AbstractAromatic volatile organic compounds (VOCs) proved to have enhanced polluting behavior upon the atmosphere and human health. Their catalytic destruction is an alternative for environmental pollution reduction in the case of gaseous emissions with low contents of VOC.In this paper, an experimental study is presented, concerning the conversion of benzene and its mono-halogenated derivatives on SCR-DeNOx (V2O5-WO3/TiO2) commercial catalyst, specific for the reduction process of nitrogen oxid...
Autori: Florin Bandrabur, Heinz Koser, Ion Balasanian, Liliana Lazar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25105

AbstractIt was investigated the bioleaching of uranyl ions from uranium ores, in aquatic medium with algae: Scenedesmus quadricauda and Nostoc linkia under different experimental conditions. The oxidation of U(IV) to U(VI) species, like uranyl ions was done by means of the atomic oxygen generated through photosynthesis by the aquatic medium from solution above of uranium ores.After almost 10 days of direct contact with the given microorganisms, it was observed a bioleaching degree between 10% an...
Autori: Alexandru Cecal, Rodica Calmoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25107

A series of new Ni(II) poly-phosphinates have been synthesised using Ni(II) acetylacetonate as nickel precursor and a succession of ligands derived from phosphinic acid: ethyl-butyl-phosphinic acid, ethyl-butyl-thio-phosphinic acid, and respectively ethylbutyl-di-thio-phosphinic acid. Chemical analysis gel-chromatography, infrared spectroscopy (IR), spin electronic resonance (RES), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), electrical resistance measurements at different temper...
Autori: Daniel Sutiman, Doina Sibiescu, , Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25118

This study presents an evaluation of the catalytic performances of Fe containing clay-based catalysts for the wet hydrogen peroxide catalytic oxidation (WHPCO) of 4-chlorophenol (4-CP) aqueous wastes. The catalysts were prepared by well-established techniques, their properties being determined by DRX, BET and chemical analysis techniques. All the tests were performed on a laboratory scale set-up. The ion-exchanged clays were the most active catalysts (100 % 4-CP and 84 % COD removal for Fe-Mt) b...
Autori: , Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25157

In this work, the ability of Romanian peat for sorption of Pb (II) ions from aqueous solution has been determined using the batch experimental techniques. The sorption equilibrium has been studied at different pH values. The equilibrium adsorption level was determined to be dependent of the pH of solution and initial Pb(II) concentration.The equilibrium adsorption capacity of Romanian peat sorbent for lead has been described by seven types of mathematical model isotherms, namely: Freundlich, Lan...
Autori: Brindusa Robu, Corneliu Cojocaru, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25160

AbstractA new photo-Fenton catalyst has been manufactured from synthetic layered clay laponite (Laponite RD) by the pillaring technique Eight different catalyst samples were prepared: four without thermal aging (WTA) calcined at 523 0K, 623 0K, 723 0K and 8230 K, and other four with thermal aging (TA) calcined at the same temperatures. The activity of the TA- 623 sample was evaluated in the phenol degradation by the photo - Fenton process. The influence of five important operating factors has be...
Autori: Beatrice Iurascu, Ilie Siminiceanu, Miguel Vincente
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25210

AbstractThe formation of the polyelectrolyte- surfactant complexes has been studied. On this purpose has been measured the critical micelle concentration for every polyelectrolyte and surfactant which had been used. The phase behaviour of mixtures of a cationic polyelectrolyte (Praestol 611) and an anionic surfactant (sodium lauryl sulphate - SLS) has been studied. For a given polyelectrolyte concentration, with increasing surfactant concentration, three phase regions were identified. The first ...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25214

AbstractThis paper dealt with Cr(VI) sorption on isomorphic substituted Mg/Zn-Al - type hydrotalcites under proper working conditions. The prepared samples were named Mg3Al, Mg2ZnAl, Mg1.5Zn1.5Al, MgZn2Al and Zn3Al. The experimental data concerning sorption isotherms were modelled in accordance with four equilibrium equations: Langmuir (L), Freundlich (F), Langmuir-Freundlich (L-F) and Redlich-Peterson (R-P) by using two ways: (i) estimation of qmax, K and n; and (ii) estimation of K and n, for ...
Autori: Aurel Iovi, Eveline Popovici, Laura Cocheci, Rodica Pode
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25215

AbstractThe absorption of CO2 into an aqueous solution with 1.45 mol/L 1,5,8,12-tetraazadodecane (APEDA) polyamine has been studied at three temperature (298, 313, 333 K) in a Lewis type absorber with a constant gas-liquid interface area of (15.34 Âą 0.05) x 10-4 m2. The experimental results have been interpreted using the equations derived from the two film model with the assumption that the absorption occurred in the fast pseudo- first- order kinetic regime. The results confirmed the validity ...
Autori: Chakib Bouallou, Ilie Siminiceanu, Ramona-Elena Tataru-Farmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25223

AbstractThis paper discusses the applications of synthetic PONILIT GT-2 anionic polyelectrolyte as soil conditioning agent into a site with high electric field around. All experimental data conclude that the use of a polymeric conditioning agent was increased the soil ability to support vegetation expressed as germination degree for some grass species (e.g., Raigras aristat). The performed values for germination degree increase from 3.05 % to 12.20 % when was added fertilized soil, and respectiv...
Autori: Carmen Zaharia, Ioan Ivanov Dospinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25225

AbstractThe mineralization of acidic aqueous solutions with 0.166 to 1.333 mM Crystal Violet (CV) in 50 mM Na2SO4 as background electrolyte has been studied by the electro- Fenton method, where the oxidizing hydroxyl radicals were produced from the Fenton reaction between added ferrous ions and hydrogen peroxide generated at a oxygen- diffusion cathode. The influence of a new operating factor on the mineralization degree has been investigated: anode material (platinum versus boron doped diamond)...
Autori: Carmen-Ionela Alexandru, Eric Brillas, Ilie Siminiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25229

AbstractAluminum and ferric salts are widely used as coagulants in water and wastewater treatment. They are effective in removing a broad range of impurities from water, including colloidal particles and dissolved organic substances. As well as traditional additives, such as aluminum sulphate ("alum") and ferric chloride, other products containing prehydrolized metal ions such as polyaluminum chlorides are now commonly used. The aim of this study was to develop a model for coagulation/flocculati...
Autori: Avid Banihashemi, Manouchehr Nikazar, , Reza Maknoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25230

AbstractThe paper presents new experimental results on the photodegradation of two important phenyl urea herbicides in water: Monuron and Isoproturon. The photodegradation was performed by two Advanced Oxidation Processes (AOPs): the homogeneous photo- Fenton process (, UV-H2O2 - Fe3+) and a heterogeneous photo - Fenton reaction using an iron pillared Laponide- RD catalyst (Fe-Lap-RD). The Fe-Lap-RD catalyst was prepared from iron nitrate 0.2 M solution and a suspension of Laponite - RD clay. Th...
Autori: Elsa Lundanes, Ilie Siminiceanu, Maria-Magdalena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25234

AbstractThe removal of formasine fines particles from water by precipitation with polyelectrolyte and surfactant complex of Polyacrylamide (industrial product Praestol 611 made by Degussa) and Sodium Lauryl Sulphate (SLS) was experimentally studied. Calcium oxide was added to initiate precipitation of the polyelectrolyte complex together with the fines particles. The experiments were carried out with complexes having the surfactants concentration higher then the critical aggregation concentratio...
Autori: Cristina Costache, Gabriel Dabija, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25238

AbstractThe health effects caused by air pollutants may range from slight biochemical and physiological changes to difficulty breathing, wheezing, coughing and aggravation of existing respiratory and cardiac conditions. This paper presents an experimental study of air quality in the city of Tg. Jiu, Gorj County, by evaluating the air-floated powders of the PM10 fraction and lead from air. The analysis was performed by measurements in sampling points using the method presented in the European Nor...
Autori: Camelia Capatana, Claudia Maria Simonescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25247

AbstractThis paper deals with a statistical treatment applied to the determination of U(VI)/U(IV) ratio in some uranium ores, depending on the pH and humidity samples taken out directly from a uranium mine. The concentrations of different uranium species were determined spectrofotometrically. Some statistical parameters were calculated for a subsequent statistical interpretation of the experimental data....
Autori: Alexandru Cecal, Gabriel Barbir, Marian E. Răileanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25255

AbstractThe paper reports experimental refractive indices of binary systems iso-propanol - water and iso-propanol - toluene over the entire range of composition at different temperature. Excess refractive indices were evaluated from the experimental data obtained. This derived property was fitted to variable-degree polynomials. The results obtained have been discussed and interpreted in terms of the type and nature of the specific intermolecular interactions between the components....
Autori: Catalin Lisa, Cerasela Huhurez, Gabriela Lisa, Ramona-Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25256

AbstractIn this paper, the study of synthesis and stability in aqueous solutions of new coordination compounds of Ti(IV) and Zr(IV) with ligand N-hydroxy-succinimide is presented. The salts: TiOSO4¡2H2O and ZrOCl2¡8H2O used for obtaining the studied coordination complexes, can derive from recycling metallic residues resulted in mechanical technologies applied for titanium and zirconium in S.C. ZIROM S.A. Giurgiu.The new complexes were synthesized in aqueous solutions and stability were study u...
Autori: Adrian Cailean, Daniel Sutiman, Doina Sibiescu, Gabriela Apostolescu, Ioan Roşca, Marian Crudu, Mihaela Vizitiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25265

AbstractConsidering that three-phase dispersions are common in chemical engineering and biotechnology, and with increasing airlift reactor applications to chemical and biotechnological processes, a experimental study was undertaken in order to investigate the liquid phase hydrodynamics and dispersion in an external-loop airlift reactor on laboratory scale. Experiments were conducted in order to find a relationship between relevant hydrodynamic and mixing parameters of a solidsuspended exter...
Autori: Florina Ungureanu, Maria Gavrilescu, Radu Z. Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25268

AbstractCatalytic combustion of methyl isobutyl ketone in diluted air streams over Pt/Al2O3 commercial catalyst was experimentally investigated. The experiments were carried out at space velocities between 180 000 - 600 000 cm3/ (gcat¡h) and ketone concentrations in the range of 900 - 2600 ppmv. On the studied domain of working parameters, carbon monoxide was not detected, although some organic intermediates were formed (especially acetic acid). Their presence was detected in the product mixtur...
Autori: Anamaria Soare, Cristina Gheorghiu, Grigore Bozga, Magdalena Boşomoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25271

AbstractTheoretical and experimental studies of gas drying processes by adsorption in fixed bed of grains are presented in this paper. Based on an extensive literature study, some of the most representative mathematical models describing gas adsorption in fixed bed and consequently gas drying processes by adsorption in fixed bed are also presented. Using a mathematical model from those mentioned describing adsorption under isotherm regime, the temperature and gas flow velocity effects over the d...
Autori: Marius Sebastian Secula, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25272

AbstractThis paper presents experimental and theoretical studies regarding the behavior after heat treatment of an AlCu4Mg1 aluminum alloy with positive effect on corrosion resistance. On the basis of these experiments and the regression data obtained, an analysis regarding the influence of heating parameters on quenching and aging in order to obtain a certain stress was made. Two cases were considered: stress and quenching temperature are fixed and aging temperature was determined; stress and a...
Autori: Adrian Dima, Alina Adriana Minea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25281

AbstractThe corrosion resistance of three types of low-carbon steels in water-contaminated mixtures of adipic acid and methanol was investigated. The concentration of water in the organic mixture was progressively raised from 1% to 5%, while the carbon concentration in the steel samples varied from 2% to 4%. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were used to investigate the insoluble corrosion products. Based on the weight losses measurements, on the polarization curves and on t...
Autori: Adrian Cailean, Daniel Mareci, Daniel Sutiman, Mircea Teodor Nechita
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25287

Abstract In this paper preliminary results of studies concerning the extraction of uranium(VI) from soils in aqueous PEG (1550) 20 % - Na2SO4 20 % - Na2CO3 10-2-10-3 M two-phase systems are presented, as well as the spectrophotometric determination of extracted uranium with pirocatechol violet (PV). A special attention was given to the experimental factors (pH, redox potential, CO32- anion concentration and initial uranium concentration), which was found to influence both the formation and stabi...
Autori: Daniel Condorachi, Doru Juravle, Dumitru Bulgariu, Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25290

AbstractThe possibility of biological phosphorus removal (BPR) was studied using a lab-scale single reactor the same as SHARON process. Up to now, there has been no investigation of the feasibility of SHARON process for the purpose of phosphate removal. The optimal operation conditions were established to obtain highest removal rates. Under the experimental conditions, the phosphorus concentration dropped from an influent concentration of 1000 mg/L to levels around 0.1 mg/L or less. It was concl...
Autori: Abbas Rezaee, Hatam Godini, Masod Solimani, Nayera Nami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25293

AbstractBiosorption an alternative process is the uptake of heavy metals from aqueous solutions by biological materials. The biosorption of nickel ions from aqueous solution was investigated by Nordmann fir (Abies nordmanniana (Stev.) Spach. subsp. nordmanniana) in a batch adsorption system as a function of pH, initial metal concentration, biomass dosage, contact time. The data showed that the maximum pH for efficient sorption of Ni(II) was 6.5. At the optimal conditions, Ni(II) ion biosorption ...
Autori: Handan Ucun, Ozkan Aksakal, Yusuf Kaya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25295

AbstractThe use of composite fuels using pitcoal and sawdust represents a high perspective. The paper deals with the experimental results focusing on the combustion efficiency of composite fuel briquettes and on the polluting emissions level. A special care is given to the determination of boiler efficiency and to the establishment of exploiting economic conditions, like the supply, cleaning etc. The research of the combustion of pitcoal-wood biomass briquettes is conducted on a 55 kW boiler.A n...
Autori: Gabriel Negreanu, Gheorghe Lăzăroiu, Ion Oprea, Ionel Pisa, Lucian Mihăescu, Radu Indries, Tudor Prisecaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25301

AbstractThe aim of this paper was to accurately analyze the sources of water pollution and loading concentrations in textile finishing mills. A process data collection was performed and integrated with a characterization of the process effluents in terms of treatability and reusability. In order to evaluate properly the wastewater loading, an analysis course was set. The samples have been gathered for two months; instantaneous samples (PI) were drawn from the wastewater, as well as from the pain...
Autori: Irina-Isabella Savin, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25314

AbstractThe work presents the negative environmental impact produced by an extraction of crude oil activity. To highlight and quantify the negative effects on the environment produced from such activity, the experimental part has been focused on evidence of samples of soil, water from groundwater aquifers and surface, and the air emissions. The values of quality indicators are presented in graphs and tables, highlighting an activity with all major impact on the environment....
Autori: Aurica Grec, Corneliu Maior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25326

AbstractDrinking water treatment plays an important role in maintaining public health. Chlorine is the most often disinfectant used for microbiological protection of water. Required residual chlorine concentration must be in treated water when it leaves treatment plant, to comply with the regulations. The chlorine residual must be 0.5 mg/L at the entrance into the distribution system and 0.25 mg/l at consumers, according to the law. Any less and there is no guarantee that the water has adequate ...
Autori: Dan Robescu, Diana Robescu, Nicolae Jivan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25328

AbstractOn the top of the ecological priority list in Romania, waste management is on the third place following the problems regarding the surface and underground water pollution, as well as that of the atmosphere. The clean-up of the landscape represents an issue largely discussed in Romania. The paper presents the advantages of waste management for the landscape, which includes: waste gathering and transfer, waste selection, waste biological treatment and the storage.Some analyses of the const...
Autori: Camelia Capatana, Claudia Maria Simonescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25331

AbstractIn this paper the results of surface water treatment process for drinking purpose are presented, using the microfiltrationultrafiltration process. The experimental studies were carried out using a microfiltration-ultrafiltration pilot plant and raw water from Bega River, Timisoara as feed. To assess process performance, the water quality, e.g., turbidity, total coliforms and hardness parameters were determined for two different operating regimes subjected to filtration time. A good effic...
Autori: Camelia Podaru, Cristian Danielescu, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Viorel Patroescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25332

AbstractTwo non-functionalized hypercrosslinked polymeric resins type Macronet (MN 202 and MN 250) were employed to remove nhexane vapors from gas phase. A comparison of the equilibrium behavior of these hypercrosslinked resins and a bituminous granular activated carbon was made. The initial n-hexane concentration in the air stream ranged from 2100 to 4500 ppm and the adsorption temperatures were 30oC, 40oC and 50oC. The results showed that the MN 250 presents the higher adsorption capacities of...
Autori: Adela Marilena Buburuzan Haleta, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25341

AbstractAn experimental three-stage subsurface flow constructed wetland system was investigated for the removal of nutrient and organic matter from primary-treated domestic wastewater. Built in the Turkey Scientific and Technical Research Council-Marmara Research Center, Gebze, Turkey (Istanbul), the system consisted of a vertical flow-gravel filtration in the first stage, a horizontalsubsurface flow bed vegetated with Iris in the second stage, and a vertical-subsurface flow bed vegetated Phragm...
Autori: Bilal Tuncsiper
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25358

Include urmatoarele articole:� CsHSO4/mesoporous silica composites - new electrolytes for solid acid fuel cells� Trend in exhaust emissions from in-use gasoline vehicles� Analysis of distribution of oxygen transfer rate in stirred bioreactors for bacterial broths� Electrochemical characteristics of Ti6Al7Nb alloy in Ringer's solution� Pulsed high voltage discharge technology as a new method for killing Hepatitis C virus (HCV) cells� Hydrodynamic modelling of pollution with LNAPL gene...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25367

â€? Bioremediation of contaminated air using a bioscrubberâ€? Quality risk evaluation of the groundwater resources on the moldavian areaâ€? Electrochemical characterization of some dental materials in accelerated environmental testingâ€? Preliminary study of simple and Fenton oxidation with hydrogen peroxide applied on final effluents from a zootechnical farmâ€? The environmental impact assessment caused by the dykes failureâ€? Revaluation of beer industry byproducts – medical implicationsâ€? ...
Autori: http://www.ecozone.ro/reviste.php?RID=25372

AbstractThe lead(II) ions sorption from aqueous solutions on three types of peat from Poiana Stampei (Romania) was studied. The peat was drawing from different deeps, such as 5-10 cm deep (peat 1), 0.5-1.0 m deep (peat 2) and from > 1.5 m deep (peat 3). The influence of several experimental parameters (initial lead concentration, contact time) was studied in batch experiments. The kinetics of sorption was followed based on the amount of lead(II) ions retained at various time intervals. The re...
Autori: Laura Bulgariu, Mioara Răţoi, Dumitru Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25389

AbstractThe paper describes in brief the electro-osmosis process and reviews the possibility to use it in dewatering the pulp and paper waste sludge. The waste sludge main characteristics and dewatering methods from the Vrancart SA factory are revealed. After the experimental method and test bench description, some results from the preliminary laboratory tests on the Vrancart SA sludge are presented and discussed....
Autori: Dorin D. Lucache, Adrian Bulgaru, Dan Ioachim, Elena Danila
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25392

AbstractThe adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated. The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed at 30, 40 and 50 ?C. Thermodynamic potentials ?H, ?S, and ?G and isosteric heats of adsorption were calculated from experiment performed at different temperatures (30-50?C...
Autori: Adela Marilena Buburuzan, Cezar Catrinescu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25393

AbstractEquilibrium data of water vapor adsorption from wet air on several materials were experimentally determined at temperature values of 313 and 333 K and air relative humidity values ranged between 30 and 90 %. Experimental data were correlated with Langmuir and Freundlich models. The obtained results emphasize the significant difference between the water retained on the adsorbent materials impregnated with various salt solutions, and on classic adsorbents....
Autori: Ioan Mămăligă, Constantin Baciu, Stelian Petrescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25394

Abstract The efficiency of Cd (II) removal from aqueous solutions was investigated using Sphagnum moss peat as sorbent. A 23 orthogonal central composite design was successfully employed for experimental design and analysis of results. The combined effect of the initial solution pH, peat dosage and initial Cd (II) concentration was studied and optimized using Response Surface Methodology (RSM). The optimum values of these variables were found to be pH = 4.72, 14.7 g peat /L and 13.64 mg Cd /L, ...
Autori: Catalin Balan, Corneliu Cojocaru, Petru Bulai, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25399

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract A set of experimental data resulted from environmental monitoring and its informational content has to be revealed and checked for its statistical character. As a result in this paper the aim was to verify if the environmental monitoring data obtained for a specific air pollutant monitored during three years presents statistical properties. Based on the results obtained by applying statistical requirements such as fixed location, fixed variation, randomness and fixed distribution, a ...
Autori: Irina Meghea, Mihaela Mihai, Ioana Lacatusu, Tiberiu Apostol
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25410

Abstract The preparation of microspheres containing chitosan, sodium alginate and ibuprofen and the pH dependent drug release were investigated. The microspheres were prepared by two experimental routes: the first one starting with a chitosan/ibuprofen core subsequently coated by an alginate shell (S1) and the second one based on an alginate/ibuprofen core, later coated by a chitosan layer (S2). The physical-chemical characterization was done by using Dynamic Light Scattering (DLS), Atomic Fo...
Autori: Luminiţa Elena Balău, Nicolae Aelenei, Marcel Ionel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25412

Abstract The paper presents the capacity of biodegradation of selected microorganism, cultivated on liquid culture media to which diesel was added in different amounts, to determine petroleum products and process efficiency. The optimum necessary conditions for development of microbial strains (pH, temperature, the quantities petroleum product / inoculum) have been established with the help of an experimental optimization program, SIMPLEX....
Autori: Dana-Camelia Cocut, Cornel Cojocaru, Mariana Diaconu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25414

Abstract Study of geopolymer is a developing field of research for capitalizing solid waste and by-products in the view of new materials achievement having characteristics necessary for using as cement substitute. Also, it provides a solution to many problems regarding environment, such as reduction of gaseous emissions and particles matter resulted from cement industry and raw materials economy. In this paper, the experimental conditions for obtaining new materials on the basis of fly ash f...
Autori: Maria Harja, , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25419

Abstract The paper highlights the combustion possibilities of crude vegetable oils as fuels for stationary application. This is an opportunity of a new utilization in Romania of tee vegetable oils, for electricity production and heating systems, instead of the current situation of using in transportation as biodiesel fuel. The research focuses on crude vegetable oils obtained from some indigenous cultures: rape, soy, sunflower. An overview of the agricultural potential of oleaginous plants is...
Autori: Ion Oprea, Ionel Pisa, , Tudor Prisecaru, Gheorghe Lazaroiu, Gabriel Negreanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25424

Abstract Changing the working space by introducing some radiant panels has the purpose of intensifying the heat transfer by convection and radiation. By centralizing the experimental results, has been obtained an energetic saving of 28.67 – 32.74 % by using radiant panels; the heating speed of the charge raises with almost 50 % and the heating time of the charge decreases. In conclusion, changing the working space by introducing some radiant panels inside the furnace leads to important ener...
Autori: Alina Adriana Minea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25426

Abstract The photocatalytic degradation of sulfamethazine, a sulfonamide drug, has been investigated experimentally, in aqueous heterogeneous solutions containing n-type oxide semiconductors as photocatalysts, and by simulation, using neural network modeling. Through direct neural network modeling, the evolution of the photocatalytic oxidation process is evaluated as function of illumination time and type of catalyst. Inverse neural network modeling is a particular optimization that gives inf...
Autori: Ciprian George Piuleac, Ioannis Poulios, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25430

Abstract The paper presents the preliminary experimental results performed at laboratory scale set-up for different combined mechanochemical treatments of final effluents from a zootechnical farm from the central Moldavian region of Romania. Because of the high content of pollutants into wastewaters, the soil can be polluted and also the ground waters. To avoid this soil pollution episode, some combined mechano-chemical processes were studied and applied into a specific technological order as...
Autori: Carmen Zaharia, Mioara Surpăţeanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25434

Abstract This work investigated the sorption removal of chromate anion, in single batch systems, from aqueous solutions. The process involves the sorption of the chromate by a series of Mg/Zn-Al - type hydrotalcites, with four Mg/Zn/Al ratios, in two forms: uncalcined and calcined at 500 °C. The calcined Mg-Al (Mg/Zn/Al = 2/0/1) material showed the highest sorption capacity: 35.7 mg/g. The three-parametered Langmuir-Freundlich model approximated the experimental equilibrium data over the con...
Autori: Laura Cocheci, Rodica Pode, Eveline Popovici, Emiliana Dvininov, Aurel Iovi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25461

Abstract In designing an efficient photovoltaic system, the meteorological data of the system location must be considered. Field data registered over years prove the importance of the implementation site characteristics in the design and optimal exploitation of a PV system, because wetting and atmospheric gaseous and particulate pollution can strongly distort the incident solar radiation. Thus, in addition to the efficiency of the solar module, the tracking efficiency, the clouds crossing fac...
Autori: Dorin Valentin Diaconescu, , Ioana Sinziana Hermenean, Maria Monica Vatasescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25464

Abstract This paper presents an experimentally study of the anionic iodide separation from a mixture with immobilized liquid membrane. The experiments were carried out in a double jet installation. In order to intensify the transfer of iodide ions from the source phase to the receiving phase, the both phases are dispersed as droplets in the membrane and the hydrodynamic parameters of the dispersed phases are measured with the photographic method. The photos of the droplets were taken with a C...
Autori: Mihaela Emanuela Craciun, Mihaela Mihai, Gheorghe Nechifor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25476

Abstract The paper proposes itself to present some aspects about woody biomass as renewable source of energy and about one of the main product namely wooden briquettes. There will be put the accent on physical features of wooden briquettes namely its density but there has be not forgotten the ecological influences. It is also stated the conditions of experimental, type of machine that is used in laboratory experiments, type and feature of raw material and wooden briquettes. Finally some condi...
Autori: Aurel Lunguleasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25491

Abstract Phenols and chlorophenols are contaminants in soils, sediments, surface waters and groundwater, largely because of their worldwide utilization in the last 50 years as wood preservatives and general biocides in industry and agriculture. The toxicity of chlorophenols and their persistence in the environment require advanced treatment techniques for their removal. This study presents the results of a comparative evaluation of the adsorption of phenol and 4-chlorophenol from aqueous sol...
Autori: , Cezar Catrinescu, Roxana Elena Apreutesei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25497

Abstract It is known that carbonhydrates are precursors of all bioactive substances we tried in thes paper work to do some investigation on these substances in the environmental area of Iasi. To observe the influence of some chemical mutagens substances on carbohydrates biosynthesis we conducted investigations on plant material (leaves) taken from the Calendula officinalis L species. We used this assay to examine the effects of the herbicide 2,4- dichlorophenoxyacetic acid (2,4-D), etidium br...
Autori: Constantin Leonte, Roxana Vatavu, Teodor Robu, Irina Volf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25502

Abstract The paper presents the experimental results, obtained using a pilot installation and hot-water boilers for reducing the pollutants emissions in combustion of heavy liquid fuels by using of additives for catalyzing of burning processes. The experiments were made using additives based on iron and cerium carboxylates. Experimental results, which are presented both in variant of heavy liquid fuels burning with additives and without additives, highlight the reducing of pollutants emissio...
Autori: Aurel Gaba, Stefania Iordache, Mircea Vladescu, Dan Ungureanu, Petrica Vizureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25509

Abstract This paper presents preliminary results of a batch-scale study assessing the contribution of the multiple phenomena involved in siloxane removal in three-phase biomatrices. Batch scale experiments were undertaken in shaken flasks containing acclimatised culture medium, solid media and siloxane vapours (octamethylcylotetrasiloxane and decamethylcyclopentasiloxane, respectively) under anaerobic gas-phase conditions. Abiotic and biotic phenomena, considered to be possible siloxane remov...
Autori: Gabriela Soreanu, Patricia Falletta, Michel Beland, Kara Edmonson, Peter Seto
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25510

Abstract The individual physical, chemical, and biological interactions that determine the exposure of plants and animals to chemicals associated with soils are of great importance in the assessment of contaminants bioavailability. Understanding of bioavailability processes is at last needed to improve the scientific basis of risk assessment and is the purpose of the present research. Since bioavailability processes are embedded within existing human health and ecological risk frameworks, so...
Autori: Brindusa Mihaela Robu, Camelia Smaranda, Florentina Anca Căliman, Laura Carmen Apostol, Lucian Vasile Pavel, Maria Gavrilescu, Raluca Maria Hlihor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25516

Abstract Waste management hierarchy has as priorities waste recycling and energy recovery. Unfortunately, Romania is in the situation so as the waste landfilling is still considered as a suitable solution for waste management. European Union imposed a number of regulations and programs in the field of waste treatment and management that Romania must comply. The paper describes some aspects regarding characterization of the leachate originating from the Tomesti landfill (situated in Iasi County...
Autori: Ana-Maria Schiopu, Brindusa Mihaela Robu, Ion Apostol, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25523

Abstract In the paper is analyzed the possibility of using some industrial wastes for obtaining new building materials. From the industry or from the power station a lot of by-products or wastes have resulted and their storage is a big problem for the environment. In the building material industry a part of these wastes can be used in different ways: for replacing the cement, as addition in concrete, as component of cements, in the mixture of polymer concrete, etc. In the present investigati...
Autori: Marinela Bărbuţă, Nicolae Taranu, Maria Harja
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25525

Abstract In this work the experimental conditions to synthesize, by direct hydrothermal synthesis, self-bonded pellets of ETS-10 phase containing iron were studied. The following gel composition was used: xNa2O-0.6KF-1.28xHCl-yFe2O3-0.2TiO2-1.49SiO2-39.5H2O with 0.8Â???xÂ???1.4 and 0.015Â???yÂ???0.08. The products obtained were characterized through X-ray diffraction on powders (XRD), thermal analysis (TG, DSC, DTG), scanning electron microscopy (SEM) and microanalysis (EDS). The data obtai...
Autori: Pierantonio De Luca, Danilo Vuono, Monica Filice
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25544

Abstract This work presents a global approach of the impact generated in the environment by rubber processing activity. The objective analyzed as a case study is a company that produces rubber tires for trucks and industrial vehicles. The experimental part includes the determination of quality indicators for each environmental factor (air, water, soil) and the evaluation of environmental impact on these factors. Determination of the environmental quality indicators was done by sampling and a...
Autori: Aurica Grec, Florin Dumescu, Corneliu Maior
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25547

Abstract The paper describes the complex research developed within a national research project. The proposed studies and researches are according to the thematic frame of the program cooperation-environment of FP7, whose fundamental objective is related to the natural and anthropogenic environmental problems and resources. Under this context, the project proposes a coherent, conceptual framework for integrated environmental risk assessment and management, generated by the presence of persiste...
Autori: Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25548

Abstract Transferability process identifies the transportation projects which could be implemented successfully in different cities in order to encourage the good practices. This paper proposes a method to evaluate the environmental efficiency of a project by using a hybrid approach based on utility theory and data mining techniques. Transferability principle is applied to show the environmental efficiency of an access controlled area in the hyper centre of two different cities. COPERT III te...
Autori: Catalin Popescu, Luminita Ion, Tatiana Cucu, Jean-Marie Boussier, Augustin Mitu, Daniela Uta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25560

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract The goal of the study was to investigate the sorption behavior of Acid Orange 7 (C.I. 15510) onto soil collected from Iasi area (Romania). The sorption isotherm, kinetic and thermodynamic studies were performed by batch mode. The effects of experimental parameters such as contact time, pH value (2-12) and temperature (20 - 400C) have been studied. Also the influence of initial dye concentration (10 - 100 mg/L) and sorbent dosage (from 5 g L-1 to 150 g L-1) were studied. It was found ...
Autori: Camelia Smaranda, Dumitru Bulgariu, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25566

Abstract In this study the adsorption of cobalt(II) from aqueous solutions on peat (from Poiana Stampei, Romania) activated by simple chemical treatments, was investigated from kinetic point of view. The chemical treatments suppose the mixing of peat with aqueous solutions of common chemical reagents (H2SO4, NaCl and NaOH), without the addition of supplementary additives. An increase of adsorption capacity of peat was obtained in case of treatments with NaCl and NaOH respectively, and this is...
Autori: Corneliu Caramalau, Laura Bulgariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25571

Abstract Heavy metals produced and released by anthropogenic activities generate serious environmental problems. Ions of toxic metals can bind to the mineral surface in a number of ways, including absorption, adsorption, precipitation, ion exchange. The paper shows that the fate and migration of heavy metals in soils strongly depend on the physical properties and chemical and mineralogical composition of such environments. Cadmium is one of the most toxic metals with carcinogenic and teratog...
Autori: Vasile Lucian Pavel, Dumitru Bulgariu, Laura Bulgariu, Raluca Maria Hlihor, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25577

Abstract As a result of the global climatic changes generated by the alteration of the environment through polution, the ecosystems' natural ressources are incontrollably distributed, generating unforseeable effects at the level of the subsequent evolution of the natural balance factors. One of the greatest challenges of the science concerned with environment protection, is that of real time monitoring of the biochemical constitution. The real time monitoring of a great number of biochemical ...
Autori: Andrada Pretorian, Bojin Dionezie, Gabriel Epure, Ion Savu, Lucia Mutihac, Mihaela Muresan, Nicoleta Petrea, Petrisor Zamora Iordache, Razvan Petre, Rodica Lungu, Vasile Somoghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25583

Abstract The removal efficiency of Pb(II) from aqueous solutions by sorption on a bifunctional acrylic ion exchange resin with groups of hydroxamic acid and amidoxime is presented. It was found that Pb(II) sorption potential varies as function of solution pH, initial metal concentration, contact time and temperature. From aqueous solutions with Pb(II) initial concentration of 82.96 ?ŽÂ?g/mL the sorption percentage is 98.64%. The Langmuir and Freundlich isotherms were used to model the Pb(II) ...
Autori: Anca Ceica, Carmen Paduraru, Igor Creţescu, Lavinia Tofan, Violeta Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25586

Abstract Wastewaters of textile and leather dying industries contain significant quantities of water-soluble dyes. Moreover the temperature and pH of these wastewaters may be controlling variables affecting the biosorption performance. In this study the sorption of dark blue dye by Aspergillus biomass and peat was studied as a function of temperature, initial dye concentration, and initial pH values. In addition, the effects of sorbent dosage on the sorption processes were systematically stud...
Autori: Cornel Cojocaru, Cornel Pohontu, Igor Creţescu, Mariana Diaconu, Roxana Elena Benchea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25587

Abstract Anaerobic digestion (AD) is a complex biological system which can be affected by several operational problems. Among them, biological foaming is one of the most difficult to deal with. It has many effects, such as causing gas pipe clogging and probe failures, and it can affect mixing devices, etc. Since the mechanisms involved in biological foaming development are not fully understood, it is not included in standard anaerobic digestion models. For this reason, a knowledge-based risk ...
Autori: Eric Latrille, Ignasi Rodriguez-Roda, Jean-Philippe Steyer, Joaquim Comas, Jordi Dalmau
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25610

Abstract An efficient environmental management system needs some air, water and soil pollution analysis software tools. The paper presents a multi-expert system, SBC-MEDIU, developed for environmental diagnosis. The system has three modules: SBC-AIR, the module for air pollution analysis and dispersion assessments, SBC-WATER, the module for surface water pollution analysis, and SBC-SOIL, the module for soil erosion risk assessments. The experimental results obtained so far are also discussed....
Autori: Daniel Dunea, Mihaela Oprea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25612

Abstract The aim of this study was to assess nitrate removal using impregnated activated carbon (AC) with MgCl2. After impregnating of AC using heat treatment, the MgCl2 is converted to efficient MgO. The denitrification was conducted at pH 6.2, 25?C, and initial concentrations of 20 mg/L nitrate-N. The effects of the operating parameters including AC dosage, pH, and contact time have been investigated. Experimental data show that AC modified by MgCl2 was more effective than virgin AC for nit...
Autori: Abbas Rezaee, Hatam Godini, Sahand Jorfi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25618

Abstract Mathematical modeling of the ultrafiltration (UF) process is motivated by the complexity of retention phenomena that occur during the UF in conjunction with the complexity of wastewater matrices submitted to ultrafiltration, as well as by the need to predict the process behavior in extreme conditions, such as high pollution loads for UF-membrane cleaning cycles optimization or for automated control of the process. Thus, series of laboratory-scale ultrafiltration experiments were perf...
Autori: , George Barjoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25630

Abstract In this study the possibility to apply the oxidation process for treating textile effluents, by using hydrogen peroxide and Fenton process was evaluated through determining the color and chemical oxygen demand (COD) removal. The experimental variables studied include the dosages of hydrogen peroxide and iron salts, oxidation time and pH value. The result showed that oxidation process using hydrogen peroxide alone is inefficient in COD and color removal, since only 25 % of COD removal...
Autori: Abdelnaser Omran, , Marniyanti Mamat Noor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25631

Abstract Equilibrium and kinetics of sorption of Zn (II) ions from aqueous solutions of pH 5 on indigene (Romanian) peat moss were investigated in batch system. The experimental equilibrium sorption data at three temperatures were analysed by Freundlich, Langmuir, Tempkin and Dubinin-Radushkevich sorption isotherm models. Results indicate the following order in to fit the isotherm equations: Langmuir > Tempkin > Dubinin-Radushkevich > Freundlich. The equilibrium sorption capacity determine...
Autori: Angelica Kicsi, Doina Bilba, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25632

? AN ASSESSMENT OF OPERATIONAL PARAMETERS FOR THE REMOVAL OF CHLOROPHENOLS FROM WASTEWATER ? ENVIRONMENTAL SCIENCES: A PSYCHOLOGICAL-BEHAVIORAL MODEL FOR RESEARCHERS ? ECOLOGICAL AGRICULTURE: DYNAMICS OF THE BIOLOGICAL ACTIVITIES IN SOILS CULTIVATED WITH MAIZE UNDER THE INFLUENCE OF ORGANIC FERTILIZATION ? SOLAR-ASSISTED JOULE-BRAYTON ENGINES USED TO REDUCE CARBON DIOXIDE EMISSIONS ? STUDY OF THE ENVIRONMENTAL EFFECTS OF HEATING SYSTEMS ? MIXED JET-VORTEX METHOD FOR ...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25662

The removal efficiency of p-xylene from gas stream was experimentally investigated in a dielectric barrier discharge (DBD) reactor, which was combined with catalyst, MnO2/Al2O3 pellets, in the discharging and the afterglow area, respectively. The CO2 selectivity of the two kinds of structure was also discussed. The results showed that in both the situation, the synergetic removal efficiency of p-xylene by the DBD-catalyst hybrid system increased with increasing the discharge power and decreasing...
Autori: Hongxia Liu, Yun Liuhttp://www.ecozone.ro/reviste.php?RID=25674

A multi-stage filtration system located next to Lushan River in Gaofeng Town of Chongqing, P.R. China was built to indicate the impact of loading rate on agricultural runoff purification performance. The experimental system was proved to be effective in the removal of agricultural non-point source pollutants, and it was adapted to the changes of influent quality and quantity. The average removal rate of chemical oxygen demand (COD), ammonia (NH4 +-N), total nitrogen (TN) and total phosphorus (TP...
Autori: Lei Huang, Xu Gao, Wei-dan Xie, Jun-hong Chen, Xiao-xia Ma, Ming-guo Chen, Jin-song Guohttp://www.ecozone.ro/reviste.php?RID=25682

Fuel injection system, intake system and the geometric shape of combustion chamber are the three key factors to the fuel-air mixture and combustion process for diesel engine. long with the need of high power density in diesel engine, the pressure of intake is higher increasingly. Together with the effect of high pressure fuel injection, the fuel-air mixture and combustion process is hard to spread as usual. In this circumstance, the performance of power, heat efficiency and emission in diesel en...
Autori: Shang Yong, Liu Fu-Shui, Li Xiang-Ronghttp://www.ecozone.ro/reviste.php?RID=25704

Abstract:Drying wood requires a significant amount of thermal energy, in order to heat-up wood and evaporate the water inside it.Therefore, solutions to minimize this consumption are a topic of maximum interest for wood-processing industries. Employingsolar power for drying wood is not a novelty, considering that this possibility was already acknowledged at the end of the 17thcentury, but since then, kiln design was significantly improved, once with the progress of knowledge regarding the mechan...
Autori: Ion Marinescu, Mihaela Câmpean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25727

The permanent magnet EDS train has been considered to be one of the most promising urban transportation vehicles due to its particular characteristics: simple configurations, low energy consumption, low noise, and suitable for high speed conditions. In order to study the characteristics of permanent magnet Electrodynamic Suspension (EDS) system, an experimental mechanism was established in this paper. The optimization of Halbach magnet array has been carried out and appropriate track for the EDS...
Autori: Zhiqiang Long, Guang He, Ning He, Zhizhou Zhanghttp://www.ecozone.ro/reviste.php?RID=25713

Abstract:Point of zero charge (PZC) is defined as the condition at which the surface charge density of a material equals to zero and, formost of the solids it is strongly pH dependent. The PZC can be controlled by tuning the solid surface properties (crystallinestructure, morphology) and by a proper environment control, thus it is important to evaluate the PZC for a certain type of material,in given working conditions, for enhancing the efficiency in the targeted application (e.g. layer by layer...
Autori: Laura Maria Bertus, Radu Adrian Carcel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25721

Abstract:Under the circumstances of the total energetic recourses deficit in the Republic of Moldova appears the problem of non-traditionalsources utilization. An important source of renewable energy is the wind energy. This paper deals with two new concepts ofvertical axis wind turbine (VAWT) with helical blades, elaborated by the authors.The main element of the wind turbine is, certainly, the rotor. It is directly subdued to the action of the air flow and transforms thekinetic energy of the ai...
Autori: Ion Bostan, Ion Vişa, Rodion Ciupercă, Valeriu Dulgheru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25722

Abstract:The operation of solar air heat collectors consists in a sequence of transient regimes, being conditioned by the availability in timeof the solar resource. This paper presents the results of an experimental research on transient regimes of two types of solar air heatcollectors. The absorbers of the collectors have different configurations and are made of different materials. One collector is acommercial passage air collector with the absorber made of aluminum. The other collector is an ...
Autori: Adrian Ciocănea, Andrei Dragomirescu, Sanda Budea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25731

Abstract:The article presents a method of monitoring the solar radiation components taking into consideration the isotropic model. Thewireless solar radiation monitoring system developed is innovative and original in comparison with the systems already availableon the market. The use of the wireless device, of the rechargeable batteries, of the sensors used for measuring the solar radiationcomponents and the temperature make this system an autonomous and a portable one. An experimental prototype...
Autori: Cornel Samoila, Daniel T. Cotfas, Doru Ursutiu, Paul Borza, Petru A. Cotfas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25735

Abstract:The paper presents the results obtained when using one ketonic Mannich base BM (1-(2’-hydroxyphenyl)-3-(1-piperidinylamino)propan-1-one hydrochloride) as corrosion inhibitor in saline environment, for different types of carbon steels,with various alloying elements. The Mannich base was synthesized and used in corrosion experiments, in concentrations varyingfrom 0….1300 ppm. The corrosion experiments were performed by potentiodynamic polarization studies, with 50 mVs-1 scanrate. The ...
Autori: Andreea Milea, Cristina Bogatu, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25754

Abstract:The paper presents a computer modelling and experimental validation for the thermodynamic performance of parabolic troughsolar collectors (PTSC) used in a micro-combined cooling,e heating and power (mCCHP) system. The thermal efficiency, fluidoutlet temperature, heat gain and heat and optical losses of the collector are calculated depending on the collector geometry,optical properties, fluid properties, fluid inlet temperature and flow rate, solar insolation, wind speed and ambient temp...
Autori: Ion V. Ion, Lizica Simona Paraschiv, Spiru Paraschiv
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25760

Abstract:The work presents the results in investigating the thermal behaviour of passive solar elements, for expanding the existing analysisand prediction methodologies. The interest focuses on solar control through natural shading with deciduous plants. This providesa natural path for incorporating all advantages the passive behaviour, available throughout the year. The simulation of thedynamic energy performance of building elements is developed, starting with a physical modelling of the vario...
Autori: Angelos D. Tzachanis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25768

Abstract:In Romania, the small hydro power scheme (mini-, micro- and pico- hydro power) represents a potential renewable energy sourcefor electrical energy. Nevertheless, this small hydro potential must be used efficiently. The paper proposes an innovative e-methodof integrating design with manufacturing, for a small Pelton turbine. The first part presents the application of Rapid ProductDevelopment (RPD) with focus on Product Design (PD) of a new, very small customized hydropower turbine. This ...
Autori: Anisor Nedelcu, Bogdan Deaky, Razvan Udroiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25769

Abstract:The oxidation of low grade complex concentrates (Cu, Pb and Zn) in aqueous media (weak alkaline) oxidized nonferrous metalsconcentrates is carried out at high pressure. Leaching is the subsequent processing step in metal extraction. The paper studies theinfluence of some parameters (temperature, time, L:S ratio, excess) on the leaching efficiency of nonferrous metals from oxidizedconcentrate. The optimum parameters determined are: S/L ratio of 10/1, 25% reactive excess, leaching tempera...
Autori: Cornelia Lupu, Dragoş Taloi, Liliana Gherghe, Luminita Mara, Teodor Velea, Vasile Predica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25774

Abstract:This study aimed to assess the coagulation performance using simple aluminum sulfate (Alum) and pre-hydrolyzed polyaluminumchloride (PACl) coagulation agents by conventional global parameters, i.e., turbidity and organic matter expressed by totalorganic carbon (TOC) and chemical oxygen demand (COD), and non-conventional spectrophotometric parameters.Non-conventional spectrophotometric parameters, expressed as absorbance recorded at different wavelengths, i.e., A254, A280,A365, allowed d...
Autori: Florica Manea, Georgeta Burtică, Ilie Pisoi, Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25777

Abstract:In this paper, photo-catalytic process for treatment of phenolic wastewater by TiO2 nano powder immobilized on concrete surfacein a recirculation hydraulic flow was investigated. The process affected by different operational conditions that the optimum onescould be obtained from variables interchange. Taguchi method as a proper method for design of experiments and optimizationwas used to find optimum conditions. Selected five parameters at four levels were consists of initial phenol con...
Autori: Bita Ayati, Hossein Ganjidoust, Mohammad Delnavaz, Sohrab Sanjabi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25778

Abstract:In this paper, the mathematical model is improved by considering the density variations of the liquid from the pollution source vs.pollutant’s concentration of this liquid and by including the sorption-desorption term (SDT), which takes into account thisphysical process, played by a first-order decay model defined by two coefficients and an exponent. In order to practically use thisimproved mathematical model, the authors inferred the calculating relationships from automatic processin...
Autori: Daniel Bucur, Esmeralda Chiorescu, Gheorghe Ţigaret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25783

Abstract:Bioremediation is considered as one of the prominent and cost-effective cleanup technology to treat oily sludge disposals. In the present investigation anaerobic bioremediation of petroleum based oily sludge was studied in a slurry reactor by applying different experimental strategies viz., bioaugmentation, biostimulation and co-substrate addition. Total petroleum hydrocarbons (TPH) present in the oily sludge before and after degradation was extracted using soxhlet extraction procedure....
Autori: Asha Juwarkar, Kuppam Chandrasekhar, Mamilla Prathima Devi, Motakatla Venkateswar Reddy, Ponnapalli Nageswara Sarma, Srinivasula Reddy Venkata Mohan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25794

Abstract:In this study, removal of nitrate from aqueous solutions was investigated using an anion exchange resin, Purolite A-520E. Theinfluence of several experimental parameters, such as initial solution pH, resin dosage, phase contact time, initial concentration ofnitrate ions from aqueous solution, and temperature, has been examined in batch experiments. The results of this investigationreveal that the ion exchange process is favored at the initial solution pH (around) 6.8. The resin studied ...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25788

Abstract:Experimental research evaluated the possibilities of air treatment efficiency of a cylindrically shaped bio-charge, namely straw, toremove volatile organic compounds from the air. As determined during experiments, the air treatment efficiency of the straw biochargefor acetone removal reached 97.3%, while for butanol removal the efficiency was 86.0%. It has been determined that, withvolatile organic compound concentrations increasing biological air treatment efficiency is decreasing as h...
Autori: Alvydas Zagorskis, Petras Vaitiekunas, Pranas Baltrenas, Raimondas Leopoldas Idzelis,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25790

Abstract:The adsorption performance of a novel support for metal ions sorption and their removal from aqueous solutions was examined.The support is a new solvent-impregnated resin (SIR) which can be considered as an alternative adsorbent material capable ofselective sorption. The adsorbent was prepared by impregnating di-(2-ethylhexyl)-phosphoric acid (D2EHPA) onto AmberliteXAD7 resin beads, by dry impregnation method. The interaction between XAD7 resin and D2EHPA was evaluated by FTIRspectrosco...
Autori: Adina Negrea, Adriana Popa, Cornelia Muntean, Corneliu Davidescu, Lavinia Lupa, Mihaela Ciopec, Petru Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25793

Abstract:Coconut coir pith, an agricultural solid waste was used for the sorption of Cd (II) from aqueous solution in batch mode. Parameters like contact time, adsorbent dosage and pH effect were studied. Langmuir and Freundlich isotherms were used to model the adsorption equilibrium data and the system followed both the isotherms. Cd (II) adsorption capacity of coir pith was found to be 18.72 mg/g. Kinetic parameters of adsorption such as the Langergren pseudo-first-order, pseudo second order r...
Autori: Nagendra Badabhagni, Puthiya Veetil Nidheesh, Rajan Gandhimathi, Srikrishnaperumal Thanga Ramesh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25800

Abstract:The aim of the present study is the optimization of biosorption conditions using a metal tolerant actinomycete (strain 723) for the removal of lead ions from waste water in batch and dynamic flow mode. The optimum conditions for lead biosorption by the strain were determined as initial pH 3.0, biomass amount 2.0 g L-1, and initial metal concentration 400 mg L-1 in the batch condition. The maximum lead biosorption performance was obtained with a 19 mm diameter column, a 1 mL min-1 flow r...
Autori: Ayşe Betül Karaduman, Maria Julia Amoroso, Mustafa Yamaç, Sergio Antonio Cuozzo, Zerrin Pat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25811

Soil hydraulic characteristics are variable, being influenced by climate changes. Research conducted until now in this area has been based on field soil sampling; their laboratory analysis using experimental techniques; and the use of models and programs for data processing and interpretation. The present research is based on the idea of incorporating smart sensors on site, each one having its own network address, accessible for any location. They can be programmed to send an alarm signal when t...
Autori: Constantin Victor Stătescu, Dorin Cotiusca Zauca, Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25831

This paper refers to the post-Darcy free level uniform filtration. The capillary tube fascicle model is applied to this filtration. The theoretical Ch?Šzy coefficient is computed and also experimentally verified for a homogenous and isotropic material, made of glass spheres. The typical features for the free-level post-Darcy filtration (depending on slope) are the lover, critical and higher stages flows....
Autori: Aron Gabor Molnar, Daniel Toacă, Daniel Toma, Iosif Bartha, Nicolae Marcoie, Victor Gabor
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25833

This paper presents a mathematical model for the prediction of pollutant transport in rivers. The model has been developed and calibrated using the Matlab software and relying on field data from Romanian Someş River (collected in case of accidental cyanide release). Field data has been used to estimate model parameters (e.g. dispersion coefficient, velocity) as variable in time and space in order account for river features non-uniformity in time and also in space. These initial parameter va...
Autori: Elisabeta-Cristina Ani, Vasile Mircea Cristea, Paul Serban Agachi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25848

This paper presents the physicochemical and rheological properties of some complex coagulants derived from the weak and medium anionic polymers and medium cationic surfactant in order to evaluate the opportunity to use them in destabilizing and removing the colloidal systems from water and wastewater. In this respect, weak anionic and medium anionic copolymers of acrylamide and sodium acrylate with commercial names of Preastol 2515 and Preastol 2540, and a medium cationic surfactant derived from...
Autori: Constantin Bobirică, Gabriel Dabija, Liliana Bobirica, Mihaela Mihai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25850

Equilibrium and kinetics of nitrate removal from aqueous solutions of pH = 6.8 were investigated using the strong base anion exchange resin (Purolite A-520E) in the batch method. The experimental equilibrium data were analyzed by means of the Langmuir, Freundlich and Dubinin-Radushkevich sorption isotherm models. The Langmuir model describes sorption isotherm of nitrates with high correlation coefficients and better than Dubinin-Radushkevich and Freundlich models. The effect of temperature on th...
Autori: Anca Ceica, Igor Creţescu, Ion Balasanian, Laura Bulgariu, Liliana Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25851

The most important argument of this experiment was to demonstrate an increased content of active principles under the influence of some substances (considered in the literature as mutagene), when used in low concentration, do not affect the environment. The purpose of this study was the selection of some treatment variants, which, during the experimentations show the same biosynthetic potential, stabilized or increased. The substances used in the experiment were ethidium bromide at the concentra...
Autori: Constantin Leonte, Marius Zaharia, Roxana Vatavu, Teodor Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25867

This paper presents an experimental study on the energy requirement for greenhouse heating. The evaluation of necessary energy for crop plants was made by systematic measurements of the thermal behavior for three non heated tunnel greenhouses, covered with polyethylene. From the comparative analysis of the measured temperatures inside and outside the tunnel, it was established the relationship for estimating the inside greenhouse average temperature (tmi), lower than the minimum temperature nece...
Autori: Maria Harja, Roxana Dana Bucur
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25879

Two experimental periods have been undertaken to investigate the biodegradability of sewage streams (mainly regarding the organic substances) produced by a gas cartridge production, filling and distribution company. A sequencing batch reactor (SBR) was used for the laboratory examinations launched with municipal sewage sludge with a concentration of approx. 3 g MLSS/L. The various conditions in the reactors followed each other cyclically (fill, anoxic, aerobic, settle, draw) three times a day. T...
Autori: Bence Fazekas, Karoly Reich, Krisztian Varga, Viktoria Pitas, Viola Somogyi, Zsuzsanna Banyai
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25902

Abstract An activated sludge from SBBR (sequencing biofilm batch reactor) reactor filled with Fe0  as filler had been acclimated to Fe(III)rich environment aiming at secure an enrichment culture of iron-reducing bacteria. The dissimilatory Fe(III) reduction ability and its efficiency on the effect of nitrogen and phosphorous removal by dosing different Fe(III) under anaerobic condition were investigated. The mechanism was also proposed based on the results derived from the experiment a...
Autori: Jie Li, Juanjuan Feng, Siyuan Zhai, Ya’e Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25943

AbstractThe adsorption of hexachlorocyclohexane (HCH) by modified meerschaum was studied. The comparison of the meerschaummodified by anion and cation surfactant was conducted to explore their effect on HCH adsorption. The results showed that theabsorbability of HCH by the CTMAB-M (cetyltrimethylammonium bromide-modified) is better than that of SAS-M (sodiumdodecyl sulphonate-modified) because the CTMAB-M has fluffier fibers structure. The addition of amount of adsorbents shouldimprove the adsor...
Autori: Chanjuan Gao, Shengke Yang, Wenke Wang, Yaqian Zhao, Yue Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25948

AbstractThe preliminary assessment of a cost-effective flow-sheet for the production of biodiesel from microalgae lipid fraction wascarried out. The study was based on approximated cost-estimation methods integrated with the simulation software Aspen PlusŽ.Several scenarios were investigated to compare costs regarding the main steps of the biodiesel production process. Ranges ofinput variables from downstream literature and experimental data were used to simulate the sections that define concret...
Autori: Antonio Marzocchella, Giuseppe Olivieri, Piero Salatino, Teresa Guida
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25973

AbstractEU policy on waste management stresses the importance of an integrated approach to waste management, which includesconstruction of waste disposal facilities with prevention of waste generation and recycling, in line with management hierarchy:prevention of waste and its negative impacts; recovery of waste through recycling, reuse, safe final disposal of waste where thereis no possibility of recovery.This paper address the issue of municipal waste management and the impacts generated into ...
Autori: Ana-Maria Şchiopu, Cristina Ghinea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25987

AbstractThe paper presents and discusses some aspects concerning the development of an expert system designed for surface watermonitoring in the context of sustainable management of water resources in Romania and neighboring countries. Technicalconsiderations, which are worthy to be included in the analysis of such kind of systems, are addressed: the system structure(number, type and location of hydrometric stations), number and type of measured indicators, transducers and sensors used formeasur...
Autori: Anatolie Iavorschi, B. S. Nanda Kumar, Victor Sontea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25988

AbstractThe paper presents an extended implementation of an adaptive filter structure for electrocardiographic (ECG) signals denoisingwhich is implemented on Field Programmable Gate Array (FPGA) circuit. The proposed FPGA adaptive filter structure can beused to clean in real-time the ECG signals from power line interferences. In order to update the adaptive filter weights, the LeastMean Square (LMS) algorithm is used. The discrete forms of the filter structure and adaptive algorithm are presente...
Autori: Cristian Győző Haba, Ioan Tudosa, Narcis Adochiei, Valeriu David
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26002

AbstractThis paper describes an integrated system of wireless temporary pacemakers for remote monitoring of patients suffering fromcardiac arrhythmias, especially atrial fibrillation. The system is built around a low power cardiac pacemaker with wireless datatransmission capability, used for patient monitoring into a limited area. The proposed system is designed to be used in emergencysituations, in healthcare institutes, helping to keep the patient’s heartbeat stable. Each wireless pacemaker at...
Autori: Cristian Rotariu, Hariton Costin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26004

AbstractIn this paper the synthesis, characterization and testing of composite material based on multi-wall carbon nanotubes and silverdopednatural zeolite (MWCNT-ZAg) has been investigated for humic acid (HA) adsorption. The surface characterization of thecomposite material has been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM/ EDX) analysis.The Langmuir and Dubinin-Radushkevich (D-R) models fitted the best experimental data informing that adsorption process ofH...
Autori: Aniela Pop, Corina Orha, Florica Manea, Virgil Tiponut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26023

AbstractThis paper deals with the experimental investigation related to removal of hydrogen sulfide from simulated groundwater byadsorption/oxidation on activated carbons. Carbonaceous adsorbents were synthesized from peach stones by physical-chemicalactivation method and modified by oxidation following impregnation with Cu2+ by ion-exchange method. Obtained carbonaceousadsorbents were characterized by specific surface area and micropore volume. Surface chemistry properties were evaluated usingB...
Autori: , , Vasile Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26026

AbstractThe aim of this work is to characterize the flocculation process of a bentonite synthetic suspension with characteristics close toBega River from Timisoara, Romania. The time stability of the synthetic suspension was firstly investigated. After a few days ofcontinuous mixing a stable suspension was reached, stability being confirmed by monitoring the main physicochemicalparameters (pH, temperature, turbidity, dissolved organic carbon and initial particle size). In order to determine the ...
Autori: Alain Liné, Cosmina-Mariana Militaru, Ligia Barna, Teodor Todinca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26027

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

AbstractThe hydrodynamics of two equipments from a surface water treatment pilot plant has been investigated through residence timedistribution (RTD) experiments using brine solution as tracer. Computational Fluid Dynamics (CFD) procedure, which isincreasingly utilized to study a wide variety of complex environmental fluid mechanics processes, was used to predict the flowpatterns and other properties of flowing fluids (e.g. velocity, concentration of species etc.). In this work, ANSYS Fluent 14....
Autori: Adina Pacala, Alain Liné, Alexandru-Dan Filep, Cosmina-Mariana Militaru, Teodor Todinca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26030

AbstractThere are many treatment methods used to remove color from textile wastewater, and Fenton oxidation, a well known AdvancedOxidation Process is one of the most efficient. Apart of Fe(II), other metal ions have been used as catalysts in Fenton’s Reagent,and Cu(II) proved to be a good alternative.In this study the effect of the concentration of dye, catalyst and hydrogen peroxide were studied and optimized for thediscoloration process of Reactive Black 5 using a Fenton-like process, H2O2/Cu...
Autori: Andrei-Petru Bertea, Armand-Florin Bertea, Romen Butnaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26042

AbstractThe paper intends to contribute to the stages of bioremediation technologies elaboration, by means of experiments and efficiencydemonstrations of adequate biological depollution and ecological reconstruction methods. During the 2009-2011 period, heavymetals and metalloids, etc phytoextraction tests were performed with Lolium perenne L, from tailing samples collected fromwaste heaps and tailings dams of the mining exploitations (Rodna, Bistriţa–Năsăud, Fundu-Moldovei, Sucea...
Autori: Alexandru Crihan, Alin Bolonyi, Bianca Malschi Florian, Cecilia Roman, Dana Malschi, Dorian Brăhaiţa, George Ghira, , Marin Şenilă, Mirela Miclean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26044

AbstractBasic principles for assessing phytotoxicity are the same whether the test compound is a heavy metal, herbicide, fungicide,insecticide or other toxic compounds. The difference lies not in the method of evaluation, but in the experimental program andworking methodology.In this paper the phytotoxic effects of heavy metals, Cr (VI) and Cd (II) on plants germination and growth were studied. Stocksolutions of the two heavy metals were prepared at a concentration of 1000 mg/L, in distilled wat...
Autori: Dana Luminiţa Sobariu, , Maria Gavrilescu, Mariana Diaconu, Vasile Lucian Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26062

AbstractThe stability of soil aggregates is an indicator of soil structure. Soil acidity affects soil structure stability. Soil acidity has twocomponents: active acidity and exchangeable acidity. In natural conditions, each soil type has a certain level of acidity, which isgiven by its composition, natural vegetation, the chemical composition of precipitations and other factors that cause changes overtime in soil pH. Acidic soils are characterized by physical, chemical and biological properties ...
Autori: Dorin Cotiusca Zauca, , Lucian Vasile Pavel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26064

AbstractIn road traffic noise issues, experimental measurements are a relevant element in order to understand the problem and to adjustmodels. Sometimes, when measurements are not possible or in the designing phase, prediction models are used to perform anestimation of the equivalent level produced by a road infrastructure. Usually models parameters are obtained by a statistical datafit and thus they are related to the area where measurements have been performed. These models are suitable for st...
Autori: Gerardo Iannone
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26087

AbstractThe ozone oxidation and disinfection stages constitute important technological phases in the modern systems of water treatment,both as unitary stages as integrated ones into systems that use advanced oxidation processes (AOP). More than half of thewater/ozone contact systems used nowadays in the water treatment plants are based on systems of contact in the bubble column.This work here aims at experimentally analysing, in terms of scale, a water-ozone contact system in the bubble column a...
Autori: Sorin Claudiu Ulinici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26088

AbstractA study on the electrochemical decolourisation, aromatic ring degradation and mineralization of Reactive Red 147 (RR) syntheticsolutions using boron-doped diamond (BDD) electrodes is presented. Electrolyses were carried out under galvanostaticconditions in 0.1 M Na2SO4 supporting electrolyte using undivided electrolytic cell. Prior to electrolysis application, theelectrochemical behaviour of BDD electrode was characterized in the presence of RR dye by cyclic voltammetry in order toestabl...
Autori: Sorina Moţoc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26089

Abstract The article presents the development of a mathematical model concerning thermal desorption in a tubular electric furnace, using the linear regression analysis principle. With a range of experimental data obtained from some laboratory tests on water evaporation plus pollutant (Hexaclorocyclohexane - HCH), evaporation resulting from the application of thermal desorption on some soil samples; a mathematical model was developed to calculate the mass of substance evaporated fro...
Autori: Calin Vasile Prodan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26125

Abstract In many industrial applications most of the solid particles are separated by size and for this purpose there are used the oscillating sieves. The separation process based on sieves is a complex one and it depends on several factors, such as the properties of solid particles submitted to the separation process and on the operating regimes of the separating equipment. We have studied the separation process of the behaviour of solid particles on a flat oscillating surface...
Autori: Ovidiu Bontas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26134

Abstract In order to accomplish the water quality standards required for a specific use, the continental surface water is treated through a sequence of operations and unit processes. The treatment technological flowsheets carry out, partially or totally, the removal of various pollutants, every treatment step being used for improving one or more qualitative parameter. The treatment scheme is specific to water source type and water use. One of the basic operations for water treatmen...
Autori: Oana Tirtoacă Irimia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26136

Abstract Large amount of radioactive sources generate gamma rays of various energies and intensities. Gamma-ray spectroscopy is applied for the quantitative study of the energy spectra of gamma-ray sources. In the present paper, a statistical analysis of the energy spectra of gamma-ray spectroscopy monitored during 4 years at the “Dosimetry and Radioprotection” Laboratory from ”Vasile Alecsandri” University of Bacău is provided. Several new mathematical parameters were calcula...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26144

Abstract This paper develops a procedure whereby breakthrough curves obtained experimentally for ion exchange process in fixed bed ion mixed exchangers during water demineralization, can be used to characterize quantitatively and optimize the ion exchange process. In this regard, based on breakthrough curves there were developed statistical models that correlate three important factors which influence the process (superficial fluid velocity through the layer, changing layer height,...
Autori: Iuliana Rogoveanu Radosavlevici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26147

Abstract Biogas can be used as a renewable and green energy source by upgrading to natural gas. Water scrubbing, which is one of the most widely-applied upgrading technologies, involves an accurate knowledge of the solubility of the main biogas components in water, which is essential to the design and optimization of the biogas upgrading process. In this work, we use several thermodynamic models available in the Aspen Plus software modeling environment to calculate the solubilit...
Autori: Petronela Cozma
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26148

Abstract After any treatment process of wastewater results residual sludge that is characterized depending on the type of the wastewater or by the sludge treatment type. The sludge treatment process can be divided in three important stages: the preliminary stage (with the sludge thickening), the stabilization stage, and the dewatering stage. The paper shows the results of the research for the identification of the most efficient organic cationic flocculants, which might be used wit...
Autori: Mariana Turcu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26149

Abstract The reason for carrying out this research is related to the significant risk of heavy metals present in wastewater on the environment and human health. The removal of heavy metal ions from aqueous solutions was performed in a batch system, using peat (from Poiana Stampei, Romania) as adsorbent. The efficiency of the process was predicted with high accuracy (correlation with experimental data more than 0.99) based on a feed-forward neural network with two hidden layers. The...
Autori: Gabriel Dan Suditu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26150

Abstract The biosorption of Pb(II) and Cd(II) ions from aqueous solution on marine green algae biomass (Ulva lactuca sp.) was studied in batch systems, at initial solution pH of 5.0 and biomass dose of 8.0 g/L, considered as optimum experimental conditions. The obtained results from experiments of a single-component biosorption were analyzed using Langmuir, Freundlich and Dubinin- Radushkevich isotherm models. The Langmuir equation describe the biosorption isotherm of Pb(II) and Cd...
Autori: Laura Bulgariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26152

AbstractDuring the normal operating of reservoir, the rock mass quality in hydro-fluctuation belt of reservoir bank will degrade graduallyunder the water-rock interaction because of the periodically impoundment and drainage. In this article, with the consideration ofthe change of water pressure, an experiment was performed to simulate the process of “immersion-air dry” cycles with sandstones selected from the hydro-fluctuation belt of Three Gorges reservoir area. Test results indicates that the ...
Autori: Huafeng Deng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26161

AbstractRock dynamic mechanical characteristic is the basic information to study the damage of rock structures under dynamic loadsinduced from earthquake or blasting. A nuclear power plant site is a granite mountain of the same active tectonic period. Dynamic triaxial compression experiments need to be conducted on the drill cores of different project parts according to the design requirements. These drill cores were formed in the same active tectonic period, but as a result of the different bur...
Autori: Liu Bo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26163

AbstractA novel parallel A2O-MBR system was developed in this study based on the theory of denitrification with phosphorus removal.By utilizing the denitrifying phosphorus accumulating bacteria (DPB), the carbon source in the influent could meet the needs ofboth the denitrification and dephosphorization processes. Therefore, the carbon source restriction in conventional A2O processeswas resolved. The proposed system was inoculated with the sludge collected from the secondary settling tank in a m...
Autori: Liang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26170

AbstractA wet flue gas desulfurization (WFGD) system adopting electrostatically-assited twin-fluid atomization injector was presented.Spatial distributions of the droplet sizes, velocity for different voltages were measured using limewater and SO2 removalefficiency for different voltages and Ca/S ratios were tested using limewater drops. The physical and chemical improvementmechanisms were analyzed using spray characteristics and double film theory. The analysis showed that electrostatically-ass...
Autori: Zhentao Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26175

AbstractGallinaceous feathers are an abundant solid waste from the poultry processing industries, which poses disposal problems. Akinetic study dealing with the adsorption process of wool reactive dye, Yellow Lanasol 4G (CI Reactive Yellow 39), ongallinaceous (Gallus gallus, Cobb 500) feathers was carried out. The main research goals of this work were to evaluate theviability of using this waste as adsorbent and to study the kinetics of the adsorption process, using a synthetic effluent. Thechar...
Autori: Sónia Adriana Figueiredo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26203

AbstractThe removal of Acid Black 1 dye was investigated by acid treated pumice stone as a low cost adsorbent, since acidicmodifications were expected to improve the sorption capacity. The main components of the considered adsorbent were SiO2 andAl2O3 and acid treated pumice shows irregular structure. The effect of various parameters such as the initial dye concentration,the contact time, the temperature and the pH were studied. An increase of the contact time, the initial dye concentration or a...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26211

AbstractThe efficiency of enzymatic hydrolysis of Penicillin G to 6-Aminopenicillanic acid under substrate inhibition has been analyzedfor a bioreactor with mobile bed of immobilized penicillin amidase. The results indicated that the optimum values of temperatureand pH remained the same as for homogeneous hydrolysis using free enzyme. The inhibitory effect induced at higher PenicillinG amount in liquid phase was attenuated by increasing the size of the biocatalyst particles. For this reason, at ...
Autori: Ramona Mihaela Matran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26224

AbstractIn this article, hydrodynamic parameters and overall Oxygen mass transfer coefficient of petroleum based micro-emulsions in anairlift reactor were investigated. Four different petroleum-in-water micro-emulsion systems containing kerosene, heavy naphtha,light naphtha and diesel as oil based were used with concentrations of 3% and 7 % (v/v). The experimental data were supportedby simulation results obtained from the Computational Fluid Dynamics (CFD) method. The CFD was properly able to si...
Autori: Mostafa Keshavarz Moraveji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26234

AbstractIn this work, a four factor three-level Box–Behnken factorial design based on response surface methodology (RSM) wasemployed to optimize the removal of phosphate from synthetic wastewater (mineral salts medium-MSM) by the bacterialconsortium (Bacillus sp. RS-1, Pseudomonas sp. YLW-7, Enterobacter sp. KLW-2). A mathematical model was then developedto show the effect of each medium composition and their interactions on phosphate removal. The effect of the lactoseconcentration (X1), pH (X2)...
Autori: Krishnaswamy Usharani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26235

AbstractIn this research, response surface methodology (RSM) was applied to model the effect of main operational variables includinginitial pH, initial phosphate concentration, current density and reaction time on phosphate removal by electrocoagulation. It wasfound that the decrease of initial pH and initial phosphate concentration, and the increase of current density and reaction time are beneficial for improving phosphate removal efficiency. According to the ANOVA (analysis of variance) resul...
Autori: Mohsen Behbahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26237

AbstractThe vortex flame concept of combustion has been well known to produce low levels of NOx. This feature qualifies it to be usedin industrial processes and in power generation to comply with the environmental regulations concerning nitrogen oxideemissions. An asymmetric vortex flame combustor has been recently proposed by the authors. The present article reports thelevels of NOx emissions of such combustor for the first time. An experimental platform designed and developed to examine theNOx...
Autori: Khalid M. Saqr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26245

AbstractThe abundant availability of solid agroindustrial waste, sugarcane bagasse from sugar mills and juice extraction units, can bepotentially beneficial for the production of fermentation based biochemicals, paper boards and power. However, its role incausing bagassosis, an acute respiratory disease among the personnel handling large dry deposits has also been detected. Disposal of liquid waste whey from dairy industries poses a formidable threat to the aquatic ecosystem due to high BOD and ...
Autori: Manoj K. Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26248

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractHealthcare waste management is one of the most important environmental problems in the world and particularly in Tunisia,because of the potential environmental hazards and public health risks. The collection of infectious healthcare waste is a highlyvisible and important service that involves large expenditures. This study discusses the off-site transport problem of infectioushealthcare waste from the 12 hospitals in the governorate of Sfax (Tunisia) to a planned steam sterilization disp...
Autori: Wafik Hachicha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26252

AbstractThis study is focused on simulating and optimizing design and configuration of anaerobic baffled reactor (ABR) by means ofartificial neural network (ANN). This approach is aimed to assess an efficient ABR performance in various operational conditionstreating municipal wastewater. For this purpose, to analyze comprehensively on a base of experimental data, the system isoperated in two pilots of 48 liters net volume made of 8 compartments. In 7 months, more than 130 sets of data are obtain...
Autori: Gagik Badalians Gholikandi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26260

AbstractThe inactivation of Escherichia coli was investigated with two types of underwater electrical discharge systems such as pulsedelectrical discharge (PED) and dielectric barrier discharge (DBD). The DBD system consisted of a quartz tube and a coaxialdischarging electrode, which was submerged in biologically contaminated water. In the underwater PED system, the electricaldischarge starting from the tip of submerged tubular discharging electrode propagated downward and the direction of worki...
Autori: Sang Don Kim
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26263

AbstractThe main objective of this study is to investigate the utilization potential of oil well-derived drilling waste (DW) in the firedshale-brick production. Different mixtures were suggested for the experimental work with the DW content varying from 20% to40%. The prepared briquettes from different mixture were fired at a temperature ranging from 950°C to 1050°C for 1 h, with aheating rate of 2~3°C /min. Water absorption, apparent porosity, bulk density, weight loss by ignition, firing shrin...
Autori: XiangGuo Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26269

AbstractA novel RHA/PFA/CFA sorbent was developed by sol-gel method using three types of ashes, i.e. rice husk ash (RHA), palm oilfuel ash (PFA) and coal fly ash. From surface analysis of selected RHA/PFA/CFA sorbents, the spent sorbent had more compactstructures covered by irregular rough surface and the specific structure of raw RHA, PFA, and CFA were no longer visible. Inaddition, lower specific surface area was obtained for spent RHA/PFA/CFA sorbent. Batch studies were performed to evaluatet...
Autori: Irvan Dahlan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26272

AbstractThe extent of the problem of the excessive fluoride in drinking water remains an important health issue. In the present work,strong-base anion resins were investigated to assess their sorptive removal capacity of fluoride from water. It was found that theremoval of fluoride was high at natural pH (7) and was improved for increasing contact time and adsorbent dosage. Themaximum sorption of the resin was 13.7 mg/g according to the Langmuir model, namely higher than the values reported in t...
Autori: Mohammad Taghi Samadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26273

AbstractIn the present work an optimized experimental condition has been developed for the treatment of pulp and paper mill wastewater using an electrocoagulation process. The removal efficiency of 85 % COD and 94 % of color with a good repeatability of results (RSD <3%) has been achieved under the optimal experimental conditions of pH-7, treatment time of 2 h and a current density of 15 A/m2. In this study, wastewater from paper mill has been used and thus, high efficacy of removing the poll...
Autori: Chhaya Sharma, Rajni Sharma, Satish Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26281

AbstractIn this study, the experimental performance of a single slope solar still coupled with an evacuated tube collector was investigated. A single slope passive solar still (PSS) and single slope active solar still (ASS) integrated with an evacuated tube collector were fabricated with an area of 1 m2 and tested in the composite climate of Coimbatore, Tamilnadu, India, (Latitude: 11°N; Longitude: 77°E and an altitude of 409 m above sea level). High water  temperatures in the range of 84.2...
Autori: Karuppusamy Sampathkumar, Palanisamy Senthilkumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26286

AbstractThe objectives of this study were to investigate of cadmium and chromium adsorption from aqueous solutions by using orange (Citrus sinensis var Tampson) and sour orange (Citrus aurantium) mesocarp. The chemometric approach was applied for the optimization of removal percent of Cd2+ and Cr6+. To optimize Cd2+ and Cr6+ removal percent, the effect of four experimental parameters on removal percent was investigated by means of multivariate analysis. The considered factors were Cd2+ and Cr6+ ...
Autori: Maryam Bagheri Ardebilian, Mohammad Ali Zazouli, Pouneh Ebrahimi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26287

AbstractThis paper presents the results of the removal of arsenite and arsenate ions from an aqueous solution using Fenton modified solid waste vegetable oil industry (SWVOI). Several factors (such as pH, contact time and Fe2+/H2O2 ratio, initial arsenic ion concentration and adsorbent concentration) that affect the arsenic ion adsorption on the SWVOI adsorbent material were investigated. The sorption characteristics of the adsorbent material before modification were also studied and compared wi...
Autori: Hoda Amiri, Mehdi Ahmadi, Nemat Jaafarzadeh, Susana Silva Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26290

AbstractThis study focus on the possibility of removing the basic textile dye Astrazon Blue FGGL 300% 03, from an aqueous solution, using Esmegel clay as adsorbent. The characterization of the adsorbent included the distribution of particle size, physical textural properties, chemical composition and determination of the point of zero charge. The equilibrium isotherms were determined at 20 and 30 °C, pH at 6.0 and 7.5 and adjusted to the Langmuir and Freundlich models, having the latter led to b...
Autori: Chia-Yau Cheng, Paula M.S.S. Luís, Rui A. R. Boaventura
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26292

AbstractSecondary aluminium production inherently generates significant amounts of slag of variate composition and including dangerous compounds. Consequently, a care treatment of the resulted slag is imperatively necessary for preventing the environment pollution and for recovering valuable materials even if present in low amounts. The aluminium recovering procedure is based on a chemical and hydrometallurgical slag treatment, leading to the technical grade aluminium sulphate (AS), possible to ...
Autori: Carmen Tociu, Cristina Maria, Elena Diacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26295

AbstractAerobic granulation is a novel biotechnique for the treatment of coloured wastewater containing toxic xenobiotics in sequencingbatch reactor (SBR). The aerobic granules were investigated as a potential biomaterial for biodegradation of p-nitrophenol. Theremoval efficiency of p-nitrophenol was 93 % after 65 days of operation at 8 hr hydraulic retention time (HRT). The aerobicgranules were cultivated at a p-nitrophenol loading rate of 0.9 kg m-3 day-1, with sodium acetate as co-substrate t...
Autori: Pijush Kanti Mondal, Rais Ahmad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26302

AbstractThe effect of the number of surrounding droplets and distance between evaporating droplets on evaporation rate of the targetdroplet is studied experimentally in an evaporator which has been validated based on the d-square law. It can be found that theevaporation rate of the target droplet decreases with the increase of the number of surrounding droplets and the decrease of thedistance between evaporating droplets. The results analyzed experimentally and theoretically show that there is a...
Autori: Li Xiang-Rong, Liu Fu-Shui, Ma Yupo, Wang Xiang-Yuan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26304

AbstractThe removal and determination of toxic heavy metal ions in aqueous solutions has been given much more attention over the pastfew years. In this paper, a removal and separation/preconcentration method for cadmium species on Poly S15-g-EMA100 (a kind ofpolystyrene-graft-ethyl methacrylate copolymer) in water samples was developed. Some experimental parameters, such assolution pH, sample flow rate, type and concentration of eluent, amount of adsorbent and effect of common matrix ions werein...
Autori: Harun Ciftci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26317

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractDue to its toxicity, persistence in the environment and specific properties, 1,2-dichlorobenzene (DCB) has been listed as apriority pollutant by the European Agency. In this study, the oxidation with ozone alone as well as in combination withultraviolet irradiation was applied for the degradation of DCB. This article presents the abatements obtained, after the varioustreatments proposed, in the levels of chemical pollution as monitored by chromatographic techniques (GC/ECD, GC/MS andHPLC...
Autori: Bertrand Sancey, Corina Bradu, Grégorio Crini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26328

AbstractThe biosorption characteristics of Cd(II) ions using the NaCl-treated Ceratophyllum demersum were studied. The effect ofaltering the conditions, such as solution pH, the biosorbent dosage and contact time for the biosorption of Cd(II), and thebiosorption/desorption studies, were investigated. Langmuir, Freundlich, Dubinin-Radushkevich and Redlich–Peterson modelswere applied to describe the biosorption isotherms. Langmuir model fitted the equilibrium data better than the other isotherms(R...
Autori: Ali Akbar Babaei, Mehdi Ahmadi, Nadali Alavi, Nemat Jaafarzadeh, Pari Teymouri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26331

AbstractThis paper presents a study of the thermoaerodynamic spectrum inside an asymmetrically heated vertical channel of a doubleskinfaçade. A double-skin façade is an envelope construction that consists of two transparent surfaces separated by an airchannel. The numerical modeling was developed using the Ansys-Fluent simulation software under conditions of forcedconvection, using a three-dimensional geometry and a “k-ε standard” turbulence model. Then, experimental tests were performedon ...
Autori: Cătălin George Popovici, Cătălin Grigoraş, , Theodor Mateescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26332

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractAlgal blooms in reservoirs used for both fish and drinking water production are a major water quality problem. The authorsassessed data gathered from both published literature and from their own field enclosure experiments to analyze the relationshipsof phytoplankton chlorophyll α concentrations with biomass and algal cell count. Experimental data were collected from indoorlocations, field enclosures, and natural water bodies. Under laboratory conditions, where the types of algae an...
Autori: Chang-juan Zang, Chao Lin, Feng Gao, Hong-chuan Pan, Miklas Scholz, Min Wu, Sheng-lan Du, Sui-liang Huang, Yong Guo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26335

AbstractThe removal of phosphorus by strongly basic anion exchanger was investigated. Removal efficiency increased with contact time,resin mass and initial solute concentration, while temperature showed a reverse effect. Equilibrium data were best fitted ontoLangmuir isotherm model (R2>0.99). Maximum sorption capacity of the resin was 66.22 mg/g, namely significantly higher thevalues reported in the literature. The Freundlich parameter (n = 4.3) and the Langmuir separation factor (RL = 0.067-...
Autori: Abdeltif Amrane, Hamid Reza Ghaffari, Mansur Zarrabi, Mohammad Mahdi Soori, Mohammad Noori Sepehr, Saied Borji
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26343

AbstractA deep understanding of the relationship between the solids deposition and head losses is vital to optimize the backwashing inbiological aerated filters (BAFs). In this article, the deposition solids were classified into four types: heterotrophic biomass,autotrophic biomass, inert biomass and extracellular polymeric substances (EPS). A concept model was developed to simulatethe solid deposition and the head loss development. The temporal and spatial distributions of the four types of sol...
Autori: Chengda He, Dongsu Bi, Jun Wu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26347

AbstractMonitoring an unstable slope is quite important for environmental safety. Based on our previous studies, this paper presents athird-generation distributed optical fibre transducer. The operating mechanism of this novel transducer was analysed for itsresponse to a single concentrated and uniform load, and a theoretical study was conducted on the elongation of the bottomsurfacefibres of a bending resistance model at the phases of linear elasticity and total cross-section cut-off stage. A b...
Autori: Bang Liu, Dong-Yan Liu, Hu Luo, Jing-Cheng Liu, Qiao-Ying Yuan, Yun-Ju Luo, Zheng-Wei Zhu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26348

AbstractThe paper represents the application of a multicriterial analysis for establishing the decisional priorities in the field of impactsgenerated by polluting emissions from large burning installations. The analytic hierarchy process (AHP) method was used inorder to express quantitatively how the environmental protection and sustainable development objectives are met. Based onexperimental determinations carried out on site at Mintia Power Station, Romania and the brainstorming sessions held ...
Autori: Dan Codruț Petrilean
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26398

AbstractThe study on the kinetics of reactive extraction of rosmarinic acid with two extractants, Amberlite LA-2 and D2EHPA,underlined the strong influence of extractant type, solvent polarity, and 1-octanol content on the relative magnitude of thediffusional or kinetic resistances and on the interfacial reaction rate. Thus, indifferent of the extractant type, the highest values ofinterfacial mass flows and reaction rates have been reached for extraction in dichloromethane. The addition of 1-oct...
Autori: Mădălina Poştaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26412

AbstractThe industrial development, the demographic growth and the limitation of the natural regions have determined a continuousdegradation of the water quality due to high concentrations and complexity of pollutants from the wastewater. The centralizedand decentralized treatment systems apply treatment procedures and techniques which can be complementary in solving theenvironmental pollution problems due to wastewater. In the present paper a three-dimensional mathematical model waselaborated b...
Autori: Narcis Barsan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26422

AbstractThis paper proposes a tridimensional mathematical model for water migration time in a soil sample, as a prerequisite for thestudy of migration of various liquid pollutants in soil. The variables taken into consideration were measurement position, soiltype, porosity and the height of soil column. The mathematical models were elaborated and tested based on experimental data,assisted by TableCurve 3D software for generating linear and non-linear equations. The proposed mathematical models o...
Autori: Alexandra-Dana Chiţimuş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26425

AbstractThe study aimed the diversification of fodder yeast assortments with viable economic effects while reducing the environmentpollution by capitalization of wastewaters with high monosaccharides content from pulp and paper industry and residual wheyfrom milk industry. Using the Response Surface Methodology the fabrication recipe has been optimized according to anexperimental program based on a mathematical model with biomass, protein and residual sugar as response functions. Theculture medi...
Autori: Livia Manea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26429

AbstractRolling bearings are one of the most commonly mechanical elements used in the construction of dynamic equipment. Thiselement can be considerate as a noise source as a result of relative motion of the components from their construction: rings,rolling elements and cage. The noise level increase with the increase of the roller bearings wear. By analyzing of the rollerbearings wear level, which appear due to the component failure, it can be determine the deterioration stage and their remaini...
Autori: Dumitru-Cristinel Nadabaica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26430

AbstractThe aim of our investigations was to assess the potential ecotoxicological effects induced by complex chemical mixtures ofanaerobically digested sewage sludge. The sensitivity of monocotyledonae cereal (Triticum aestivum L.) test plant to varioussanitization treatments of anaerobic stabilized sewage sludge was evaluated. Several biometrical and biochemical responseindicators were selected as endpoint in this ecotoxicological tests. Thus, the ecotoxicity of sewage sludge was evaluated thr...
Autori: Dumitra Raducanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26437

AbstractEvaluation of radon concentration is a very difficult task and a very important issue, in relation to the protection of human health.This is especially the case when there is an increase in concentration of radon on a deterministic basis, as is the case of nearbyphosphogypsum residues or geological characteristics. Radon gaseous that can be found in the environment occurs mainly fromnatural radioactive decay chains. The gamma ray spectroscopy is a powerful tool in order to monitor the en...
Autori: Marius Stamate
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26441

AbstractThis paper presents a three-dimensional mathematical model which characterizes the variation of sound pressure levelpropagation and the variation of attenuation of the sound pressure level propagated in an enclosed space. The variable taken intoconsideration both in the experiments and in the mathematical modeling were: the positions of the acoustic screen to noisesource; the height of the microphone to record the sound pressure level for a variable number of walls. The mathematical mode...
Autori: Claudia Tomozei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26443

AbstractThe purpose of this article is to elaborate a mathematical model for the prediction of average monthly environmental/outsidetemperature (T) levels in the region of Ruse, Bulgaria. Based on the method of harmonic analysis, amplitudes and phases of themain harmonic oscillations were defined. The results show the dominance of the first three harmonics for the period of theresearch. Visualization of experimental and theoretical values of the model shows a high degree of consistency between t...
Autori: Stoyan Yanev
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26446

AbstractThe process of semi-volatile aerosol particle evaporation was studied with respect to both computational and experimentalapproaches. A Sinclair-La Mer type aerosol generator was used to produce monodisperse particles from four n-alkanes(tetradecane, hexadecane, octadecane, eicosane) while particle sizing and FID measurements were applied to quantify particleandvapor mass and their subsequent phase distribution. Aerosol dilution and later stationary analyses in a flow tube at two timeinte...
Autori: George C. Dragan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26448

AbstractThe washing method for uranium contaminated soils using three different reagents was investigated. Experimental data havebeen obtained for four types of soils, which have been characterized in terms of particle size distribution, as well as structure andchemical composition. Thus, the decontamination degree for each type of soil and reagent respectively has been measured.Subsequently, the decontamination process has been simulated using an artificial neural network. Based on this neural ...
Autori: Alexandru Woinaroschy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26451

AbstractIn the present work, the kinetics of amaranth dye biosorption onto the roots, stems, leaves and the whole plant of water hyacinth(Eichhornia crassipes) were studied for differential evaluation of the plant’s biosorptive potential to remove the toxic dye fromaqueous solutions. E. crassipes´ leaves showed the highest level of amaranth dye biosorption (43.1 mg/g), followed by the entireplant (31.18 mg/g), the roots (28.51 mg/g), and finally by the stems (23.97 mg/g). The same differential t...
Autori: Imelda Guerrero-Coronilla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26463

AbstractThe main purpose of the present work was to evaluate the potential of plum (P. domestica L.) tree bark (PDB) to remove Cr(VI)and total chromium from aqueous solutions in batch systems. Experimental data showed that the Cr(VI) and total chromiumremoval capacity was dependent on operating variables such as PDB particle size, PDB pretreatment, solution pH, initial Cr(VI)concentration, and contact time. The mechanism of Cr(VI) removal by PDB implies two simultaneous processes: 1) the reducti...
Autori: Perla Vianey Lopez-Nuńez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26464

AbstractIn this paper, a study is conducted to assess the ability and the accuracy of a CFD approach concerning the behavior of a linearheat source positioned in a test room. Firstly, the main characteristics of our numerical model (mesh generation, turbulencemodel, near wall treatment, radiation model and boundary conditions) are presented after a briefly description of the test roomtaken into account. In addition, we show also the significance of these issues within our CFD approach. Furthermo...
Autori: Raluca Teodosiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26467

AbstractThis work presents an original method and an automated installation to recover by combustion the waste gas obtained in theignition process of xylites in rotary kiln. The flue gas resulting from the combustion of waste gas, with light fuel support areused in the technological processes of obtaining activated carbon, satisfying the conditions where the oxygen content does notexceed 0.3 % vol. and the temperature is above 1200°C, conditions imposed by the Project Manager of the European pro...
Autori: Aurel Gaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26461

AbstractThe present contribution describes the investigation of a solar air collector for space heating in order to develop more efficientand cost effective energy process. Various configurations of absorber and different air flows through the collector were tested.The influence of the air mass flow on the air outlet temperature and thermal efficiency has been studied. The thermal efficiency,fluid outlet temperature, heat increase and heat losses of the collector are calculated depending on the ...
Autori: Lizica Simona Paraschiv
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26468

AbstractThe present study was undertaken to experimentally evaluate the heavy metal (HM) removal capacity of a municipal wastewatertreatment plant (WWTP) as a kind of mass balance. The aim of the work was to find a water or sludge stream in the WWTP thatcould be treated separately for heavy metal removal to maximize the same efficiency of the whole treatment technology.Although literature says that the HM content of sewage accumulates in the sewage sludge, the experimental results showed nocompl...
Autori: Gábor Gulyás
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26477

AbstractThe performance of some complex coagulants derived from weak and medium anionic polymers and medium cationic surfactantin coagulation-flocculation process for water treatment was experimentally investigated by carrying out kinetic studies and bydetermining the optimum coagulant dose. The complex coagulants were prepared from weak anionic and medium anioniccopolymers of acrylamide and sodium acrylate with the commercial names Praestol 2515 and Praestol 2540, and mediumcationic surfactant ...
Autori: Constantin Bobirică
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26478

AbstractThe conducted research has proved the dependence of gas flow rate in the separate channels of the two-level multichannel cycloneat a different inflow velocity and the number of channels. The carried out investigation demonstrates the dependence of changesin velocity in the channels under varying relations between peripheral and transitional flows. The work of a cyclone of the channelis based on centrifugal forces and an additionally occurring filtration process caused by the interaction ...
Autori: Pranas Baltrėnas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26488

AbstractBisphenol-A (BPA; 2,2-bis(4-hydroxyphenyl)propane) is a monomer used primarily in the production of polycarbonate andepoxy resins that has been reported to have estrogenic activity. The biodegradability of BPA has been previously investigated inseveral studies designed to simulate surface waters and biological wastewater treatment systems. However, there is littleinformation available about the phytoremediation of groundwater contaminated with BPA. Halophytic species are of specialintere...
Autori: Margarita A. Petoussi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26493

AbstractEvaluation of the quality of natural waters used as sources for drinking water supply is very important for selection of the propertechnological treatment system that would ensure the compliance of physical, chemical and microbiological parameters with thespecific standards. The current study aims at investigating the quality of two natural waters used as sources for drinking watersupply of Iasi City: Prut River (surface water) and Timisesti (groundwater). The experimental analysis of th...
Autori: Maria Cohl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26509

AbstractTetracycline (TC) are used as bacteriostatic agents, inhibits the synthesis of bacterial proteins, with activity against awide variety of organisms with application in human and veterinary medicine. The presence of TC in theenvironment constitutes a serious problem, being weakly metabolized or absorbed into the human or animal bodycon. TC residues even in low concentration may produce serious toxic and other effects on humans and livingorganism. In this study are presented the applicatio...
Autori: Carmen Ionela Brînzilă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26513

AbstractFailures of geothermal system pipes are often caused by limescale buildup on the walls of the pipes. The primary aim of thiswork is to investigate the influence of the scale formed on the walls of the pipes on the vibration parameters and naturalfrequencies of pipelines. To this end, the different phases of deposition are artificially simulated in the model experiments. In thedifferent states, vibration tests are preformed to evaluate the status of the pipe section and the rate of deposi...
Autori: Dénes Kocsis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26541

AbstractDue to the continuously increasing trend in the costs of the traditional fossil fuels, the development of residential or commercialbuildings with reduced energy needs becomes a significant and more pressing scientific challenge. At the same time, consumersare increasingly demanding more comfortable buildings, where the energy needs are addressed using locally available renewableenergy resources. Consumers also require a higher level of security, supervision, and control of the building, ...
Autori: Géza Husi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26553

AbstractThe adsorption potential of 10 wt.% COOH/TUD-1 material for removing Cd2+ from aqueous solutions was investigated via thebatch technique, and the effects of pH, temperature and contact time were studied. Experimental data showed that the maximumCd2+ adsorption, 90%, occurred at pH 6. The adsorption equilibrium was reached within 35 min for 10 wt.% COOH/TUD-1. Theadsorption mechanism was investigated in terms of its thermodynamics and kinetics. The adsorption data were fitted using theLan...
Autori: Nabila Bensacia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26558

AbstractThe distribution of mixing time for a split-cylinder gas-lift bioreactor has been investigated for simulated broths with apparentviscosities up to 26 cP. The results indicated important variation of mixing time on the height of riser or downcomer, as well asdifferent behavior of dispersion flows in the two regions. Thus, the highest mixing efficiency for the ascending circulation hasbeen recorded for the intermediary positions, placed above the sparger. Contrary, for the downcomer, the i...
Autori: Anca-Irina Galaction
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26560

AbstractThis paper presents the experimental results obtained during testing in an electromagnetic field with non-ionizing radiations fromlow-intensity microwaves acting on a group of substances consisting of: double distilled water, neutralized to pH = 7; drinkingwater with pH = 7.3; slightly acidic aqueous solutions obtained by diluting the acetic acid at concentrations of 2.25‰, 4.5‰ and9‰ in double distilled water, for pH = 6.8, 6.7 and 6.5, respectively. The exposure of the samples was perf...
Autori: Gheorghe Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26562

AbstractGraphene oxide (GO) was prepared from expandable graphite by a modified Hummers’ method and characterized by TEM,XRD, FTIR, and Raman spectroscopy. The batch adsorption experiments were carried out to study the effect of variousparameters, such as the initial concentration, adsorbent dosage, initial pH, contact time and temperature on adsorption propertiesof cationic red X-GRL onto GO. The Langmuir and Freundlich models were used to fit the experimental data of adsorptionisotherms. The k...
Autori: Jiankun Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26570

AbstractThe CO2 electroreduction in gas phase using Pt on carbon black catalysts is investigated in this work. This process is expected tobecome a key technology to prevent anthropogenic CO2 emissions. Specifically, the electrocatalytic reduction in a solventless gasphase is studied, as a first approach to later develop a photoelectrocatalytic device for the efficient conversion of CO2 to fuelsusing solar energy for the reaction. The objective of this preliminary work has been the tuning up of t...
Autori: Fabiola Martínez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26578

Abstract Cadmium leaching experiments from hazardous waste containing 16.5 wt% CdO were conducted using H2SO4. Dominant experimental and process parameters were determined by factorial design. Six controlling factors were considered, i.e. solidliquid ratio, acid concentration, reaction time, particle size, stirring speed and temperature. Analysis of variance (ANOVA) was used to identify main effects and their interactions. An empirical model, based upon experimental results, was developed to...
Autori: Mahdi Gharabaghi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26590

Abstract Xi’an-Baoji Highway is one of the oldest and most important highways in northwest China. In this study, the concentrations (0-20 cm) of Pb, Zn, Cu and Cr at 5-1000 m distances in the roadside soils along Xi’an-Baoji Highway were experimentally determined to analyze their spatial distribution and evaluate their contamination levels. The spatial distribution (mg·kg-1) of Pb, Zn, Cu and Cr at 5-1000 m distances from the both roadsides (North/South) is, respectively, ...
Autori: Shuanxi Fan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26610

Abstract The objective of this study is to develop a mathematical model which would confidently predict the rate of substrate degradation of an oil-water emulsion in a laboratory-scale completely-mixed continuous flow reactor using the photo-Fenton treatment process. Two models are developed from first principles and the predicted substrate removal rates for both models are compared with experimental data. The principal conclusions of the study are that both models produce good correlations ...
Autori: Maha A. Tony
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26613

Abstract The present study deals with the removal of Cr (VI) from aqueous solution by polypyrrole (PPy). Response surface methodology (RSM) was applied for the design and analysis of experiments in the optimization of pH, temperature, initial concentration, contact time and adsorbent dose during the removal of the Cr (VI). The optimum adsorbent dose, temperature, initial concentration of Cr (VI), pH and contact time were found to be 0.8 g, 46.5 oC, 187.5 mg/L, 5.3 and 15.4 min respectively. ...
Autori: Ehsan Hasani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26614

Abstract This study is focused on the dissolution kinetics of zinc oxide in ammonium acetate solutions to recover the zinc from alkaline and zinc-carbon spent battery powders. This study represents a first step for further studies in which actual waste powder is to be used. Therefore, the experiments were performed by using pure zinc oxide powder to evaluate the dissolution behavior of zinc. The effects of ammonium acetate concentration, reaction temperature, stirring speed and solid to liqu...
Autori: Nizamettin Demirkıran
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26618

Abstract The objectives of this paper address the identification and statistical analysis of the laws underlying the variability of the magnitude of the damages to torrent control structures induced by four of the most well-known events affecting their stability, resistance and durability. The research set consists of 100 torrent control structures that have continuously functioned for almost three decades in a managed torrential watershed in the forested mountainous area of Romania. In the ...
Autori: Ioan Clinciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26619

Abstract This study examined the characteristics of geopolymer with solar panel waste glass. After 28 days of curing, the compressive strengths of the geopolymer samples containing 10 mass % and 20 mass % solar panel waste glass were 63.3± 1.8 and 49.1 ± 2.2 MPa, respectively. The geopolymer sample with 10% solar panel waste glass exhibited a stronger reaction than that with 20% solar panel waste glass, and the strength decreased as the amount of solar panel waste glass increas...
Autori: HuiCong Hao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26621

Abstract The feasibility of catholyte-conditioning to enhance the electrokinetic (EK) remediation of cobalt and lead polluted soil has been investigated in this study. Electrokinetic experiments were conducted using an EK cell 10 cm in width, 10 cm in height, and 50 cm in length. Plate type electrode of graphite was used as electrode material. Two experiments were conducted under constant voltage condition (2 V/cm). The pH values of the soil significantly affect the removal of Co and Pb ions...
Autori: Mahdi Bahemmat
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26623

Abstract Activated carbon was prepared from renewable plant material, that is Euphorbia rigida, by chemical activation using zinc chloride as activating reagents. The adsorption of Basic Blue 9 (BB9) onto activated carbon was investigated in a batch system with respect to contact time, pH and temperature from aqueous solutions. The experimental data indicated that the adsorption isotherms are well described by the Langmuir isotherm model and the calculated maximum adsorption capacity of acti...
Autori: Özgül Gerçel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26627

Abstract Based on the spray mixing field-effect analysis method, this paper has taken into consideration the variation in the distribution of oxygen concentration in the combustion process and has put forward the combined combustion field-effect analysis method. The method is applied to the matching study of a certain kind of diesel engine’s combustion chamber with air admission and fuel injection parameters and can also be used to complete the simulation analysis and evaluation of mix...
Autori: Xiang-Rong Li
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26634

Abstract Established applications of emulsion liquid membranes (ELM) refer to refining in hydrocarbons and hydrometallurgical processing, rehabilitation of poisoned patients. In this work we investigated the separation of aromatic compounds of biological interest, more often encountered as intermediates in dyes and drugs industry: aniline, nitrobenzene, ortho and para-toluidine, using emulsion liquid membranes. The experimental results showed that in the case of basic substances separation t...
Autori: Alexandra Raluca Miron
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26650

Abstract Reactive Blue 19 (RB 19) dye removal from aqueous solutions by using layered double hydroxides containing nitrate as the intergallery anion (MgAlLDH) as adsorbents was investigated. The adsorption process was found to be influenced by the contact time, the initial dye concentration, the presence of inorganic anions and the temperature. The XRD and FTIR analysis evidence two competitive processes: adsorption and/or intercalation of the molecules may take place, depending on the initi...
Autori: Maria Celina Alexandrica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26651

Abstract This paper presents the results obtained using the prehydrolysis treatments of rapeseed stalks depending on regime and the catalyst. The vegetal materials were subjected under different temperature conditions and then characterized for the yield reducing substances. The differences between samples have been established by using FTIR and depend on the successive hydrolytic treatments of dynamic and static regime in the presence of various catalysts. The experimental data show that th...
Autori: Corina Măluţan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26654

Abstract The oxygen transfer into the fermentation broths could be improved in presence of oxygen-vectors, without intensification of mixing or aeration. The experimental results for simulated, P. shermanii and S. cerevisiae broths indicated the significant increase of kLa, by adding n-dodecane, but the magnitude of this effect depends especially on the cells affinity for hydrocarbon droplets. Therefore, due to the higher affinity of yeasts cells for hydrocarbon droplets during their entire ...
Autori: Anca Irina Galaction
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26657

Abstract This study focused on the use of jet aeration to treat printing and dyeing wastewater. The related environmental factors influencing the dynamical efficiency of a jet aerator were investigated. Results showed that an ideal linear relation existed between dynamical efficiency and working pressure (R2 > 0.98), with dynamical efficiency decreasing gradually as the working pressure increased. When the gas–liquid ratio was approximately 0.6:1 to 1.4:1, more bubbles were formed b...
Autori: Chunsheng Le
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26664

Abstract Adsorption equilibrium and effective diffusion coefficients of water vapor, in cylindrical particles of activated alumina (A) and activated alumina impregnated with calcium chloride (MCA), are experimentally determined. The experiments were conducted at 303 K and 323 K using cylindrical particles with 2.5 mm in both length and diameter. Diffusion coefficients were determined from the kinetics of water sorption. The measurements were conducted in a constant pressure unit based on a m...
Autori: Eugenia Teodora Iacob Tudose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26665

Abstract The variation of the content of 12 phenolic compounds from 5 months aged Cabernet Sauvignon and Merlot wine samples treated with siliceous and aluminosiliceous porous materials was analysed through a HPLC method. The standard physical-chemical analyses (alcoholic concentration, total acidity, volatile acidity, relative density, reductive sugars, total dry extract, non-reductive extract, free SO2, total SO2, pH) were registered. The used nanomaterials: SBA-15, Al-MCM-41, KIT-6 were s...
Autori: Camelia Elena Luchian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26667

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract Magnetic contamination is considered more and more as a challenging issue related to biosphere pollution with magnetic materials originating in natural and artificial sources (volcanic eruptions and respectively industrial activities that contributed to iron and other metal compounds spreading in air, water and soil). Aiming to study the impact of magnetic metal ions such as iron and cobalt on the metabolism of some environmental microorganisms, in this paper an experimental simulat...
Autori: Lacramioara Oprica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26675

Abstract The performance of electrocoagulation (EC) process, a non-specific electrochemical technology, was investigated for the removal of carbamazepine (CBZ), an antiepileptic drug, from water. Experiments were carried out in synthetic wastewater in a batch cell. The respective influences of some key process parameters were studied, such as mixing conditions, initial pH, and current on aluminium electrodes. Experimental results showed that a CBZ removal efficiency of 62% was observed under...
Autori: Tania Yehya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26683

Abstract In the process of chitin extraction, shrimp shell powder was treated by Lactobacillus plantarum culture. The efficiency of microbial demineralization (DM) under aerobic and anaerobic conditions was investigated. The shrimp shell powder was incubated at 30 °C for 6 days with L. plantarum. In order to prepare microbial culture, inoculums size was 5% for culture inoculation. Date syrup with total reduce sugar concentration of 30 g.L-1 was used. The value of pH in anaerobic conditio...
Autori: Marjan Khorrami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26692

Abstract In many coastal areas strong currents may occur from tidal effects, rivers discharges and high waves breaking due to abrupt changes in local topography. The modification of the wave fields by currents and vice versa need to be predicted by reliable nonlinear numerical models, when wave and current coexist along and around the approach tracks of the ports and harbors, or in the areas of ongoing offshore and coastal developments, or in areas subjected to intense navigation. Various wa...
Autori: Angela Ivan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26695

Abstract In the present work, the removal of cadmium ions from aqueous solution using an agricultural waste as biosorbent, namely trunk palm fibers was investigated. The adsorption equilibrium and kinetics for this system were studied. Four adsorption models were applied to understand the nature of the adsorption process. Freundlich adsorption isotherm was found to best fit the experimental data. The maximum adsorption capacity was found to be 23.8 mg/g. The adsorption process was found to b...
Autori: Hosam Altaher
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26699

Abstract Individual exposure to particulate matter (PM) fractions is mainly determined by indoor source characteristics and personal activity patterns. This paper discusses experimental results obtained through the analysis of individual exposure of women to PM10 and PM2.5. To this purpose, 15 volunteers of different ages and lifestyles living/working in Ceccano (Italy) were selected and their exposures to PM10 and PM2.5 were measured through a handheld photometer. They also filled out a tim...
Autori: Giorgio Buonanno
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26703

Abstract Simple, cost effective, accurate and reproducible UV-spectrometric method was developed and validated in order to estimate total polyphenolics content (TPC) of some Romanian red and white wines. Furthermore, the total flavonoids and nonflavonoids of the wines were also determined. The TPC has been measured using the Folin-Ciocalteu method. The method was tested and validated for various parameters: specificity and selectivity, precision, accuracy, detection and quantization limits a...
Autori: Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26708

Abstract Adsorption has proved to be an excellent way to treat industrial wastewater, due to its significant advantages like easy availability, inexpensive, ease of operation and highly efficient, compared to conventional expensive adsorbents like activated charcoal, alumina etc. The present investigation focused on utilization of Mangifera indica seed shell substrate for the removal of toxic heavy metals like Fe(II) and Mn(II) from wastewater. Mangifera indica seed shell substrate as an eff...
Autori: Tikaram D. Kose
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26713

Abstract Maximum removal (94±1.2%) of 2, 4 dichlorophenol (50 mg.dm-3) was achieved on silica with agitation of 4 hours, at pH 8 and 42°C. The positive enthalpy (ΔH) and negative free energy values (ΔG315K) suggested the endothermic and a spontaneous nature of sorption. The free energy of the process at all temperature was negative and increased with the increase in temperature. The values of free energy suggested a spontaneous process where the spontaneity decreased w...
Autori: Abdul Ghaffar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26718

Abstract Impact damage is considered the primary cause of in-service delamination in composite materials and promotes significant reduction in residual strength. Non-destructive techniques (NDT) include several methods able to detect the shape and the size of the interior damages without destruction of the structure or component, which is economically advantageous. The aim of this paper is to evaluate the properties after low velocity impacts using an experimental-numerical procedure based o...
Autori: Ana Martins Amaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26726

Abstract This study was carried out to investigate the adsorption of methylene blue (MB) onto pumice powder, as a low-cost adsorbent for the removal of dyes. The experiments were designed based on a central composite design (CCD) and the process was analyzed and modeled using response surface methodology (RSM). In order to study the adsorption process, three important factors viz. pumice dosage (20- 50 mg/50mL), MB concentration (20-40 mg/l) and contact times (5- 35 min) were chosen as varia...
Autori: Kiomars Sharafi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26729

Abstract The aim of this study is to evaluate adsorption kinetics, isotherms and thermodynamic parameters of anionic textile dye (Acid Red 88) onto montmorillonitic clay from aqueous solutions. The parameters of pH, initial dye concentrations, temperature, and the adsorbent dosage were investigated experimentally. Four kinetic models including pseudo-second order, pseudo-nth order, Bangham’s equation and double exponential equation (DEE) were selected to follow the adsorption process. ...
Autori: Sedef Dikmen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26731

Abstract Response surface methodology and central composite experimental design were used to model and optimize the operational parameters of the excess sludge protein extraction yield by ultrasonic wave-assisted extraction. The three variables involved in this research were the ultrasonic extraction time, pH, and temperature. In the range studied, statistical analysis of the results showed that selected variables had a significant effect on protein extraction yield. The optimized extraction...
Autori: Yulin Xiang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26736

Abstract Chitosan and keratin were tested as low cost biosorbents to remove phenol from water solutions at variable temperature (20- 50°C), initial phenol concentration (10-90 mg L-1) and pH (5.0-10.0), and fixed biosorbent dosage (10 g L-1). The pseudo-second order kinetic model exhibited the best fit to the experimental data and allowed estimating theoretical values of sorption capacity of 4.51 mg g-1 with keratin and 2.87 mg g-1 with chitosan. Equilibrium isotherms, described at best ...
Autori: Attilio Converti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26743

Abstract An experimental study of mixing in autoclave vessel equipped with an anchor impeller was performed on the sludge proceeding from the treatment of mixed municipal and industrial wastewater. This unit operation is part of a process for the recovery of sludge. The mathematical modelling of the mixing was done having in view the scaling-up of this process. The mathematical model allows the calculation of the mixing power N as a function of the impeller diameter d, the vessel diameter D,...
Autori: Ancaelena Eliza Sterpu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26744

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract The aim of this paper is to determine the heat of combustion of plastic wastes resulted from municipal solid waste, automotive shredder facility waste and building and construction waste. The plastic wastes have been separated by flotation technique using as flotation media: water, ethanol, their mixtures and magnetic fluid. Resulted fractions have been analyzed aiming to determine the most effective fraction from the heat of combustion point of view. The obtained results have been ...
Autori: Liviu Costiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26750

Abstract The present work systematically investigates the photocatalytic degradation of carbamazepine (CBZ), an organic compound, known as refractory to the conventional wastewater treatment by the titanium dioxide PC 500 catalyst. The effects of some fundamental operating parameters in heterogeneous photocatalysis were investigated in this work in order to determine the main ones affecting the degradation kinetics. The obtained results clearly showed that the removal rate of the target comp...
Autori: Lidia Favier
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26754

Abstract This study is focused on the removal of leachable lead present in CRT (cathode ray tube) glass employing different chelating agents, NTA (nitrilotriacetic acid) and ATMP (amino trimetilen phosphonic acid), and then on the evaluation of their extractive capability. The operating conditions are the following: T=80°C, t=1h, pH=10, solid/liquid weight ratio=1/10, reagent concentration= 0.1 M. Afterwards a number of leaching tests at controlled pH were performed in the 5-9 range for ...
Autori: Elena Bursi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26772

Abstract The recent awareness about recycling also involves the resources used in civil engineering. The use of Recycled Aggregate Concrete (RAC) has several advantages in terms of conservation of natural resources and of reduction of pollution. Although the interest on the use of structural concrete with recycled aggregates is increasing, extensive studies on the mechanical behaviour of such materials that can allow their use in alternative to standard concrete are still lacking. As a conse...
Autori: Marco Breccolotti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26776

Abstract Sustainability issues have driven academic researchers towards the definition of methodological tools to assess the impacts derived from products and services and to make them more ecologically friendly, economically profitable and socially suitable, and whose results have to be clear and understandable to a broad public. In the evaluation of complex socio-environmental systems, like agricultural ones, uncertainty often arises and the quality of decision processes can be a high conc...
Autori: Anna Irene De Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26779

Abstract The Bio.Lea.R project aims to demonstrate the performance of a landfill for less reactive, biologically treated waste (pretreated organic wastes) compared to a conventionally managed landfill, with regard to both environmental (biogas and leachate production) and economic aspects. The objective is to control the pretreated biodegradable waste through a liquid injection in order to achieve the same biogas quantity in a shorter time than in conventional landfill. Laboratory and full ...
Autori: Alberto Godio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26784

Abstract The use of non-conventional water resources including treated municipal wastewater has been increasing in the Mediterranean regions over the last decades to cope with water shortages and uneven rainfalls due to climate change. The aim of this paper is to present the first results from two years of experimental field activities carried out in two different demo-places in Southern Italy: the municipal wastewater treatment plants of Noci and Castellana Grotte (Apulia region). In these ...
Autori: Antonio Lonigro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26787

Abstract It has been recently shown that acid activation enhances the ability of zeolitic tuffs to bind weak organic bases. More specifically, tuff containing acid-resistant zeolites (i.e. clinoptilolite) exhibits higher sorption capacity than chabazite/phillipsite-rich tuff. Based on the above considerations, we investigated in depth the adsorption behaviour of two pesticides onto acid-activated clinoptilolitic tuff under different experimental conditions. The pesticides simazine and boscal...
Autori: Stefano Salvestrini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26791

Abstract The feasibility of humidification-dehumidification utilizing waste heat from exhaust gas was investigated. The exhaust gas below 100°C was used as the heat resource and to evaporate the salt water. The effect of operation conditions on the fresh water productivity and thermal efficiency was studied, including the salt water flow rate, exhaust gas flow rate and temperature. The performance of this process was discussed from the view of temperature field, and the temperature field...
Autori: Huaigang Cheng
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26812

Abstract Braila Small Island is situated on the Danube, in Braila County, Romania being considered a protected area, in the category V IUCN - Natural Parks. Because of aggressive tourism, inappropriate behaviour of the tourists as well as of the residents, as well as of the fact that the navigation channels are open and the transit is made by engine boats, the whole ecosystem is endangered by noise pollution. The purpose of this paper is to determine the level of the noise pollution emerging...
Autori: Mihaela Picu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26823

Abstract An experimental study on the hydrodynamics of fixed, fluidized and spouted granular bed was performed. With this aim two commercial adsorbent materials and a composite material obtained by impregnation with a hygroscopic inorganic salt were employed. The fluid phase consisted in dry air. The obtained results highlight the influence of grain size, material density and roughness over pressure drop and gas velocity. Increasing grain size leads to decreasing pressure drop and increasing...
Autori: Ioan Solomon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26854

Abstract This work presents the optimization of process variables to maximize the percent of Fe (II) removal, R (%), by chelating resin Purolite S930 from 34% CaCl2 solutions. To study the combined effect of the initial solution pH, initial Fe (II) concentration and resin dosage was used a 23 orthogonal central composite design and Response Surface Methodology (RSM) for analysis of experimental data. To optimize the regression equation was used The Gradient method. The study discovered that ...
Autori: Camelia Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26856

Abstract Free cells of Rhizopus oryzae were used to study adsorption of several cations (Cu2+, Zn2+, Mn2+, Ni2+, Cd2+ and Pb2+) from wastewater within various experimental conditions. The influence of biomass dosage, pH and temperature on the removal process was investigated. The sorption efficiency increased with increasing the temperature in the range from 25 ºC to 30 ºC and pH from 5 to 8. The maximum removal percentage was achieved at a biosorbent concentration 0.25 – 0.3...
Autori: Kolishka Tsekova
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26857

Abstract The atmospheric air is considered a large and renewable source of fresh water. The present work investigates the application of solar energy to heat wick clothes impregnated with calcium chloride to extract water from atmospheric air. A wick desiccant solar collector is erected at Tanta – Egypt for this purpose. The desiccant concentration at the beginning of regeneration is determined according to the climatic conditions. The saturated wick desiccant is exposed to an ambient ...
Autori: Abd elnaby Kabeel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26861

Abstract The adsorption of phosphorus (P) on sediment plays a significant role in phosphorus transport in aquatic systems. This research examined the effect of the main components of sediments (including iron (Fe), manganese (Mn) oxides and organic matter (OM)) on P adsorption and to evaluate their relative contribution with different sediment particle sizes. The sediments were separated into four particle-size fractions: 0-30 μm, 30-62 μm, 62-90 μm, and 90-125 μm, and then selec...
Autori: Yang Xiao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26873

Abstract The aim of the present study was to determine the most feasible experimental conditions for the dissolution of base metals (Cu, Ni, Zn, Pb, etc.) from waste printed circuit boards (WPCBs) obtained from WMP. The leaching of WPCB samples was performed with FeCl3 in HCl solution which allowed the separation of a precious metal rich solid residue and a high base metal concentration solution adequate for base metal recovery. The most favorable conditions for the leaching process were ide...
Autori: Szabolcs Fogarasi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26877

Abstract Phytoremediation tests on heavy metals bioaccumulation were performed during 2012-2014 with aquatic species Lemna minor, Pistia stratiotes, Eichhornia crassipes, Vallisneria spiralis, Hydrilla verticillata, Cladophora glomerata on samples of contaminated waters collected from the toxic pond of waste landfill Şomârd-Mediaş, Sibiu County. With the purpose to check the species capacity for heavy metal removal and bioaccumulation, comparative analysis of water samples wa...
Autori: Dana Malschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26882

Abstract In this study, activated carbon was synthesized from durian peel and used for the removal of lead (II) ions from water. The activated carbon was produced with physical activation method using CO2 as the activating agent at 900 oC. Prior to the activation process, durian peel was carbonized under either nitrogen atmospheric or vacuum pyrolysis in order to compare the properties of the synthesized activated carbons. Suitable adsorption kinetics and isotherm models for the lead (II) re...
Autori: Samorn Hirunpraditkoon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26901

The biosorption of a basic dye, safranin from aqueous solutions by marine fungus Aspergillus wentii, which was chemicallymodified by esterification of the carboxylic acids (CB), or methylation of amine (NB), or raw biomass (RB) was investigated. The equilibrium was established after 40 min and the experimental kinetic data obtained for various forms of A.wentii were applied to the pseudo-first order, pseudo-second order, Bingham and Weber-Morris kinetic models. The pseudo-second order model ...
Autori: Yasmin Khambhaty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26930

Adsorptive removal of dibutyl phthalate (DBP) by bamboo biochar (BC) was investigated under various experimental conditions. BC demonstrated excellent sorptive ability to remove DBP from the aqueous solutions. The removal of DBP by BC increased as the contacting time increased and reached an equilibrium value after 240 min. The presence of natural organic matter decreased the removal efficiency while increased the time to reach sorption equilibrium. The adsorption of DBP on BC could be well ...
Autori: Junliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26934

In this paper, the classical adiabatic model was chosen. The assumption of perfect gas working fluid was replaced by that of a real gas working fluid. This last assumption was defined by the van der Waals state equation. A Gamma type Stirling engine functioning with a maximum filling pressure of 10 bars was used to carry out experiments. Both theoretical models: the Perfect Gas Adiabatic Model (PGAM) and the Real Gas Adiabatic Model (RGAM) were applied to the Gamma Stirling engine. The influ...
Autori: Ramla Gheith
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26937

The influence of key process parameters of homogenous catalytic ozonation using ferrous or manganese catalysts on the mineralization rate of salicylic acid (SA), model pharmaceutical pollutant, in water was investigated. In order to assess the combined influence and interactions of studied process parameters as well, the empirical/statistical approach applying Box- Behnken experimental design (BBD) combined with response surface methodology (RSM) was applied. Three numerical and one categori...
Autori: Kresimir Koricic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26939

In this study, response surface methodology (RSM) method was applied based on a five-level and four-variable central composite design. The optimization of the C.I. Direct Red 81 (DR81) removal by the combination of electrocoagulation (EC) and UV processes was also performed. The effect of initial pH, reaction time, current density and initial dye concentration on the dye removal was investigated to obtain the optimal experimental conditions. The optimal conditions with the dye removal of 95% ...
Autori: Elmira Pajootan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26942

In the context of sustainable development, focus must be set on reasonable use of natural and energetic resources, which is a real must at present. Besides these, material and informational resources add up to give the full picture of sustainable development resources. The paper introduces a valid solution of powdery waste recycling into pellets for the steelmaking industry. The pellets are obtained from powdery wastes (steel plant dust, red sludge, lime dust, dolomite waste, waste limestone,...
Autori: Ana Virgina Socalici
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26944

This paper studies, in lab scale, the possibility of removing a rich-in-pollutant soil fraction using flotation, with the clean fraction been restored to its natural condition. The tests were carried out in a conventional flotation cell with mechanical agitation. Artificially polluted soil was used throughout this study by mixing soil with diesel fuel. The effect of the following flotation factors was studied: pulp pH, collector type and quantity, conditioning and flotation time, initial soil...
Autori: Nickolaos Georgiou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26960

The adsorption characteristics of nitrate ions from aqueous solution using Lewatit FO 36 was investigated as a function of pH, biomass dosage and contact time. Results showed that optimum conditions were obtained at pH 8, adsorbent dosage of 160 mg/L and contact time of 60 min. At the optimized experimental parameters, the maximum nitrate adsorption capacity of Lewatit FO 36 was 200 mg/g and nitrate adsorption followed Freundlich model. Among seven kinetic models used in this study, the adso...
Autori: Mehdi Ahmadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26996

In this study, it was aimed to determine the relationship between the temperature decrease of the air passing through the pad and flow rate of pad wetting water for pad evaporative cooling. In the experiments, a commercially available cellulose based evaporative cooling pad (CELdek®7060-15 pad) was used. Experiments were conducted at three different water flow rates (2 L min-1 m-2; 4 L min-1 m-2 and 6 L min-1 m-2) and two different air velocities (1.0 m sec-1 and 1.5 m sec-1). The tempera...
Autori: Cengiz Karaca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27006

The aim of this study was the diversification of fodder yeast assortments with viable economic effects while reducing the pollution to the environment by capitalisation of wastewaters with high monosaccharides content from pulp and paper industry. As inoculum, in the bioreactor, a mixture of two species of yeasts Candida utilis and Candida arboreea (1:1 ratio) was used at 38°C, pH 5.5 and an air flow of 0.02 L/h was insured. Wastewaters from technological process of pulping of softwood wi...
Autori: Andrei I. Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27028

Maghemite nanoparticles (γ-Fe2O3) were synthesized in order to be used as magnetic adsorbent for two heavy metals, Pb(II) and Zn(II), from aqueous solutions. γ-Fe2O3 was prepared from magnetite nanoparticles and was tested for single and binary aqueous solutions. Efficiency removal (%) for single solutions appears only after 10 minutes and was higher than 80%. In case of binary solutions, same results regarding efficiency removal were registered after 60 minutes, being almost 90% ...
Autori: Ecaterina Matei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27029

This paper presents a research on ways to reduce waste and to diminish sound pollution by recovery of fir sawdust and recycled rubber granules and use in making sound absorbing composite materials. Four materials were prepared using raw materials (fir sawdust and recycled rubber granules) in various percentages, and polyurethane binder. Materials mechanical and acoustic properties were characterized, proving these materials have useful properties. Materials acoustic performance was compared w...
Autori: Ancuţa Elena Tiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27039

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

This work evaluates the potential of Phyllanthus debilis for the adsorption of Zn2+ and Ni2+ ions using synthetic solutions. Adsorption experiments were performed in order to examine the effect of pH, contact time, biomass concentration and initial metal ion concentration in the removal process, in a batch mode. The results revealed that the adsorption is highly pH dependent. The adsorption of Zn2+ and Ni2+ ions were concentration dependent and increased from 2.446 to 8.688 mg/g for Zn2+ and ...
Autori: Mohammad Aslam
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27084

Experimental research focus on the emission characteristics of a diesel engine employed a new combustion system-double swirl combustion system (DSCS) is carried out. The influence of spray angle on diesel emission characteristics with DSCS is analyzed by experimental and numerical method. Main emissions such as particulate matters (PM) and nitrogen oxidants (NOx) are measured in diesel engine with DSCS and the original engine. Also, fuel consumption, combustion pressure, heat release rate are...
Autori: Liwang Su
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27087

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

Biological control relying on soil microorganisms may offer feasible and sustainable perspectives in many agrosystems for management of soil pests such as root-knot nematodes (RKNs, Meloidogyne spp.). The rhizosphere environment shows a complex of soil microbial communities, including beneficial organisms such as specialized bacterial pathogens and/or of rhizosphere fungi. New advanced technologies like Next Generation Sequencing (NGS) may enlarge our knowledge about the biodiversity and rol...
Autori: Aurelio Ciancio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27109

Acetophenone can be enzymatically produced by conversion of methylbenzylamine using transaminase. The enzymatic process is strongly affected by the product inhibition, thus requiring the acetophenone removal from the media during its synthesis. In this purpose, the individual and selective extraction of acetophenone and methylbenzylamine with the biocompatible solvent nheptane containing 1-octanol, D2EHPA or TOA has been analyzed at three values of pH (5, 7, and 9). Regardless of the solvent ...
Autori: Lenuţa Kloetzer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27111

The goal of this paper is to determine the characteristics of a Stirling engine able to be used by a micro-solar power plant as energy conversion system. The purpose is to use solar energy as heat source and a Stirling engine because of its numerous advantages, as its high (theoretical) efficiency. This work was made in collaboration with several industrials involved in the project named MiCST, whom objective is to electrify remote villages in Africa. Results of a simple 0-D model built on M...
Autori: Nadia Martaj
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27116

Sequencing Batch Biofilter Granular Reactors (SBBGRs) represent an innovative technology; coupling granular and attached biomass and operating in a batch mode. These systems allow good removal rates with low sludge production and space requirement. A particular application, consisting of an aeration unit and an upflow SBBGR in series, has been tested at pilot scale. The pilot system was installed at a conventional activated sludge plant and fed with average-strength urban wastewater after pre...
Autori: Paolo Cirello
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27123

In this study, the toxic effects of binary mixtures of Pharmaceutical Active Compounds (PhACs) that are observed in the effluents from a wide range sewage treatment plants and surface water bodies were investigated using the bioluminescent bacterium Aliivibrio fischeri (Microtox® test). The selected chemicals were the nonsteroidal anti-inflammatory drug (NSAID) diclofenac sodium [DCF] and the anti-epileptic carbamazepine [CBZ]. In addition, caffeine [CFF], a psychoactive stimulant of the...
Autori: Valeria Di Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27126

In this study, the impact of silicate admixture in 2-line ferrihydrite on its sorption properties is presented. Synthetic ferrihydrites with broad Si content in the range of 0 to 1.5 Si/Fe molar ratios were prepared and characterized using X-ray diffractometry (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM-EDS). With an increase in the Si/Fe ratio, a typical XRD peak at 2.5Å broadens and shifts toward 3 Å; the position of Si-O stretchi...
Autori: Gabriela Pieczara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27140

The objective of this research was to study the degradation of chloramphenicol (CAP) in soil using activated carbon fiber supported nanoscale zerovalent iron (ACF/nZVI) coupled with microwave (MW) irradiation. Compared to ACF/MW, nZVI/MW and MW alone, the ACF/nZVI/MW system had a higher degradation efficiency. A Box-Behnken experimental design was employed to analyse relative significance of independent variables A (irradiation time), B (MW power), and C (MW absorber dosage), and combined ef...
Autori: Wengui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27154

It is of great concern to reduce greenhouse gases (GHG) and ammonia (NH3) emissions from animal manure composting in China. The purpose of this study was to investigate effects of adding red mud on emissions of GHG (methane (CH4), nitrous oxide (N2O)) and NH3 in full-scale swine manure windrow composting. Two full-scale swine manure windrow composting experiments were carried out to compare emission of GHG and NH3 with and without addition of red mud. Results showed that the addition of modified...
Autori: Chenyang Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27158

The adsorption of tartrazine from aqueous solution was evaluated using an iron (III) modified zeolitic tuff. The adsorbent was characterized by scanning electron microscopy and X-ray power diffraction; the modification process does not affect the crystalline structure of the zeolitic tuff. Sorption kinetic, isotherms, dose and pH effects were determined and the adsorption behavior was analyzed. The sorption equilibrium was reached in 72 hours, the adsorption capacity determined by the Langmuir m...
Autori: Adrián Alcántara-Cobos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27182

The aim of this research is to investigate adsorption characteristics of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) complexes with MGDA (methylglycinediacetic acid) from aqueous solutions by using the multifunctional chelating ion exchanger Diphonix. MGDA, belonging to a group of new generation complexones which readily undergo biodegradation, is patented by BASF and marketed under the brand name Trilon M. Optimum adsorption conditions were determined as a function of phase contact time, ...
Autori: Justyna Jachuła
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27183

The adsorbent gels utilized in this research project were synthesized from non-commercially available chitosan, obtained by deacetylation of chitin, which was isolated from fermented shrimp waste by a major local industrial food biopolymer. Chitosan-based adsorbent gels were used for the removal of a tris-azo dye (Direct Blue 71) from aqueous solutions. Sorption experiments focused on the chemical modification of chitosan using two cross-linking agents, sodium tripolyphosphate (TPP) and glutaral...
Autori: Reyna G. Sánchez-Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27184

Hesperaloe funifera was studied as a new raw material for paper manufacturing and lignin recovery. An experimental design was carried out to improve the quality of the obtained pulp varying the process temperature (155, 170 and 185 ºC), time reaction (20, 40 and 60 minutes) and soda concentration (5, 10 and 15 %). All experiments were carried out with 1% anthraquinone. Lignin content, holocellulose content, α-cellulose, viscosity, Kappa number and drainability were determined in the d...
Autori: MŞ Ángeles de Andrés
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27185

There has been a growing amount of work on microbial fuel cells (MFCs) in the last years, both on the microbiological issues and on the engineering ones, which managed to increase power outputs by an order of magnitude. However, they are technically still far from attaining acceptable levels of power output. Therefore, it is necessary to go deeper in understanding the mechanisms involved in electricity production with MFCs and use this new knowledge to achieve significant increases in power outp...
Autori: Vânia Oliveira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27187

A natural Cretaceous sodium (Na) bentonite from North Patagonia, Argentine, is considered a potential construction material for landfill liners. It is studied alone and in mixtures with sand. Physical and chemical properties of the Na-bentonite were determined to verify the suitability of this material for the construction of low permeability mineral liners. Hydraulic conductivity measurements were conducted on pure bentonite and on mixtures of poorly graded sand with 3, 6, 9 and 12% of Na-bento...
Autori: Telma Belén Musso
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27190

In this paper low power microwave radiation impact on Zea mays root meristeme tissues was investigated. Seeds with uniform genophond were exposed for 3 hours at 10 W incident power level in controlled condition to continuous wave at three different frequencies (0.6 GHz, 1 GHz and 2.5 GHz) and let to germinate after electromagnetic exposure. Dosimetric assessment made experimentally and computationally allowed the proper energetic characterization of the interaction between vegetal tissue and rad...
Autori: Mihaela Răcuciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27196

Various azodyes containing one or more sulfonic groups were removed from aqueous solutions by biosorption on untreated wood shavings from Picea abies. The sorption kinetics was described by the pseudo-first-order (PFO), pseudo-second-order (PSO) and modified pseudo-n-order (MPnO) equations, from which the MPnO model provided the best fit to the experimental data. The surface reaction was identified as a rate-limiting step governing the dye sorption on wood shavings, but a mixed kinetics (with a ...
Autori: Pavel Janoš
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27207

Intensive cereal crops planted on soils from the Western part of Romania determine, annually, significant losses of essential microelements and macronutrients for plant development from the agricultural soil, which lead to the depletion of such lands. Fly ash (FA) resulted from coal combustion at the CET Timisoara power plant, can be used as supplement to an organic fertilizer, such as manure (M) to restore the balance of micro- and macronutrients, important to obtain healthy cereal crops and hi...
Autori: Smaranda Masu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27208

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

In this study, the biosorption of zinc(II) ions from the aqueous solutions by the lichen biomass of Xanthoria parietina (L.) Th. Fr. was studied as a function of contact time, initial pH of metal solution, biosorbent concentration, initial metal ion concentration and stirring speed in a batch system. The optimum pH value for maximum zinc biosorption was found to be 5.5. Concentrations intervals from 50 mg/L to 250 mg/L were tested and it was observed that the biosorption efficiency depends on th...
Autori: Zuleyha Bingul
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27213

Banana stalk (BS) waste is used to remove Pb2+ from aqueous solution. Equilibrium data were analyzed with Langmuir and Freundlich adsorption models, which fit better in the former equation. The qmax (maximum metal uptake capacity) for Pb2+ adsorption was 105.14 mg/g of BS at pH 5.0, which followed pseudo-second order kinetics model. IR spectra confirmed the participation of hydroxyl, amino, and acidic functional moieties in the removal of Pb2+. The major mechanism involved in the biosorption of ...
Autori: Kashif Iqbal Sahibzada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27214

Adsorption equilibrium, kinetic and dynamic studies were done for removal of zinc (II) from aqueous solutions using alunite ore. The alunite sample was characterized by using X-ray fluorescence (XRF), optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) porosimetry, differential thermal (DTA), and Thermogravimetric (TG) analyses. The batch equilibrium adsorption data of zinc (II) ions onto alunite particles were applied to some...
Autori: Hoda Arabyarmohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27216

Stillage (distillery wastewater) is a major waste by-product from process of bioethanol production. It contains large amounts of organic matter and suspended solids, so it should not be disposed in the nature before previous treatment. This work studies the application of ceramic microfiltration membrane for stillage purification. Also, the influence of operating factors on permeate flux and removal efficiency was investigated using Response Surface Methodology. The factors considered for design...
Autori: Vesna Vasić
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27218

The mixed microbial culture, isolated from the aerobic sludge was used to study biodegradation of 1,1-DCE as the sole carbon source in batch flasks. 1,1-DCE initial concentration in the medium was varied from 100μg/L to 1000μg/L. The maximum removal rate of 1,1-DCE was 89.2% obtained at 400μg/L 1,1-DCE concentration in the medium. The biodegradation kinetics of 1,1-DCE was found to follow three-half-order model at all initial 1,1-DCE concentrations with regression values greater than 0....
Autori: Shizong Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27219

In the present study, the effect of chitosan as an eco-friendly coagulant aid was investigated for removing turbidity (bentonite) and humic acid (HA) in the coagulation process. The effects of various operational parameters such as initial pH of the solution (4-9), dosage of chitosan (1-4.5 mg/L), dosage of alum (10-40 mg/L) and initial turbidity (10-150 NTU) were investigated. An artificial neural network (ANN) model was used to predict the performance of turbidity removal efficiencies by coagu...
Autori: Abdolmotaleb Seid Mohammadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27223

In this study, an upflow anaerobic sludge blanket (UASB) bioreactor at the mesophilic temperature (38ºC) was successfully used for the treatment of petroleum refinery effluents. Response surface methodology (RSM) was applied for the design and analysis of experiments to predict the behavior of the initial COD and the hydraulic retention time (HRT) in the bioreactor. A statistical analysis indicated that the models adequately represented the experimental data. At the optimal conditions, the ...
Autori: Seyed Omid Rastegar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27233

This paper describes laboratory experiments conducted to investigate groundwater flow and solute transport within the capillary fringe (CF) and exchanges between the CF and the region below the water-table. An experimental bench was developed in order to simulate an unconfined aquifer, to observe the development of the CF and to study nitrates transfer from groundwater to CF, and also the fate of nitrates into the CF. The experimental bench has three compartments, the middle one being filled wi...
Autori: Mihaela Amalia Diminescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27277

The paper presents some aspects regarding the use of certain bark biomass as sustainable and renewable fuel. The main bark uses are listed exhaustively, emphasizing the fact that they are parts of the forestry biomass. The main problems arising from the ecological burning of bark are highlighted, namely the amount of ash and the resulting gases, especially carbon dioxide, but the emphasis is placed on the amount of heat and ash that bark produces during combustion. Accordingly, the high and low ...
Autori: Aurel Lunguleasa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27288

The level of dissolved oxygen (DO) in the water downstream hydro power plants is an essential parameter which allows preservation and development of the aquatic habitat. The objective of this paper is to identify a new technical solution that contributes to the increase of DO level in the water passing through the turbine. The current technical solutions improve the DO level but affect the hydraulic efficiency of the turbine. There is no general technical solution for aeration of water used by h...
Autori: Florentina Bunea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27296

According to literature, aggregate stability of soils is influenced by: particle size and soil texture, soil structure, content of Ca2+ and Mg2+, mineral clay type, soil content of organic matter, soil processing degree. This paper aims to investigate the influence of some physical, microbiological and chemical properties of saline soil concerning water-stable aggregate. The hydro system stability of the aggregates appears in the specialized studies as having a positive correlation with microorg...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27300

Ground water is an important source of clean water supply throughout the world. A growing literature on the management of groundwater which takes into account the interaction of groundwater with surface water resupply sources (e.g., streams or lakes) is driven by concerns of intensified global fresh-water use coupled with increasing industrial and agricultural pollution levels. Our joint laboratory and numerical experiments simulate water withdrawals via two pumping wells from an unconfined aqui...
Autori: Anca Marina Marinov
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27302

The present work illustrates the results of a long-term field experiment with sewage sludge used on agricultural land in order to assess the influence of sewage sludge on wheat crop productivity. The experimental research was conducted for three years as following: the evaluation of the agricultural use of sewage sludge in the year of application and its residual effect in grain and in soil for the next two years. The sewage sludge considered in the framework of the study was from Sfantu Gheorgh...
Autori: Diana Mariana Cocarta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27303

Construction industry uses a huge quantity of traditional and modern building materials which generally are produced to satisfy different demands, such as: resistant and safety requirements, friendly with the environment, architectural aspects etc. Researches must solve any requirements related to materials properties and offer a large diversity from which the proper solution must be considered. For improving the mechanical properties of polymer concrete, the use of fibers of different types is ...
Autori: Vasilică Ciocan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27306

The experimental results of studies on cement concrete with fly ash and metallic fibers are presented and are compared with a control mix. In the tested mixes five dosages of cement replacement with fly ash and two dosages of metallic fibers were considered. Mechanical characteristics such as compressive, flexural and split tensile strengths were experimentally determined. Tests results had shown that fly ash as replacement of cement generally reduced the mechanical strengths of concrete. In the...
Autori: Adrian Alexandru Șerbănoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27307

This paper presents some experimental results regarding mechanical behaviour at shear cutting Miscanthus x giganteus stem with an oblique blade of different edge angles. Experimental determinations were performed using samples of about 30 mm in length and a medium diameter of about 6.3 mm to 8.9 mm. The biomass was cut with three bevel cutting blades of 30 degrees, with a tool angle of 10, 30 and 50 degrees, fitted on an equipment used for mechanical experiments type Hounsfield, with a working s...
Autori: Georgiana Moiceanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27317

A possible prediction methodology for the concentration of pollutants wave in aquatic environment using Rough Set Theory is presented. The issue is of increasingly importance especially for early pollution risk warning. The hydro-morphologic complex characteristics of surface water bodies should be taken into account when pollution dispersion models are designed. However, when more characteristics/multi-criteria are taken into account, including pollutants physical-chemical ones and their enviro...
Autori: Georgeta Mădălina Aramă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27319

This study considers the removal of diclofenac (an important representative of pharmaceuticals and personal care products - PPCPs) from the secondary effluents of Iasi municipal wastewater treatment plant by means of different advanced oxidation processes (homogeneous Fenton, photo-Fenton and photolysis), carried out in a laboratory scale reaction system. The influence of three qualitative or quantitative factors (Fe3+ concentration, the absence/presence of UV-A radiation and H2O2) was studied i...
Autori: Cezar Catrinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27322

The paper aims to present the sorption properties of two sorbent substrates (composts) prepared by aerobic fermentation from vegetables waste composted with beech sawdust (BR2) and beech ash (BC1) to be used for Cu2+ removal from wastewaters. The composts structures and surface properties were characterised in terms of active groups (FTIR), crystallinity (XRD), morphology (SEM), topography (AFM) and specific surface and pores analysis (BET), and the changes in properties after Cu2+ sorption were...
Autori: Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27323

Chlorophenols, commonly found in industrial effluents, are considered as priority pollutants because they may cause severe environmental impacts and human health related problems. Nanofiltration (NF) represents an important option for the removal of chlorophenols present in aqueous effluents. This study presents some results on the performance of nanofiltration for the removal of 4-chlorophenol and 2,4-dichlorophenol from synthetic wastewaters considering the selection of adequate operating and ...
Autori: Corina-Petronela Musteret
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27324

The composition and the structure of the soil matrix have an important role in determining the water and the air regime into the soil. In the soil pore the area occupied by water and air, capillary and adsorption phenomena occur, together defining the suction of the matrix. The suction-humidity relationship varies from one soil to another, but also to the same soil in time. This paper sets out the results of investigations aimed at highlighting the influence of the composition and structure of...
Autori: Florian Stătescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27332

The global renewable energy share should reach and exceed 30% by 2030. Mini-scale hydropower installations are environmentally-friendly technologies, unlike large hydroelectric power plants that have certain drawbacks from the environmental point of view. A safe and clean solution is the cross-flow turbine, but the commercial types require a minimum head, usually captured by additional hydro-technical works that can also damage the environment. In this context, a very good solution could be a lo...
Autori: Daniela Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27343

In the economic activities related to combustible substances, it may occur possible emissions and explosive atmospheres. Some typical examples include industrial activities in general, firedamp mines and power generation in particular. The aim of this paper is to accentuate hidden aspects regarding ignition sensitivity of moisturized air methane mixtures. Therefore, the first objective of the paper is to emphasize the air humidity as an extra factor needed to be considered in relation to igniti...
Autori: Marius Darie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27351

This paper aims to study the behavior of air-gas explosion systems, in terms of propagation speed of pressure wave and flame front, based on experimental measurements in a shock tube, in order to prevent accidental pollution with the combustion gases. The characteristic parameters of the explosion process determined using the shock tube, the velocity of propagation of the flame front, the speed of propagation of the wave of pressure, explosion pressure at various distances from the source of in...
Autori: Emilian Ghicioi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27355

In order to investigate the degree of pollution by heavy metals, mining water samples were subjected to analysis, using inductively coupled plasma optical spectrometry method. An experimental module was developed and the water treatment capacity of natural zeolites was studied. The contaminated water was passed through 3 columns filled with zeolites, under static and dynamic mode in order to optimize the ion exchange process. Experiments were performed using different particle sizes of zeolite...
Autori: Andrei Szollosi-Moţa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27368

The main objective of this study was to investigate the potential utilization of polyethylene terephthalate PET waste in cementitious matrix, as substituent to cement, to develop lightweight construction materials and for preventing chemical attacks or repairing various reinforced concrete structures. Composites containing different amounts of PET particles, as partial replacement to cement by weight, were characterized by destructive and non-destructive testing. So, the thermal conductivity, ul...
Autori: Ahmed Soufiane Benosman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27381

This work presents an experimental analysis of the influence of a monocrystalline photovoltaic (PV) panels’ temperature on its main operating parameters. Victron Energy, SPM 30-12 PV panel is tested, using a double climatic chamber. The PV panel is placed as a barrier between the two rooms of the climatic chamber. The study is focused on the establishing the effect of raising temperature of PV panel over electrical parameters: voltage, current and power produced and also over the effici...
Autori: Sebastian Valeriu Hudisteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27397

• EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DE...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27398

EXPERIMENTAL INVESTIGATION OF TEMPERATURE EFFECTS ON THE PARAMETERS OF PHOTOVOLTAIC PANELS    • CONCENTRATIONS OF CHROMIUM, CADMIUM AND NICKEL IN TWO CONSUMED FISH SPECIES OF PERSIAN GULF, IRAN    • IMPROVING THE ENERGY EFFICIENCY OF RESIDENTIAL BUILDINGS BY USING A DRAIN WATER HEAT RECOVERY SYSTEM    • ASSESSMENT OF METAL CONTAMINATION AND ECOLOGICAL RISK IN URBAN SOILS SITUATED NEAR A METALLURGICAL COMPLEX    • FINANCIAL DEVELOPME...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27399

The data presented in this work has been obtained from experimental research aiming towards the usage of natural resources of the National Park of Sila in Calabria, Southern Italy. Such resources are: “Laricio” pine resin, beeswax, mineral inert and charcoal to make natural glues. Furthermore, research has been done to find out if by using small quantities of carbon nanotubes, the strength of adhesion of prepared glues improves. Raw materials were characterized by physico–ch...
Autori: Pierantonio De Luca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27402

Improving the awareness of the responsibility of our actions is the basis of achieving the ambitious aim of waste management and prevention established by the European Waste Framework Directive 2008/98/CE and the most recent Circular Economy Package. Circular Economy is connected both to improve manufacturing technologies and also educate people towards responsible consumption and waste reduction. Due to its educational and institutional role, universities provide a context to rethink not on...
Autori: Sara Rizzo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27414

Three different synthetic textile dyeing wastewaters were treated by a chemical coagulation/flocculation process, using ferric sulphate as coagulant. Polyacrylamide (Magnafloc 155) and polyamine (Superfloc C-573) based flocculants were applied. The influence of pH (between 3.5 and 10.4) and Fe3+ concentration (from 15 to 4000 mg/L) in both color and dissolved organic carbon (DOC) removal of polyester, cotton and acrylic dyeing wastewaters was assessed in the coagulation stage. As far as floc...
Autori: Carmen S.D. Rodrigues
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27427

In the present study, anaerobic treatment of food wastes from restaurants of a fermentation industry and methane gas production yields produced during the treatment were investigated. For this purpose, food wastes with a Total Solid Contents (TS) ratio of 5- 7-10% were digested in a 100l experimental reactor. Batch anaerobic digestion studies were conducted at mesophilic temperatures (36.5 oC) for 30 days and optimum Volatile Fatty Acids (VFA) and alkalinity values for methane gas production ...
Autori: Sevgi Fersiz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27429

The Artificial Neural Network (ANN) model was used to predict dye (Reactive Blue 19) removal efficiency from aqueous solution using modified pomegranate residual based on 124 experimental sets. Three-layer ANN models with different neurons numbers at a hidden layer were developed. The optimum network yielded a network error of 0.0054 and 0.9606 for mean square error and coefficient of determination, respectively. Furthermore, sensitivity analysis of the network revealed that the adsorbent do...
Autori: Elham Radaei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27439

Soil erosion by water, sediment transport, sediment deposition and their impact on watershed area are complex processes. Therefore, the state of theoretical knowledge and mathematical modeling of them are still in an incipient phase. Most of the existing mathematical models are based on relations obtained either experimentally or in laboratory conditions, either in situ or physical models; because of existence of multitude factors involved in these processes and influence each other. These m...
Autori: Erika Beilicci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27449

The problem of water and land pollution in the coastal area of the river Bor, downstream from the Bor flotation tailings, dates back to 70-year of the last century. The paper provides an attempt to restore this degraded area by flotation tailings using method of setting the neutralization layer of wasted lime –filler height 0.1 m between layers of flotation tailings and newly drifted 0.5 m height mold layer on top. The newly formed recultivated area can be used for food production, whether...
Autori: Ljubisa Obradovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27453

In many laboratories, offices and home rooms exists devices and equipment working in the radio frequency (RF) and microwave (MW) bands. People working with these equipments may be exposed to electromagnetic fields of high density that can produce adverse effects on human health. It is suitable to perform measurements on the scattered fields, especially in the near-field regions (Fresnel’ radiating and reactive regions), where the incident power density can reach dangerous levels for occ...
Autori: Sorin-Bogdan Balmus
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27466

This paper reports the possibility of using zinc ash as a secondary source for zinc oxide, which can be further used as white pigment. For the extraction of zinc from zinc ash, sulphuric acid was used. The impact of different parameters (ash fraction, contact time, sulphuric acid concentration and liquid:solid (L:S) ratio) upon the extraction degree of metallic ions from zinc ash was studied. The optimum conditions for the metallic ions extraction are: 20 % H2SO4, 30 minutes contact time, 1:1 L:...
Autori: Adina Negrea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27475

Fly ash ponds are dangerous for the environment because the fly ash can cause multiple harmful effects. This is cause for major concern for researchers and industry people alike. The rise of the water table level inside the ash structure may cause a loss of stability over time, with adverse effects on the environment. Therefore it is necessary to adopt efficient solutions to ensure the stability of ash ponds and rapid measures that can be applied. The use of geosynthetic materials has proven to ...
Autori: Lidia Niculiţă
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27483

An experimental study of the wires-two plates is presented in this paper. The principal running of these types of electrostatic precipitators is based on the corona discharge on which depend their performances. The factors affecting corona formation on wire - to- plate gaps are investigated experimentally. There are many factors affecting such corona formation. The investigated factors were the interspace between the two wires, gap length between the wire and the plate, ambient temperature, r...
Autori: Nouri Hamou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27485

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

An apatitic calcium phosphate gel (HaG) was elaborated and used to treat municipal wastewater in a physicochemical cycle prior to the standard biological degradation process. Preliminary laboratory batch experiments outlined the kinetics of heavy metal sorption by monitoring the concentrations found in filtered fractions as a function of treatment time. On site experiments were performed in a municipal wastewater treatment plant by derivation of real wastewater into an experimental tank. In this...
Autori: Nathalie Lyczko
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27488

The phenol degradation capacity of Serratia marcescens NSO9-1 isolated from olive mill wastewater was evaluated and optimized in this study. Plackett-Burman design coupled with Box-Behnken methodology was used to evaluate the effects of medium components and significant parameters on phenol degradation by this relevant strain. According to Plackett-Burman-based statistical screening, seven of the eleven components of the medium had a significant effect on the metabolism of phenol degradation. Th...
Autori: Nurdan Saraç
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27495

This study aims to obtain high performance cement under friendly environmental conditions, through the optimization of clinkerization process. The influence exerted by mineralizers i.e. fluoride (NaF, KF) or oxide (CuO, TiO2) on the Portland clinker characteristics and derived cement properties is presented in this experimental study. The presence of these additions in low concentration (i.e. 0.5-0.8 wt. %) permits the reduction of the burning temperature (with 20oC up to 70oC) of raw mix and mo...
Autori: Jenica Paceagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27500

This paper highlights the utility of rice husk ash for the adsorption of Cr(VI) ions from aqueous solutions. Rice husk ash (RHA) is produced when rice husk is burnt for various purposes. Application of Treated Rice Husk Ash (TRHA) as an adsorbent for the removal of Cr(VI) from aqueous solutions has been investigated. For this purpose, RHA was thermally treated. RHA and treated RHA (TRHA) were characterized by XRD, SEM and FTIR to investigate the effect of treatment on the nature and surface char...
Autori: Varsha Srivastava
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27504

The potential use of a novel low-cost adsorbent, Eupatorium adenophorum Spreng, as a solution to remove Cr(VI) ions from aqueous was reported. Effects of various regulating parameters, such as pH value of reaction, adsorbent dosage and temperature, were investigated. To fit the adsorption equilibrium data, Langmuir isotherm and Freundlich isotherm were invoked. Additionally, thermodynamic parameters of the adsorption process, such as ΔG, ΔS and ΔH, were also calculated. The res...
Autori: Chen Jin-fa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27535

A micelle-mediated preconcentration method has been developed for determination of Safranine T at trace amounts, which is widely used in textile industry. It can be evaluated as one of the dangereous chemicalsdue to its carcinogenicity and toxic properties. The method is based on the cloud point extraction (CPE) of Safranine T at pH 8.0 in the presence of Triton X-114 as nonionic surfactant. The obtained surfactant–rich phase (SRP) was diluted with ethanol and its absorbance was measured ...
Autori: Songül Ulusoy
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27538

It is acknowledged that organic fertilizers and wastes, such as animal slurries/manure from intensive farm enterprise, sewage sludge, poultry litter are and will continue to be spread on agricultural land and provide beneficial nutrients to crops. However, many of these materials which are also potentially polluting if not properly managed can pose a risk to groundwater and surface water quality. Generally, their distribution on the soil is performed with specialized machines to reduce the risk...
Autori: Vasilica Ştefan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27545

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

In this study major factors affecting the phenolation process of lignosulfonate (LS) waste liquor (recovered from pulp and paper industry) were optimized in order to improve LS substitution for replacing petroleum-based phenols during phenolic resin manufacturing. Four different parameters, namely phenol/lignosulfonate ratio, time, temperature and lignosulfonate waste liquor concentration, were varied in an experimental program having as response function the reaction yield. Response Surface Met...
Autori: Andrei Ionuţ Simion
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27551

There is an increasing interest in the food industry and in protective health care for the expansion of natural antioxidants from plant materials. The solid wastes generated by the winemaking industry represent about 30% of the material used and it consists mainly of grape pomace (containing seeds, pulp, stem and skin). It is well known that high quantities of valuable compounds like dietary fibre, oils from the seeds, anthocyanins and phenolic compounds still remain within the grape marc. The p...
Autori: Valeriu V. Cotea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27553

The solid-liquid extraction process and some of its influencing factors such as solid-liquid ratio, temperature and salt initial amount have been investigated. Also, mathematical modeling for mass transfer coefficients calculation was applied. An inert porous solid material (coal), impregnated with 10% and 20% mass NaCl or 15% and 30% mass CaCl2, was used. The leaching was conducted in a fixed bed column, in laminar flow. The CaCl2 impregnated samples were investigated in a column with a height...
Autori: Marcel Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27557

Fusarium Head Blight is caused by several Fusarium species. Infections can result in mycotoxin contamination on cereals and associated foods. Harvested products are contaminated due to its secondary metabolites. The aim was to analyse the occurrence of spike Fusarium and Alternaria spp. in hulled Triticum spelta L. wheat species via polymerase chain reaction (PCR) method and the deoxynivalenol (DON) content analysis. Three varieties of spelt were used (Ceralio and Rubiota – winter and one ...
Autori: Karel Suchý
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27562

The potential of Sphagnum moss peat to adsorb oxyanions (As(III), As(V), Sb(III), Sb(V) and Se(VI)) from aqueous solution was studied in batch mode. For arsenic (both species) and selenium, the results were negative: moss peat is not able to retain these oxyanion. For antimony, the hydroxyl and carboxyl groups from the Sphagnum moss peat surface seems to be responsible for Sb uptake. Kinetic studies were conducted for both Sb(III) and Sb(V) and a fast uptake process was observed, equilibrium bei...
Autori: Gabriela Ungureanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27565

This paper presents an experimental study regarding the influence of fine bubble generators (FBG) nozzles on the oxygen transfer rate from air to water, in case of pneumatic aeration processes of stationary (still) waters. This experimental study was conducted after three types of fine bubbles generators were previously computed, designed and constructed to satisfy the conditions imposed in order to provide valid experimental results. The three constructive versions were tested under similar op...
Autori: Ionela Mihaela Căluşaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27579

This study dealt with investigation of arsenic removal from groundwater using electrocoagulation (EC) method in a batch mode by the Box-Behnken experimental design method. Effects of some cations like Ca, Fe, Mg, Mn and operating time on the removal were explored by an air injected EC reactor. The combined effects of these variables were analyzed by the quadratic model for predicting the highest removal efficiency of arsenic from groundwater. The arsenic removal efficiency was found to be depen...
Autori: Mehmet Kobya
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27584

This paper presents the results of experimental tests on polymer concrete prepared with different wastes. Two types of polymer concrete mixes were compared. The control polymer concrete was obtained with epoxy resin, natural aggregates in two sorts (0-4 mm and 4-8 mm) and fly ash waste used as filler. To the control mix, both sorts of natural aggregate were replaced in different dosages by polystyrene granules waste. The influence of polystyrene granules as substitution of aggregate on density, ...
Autori: Andrei Burlacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27599

This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

A new low-cost activated carbon was developed from kiwi peel for removing Pb(II) from aqueous solution. The adsorbent characteristics were determined by different analyses such as BET, FTIR and SEM. The adsorbent demonstrated remarkable characteristics such as high surface area (306.18 m2.g-1) and large total pore volume (0.4810 cm3.g-1). The effect of pH, contact time, initial concentration, shaking rate and adsorbent dosage on the Pb removal efficiency was investigated. It was found that the o...
Autori: Mostafa Rahimnejad
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27605

Neural networks are a series of simple mathematical models, created on the architecture of human brain which gives a superior capacity of learning based on numerous connections established among neurons. The artificial neural networks have strong units of processing which are characterized by an extreme simplicity, but because of their whole interaction, the results are complex. The paper presents the comparison of two methods: mathematical regression and artificial neural network, used for pred...
Autori: Daniel Lepadatu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27608

The present work aimed to optimize a new economic medium for biopolymers production by Rhizobium leguminosarum. Biopolymers were poly-β-hydroxybutyrate and exopolysaccharide (EPS and PHB). They were extensively used in various industrial sectors. Statistical experimental designs and Response Surface Methodology were employed to optimize the medium components. A central composite design was applied to increase the production yield and predict the optimal values of the selected factors. An op...
Autori: Mohamed Sellami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27609

The study of binary biosorption of Pb(II) and Cu(II) was performed by pine nuts shell. Results were compared with the single biosorption of Pb(II) and the single biosorption of the Cu(II). Experiments were performed in batch stirred and in a continuous system. The presence of lead caused a slightly decrease of the copper biosorption yield and can be related to the copper equilibrium uptake. This antagonistic action can be related to competition phenomena between metal ions in solution for active...
Autori: Gabriel Blázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27611

The thermal degradation of kenaf (Hibiscus cannabinus) under the effect of several variables (particle size, Ar flow rate, sample initial mass and heating rate) was investigated. From experimental data and by application of various model-free methods (Friedman, Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa), the activation energies (EA) were calculated as a function of conversion. The results obtained allowed to conclude that kenaf follows a multi-stage degradation mechanism, with EA values rang...
Autori: Silvia Román
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27617

Water is currently becoming a strategically important material, and the importance of water and wastewater treatment technologies is therefore increasing. Wastewater from the food industry has many special features originating from its high organic matter content. Meat industry wastewater additionally has a high fat content. We investigated the effects of ultrafiltration and ozonation, individually and in combination, for the treatment of meat industrial wastewater. Ozone gas was generated from ...
Autori: Cecilia Hodúr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27631

The growth of a non-axenic Phormidium bigranulatum-dominated mat was tested under a range of chemical parameters and types of substrate. Total biomass yield (in term of mg chlorophyll a) of mats grown on muslin cloth (0.64 mg) and cotton mesh (0.62 mg) were significantly higher than those on other substrates, such as, nylon net (0.50 mg), sands of river Sone (0.43 mg) and river Ganga (0.30 mg), rice husk (0.38 mg) and saw dust (0.21 mg). The Phormidium mat would be easy to handle in bioremdation...
Autori: Dhananjay Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27635

The mineralization of azo dyes could be realized through solar photocatalytic degradation that is a green method where non-harmful end products are produced. The aim of this study was to investigate the mineralization of Orange G (OG) and New Coccine (NC) using ZnO as catalyst. The degradation of the azo dyes was conducted at different experimental conditions, and parameters such as effect of sunlight to the degradation rate, initial azo dye concentration, amounts of catalyst dosage, pH and effe...
Autori: Wan Fadhilah Khalik
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27643

Hexavalent chromium Cr(VI), a constituent of wastewater from many industries, is regulated by the Environmental Protection Agency (EPA) as one of the priority pollutants. Adsorption is an important technique that can be used for Cr(VI) removal from wastewater. The challenge in adsorption techniques is to find a cheap, widely available adsorbent that has a high adsorption capacity to Cr(VI). Dates stones (DS) and palm fiber (PF) are two agricultural wastes that are produced from palm trees. These...
Autori: Reda Abubeah
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27689

The reuse of sewage sludge will be increasing in the future, with expansion of sewerage works and advanced sewage treatments. During anaerobic digestion of sewage sludge from wastewater treatment plants the humification of organic matter will have an important effect on the physico-chemical forms of heavy metals. The aim of our paper was to investigate mobility of zinc from dried anaerobic sludge (DANS) from municipal wastewater treatment plant (WWTP) via single step (simultaneous) extraction pr...
Autori: Vladimír Frišták
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27695

Novel systems based on modified azo-polysiloxanes and gelatin with potential biological applications were prepared and characterized. Simultaneous rheological and UV irradiation studies allowed evidencing structural modification inside the gelatin matrix. For all analyzed samples a shift in the temperature corresponding to the physical network destructuration, from 30˚C (corresponding to gelatin) to 40˚C (for the composite) was noticed. The experimental results proved the existence of ...
Autori: Elena- Luiza Epure
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27699

This paper aims to compare the adsorption performance of activated carbon and pine bark for iron and manganese removal from contaminated groundwater. Moreover, their environmental compatibility was checked for their possible use as reactive media in a permeable reactive barrier for in situ remediation. Batch tests were carried out with different iron and manganese concentrations and different particle-size distributions, in order to evaluate the effectiveness of the activated carbon and pine bar...
Autori: Silvia Sbaffoni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27779

The adsorption rate and dynamic behavior of the system are important factors as regards the process design and operational control. The aim of this study was to find a suitable kinetic model for the hexavalent chromium removal in a batch reactor. The experimental data were analyzed using four adsorption kinetic models: the pseudo- first and second order equations, the Elovich equation, and the intraparticle diffusion equation, so as to determine the best fit equation of the Cr(VI) adsorption ont...
Autori: Ankica Radjenovic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27773

Influence of soil pH on the mechanical characteristics of glass reinforced plastic (GRP) pipes type was often investigated in different situations encountered in the field. GRP degradation is directly proportional to the exposure to soil with non-neutral reaction. The theoretical and experimental results lead during time to design standards, which allow the application of GRP pipes in water and soil, so as minimum interferences with the materials used in the manufacture of pipes would appear. Sa...
Autori: Ana Diana Ancas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27768

Bare zero-valent iron nanoparticles (bare-ZVIN) have a great tendency to aggregate, which drops their reactivity with pollutants. To address this issue, polyvinylpyrrolidone stabilized-ZVIN (PVP-ZVIN) was synthesized and used for the removal of Cd2+ from aqueous solution in a batch system. The effects of operation conditions such as the pH of aqueous solution (2-8), reaction time (0-120), adsorbent concentration (1-6 g L-1) and the initial Cd2+ concentration (10-60 mg L-1) on the removal efficie...
Autori: Amirhosein Ramazanpour Esfahani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27764

6In this paper, an application artificial neural network (ANN) and adaptive neuro-fuzzy inference system (ANFIS) are presented to predict the heat transfer rate and effectiveness in the corrugated plate heat exchangers. First, the thermal performances of the corrugated plate heat exchangers were evaluated experimentally. Experimental data were used for training and testing network. The results of the ANN are compared with the ANFIS in which the same data sets are used. The ANN model is slight...
Autori: Bayram Kılıç
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27763

The objective of this study was to evaluate the effect of different doses of meat and bone meal (MBM) applied as organic fertilizer on the quality of groundwater in arable fields. The effect of meat and bone meal fertilizer applied at rates of 1.0, 1.5, 2.0 and 2.5 t ha-1 was compared with no fertilization, mineral fertilization, and manure fertilization (10 t ha-1). Groundwater samples for chemical analyses were collected every month during the growing season using piezometers installed in the ...
Autori: Arkadiusz Stępień
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27742

Debris from deciduous trees in the form of park green waste was investigated as a potential biosorbent for the removal of chlorinated solvents from water. The sorption properties of beech leaves and cupules, oak leaves and acorns, birch leaves and lime leaves (all tree species common for a moderate climate) in a non-modified form were investigated with regard to the removal of perchloroethylene, 1,1,2-trichloroethane and 1,1,1,2-tetrachlorothane. The preliminary results showed that these biosorb...
Autori: Marek Tobiszewski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27760

In this paper, the typical measurement techniques and production procedures defined in the UNI-EN guidelines for ceramic manufacture are taken into consideration to evaluate the properties and the characteristics of the bricks produced by using a mixture containing cubilot slag. The results of the experimental tests demonstrate that these measurement techniques are not enough to define the safety of the waste bricks. Up to now, UNI-EN guidelines for ceramics do not define crystallinity measureme...
Autori: Domenico Luca Carni
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27787

This study aims to monitor Volatile Organic Compounds (VOCs) and odour annoyance perceived by the exposed population living nearby a petroleum plant through an integrated high temporal resolution methodological approach. The area under investigation is considered one of the most critical industrial areas of the South of Italy (Basilicata) because of presence of the largest Italian petroleum plant, called the "Center Olio Val d'Agri" (COVA). In fact, VOCs and odours emitted from ext...
Autori: Alessia Di Gilio
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27791

Algal bloom can represent a serious consequence of the eutrophication of surface water. Some of these algae, called cyanobacteria, are of particular interest for their effect on human health due to their capacity to produce cyanotoxins. In many countries, in fact, there are important problems of poisoning attributed to toxic cyanobacteria and contamination of water sources (specially lakes) resulting in increased cyanobacterial growth. Cyanobacteria can become particularly harmful for humans whe...
Autori: Sabrina Sorlini
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27800

This paper deals with the relevant environmental issues concerning marine sediments contamination, for which there is the need for further development of sustainable remediation technologies. Among the in-situ remediation options, the reactive capping turns out to be an interesting approach. On the other hand, when the sediments must be dredged, the stabilization and solidification (S/S) treatments can represent an efficient and sustainable solution for the recovery of the materials, in the spir...
Autori: Francesco Todaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27801

Transesterification is one of the main biodiesel production method that produces huge amount of wastewater due to the high organic substance content (COD =300000-400000 mg/L, oil and grease= 17000-25000 mg/L). Although there are several treatment methods, flotation is the current conventional treatment method for oil and grease (O&G) before the biological treatment. In this study solvent extraction method was developed for pre-refining of biodiesel wastewaters. For the solvent extraction met...
Autori: Pınar Tanattı
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27850

The goal of the present work is to evaluate the efficiency of bioventing on low permeability soils stimulated with hydraulic fractures and polluted by a mixture of semi-volatile and non-volatile hydrocarbons. A synthetic non-aqueous phase liquid (NAPL) composed of 5 hydrocarbons is prepared: 1,2,4-trimethylbenzene (TMB), methylcyclohexane (MCE), n-dodecane (n-C12), n-decane (n-C10), n-eicosane (n-C20). The capacity of indigenous bacteria to degrade high NAPL concentrations is evaluated with biov...
Autori: Dimitra N. Tzovolou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27849

In this paper, an improved engineering model and analysis techniques are presented of the fly ash particles coagulation with droplets in Venturi tubes of industrial scale, based on spatial variation of the collection efficiency of particles on individual droplets, accounting for spray water flow polydispersity and particle size distribution, which allows to define optimal droplets size and spray water flow rate at different modes of thermal power units operation. The model is validated with the ...
Autori: Igor Volchyn
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27836

Changes in material properties are examined in this work by vibration diagnostic techniques. In the article examinations of soft poly(vinyl chloride) (PVC) fibers, which were tested as vibrating strings are presented after different UV light induced aging times. The developed experimental system is presented in this manuscript and the main goal is to determine material changes as the results of artificial aging by special vibration diagnostic methods. The damped oscillations, where PVC fibers ar...
Autori: Dénes Kocsis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27841

The macrophyte Pistia stratiote was used as biosorbent for the removal of Black Krom KJR (BK-KJR) dye in synthetic aqueous solution. Initially, some tests were performed to verify the best operational conditions such as pH, biosorbent particle size, sorption temperature and stirring speed, which were later used in the kinetic and equilibrium tests. All tests were performed in duplicate. The highest removal rates of the pollutant were achieved at the process conditions of initial pH 2, granulo...
Autori: Aparecido Nivaldo Módenes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27843

This paper presents the results of experimental researches regarding the optimization of a decontamination process through thermal desorption of soils contaminated with crude oil. The optimization was performed for the following desorption parameters: heating temperature of the soil and the treatment duration, by increasing the temperature from 300°C to 350°C and decreasing the treatment duration from 10, 15 and 20 minutes to 5, 10 and 15 minutes. The economic calculation of the decontam...
Autori: Dorina Pop
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27846

There has been an increasingly awareness over the environmental impact of human activities, along with the exponential industrial growth, over the last decades. One of the negative important issues is the air pollution and its impact over the human health in recent years. Therefore, there have been initiated several laws and projects in order to monitor, analyze and forecast the evolution of the most important air pollutants. In this paper, it have been designed a multi agent system based mod...
Autori: Elia Georgiana Dragomir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27888

In this work, we report a methodology to provide emission factors based on micro-reactor studies. We propose emission factors for ammonia (NH3, 158 mg/km), nitrous oxide (N2O, 322 mg/km) and molecular hydrogen (H2, 72 mg/km) for vehicles equipped with three-way catalytic converter (TWC). Our experimental conditions were similar to those prevailing on vehicles during catalyst light-off and transient urban driving cycle. NH3 and H2 emission factors reported in this work are quantitatively simil...
Autori: Gustavo Ariel Fuentes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27899

In this study, Mg-doped ZnO nanoparticles with 2% Mg content were synthesized by sol-gel method. The structure and morphology of the nanoparticles were characterized by TEM, BET and UV-Vis absorbance techniques. From TEM image, it was found out that the nanoparticles had uniform size and uniform distribution. BET analysis revealed that in comparison with pure ZnO, Mg 2%/ZnO nanoparticles had a higher specific surface area. Based on UV-Vis absorbance analysis, Mg 2%/ZnO nanoparticles shifted t...
Autori: Nahide Zarei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27909

Latest analysis regarding the climate change phenomenon arises issues related to air quality, human comfort within urban environments and an increased energy demand attributed to the building sector. The Urban Heat Island (UHI) phenomenon is directly responsible for the poor quality of life in cities and for increased energy consumption. Characteristic features pertaining to a specific urban environment, such as local microclimatic conditions, urban morphology and anthropogenic heat release ...
Autori: Adriana Lucia Kadhim-Abid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27913

Biosorption of copper(II) by lyophilized and thermally treated bacterial biomass of Pseudomonas aeruginosa PAO1 and Pseudomonas fluorescens BME in aqueous suspension was studied. The cell surface properties were characterized and the experimental conditions, e.g., pH, adsorption time, and initial metal concentration were optimized for efficient biosorption. The surface charge was negative at pH above 2.5 for P. aeruginosa, and above pH 4 for P. fluorescens. The highest copper(II) uptake was ...
Autori: Anikó Kőnig-Péter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27917

The theoretical and computational studies of dye sensitized solar cells (DSSCs) can contribute to a deeper understanding of these types of solar cells. The DSSCs are the novel design of solar cells which could be used as power producing windows or skylights. They represent a particular promising approach to a direct conversion of sunlight into electrical energy at low cost and with high efficiency. The light adsorption occurs in dye molecules adsorbed on a highly porous structure of TiO2 film...
Autori: Nnditshedzeni Eric Maluta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27932

The aim of this study was to produce high quality activated carbons from Diplotaxis harra biomass by potassium hydroxide activation and their application in heavy metals removal. To reduce the number of experiments, full factorial experimental design at two levels (24) was carried out to occur optimal preparation conditions for efficient removal of cadmium and cobalt ions from aqueous solutions. Different variables influencing activation process, such as carbonization temperature (500–6...
Autori: Hanane Tounsadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27934

Agro-industrial waste are seen as potential precursors in the development of adsorbents for the removal of phenolic compounds, which exhibit a harmful effect to human health due to their high toxicity. This work evaluated the use of coal prepared from coconut tree agro-industrial waste, for the adsorption of phenol in aqueous solutions. Three coal samples were prepared as follows: carbonized only (Cb), activated with synthetic air (Cair) and activated with CO2 (CCO2). Based on the results of ...
Autori: Marta Duarte
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27937

The present study explores the potential use of plant waste i.e. spotted golden thistle (Scolymus maculatus L.) stalks, as an inexpensive sorbent for the removal of methylene blue from synthetic aqueous solutions. Firstly, the waste material was characterized using different analysis methods, then kinetics and equilibrium of dye sorption were investigated using a batch sorption technique. The influence of contact time, initial dye concentration, sorbent dose, particle size and agitation speed...
Autori: Zoubida Senouci Bereksi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27941

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27946

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27947

The current paper is an overview on previous and ongoing research carried out by the authors concerning the use of Computational Fluid Dynamics for the accurate classification of hazardous Ex areas generated by flammable gases, for the optimization of computational simulation of air-methane mixture explosions by using ANSYS CFX and FLUENT and for calibrating computational simulations of gas explosions using the Schlieren effect. These research works containing analytic studies have led to the...
Autori: Vlad Mihai Păsculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27962

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

• ENVIRONMENTAL CHANGES IN NORTH-EASTERN ROMANIA – A TRIGGER FACTOR FOR LYME DISEASE    • HYDROGEOCHEMISTRY AND ENVIRONMENTAL ISOTOPE COMPOSITIONS AND THEIR EVOLUTION IN GEOTHERMAL GROUNDWATER IN YIZHANG, HUNAN PROVINCE, CHINA    • CONSTRUCTION OF A BIOGAS HEAT STORAGE GREENHOUSE ECOSYSTEM UNDER THE CONTEXT OF WATER POLLUTION RESULTING FROM LIVESTOCK BREEDING    • ENVIRONMENTAL NOISE: HEALTH AND POLICY - AN UP TO DATE MINIREVIEW  &nb...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27968

The paper presents the experimental results obtained on cement concrete with different types of waste and the analysis of their effects on density, compressive strength, flexural strength and splitting tensile strength. The tests results were compared with a control mix without aggregate substitution. The fly ash was used as replacement of cement and polystyrene granules, chopped plastic bottle (PET) and wood waste were used as substitution of 0-4 mm aggregate sort in different dosages from 0% t...
Autori: Vasilică Ciocan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27978

The influence of Spathiphyllum “Sweet Silvio” flowers on indoor air quality (IAQ) and energy savings were studied experimentally in a bedroom, part of a 65 m2 three-room apartment, in Brașov, Romania. We used four 14 cm pots of Spathiphyllum “Sweet Silvio” with a total leaf surface of 134.29 cm2. The residential space has a low number of air exchange rates because exterior walls are insulated with 5 cm polystyrene, and windows have high-energy efficiency glass in ...
Autori: Gabriel Năstase
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27991

The paper presents an experimental system enabling a laboratory simulation of several types of critical situations and aggravating circumstances (sources of smoke, fog, rain, heat) using a thermovision equipment. The critical situations taken into consideration are those caused by human negligence or natural disasters such as earthquakes. Aggravating circumstances are those considered as being limit. The proposed thermovision equipment with appropriate accessories must highlight and determine...
Autori: Catalin Spulber
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27997

Our research aims to establish the influence of Osmocote®Pro fertilizer on ornamental characteristics, photosynthetic pigments content, superoxide dismutase and peroxidase activities for Lillium regale species. The tests were organized in four variants, each with three replicates, each replicate consisting of 10 bulbs. The growth of plants in the four experimental variants was achieved without fertilization in case of the control variant (M) and under fertilization conditions with Osmocot...
Autori: Maria Brînză
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28005

Dairy wastewater has been a major environmental concern because of massive effluents characterized by high pollution load. This study reports the influence of initial pH (pHi), residence time (τ) and elapsed time (t) on the %COD removal (Y1) and specific energy consumed (kWh per kg of COD removed, Y2) for real dairy industry wastewater treatment in continuous stirred tank electrochemical reactor (CSTER) using aluminum electrodes. Central composite design (CCD) was applied for designing th...
Autori: Poonam Kumari
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28011

The limited availability of fossil fuels, as well as the already proven effects of global warming, highlight the need for alternative, environmentally-friendly energy generation. Consideration of primary energy inputs from new and renewable energy resources and technologies represent a major scientific challenge, and a major innovation if realized. This will open up new opportunities for benefit and realized value, in the form of lower costs of energy supply, through the utilization of indige...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28027

Aspergillus fumigatus has been selected to bioleach the metals ion from brown shale. Process parameters like pH (5.0, 5.5, 5.8, 6.0, and 6.5), substrate concentration (2, 4, 6, 8, and 10%), pulp density (1, 5, 10, 15, and 20%), temperature (30, 35, 40, 45, 50oC) and agitation (100, 150, 200, 250, 300 rpm) were optimized according to L25 Taguchi orthogonal experimental array design that resulted in the twenty five batch bio recovery experiments. After biorecovery experiments, optimum value of ...
Autori: Fozia Anjum
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28035

In this work we aimed to examine the influence of the main abiotic factors (temperature, rainfall, relative humidity, atmospheric pressure) on the synthesis of active compounds (phenolics, flavonoids), with antioxidant and therapeutic effect of two herbs - Capsella bursa-pastoris (shepherd's purse) and Marrubium vulgare (horehound) collected from two different areas of Romania: Dobrogea (Constanta) and Muntenia (Bucharest). The studies have shown that biogenesis and accumulation of second...
Autori: Elena Neagu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28041

Several theoretical studies were oriented towards the relationship between the main two building design estimators (building energy consumption and indoor environmental quality) but very little experimental research has been carried out in order to underline the correlation between this two parameters. This paper is focused towards the experimental study of the correlation between these two design estimators. Several indoor comfort parameters (air temperature, radiant mean temperature, sound ...
Autori: Mihai Toderaşc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28042

The main objective of the research was to study the efficiency of the glyphosate amine pesticide mineralization in wastewaters (real and model type of wastewaters respectively) using ozonation treatment as an advanced oxidation processes (AOP). The wastewater samples (model wastewater) were obtained by mixing a given volume of the stock solution prepared from glyphosate isopropyl-amine in different volumetric ratios with distillated water and with real wastewater obtained from a domestic wastewa...
Autori: József Németh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28050

The influence of 50 Hz sinusoidal magnetic field on physico-chemical properties of water was studied. Tanks with distilled water (120 mL) were individually exposed to action of homogenous 50 Hz magnetic fields, using a Helmholtz coils system. For magnetically exposure have been used different values of magnetic flux density (between 1 and 5 mT) and different durations of exposure (between 5 and 240 minutes). By means of this experimental study the physico-chemical properties of exposed water sam...
Autori: Mihaela Răcuciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28061

This paper focuses on the effect of some water quality parameters of river water which helps in the calculation of water quality index (WQI) that culminates in the development of a regression model for prediction of WQI of the river system in India. The index was calculated by arithmetic index method using twelve various experimentally estimated water quality parameters such as potential hydrogen, chlorides, dissolved oxygen saturation, nitrates, sulphates, phosphates, total dissolved solids, bi...
Autori: Divya Airattil Haridas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28065

In the European Union, 88 million tons of food is wasted annually, 30% of which comes from the production and processing sectors. Among the different food waste, vegetable ones represent a remarkable share and their management is complicated by the usually high-water content and the difficult storage. In this context, the earthworms are an interesting solution because transform vegetable waste into valuable products: the vermicompost, that can be sold as organic fertilizer, and the earthworms th...
Autori: Cecilia Conti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28073

Agriculture is a highly water-demanding sector. Developed in recent years, the precision farming approach allows to optimize irrigation without compromising crops productivity. WSN networks are a key element of this approach because they allow to monitor continuously large number of parameters providing the possibility of a real-time intervention on field management practices. The WSN networks can be used to measure traditional parameters such as precipitation, soil moisture, or irradiation and ...
Autori: Sara Simona Cipolla
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28083

Sediments in coastal areas can accumulate a variety of contaminants, acting as both carriers and long-term secondary sources of contamination for aquatic ecosystems. Nowadays, there is a growing interest on developing new assessment criteria of sediment ecological quality for setting priorities and management strategies of contaminated materials. According to the literature, the weight of evidence (WOE) approach has been developed to provide a multidisciplinary characterization which combines di...
Autori: Francesco Todaro
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28089

The normal operation of spray humidification air cooler hinges on the good contact between droplets and air in the humidification chamber. The spiral pressure nozzle was chosen for the experiment on inlet air spray cooling. During the experiment, the spray cooling performance and atomization features were examined, and the cooling effects of different nozzle layouts were compared.Through the analysis of heat and mass transfer, the critical pressure of the spiral pressure nozzle was determined, a...
Autori: Xiaoqing Huang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28110

Wastewater generated from industrial activities has delivered elevated heavy metal concentrations into fresh and salted aqueous systems. Herein, the migrated trace metals were studied from their initial location through a coastal aquifer up to the seawater. The experiments were carried out at lab scale using a sandbox with glass beads and two attached chambers containing natural groundwater and seawater. The study focused on the transport behaviour of heavy metals such as copper, zinc and lead i...
Autori: Abdelkader Tawfeek Ahmed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28111

In this study we present time-related 3D ERI models for a site that was contaminated using waste automobile engine oil. The pristine geo-electrical characteristics of the site were recorded before the contamination was carried out. The purpose of the study was to progressively monitor the geo-electrical responses of the site for possible natural bio-transformations on the waste oil. Data were acquired once every two weeks for a period of three months using eight parallel 2D resistivity profiles....
Autori: Bokani Nthaba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28118

The present study represents an extension of ergosterol production by Saccharomyces cerevisiae fermentation processes using oxygen-vector by establishing the influence of the analyzed main factors, such as aeration efficiency and hydrocarbon concentration. The study has been developed for batch and fed-batch fermentation systems and has been focused on the variation of ergosterol content inside the yeast cells during the fermentation cycle in correlation with hydrocarbon volumetric fraction, COV...
Autori: Corina Ciobanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28130

The performance, in terms of sorption properties, of the two natural sorbents were compared with the commercial synthetic sorbent Fibroil. The experiments were conducted using two continuous setups of filtration under dynamic conditions. Experimental results revealed that the removal of chemical oxygen demand (COD) was 89%, 87% and 37% for Fibroil, Schoenoplectus lacustris and Acorus calamus respectively in a down-flow filtration, while with the up-flow filtration the removal efficacy of COD wa...
Autori: Zineb Chaouki
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28141

As CO2 concentration levels in the atmosphere are steadily reaching a point of no return, it is paramount that actions are taken towards mitigating emissions by improving the efficiency of existing processes. Sorption-enhanced water-gas shift (SEWGS) combines the water-gas shift reaction with in-situ adsorption of CO2 on potassium-promoted hydrotalcite (K-HTC). This enables a direct conversion of syngas into separate hot streams of H2 at feed pressure and CO2 at regeneration pressure, making th...
Autori: Vlad-Cristian Sandu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28149

Soluble dyes are intensively used in various industrial activities. They represent an important class of water pollutants from which they are rather difficult to remove. This paper focusses on the elimination of Congo Red (CR) ionic azo dye by adsorption on a low cost material. Cherry stones were used for activated carbon preparation by carbonization method. A temperature of 600 °C and a time of 4 h were found as adequate parameters for the physical activation and led to a final white powder...
Autori: Cristina-Gabriela Grigoraș
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28153

The Cellets product represents a cellulose material, which combines different properties such as the perfect sphericity, fine particle size distribution, low friability and solubility, and inertness. The experiments were carried out with Cellets 200 granulated celluloses used as a filling material for a laboratory glass column, using diluted dye solution (9-10 mg of dye /L of solution) at adequate initial pH (4.7). The effect of flow rate was investigated, and the modeling of experimental data f...
Autori: Iulia Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28155

In this work, the removal of methyl orange (MO) and Cd2+ by simultaneous adsorption on adsorbent obtained from modified charcoal (BCBH) coated with TiO2 has been studied. The synthesized materials obtained from wood branches were characterized using atomic force microscopy (AFM) for the roughness and SEM to determine the morphology of the surface. EDX spectroscopy indicates the presence of C, N, O, Na, K, P and Ti on the surface of the adsorbent materials. The micro-porosity and BET specific sur...
Autori: Nicoleta Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28157

The bio-inspired algorithms are versatile approaches that can be applied to a variety of problems. However, their efficiency is influenced by a multitude of characteristics such as quality of final solution, consumed computational resources, diversity management, convergence, complexity of the problem being solved. Consequently, the issue of choosing the best approach for a particular problem is a difficult task. In this work, the performance of two bio-inspired algorithms, Differential Evolutio...
Autori: Elena Niculina Dragoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28159

The paper covers the results of a study, carried out during 2005 and 2018, regarding the impact of sludge dump of a wastewater treatment plant from Iasi city, Romania, on the soil characteristics. Experimental research was conducted to highlight the evolution of the heavy metal content of both the material in the storage site and the soil in its proximity. The following heavy metal concentrations were analyzed with atomic adsorption spectrometry method: Zn, Ni, Cr, Pb, Co, Cu and Cd. Research ha...
Autori: Georgiana Cezarina Bartic Lazăr
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28164

Distribution of solid particles in the atmosphere around the pollution sources has an important role in decision making to oppose with air pollutants. This study reports the concentration and distribution of 11 heavy metals including Cu, Co, Ni, Cd, V, Ti, Mo, Cr, Pb, As, and Hg emitted from 6 incinerators (A to F) with various feeds and operating conditions to determine the extent of exposure for industrial and residential areas. These incinerators located at Petrochemical Special Economic Zone...
Autori: Akbar Pirbadali-Somarin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28166

The objective of the present work was to introduce a novel adsorbent with high adsorption potential toward methylene blue by decorating montmorillonite clay (MMT clay) with Zn(OH)2–nanoparticles (Zn(OH)2–NPs). The adsorbent was characterized structurally by FE-SEM and FTIR techniques. Central composite design–response surface methodology was applied to optimize experimental variables including adsorbent dosage, pH, initial MB concentration, NaCl concentration, and sonication ti...
Autori: Adel Valipour
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28173

Adsorption of diazinon from aqueous solution was studied by using cross-linked Chitosan/Carbon Nanotube (CHN-CNT) in a fixed-bed column. The cross linked CHN-CNT with 2.5% of MWCNT was prepared with a protected crosslinking method. The effects of the initial concentration of diazinon, bed-height, and flow rate on the adsorption of diazinon onto the cross linked CHN-CNT were investigated. The highest bed capacity of 29.47 mg/g was obtained at the initial concentration of 50 mg/L, flow rate of 10....
Autori: Tahere Taghizade Firozjaee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28174

The efficiency of drainage installed in clay soils using ditch backfill of soil mixed with lime is presented in this paper. The drainage ditch backfill was mixed with lime where 0.6% of soil matter consists of active CaO. The paper proposes a methodology that determines an optimal amount of lime. The experimental site was set in Kalnujai, Raseiniai district, Lithuania. The measurement of filtration in drainage trench, the arable layer and the soil between drains was performed using a double r...
Autori: Mindaugas KlimaĹĄauskas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28177

Clearly, the purpose of this paper is to find an answer to the following question “Is the ethanol additive more environmentally friendly for an SI engine or for a CI engine?”. The tests, therefore, were conducted on both an SI and a CI engine for the same parameters under both same conditions and laboratory. Ethanol was blended into neat diesel (D100) and neat gasoline (G100) at the same proportion (10 vol. %) and two blends were prepared in the study, namely D90E10 and G90E10, re...
Autori: Suat SarÄądemir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28190

In the present research, four meta-heuristic algorithms named Genetic Algorithm (GA), Gravitational Search Algorithm (GSA), Particle Swarm Optimization (PSO), and Artificial Bee Colony (ABC) have been used for optimal design of cascade spillway to minimize the construction cost. Usually, the traditional design methods such as Vittal and Porey (VP) method or experimental modeling are used to solve this problem leading to infeasible or near optimal solution. The main novelty of this paper is to...
Autori: Pedram Jazayeri
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28195

Nine samples of recycled acrylonitrile butadiene styrene (ABS) with organic montmorillonite and fire retardants adding were combined to prepare ABS copolymer nanocomposites. A very good dispersion of clay and fire retardant was noticed in the recycled ABS (reABS) matrix. The effect of montmorillonite and fire retardants on the mechanical and thermal properties of the reABS nanocomposites was further investigated. Experimental results showed that the addition of organic montmorillonite increased ...
Autori: Tudor Mihai Simionescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28203

The textile industry has been contributing to the generation of wastewater containing dyes during the dyeing process. In this sector, Reactive Blue BB is a dye used on a large scale. One method widely applied to dyes wastewater treatment is adsorption. This technique is inexpensive since it can apply industrial by-products as adsorbents. In this work, the adsorption of Reactive Blue BB dye by the sugarcane bagasse, a by-product from the sugar and alcohol industry, was evaluated in batch syste...
Autori: Handria Hariane Piffer
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28226

Release of dyes without performing adequate treatment into the water can lead to environmental risk and serious health problems. The development of effective and economic adsorbent materials for the removal of dyes from industrial wastewaters has gained great consideration in recent years. In the present study, a novel bio-based nanocomposite has been developed for ultrasoundassisted adsorption of malachite green (MG) from aqueous solutions. The synthesized adsorbent consisting of both hydropho...
Autori: Mohsen Nekoeinia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28232

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

The olive oil extraction industry is one of the most polluting wastewaters from the food industry, which is considered an important economic activity in the world. The environmental effects of olive wastewater are related to chemical and organic loading, which is resistant to biodegradation processes. The purpose of this study was to determine the efficiency of combined electrocoagulation, catalytic ozonation, to reduce organic load and improve the biodegradability of olive oil sewage. The pres...
Autori: Mohammad Reza Khani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28261

An experimental inquest was performed to quantify the turbulent flow characteristics near the eroded region of an artificial sidewall bank at three different flow depths, and a comparison study is made between before and after erosion for two Reynolds numbers. Instantaneous flow velocities were taken with an acoustic Doppler velocimeter (ADV) at near bank of the vertical side wall. The mean flows and other turbulence quantities such as Reynolds shear stress, turbulent intensities, and turbulent ...
Autori: Krishnendu Barman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28264

This study analysed the recycling of debris derived from the partial and selective demolition of concrete structures of Sant’Elia Stadium in Cagliari (Sardinia, Italy). This recycling was carried out to obtain coarse recycled aggregates for the production of recycled concrete. The experimental investigations demonstrated the possibility of using these recycled concrete aggregates in structural concrete and in precast concrete element, with unchanged production processes and suitable mechan...
Autori: Luisa Pani
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28307

The ocean is an indispensable source of materials and energy for the survival of human beings and social development. It is also an essential factor affecting climate change and ecological balance. In view of the dynamic, three-dimensional (3D), and complex marine environment, this study proposes the construction and dynamic visualization of a marine spatio-temporal process model based on Network Common Data Form (NetCDF) and optimal interpolation. The proposed model combines the advantages of ...
Autori: Xu Shenghua
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28315

This study shows the results of the experimental investigation of refinery wastewater treatment by the electro-Fenton process. The experiments were designed using Taguchi design approach with an orthogonal array (OA) of L16 runs. Four process variables (current density (CD), temperature (T), Fe2+ concentration (Fe2+), and time (t)) at four different levels were considered for the present design. Regression analysis was performed to predict a correlation for the response function (chemical oxyge...
Autori: Zainab I. Abbas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28322

The study presents the experimental testing of a heat exchanger with uniform thermal flux (HEUTF), used as a cold source in HVAC systems with heat pumps. A water-water heat exchanger is tested, having a special geometry, with uniform thermal flux along the system. The heat exchanger proposed consists of a distributor and a collector, connected to each other by means of 20 staggered copper pipes, being suitable for serving low or medium geothermal sources. The innovation consists in the uniformit...
Autori: Sebastian Valeriu Hudișteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28340

Water treatment has been extensively studied; however, only a few studies have considered it in isolated sites that do not have electric supply, which is a major inconvenience for inhabitants of rural areas. In this paper, the aim was to develop and implement a photovoltaic generator (PVG) that powers a pumping system, and water treatment with ozone. First, the PVG panel’s orientation was optimized using response surface modelling to identify the optimum operating orientation angles. Then,...
Autori: Mohammed Nadjib Brahami
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28341