS). The alternative raw materials were employed as pore forming agent, in order to reduce sintering temperature and energy consumption of the furnace. The three technical nutrients studied were provided for local food industries: sludge from wastewater trea...
Autori: Romina D. Farias
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27405

The paper presents results obtained by analysis of some soil and wastes samples in order to establish the heavy metal (HM) content from these samples. The analyzed wastes were sewage sludge from municipal waste treatment and hydrotechnical basin sludge. These types of wastes were mixed with soil from Oltenia Sub-Carpathian area, obtaining the substrates useful for different types of plants. It was studied the migration potential of the metals from substrate to apple trees, the results being comp...
Autori: Cristian Predescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27476

Wastewater treatment using sequencing batch reactor (SBR) has certain advantages over conventional activated sludge system. The performance of sequencing batch reactor in treating high C/N ratio was investigated with suspended polyurethane and polystyrene attached growth biomass configuration. A sequence of 4 hr HRT, 0.3 month SRT and 1kg COD/m3 was employed to study treatment efficacy. Treatment performance was assessed by means of chemical oxygen demand (COD), total nitrogen (TN) and total pho...
Autori: Beenish Saba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27478

Fungal isolate Aspergilius niger V-8 (IITB) was isolated from the sludge of anaerobic digester of distillery wastewater treatment plant and was found to be an appropriate fungal isolate for the purposes of decolourization of anaerobically digested molasses spentwash (ADMS). The study aimed at optimization of the environmental parameters for achieving maximum decolourization of ADMS using isolated fungal species. Environmental parameters like initial pH, mixing, immobilization and surfactant a...
Autori: Mrityunjay Singh Chauhan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27502

A polycrystalline CeO2-ZnO catalyst was prepared by using a hydrothermal procedure in order to improve the structural properties. This polycrystalline material was then used to remove organic pollutants from aqueous solutions by the means of photocatalysis. The structural, morphological and optical properties of as-prepared materials were characterized by several techniques, such as UV-visible spectroscopy, SEM, FTIR, XRD. The SEM analysis shows that the crystallite size sample varies in the ran...
Autori: Nicolae Apostolescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27550

Chemical oxidation of pyrite and chalcopyrite by ferric sulfate (Fe2(SO4)3) solution and biogenic ferric iron obtained by mixed culture of isolated thermotolerant Acidithiobacillus sp. 13Zn and Leptospirilum ferriphilum CC immobilized on natural carriers- zeolite and shungite was studied. Oxidation rate of sulfide minerals was estimated by the decrease of Fe3+ (oxidant) and increase of Fe2+ ions in the solution. It was revealed that chemical oxidation of chalcopyrite by biogenic ferric iron occu...
Autori: Arevik Vardanyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27563

This work focuses on the analysis of material composition of mixed municipal solid waste (MSW) in the city of Košice, the second largest city in Slovakia, and in the village of Poproč, which is representative of the region. The paper describes the characteristics of the monitored localities, the methodology and the original evaluation procedure. The analysis of the mixed MSW composition in Poproč was performed in 2009-2010, and in Košice in 2011. In both cases, the analys...
Autori: Takáčová Zita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27570

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27577

• Environmental engineering and Management Journal No. 4    • AN ENHANCED ENVIRONMENTAL MULTIMEDIA MODELLING SYSTEM (FEMMS): PART II – USER INTERFACE AND FIELD VALIDATION    • COST-EFFECTIVENESS OF OPTIMIZING CONCENTRATED FEED BLENDS TO DECREASE GREENHOUSE GAS EMISSIONS    • FATE AND BIODEGRADATION OF ESTROGENS IN THE ENVIRONMENT AND ENGINEERING SYSTEMS – A REVIEW    • ANALYSIS OF THE MATERIAL COMPOSITION OF MIXED MUN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27576

In order to reduce the production of pollutants, it is most important that landfills are adapted to the climatic conditions of the area where they are located. In this sense, there are very few studies focused on how to reduce leachates from landfills in semiarid regions, which are especially sensitive to the impacts that this type of activity potentially has on water resources. The aim of this study is to identify the best type of landfill cover that reduces leachate production in semiarid regi...
Autori: Javier Senent-Aparicio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27595

Increased concern about global warming in today’s world has led to the legislation of regulations that seek to gradually reduce the amount of greenhouse gases emitted by industrial sectors and along their supply chains. This study focuses on the amount of carbon emitted in a two-echelon supply chain in which one supplier delivers a single product to a group of retailers and attempts are made to integrate and coordinate its different members. A mixed integer programming model is thus develo...
Autori: Seyed Hesameddin Anvar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27610

The mineralization of azo dyes could be realized through solar photocatalytic degradation that is a green method where non-harmful end products are produced. The aim of this study was to investigate the mineralization of Orange G (OG) and New Coccine (NC) using ZnO as catalyst. The degradation of the azo dyes was conducted at different experimental conditions, and parameters such as effect of sunlight to the degradation rate, initial azo dye concentration, amounts of catalyst dosage, pH and effe...
Autori: Wan Fadhilah Khalik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27643

Recycling of solid plastic waste composed of post-consumer mixed polyolefines (polypropylene and polyethylene) was carried out by injection moulding of secondary material streams. The materials have been characterized by melt flow index (MFI), tensile, bending and impact measurements, density and differential scanning calorimetry (DSC). The sink-float technique was used to separate the polyethylene fraction, which was then blended into virgin polyethylene at different ratios and processed anew. ...
Autori: Laurens Delva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27646

This study concerns the effectiveness of helminth eggs elimination during co-composting of activated sludge from a wastewater treatment plant mixed with ligno-cellulosic waste in a ratio of either 1/3-2/3 or 1/2-1/2 for 180 days. The Analysis of the initial sludge showed a load of 4-27 nematode eggs /g fresh matter identified as Ascaris sp., Capillaria sp. and Trichuris sp. During the co-composting stabilization phase, the reduction of the number of eggs varied between 50 and 90%. At the end of ...
Autori: Loubna El Fels
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27650

This study presents a Rough Set Analysis (RSA) application, partially based on dominance in relation to air micro-pollution management in an industrial place with a high environmental risk rate, such as the industrial area of Siracusa, located in the South of Italy. This new data analysis instrument has been applied to different decisional problems in various fields with considerable success. Therefore, it is believed that it could also be used for the environmental issue related to multi-att...
Autori: Agata Matarazzo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27663

Organoarsenic compounds are used extensively as swine feed-additives to promote animal growth and control diseases, e.g. roxarsone (4-hydroxy-3-nitrobenzenearsonic acid) and arsanilic acid (4-aminophenylarsonic acid) are usually overused in swine industry in China. As a cost-effective technology for animal manure treatment and reuse, composting is widely used for swine manure treatment. Therefore, the purpose of this study was to investigate changes of arsenic species and fractions during a full...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27683

Industrial wastewater is of particular importance. In most wastewater treatments, physicochemical parameters are used to determine the performances which are costly while protozoa can be used as less expensive biological indicators to determine the efficiency of the treatment plant. The purpose of this study was to investigate the relationship between protozoa and physic-chemical characteristics of the Abadan wastewater treatment industry. Samples were collected from wastewater stabilization po...
Autori: Abotaleb Bay
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27694

Monitoring of air emission and pollution control cost is a key to improve air quality management of electricity generation industry. This research comprehensively evaluates abatement cost of sulfur dioxide (SO2), nitrogen oxides (NOx), emission intensity and emission inventory of sulfur dioxide (SO2), nitrogen oxides (NOx), particulate matter (PM), and carbon dioxide (CO2) emitted from Thailand’s fossil fuel power plants. The research applied bottom-up approach with continuously monitored ...
Autori: Wasin Pinprateep
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27740

The development of Multi-Energy Systems (MES) or District Energy Systems (DES) requires suitable design and operation optimization tools, in order to assess their feasibility and economic profitability. These tools can be helpful in choosing the proper technologies and also in the perspective of defining proper incentive or taxation schemes. A critical result of the analysis of MES is that, when optimizing their design, the operation strategy and the part load behavior of the units must be consi...
Autori: Matteo Zatti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27795

The development of Multi-Energy Systems (MES) or District Energy Systems (DES) requires suitable design and operation opti-mization tools, in order to assess their feasibility and economic profitability. These tools can be helpful in choosing the proper technologies and also in the perspective of defining proper incentive or taxation schemes. A critical result of the analysis of MES is that, when optimizing their design, the operation strategy and the part load behavior of the units must be cons...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27796

The development of Multi-Energy Systems (MES) or District Energy Systems (DES) requires suitable design and operation opti-mization tools, in order to assess their feasibility and economic profitability. These tools can be helpful in choosing the proper technologies and also in the perspective of defining proper incentive or taxation schemes. A critical result of the analysis of MES is that, when optimizing their design, the operation strategy and the part load behavior of the units must be cons...
Autori: Marco Migliore
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27803

This paper exposes the research activities regarding REBAF (Energetic Recover of River Biomasses) project, focused on the maintenance operations self-sustainability of the Secchia river (Italy). Poplar was found as the most abundant and representative wood plant of Secchia riverbanks, with a good behavior during gasification process: from 1 hectare of maintenance every three year, it was possible to produce 23 MWh of electrical power and 31 MWh of thermal power. The biochar obtained was characte...
Autori: Vittorio Vezzali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27804

Electrochemical behaviour of YBaCo2O5 perovskite in alkaline solution was studied during oxygen insertion/release process. In correlation with electrochemical studies was analyzed the compound morphology and structure. Compound electrochemical oxidation consists in intercalation of oxygen atoms in crystalline structure, which is equivalent with a structure compaction. These results were correlated with the Brunauer-Emmett-Teller (BET) surface area of sample and also with SEM pictures. Compactio...
Autori: Mircea Dan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27866

The Eco-Indicator 99 (EI99) method and the ReCiPe method are used to determine the fundamental uncertainties in the life cycle impact assessment (LCIA) model through the configurations of the following six methodological options: egalitarian/egalitarian (e/e), egalitarian/average (e/a), hierarchist/hierarchist (h/h), hierarchist/average (h/a), individualist/individualist (i/i), and individualist/average (i/a). In this study, the aforementioned options were presented as (i) a set of methodologica...
Autori: Oleg Verbitsky
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27839

This study emphasis the hydrogen fermentation from de-oiled Jatropha waste (DJW), a secondary and promising waste from biodiesel industry via influence of various combination of heat pretreatment using sewage sludge as inoculum. Batch experiments were carried out at a DJW concentration of 50 g/L, temperature of 55oC and an initial cultivation pH of 7. The peak hydrogen production rate and hydrogen yield of 16.3 mmol H2/L-d and 1.10 mmol H2/g volatile solids (VS), respectively, were obtained ...
Autori: Gopalakrishnan Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27874

In this study, Mg-doped ZnO nanoparticles with 2% Mg content were synthesized by sol-gel method. The structure and morphology of the nanoparticles were characterized by TEM, BET and UV-Vis absorbance techniques. From TEM image, it was found out that the nanoparticles had uniform size and uniform distribution. BET analysis revealed that in comparison with pure ZnO, Mg 2%/ZnO nanoparticles had a higher specific surface area. Based on UV-Vis absorbance analysis, Mg 2%/ZnO nanoparticles shifted t...
Autori: Nahide Zarei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27909

The proper evaluation of soil resources, especially in mountainous areas, is very important for the suitable development of the local communities, which host traditional sustainable agriculture. Nonetheless, regarding the preservation of traditional sustainable agriculture and the introduction of a modern development plan to the area, an actualized and detailed distribution of soil cover is crucial. Soil legacy data is not always available at the right scale and spatial cover. To overcome suc...
Autori: Mihai Niculiță
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27919

In this study we investigated the possibilities of using recyclable fine and coarse grain waste obtained by grinding Polyethylene Terephthalate (PET) containers, as light filling materials for different applications (clay dams, highway embankments, and backfills behind retaining structures. Various geotechnical tests were performed on clayey soil and soil-PET mixtures using recycled fine and coarse granules of Polyethylene Terephthalate bottles. The results indicated that the use of the recyc...
Autori: Osman Gunaydin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27920

Atrazine is a herbicide used widely with a large quantity in Thailand and can contaminate in surface and groundwater. This work investigated atrazine removal from an aqueous solution by catalytic photodegradation using oxides of metal-cerium-zinc (M-Ce-ZnO, M = Ag, Fe, and Cu). ZnO is texturally modified with sticky rice starch template, doped with cerium (Ce) and either Ag, Fe, or Cu with the M:Ce:Zn molar ratio of 0.005:0.005:1. The catalysts were characterized by XRD, UV-Vis-DRS, and N2 adsor...
Autori: Pummarin Khamdahsag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27974

Nanoparticles (NPs) have recently been concerned as emerging contaminants. Determination of NPs in different environmental compartments is a revealing topic for researchers studying their impacts in nature. Various methods of analysis have been reported in literature for their measurement and recovery. However, there are difficulties in their quatification in landfill leachate. Taking into account varying landfill components and their possible interactions with NPs, different types of NPs wer...
Autori: Ceyda Senem Uyguner-Demirel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27989

Inorganic thermal insulators are commonly used to improve energy efficiency. However, environmental and health aspects of their production until the end of life have been increasingly concerned. Agricultural wastes including rice straw, rice husk and corn cobs are abundant in Thailand and converted into value-added products such as thermal insulation materials offers a viable recycling opportunity as the ecological burden of a product has now become a widely-discussed issue. In this paper, gl...
Autori: Phairat Usubharatana
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28033

Substantial quantities of toner cartridges are produced and used in photocopiers and printers every year. Spent toner cartridges are classified as hazardous waste because they contain toner powder with specific chemical composition, making a recovery of waste toner cartridges a very important issue from the aspect of waste management and environmental protection. Spent toner cartridges are mechanically processed to exploit valuable materials such as metals, plastics and magnets and to separate t...
Autori: Ivana Melnjak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28053

A simultaneous hierarchical classification of groundwater in the Banat Plain-southwestern Romania and associated characteristics such as As(III), As(V), total As, trace metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn), pH and redox potential using Fuzzy Hierarchical Cross Clustering Algorithm was carried out. In samples containing more than 10 μg/Ltotal As (13.9 – 77.3 μg/L), the As(V) species represented 57±20% and 73±18% in the others. Arsenic speciation pattern was in agr...
Autori: Marin Senila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28059

Iodine is an essential microelement required by humans and animals. Leaching of soils under intensive rains has threatened the fertility status of iodine in soils. Therefore, four discrete amendments were used for the mitigation of iodine leaching from soils. For this study, soils collected from four land uses were mixed with the amendments (gypsum, lime, fly ash, charcoal and sawdust) at the rate of 0, 2.5% and 5% (w/w) in PVC columns. Potassium iodide (KI) was applied to the soil at rate of 10...
Autori: Muhammad Mohiuddin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28071

This research is intended to study the possible transfer of the residual chemical contamination from treated wastewaters reused for irrigation purposes of Fragaria x ananassa strawberry (cv. Camarosa). Different sewages from urban, and mixed urban-textile origins treated according to different treatment trainswere used for the irrigation of strawberry in pots. Organic and inorganic chemical contamination indicators, i.e.: PCBs, including dioxin-like congeners, PAHs, and Cr(VI), were monitored al...
Autori: Luca Rivoira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28075

This manuscript presents the bicriteria optimization of a polygeneration system to be installed in a tertiary sector building, considering economic and environmental objective functions. Electricity, hot water, steam, and cooling demands were considered. The bicriteria problem considered the annual costs and the annual carbon footprint. Updated environmental information was obtained through the application of the Life Cycle Assessment methodology and implemented within a Mixed Integer Linear Pr...
Autori: Bruno Campos Teixeira de Carvalho
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28103

In Spain, most substrates used in the production of plants in containers, are composed of peat in combination with other components such as pine bark, perlite or vermiculite. In order to find alternatives to the use of peat, shredded switchgrass (Panicum virgatum L.) biomass was evaluated as a component of the substrates. Five substrates were prepared with the following proportions, by volume, of commercial substrates:switchgrass: 100/0, 75/25, 50/50, 25/75 and 0/100. Pots were filled with the ...
Autori: Jose Alberto Oliveira Prendes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28134

Molybdate anions are used in a lot of fields and represent an essential trace element for plant and animal life; however, excessive amounts can cause adverse effect on various organism and environment. Therefore, in the present paper the adsorption performance of MgnFe- layered double hydroxides in the removal process of molybdate from aqueous solutions was studied. The layered double hydroxide (LDH) was synthesized by co-precipitation at low oversaturation method. Different ratio between Mg and...
Autori: Alin Golban
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28152

This work seeks to develop a suitable heavy metals precipitation modeling approach that could give reasonable results in mainstream use with industrial wastewater treatment. This paper is devoted to the thermodynamic analysis of the degree of precipitation of slightly soluble hydroxides and salts in industrial wastewaters in order to optimize the technological schemes of extraction and reuse of heavy metals from industrial waste. Based on the notion of the solubility product, the equations desc...
Autori: Igor Povar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28156

The pyrolysis of frying palm oil was studied in continuous stationary process, in a micropilot plant. The main factors affecting the products yields are temperature and residence time. For the studied parameters range (temperature: 475oC - 630oC and residence time: 120 s- 240 s), the gas yield varied between 7.9% (w/w) and 63.3% (w/w), related to feed. Unsaturated hydrocarbon yields (olefins) can reach 24-29% (w/w) related to feed, at the right processing parameters, the main products having goo...
Autori: Ana Maria Sivriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28162

The goal of this paper is to contribute to environmental improvement. This goal has been achieved by the development of an algorithm that allows the optimization of fuel consumption and transport of combustion products. The paper considers the outlier – robust recursive algorithm. This algorithm is used for identification of multivariable ARMAX (Autoregressive Moving Average with Exogenous Variables) models. In this paper, we introduce pseudo-Huber loss function which is a continuous nonli...
Autori: Vojislav Filipovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28167

The efficiency of drainage installed in clay soils using ditch backfill of soil mixed with lime is presented in this paper. The drainage ditch backfill was mixed with lime where 0.6% of soil matter consists of active CaO. The paper proposes a methodology that determines an optimal amount of lime. The experimental site was set in Kalnujai, Raseiniai district, Lithuania. The measurement of filtration in drainage trench, the arable layer and the soil between drains was performed using a double r...
Autori: Mindaugas KlimaĹĄauskas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28177

Biological ammonium removal from wastewater requires coupling of nitrification and denitrification processes in respective aerobic and anaerobic conditions. This difference in environmental requirements pose a big challenge in the design of systems intended to effect both nitrification and denitrification processes. Alcaligenes faecalis strain No. 4, however, has both heterotrophic nitrification and aerobic denitrification abilities in aerobic conditions, eliminating the need to provide anaerobi...
Autori: Hung-Soo Joo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28186

Inorganic ceramic materials is receiving more attention in recent times due to their unique characteristics which include different pore structures, hydrophilic surfaces, high chemical, thermal and mechanical stabilities that offer avenues for application in water treatment. In the present work, cost-effective clay ceramic water filters of different designs were developed from clay (50, 60, and 70) %, sawdust (15, 20, 25, and 35) %, grog (5, 10 and 15)% ratios plus 5% bone char by volume and ...
Autori: Enyew Amare Zereffa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28196

Ametryn (2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine), a herbicide present in different type of wastewater was treated using the anaerobic-aerobic batch reactor in the presence of anthraquinone-2,6-disulphonate (AQS) as a redox mediator. The anaerobic co-treatment process was conducted for an influent ametryn concentration of 8-10 mg/L during 280 days in previously acclimated biomass. Different intermediate compounds of ametryn were identified in the anaerobic effluent using the...
Autori: Mahesh Chandra Chattopadhyaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28245

Three scenarios for the management of Municipal Solid Waste (MSW) produced in the study area of Bari (Southern Italy) were defined and evaluated in terms of separately collected material and fate of the residual fraction. The first scenario represented the bring points MSW separate collection system in the current configuration with a collection rate approx. 40%. The second scenario considered the study area in the optimal configuration, with a percentage of separate collection > 80% obtaine...
Autori: Sabino De Gisi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28293

Groundwater at an abandoned industrial area near Bergamo, Italy, was historically contaminated by tetrachloroethylene (PCE) (>100 μg/L) and, to a lesser extent, by trichlorethylene (TCE), dichloropropane (DP) and 1,1,2,2-tetrachloroethane (R-130). A liquid reagent (EHC® Liquid) was selected for remediation of groundwater at the site. The reagent is provided in two parts: EHC® Liquid Mix (a soluble organo-iron salt), and ELS® Microemulsion (a lecithin-based carbon substrate), a...
Autori: Alberto Leombruni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28300

Healthcare wastes are produced from all medical and therapeutic activities in hospitals and healthcare centres. Around 15-20% of these wastes are classified as infectious wastes that could be hazardous. Therefore, an effective approach is required for handling costs and environmental issues. In this paper, a bi-objective Mixed-Integer Linear Programming (MILP) model is presented for logistics of infectious and non-infectious wastes. The proposed bi-objective model aims to minimize network costs ...
Autori: Mohammad Nikzamir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28314

Zinc oxide and strontium doped zinc oxide nanoparticles were synthesized through hydrothermal route. The synthesized nanoparticles were characterized by UV, FTIR, SEM, X-Ray diffraction (XRD) and energy dispersive x-ray (EDX) spectroscopic techniques. The optical band gaps were calculated to be 3.16EV and 2.90EV for ZnO and Sr-ZnO nanoparticles, respectively. FTIR confirmed the incorporation of the Sr into ZnO nanoparticles. Average particles size of undoped ZnO and Sr-doped ZnO nanoparticles wa...
Autori: Fazal Akbar Jan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28323

Saline-sodic soil reclamation can be enhanced with a sustainable and environmental approach by using organic waste materials. Moreover, wastewater can be used in leaching processes to protect freshwater resources in regions with water shortages. The aim of this study was to reclaim saline-sodic soil by using recycled wastewater and stabilized sewage sludge together with gypsum. The experiment was designed with three replicates using four different sewage sludge doses (0, 4, 8 and 12 kg m-2), an...
Autori: Almujtaba Hassbalrassol Muhammed Abdallh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28330